KR102028612B1 - High strength lightweight concrete composition using sludge - Google Patents

High strength lightweight concrete composition using sludge Download PDF

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KR102028612B1
KR102028612B1 KR1020190081953A KR20190081953A KR102028612B1 KR 102028612 B1 KR102028612 B1 KR 102028612B1 KR 1020190081953 A KR1020190081953 A KR 1020190081953A KR 20190081953 A KR20190081953 A KR 20190081953A KR 102028612 B1 KR102028612 B1 KR 102028612B1
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sludge
aggregate
concrete composition
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KR20190104006A (en
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김영수
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경복대학교 산학협력단
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/027Lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0427Dry materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0076Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0032Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

본 발명은 시멘트, 물 및 골재에 혼화제를 첨가해서 콘크리트 조성물을 혼합 제조할 때에 상기 골재의 25% 이상을 인공 경량골재로 치환하여 사용하는 고강도 경량 콘크리트 조성물로서, 기건단위중량이 1850 kgf/㎥ 이하이면서 28일 압축강도가 27 MPa 이상이고, 상기 인공 경량골재는 오니를 구형상체로 성형하고 공기 중에서 건조한 후 1000 ℃ 까지 가열 소성하여 제조되는 오니로 이루어진 인공 경량골재인 것을 특징으로 하는, 오니를 활용한 고강도 경량 콘크리트 조성물을 제공한다.The present invention is a high-strength lightweight concrete composition used by replacing at least 25% of the aggregate with artificial lightweight aggregate when mixing the concrete composition by adding admixture to cement, water and aggregate, the dry weight of the unit is less than 1850 kgf / ㎥ While 28 days compressive strength is 27 MPa or more, the artificial lightweight aggregate is characterized in that the artificial lightweight aggregate made of sludge produced by molding the sludge into a spherical body and dried in air and calcined by heating to 1000 ℃. One high strength lightweight concrete composition is provided.

Description

오니를 활용한 고강도 경량 콘크리트 조성물 {High strength lightweight concrete composition using sludge}High strength lightweight concrete composition using sludge

본 발명은 오니를 활용한 고강도 경량 콘크리트 조성물에 관한 것으로, 보다 상세하게는 다양한 조건에서 발생하는 산업폐기물인 오니로 인공 경량골재를 만들어 콘크리트 조성물에 사용하여 경량화함으로써 구조물의 자중을 감소시키고 공사비를 절감할 수 있는 오니를 활용한 고강도 경량 콘크리트 조성물에 관한 것이다.The present invention relates to a high-strength lightweight concrete composition using sludge, and more specifically, to make artificial lightweight aggregate with industrial waste, which is generated under various conditions, and to use it in a concrete composition to reduce the weight of the structure and reduce construction cost. It relates to a high strength lightweight concrete composition utilizing sludge that can be.

다시 말해서, 본 발명은 콘크리트 조성물 중에서 무게가 가장 많이 나가는 자갈 등의 골재를 산업폐기물인 오니(슬러지, sludge)로 치환 대체함으로써 콘크리트의 자중을 경감한 경량콘크리트를 개발하여 고강도화 시킴으로 구조물에 적용하기 위한 조성물에 관한 것이다.In other words, the present invention is to replace the aggregates such as gravel, which weighs the most weight among the concrete composition with sludge (sludge), which is an industrial waste, to develop lightweight concrete that reduces the weight of concrete and apply it to the structure by increasing the strength. To a composition.

현대 건축에 있어 구조물의 주된 재료로 사용되는 콘크리트는 경제성과 우수한 성능을 가지고 있어 가장 많이 사용되고 있는 건설 재료이다. 그러나 콘크리트는 강도에 비해 중량이 크기 때문에 구조물의 자중을 증가시키는 단점을 가지고 있다. 더구나 최근의 구조물은 점차 고층화, 대형화되어 콘크리트의 고강도화 및 경량화에 대한 연구의 필요성이 대두되고 있다.Concrete, which is used as the main material of the structure in modern architecture, is the most used construction material because of its economic efficiency and excellent performance. However, concrete has a disadvantage of increasing the weight of the structure because the weight is greater than the strength. In addition, the recent structure of the structure is gradually higher and larger, the need for research on the high strength and light weight of concrete has emerged.

그러나 아직까지 구조용 경량골재의 부족, 고강도 경량 콘크리트의 배합 설계, 시공 기술의 부족 및 고강도 경량 콘크리트에 대한 인식 부족 등으로 경량골재가 구조용 재료로 사용되기보다는 단열이나 방음용인 비구조용 경량 콘크리트로 제조, 생산되고 있으며 고강도 경량 콘크리트에 대한 개발은 아직 미미한 실정이다.However, due to the lack of structural lightweight aggregate, mix design of high strength lightweight concrete, lack of construction technology and lack of awareness of high strength lightweight concrete, lightweight aggregate is manufactured from non-structural lightweight concrete that is used for insulation or sound insulation, rather than being used as structural material. The development of high-strength lightweight concrete is still insignificant.

