KR102000529B1 - skin care kit and skin care method - Google Patents

Abstract

The present invention relates to a skin care composition kit and skin care method. The present invention relates to a basic composition of elastin polymer, similar to the elasticity of skin tissue and a specific drug release system using a polymer, and also relates to a dual-cured silicone composition that cures quickly at room temperature to form elastin morphology with physical properties similar to skin tissue. The present invention also relates to a system in which such a composition forms a film on the skin while at the same time slowly releasing a specific drug.

Description

Skin care kit and skin care method "

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a skin care composition kit and a skin care method, and more particularly, to a characteristic drug release system using an elastin polymer basic composition and a polymer similar to the elasticity of skin tissue. Minimizing or even eliminating skin wrinkles and other skin changes associated with environmental damage.

The skin is aged by many compounds or damaged by the external environment. In addition, the skin is damaged by a number of extrinsic and intrinsic factors. Exogenous factors include ultraviolet rays, environmental pollution, atmospheric, humidity, surfactants contained in living products, abrasives, and the like. Endogenous factors include chronological aging and biochemical changes from within the skin. These factors are visible signals of skin aging and environmental damage, such as wrinkles and other forms of roughness, skin aging, or other systemic changes associated with damage. For many people, skin wrinkles indicate the disappearance of the sound. After all, wrinkle removal is an area of industry that is booming in a society that recognizes youth.

The therapies in these related industries range from cosmetics to creams and moisturizers to various types of cosmetic surgery.

Therefore, in order to satisfy the above-mentioned range, an environment similar to elastin in the skin tissue is formed on the surface of the skin.

Skin is a multipurpose organ with multiple physiological functions and provides protection from external environments. It serves as a guard to mitigate exposure to external factors such as extreme temperatures (temperature, toxins, microorganisms, radiation) and internally acts as a barrier to aging, environmental changes and certain disease states.

Skin changes suddenly due to internal or external changes. That is, as the aging of skin progresses, the integrity of biomechanics is lost and at the same time, it becomes more vulnerable to environmental changes. In addition, the elastin action of the skin is reduced, causing problems in wound healing. In addition, due to advances in material science and engineering, techniques for delivering medicines have been greatly developed. However, the above-mentioned problems may result in a decrease in original purpose functions. Thus, there is a need for a "skin memory" that can be worn invisibly to restore skin barrier function and normal elastin action while reducing normal skin loss by aging.

Korean Patent No. 10-1689639

The present invention is to apply a two-step topical application to implement a system that safely and easily attaches to and maintains skin, while releasing the active ingredient.

The first step is a reactive, polysiloxane-reactive polysiloxane component that undergoes crosslinking cure due to the addition reaction of siloxane containing Si-H to unsaturated groups in the presence of active platinum.

The second step involves the step of finely curing the surface of the first cross-linked cured silicone to produce the bound polysiloxane network as an enantiomer of the enantiomer.

In the case of using the polymer made of the conventional silicone addition polymerization, the skin elasticity is not taken into consideration, or excessive water or hydrogen gas is generated when the addition polymerization hardening occurs, which causes irritation to the skin.

The present invention provides a dual cured polysiloxane network that maintains the reflectance and elasticity of light similar to the skin when the individual's skin condition is at its maximum. In addition, it is a technical problem of the present invention to form a chemically stereoscopic (3D) polymer network which is superior in skin stickiness to form a natural skin.

The third step includes the step of releasing a specific active ingredient in the course of the second step.

Accordingly, a technical problem to be solved by the present invention is to design and develop optimal biomimetic skin compatibility. In addition, the transparent elastic film is intended to restore safety and normal skin aesthetics to the skin while applying stress to the surface of the skin, while restricting the skin shape by penetrating a specific component into the epidermis to be used in various cosmetic and medical applications. Technical challenges and objectives.

The object of the present invention is not limited to the above-mentioned object. The objects of the present invention will become more apparent from the following description, which will be realized by means of the appended claims and their combinations.

An aspect of the present invention is a skin care kit, said kit comprising a kit comprising:

(a) a polymer composite composition similar to a skin elastin structure comprising as the composition A polyvinylsiloxane, hydrosiloxane, silica, additives, emulsifiers, thickeners and preservatives;

(b) at least one of platinum activated as the composition B, or a metal or catalyst selected from the group consisting of a platinum catalyst, a palladium catalyst or a rhodium catalyst, an organic solvent, a substance with double crosslinking, an additive, a preservative, ; And

(c) the composition A is applied to the skin and then the composition B is applied to the layer A coated.

In one aspect of the present invention, the polyvinylsiloxane of the composition A is selected from the group consisting of polydimethylsiloxane having a vinyl group molar concentration of 0.015 to 3.00 mmoles / gm and copolymers or cyclic copolymers thereof, polydimethylsiloxane diphenylsiloxane copolymer and Wherein the polyvinylsiloxane is at least one of a cyclic copolymer thereof, Silgard 184, 2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane, and a copolymer thereof, A and 20 to 50 parts by weight based on 100 parts by weight of the skin care kit.

In one aspect of the present invention, the hydrosiloxane of the composition A is at least one of a polydimethylsiloxane methylhydrosiloxane copolymer, a polydimethylsiloxane and a copolymer thereof, and the molar concentration of Si-H is 0.10 to 9.00 mmoles / gm , And 5 to 20 parts by weight based on 100 parts by weight of the composition A.

In one aspect of the present invention, the skin of the composition A is at least one of fumed silica, precipitated silica, diatomaceous earth, ground quartz and fused quartz, and 0.01 to 8.0 parts by weight based on 100 parts by weight of the composition A, to provide.

