KR102040102B1 - Environment-friendly multifunctional flame-retardant coating agent and method for producing the flame-retardant coating agent - Google Patents
Environment-friendly multifunctional flame-retardant coating agent and method for producing the flame-retardant coating agent Download PDFInfo
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Abstract
Description
본 발명은 방염코팅제에 관한 것으로, 더욱 상세하게는 난연성과 내화성, 친환경성을 겸비한 방염물질로서, 일반생활용품, 산업용품, 건축용품, 장식용품은 물론, 자동차, 지하철, 항공기 등, 각종 교통수단의 실내 마감재에 이르기까지 어느 특정된 대상물에 구애받음 없이 화기에 취약한 물품 내지 장소라면 그 어디에든 적용 가능하게 하여, 화재발생을 억제하고, 예견치 못한 상황에 화재가 발생하는 경우라도 화염의 급속한 확산과 유독가스의 배출을 최소화하여, 인명과 재산을 보호할 수 있도록 한 친환경 다기능 방염코팅제 및 그 방염코팅제의 제조방법에 관한 것이다. The present invention relates to a flame retardant coating agent, and more particularly, to a flame retardant material having flame retardancy, fire resistance, and eco-friendliness, as well as general transportation products, industrial products, building supplies, decorative articles, automobiles, subways, aircrafts, etc. It can be applied to any item or place that is vulnerable to fire without regard to any specific object, even to interior finishing materials. It can suppress the occurrence of fire and rapidly spread the flame even in the event of a fire in an unforeseen situation. It relates to an environmentally friendly multifunctional flame retardant coating agent and a method for producing the flame retardant coating agent to minimize the emission of toxic gases and to protect people and property.
소중한 생명과 재산을 순식간에 앗아가는 매우 위험한 존재로서의 화재, 이러한, 화재의 원인은 크게 자연적 원인과 인위적 원인으로 나눌 수 있다.Fires, which are very dangerous beings that quickly take away precious life and property, can be divided into natural and artificial causes.
그중에서도 특히, 인위적 원인에 의한 화재는, 화기취급시 부주의와 안전에 대한 인식부족, 기타, 고의적 방화 등에 의해 불특정 지역에서 끊임없이 발생하는 것으로, 통계적 측면에서 볼 때 자연적 원인보다 훨씬 많은 비중을 차지함을 알 수 있다. Among them, fires caused by artificial causes are constantly occurring in unspecified areas due to carelessness and lack of safety awareness, and other deliberate arsons when handling firearms. Can be.
화재발생시 현장에서의 생존율은 단 몇 초의 시간으로 좌우된다 할 수 있다. 안전의 마지막 노선으로 3분의 감소는 엄청난 것이다. 국가적으로, 소방대가 경보를 받고 현장에 대처하기까지 요하는 시간은 대략 3분30초이다. 화재 경보를 알리는데 1~3분이 필요하고 그로부터 3분 30초 후에야 소방대가 현장에 도착한다고 고려해 볼 때, 그 시간은 화염의 확산시간보다 늦어 인명을 구조할 수 없고, 이미 주요 손실이 일어났을 때인 것이 대부분이다. 하지만, 화재진압의 과실은 소방대의 능력에 있는 것이 아니라 우리들의 건축 기술과 각종 건축 자재에 있는 현실임을 알 수 있다. Survival at the site in the event of a fire depends on a few seconds. The last three minutes of safety is a tremendous amount. Nationally, the time required for a fire brigade to be alerted and respond to the scene is approximately 3:30. Given that a fire alarm would take 1-3 minutes to announce a fire alarm and only three minutes and thirty seconds later, the fire brigade would arrive at the scene. Most of them are. However, it can be seen that the negligence of fire suppression is not in the capabilities of the fire brigade but in the reality of our building technology and various building materials.
예컨대, 화재현장에서 탈출시간이 감소 된 주요원인은, 각종 건축자재와 가구, 기타 다양한 생활용품 등에 합성수지 및 합성섬유와 같은 각종 합성물질의 사용이 증가하고 있음이라 할 수 있다. 즉, 우리들의 생활주변에 산재하고 있는 합성물질들은 통상 천연물질에 의한 열 복사량보다 2-3배 더 많은 열을 방출하고, 특히, 합성수지 사용으로 인한 복사열의 불균형은 화염의 확산은 물론, 대류에 현상에 의해 뜨거운 공기의 양을 증가시키며, 결과적으로 섬락까지의 시간을 단축시키기 때문이 그 이유라 할 수 있다.For example, the main reason for the reduced escape time at the fire site is the increasing use of various synthetic materials such as synthetic resins and synthetic fibers in various building materials, furniture, and various other household items. In other words, synthetic materials scattered around our lives usually emit 2-3 times more heat than natural heat radiation, and in particular, the imbalance of radiant heat due to the use of synthetic resins can lead to convection and convection. This is because the phenomenon increases the amount of hot air and consequently shortens the time to flashover.