한편, 인공골재는 자연골재에 비하여 기공율, 부피비중, 흡수율, 크기, 형상 등의 물성을 제어할 수 있다는 장점이 있어 고층건물, 교량 등의 자중 감소용 콘크리트 등 구조용 골재 분야, 또는 방음 및 방습용 콘크리트, 토양 대체재료, 배수재, 세라믹 담체 등의 비구조용 골재 분야에 폭 넓게 이용될 수 있다.On the other hand, artificial aggregate has the advantage of controlling the physical properties such as porosity, volume specific gravity, absorption rate, size, shape, etc., compared to natural aggregates, structural aggregates such as concrete for reducing the weight of high-rise buildings, bridges, or soundproofing and moisture proof It can be widely used in the field of non-structural aggregates such as concrete, soil substitute, drainage, ceramic carrier and the like.

최근 들어서는 다양한 산업폐기물로부터 친환경적인 인공 경량골재를 생산하는 연구가 활발히 진행되고 있다.Recently, research is being actively conducted to produce environmentally friendly artificial lightweight aggregates from various industrial wastes.

그 중에서, 특허문헌 1에는 폐기물인 석탄 비산재 및 석분오니를 점토에 첨가하여 4가지 다른 방법으로 성형한 뒤 1100~1200℃ 범위에서 소결하여 인공골재를 제조한 뒤, 성형체의 표면조직 및 소지조직 변화가 소결된 인공골재의 표면 치밀층(shell) 및 내부 환원영역(black core) 형성에 미치는 영향을 연구하여, 한 가지 배치조성으로부터 다양한 물성을 갖는 인공골재 제조가 가능하도록 하는 인공 경량골재를 제조하기 위한 성형방법이 공개되어 있다.Among them, Patent Document 1 is added to the coal fly ash and stone dust sludge as a waste and molded by four different methods and then sintered in the range of 1100 ~ 1200 ℃ to produce artificial aggregate, the surface structure and body structure changes of the molded body To study the effects on the surface dense layer (shell) and internal reduction zone (black core) formation of pre-sintered artificial aggregate, to manufacture artificial lightweight aggregate to enable the production of artificial aggregate having various properties from one batch composition Molding methods are disclosed.

또한, 특허문헌 2에는 오폐수 처리장에서 수거한 오니를 탈수 처리하여 수분을 제거하고, 폐유리를 분쇄하여 분말화시키는 원료 준비 단계와; 주원료로서 탈수된 오니 및 폐유리 분말과, 보조원료로서 붕사와 불화규소나트륨 중 선택된 어느 하나를 혼합한 후, 물을 첨가하여 교반하는 원료 혼합 단계와; 혼합된 원료를 구형 과립으로 제조하는 제립 단계와; 제조된 구형 과립의 건조 단계와; 건조된 구형 과립의 소성 및 냉각 단계를 포함하는 인공 경량골재의 제조 방법이 공개되어 있다.In addition, Patent Document 2 includes a raw material preparation step of dewatering the sludge collected in the waste water treatment plant to remove water, and pulverize the waste glass to powder; A raw material mixing step of mixing any one selected from dehydrated sludge and waste glass powder as a main raw material, and borax and sodium fluoride as an auxiliary raw material, and then adding water and stirring; A granulation step of preparing the mixed raw material into spherical granules; Drying the prepared spherical granules; Disclosed is a method for producing artificial lightweight aggregate, comprising the step of firing and cooling the dried spherical granules.

그러나, 위와 같은 특허문헌들은 다양한 환경 속에서 발생되는 산업폐기물인 오니를 석탄 비산재, 폐유리 등의 다른 산업폐기물들과 혼합하여 인공 경량골재를 제조하는 것과 관련된 기술들로서 산업폐기물인 오니만을 활용하여 인공 경량골재를 제조하는 것에 대해서는 공개된 바 없다.However, the above patent documents are related to the manufacture of artificial lightweight aggregate by mixing industrial sludge, which is generated in various environments, with other industrial wastes such as coal fly ash and waste glass. There is no disclosure about manufacturing lightweight aggregates.

또한, 위와 같은 특허문헌들에 공개된 인공 경량골재들은 경량성은 만족하겠지만, 고강도가 요구되는 구조용 재료로서 활용될 수 있다는 점에 대해서는 전혀 공개 또는 시사된 바 없다.In addition, artificial lightweight aggregates disclosed in the above patent documents will satisfy the light weight, but has not been disclosed or suggested at all that can be utilized as a structural material that requires high strength.

따라서, 산업폐기물인 오니를 활용하여 우수한 경제성은 물론, 경량성과 고강도성을 동시에 만족시킬 수 있는 고강도 경량 콘크리트 조성물에 대한 획기적인 연구가 필요한 실정이다.Therefore, the use of industrial waste sludge is a situation that requires a breakthrough research on high-strength lightweight concrete composition that can satisfy both light weight and high strength as well as excellent economic efficiency.

