KR102188303B1 - Manufacturing method of laminated interior material for construction and automobile and its laminated interior material - Google Patents

Manufacturing method of laminated interior material for construction and automobile and its laminated interior material Download PDF

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KR102188303B1
KR102188303B1 KR1020190139358A KR20190139358A KR102188303B1 KR 102188303 B1 KR102188303 B1 KR 102188303B1 KR 1020190139358 A KR1020190139358 A KR 1020190139358A KR 20190139358 A KR20190139358 A KR 20190139358A KR 102188303 B1 KR102188303 B1 KR 102188303B1
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adhesive
layer
water glass
metal
woven fabric
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KR1020190139358A
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Korean (ko)
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김남성
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김남성
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/14Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/067Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/003Interior finishings

Abstract

The present invention relates to a laminated interior material for construction and automobiles used to finish and decorate the interior of a building, a small ship, an automobile, etc. and, more specifically, to a laminated interior material for construction and automobiles, which is lightweight, has excellent soundproofing, heat insulation, and heat resistance, is not deformed even if used for a long period of time, and can maintain a deformed shape if deformed into a shape to be installed. A manufacturing method of the laminated interior material for construction and automobiles forms an adhesive mixture layer on one surface of a metal film material by mixing water, glass, and a metallic adhesive, laminates a woven fabric layer for improving sound-absorbing efficiency and flame-retardant efficiency on the adhesive mixture layer, and attaches and installs a flame-retardant sheet obtained by sequentially laminating an adhesive and nonwoven fabric on an upper portion of the fabric layer on both sides of a base material obtained by foaming a synthetic resin material.

Description

건축 및 자동차용 적층내장재의 제조방법 및 그 적층내장재{Manufacturing method of laminated interior material for construction and automobile and its laminated interior material}Manufacturing method of laminated interior material for construction and automobile and its laminated interior material

본 발명은 자동차, 소형선박, 건축 등의 내부를 마감하고 장식하는데 사용되는 건축 및 자동차용 적층내장재에 관한 것으로서 보다 상세하게는 하중이 작고 방음성, 단열성, 내열성이 우수하며 장기간 사용시에도 변형되지 않으며 설치하고자 하는 형상으로 변형하면 변형시킨 형상을 유지할 수 있는 건축 및 자동차용 적층내장재에 관한 것이다.The present invention relates to a laminated interior material for buildings and automobiles used to finish and decorate the interior of automobiles, small ships, and buildings, and in more detail, it has a small load and is excellent in sound insulation, heat insulation, heat resistance, and does not deform even when used for a long period of time. It relates to a laminated interior material for buildings and automobiles capable of maintaining the modified shape when transformed into a desired shape.

일반적으로 흡음재나 마감재, 또는 내장재 등은 건축물의 실내ㆍ외에서부터 자동차의 실내 천정에까지 매우 다양한 곳에서 쓰여지고 있다. 이러한 종래의 마감재 제조공정은 다음과 같다. 도시된 도 7에서 보는 바와 같이, 내장 마감재 제조에 필요한 길이 이상의 폴리우레탄폼(10)이 이송컨베이어(20)의 구동에 따라 이송된다. 그리고 폴리우레탄폼(10)의 상면과 하면에는 각각 4개의 롤(1,2,3,4,5,6,7,8)이 구비되어 있다. 이 롤(1,2,3,4,5,6,7,8)들에는 내측에서부터 순차적으로 각각 부직포(30)와 제1 수지필름(31), 글래스매트(32)와 제 2수지필름(33)이 안내되어 해당 위치에서 이송되는 폴리우레탄폼(10)의 상면과 하면에 위치되도록 이송된다.In general, sound-absorbing materials, finishing materials, or interior materials are used in a wide variety of places, from indoors and outdoors of buildings to indoor ceilings of automobiles. This conventional finishing material manufacturing process is as follows. As shown in Fig. 7, the polyurethane foam 10 that is longer than the length required for manufacturing the interior finishing material is transferred according to the driving of the transfer conveyor 20. In addition, four rolls (1, 2, 3, 4, 5, 6, 7, 8) are provided on the upper and lower surfaces of the polyurethane foam 10, respectively. These rolls (1, 2, 3, 4, 5, 6, 7, 8) sequentially from the inside, respectively, the non-woven fabric 30, the first resin film 31, the glass mat 32, and the second resin film ( 33) is guided and transferred to be located on the upper and lower surfaces of the polyurethane foam 10 that is transferred from the corresponding position.

즉, 1차적인 폴리우레탄폼(10)의 일면 접착 및 라미네이팅을 위하여 각 롤(1,2,3,4,5,6,7,8)에 권취된 제 1수지필름(31)과 제 2수지필름(33), 글래스매트(32)와 부직포(30)가 동일방향으로 이송되어 폴리우레탄폼(10)을 실어서 프레스(40)와 히트챔버(50) 사이에 위치된다. That is, the first resin film 31 and the second resin wound on each roll (1,2,3,4,5,6,7,8) for bonding and laminating one side of the primary polyurethane foam 10 The resin film 33, the glass mat 32, and the non-woven fabric 30 are transferred in the same direction to load the polyurethane foam 10 and are positioned between the press 40 and the heat chamber 50.

상기 히트챔버(50)와 프레스(40)는 그 사이에 폴리우레탄폼(10)이 위치되었을 때 승강 및 하강에 의하여 폴리우레탄폼(10)과 글래스매트(32) 및 부직포(30)를 열압착시킨다. 이때, 제작자의 의도에 따라 프레스(40) 또는 히트챔버(50)만 승강 또는 하강되도록 구성할 수 있으며, 프레스(40)와 히트챔버(50) 둘 모두 승하강되도록 구성할 수 있다. 또는 히트챔버(50)와 프레스(40)의 간격을 목적하는 소정 간격으로 설정해 놓고 상기 적층물을 그 틈으로 유도하는 식으로 열압착을 수행할 수도 있다.The heat chamber 50 and the press 40 heat-compress the polyurethane foam 10 and the glass mat 32 and the nonwoven fabric 30 by raising and lowering when the polyurethane foam 10 is positioned therebetween. Let it. At this time, according to the intention of the manufacturer, only the press 40 or the heat chamber 50 may be configured to be raised or lowered, and both the press 40 and the heat chamber 50 may be configured to be raised or lowered. Alternatively, thermocompression bonding may be performed by setting the distance between the heat chamber 50 and the press 40 to a predetermined predetermined distance and guiding the laminate into the gap.