여기서, 섬락이라 함은, 급속한 온도상승으로 인해 연소 가능한 모든 물질의 표면과 불완전 연소된 부산물에 순간적으로 점화가 일어나는 현상, 예컨대, 열로 인해 팽창된 기체가 밀폐공간 내에 수용될 수 있는 정도를 넘어설 경우 발생하는 일종의 폭발현상을 의미하는 것으로, 지난 30년 동안 화재현장에 있어, 발화시점부터 섬락현상에 이르기까지 걸리는 시간은 5분에서 2분 이하로 단축된 현실임을 알 수 있다.Here, flashover is a phenomenon in which a rapid ignition occurs on the surface of all combustible materials and incompletely burned by-products due to rapid temperature rise, e.g., the extent to which gas expanded due to heat can be accommodated in a confined space. It means a kind of explosion that occurs in the case of fire in the last 30 years, it can be seen that the time taken from the point of ignition to the flashover phenomenon is shortened from 5 minutes to 2 minutes or less.
따라서, 근래에는 화재발생을 억제하기 위한 방안, 예컨대, 가연성 물질의 연소온도를 상승시켜 불꽃점화 현상을 억제 시키고, 점화된 화염의 확산시간을 지연시켜 화재현장에서의 탈출시간을 안전하게 확보하며, 아울러, 연소시 발생하는 유독가스의 배출 또한 최소화할 수 있도록 한 방염제가 개발 이용되는 실정인바, 그 대표적인 일 예로 대한민국 특허청에 선출원 등록된 "불연선 도막 형성용 조성물 및 이로부터 얻어진 불연성 도막"이 창안된 바있다.Therefore, in recent years, measures to suppress the occurrence of fire, for example, to increase the combustion temperature of the combustible material to suppress the spark ignition phenomenon, delay the diffusion time of the ignited flame to secure the escape time at the fire site, In addition, a flame retardant is developed and used to minimize the emission of toxic gases generated during combustion. As a representative example, the "composition for forming a non-combustible coating film and a non-combustible coating film obtained therefrom", which is registered as a preliminary application to the Korean Patent Office, was created. There is a bar.
상기 선등록 기술로서의 "불연선 도막 형성용 조성물 및 이로부터 얻어진 불연성 도막"은, (a)수용성 또는 수분산성 아크릴계 수지 및 수용성 또는 수분산성 비닐계 수지에서 선택된 적어도 1종의 바인더수지 504 ~ 648 중량%와; (b)물 196 ~ 252 중량% 와; (c)팽창성 흑연 6 ~ 26중량% 와; (d)백등유 2 ~ 4 중량%를 포함하는 불연성 도막 형성용 조성물 및 이 조성물로부터 얻어진 불연성 도막을 기술의 특징으로 한다.The "composition for forming a non-combustible coating film and a non-combustible coating film obtained therefrom" as the pre-registration technique is (a) at least one binder resin 504-648 weight selected from a water-soluble or water-dispersible acrylic resin and a water-soluble or water-dispersible vinyl resin. %Wow; (b) 196-252 weight percent of water; (c) 6 to 26% by weight of expandable graphite; (d) A composition for forming a non-flammable coating film containing 2 to 4% by weight of white kerosene and a non-flammable coating film obtained from the composition are characterized by technology.
이와 같은, 선등록 기술은, 건조속도와 장기 보관성이 우수함은 물론, 피도물 표면에 치밀한 불연성 도막을 간편하게 형성되게 하여 불연성뿐만 아니라 내수성과 내열성, 그리고, 기계적 강도가 우수한 기능 특징을 부여한다.Such a pre-registration technology not only has excellent drying speed and long-term storage property, but also allows the formation of a dense non-flammable coating film on the surface of the workpiece, thereby imparting not only non-flammability but also excellent water resistance, heat resistance, and mechanical strength.
하지만, 팽창흑연의 고체분말은 이를 분쇄하여 알갱이의 크기를 최소화해도 400mesh(35㎛) 이상이며, 이것을 코팅제에 첨가하는 경우 알갱이의 질감이 유동체인 코팅제와 구분되며, 유동체 내에서 알갱이의 형상이 관찰되어 질감 및 외관이 매끄럽지 못함에 따라 피 코팅체에 이를 그대로 적용하기에 용이하지 못한 문제점이 있다.However, even when the solid powder of expanded graphite is crushed to minimize the size of the grains, the grain size is more than 400 mesh (35 μm), and when it is added to the coating, the texture of the grains is distinguished from the coating which is the fluid, and the shape of the grains in the fluid is observed. There is a problem that the texture and appearance is not smooth, so it is not easy to apply it to the coating.
또한, 전술한 바와 같은, 선등록 기술은, 질감과 외관이 매끄럽지 못한 재질적 특성으로 인해 그 사용범위가 극히 제한될 수밖에 없는 범용성 저하의 문제점이 있고, 코팅제에 포함된 팽창흑연 가열시 황산이나 이산화탄소 등의 유독 물질이 발생하며 인체에 유해요인으로 작용하는 문제점이 있으며, 특히, 단순 방염 내지 난연기능 이외에 부가적 기능은 전혀 기대할 수 없는 매우 비효율적인 사용상의 문제점 또한 상존한다. In addition, as described above, the pre-registration technology, there is a problem of deterioration of the general purpose that the use range is extremely limited due to the material characteristics of the texture and appearance is not smooth, sulfuric acid or carbon dioxide when heating the expanded graphite contained in the coating agent Toxic substances, etc. are generated and there is a problem that acts as a harmful factor to the human body. In particular, in addition to the simple flame retardant or flame retardant function, there are also very inefficient use problems that cannot be expected at all.