한국 등록특허공보 제10-1153904호Korean Patent Publication No. 10-1153904 한국 등록특허공보 제10-1123278호Korean Patent Publication No. 10-1123278

본 발명은 위와 같은 종래기술에서의 문제점들을 해결하기 위하여 안출된 것으로, 산업폐기물을 활용한 인공 경량골재를 자갈 등의 천연골재를 대체하여 사용함으로써 콘크리트 구조물의 자중을 줄일 수 있는 경량성과 더불어 천연골재의 고갈에 대한 대체효과 및 자연보호에도 기여할 수 있는 오니를 활용한 고강도 경량 콘크리트 조성물을 제공하는 것을 목적으로 한다.The present invention has been made to solve the problems in the prior art as described above, by using an artificial lightweight aggregate utilizing industrial waste to replace natural aggregates such as gravel natural aggregates with light weight to reduce the weight of the concrete structure The object of the present invention is to provide a high-strength lightweight concrete composition utilizing sludge that can contribute to the replacement effect and the protection of nature.

또한, 본 발명은 구조용 고강도 경량콘크리트 조성물을 개발하여 건축 구조물의 자중을 줄임으로써 부재 단면을 축소하고 시공을 간소화시킬 수 있기 때문에 전체 건설 비용을 절감할 수 있는 오니를 활용한 고강도 경량 콘크리트 조성물을 제공하는 것을 또다른 목적으로 한다. In addition, the present invention provides a high-strength lightweight concrete composition using sludge that can reduce the overall construction cost because by reducing the weight of the building structure by developing a high-strength lightweight concrete composition for structural reduction and simplifying construction Another purpose is to do it.

상기와 같은 목적을 달성하기 위한 본 발명의 일 실시예에 따른 오니를 활용한 고강도 경량 콘크리트 조성물은, 기건단위중량이 1850 kgf/㎥ 이하이면서 28일 압축강도가 27 MPa 이상인 고강도 경량 콘크리트 조성물로서, 시멘트, 물, 모래, 골재 및 혼화제만이 중량배합(kgf/㎥) 기준으로, 시멘트 : 물 : 모래 : 골재 : 혼화제 = 7.3 : 1.88 ~ 3.08 : 19.3 : 15.4 : 0.04의 비율로 혼합되어 이루어지고, 중량배합 기준으로 상기 골재의 25% 이상을 인공 경량골재로 치환하여 사용하되, 상기 인공 경량골재는 오니를 구형상체로 성형하고 공기 중에서 건조한 후 1000 ℃ 까지 가열 소성하여 제조되는 오니로 이루어진 인공 경량골재이고, 상기 오니로 이루어진 인공 경량골재는 직경 5 mm, 10 mm, 20 mm의 구형상체를 각각 제조한 후 혼합 사용하는 것을 특징으로 한다.High-strength lightweight concrete composition using sludge according to an embodiment of the present invention for achieving the above object is a high-strength lightweight concrete composition having a unit weight of 1850 kgf / ㎥ or less and 28 days compressive strength of 27 MPa or more, Only cement, water, sand, aggregate and admixtures are mixed by weight ratio (kgf / ㎥), cement: water: sand: aggregate: admixture = 7.3: 1.88 ~ 3.08: 19.3: 15.4: 0.04 It is used by replacing at least 25% of the aggregate with an artificial lightweight aggregate on the basis of weight mixing, wherein the artificial lightweight aggregate is an artificial lightweight aggregate made of sludge manufactured by molding sludge into a spherical body, drying in air, and heating and baking to 1000 ° C. And, the artificial lightweight aggregate made of sludge is characterized in that the use after mixing the spherical body of 5 mm, 10 mm, 20 mm in diameter, respectively.

또한, 본 발명의 일 실시예에 따른 오니를 활용한 고강도 경량 콘크리트 조성물은, 상기 오니로 이루어진 인공 경량골재는 가연성 재질의 코어를 오니가 감싸는 구형상체로 성형된 후 가열 소성되는 것을 특징으로 한다.In addition, the high-strength lightweight concrete composition using sludge according to an embodiment of the present invention is characterized in that the artificial lightweight aggregate made of sludge is heated and calcined after being molded into a spherical body wrapped around the core of a combustible material.

또한, 본 발명의 일 실시예에 따른 오니를 활용한 고강도 경량 콘크리트 조성물의 제조방법은, 위와 같은 실시예에 따른 오니를 활용한 고강도 경량 콘크리트 조성물의 제조방법으로서, 오니를 구형상체로 성형하고 공기 중에서 건조한 후, 1000 ℃ 까지 가열 소성하여 오니로 이루어진 인공 경량골재를 준비하는 단계, 및 시멘트, 물, 모래, 골재 및 혼화제만을 혼합하되, 상기 골재에는 상기 오니로 이루어진 인공 경량골재가 중량 배합 기준으로 25% 이상 치환하여 사용되는 혼합 단계를 포함하고, 상기 오니로 이루어진 인공 경량골재를 준비하는 단계는, 직경 5 mm, 10 mm, 20 mm의 구형상체를 각각 제조한 후 혼합 사용하는 것을 특징으로 한다.In addition, the method of manufacturing a high strength lightweight concrete composition using sludge according to an embodiment of the present invention, as a method of manufacturing a high strength lightweight concrete composition using sludge according to the above embodiment, by molding the sludge into a spherical body and air After drying, heating and firing to 1000 ℃ to prepare an artificial lightweight aggregate made of sludge, and mixing only cement, water, sand, aggregate and admixture, the aggregate artificial lightweight aggregate made of sludge on the aggregate Including the mixing step used to replace more than 25%, the step of preparing an artificial lightweight aggregate consisting of the sludge, characterized in that for producing the spherical body of 5 mm, 10 mm, 20 mm in diameter and then mixed and used .