상기한 유기고분자 단섬유를 압착하여 제조한 부직포 판재가 흡음특성이 우수하기 때문에 건축용 내외장재, 칸막이용 보드 등으로 활발히 사용되고 있다. 예를 들면, 한국특허공고번호 87-5764호는 섬유상의 폴리프로필렌을 잘게 분쇄하고 이에 아크릴, 폴리에스테르, 나이론 등의 화학섬유를 10mm 정도로 절단하여 소면기에 넣어 만든 웹(web)을 가열실에서 일정시간 가열한 후 절단하여 압압판으로 압축성형한 화섬판재를 개시한다. 그러나 이에 의한 화섬판재는 화섬물을 10mm 정도의 단섬유로 절단함으로써 단섬유들간의 엉킴이 적어 잘 부서지는 문제점이 있다.Since the non-woven fabric plate produced by pressing the short organic polymer fibers has excellent sound-absorbing properties, it is actively used as interior and exterior materials for buildings and boards for partitions. For example, in Korean Patent Publication No. 87-5764, fibrous polypropylene is crushed finely, and chemical fibers such as acrylic, polyester, and nylon are cut to about 10 mm, and a web made by putting in a carding machine is fixed in a heating room. After heating for a period of time, a chemical fiber plate is cut and compression molded into a pressure plate. However, there is a problem in that the chemical fiber sheet material is easily broken due to less entanglement between the short fibers by cutting the chemical fiber into short fibers of about 10 mm.

한국특허공고번호 제95-6863호는 폐화섬물을 50~ 100mm 정도의 장섬유로 절단하여 타면기에서 타면하여 솜상태로 하고 이를 일정두께의 매트형태로 한 다음 이들을 적당한 두께의 층으로 적층하여 섬유실끼리 서로 일체가 되도록 고열, 고압으로 가열가압함으로써 화섬판재를 제조하는 방법을 개시하고 있다. 그러나 이방법에 의하여 제조된 화섬판재는 고온 및 고압에서 성형되므로 섬유구성물질인 고분자 물질의 분해를 초래하게 되고 섬유의 고유특성이 상실되는 문제점이 있다.In Korean Patent Publication No. 95-6863, waste chemicals are cut into long fibers of about 50 to 100 mm, and the cotton is made into cotton by tying them on a cotton machine. After making them into mats of a certain thickness, they are laminated in layers of appropriate thickness to form fibers. Disclosed is a method of manufacturing a chemical fiber plate material by heating and pressing at high temperature and high pressure so that threads are integrated with each other. However, since the chemical fiber sheet manufactured by this method is molded at high temperature and high pressure, it causes decomposition of the polymer material, which is a fibrous material, and there is a problem in that the inherent characteristics of the fiber are lost.

한국공개특허공보 제2001-0084426호는 고융점 폴리에스테르 섬유 50중량% 이상과 상기 고융점 폴리에스테르 섬유 보다 융점이 50℃ 이상 낮은 저융점 폴리에스테르 섬유 50중량% 이하가 혼합되어 이루어진 폴리에스테르 부직포 판재를 개시하고 있다. 그러나, 이 방법에 의하여 제조된 폴리에스테르 부직포 판재는 흡음효과는 우수하지만 차음효과가 낮어서 방음효과면에서 개선의 여지를 남기고 있다.Korean Laid-Open Patent Publication No. 2001-0084426 is a polyester non-woven sheet made of a mixture of 50% by weight or more of high melting point polyester fibers and 50% by weight or less of low melting point polyester fibers having a melting point of 50° C. or higher than that of the high melting point polyester fiber. Is initiating. However, the polyester nonwoven fabric plate produced by this method has excellent sound absorption effect, but low sound insulation effect, leaving room for improvement in terms of sound insulation effect.

한국공개특허공보 제2001-0107523호는 열융착성 섬유를 함유하는 견면 또는 저밀도 부직포 판재인 피가공물을 가열판식 핫프레스에 투입하여 가열, 압축하되, 가열판식 핫프레스의 조작온도에서 가열판에 융착되지 않는 부직포 또는 직포로 적어도 상기 가열판의 압축방향에 수직하는 피가공물의 표면 및 이면을 덮어씌운 상태에서 가열, 압축하여 고밀도 부직포 판재로 성형한 후, 핫프레스에서 배출하여 상기 부직포 또는 직포가 덮어 씌어진 상태에서 냉각하는 단계를 포함하는 것을 특징으로 하는 고밀도 부직포 판재의 제조방법을 개시하고 있다. 그러나, 이 방법은 간단한 제조설비 및 공정을 통하여 품질균일성이 우수한 고밀도 부직포 판재를 제조할 수 있지만, 이에 의하여 제조된 부직포 판재도 역시 흡음효과가 우수하지만 차음효과가 낮아서 방음효과가 충분하지 않다.Korean Laid-Open Patent Publication No. 2001-0107523 discloses that a work piece, which is a soft or low-density nonwoven sheet containing heat-sealable fibers, is put into a heating plate type hot press and heated and compressed, but is not fused to the heating plate at the operating temperature of the heating plate type hot press. The non-woven fabric or woven fabric is heated and compressed to form a high-density non-woven fabric plate while covering at least the surface and back of the workpiece perpendicular to the compression direction of the heating plate, and then discharged from a hot press to cover the non-woven fabric or woven fabric. Disclosed is a method of manufacturing a high-density non-woven fabric plate comprising the step of cooling at. However, this method can produce a high-density nonwoven fabric plate having excellent quality uniformity through a simple manufacturing equipment and process, but the nonwoven fabric plate produced by this also has excellent sound absorption effect, but the sound insulation effect is low, so the sound insulation effect is not sufficient.

이와 같이, 이러한 부직포 판재가 건축내장재용으로 사용되는 경우에는 흡음 특성 및 차음 특성 이외에 일정기준 이상의 난연성을 갖추어야 한다. 특히, 미국의 경우 이러한 부직포 판재가 실내에 사용되는 건축내장용으로 판매되기 위해서는 ASTM(American Society for Testing and Materials) E84에 의거하여 탄화면적시험(flame spread test) 및 연기발생시험(smoke development test)을 하였을 때, A 등급(최우수 등급)을 만족하여야 한다. 부직포 판재에 난연성을 부여하기 위한 시도로서는 다음과 같은 것을 들 수 있다.As described above, when such a non-woven sheet is used for interior construction materials, it must have flame retardancy of more than a certain standard in addition to sound-absorbing properties and sound-insulating properties. In particular, in the case of the United States, in order to sell such non-woven sheet materials for interior use in buildings, flame spread test and smoke development test according to ASTM (American Society for Testing and Materials) E84. When you do, you must satisfy the A grade (the best grade). The following are mentioned as an attempt to impart flame retardancy to the nonwoven fabric plate.