본 발명은 종래 방염처리제의 제반적인 문제점을 해결하고자 창안된 것으로;The present invention was devised to solve the general problems of the conventional flame retardant;
본 발명의 목적은, 난연성과 내화성, 그리고, 친환경성을 겸비한 방염코팅 물질로서, 물품의 용도나 구조, 형태, 성질 등에 구애받음 없이 불특정 다수의 대상물품, 예컨대, 일반생활용품, 산업용품, 건축용품, 장식용품은 물론, 자동차, 지하철, 항공기 등, 각종 교통수단의 실내 마감재에 이르기까지 어느 특정된 대상물에 제한됨 없이 화기에 취약한 물품 내지 장소라면 그 어디에든 적용 가능하게 하여, 초기 불꽃점화 현상의 억제, 점화된 화염의 확산지연, 그리고, 화재발생시 유독가스 배출 저감 기능을 복합적으로 행하게 함으로써, 안전성과 편리성, 그리고 사용효율성을 극히 향상시킬 수 있도록 한 친환경 다기능 방염코팅제 및 그 방염코팅제의 제조방법을 제공함에 있다.An object of the present invention is a flame retardant coating material that combines flame retardancy, fire resistance, and eco-friendliness, and can be used for any number of unspecified objects, for example, general household goods, industrial products, and architecture, regardless of the use, structure, shape, and properties of the article. Supplies, decorative items, as well as interior finishing materials of various means of transportation such as cars, subways, airplanes, etc., without being limited to any specific object, any item or place that is vulnerable to fire, can be applied anywhere, the early spark ignition phenomenon Environment-friendly multifunctional flame retardant coating agent and method for manufacturing the flame retardant coating agent that can greatly improve safety, convenience, and use efficiency by carrying out a combination of suppression, delay of ignition flame spread, and reduction of toxic gas emission in case of fire. In providing.
또한, 본 발명의 목적은, 방염 및 난연 기능을 행하는 무기염 원료에 친환경 천연물질인 시나몬과 피톤치드를 첨가하여, 단순한 화재지연 기능으로서뿐만 아니라 방충 및 탈취기능을 복합적으로 병행할 수 있도록 하고, 아울러, 사용이 편리한 스프레이 분사 코팅방식에 의해 별도의 특수코팅장비 내지 전문기술자의 도움을 필요함 없이도 남여노소 누구나 다양한 물품을 대상으로 방염코팅작업을 행할 수 있게 함으로써, 취급성과 범용성을 증대되도록 한 친환경 다기능 방염코팅제 및 그 방염코팅제의 제조방법을 제공함에 있다. In addition, it is an object of the present invention, by adding an eco-friendly natural material cinnamon and phytoncide to the inorganic salt raw material that performs flame retardant and flame retardant function, so that not only as a simple fire delay function but also a combination of insect repellent and deodorizing function, Eco-friendly, multi-functional flame retardant to increase handling and versatility by allowing anyone of all ages to carry out flame-retardant coating work on a variety of items without the need for special coating equipment or expert technicians. The present invention provides a coating agent and a method for preparing the flame retardant coating agent.
상기 목적을 달성하기 위한 본 발명에 따른 친환경 다기능 방염코팅제 및 그 방염코팅제의 구체적 수단으로는;As a specific means of an environmentally friendly multifunctional flame retardant coating agent and a flame retardant coating agent according to the present invention for achieving the above object;
증류수 용제에 인산암모늄 분말과, 인산나트륨 분말과, 황산염 분말과, 카올린 분말과, 시나몬 분말과, 피톤치드 분말을 첨가 혼합하여 방염코팅 조성물을 생성되게 함으로써, 달성한다.It is achieved by adding and mixing ammonium phosphate powder, sodium phosphate powder, sulfate powder, kaolin powder, cinnamon powder, and phytoncide powder to a distilled water solvent to produce a flame retardant coating composition.
또한, 상기 방염코팅 조성물을 생성하기 위한 제조방법으로, 첨가소재 분쇄공정과, 첨가소재 정제공정과, 방염코팅액 생성공정(S3)과, 방염코팅제 제품화공정을 행하도록 하여 달성한다.In addition, the production method for producing the flame retardant coating composition, it is achieved by performing the additive material grinding step, the additive material purification step, the flame retardant coating solution generation step (S3), and the flame retardant coating agent commercialization step.
이상, 본 발명에 따른 친환경 다기능 방염코팅제 및 그 방염코팅제의 제조방법은, 물품의 용도나 구조, 형태, 성질 등에 구애받음 없는 불특정 다수의 대상물품, 예컨대, 일반생활용품, 산업용품, 건축용품, 장식용품은 물론, 자동차, 지하철, 항공기 등, 각종 교통수단의 실내 마감재에 이르기까지 어느 특정된 대상물에 제한됨 없이 화기에 취약한 물품 내지 장소라면 그 어디에든 분사도포 내지 침지도포 방식에 의해 선택적으로 적용 가능하게 한 것으로, 이는, 사용의 안전성과 편리성, 그리고, 효율성을 향상되게 한 효과를 제공한다.As described above, the environment-friendly multifunctional flame retardant coating agent and the method for manufacturing the flame retardant coating agent according to the present invention are irrespective of the use, structure, shape, properties, etc. of the article, a number of unspecified target articles, such as general household goods, industrial products, building supplies, It can be selectively applied by spray coating or immersion coating method to any place or object vulnerable to fire, without being limited to any specific object such as decorative items, interior finishing materials of various means of transportation such as automobiles, subways, aircrafts, etc. In this regard, it provides the effect of improving safety and convenience of use and efficiency.