위와 같은 구성을 갖는 본 발명에 따른 오니를 활용한 고강도 경량 콘크리트 조성물을 사용하게 되면, 전국에서 나올 수 있는 산업폐기물을 이용해 인공 경량골재를 만들어 자원을 재활용할 수 있는 장점이 있을 뿐만 아니라, 경제성이 있는 고강도 경량 콘크리트가 개발되면 구조체의 자중이 감소함에 따라 공사비의 절감을 얻을 수 있다.When using a high-strength lightweight concrete composition using sludge according to the present invention having the configuration as described above, there is an advantage to recycle resources by making artificial lightweight aggregate using industrial waste that can come from all over the country, If high strength lightweight concrete is developed, the construction cost can be reduced as the weight of the structure is reduced.

또한, 콘크리트가 경량화 되면 구조부재 크기를 감소시켜 구조체의 공사비용과 철근 배근량이 줄어들며 시공비용도 절감되므로 전체 건설비용의 약 10%를 절감할 수 있는 효과가 있다.In addition, when the light weight of concrete reduces the size of the structural member, the construction cost and reinforcement amount of the structure is reduced, and the construction cost is also reduced, thereby reducing about 10% of the total construction cost.

도 1은 압축강도 시험용 공시체의 무게를 비교하여 도시한 그래프,
도 2는 압축강도 시험용 공시체의 압축강도를 비교하여 도시한 그래프,
도 3은 콘크리트 보 실험체 제작을 위한 도면,
도 4는 콘크리트 보 실험체에 대한 실험을 위한 실험실 세팅 도면,
도 5는 콘크리트 보 실험체의 실험 사진,
도 6은 실험 후의 콘크리트 보 실험체 사진,
도 7은 콘크리트 보 실험체의 실험 결과 그래프이다.
1 is a graph showing the comparison of the weight of the test specimen for compressive strength,
2 is a graph comparing the compressive strength of the test specimen for compressive strength,
3 is a view for manufacturing a concrete beam test specimen,
4 is a laboratory setting diagram for an experiment on a concrete beam specimen,
5 is an experimental photograph of the concrete beam test specimen,
6 is a concrete beam specimen after the experiment,
7 is a graph showing experimental results of concrete beam specimens.

이하에서는 첨부 도면을 참조하여 본 발명의 일 실시예에 따른 오니를 활용한 고강도 경량 콘크리트 조성물에 대하여 상세히 설명한다.Hereinafter, with reference to the accompanying drawings will be described in detail with respect to high-strength lightweight concrete composition using sludge according to an embodiment of the present invention.

우선적으로, 본 발명의 일 실시예에 따른 오니를 활용한 고강도 경량 콘크리트 조성물의 경우, 시멘트, 물, 모래, 골재와 혼화제만을 혼합하여 기건단위중량이 1850 kgf/㎥ 이하이면서 28일 압축강도가 27 MPa 이상이 되는 고강도 경량 콘크리트 조성물을 제공할 수 있도록 해야 한다. 경량 콘크리트로서의 요구 조건과 고강도 콘크리트로서의 요구 조건을 동시에 만족시켜야 하기 때문이다.First, in the case of high-strength lightweight concrete composition using sludge according to an embodiment of the present invention, by mixing only cement, water, sand, aggregate and admixture, the dry weight of the unit is 1850 kgf / ㎥ or less 28 days compressive strength 27 It should be possible to provide high strength lightweight concrete compositions that are at least MPa. This is because the requirements as lightweight concrete and the requirements as high strength concrete must be satisfied at the same time.

여기서, 상기 혼화제는 내구성개선, 응결경화조절, 유동성개선 목적으로 사용되고 사용량이 비교적 적어(1% 이하) 배합설계시 무시되는 AE제, 유동화재 등을 지칭하며, 잠재수경성, 팽창유발, 고강도 등의 목적으로 사용량이 비교적 많아서(5% 이상) 콘크리트 배합설계시 고려되는 플라이애시, 고로슬래그, 실리카흄, 포졸란 등의 혼화재와 명확히 구별된다.Here, the admixture refers to AE agents, fluidized fires, etc., which are used for the purpose of durability improvement, coagulation hardening control, and fluidity improvement, and are neglected when used in a compounding design (less than 1%). Due to its relatively high usage (more than 5%), it is clearly distinguished from admixtures such as fly ash, blast furnace slag, silica fume, and pozzolane, which are considered in concrete mix design.