In one aspect of the present invention, the activated platinum or platinum-based catalyst of the composition B is selected from platinum, chloroplatinic acid, a reactant of chloroplatinic acid with a monohydric alcohol, a complex of chloroplatinic acid with olefins, platinum tetramethyl divinyl disiloxane, And 0.5 to 2.0 parts by weight based on 100 parts by weight of the B composition.

In one aspect of the present invention, the organic solvent of the composition B is at least one selected from aliphatic alcohols, aromatic hydrocarbons, aliphatic or substituted hydrocarbons, halogenated hydrocarbons, and ketones, and is used in an amount of 30 to 50 parts by weight , Skin care kit.

In one aspect of the invention, the material comprising the double bridging of the composition B is selected from the group consisting of Iron Oxides and Isopropyl Titanium Triisostearate Mixtures, Chromium Oxide Greens and Isopropyl Titanium Triisostearate Mixtures, Chromium Hydroxide Greens and Isopropyl Titanium Triisostearate Mixtures, Ferric Ammonium Ferrocyanide and Isopropyl Mixtures of Titanium Triisostearate, Iron Oxides, Talc and Isopropyl Titanium Triisostearate, Mixtures of Manganese Violet and Isopropyl Titanium Triisostearate, Mixtures of Ultramarines and Isopropyl Titanium Triisostearate, Mixtures of Titanium Dioxide and Isopropyl Titanium Triisostearate, Mixtures of Titanium Dioxide, Aluminum Hydroxide and Isopropyl Titanium Triisostearate, Iron Oxides , Titanium Dioxide, Aluminum Hydroxide and Isopropyl Titanium Triisostearate Mixture, Zinc Oxide and Isopropyl Titanium Triisostearate Mixture, Polymethylmethacrylate and Isopropyl Titanium Triisostearate Mixture, Nylon 12 and Isopropyl Titanium Triisostearate e mixture, Mica and Isopropyl Titanium Triisostearate mixture, Talc and Isopropyl Titanium Triisostearate mixture, Aluminum Starch Octenylsuccinate and Isopropyl Titanium Triisostearate mixture, and 0.1 to 10 parts by weight based on 100 parts by weight of Composition B, Skin skin care kit.

Another aspect of the present invention is a skin skin care method comprising the steps of: a primary curing step comprising applying composition A to the skin, a second curing step comprising applying the composition B to the top surface of the composition A after the primary curing, Wherein the composition A is a polymer composite composition similar to a skin elastin structure comprising polyvinylsiloxane, hydrosiloxane, silica, additives, emulsifiers, thickeners and preservatives, wherein the composition B is an activated platinum or platinum based Wherein the composition is a composition comprising a metal and a catalyst selected from the group consisting of a catalyst, a palladium-based catalyst and a rhodium-based catalyst, an organic solvent, a substance accompanied by double crosslinking, an additive, a preservative, an emulsifying agent and an thickening agent .

The present invention can provide an optimal biomimetic skin, restore safety and normal skin aesthetics to the skin while stressing the surface of the skin, while restricting the skin shape by penetrating a specific ingredient into the epidermis, There is an effect that can be used in medical applications.

The effects of the present invention are not limited to the effects mentioned above. It should be understood that the effects of the present invention include all reasonably possible effects in the following description.

FIG. 1 is a schematic view of a system in which a mixture of A and B is mixed and then a characteristic component is released after a primary curing and a secondary curing.
FIG. 2 is a photograph of a 50-year-old woman applying this product. a is a photograph before application of the present invention, and b is a photograph after application of the present invention. c is a photograph before application of the present invention, and shows two points of loss of elasticity under the eyes. d is a photograph in which the present invention is applied to the portion indicated by c and the two points indicated after one hour have elasticity.
FIG. 3 is a measurement data of tensile strength and permanent deformation with respect to Si-H / vinyl ratio.
FIG. 4 is a graph showing the time-dependent hardening of Si-H / vinyl ratio at 25 ° C.
FIG. 5 is a graph showing the time-dependent hardening of Si-H / vinyl ratio at 36 ° C.
Fig. 6 is data obtained by measuring the surface with an optical microscope after curing within the range of the embodiment of the present invention.
Fig. 7 is a photograph of the surface of the cured product measured by an optical microscope outside the range of the present invention.
Fig. 8 is a photograph of the surface of the cured product measured under an optical microscope within the range of the present invention. Regular observations of particles of poorly soluble and water soluble drugs are seen.
FIG. 9 is a photograph of the skin of FIG. 8 adhered to the skin and desorbed after one hour and measured with an optical microscope. It can be observed that particles of poorly soluble and water-soluble drugs partially shrink or disappear.
FIG. 10 is a graph illustrating drug release over time. FIG.
11 is a graph showing an experiment for inhibiting the growth of E. coli when using a preservative mixture. b is an experimental data on the inhibitory effect of S. aureus on preservative mixing. c is an experimental data on the inhibitory effect of P. aeruginosa on preservative mixing. d is a test for inhibiting the growth of Candida albicans (C.albicans) when mixed with preservatives.
Fig. 12 shows the tensile test data. Fig. 6 shows the average values of the tensile forces in the test examples 2 to 3, and Fig. 7 shows the average tensile strengths out of the test examples 2 to 3 . FIG. 8 is a graph showing the average tensile strength of the film prepared by increasing the drug effectiveness of the additive among the items tested in FIG.