또 다르게, 본 발명에 따른 친환경 다기능 방염코팅제 및 그 방염코팅제의 제조방법은, 방염 및 난연 기능을 행하는 무기염 원료, 예컨대, 인산암모늄, 인산나트륨, 황산염 등의 원료에 친환경 천연물질인 시나몬과 피톤치드를 첨가하여, 단순한 화재지연 기능으로서뿐만 아니라 방충 및 탈취기능을 복합적으로 병행할 수 있게 한 것으로, 이는, 취급성과 범용성 또한 증대되게 하는 등, 매우 유용한 기대효과를 제공한다. Alternatively, the eco-friendly multifunctional flame retardant coating agent and the method for preparing the flame retardant coating agent according to the present invention, an inorganic salt raw material that performs flame retardant and flame retardant function, for example, cinnamon and phytoncide which is an environmentally friendly natural material to raw materials such as ammonium phosphate, sodium phosphate, sulfate In addition to the simple fire delay function, as well as a combination of the insect repellent and deodorant function can be combined, which provides a very useful expected effect, such as increased handling and versatility.
도 1은 본 발명에 따른 친환경 다기능 방염코팅제의 성분구성도
도 2는 본 발명에 따른 친환경 다기능 방염코팅제의 제조공정순서도1 is a block diagram of an environmentally friendly multifunctional flame retardant coating agent according to the present invention
Figure 2 is a manufacturing process flow chart of the eco-friendly multifunctional flame retardant coating agent according to the invention
이하, 본 발명에 따른 친환경 다기능 방염코팅제 및 그 방염코팅제의 제조방법의 바람직한 실시예 구성을 첨부도면에 의거하여 상세히 설명하기로 한다.Hereinafter, with reference to the accompanying drawings, preferred embodiments of the environment-friendly multi-functional anti-corrosive coating agent and a method for producing the anti-corrosive coating agent according to the present invention will be described in detail.
첨부도면을 참고로 하여 본 발명에 적용되는 주요 첨가원료의 성분구성을 살펴보면;Looking at the composition of the main additives applied to the present invention with reference to the accompanying drawings;
이는, 인산암모늄과, 인산나트륨과, 황산염과, 카올린과, 시나몬과, 피톤치드 성분의 첨가원료로 구성된다.It consists of an additive raw material of ammonium phosphate, sodium phosphate, sulfate, kaolin, cinnamon, and a phytoncide component.
여기서, 먼저, 상기 인산암모늄은, 암모늄 이온의 인산염, 인산의 수소 원자가 모두 암모늄으로 바뀌어 만들어진 무색의 결정체로서, 이러한 인산암모늄은 통상 제1인산암모늄(NH4H2PO4), 제2인산암모늄(NH42HPO4), 제3인산암모늄(NH43PO4)의 세 종류로 분류되고, 이와 같이, 분류된 인산암모늄 중 특히, 제1인산암모늄(NH4 H2PO4)은 열 분해시 흡열 반응에 의한 냉각작용, 불연성 가스(NH3, H2O 등)에 의한 질식작용, 반응 과정에서 생성된 메타인산(HPO3)의 방진작용, 열방사 차단작용, 오르쏘 인산에 의한 섬유소의 탈수 및 탄화 작용 등에 의해 화재를 진압하는 소화기의 주요 약제, 또는, 내화 약품, 내화 페인트 등에 널리 이용되는 물질특성을 갖는 것인바, 이에, 본 발명에 적용되는 인산암모늄은, 상기 인산암모늄의 종류 중 제1인산암모늄(NH4H2PO4)을 주요 성분 첨가원료로 이용함이 바람직하다.Here, first, the ammonium phosphate is a colorless crystal formed by changing all of the phosphate of the ammonium ion and the hydrogen atom of the phosphoric acid into ammonium. The ammonium triphosphate (NH43PO4) is classified into three types, and thus, among the classified ammonium phosphates, the first ammonium phosphate (NH4 H2PO4) is cooled by an endothermic reaction during thermal decomposition, incombustible gases (NH3, H2O, etc.) Fire extinguishing agent, fire retardant, or fire extinguishing agent for extinguishing fires by asphyxiation, dust protection of metaphosphoric acid (HPO3) produced during the reaction, heat radiation blocking action, dehydration and carbonization of fibrin by orthophosphoric acid, etc. It has a widely used material properties, such as refractory paints, ammonium phosphate to be applied to the present invention, the ammonium phosphate (NH4H2PO4) of the type of the ammonium phosphate is the main component addition source This is preferred by utilizing.