이처럼 본 발명에서는 시멘트, 물, 모래, 골재와 혼화제만을 혼합하여 이루어지는 콘크리트 조성물만으로도, 즉, 고강도화의 목적으로 플라이애시, 고로슬래그 등의 혼화재를 다량으로 배합 사용하지 않더라도 고강도화 및 경량화가 가능하도록 함을 특징으로 한다.Thus, in the present invention, even if only a concrete composition consisting of only admixtures with cement, water, sand, aggregate and admixture, that is, high strength and light weight can be achieved even without using a large amount of admixture such as fly ash, blast furnace slag for the purpose of high strength. It features.

경량골재는 자연 경량골재와 인공 경량골재로 나눌 수 있으며 경량골재의 종류에는 여러 가지가 있으나, 본 발명의 일 실시예에 따른 고강도 경량 콘크리트 조성물에서는 다양한 환경에서 발생되는 산업폐기물인 오니를 사용하여 인공 경량골재를 제조하여 사용한다.Light weight aggregates can be divided into natural light weight aggregates and artificial light weight aggregates, but there are various kinds of light weight aggregates, in the high-strength lightweight concrete composition according to an embodiment of the present invention, using artificial sludge, which is an industrial waste generated in various environments, Manufacture and use lightweight aggregate.

이러한 인공 경량골재가 건설 구조물에 사용되기 위해서는, 압축강도 및 콘크리트 보의 휨성능과 전단성능 등 콘크리트의 일반적인 성능을 만족하여야 한다.In order to use such an artificial lightweight aggregate in a construction structure, the general performance of concrete, such as compressive strength and bending performance and shear performance of the concrete beam, must be satisfied.

그 중에서 제일 중요한 요소인 압축강도를 만족시키는지 확인하기 위해서 콘크리트 공시체를 만들고 압축강도 시험을 통해 확인하였다.In order to check whether the compressive strength, which is the most important factor, is satisfied, concrete specimens were made and confirmed by compressive strength test.

인공 경량골재를 성형 제조하기 위하여, 산업폐기물인 오니를 점토와 같은 상태에서 대략 직경 5 mm, 10 mm, 20 mm의 크기의 구형상체로 만들어 공기 중에서 물기가 없을 정도로 건조시킨다. 건조된 인공 경량골재를 약 1000 ℃ 까지 소성 가열하여 최종적으로 오니로 이루어진 인공 경량골재를 준비한다. 위와 같이 직경이 다른 구형상체로 제조한 후 혼합하여 사용할 경우, 제조가 용이할 뿐 아니라, 굵은 골재 및 세골재로 적절하게 치환 사용이 가능하고, 혼합 사용에 따른 기공 조절 등이 용이하다는 장점이 있다.In order to manufacture the artificial lightweight aggregate, industrial waste sludge is made into spherical bodies having a diameter of about 5 mm, 10 mm, and 20 mm in a clay-like state and dried to dryness in the air. The dried artificial lightweight aggregate is calcined and heated to about 1000 ° C. to finally prepare an artificial lightweight aggregate composed of sludge. When prepared by mixing the spherical body with a different diameter as described above, not only is easy to manufacture, but also can be used appropriately substituted by coarse aggregate and fine aggregate, there is an advantage that the pore control according to the mixed use is easy.

이때, 인공 경량골재의 추가 경량화를 위하여 직경 20 mm의 비교적 굵은 골재용의 인공 경량골재 등의 경우, 소성 가열 단계에서 타서 제거됨으로써 추가적인 기공을 생성할 수 있도록 종이, 신문지, 휴지 등의 가연성 재질을 중앙에 코어로 활용하여 구형상체로 성형하는 것이 바람직하다. 또한, 인공 경량골재의 입형은 구형에 가깝고 입자 표면 상태는 요철이 없이 매끄러운 상태가 되도록 성형 제조하는 것이 바람직하다.At this time, in order to further reduce the weight of the artificial lightweight aggregate artificial lightweight aggregate for a relatively thick aggregate having a diameter of 20 mm, such as paper, newspaper, tissue paper, and combustible materials to create additional pores by burning and removing during the firing step. It is preferable to shape | mold in spherical shape by utilizing as a core in a center. In addition, it is preferable that the granular shape of the artificial lightweight aggregate is molded and manufactured so as to be close to a spherical shape and the particle surface state is smooth without irregularities.

위와 같이 오니로 제조된 인공 경량골재를 KS F 2503 2002에 따라 시험한 물리적 성질은 다음 표 1과 같다.The physical properties tested according to KS F 2503 2002 for artificial lightweight aggregate made of sludge as shown above are shown in Table 1 below.