한국공개특허공보 제2002-0014032호는 폴리에스테르 부직포 판재의 표면에 난연도료가 코팅되어 있는 난연성 폴리에스테르 부직포 판재를 개시한다. 이 방법에 의하여 제조된 부직포 판재는 난연성이 우수하여 화재시에도 불꽃이 제거되면 소화되는 자기소화성을 발휘할 수 있으나, 건축내장재 또는 칸막이용 판재로 적용될 때 여전히 흡음메커니즘에 의해서만 방음효과를 달성하고 차음효과를 발휘할 수 없어 방음효과면에서 개선의 여지가 많다. 부직포 판재에 난연성을 부여하기 위한 다른 방법으로서는 난연제가 첨가된 섬유를 이용하여 부직포 판재를 제조하는 방법, 또는 난연제 조성물로 부직포 판재를 처리하는 방법 등이 있다. 예를 들면, 폴리에스테르 부직포 판재의 경우, 옥타브로모 비페닐, 헥사브로모비페닐 아민, 테트라브로모-비스페놀 A와 같은 난연제 화합물이 첨가된 폴리에스테르 섬유를 이용하여 부직포 판재를 제조하는 방법, 또는 폴리에스테르 섬유로 제조된 부직포 판재를 2-(2,4,6,-트리브로모페녹시) 페놀, 트리스(2,3-디브로모프로필) 포스 페이트 등과 같은 난연제 화합물을 포함하는 액상조성물로 처리하는 방법 등을 들 수 있다. 그러나 이와 같이 난연제를 이용하여 난연처리를 하면, 생산단가의 대폭 증가 이외에 흡음 특성이 처리전보다 오히려 저하되는 문제점이 있다.Korean Laid-Open Patent Publication No. 2002-0014032 discloses a flame-retardant polyester nonwoven fabric plate in which a flame retardant paint is coated on the surface of the polyester nonwoven fabric plate. The non-woven fabric plate manufactured by this method has excellent flame retardancy and can exhibit self-extinguishing properties that are extinguished when the flame is removed even in the event of a fire.However, when applied as a building interior material or as a partition plate, it still achieves sound insulation effect only by the sound-absorbing mechanism and sound insulation effect There is a lot of room for improvement in terms of sound insulation effect as it cannot be used. As another method for imparting flame retardancy to the nonwoven sheet material, there is a method of manufacturing a nonwoven sheet material using fibers to which a flame retardant is added, or a method of treating the nonwoven sheet material with a flame retardant composition. For example, in the case of a polyester nonwoven sheet, a method of manufacturing a nonwoven sheet using polyester fibers to which a flame retardant compound such as octabromo biphenyl, hexabromobiphenyl amine, and tetrabromo-bisphenol A is added, or poly Treatment of a non-woven sheet made of ester fiber with a liquid composition containing a flame retardant compound such as 2-(2,4,6,-tribromophenoxy) phenol, tris(2,3-dibromopropyl) phosphate, etc. And how to do it. However, when flame retardant treatment is performed using a flame retardant as described above, there is a problem in that the sound-absorbing properties are lowered rather than before treatment, in addition to a significant increase in production cost.

상기한 종래 문제점을 해소하기 위하여 대한민국 실용신안등록 제421094호 난연성, 흡음 및 차음 특성이 우수한 건축내장재용 부직포복합판재가 제안된 바 있으며 상기한 건축내장재용 부직포복합판재는 부직포 또는 부직포의 일면 또는 양면에 금속필름을 접합한 구조로 상기 금속필름은 알루미늄 박막이 일면에만 설치되어 있을 때 금속필름층은 벽면 또는 천정에 부착되고, 직포 또는 부직포층은 실내로 노출되는 배치상태로 사용된다. In order to solve the above-described conventional problems, a non-woven fabric composite plate for building interior materials with excellent flame retardancy, sound-absorbing and sound-insulating properties has been proposed in Republic of Korea Utility Model Registration No. 421094. The metal film is a structure in which a metal film is bonded. When an aluminum thin film is installed on only one side, the metal film layer is attached to the wall or ceiling, and the woven or nonwoven fabric layer is used in an arrangement state that is exposed indoors.

그러나 직포 또는 부직포층의 양면에 금속필름층인 알루미늄 필름을 추가하여 설치하도록 하여 외관상의 손상은 발생하지 않으면서도 난연성을 향상시킬 수 있는 하고 있다.However, by adding an aluminum film, which is a metal film layer, on both sides of the woven or nonwoven fabric layer, it is possible to improve flame retardancy without causing any external damage.

그러나 상기한 건축내장재용 부직포복합판재를 1,200~1,400℃로 가열 하였을 때 알루미늄의 용융온도가 약 660℃ 정도이고 그 속에 합지된 직포 또는 부직포의 용융온도는 대략 160~200℃에서 용융됨으로 첨부도면 도 5a와 같이 앞뒤가 관통되게 연소되어 난연성 효율이 저하되는 문제와 직포 또는 부직포를 금속필름층과 접착은 일반적인 접착제를 사용하기 때문에 접착이 잘 이루어지지 않고 박리되는 문제가 있다.However, the melting temperature of aluminum is about 660℃ when the nonwoven fabric composite plate for building interior materials is heated to 1,200~1,400℃, and the melting temperature of the woven or nonwoven fabric laminated therein is melted at about 160~200℃. As shown in 5a, there is a problem in that the flame retardant efficiency is lowered by burning through the front and back, and the woven or non-woven fabric is bonded to the metal film layer because a general adhesive is used, so that adhesion is not well performed and there is a problem of peeling.

한편 종래의 건축내장재용 부직포복합판재를 자동차에 적용하여 사용하기 위하여 성형하면 플렉시블하여 강도가 낮아 형태 유지가 어려운 문제가 있고 흡음 효율 및 내화성이 저하되어 자동차 내장재용으로도 사용할 수 없는 문제도 있다.On the other hand, when a conventional nonwoven composite plate for building interior materials is applied to and used in a vehicle, there is a problem that it is difficult to maintain its shape because it is flexible and has low strength, and there is a problem that sound absorption efficiency and fire resistance are deteriorated, so that it cannot be used for automotive interior materials.

대한민국 공개특허공보 제2002-001403호Republic of Korea Patent Publication No. 2002-001403 대한민국 공개특허공보 제2001-0107523호Republic of Korea Patent Publication No. 2001-0107523 대한민국 특허공고번호 제95-6863호Korean Patent Publication No. 95-6863 대한민국 특허등록 제0151629호Republic of Korea Patent Registration No. 0151629

상기한 종래 문제점을 해소하고자 안출한 본 발명의 목적은 폴리우레탄폼으로 이루어진 기재의 양면에 금속필름과 물유리를 이용하여 화재발생시 유독가스 발생을 억제시켜 환경오염 방지 및 그로 인해 발생되는 인명피해를 방지하는 효과와 난연 특성도 우수한 건축 및 자동차용 적층내장재를 제공하는데 있다.The object of the present invention, conceived to solve the above-described conventional problems, is to prevent the occurrence of toxic gases in the event of a fire by using metal films and water glass on both sides of a substrate made of polyurethane foam to prevent environmental pollution and human injury caused by it. It is also to provide laminated interior materials for construction and automobiles with excellent flame retardant properties.

본 발명의 다른 목적은 금속 필름과 직포 또는 부직포를 이용하여 흡음 특성 뿐만 아니라 차음 특성까지 발휘할 수 있어서 방음효과가 우수할 뿐만 아니라 가열, 가압에 의한 성형성 향상과 난연성 향상과 기계적 성질이 우수한 내장재 적층체를 제공함에 있다.Another object of the present invention is to exhibit sound-absorbing properties as well as sound-insulating properties by using a metal film and a woven or non-woven fabric, so that not only has excellent soundproofing effect, but also improves formability by heating and pressurization, improves flame retardancy, and has excellent mechanical properties. In providing a sieve.