Unless otherwise specified, all numbers, values, and / or expressions used herein that express the components, reaction conditions, content of components used herein are intended to encompass a wide variety of measurements that occur when these numbers are inherently derived from these values among others Since uncertainties are approximations that reflect this, it should be understood that in all cases it is modified by the term "about ". Also, where a numerical range is disclosed in this specification, such a range is contiguous and includes all values from the minimum value of this range to the maximum value including the maximum value, unless otherwise indicated. Further, when such a range refers to an integer, all integers including the minimum value to the maximum value including the maximum value are included unless otherwise indicated.

In the present specification, when a range is described for a variable, it will be understood that the variable includes all values within the stated range including the end points described in the range. For example, a range of "5 to 10" may include any subrange, such as 6 to 10, 7 to 10, 6 to 9, 7 to 9, etc., as well as values of 5, 6, 7, 8, 9, And will also be understood to include any value between integers that are reasonable within the scope of the stated ranges such as 5.5, 6.5, 7.5, 5.5 to 8.5 and 6.5 to 9, and so on. Also, for example, a range of "10% to 30%" may range from 10% to 15%, 12% to 12%, as well as all integers including values of 10%, 11%, 12%, 13% And any arbitrary integer within the range of ranges described, such as 10.5%, 15.5%, 25.5%, and the like, including any subranges such as 18%, 20%

Hereinafter, the present invention will be described in detail.

The present invention relates to a local skin care composition having improved aesthetics containing a skin care active agent, wherein the locally applied silicone composition is a silicone composition that enables a medically short cycle time in terms of generation of a primary silicone bond . In addition, the secondary bonding (Reaction Formula 2) is performed by the Hydrophilic Pigment Surface and the Isopropyl Titanium Triisostearate of the silicon surface of the primary curing (Reaction Formula 1) to form a lipophilic Treated Pigment Surface.

That is, the present invention relates to a system that plays a role of maintaining skin elasticity for a long time and emits a characteristic component.

<Reaction Scheme 1>

<Reaction Scheme 2>

 The design and adoption of the 'second skin' is applied locally and the material of the wearable skin has some essential conditions.

First, it must be a material safe for irritating and sensitive skin.

Second, it should be easily incorporated into topical preparations.

Third, it should not stick to the skin while providing a protective interface.

Fourth, the material must have mechanical properties close to the skin elastin.

Fifth, it should not react chemically to the external environment.

Sixth, the release of active ingredient should proceed smoothly.

The raw material meeting these conditions is a silicon-based material, and the characteristics of silicon according to the present invention are described as follows. Silicone oils generally have a chain-like molecular structure as shown in Scheme 1. The skeleton of this molecule is formed by a siloxane bond. When molecules having this structure aggregate to form a substance, since the individual molecules are independent, the molecular chains can move freely between each other, In other words, it is a property of liquid. The longer the chain length of the molecule, the more difficult it is to move, and as a result, the viscosity becomes higher. And, the silicone rubber is a molecule of the network structure as in the structural formula 2. And the number of crosslinking points is usually a loose structure including one for every several hundred R ₂ SiO. In such a structure, unlike silicone oil, the molecular chains can not move with each other, so the fluidity is lost, but the degree of freedom of the molecules is increased and the elasticity is exhibited to show the properties of the rubber. As the crosslinking of the rubber progresses, the degree of freedom of the molecule decreases and the elasticity is decreased, so that the hardened polymer becomes hard. Use silicone resin to increase this density to the extreme. Unlike rubber, resin does not cure the straight-chain molecule later, but uses a structural unit that is easy to crosslink at the beginning. Such a resin is composed of a network structure as in Structural Formula 3.

<Structure 1>

&Lt; Formula 2 >

<Formula 3>

Therefore, characteristics of silicon include low surface tension, nonionic and nonpolar, hydrophobic and water repellent, heat resistance and oxidation stability, low temperature stability, gas permeability, chemical inertness, flame retardancy, environmental friendliness, and non-toxicity.

Silicon has a unique duality that has both inorganic and organic properties in the molecular structure. Therefore, each feature has a very high utilization rate and is currently used in most industrial fields.

The chemical properties of silicon are divided into two intrinsic properties: heat and oxidation, and hydrolysis. Silicon (Si) and oxygen (O) are close to ionic bonds because of the great difference in electronegativity, and therefore they are stable in energy and strong against heat and oxidation. Therefore, they are stable when used at high temperature. When a substance acting in the hydrolysis reaction is present, the silicon molecule is changed into a low molecular weight substance when it comes into contact with high temperature steam. For example, if the silicone rubber is heated in a sealed state or placed in water vapor, it may be softened.

The physical properties of silicon oils are lower than those of other liquids because of the small intermolecular attractive force of silicon oil, and silicon tends to be thinner and wider on the surface of the object. Silicone oil and rubber are also excellent in cold resistance due to low solidification point. This property is much more effective in practical use in industry than other materials. Since the internal molecules of silicon have a large distance between molecules, they are less influenced by temperature and have low temperature dependency and high gas permeability. In addition, silicon has low surface tension, so that the water repellency of the surface is high, so that if water is adhered to the surface of the silicon, water is converted into spherical water droplets.

Silicone is colorless. Odorless, most physiologically inert, water repellent, dysplastic, and inactive to other substances, and so on. It is used as protective cream in medical relationship, and silicon has most effect on the skin layer, giving protective action and good water repellency.

Silicon is also used for anti-rusting of medical instruments, improvement of lubrication of the needle, oiling of glass containers, and water repellency.

As the cosmetic, 5 to 1,000 cSt is used as the dimethyl silicone oil and 10 to 50 cSt of the alcohol-soluble methylphenyl silicone is used.

Further, in recent years, polyoxyalkyl-modified silicone oil has also been used in hair relation such as shampoo and rinse.