또한, 상기 인산나트륨(Na4P2O7)은, 인산을 탄산나트륨의 수용액에 포호시켜 생성한 무색 투명한 기둥모양의 결정체로서, 화염에 연소되지 않고 오히려 소화기능을 행하는 주지의 물질특성을 갖는 것인바, 이러한, 인산나트륨(Na4P2O7)을 본 발명에 적용함에 있어서는, 제1인산나트륨(결정)(NaH2PO4. 2H2O)과, 제2인산나트륨(결정)(Na2HPO4. 12H2O), 그리고, 제3인산나트륨(결정)(Na3PO4. 12H2O) 중 어느 하나의 인산나트륨을 선택적으로 택일하여 본 발명의 첨가원료로 이용함이 바람직하다. In addition, the sodium phosphate (Na 4 P 2 O 7) is a colorless transparent columnar crystal formed by encapsulating phosphoric acid in an aqueous solution of sodium carbonate, and has a well-known material property that does not burn in a flame but rather performs a digestive function. In applying sodium (Na 4 P 2 O 7) to the present invention, the first sodium phosphate (crystal) (NaH 2 PO 4.2 H 2 O), the second sodium phosphate (crystal) (Na 2 HPO 12H 2 O), and the third sodium phosphate (crystal) (Na 3 PO 4) 12H2O) is preferably used as the additive raw material of the present invention by selectively selecting any one of sodium phosphate.
또한, 상기 황산염은, 일종의 촉매제로써, 중정석, 천청석 등의 황산염광물로부터 추출된 분말형태의 황산염을 이용함이 바람직하다.In addition, the sulfate is a kind of catalyst, it is preferable to use a sulfate in the form of powder extracted from sulfate minerals such as barite, cheonseokite.
또한, 상기 카올린은, 천연 점토광물, 즉, 규산염 광물로부터 생산되는 함수규산 알루미늄으로서, 백색 또는 유백색의 분말형태를 취하고, 일반적으로 고령토라 불리며, 화학식은 Al2Si2O5(OH)4로서, 촉감이 미끌미끌하고 특히, 다량의 음이온과 양자에너지, 그리고, 원적외선 방출기능 등에 의해, 항균, 제습, 탈취는 물론, 정화작용과 제독작용 등에 있어, 매우 우수한 효과를 발휘하는 주지의 물질특성을 갖는 것인바. 이에, 방염코팅제 생성시 음이온 및 원적외선 방출기능을 극대화 시키기 위한 방안으로, 상기 카올린 성분을 첨가원료로 이용하는 것이며, 이러한, 카올린을 본 발명에 적용함에 있어서는, 자연에서 채취한 점토광물, 예컨대, 고령토를 분말형태로 가공 정제하여 이용함이 바람직하다. In addition, the kaolin is a hydrous aluminum silicate produced from natural clay minerals, that is, silicate minerals, take the form of a white or milky white powder, generally called kaolin, and the chemical formula is Al 2 Si 2 O 5 (OH) 4 It is slippery to the touch, and it has a large amount of negative ions, quantum energy, and far-infrared ray emission function. It has a well-known material characteristic that shows very good effect in antibacterial, dehumidification, deodorization, purification and detoxification. To have. Thus, as a method for maximizing anion and far-infrared emission function when producing a flame retardant coating agent, the kaolin component is used as an additive material. In applying the kaolin to the present invention, clay minerals, such as kaolin, are collected from nature. It is preferable to use it by processing and refining in powder form.
또한, 상기 시나몬은, 육계(C.cassia), 실론육계(C.zeylanica), 계수나무(C.laureirii) 등의 천연식물 껍질로 만든 향신료의 일종으로, 이는, 각종 음료 내지 음식물에 첨가되는 식품용도로써 뿐만 아니라 방향제로도 널리 이용되고, 아울러, 이러한 시나몬은 집먼지 진드기를 퇴치하고, 소취 기능 또한 우수한 주지의 물질특성을 갖는 것인바, 이에, 방염코팅제 생성 사용시, 단순 화염억제기능으로써 뿐만 아니라 방향기능과 소취기능, 그리고, 유해충 퇴치기능을 부여하기 위한 수단으로, 상기 천연식물(나무)로부터 추출한 시나몬 원료를 분말형태로 가공 정제하여 이용함이 바람직하다. In addition, the cinnamon is a kind of spice made from natural plant shells, such as broiler (C.cassia), Ceylon broiler (C.zeylanica), cassia (C.laureirii), which is a food added to various beverages or food It is widely used not only as a fragrance but also as a fragrance. In addition, the cinnamon has a well-known material characteristic to combat house dust mites and deodorizing function. Therefore, when using a flame retardant coating agent, it is not only a simple flame retardant function but also a fragrance. As a means for imparting a function, a deodorizing function, and a harmful insect control function, it is preferable to process and refine the cinnamon raw material extracted from the natural plant (tree) in powder form.
또한, 상기 피톤치드는, 나무가 해충과 병균으로부터 자신을 보호하기 위해 내뿜는 자연 항균물질로써, 이는 스트레스 해소, 심폐기능 강화, 살균작용은 물론 아토피를 유발하는 집먼지 진드기의 번식을 억제하고, 공기를 정화시켜 쾌적한 실내환경을 유지되게 하는 주지의 물질특성을 갖는 것인바, 이에, 방염코팅제 생성 사용시, 단순 화염억제기능으로써 뿐만 아니라 항균 및 살균기능, 유해충 퇴치기능, 공기정화기능을 부여하기 위한 수단으로, 편백나무, 잣나무 등과 같이 피톤치트 방출량이 우수한 천연식물로부터 추출하여 분말형태로 가공 정제한 피톤치드를 이용함이 바람직하다. In addition, the phytoncide is a natural antibacterial substance that the tree exhales to protect itself from pests and germs, which relieve stress, strengthen cardiopulmonary function, sterilization as well as inhibit the reproduction of house dust mites that cause atopy, purify the air It has a well-known material characteristic to maintain a comfortable indoor environment, and therefore, as a means for imparting antibacterial and bactericidal function, harmful pest control function, and air purifying function as well as simple flame suppression function when using flame retardant coating agent. It is preferable to use phytoncide which is extracted from natural plants having excellent phytoncite release amount such as cypress, pine, etc. and processed into powder form.