이러한 본 발명의 목적은 건축 및 자동차용 적층내장재의 제조방법에 있어서, 금속필름재의 일면에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층을 형성시키고 상기 접착혼합물층에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하고 상기 직물층의 상부에 접착제와 부직포를 순차적으로 적층한 난연 시이트를 합성수지재로 발폼되어 이루어진 기재의 양측면에 부착 설치되어 이루어진 것을 특징으로 하는 건축 및 자동차용 적층내장재의 제조방법에 의하여 달성된다.The object of the present invention is to form an adhesive mixture layer formed by mixing water glass and a metal adhesive on one surface of a metal film material, and to improve sound absorption efficiency and flame retardant efficiency in the adhesive mixture layer in the method of manufacturing a laminated interior material for construction and automobiles. Manufacturing of laminated interior materials for construction and automobiles, characterized in that a woven fabric layer is laminated and a flame-retardant sheet in which an adhesive and a non-woven fabric are sequentially laminated on top of the fabric layer is attached to both sides of a substrate formed by foaming with a synthetic resin material. Achieved by means of a method.

본 발명의 다른 제조방법으로는 건축 및 자동차용 적층내장재의 제조방법에 있어서, 금속필름재의 일면에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층을 형성시키고 상기 접착혼합물층에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하여 제1복합부재를 준비하는 제1준비공정과; 부직포의 일면에 접착층이 구비된 제2복합층을 준비하는 제2준비공정과; 상기 제1복합부재와 제2복합층을 합지하여 난연시트를 제조하는 합지공정과; 상기 난연시트를 합성수지재로 이루어진 기재의 양측면에 부착 설치하여 결합하는 마무리공정에 의해 제조된 것을 특징으로 하는 건축 및 자동차용 적층내장재의 제조방법에 의하여 달성된다.In another manufacturing method of the present invention, in the manufacturing method of laminated interior materials for buildings and automobiles, an adhesive mixture layer formed by mixing water glass and a metal adhesive is formed on one side of a metal film material, and sound absorption efficiency and flame retardant efficiency are improved in the adhesive mixture layer. A first preparation step of preparing a first composite member by laminating the improved woven fabric layer; A second preparation step of preparing a second composite layer having an adhesive layer on one side of the nonwoven fabric; A laminating process of laminating the first composite member and the second composite layer to manufacture a flame retardant sheet; It is achieved by a method of manufacturing a laminated interior material for construction and automobiles, characterized in that the flame-retardant sheet is manufactured by a finishing process of attaching and bonding to both sides of a substrate made of a synthetic resin material.

상기 직물층의 양면에 금속필름재가 더 부착되어 이루어진 것을 특징으로 하는 건축 및 자동차용 적층내장재의 제조방법에 의하여 달성된다.It is achieved by a method of manufacturing a laminated interior material for construction and automobiles, characterized in that the metal film material is further attached to both sides of the fabric layer.

상기 기재는 발포된 폼재인 것을 특징으로 하는 건축 및 자동차용 적층내장재의 제조방법에 의하여 달성된다.The substrate is achieved by a method of manufacturing a laminated interior material for construction and automobiles, characterized in that it is a foamed foam material.

이러한 상기 본 발명의 방법의 구현은 건축 및 자동차용 적층내장재에 있어서, 금속필름재의 일면에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층을 형성시키고 상기 접착혼합물층에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하고 상기 직물층의 상부에 접착층과 부직포를 순차적으로 적층한 난연 시이트를 합성수지재로 발폼되어 이루어진 기재의 양측면에 부착 설치되어 이루어진 것을 특징으로 하는 건축 및 자동차용 적층내장재에 의하여 달성된다.The implementation of the method of the present invention is to form an adhesive mixture layer formed by mixing water glass and a metal adhesive on one surface of a metal film material in a laminated interior material for construction and automobiles, and to improve sound absorption efficiency and flame retardant efficiency in the adhesive mixture layer. By laminating a woven fabric layer and attaching and installing a flame-retardant sheet in which an adhesive layer and a non-woven fabric are sequentially laminated on top of the fabric layer and attached to both sides of a substrate formed by foaming with a synthetic resin material. Is achieved.

상기 직물층과 부직포의 사이에 금속필름재가 더 부착되어 이루어진 것을 특징으로 하는 건축 및 자동차용 적층내장재에 의하여 달성된다.It is achieved by a laminated interior material for construction and automobiles, characterized in that a metal film material is further attached between the fabric layer and the nonwoven fabric.

상기 금속필름재는 알루미늄인 것을 특징으로 하는 건축 및 자동차용 적층내장재에 의하여 달성된다.The metal film material is achieved by a laminated interior material for construction and automobiles, characterized in that aluminum.

상기 직포에 무기분말이 산포되어 이루어진 것을 특징으로 하는 건축 및 자동차용 적층내장재에 의하여 달성된다.It is achieved by a laminated interior material for construction and automobiles, characterized in that the inorganic powder is scattered on the woven fabric.

상기 기재는 발포된 폼재인 것을 특징으로 하는 건축 및 자동차용 적층내장재에 의하여 달성된다.The substrate is achieved by a laminated interior material for construction and automobiles, characterized in that the foamed foam material.

상기 직물층은 유리섬유재 직포, 테프론재 직포, 케블라 직포 중 어느 하나인 것을 특징으로 하는 건축 및 자동차용 적층내장재에 의하여 달성된다.The fabric layer is achieved by a laminated interior material for construction and automobiles, characterized in that it is any one of a glass fiber woven fabric, a Teflon woven fabric, and a Kevlar woven fabric.

상기 금속접착제는 에폭시, 아크릴, 폴리우레탄 중 어느 하나인 것을 특징으로 하는 건축 및 자동차용 적층내장재에 의하여 달성된다.The metal adhesive is achieved by a laminated interior material for construction and automobile, characterized in that any one of epoxy, acrylic, and polyurethane.

이와 같은 본 발명의 내장재 적층체는 폴리우레탄폼으로 이루어진 기재의 양면에 금속필름과 물유리를 이용하여 화재발생시 유독가스 발생을 억제시켜 환경오염 방지 및 그로인해 발생되는 인명피해를 방지하는 효과와 금속 필름과 직포 또는 부직포를 이용하여 흡음 특성 뿐만 아니라 차음 특성까지 발휘할 수 있어서 방음효과가 우수할 뿐만 아니라 가열, 가압에 의한 성형성 향상과 난연성 향상과 기계적 성질이 우수한 효과가 있는 매우 유용한 발명이다.The interior material laminate of the present invention uses a metal film and water glass on both sides of a substrate made of polyurethane foam to suppress the generation of toxic gases in the event of a fire, thereby preventing environmental pollution and preventing human damage caused by it. It is a very useful invention that not only has sound-absorbing properties but also sound-insulating properties by using a woven or non-woven fabric, which not only has excellent sound insulation effects, but also improves moldability by heating and pressurization, and improves flame retardancy and mechanical properties.