Among them, the preceramic polymer (Polysiloxane) is a polymer that can be ceramicized by pyrolysis, including an organic group, a metal atom, or atoms capable of being ceramized in a main chain of a polymer. Among them, And oxygen atoms (O) and organic groups, and the number of silicon atoms has a great influence on physical properties.

In the form of a polyfunctional monomer (R3Si-), a bifunctional monomer (R2Si =), a trifunctional monomer (R2Si≡), and a quadrupole monomer (= Si =), Si atoms and Si atoms are separated by oxygen atoms, Is referred to as siloxane. When two Si atoms are separated by one oxygen atom, the compound is called a disiloxane. If three Si atoms are separated by the same method, they are called trisiloxane, and many Si atoms are separated by this method The separated compounds are collectively referred to as polysiloxane.

Polysiloxanes are mostly composed of linear molecules. The arrangement of these atoms makes it possible to use at a wide range of temperatures by imparting a low glass transition temperature (Tg), and has excellent thermal stability, oxidation resistance and chemical stability. In order to utilize this amorphous polymer effectively, cross-linking between molecules is required. This is because the basic shape and characteristics of a silicon compound depend on whether a network is connected between a silicon atom or an oxygen atom. In order to form a three-dimensional network through a crosslinking reaction, at least one of the molecules used must be trifunctional, and most organic chemistry principles are used here.

The free radical reaction using peroxide can be cured with a small amount of aryloxy peroxide by replacing some of the methyl groups of dimethylsiloxane with vinyl groups, as shown in the following reaction formula 3. Despite the many studies and developments of peroxide, there is no peroxide commonly used in all applications. Silicone rubber technologists have found that a range of siloxane polymers and a limited range of peroxides, 2,4-dichlorovenzoylperoxide, dicumylperoxide, di-t-butylperoxide in air, and dicumly or di-t-butylperoxide are mainly used for the production of rubber containing thick or carbon black. Curing of vinyl containing vinyl groups eliminates secondary curing and provides better compression set characteristics.

<Reaction Scheme 3>

In the crosslinking reaction using the condensation reaction, the condensation reaction of the silanol group occupies an important position in the silicon chemistry, as shown in the following reaction formula (4). If one or more silanol groups are present in the molecule, three-dimensional crosslinking is possible, and hardness and physical properties can be changed depending on the degree of crosslinking.

If hydrolyzable groups such as alkoxy, acyloxy, and oxime are bonded to the atoms, crosslinking is possible at room temperature with moisture.

-silanol기를 갖는 polydimethylsiloxane이 tetra, 또는 trifunctional silane과 같이 존재할 경우, 3차원적으로 가교된 구조를 얻게 된다. 따라서 이러한 반응형식은 1액형, 2액형 제품을 가능케 한다. 이 가교를 위해서 사용되는 촉매는 tin, tianate계 화합물들이다.a,

When a polydimethylsiloxane having a silanol group is present as tetra or a trifunctional silane, a three-dimensionally crosslinked structure is obtained. Therefore, this reaction type enables one-component and two-component products. The catalysts used for this crosslinking are tin and tianate compounds.

<Reaction Scheme 4>

Crosslinking using a hydrosilylation reaction is an addition reaction of a siloxane having Si-H bond with a siloxane having an unsaturated hydrocarbon bond as shown in the following reaction formula (5).

<Reaction Scheme 5>

The crosslinking using the hydrosilane / silanol reaction can be regarded as a combination of condensation or hydrosilylation reaction as shown in the following reaction scheme 6, and can be expressed as a one-step reaction or a two-step reaction.

This reaction can occur simultaneously depending on the conditions and can produce silicon foam.

<Reaction Scheme 6>

Crosslinking using Radiation has been of great interest and research on the effect of ionizing radiation on polymethylsiloxane as well as on most polymers and has enabled crosslinking using radiation. There are generally two types of crosslinking.

First, there is crosslinking through irradiation of polymethylsiloxane by generating high radiation energy, crosslinking by reaction of organic radicals formed by decomposition of radicals, and second, initiation of photocatalysis which is dependent on activation of mixed initiator.

In order to obtain the photoinitiation reaction of siloxane, photoinitiation reaction of well-known organic materials is applied as it is, and therefore, the organoleptic groups in the polymethylsiloxane polymer must exist in the form of pendant.

These photoinitiated reactions are thiol-end reactions using well-known aromatic ketones as photoinitiators and hydridsilane-ene reactions in the presence of photoinitiators.

Among the above-mentioned silicones, polyvinylsiloxane applicable to biotechnology is a polydimethylsiloxane liquid silicone polymer having a vinyl group, which is reacted with a double bond of a hydrogen vinyl group of a silyl hydride (Si-H) group under a room temperature condition in the presence of active platinum It turns into a solid elastomer. In addition, due to its excellent tear strength, fine detail reproducibility and elastic recovery rate, it is suitable for use in bioengineering, and its application range is greatly increased. The reactivity of the raw material, polydimethylsiloxane liquid silicone polymer, has various ranges, and it has an advantage that the working time and the curing rate can be easily controlled by varying the content of the crosslinking agent and the amount of the inhibitor or activator. However, there are not many products and research literature that appropriately control the change of the physical properties of the polyvinylsiloxane composition.

The polymer connecting the linear polyvinylsiloxane is a short chain length liquid silicone polymer having a hydrogen functional group at the chain side. The vinyl functional group of the linear prepolymer is reacted with the vinyl functional group to form a three-dimensional network structure. The vinyl content of the prepolymer and the hydrogen group content and position of the polymer vary in the crosslinking density, thereby changing the mechanical properties.