한편, 상기와 같은, 기능성 원료들을 주요 성분으로 하는 본 발명은, 그들 성분을 마련하기 위한 일련의 준비과정과, 준비과정을 통해 마련된 성분원료들의 혼합과정에 있어, 또 다른 독창적 형태의 기술 특징을 갖는 것인바, 따라서, 본 발명에 따른 친환경 다기능 방염코팅제 제조방법을 살펴보면;On the other hand, the present invention using the functional ingredients as a main component, as described above, in the series of preparation process for preparing these components, and the mixing process of the component raw materials prepared through the preparation process, another original form of technical features If you have, therefore, look at the environment-friendly multi-functional anti-corrosive coating method according to the invention;
이는, 첨가원료 분쇄공정(S1)과, 첨가원료 정제공정(S2)과, 방염코팅액 생성공정(S3)과, 방염코팅제 제품화공정(S4)으로 이루어진다.This comprises an additive raw material grinding step (S1), an additive raw material purification step (S2), a flame retardant coating liquid generation step (S3), and a flame retardant coating agent commercialization step (S4).
여기서, 먼저 상기 첨가원료 분쇄공정(S1)은, 통상의 화학적 반응에 의해 인위적으로 생성한 인산암모늄 결정체와 인산나트륨 결정체를 마련하고, 천연광물로부터 산출한 황산염 분말체와 카올린 분말체를 마련하며, 재차, 천연식물(나무)로부터 채취한 시나몬 분말체와 피톤치드 분말체를 마련토록 한 후, 상기 마련된 각 원료를 성분별로 분류하고, 분류된 각 성분원료를 주지의 산업용 입자분쇄기(도시생략)에 개별투입하여 2~3㎛의 분말입자크기로 분쇄가공하는 과정으로 이루어지게 함이 바람직하다.Here, first, the additive raw material grinding step (S1), the artificially produced ammonium phosphate crystals and sodium phosphate crystals produced by a conventional chemical reaction, and the sulfate powder and kaolin powders calculated from natural minerals, Once again, cinnamon powder and phytoncide powder collected from natural plants (trees) are prepared, and each of the prepared raw materials is classified by ingredients, and each of the classified ingredients is classified in a well-known industrial particle grinder (not shown). It is preferable to make it into the process of milling into a powder particle size of 2 ~ 3㎛.
또한, 상기 첨가원료 정제공정(S2)은, 전술한 첨가원료 분쇄공정(S1)을 통해 분쇄처리된 각 성분원료를 개별적으로 분류하여 주지의 산업용 초음파 진동선별기(도시생략)에 개별 투입하고, 투입된 원료에 진동필터링 작용을 부여하여 2~3㎛ 이상의 크기를 갖는 불량원료 분말입자와, 기타 이물질을 선별처리하는 과정으로 이루어지게 함이 바람직하다.In addition, the additive raw material purification step (S2), by separately classifying each component raw material that was processed through the above-mentioned additive raw material grinding step (S1) separately and put into a well-known industrial ultrasonic vibration separator (not shown), It is preferable to impart a vibration filtering action to the raw material so that the raw material powder particles having a size of 2 to 3 μm or more, and other foreign matters are selected.
또한, 상기 방염코팅액 생성공정(S3)은, 전술한 첨가원료 정제공정(S2)을 통해 균일한 분말형태로 정제처리된 각 성분원료를 혼합조성하여 방염코팅 조성물을 생성하는 과정인바, 이는, 먼저, 50~60%의 중량비율로 설정된 증류수를 용제로 마련하고, 상기 마련된 용제로서의 증류수에, 정제공정을 행한 인산암모늄 분말을 15~20% 중량비율, 인산나트륨 분말을 10~15%의 중량비율, 황산염 분말을 5~10%의 중량비율, 카올린 분말을 5~10% 중량비율, 시나몬 분말을 0.5~1%의 중량비율, 피톤치드 분말을 0.5~1%의 중량비율로 첨가시키며, 이와 같이, 설정된 중량비율로 각 성분원료가 투입된 증류수를 주지의 산업용 믹싱기(도시생략)에 투입하여 60~80분간의 회전 교반작용에 의해 혼합하여 방염코팅 조성물을 생성토록 하는 과정으로 이루어지게 함이 바람직하다.In addition, the flame retardant coating solution generating step (S3) is a process of producing a flame retardant coating composition by mixing the composition of each component raw material purified in a uniform powder form through the above-described additive raw material purification step (S2), which is, first , 15 to 20% by weight of the ammonium phosphate powder subjected to the refining process, and 10 to 15% by weight of sodium phosphate powder 5 to 10% by weight of sulphate powder, 5 to 10% by weight of kaolin powder, 0.5 to 1% by weight of cinnamon powder, and 0.5 to 1% by weight of phytoncide powder. Distilled water in which each ingredient is added at a set weight ratio is added to a well-known industrial mixer (not shown) and mixed by rotational stirring for 60 to 80 minutes to produce a flame retardant coating composition. .