도 1은 본 발명인 건축 및 자동차용 적층내장재의 제조방법을 보여주는 공정도.
도 2는 본 발명의 다른 제조방법을 보여주는 일실시예.
도 3은 본 발명인 건축 및 자동차용 적층내장재의 제조방법에 의해 제조된 적층내장재의 구조를 보여주는 단면도.
도 4는 본 발명인 적층내장재의 다른 구조를 보여주는 단면도.
도 5a는 일반적인 적층내장재를 가열하였을 때의 모습을 보여주는 사진.
도 5b는 본 발명인 적층내장재를 가열하였을 때의 모습을 보여주는 사진.
도 6은 본 발명인 적층내장재의 사용상태를 보여주는 사진.
도 7은 종래의 마감재를 제조하는 방법을 도시한 실시예.
1 is a process chart showing a method of manufacturing a laminated interior material for construction and automobiles according to the present invention.
Figure 2 is an embodiment showing another manufacturing method of the present invention.
3 is a cross-sectional view showing the structure of the laminated interior material manufactured by the present inventors manufacturing method of the interior laminated material for construction and automobiles.
Figure 4 is a cross-sectional view showing another structure of the present inventors laminated interior material.
Figure 5a is a photograph showing a state when a general laminated interior material is heated.
Figure 5b is a photograph showing a state when the present inventors laminated interior material is heated.
Figure 6 is a photograph showing the state of use of the inventors laminated interior material.
Figure 7 is an embodiment showing a method of manufacturing a conventional finishing material.

이하 본 발명의 바람직한 실시예를 첨부된 도면에 의거하여 상세히 설명하면 다음과 같다. Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

첨부도면 도 1은 본 발명인 건축 및 자동차용 적층내장재의 제조방법을 보여주는 공정도로써 이에 따른 본 발명의 건축 및 자동차용 적층내장재의 제조방법은 금속필름재(10)에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층(20)을 형성시키고 상기 접착혼합물층(20)에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층(30)을 적층하여 제1준비공정(S100)을 수행한다.1 is a process chart showing a method of manufacturing a laminated interior material for buildings and automobiles according to the present invention. The manufacturing method of a laminated interior material for building and automobiles according to the present invention is made by mixing water glass and a metal adhesive in a metal film material 10. A first preparation step (S100) is performed by forming an adhesive mixture layer 20 and laminating a woven fabric layer 30 for improving sound absorption efficiency and flame retardant efficiency on the adhesive mixture layer 20.

상기 금속필름재(10)에 사용되는 금속으로는 알루미늄박막의 필름이 바람직하며 두께는 6~50㎛의 것을 사용한다. 알루미늄박막의 필름을 사용하는 이유는 화재로부터 보호하고 열 전달을 차단하기 위함이며, 또한 성형시 형태를 유지시키면서 탄성에 의해 원상태로 복원되는 것을 방지하기 위함이다.The metal used for the metal film material 10 is preferably an aluminum thin film, and a thickness of 6 to 50 μm is used. The reason for using the aluminum thin film is to protect it from fire and block heat transfer, and also to prevent it from being restored to its original state by elasticity while maintaining its shape during molding.

상기 접착혼합물층(20)은 물유리와 금속접착제를 혼합하여 제조하되 물유리와 금속접착제의 혼합이 용이하도록 MC계열의 용가제를 물유리와 금속접착제의 혼합량의 총합이 100이라 할 때 5~15중량%를 사용한다. 상기 MC계열의 용가제를 5중량% 이하로 사용되면 혼합이 이루어지지 않으며 15중량% 이상을 사용하면 물유리의 농도가 저하되는 문제가 있다.The adhesive mixture layer 20 is prepared by mixing water glass and a metal adhesive, but 5 to 15% by weight when the total amount of the mixed amount of the water glass and the metal adhesive is 100 for the MC-series filler to facilitate mixing of the water glass and the metal adhesive. Use. If the MC-series filler is used in an amount of 5% by weight or less, mixing is not performed, and when 15% by weight or more is used, the concentration of the water glass decreases.

상기 물유리와 금속접착제의 혼합비는 물유리 50~80중량%이고 금속접착제는 50~20중량%가 바람직하다. 여기서 상기 금속접착제가 50중량% 이상이 되면 화재발생시 유해성 가스가 너무 많이 발생하게 되는 문제가 있고 20중량% 이하이면 접착력이 저하되는 문제가 있다. 상기 물유리는 내열성을 향상시키는 효과와 직물과 금속을 접합하는 접합강도를 향상시키는 효과도 있다. The mixing ratio of the water glass and the metal adhesive is preferably 50 to 80% by weight of the water glass and 50 to 20% by weight of the metal adhesive. Here, when the metal adhesive is 50% by weight or more, there is a problem that too much harmful gas is generated when a fire occurs, and when it is 20% by weight or less, there is a problem that the adhesive strength is lowered. The water glass has an effect of improving heat resistance and an effect of improving the bonding strength of bonding fabrics and metals.

한편 상기 직물층(30)은 유리섬유로 이루어진 직포를 사용하며 부직포는 사용할 수 없다. 그 이유는 상기 직물층은 내열성 향상과 공기 투과를 막기 위해 사용되는 것으로 부직포는 공극이 불규칙하게 형성되어 있어 공기를 투과가 불규칙적으로 발생되는 문제가 있다.Meanwhile, the fabric layer 30 uses a woven fabric made of glass fibers, and a non-woven fabric cannot be used. The reason is that the fabric layer is used to improve heat resistance and prevent air permeation, and the non-woven fabric has irregular pores, which causes irregular air permeation.

또한 직물층(30)은 규칙적으로 제직되어 있어 균등한 분포 하중을 나타내며 변형도 부직포와 대비 규칙하게 발생되고 열투과도 규칙적으로 투과되는 반면에 부직포는 조직 자체가 불규칙적이어서 변형도 불규칙하게 발생되고 열 투과도 불규칙하게 전달되므로 화재발생시 열을 차단하는 열차단 효과가 불균일하게 발생되는 문제가 부직포에는 내재하고 있기 때문이다.In addition, since the fabric layer 30 is regularly woven, it exhibits an even distribution load, and the deformation occurs regularly compared to the nonwoven fabric, and the heat transmittance is regularly transmitted, whereas the nonwoven fabric itself has an irregular structure, so the deformation occurs irregularly and the heat transmittance. This is because non-woven fabrics have a problem in which the heat-blocking effect that blocks heat in case of fire is unevenly generated because it is transmitted irregularly.

상기 직물층(30)은 유리섬유재 직포, 테프론재 직포, 케블라 직포 중 어느 하나인 것을 사용하며, 상기 접착혼합물층(20)을 형성하기 위한 금속접착제는 에폭시, 아크릴, 폴리우레탄 중 어느 하나를 사용한다.The fabric layer 30 is made of any one of a glass fiber woven fabric, a Teflon woven fabric, and a Kevlar woven fabric, and the metal adhesive for forming the adhesive mixture layer 20 is epoxy, acrylic, or polyurethane. use.