To apply silicone polymers to biotechnology, proper density must be involved. When the degree of cross-linking is low, tearing and tensile strength are weak. When the crosslinking density is increased, the mechanical properties are improved. When the crosslinking density is too high, the physical properties are poor.

Therefore, in order to have proper elasticity and strength, which is a property required for a silicone polymer used in biotechnology, it is necessary to select a silicone prepolymer having an appropriate vinyl content and then use a polymer having a proper content.

In order to avoid reaction by-products, an accurate ratio between the vinyl group content of the silicone prepolymer and the silyl hydride (Si-H) group content of the crosslinking agent should be maintained. Otherwise, secondary reaction between water and residual hydrogen functionality or reaction between hydrogen functional groups under the influence of active platinum can produce hydrogen gas and become an inaccurate model containing bubbles.

Therefore, in recent commercial products of polyvinylsiloxane commercial products, platinum or palladium may be added at the time of production to minimize the adverse effect thereof, and thus, the product may act as a collector for hydrogen gas.

According to the curing reaction formula of the polyvinylsiloxane, the ratio of the vinyl group of the silicone prepolymer and the crosslinking agent Si-H group should be adjusted to 1: 1, but the prepolymer sol component that can be eluted is not present and the unreacted Si-H group is not left The ratio of Si-H / Vinyl for proper physical properties ranges from about 1.5 to about 2.8, and is slightly different depending on the raw material used.

Secondary curing should be done sequentially to form elastin similar to skin tissue after primary curing.

Also, during the secondary curing process, release of the characteristic drug and component should proceed simultaneously.

Accordingly, there is a need in the art to prepare a polyvinylsiloxane complex having satisfactory physical properties for use as a material applicable to the skin.

As used herein, "hardening" does not necessarily mean completely achieving the ultimate mechanical properties. Rather, the term is used to describe a state in which cohesion has been achieved that at least prevents the material from being destroyed when exposed to mechanical pressure.

"Room temperature" means an indoor and outdoor temperature in the range of 22 to 35 ° C.

It is an object pursued by the present invention to form a binding network using a siloxane polymer and a related polymer based on the above-mentioned material characteristics, and at the same time to realize a skin memory as close as possible to a skin using a biocompatible material.

The inventors of the present invention have conducted intensive studies in order to achieve the above object. As a result, the present inventors have found out that a chemical mechanism is added to meet the object of the present invention with a curable silicone bond formed by mixing (A) By using the composition of the present invention, skin application is excellent, the cured product of the composition has surface stickiness, and has appropriate hardness and strength, so that it is not affected by repeated skin contraction and relaxation, And the present invention has been accomplished.

Therefore, the present invention can be divided into (A) type and (B) type.

Finally, the above (A) type and (B) type are mixed and used.

(A) type,

In the vinyl silicone composition of the present invention,

The polyvinylsiloxane of the present invention is a copolymer of polydimethylsiloxane (vinyl terminated) having a vinyl group (-CH = CH ₂ ) at the terminal and a copolymer or a cyclic copolymer thereof, a polydimethylsiloxane diphenylsiloxane copolymer Poly (dimethylsiloxane- co -diphenylsiloxane), divinyl terminated) and his ring copolymer thread guard ^{184 (SYLGARD ® 184), 2,4,6,8} , - tetramethyl-2,4,6,8-tetrahydro-vinyl (2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane) and copolymers thereof, which are used singly or in combination of two or more, and the vinyl group Is in the range of 0.015 to 3.00 mmoles / gm. If it is 0.015 mmoles / gm or less, an excess amount of polyvinylsiloxane is injected to cause sticking on the surface after curing, or curing time is increased. If it is more than 3.00 mmoles / gm, the content of the cross-linking agent is relatively increased, and unreacted materials are present or a rapid curing reaction occurs. And the elastin of the final film decreases. That is, it is possible to form a film having a hard shape rather than a soft property, or a large amount of water and a secondary reaction with a residual hydrogen action period may occur during curing.

The blending amount of these polyvinylsiloxanes is 20 to 50 parts by mass, preferably 30 to 40 parts by mass based on 100 parts by mass of the total of the components (A).

If the amount is less than 20 parts by weight, the elasticity after curing is deteriorated. If the amount is more than 50 parts by weight, excess water may be generated during curing, or the film may partially break. Further, uniform application is not performed when applying the skin.

The hydrogen silicone composition of the present invention,

The present invention relates to polydimethylsiloxane-methylhydrosiloxane copolymers (poly (dimethylsiloxane-co-methylhydrosiloxane), trimethylsilyl terminated), polydimethylsiloxane having a hydroxyl group at the terminal, (Poly (dimethylsiloxane), chlorine terminated) having a chloride group and a copolymer thereof, poly (methylhydrosiloxane) and a copolymer thereof, hexamethyldisiloxane and a copolymer thereof, bis Poly (dimethylsiloxane), bis (hydroxyalkyl) terminated having a hydroxyalkyl group and a copolymer thereof, polydimethylsiloxane having a bis-3-aminopropyl group at the terminal, bis (3-aminopropyl) terminated ) And a copolymer thereof, polydimethylsiloxane having a monohydroxyl group at the terminal (poly (dimethylsiloxane), monohy (poly (dimethylsiloxane), diglycidyl ether terminated) having a diglycidyl ether group at the terminal and a copolymer thereof, or a copolymer thereof, or a combination of two or more thereof And a molar concentration of Si-H of 0.10 to 9.00 mmoles / gm is used, and when it is less than 0.10 mmoles / gm, excess polyvinylsiloxane is injected to cause sticking on the surface after curing, In addition, when it is more than 9.00 mmoles / gm, the content of the crosslinking agent is relatively increased to cause an unreacted substance or a fast curing reaction, and the elastin of the final film is decreased, that is, Or a large amount of water and a secondary reaction of the residual hydrogen action period may occur during curing.