끝으로, 상기 방염코팅제 제품화공정(S4), 전술한 방염코팅액 생성공정(S3)을 통해 생성된 방염코팅 조성물을 사용자에게 제공하기 위한 일종의 제품포장과정인바, 이와 같은, 방염코팅제 제품화공정(S4), 방염코팅액 생성공정(S3)에 의해 생성된 방염코팅 조성물을 설정된 용량으로 하여, 수동펌프방식의 분무용기(분무기), 또는, 에어 스프레이방식 분사용기(에어로졸 캔), 또는, 사용자가 필요한 용량만큼 덜어내어 사용할 수 있도록 한 보관포장용기 중 어느 하나의 수용용기에 충진시켜 상품화된 방염코팅제를 형성하는 과정으로 이루어지게 함이 바람직하다.Finally, the flame retardant coating product commercialization step (S4), a kind of product packaging process for providing the user with the flame retardant coating composition generated through the above-described flame retardant coating solution generation process (S3), such, flame retardant coating agent commercialization process (S4) By using the flame retardant coating composition produced by the flame retardant coating liquid generation step (S3) as a set capacity, a spray container (atomizer) of a manual pump method, or an air spray spray container (aerosol can), or as required by a user It is preferable to be made of a process of forming a commercialized flame retardant coating agent by filling in any one of the storage packaging container to be used to remove.
따라서, 전술한 바와 같은, 일련의 제조과정을 통해 형성된 방염코팅제는 사용자 선택에 따라 화기에 취약한 물품이나 장소, 예컨대, 각종 생활용품, 산업용품, 건축용품, 장식용품 등은 물론, 자동차, 지하철, 항공기 등, 각종 교통수단의 실내 마감재에 이르기까지 어느 특정된 대상물에 제한됨 없이 선택적으로 방염코팅제를 도포처리하여 사용하게 되는 것인바, 그러한 도포방식은, 분무기 및 에어로졸 캔을 이용한 분사도포방식, 보관포장용기로부터 방염코팅액을 일정량 덜어내어 덜어내어진 방염코팅액을 붓이나 롤러를 이용 대상물품의 표면에 칠하는 브러쉬 도포방식, 그리고, 방염코팅액을 일정량 덜어내어 덜어내어진 방염코팅액에 대상물품을 침지시키는 침지 도포방식 중 어느 하나의 방식을 이용하여, 그 사용관계를 갖게 된다.Therefore, as described above, the flame-retardant coating agent formed through a series of manufacturing processes according to the user's selection, the article or place vulnerable to fire, for example, various household goods, industrial products, building supplies, decorative products, as well as automobiles, subways, It is to be used by selectively applying a flame retardant coating agent, without being limited to any specific object up to the interior finish of various means of transportation, such as aircraft, such a coating method, spray coating method using a spray gun and aerosol can, storage packaging Brush coating method that paints a certain amount of flame retardant coating liquid from the container and removes the flame retardant coating liquid on the surface of the object using a brush or roller, and immerses the object to be immersed in the flame retardant coating liquid after removing a certain amount of flame retardant coating liquid. By using any of the coating methods, the use relationship is obtained.
한편, 본 발명에 따른 친환경 다기능 방염코팅제 및 그 방염코팅제의 제조방법은, 또 다른 이 실시예로서, 전술한 일시예의 제조방법을 통해 생성된 방염코팅 조성물에 절연체 기능을 갖는 추가적 성분원료, 예컨대, 셀룰로오스 분말을 8:2의 중량비율로 첨가 혼합하여 셀룰로오스 분말이 혼합된 다기능 방염코팅제를 형성할 수 있는 것으로, 이 또한 본 발명의 범주에서 벗어나는 것은 아니다.On the other hand, the environmentally friendly multi-functional anti-corrosive coating agent according to the present invention and a method for producing the anti-corrosive coating agent, as another embodiment, an additional ingredient raw material having an insulator function in the anti-flame coating composition produced through the manufacturing method of the above-described one example, for example, The cellulose powder may be added and mixed at a weight ratio of 8: 2 to form a multifunctional flame retardant coating agent in which the cellulose powder is mixed. This also does not depart from the scope of the present invention.
이때, 상기 이 실시예로 첨가되는 셀룰로오스는 면 섬유를 탈지하여 묽은 알칼리 수용액과 끓여서 얻어지는 무취의 백색 고체로써, 열이나 전기를 흐르지 못하게 하는 절연체 기능의 물질 특성을 갖는 것으로, 이러한, 셀룰로오스를 본 발명에 적용함에 있어서는, 전술한 일실시예의 각 성분원료와 동일한 형태로써, 산업용 입자분쇄기(도시생략)에 의해 2~3㎛의 분말입자크기 분쇄가공하고, 분쇄가공된 셀룰로오스 분말을 산업용 초음파 진동선별기에 의해 정제처리하여 이용함이 바람직하다.In this case, the cellulose added in this embodiment is a odorless white solid obtained by degreasing cotton fibers and boiling with a dilute aqueous alkali solution, and having a material characteristic of an insulator function that prevents heat or electricity from flowing. In the application to the above, in the same form as each of the ingredients of the above-described embodiment, an industrial particle grinder (not shown) is used to grind the powder particle size of 2 ~ 3㎛, and the milled cellulose powder to the industrial ultrasonic vibrating separator It is preferable to use it by purification.