상기 직물층(30)을 형성시킬 때 분말 형태의 무기분말을 산포하여 사용할 수도 있다. 상기 무기분말은 세라믹 분말, 일아리트 분말, 탄소 분말, 규조토 분말, 중 하나 또는 2 이상의 혼합물을 사용할 수 있다. 상기 분말 형태인 무기분말은 화재발생시 각 소재들의 탄화시 진화를 억제하는 효과와 열 전달을 차단하는 효과를 얻을 수 있기 때문이다.When forming the fabric layer 30, the inorganic powder in the form of powder may be dispersed and used. The inorganic powder may be ceramic powder, ilartite powder, carbon powder, diatomaceous earth powder, or a mixture of two or more of them. This is because the inorganic powder in the form of a powder can obtain an effect of inhibiting the extinguishing of each material during carbonization in the event of a fire and an effect of blocking heat transfer.

한편 상기 제1준비공정(S100) 수행 후 순차적으로 접착제(40)를 직물층(30)에 도포 후 부직포(50)를 적층하는 제2준비공정(S200)을 수행하여 난연시이트(C)를 제조한다. 상기 접착제(40)로는 PE계열의 핫 멜트 파우더(Hot Melt Powder) 또는 열융착필름(Hot Melt Film) 또는 MDI계열의 액상의 접착제를 사용한다. 접착제 수용성 아크릴 접착제는 수분에 약하여 하절기시 박리현상이 발생되기 때문에 사용이 적합하지 않다. Meanwhile, after performing the first preparation process (S100), the second preparation process (S200) of sequentially applying the adhesive 40 to the fabric layer 30 and then laminating the nonwoven fabric 50 is performed to manufacture a flame-retardant sheet (C). do. As the adhesive 40, a PE-based hot melt powder, a hot melt film, or an MDI-based liquid adhesive is used. Adhesive Water-soluble acrylic adhesive is not suitable for use because it is weak to moisture and causes peeling during summer.

상기 핫 멜트 파우더는 미세한 입자로써 상기 부직포(50)와 함께 살포 또는 부직포(50) 제조 후 부직포의 일면에 살포하여 사용할 수 있고, 상기 열 융착필름은 가공처리된 얇은 수지재이다. 상기 열 융착필름을 사용할 경우, 상기 부직포(50)의 일면에 부착한다.The hot melt powder may be used by spraying with the nonwoven fabric 50 as fine particles or spraying on one side of the nonwoven fabric after manufacturing the nonwoven fabric 50, and the heat fusion film is a processed thin resin material. When using the heat-sealing film, it is attached to one side of the nonwoven fabric 50.

상기 부직포(50)는 시이트를 부착시키는 발포재의 수축과 팽창을 잡아주면서 대응하는 부재로 사용하는 효과가 있다. 즉, 동절기시와 하절기시 온도변화에 따라 미설명된 기재가 변형이 되었을 때 상기 기재의 변형량에 대하여 같이 변형되면서 제품의 변형을 방지할 수 있는 대응력이 향상되는 이점이 있다. The non-woven fabric 50 has the effect of using as a corresponding member while holding the contraction and expansion of the foam material to which the sheet is attached. That is, when the unexplained substrate is deformed according to temperature changes in winter and summer, it is deformed with respect to the amount of deformation of the substrate, thereby improving response power to prevent deformation of the product.

상기 부직포(50)가 시트이거나 필름 또는 직포일 경우 기재의 변형량에 대응할 수 없는 단점이 있기 때문이며, 상기 직물층(30)에 적층된 부직포(50)와 접착제(40)는 미도시된 가열수단에 의해 열이 전달되어 상기 접착제(40)가 융해된다. 이때, 상기 부직포(50)와 직물층(30)이 접착되는 것이다. 이후 프레스나 압연기를 통해 상기 직물층(30)과 부직포(50)에 가압된다. 공정에 따라서는 가열과 가압을 동시에 수행할 수도 있다.This is because when the nonwoven fabric 50 is a sheet, a film, or a woven fabric, there is a disadvantage that it cannot respond to the amount of deformation of the substrate, and the nonwoven fabric 50 and the adhesive 40 laminated on the fabric layer 30 are not shown in the heating means. As a result, heat is transferred and the adhesive 40 is melted. At this time, the non-woven fabric 50 and the fabric layer 30 are bonded. After that, the fabric layer 30 and the non-woven fabric 50 are pressed through a press or rolling mill. Depending on the process, heating and pressing may be performed simultaneously.

한편 도 2는 본 발명의 다른 제조방법을 보여주는 예시 공정도로서 이에 따르면 금속필름재(10)에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층(20)을 형성시키고 상기 접착혼합물층(20)에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하여 제1복합부재(A)를 준비하는 제1준비공정(S100)을 수행한다.Meanwhile, FIG. 2 is an exemplary process diagram showing another manufacturing method of the present invention. According to this, an adhesive mixture layer 20 made of a mixture of water glass and a metal adhesive is formed on the metal film material 10, and the adhesive mixture layer 20 is absorbed. A first preparation step (S100) of preparing the first composite member (A) by stacking a woven fabric layer that improves efficiency and flame retardant efficiency is performed.

또한 부직포(50)의 일면에 접착제(40)가 구비된 제2복합부재(B)를 준비하는 제2준비공정(S200)을 별도로 수행 후 상기 제1복합부재(A)와 제2복합부재(B)를 합지하는 합지공정(S300)에 의해 난연시이트(C)를 제조할 수도 있으며, 다른 방법으로는 부직포(50)만 단독으로 예컨대 접착제가 도포되진 않고 부직포만 부착된 난연시이트(C)를 제조할 수도 있다.In addition, after separately performing a second preparation step (S200) of preparing a second composite member (B) having an adhesive 40 on one side of the nonwoven fabric 50, the first composite member (A) and the second composite member ( The flame-retardant sheet (C) may be manufactured by the laminating process (S300) of laminating B), and as an alternative method, a flame-retardant sheet (C) with only the non-woven fabric without an adhesive applied alone is used as the non-woven fabric 50 alone. It can also be manufactured.

본 발명에 있어서 난연시이트(C)의 제조방법은 도 1과 같이 하나의 생산라인에서 한 번에 제조할 수도 있으나 도 2에 도시된 바와 같이 제1준비공정(S100)과 제2준비공정(S200)을 각각 별도로 수행하여 합지하는 방법 등을 이용하여 생산할 수도 있다.In the present invention, the method of manufacturing the flame-retardant sheet (C) may be manufactured at one time in one production line as shown in FIG. 1, but as shown in FIG. 2, the first preparation process (S100) and the second preparation process (S200) ) Can also be performed separately and produced using a method of laminating.

한편 첨부도면 도 4에 도시된 바와 같이 상기 직물층(30)의 양면에 금속필름재층(10)을 하나 더 부착시켜 사용할 수도 있다. 상기에서와 같이 난연시이트(C)를 제조 후 기재(60)에 부착시키는 마무리공정(S400)을 수행한다. Meanwhile, as shown in FIG. 4 of the accompanying drawings, one more metal film material layer 10 may be attached to both sides of the fabric layer 30 to be used. As described above, a finishing process (S400) of attaching the flame-retardant sheet (C) to the substrate 60 after manufacture is performed.

상기 기재와 난연시트(C)의 부착방법은 접착제를 이용하는 방법과 가열에 의한 접착방법 모두 사용 가능하며, 상기 기재(60)는 합성수지재를 발포하여 제조한 것으로 가압하여 두께를 조절한 것과 발포 상태로 된 것 두 가지 모두 사용 가능하다.The attachment method of the base material and the flame-retardant sheet (C) can be used either by using an adhesive or by heating, and the base material 60 is manufactured by foaming a synthetic resin material, and the thickness is adjusted by pressing Both can be used.