The blending amount of these polyvinylsiloxanes is 5 to 20 parts by mass, preferably 5 to 10 parts by mass based on 100 parts by mass of the total of the component (A).

The fine powdered silica of the present invention is added to improve the strength and tackiness of silicon, and may be any of those mainly composed of SiO ₂ , but is preferably selected from fumed silica, precipitated silica, diatomaceous earth, ground quartz and fused quartz Or a combination of two or more thereof.

The average particle diameter of the fine powder silica is preferably 5 탆 or less. If it is 5 m or more, it may cause fine scratches on the surface of the skin during application and lower the strength of silicon.

These fine powdered silicas may be used as they are, or they may be pretreated with a surface hydrophobicizing agent, or may be prepared by adding a surface treating agent to one or more kinds of silicone oils. The surface treatment agent may be any one of alkylalkoxysilane, alkylchlorosilane, alkylsilazane, silane coupling agent, titanate-based treatment agent, fatty acid ester and the like, either alone or in combination of two or more.

The blending amount of these fine powder silica is 0.01 to 8 parts by mass, preferably 1 to 6 parts by mass based on 100 parts by mass of the total of the component (A). If it exceeds 8 parts by mass, the strength of the film may be deteriorated or fine cracks may occur on the surface of the film after curing. In addition, uniform mixing is not achieved properly in the production process.

In the present invention, additives such as a moisturizing wetting agent, an antioxidant, a whitening agent, a lifting agent and the like may be used.

The additives are exemplified as follows. Examples of natural animal and vegetable oils and semi-synthetic oils are avocado oil, amanic oil, almond oil, pewter, perilla oil, olive oil, cacao oil, carnauba wax, kaya oil, calnova wax, liver oil, canary lacquer wax, Safflower oil, Safflower oil, Safflower oil, Safflower oil, Safflower oil, Safflower oil, Chrysanthemum oil, Safflower oil, Safflower oil, , Soybean oil, tea oil, camellia oil, colostrum, corn oil, lard, rape oil, Japanese pung oil, rice bran wax, embryo oil, marge oil, palm oil, palm oil, castor oil, hardened castor oil, castor oil fatty acid methyl Bees wax, milk oil, cottonseed oil, cotton wax, Japanese wax, aerosol seed oil, montan wax, coconut oil, hardened coconut oil, tree coconut oil Dissolve glyceride, sunflower, peanut Lanolin, Lanolin, Lanolin, Lanolin, Lanolin, Lanolin, Lanolin Acetate, Lanolin Isopropyl, Lanolin Hexyl, POE Lanolin Alcohol Ether, POE Lanolin Alcohol Acetate, Lanolin Propylene Polyethylene Glycol, POE Hydrogenated Lanolin Alcohol Ether, egg yolk;

Examples of the hydrocarbon oil include zeolite, squalane, squalane, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, vaseline and the like;

Examples of the higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linolic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) Isostearic acid, 12-hydroxystearic acid and the like;

Examples of the higher alcohol include lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldodecanol, octyldodecanol, Alcohol, 2-decyltetradecinol, cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerin ether (butyl alcohol), monooleyl glyceryl ether (cerakyl alcohol) and the like;

Examples of ester esters include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptyl undecyl adipate, N-alkyl mono isostearate, isosyl isostearate, trimethylolpropane triisostearate, di Ethylhexanoic acid ethylene glycol, 2-ethylhexanoate, tri-2-ethylhexanoate trimethylolpropane, tetra-2-ethylhexanoic acid pentaerythritol, octanoic acid ethyl ester, octyldodecylsulfame ester, , Octyldodecyl oleate, dicapric acid neopentyl glycol, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyl acetate, isosertyl stearate, butyl stearate, diisopropyl sebacate, Hexyldecyl palmitate, 2-heptylundecyl palmitate, 2-heptylundecyl palmitate, 12-hydroxystearyl cholestearyl, 2-ethylhexyl palmitate, Dipentaerythritol fatty acid esters, isopropyl myristate, 2-octyldodecyl myristate, 2-hexyldistyl myristate, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate , N-lauroyl-L-glutamic acid 2-octyldodecyl ester, diisostearyl malate, dextrin palmitate, dextrin stearate, dextrin 2-ethylhexanoate palmitate, sucrose palmitate, sucrose stearate , Monobenzylidene sorbitol, dibenzylidene sorbitol and the like;

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The glyceride oil may be selected from the group consisting of acetoglyceryl, triisooctanoic acid glyceryl, triisostearic acid glyceryl, triisopalmitic acid glyceryl, tri-2-ethylhexanoic acid glyceryl, monostearic acid glyceryl, Trimethylsilyl glyceryl, etc .;

Examples of the silicone oil include organopolysiloxane having a low viscosity to high viscosity such as dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane and dimethylsiloxane / methylphenylsiloxane copolymer, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexane Cyclic siloxane such as siloxane, tetramethyltetrahydrocyclotetrasiloxane and tetramethyltetraphenylcyclotetrasiloxane, gum-like dimethylpolysiloxane with high polymerization degree, silicone rubber such as gum-shaped dimethylsiloxane-methylphenylsiloxane copolymer, Siloxane solution, trimethylsiloxy silicate, cyclic siloxane solution of trimethylsiloxysilicate, higher alkoxy-modified silicone such as stearoxysilicon, higher fatty acid-modified silicone, alkyl-modified silicone, amino-modified silicone, fluorine-modified silicone, silicone resin, silicone resin ;

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Examples of the fluorine-based emulsions include perfluoropolyether, perfluorodecarnine, perfluorooctane, fluorinated pitch, fluoroalcohol and the like;

Examples of alcohols include lower alcohols such as ethanol, propanol and isopropanol; Polyhydric alcohols such as ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin and diglycerin; Alcohols such as ethylene glycol monoalkyl ether and diethylene glycol monoethyl ether; Sugar alcohols such as sorbitol and mannitol; Cholesterol, sitosterol, phytosterol, lanosterol, and the like.