시험항목Test Items 시료구분Sample classification 시험방법Test Methods 5 mm5 mm 10 mm10 mm 20 mm20 mm 표면건조포화상태의 밀도 (g/㎤)Density in surface dry saturation (g / cm 3) 2.152.15 1.851.85 1.931.93 KS F 2503
2002
KS F 2503
2002
절대건조밀도 (g/㎤)Absolute Dry Density (g / cm 3) 1.851.85 1.591.59 1.671.67 흡수율 (%)Absorption rate (%) 15.7715.77 16.5516.55 15.8115.81

한편, 위와 같이 제조한 인공 경량골재와 일반적인 콘크리트 조성물에서 골재로 사용되는 쇄석의 비중 및 공기량 측정을 아래 표 2에 도시한 바와 같이 진행하였다.On the other hand, the measurement of the specific gravity and air amount of the crushed stone used as aggregate in the artificial lightweight aggregate and the general concrete composition prepared as described above as shown in Table 2 below.

Figure 112019069591914-pat00001
Figure 112019069591914-pat00001
Figure 112019069591914-pat00002
Figure 112019069591914-pat00002

시멘트는 KS L 5201의 규정에 의거 보통 포틀랜드 시멘트를 사용하였으며, 물은 수경성 시멘트에 있어서 1차적 영향 요인으로 시멘트와의 수화작용을 통하여 콘크리트 강도 발현 및 내구성에 미치는 영향이 크므로 KASS 5.2.3의 규정에 따라 그름, 산, 알칼리, 염류, 유기물 등을 포함하지 아니한 시험실 내 상수도를 사용하였다.As cement, portland cement is used in accordance with KS L 5201. Water is the primary influencing factor in hydraulic cement, and water has a great effect on concrete strength development and durability through hydration with cement. In-house tap water was used according to the regulations, which did not include groups such as acid, alkali, salt, organic matter, etc.

고성능 AE 감수제는 나프탈렌계로서 비중이 1.2 ± 0.02이며 암갈색의 액상 혼화제를 사용하였고, 그 특성은 다음 표 3과 같다.The high-performance AE water reducing agent is naphthalene-based, specific gravity of 1.2 ± 0.02, dark brown liquid admixture was used, the characteristics are shown in Table 3.

유형type color 주성분chief ingredient 특성characteristic 빙점freezing point 비중importance 액상Liquid 암갈색bitumen Naphthalene
sulphonate
Naphthalene
sulphonate
없음none -2℃-2 ℃ 1.2±0.021.2 ± 0.02

또한, 본 발명에서 사용된 굵은 골재 크기(10 mm, 20 mm), 잔골재의 크기(5 mm), 잔골재의 비중 및 흡수량 시험은 각각 KS F 2504에 의거 실시하였고, 단위용적중량과 빈틈시험은 KS F 2505, KS F2506에 의거 실시하였다.In addition, the coarse aggregate size (10 mm, 20 mm), fine aggregate size (5 mm), the specific gravity and the absorption of the fine aggregates used in the present invention were carried out in accordance with KS F 2504, respectively, the unit volume weight and gap test were KS It carried out based on F2505 and KS F2506.

물시멘트비는 기존의 연구에서 효과가 있는 것으로 확인된 50%로 하였고, 시험 인자는 인공 경량골재의 쇄석 대체율을 25%, 50%, 100%로 설정하여 시험체를 제작하였다.The water cement ratio was 50%, which was found to be effective in the existing studies, and the test factor was set to 25%, 50%, and 100% for the replacement of artificial lightweight aggregates.

위와 같이 준비된 시멘트, 인공경량골재, 모래, 쇄석, 혼화제 및 물을 혼합하여 콘크리트 공시체를 제작하여, 무게 및 압축강도를 다음 표 4에 나타낸 바와 같이 측정하였다. 시험체 배합비는 다음 표 5에 나타낸다.The cement, artificial lightweight aggregate, sand, crushed stone, admixture and water prepared as described above were prepared to prepare a concrete specimen, and the weight and compressive strength were measured as shown in Table 4 below. The test mixture ratio is shown in Table 5 below.

Figure 112019069591914-pat00003
Figure 112019069591914-pat00003
Figure 112019069591914-pat00004
Figure 112019069591914-pat00004

공시체Specimen 중량배합(kgf/㎥)Weight compounding (kgf / ㎥) 공시체 중량Specimen weight 시멘트cement 경량골재Lightweight aggregate 쇄석broken stone 모래sand water 혼화제Admixture 일반콘크리트General Concrete 7.37.3 00 15.415.4 19.319.3 3.083.08 0.040.04 3.623.62 대체율 25%25% replacement rate 3.473.47 11.9311.93 1.881.88 3.493.49 대체율 50%50% replacement rate 6.946.94 5.975.97 1.931.93 3.303.30 대체율 100%100% replacement rate 15.415.4 00 2.492.49 3.163.16

공시체 제작은 KS F 2403에 의거하여 Φ10 x 20 cm의 크기로 각 대체율 조합별로 압축강도용 3개씩 제작하고, 24시간 후에 캡핑(Capping) 한 뒤, 다시 24시간 동안 기건양생 후 탈형하여 20 ± 2 ℃의 항온 수조에서 28일간 수중 양생하였다.The specimens were manufactured in accordance with KS F 2403 with a size of Φ10 x 20 cm for each compressive strength combination, 3 pieces for compressive strength, capping after 24 hours, and demolded for 24 hours after demolding for 20 ± 2 It was cured in water for 28 days in a constant temperature water bath.