상기한 제조방법에 의해 제조된 본 발명의 건축 및 자동차용 적층내장재의 구조는 첨부도면 도 3에 도시된 바와 같이 금속필름재(10)에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층(20)을 형성시키고 상기 접착혼합물층(20)에 흡음 효율과 난연 효율을 향상시키는 유리섬유로 제직된 직물층(30)을 적층하고 상기 직물층(30)의 상부에 접착제(40)와 부직포(50)를 순차적으로 적층되어 이루어진 난연시이트(C)를 제조한다. The structure of the laminated interior material for buildings and automobiles of the present invention manufactured by the above manufacturing method is an adhesive mixture layer 20 formed by mixing water glass and a metal adhesive in a metal film material 10 as shown in FIG. 3 of the accompanying drawings. And laminated a fabric layer 30 woven of glass fiber to improve sound absorption efficiency and flame retardant efficiency on the adhesive mixture layer 20, and an adhesive 40 and a nonwoven fabric 50 on the upper portion of the fabric layer 30 A flame-retardant sheet (C) is prepared by sequentially stacking.

상기 난연시이트(C)는 부직포(50)에 접착제가 도포된 것 또는 도포되지 않는 것 모두 사용할 수 있다. 이때 상기 직물층(30)과 부직포(50)의 사이에 금속필름재(10)를 하나 더 부착 설치하여 사용할 수 있다. 상기 직물층(30)을 중심으로 양면에 알루미늄필름으로 이루어진 금속필름재(10)를 부착한 후 가열하였더니 종래의 적층내장재는 첨부도면 도 5a에 도시된 바와 같이 종래의 시이트는 관통이 되었으나 도 5b에 도시된 바와 같이 본 발명의 적층내장재는 직접 가열되는 면만이 약간 변형이 발생되는 것을 확인할 수 있었다.The flame-retardant sheet (C) may be used either with or without an adhesive applied to the nonwoven fabric 50. At this time, one more metal film material 10 may be attached and installed between the fabric layer 30 and the nonwoven fabric 50. When the metal film material 10 made of aluminum film was attached to both sides of the fabric layer 30 and heated, the conventional laminated interior material penetrated through the conventional sheet as shown in FIG. 5A. As shown in 5b, it was confirmed that the laminated interior material of the present invention slightly deformed only the directly heated surface.

상기 알루미늄재로 이루어진 금속필름재(10), 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층(20) 및 유리섬유로 제직된 직물층(30)은 가열시 용융점이 600~800℃이므로 내열성이 증가되는 효과를 얻을 수 있기 때문이다.The metal film material 10 made of the aluminum material, the adhesive mixture layer 20 made of a mixture of water glass and a metal adhesive, and the fabric layer 30 made of glass fiber have a melting point of 600 to 800°C when heated, so heat resistance is increased. This is because you can get the effect of being.

한편 상기 표면쪽에 설치되는 금속필름재(10)에 앰보싱을 형성시켜 사용할 수도 있다. 상기 앰보싱은 에어 포켓을 형성시켜 열 전달을 차단 및 방지할 수 있는 효과가 있다.On the other hand, it may be used by forming an embossing on the metal film material 10 installed on the surface side. The embossing has an effect of blocking and preventing heat transfer by forming an air pocket.

또한 상기 앰보싱에 미세 홀을 천공하여 폼을 제조시 발포된 폼이 냉각되어 경화되기 전 양쪽면에 부착는 난연시이트(C)에 나노 사이즈의 미세 기공을 형성시킬 수도 있다. 상기 미세기공은 폼에서 발생하는 가스를 배출시키기 위함이다.In addition, nano-sized micropores may be formed in the flame-retardant sheet (C) adhered to both sides before the foamed foam is cooled and cured when the foam is manufactured by drilling fine holes in the embossing. The micropores are for discharging the gas generated in the foam.

상기와 같이 제조된 본 발명인 건축 및 자동차용 적층내장재 사용은 첨부도면 도 6에 도시된 바와 같이 자동차의 인슐레이션으로 사용할 수도 있다. 이는 굴곡이 과다한 제품에 편리하게 사용할 수 있음을 확인할 수 있는 것이다.The use of laminated interior materials for construction and automobiles according to the present invention manufactured as described above may be used as insulation of automobiles as shown in FIG. 6 of the accompanying drawings. This can be confirmed that it can be conveniently used for products with excessive bending.

이와 같은 본 발명의 내장재 적층체는 폴리우레탄폼으로 이루어진 기재의 양면에 금속필름과 물유리를 이용하여 화재발생시 유독가스 발생을 억제시켜 환경오염 방지 및 그로 인해 발생되는 인명피해를 방지하는 효과와 금속 필름과 직포 또는 부직포를 이용하여 흡음 특성 뿐만 아니라 차음 특성까지 발휘할 수 있어서 방음효과가 우수할 뿐만 아니라 가열, 가압에 의한 성형성 향상과 난연성 향상과 기계적 성질이 우수한 효과가 있는 매우 유용한 발명이다.The interior material laminate of the present invention uses a metal film and water glass on both sides of a substrate made of polyurethane foam to suppress the generation of toxic gases in the event of a fire, thereby preventing environmental pollution and preventing human damage caused by it. It is a very useful invention that not only has sound-absorbing properties but also sound-insulating properties by using a woven or non-woven fabric, which not only has excellent sound insulation effects, but also improves moldability by heating and pressurization, and improves flame retardancy and mechanical properties.

10 : 금속필름재 20 : 접착혼합물층
30 : 직물층 40 : 접착제
50 : 부직포 60 : 기재
S100 : 제1준비공정 S200 : 제2준비공정
S300 : 합지공정 S400 : 마무리공정
10: metal film material 20: adhesive mixture layer
30: fabric layer 40: adhesive
50: nonwoven fabric 60: base material
S100: 1st preparation process S200: 2nd preparation process
S300: Laminating process S400: Finishing process

Claims (12)