Examples of the water-soluble polymer include water-soluble polymers such as gum arabic, tragacanth gum, arabinogalactan, rocarutobin gum, guar gum, karaya gum, carrageenan, pectin, agar, queen seed, Microbial polymers such as xanthan gum, dextran, succinoglucan and furan, animal polymers such as collagen, casein, albumin and gelatin, carboxymethylcellulose such as carboxymethylcellulose, Starch and starch polymers such as methylhydroxypropyl starch, cellulose derivatives such as methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nitrocellulose, sodium cellulose sulfate, carboxymethylcellulose sodium, Cellulose-based polymers such as crystalline cellulose and cellulose, sodium alginate, and propylene glycol alginate Stearic acid and the like, vinyl-based polymers such as polyvinyl methyl ether and carboxyvinyl polymer, polyoxyethylene-based polymers, polyoxyethylene-polyoxypropylene copolymerization system polymers, sodium acrylate, polyethyl acrylate, polyacrylic acid Amide and the like, polyethyleneimine, cationic polymer, bentonite, aluminum magnesium silicate, laponite, hectorite and silicic anhydride.

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Among these, a film forming system such as polyvinyl alcohol or polyvinyl pyrrolidone is included.

Among these, Maltodextrin and Acerola Fruit Extract, Pyrus Malus (Apple) Fruit Extract, Butylene Glycol, and Water (Glycol) And Arctium Majus Root Extract Zinc Sulfate Biotin Propanediol Water Alcohol and Oris Root Extract. (Iris Florentina Root Extract) and (and) Retinyl Palmitate, Butylen Glycol, Water, and Niacinamide (and) Fraxinus Excelsior Bark Extract and Silanetriol Potassium Citrate Propanediol Water Kigelia Africana Fruit Extract and / Quillaja Saponaria Bark Extract, Hydrolyzed El Hydrolyzed Elastin, Butylene Glycol and Coconut Nucifera (Coconut) water and Withania Somnifera Root Extract, Water and Carrot Extract Actinidia chinensis (Kiwi) Fruit Extract, Water (and) Mangifera Indica (Mango) Fruit Extract, Water (and) Pumpkin Extract (Cucurbita) Pepo (Pumpkin) Fruit Extract, Fragaria Vesca (Strawberry) Fruit Extract, Ranunculus Ficaria Extract, Water and Juglans Regia (walnut) Seed Extract, Octyldodecyl Myristate and Capparis Spinosa Fruit Extract, Alcohol and Water, Acmella Oleracea Extract, Caprylic / Capric, Triglyceride (and) Gold sputum extract (Spilanthes Acmella Flower E Propanediol and Evodia Rutaecarpa Fruit Extract, Water and Fagus Sylvatica Bud Extract, Water and Beech Extract, Butylene Glycol, and Water Cryptomeria Japonica Bud Extract, Water (and) Beech Extract, Alcohol (and) Water (and) Onopordum Acanthium Flower / Leaf / Stem Extract, Butylene Glycol and Kiwi (Actinidia Chinensis (kiwi) Fruit water, and Alcohol and Sophora Flavescens Root Extract, Hematite Extract, Lactose Nonfat Dry Milk, and Whey, Whey Protein, Lactose and Whey Protein, Citrus Limon (Lemon) Fruit Extract, Prunus Armeniaca (Apricot) Kernel Oil, and Tomato Extract (Solanum Lycopersicum (Tomato) Fruit / Leaf / Stem Extract), Apricot Oil (Prunus Armeniaca (Apricot) Kernel Oil), and Tomato Extract (Hordeum Vulgare Seed Extract), Hydrated Elastin (and) Mimosa Tenuiflora Bark Extract, Water (and / or Water Extract), Solanum Lycopersicum (Tomato) Fruit / Leaf / Stem Extract, And Olivine Extract, Propylene Glycol, and Water (and) Barkberry Extract (Arctostaphylos uva ursi leaf extract), Propylene Glycol (and) Water (and) Cinnamomum Zeylanicum Bark Extract, Propylene Glycol (And) green tea extract (Camellia sinensis leaf extract), propylene glycol (and) water (and) Paullinia Cupana Seed Extract, wine extract, Citrus Aurantium Dulcis (Orange ) Fruit water, Prunus Cerasus (cherry) Fruit water, Vaccinium Macrocarpon (Cranberry) Fruit water, Zingiber Officinale (Ginger) Water, Vitis Vinifera (Grape) Fruit Water ), Grapefruit (Citrus Grandis (Grapefruit) Fruit Water, fruit juice (Actinidia chinensis (Kiwi) Fruit Water), trus Limon (Lemon) Fruit Water, Nelumbo Nucifera Root Water, Citrus Aurantium Dulcis (Orange) , Oryza Sativa (Rice) Bran Water, Pyrus Malus (Apple) Fruit Water, Phyllostachys Edulis Shoot Water, Soluble Collagen, Maltodextrin (and) Papaya Extract (Carica Papaya (Papaya) Fruit Extract, Hydrolyzed Soy Protein, Sesamum Indicum (Sesame) Seed Oil, and Melia Azadirachta Seed Oil (and) Boswellia Serrata Oil, Mineral Oil and Vegetable Oil (And) aloe extract, water (and) propylene glycol (and) aloe extract, mineral oil and (and) apricot oil, and (b) Arnica montana flower extract, water and propylene glycol and , Propylene glycol (and) water (and) Betula alba bark extract, (And) Water (and) Calendula officinalis flower extract, Mineral oil (and) Prunus armeniaca (Apricot) kernel oil Calendula officinalis flower extract, Glycine soja (soybean) oil Daucus carota sativa (carrot) root extract (and) beta-carotene, propylene glycol (and) Urtica dioica (nettle) extract, propylene glycol and water, and Centaurea cyanus flower extract, propylene glycol and water and ginkgo leaf extract , Propylene glycol (and) water and (ginseng root extract), propylene glycol (and) water and (grapefruit extract), propylene glycol (and) water and (chestnut) seed extract (Aesculus hippocastanum ) seed extract, propylene glycol (and) water and (and) equisetum arvense extract, propylene glycol and water, and Centella asiatica extract, propylene glycol and water and (Hedera helix (ivy) leaf / stem extr Lavandula angustifolia (lavender flower / leaf / stem extract), propylene glycol and water (and) lemon extract (citrus limon (lemon) fruit extract), propylene glycol Glycol (and) water (and) Nelumbo nucifera flower extract, propylene glycol (water) and water (and) Malva sylvestris (mallow flower / leaf / stem extract), propylene glycol ) Althaea officinalis root extract, mineral oil and prunus armeniaca (Apricot kernel oil), and chamomilla recutita (matricaria flower extract), butylene glycol (and) Water (and) matricaria flower extract, chamomilla recutita (matricaria flower extract), propylene glycol (and) water (and) chamorilla recutita (matricaria flower extract), propylene glycol (and) Marticaria extract (chamomilla recutita (matricari a) flower extract, water and glycerin (oven) kernel extract, water (and) propylene glycol (and) Quillaja saponaria bark extract, propylene glycol (and) Water extracts such as Vitis Vinifera (Grape Leaf Extract), propylene glycol (and) water (and) Rosa centifolia flower extract, propylene glycol (and) water (and) sage leaf extract Salvia officinalis (sage) leaf extract, Propylene glycol (and) Water (and) Fucus vesiculosus extract, Propylene glycol (and) Water and Viola tricolor extract, Propylene glycol (and) Water Mentha Arvensis Leaf Oil (and Citrus Medica Limonum (Lemon) Peel Oil), and Cypress Oil (Cupressus Sempervirens (Lemon Peel Oil) Oil (and) Lavandula Hybrida Oil (and) City Cistus Ladaniferus Oil, Water and Smithsonite Extract, Coenzyme Q10 and its derivatives, Peptides and derivatives thereof, PDRN and its derivatives, Zinco and its derivatives, ascorbic acid and its derivatives , Ginseng and its extracts, fibroin and its derivatives, drug components include dichlorophenoxamine sodium and its derivatives, capsaicin and its derivatives, lidocaine and its salts, insulin and its derivatives, botulinum and its synthetic derivatives, docetaxel And derivatives thereof, paclitaxel and derivatives thereof, capecitabine and derivatives thereof.