위와 같이 제작한 공시체의 무게 및 압축강도를 비교해 본 결과, 도 1 및 도 2에 도시한 바와 같이, 중량면에서 본 발명에 따른 고강도 경량 콘크리트가 일반 콘크리트에 비해 약 15%까지 감소를 보였고, 본 발명에 따른 고강도 경량 콘크리트의 20일자 압축강도가 18 MPa ~ 33 MPa의 범위에 있어, 28일 압축강도로 환산하면 20 MPa ~ 38 MPa로 보일 것으로 생각되어, 고강도의 기준값인 27 MPa를 상회하는 범위 내로 제조할 수 있음을 확인하였다.As a result of comparing the weight and compressive strength of the specimen prepared as described above, as shown in Figures 1 and 2, the high-strength lightweight concrete according to the present invention showed a reduction of about 15% compared to the general concrete in terms of weight, The 20-day compressive strength of the high-strength lightweight concrete according to the invention is in the range of 18 MPa to 33 MPa, and in terms of 28-day compressive strength, it is considered to be 20 MPa to 38 MPa, exceeding the high strength standard value of 27 MPa. It was confirmed that it can be prepared into.

다음으로, 본 발명에 따른 고강도 경량 콘크리트 조성물의 압축강도에 이어 콘크리트 구조물로의 효용 가치를 확인해 보기 위해서, 콘크리트 보의 휨성능과 전단성능을 확인하기 위해서 실험체를 5개 제작하여 국제공인시험기관인 (주)토탈이엔씨(한양대 에리카캠퍼스)에서 구조실험(휨 및 전단강도)을 실시하였다.Next, in order to confirm the utility value of the high strength lightweight concrete composition according to the present invention to the concrete structure, in order to confirm the bending performance and shear performance of the concrete beam, five test specimens were manufactured and manufactured by the internationally recognized testing institute ( Note) Structural experiments (bending and shear strength) were conducted at Total E & C (Hanyang University Erica Campus).

보 실험체는 휨성능과 전단성능을 검증하기 위해서 실험인자로 보의 휨에 대해서는 주근으로, 전단은 늑근 간격으로 하였으며, 실험체의 축척은 제작 환경과 운반 여건 등을 고려하여 1/2로 하였다. 보의 실험체는 일반 콘크리트 3개, 고강도 경량 콘크리트 2개, 총 5개를 제작하였으며 실험체 사양은 다음 표 6 및 도 3에 나타냈다. 상기 고강도 경량 콘크리트는 위의 실시예에서 설명한 쇄석 대체율 25%의 오니를 활용한 고강도 경량 콘크리트 조성물을 이용하여 제조한 것이다.The beam specimens were used as test factors to verify the flexural and shear performances. The beams were used as the main root for the bending of the beams, and the shear was the spacing of the roots. The scale of the specimens was 1/2 in consideration of the manufacturing environment and transport conditions. The test specimens of the beam were made of three general concretes, two high-strength lightweight concretes, and a total of five. The specimen specifications are shown in Table 6 and FIG. 3. The high strength lightweight concrete is prepared using a high strength lightweight concrete composition utilizing sludge of 25% crushed stone replacement rate described in the above embodiment.

NONO 실험체명Subject name 주근Freckle 늑근Weight 비고Remarks 1One C@200C @ 200 2-HD132-HD13 Φ9@200Φ9 @ 200 일반콘크리트/중앙부 Φ9@300General concrete / center Φ9 @ 300 22 LC@200LC @ 200 2-HD132-HD13 Φ9@200Φ9 @ 200 경량콘크리트/중앙부 Φ9@300Lightweight concrete / center Φ9 @ 300 33 C@300C @ 300 2-HD132-HD13 Φ9@300Φ9 @ 300 일반콘크리트General Concrete 44 LC@300LC @ 300 2-HD132-HD13 Φ9@300Φ9 @ 300 경량콘크리트Lightweight concrete 55 CONCON 무근Rootless 무근Rootless 일반콘크리트General Concrete

위와 같은 보 실험체에 대한 실험을 위한 실험실 세팅 현황은 도 4에 도시한 바와 같고, 실험에 사용한 실험 장비의 제원은 다음 표 7과 같다.The laboratory setting status for the experiment on the beam specimen as described above is shown in Figure 4, the specifications of the experimental equipment used in the experiment is shown in Table 7 below.