삭제delete 건축 및 자동차용 적층내장재의 제조방법에 있어서,
금속필름재의 일면에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층을 형성시키고 상기 접착혼합물층에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하여 제1복합부재를 준비하는 제1준비공정과;
부직포의 일면에 접착제가 구비된 제2복합층을 준비하는 제2준비공정과;
상기 제1복합부재와 제2복합층을 합지하여 난연시트를 제조하는 합지공정과;
상기 난연시트를 합성수지재를 발포시켜 된 발포된 폼재로 이루어진 기재의 양측면에 부착 설치하여 결합하는 마무리공정으로 이루어지는 것으로,
상기 제1준비공정의 직물층은 양면에 금속필름재가 더 부착되어 이루어지며,
상기 금속필름재는 알루미늄이며,
상기 직물층에는 무기분말이 산포되어 이루어지며,
상기 금속필름재는 일면에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층을 형성시키고 상기 접착혼합물층에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하고 상기 직물층의 상부에 접착제와 부직포를 순차적으로 적층한 난연 시이트를 합성수지재로 발폼되어 이루어진 기재의 양측면에 부착 설치되어 이루어지며,
상기 접착혼합물층은 물유리와 금속접착제를 혼합하여 제조하되 물유리와 금속접착제의 혼합이 용이하도록 MC계열의 용가제를 물유리와 금속접착제의 혼합량의 총합이 100이라 할 때 5~15중량%를 사용하며, 상기 물유리와 금속접착제의 혼합비는 물유리 50~80중량%이고 금속접착제는 50~20중량%의 중량비로 혼합하는 것을 특징으로 하는 건축 및 자동차용 적층내장재의 제조방법.
In the manufacturing method of the laminated interior material for construction and automobile,
The first preparation process of preparing a first composite member by forming an adhesive mixture layer made of a mixture of water glass and a metal adhesive on one side of a metal film material, and laminating a woven fabric layer that improves sound absorption efficiency and flame retardant efficiency on the adhesive mixture layer and;
A second preparation step of preparing a second composite layer provided with an adhesive on one side of the nonwoven fabric;
A laminating process of laminating the first composite member and the second composite layer to manufacture a flame retardant sheet;
It consists of a finishing process of attaching and bonding the flame-retardant sheet to both sides of a substrate made of a foamed foam material formed by foaming a synthetic resin material,
The fabric layer of the first preparation process is made by further attaching metal film materials on both sides,
The metal film material is aluminum,
The fabric layer is made by scattering inorganic powder,
The metal film material forms an adhesive mixture layer made of a mixture of water glass and a metal adhesive on one side, and a woven fabric layer that improves sound absorption efficiency and flame retardant efficiency is laminated on the adhesive mixture layer, and an adhesive and a non-woven fabric are formed on the upper part of the fabric layer. It is made by attaching and installing the sequentially laminated flame-retardant sheets on both sides of the base material formed by foaming with a synthetic resin material,
The adhesive mixture layer is prepared by mixing water glass and metal adhesive, but to facilitate mixing of water glass and metal adhesive, 5 to 15% by weight is used when the total amount of mixing of the water glass and metal adhesive is 100 for the MC-series filler. , The mixing ratio of the water glass and the metal adhesive is 50 to 80% by weight of the water glass, and the metal adhesive is mixed at a weight ratio of 50 to 20% by weight.
삭제delete 삭제delete 건축 및 자동차용 적층내장재에 있어서,
금속필름재의 일면에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층을 형성시키고 상기 접착혼합물층에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하여 제1복합부재를 준비하는 제1준비공정과;
부직포의 일면에 접착제가 구비된 제2복합층을 준비하는 제2준비공정과;
상기 제1복합부재와 제2복합층을 합지하여 난연시트를 제조하는 합지공정과;
상기 난연시트를 합성수지재를 발포시켜 된 발포된 폼재로 이루어진 기재의 양측면에 부착 설치하여 결합하는 마무리공정에 의해 제조된 것으로,
상기 제1준비공정의 직물층은 양면에 금속필름재가 더 부착되어 이루어지며,
금속필름재의 일면에 물유리와 금속접착제가 혼합되어 이루어진 접착혼합물층을 형성시키고 상기 접착혼합물층에 흡음 효율과 난연 효율을 향상시키는 제직된 직물층을 적층하고 상기 직물층의 상부에 접착제와 부직포를 순차적으로 적층한 난연 시이트를 합성수지재로 발폼되어 이루어진 기재의 양측면에 부착 설치되어 이루어지며,
상기 접착혼합물층은 물유리와 금속접착제를 혼합하여 제조하되 물유리와 금속접착제의 혼합이 용이하도록 MC계열의 용가제를 물유리와 금속접착제의 혼합량의 총합이 100이라 할 때 5~15중량%를 사용하며, 상기 물유리와 금속접착제의 혼합비는 물유리 50~80중량%이고 금속접착제는 50~20중량%의 중량비로 혼합하는 것을 특징으로 하는 건축 및 자동차용 적층내장재.
In laminated interior materials for construction and automobiles,
The first preparation process of preparing a first composite member by forming an adhesive mixture layer made of a mixture of water glass and a metal adhesive on one side of a metal film material, and laminating a woven fabric layer that improves sound absorption efficiency and flame retardant efficiency on the adhesive mixture layer and;
A second preparation step of preparing a second composite layer provided with an adhesive on one side of the nonwoven fabric;
A laminating process of laminating the first composite member and the second composite layer to manufacture a flame retardant sheet;
It is manufactured by a finishing process of attaching and installing the flame-retardant sheet to both sides of a substrate made of a foamed foam material by foaming a synthetic resin material,
The fabric layer of the first preparation process is made by further attaching metal film materials on both sides,
An adhesive mixture layer formed by mixing water glass and a metal adhesive is formed on one side of the metal film material, and a woven fabric layer that improves sound absorption efficiency and flame retardant efficiency is laminated on the adhesive mixture layer, and an adhesive and a non-woven fabric are sequentially placed on the top of the fabric layer. It is made by attaching and installing the laminated flame-retardant sheet on both sides of the base material formed by foaming with a synthetic resin material,
The adhesive mixture layer is prepared by mixing water glass and metal adhesive, but to facilitate mixing of water glass and metal adhesive, 5 to 15% by weight is used when the total amount of mixing of the water glass and metal adhesive is 100 for the MC-series filler. , The mixing ratio of the water glass and the metal adhesive is 50 to 80% by weight of the water glass, and the metal adhesive is mixed at a weight ratio of 50 to 20% by weight.
삭제delete 삭제delete 삭제delete 삭제delete 삭제delete 제 5 항에 있어서,
상기 직물층은 유리섬유재 직포, 테프론재 직포, 케블라 직포 중 어느 하나인 것을 특징으로 하는 건축 및 자동차용 적층내장재.
The method of claim 5,
The fabric layer is a laminated interior material for construction and automobiles, characterized in that any one of a glass fiber woven fabric, a Teflon woven fabric, and a Kevlar woven fabric.
제 5 항에 있어서,
상기 금속접착제는 에폭시, 아크릴, 폴리우레탄 중 어느 하나인 것을 특징으로 하는 건축 및 자동차용 적층내장재.
The method of claim 5,
The metal adhesive is a laminate interior material for construction and automobiles, characterized in that any one of epoxy, acrylic, and polyurethane.
KR1020190139358A 2019-11-04 2019-11-04 Manufacturing method of laminated interior material for construction and automobile and its laminated interior material KR102188303B1 (en)

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KR0151629B1 (en) 1995-06-20 1998-10-15 금병찬 Interior finishing material of a car
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Publication number Priority date Publication date Assignee Title
KR950006863A (en) 1993-08-26 1995-03-21 세끼모또 다다히로 A semiconductor memory device and a method for controlling the operation of the semiconductor memory device
KR0151629B1 (en) 1995-06-20 1998-10-15 금병찬 Interior finishing material of a car
JPH09277415A (en) * 1996-04-09 1997-10-28 Inoac Corp Interior material for car and production thereof
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