S1 : 첨가원료 분쇄공정
S2 : 첨가원료 정제공정
S3 : 방염코팅액 생성공정
S4 : 방염코팅제 제품화공정S1: additive raw material grinding process
S2: Additive Purification Process
S3: Flame retardant coating solution generation process
S4: Commercialization of Flame Retardant Coating Agent
Claims (4)
상기 증류수 용제에 인산암모늄 분말을 15~20% 중량비율;
인산나트륨 분말을 10~15%의 중량비율;
황산염 분말을 5~10%의 중량비율;
카올린 분말을 5~10% 중량비율;
시나몬 분말을 0.5~1%의 중량비율;
피톤치드 분말을 0.5~1%의 중량비율로 첨가 혼합하여 방염코팅 조성물을 생성함을 특징으로 하는 친환경 다기능 방염코팅제.Using distilled water having a weight ratio of 50 to 60% as a solvent;
15-20% by weight of ammonium phosphate powder in the distilled water solvent;
Sodium phosphate powder by weight ratio of 10 to 15%;
Sulfate powder by weight ratio of 5 to 10%;
5-10% weight ratio of kaolin powder;
Cinnamon powder by weight ratio of 0.5-1%;
Eco-friendly multi-functional anti-corrosive coating agent, characterized in that to produce a flame-retardant coating composition by adding and mixing phytoncide powder in a weight ratio of 0.5 ~ 1%.
상기 친환경 다기능 방염코팅제는, 방염코팅 조성물에 절연체로서의 셀룰로오스 분말을 8:2의 중량비율로 첨가 혼합하여 조성됨을 특징으로 하는 친환경 다기능 방염코팅제. The method of claim 1;
The eco-friendly multi-functional anti-corrosive coating agent, the eco-friendly multi-functional anti-corrosive coating agent is characterized in that the composition is formed by adding and mixing the cellulose powder as an insulator to the anti-flame coating composition in a weight ratio of 8: 2.
상기 친환경 다기능 방염코팅제는, 분사도포방식, 브러쉬 도포방식, 침지 도포방식 중 어느 하나의 방식에 의해 방염처리 대상물품에 코팅 처리됨을 특징으로 하는 친환경 다기능 방염코팅제. The method of claim 1 or 2;
The eco-friendly multi-functional anti-corrosive coating agent, the eco-friendly multi-functional anti-corrosive coating agent characterized in that the coating treatment to the flame-retardant treatment object by any one method of spray coating method, brush coating method, immersion coating method.
상기 분쇄처리된 각 성분원료를 산업용 초음파 진동선별기에 개별 투입하여, 진동필터링 작용에 의해 2~3㎛ 이상의 크기를 갖는 불량분말입자와 이물질을 선별처리하는 첨가원료 정제공정(S2);
50~60%의 중량비율로 마련된 증류수에, 정제공정을 행한 인산암모늄 분말 15~20% 중량비율, 인산나트륨 분말 10~15%의 중량비율, 황산염 분말 5~10%의 중량비율, 카올린 분말 5~10% 중량비율, 시나몬 분말 0.5~1%의 중량비율, 피톤치드 분말 0.5~1%의 중량비율로 첨가시키고, 이를, 산업용 믹싱기에 투입하여 60~80분간의 회전 교반작용에 의해 혼합하여 방염코팅 조성물을 형성하는 방염코팅액 생성공정(S3);
상기 생성된 방염코팅 조성물을 수동펌프식 분무용기, 에어 스프레이식 분사용기, 보관포장용기 중 어느 하나의 수용용기에 충진시켜 방염코팅제를 제품화하는 공정(S4)으로 이루어짐을 특징으로 하는 친환경 다기능 방염코팅제 제조방법.
The ammonium phosphate crystals and sodium phosphate crystals produced by the chemical reaction, sulfate powders and kaolin powders derived from natural minerals, and cinnamon powders and phytoncide powders obtained from natural plants are classified and classified. An additive raw material grinding step (S1) of separately feeding each ingredient raw material into an industrial particle grinder to grind into a powder particle size of 2 to 3 µm;
An additional raw material refining step (S2) of separately inputting each of the pulverized component raw materials into an industrial ultrasonic vibrating separator and sorting out defective powder particles and foreign matters having a size of 2 to 3 μm or more by vibrating filtering action;
15 to 20% weight ratio of ammonium phosphate powder, distilled water prepared in 50 to 60% weight ratio, the weight ratio of sodium phosphate powder 10 to 15%, the weight ratio of sulfate powder 5 to 10%, kaolin powder 5 -10% weight ratio, cinnamon powder 0.5-1% weight ratio, phytoncide powder 0.5-1% weight ratio, and added to the industrial mixer, mixed by rotation stirring for 60-80 minutes, flame retardant coating Flame retardant coating solution forming step of forming a composition (S3);
Eco-friendly multi-functional anti-corrosive coating agent comprising the step (S4) of filling the produced flame retardant coating composition in any one of the manual pump spray container, air spray-type spray container, the storage packaging container to produce a flame retardant coating agent. Manufacturing method.
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