용 량Volume 수 량Quantity 500kN 엑츄에이터500 kN actuator Stroke: ±150mm
Force : ±500kN
Stroke: ± 150mm
Force: ± 500kN
1One
데이터로거(TDS-303)Data Logger (TDS-303) 30 CH30 CH 1One LVDTLVDT 200mm
100mm
200 mm
100 mm
1
2
One
2

경량 콘크리트 실험체는 표면의 골재 부립에 따른 요철 등의 현상이 발견되지 않아 배합과 다짐 등의 시공이 양호하게 제작되었음을 확인할 수 있었고, 실험 결과는 도 7과 같으며, 무근 일반콘크리트를 제외하고 휨균열에 의해 파괴되었으며(실험 과정 및 실험 후의 사진인 도 5 및 도 6 참조) 경량 콘크리트의 휨성능과 전단성능은 일반 콘크리트와 큰 차이가 없음을 확인할 수 있었다.Lightweight concrete specimens were confirmed that the construction of the formulation and compaction was made well because the phenomenon such as irregularities due to the aggregate aggregate of the surface was not found, the experimental results are as shown in Figure 7, except for the normal concrete without bending cracks It was destroyed by (see Fig. 5 and 6, the experimental process and the photograph after the experiment) it was confirmed that the bending performance and shear performance of the lightweight concrete is not significantly different from the general concrete.

Claims (3)

기건단위중량이 1850 kgf/㎥ 이하이면서 28일 압축강도가 27 MPa 이상인 고강도 경량 콘크리트 조성물로서,
시멘트, 물, 모래, 골재 및 혼화제만이 중량배합(kgf/㎥) 기준으로, 시멘트 : 물 : 모래 : 골재 : 혼화제 = 7.3 : 1.88 ~ 3.08 : 19.3 : 15.4 : 0.04의 비율로 혼합되어 이루어지고,
중량배합 기준으로 상기 골재의 25% 이상을 인공 경량골재로 치환하여 사용하되,
상기 인공 경량골재는 오니를 구형상체로 성형하고 공기 중에서 건조한 후 1000 ℃ 까지 가열 소성하여 제조되는 오니로 이루어진 인공 경량골재이고,
상기 오니로 이루어진 인공 경량골재는 직경 5 mm, 10 mm, 20 mm의 구형상체를 각각 제조한 후 혼합 사용하는 것을 특징으로 하는, 오니를 활용한 고강도 경량 콘크리트 조성물.
High strength lightweight concrete composition with a unit weight of 1850 kgf / ㎥ or less and 28 days compressive strength of 27 MPa or more,
Only cement, water, sand, aggregate and admixtures are mixed by weight ratio (kgf / ㎥), cement: water: sand: aggregate: admixture = 7.3: 1.88 ~ 3.08: 19.3: 15.4: 0.04
25% or more of the aggregates on the basis of the weight of the composite to be replaced with artificial lightweight aggregate,
The artificial lightweight aggregate is an artificial lightweight aggregate made of sludge which is manufactured by molding sludge into a spherical body and drying in air and then heating and baking to 1000 ° C.,
The artificial lightweight aggregate consisting of the sludge is characterized in that the mixture used to produce a spherical body of 5 mm, 10 mm, 20 mm in diameter, respectively, high strength lightweight concrete composition utilizing sludge.
청구항 1에 있어서,
상기 오니로 이루어진 인공 경량골재는 가연성 재질의 코어를 오니가 감싸는 구형상체로 성형된 후 가열 소성되는 것을 특징으로 하는, 오니를 활용한 고강도 경량 콘크리트 조성물.
The method according to claim 1,
The artificial lightweight aggregate made of sludge is characterized in that the core of the combustible material is molded into a spherical body wrapped around the sludge and then heated and fired, high strength lightweight concrete composition utilizing sludge.
청구항 1 또는 청구항 2에 기재된 오니를 활용한 고강도 경량 콘크리트 조성물의 제조방법으로서,
오니를 구형상체로 성형하고 공기 중에서 건조한 후, 1000 ℃ 까지 가열 소성하여 오니로 이루어진 인공 경량골재를 준비하는 단계, 및
시멘트, 물, 모래, 골재 및 혼화제만을 혼합하되, 상기 골재에는 상기 오니로 이루어진 인공 경량골재가 중량 배합 기준으로 25% 이상 치환하여 사용되는 혼합 단계를 포함하고,
상기 오니로 이루어진 인공 경량골재를 준비하는 단계는, 직경 5 mm, 10 mm, 20 mm의 구형상체를 각각 제조한 후 혼합 사용하는 것을 특징으로 하는, 오니를 활용한 고강도 경량 콘크리트 조성물의 제조방법.
A method for producing a high strength lightweight concrete composition using sludge according to claim 1 or 2,
Molding the sludge into a spherical body and drying in air, and calcining it by heating to 1000 ° C. to prepare an artificial lightweight aggregate made of sludge; and
Mixing only cement, water, sand, aggregate and admixture, the aggregate includes a mixing step in which the artificial lightweight aggregate made of sludge is substituted by at least 25% by weight,
The step of preparing an artificial lightweight aggregate made of sludge, characterized in that for producing a spherical body of 5 mm, 10 mm, 20 mm in diameter, respectively, mixed and used, the method for producing a high strength lightweight concrete composition using sludge.
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