Examples of the amino acids include deoxyribonucleic acids such as glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine and tryptophan; Tennyl estradiol and the like.

Among the amino acids, aspartic acid (Asp), threonine (Thr), serine (Ser), glutamic acid (Glu), glycine (Gly), alpha linolenic acid (Ala), cysteine (Cys), valine A peptide consisting of one or more amino acids of leucine (Ile), leucine (Leu), tyrosine (Tyr), phenylalanine (Phe), lysine (Lys), histidine (His), arginine A peptide to which a salt, ethyl, cation, amino group, or the like is attached at both ends;

Salicylic acid, erythromycin, clindamycin, retinoids and derivatives thereof, tretinoin, adapalene, azelaic acid, benzoyl peroxide, benzoyl peroxide, tea tree, bach, aha, niacinamide;

Examples of skin cosmetic ingredients include a cellulase activator such as a placenta extract, arbutin, glutathione and Yukinoshita extract, royal jelly, a photosensitizer, a cholesterol derivative, a juvenile blood extract, a skin trouble improver, a nonic acid valinylamide, Ester, niacin beta-butoxyethyl ester, capsaicin, gingerone, kantarystine, icatamol, caffeine, tannic acid, alpha -bornone, nicotinic acid tocopherol, inositol hexanicotinate, cyclandelate, cinanidine, , Blood circulation accelerators such as acetylcholine, verapamil, cephalatine and? -Orizanol, skin astringents such as zinc oxide and tannic acid, and antirheumatics such as sulfur and tianthrol. Examples of the vitamins include vitamin A oil, retinol , Vitamin A such as retinol acetate and retinol palmitate, vitamin B2 such as riboflavin, riboflavin butyrate, nucleotides such as pravaine adenine, pyridoxine hydrochloride ,

Vitamin B 6 and its derivatives such as pyridoxine dioctanoate and pyridoxine tripalmitate, vitamin B 12 and its derivatives, vitamin B such as vitamin B 15 and its derivatives, L-ascorbic acid, L-ascorbic acid,

Esters, vitamin C such as L-ascorbic acid-2-sulphate and di-ester dicarboxylic acid L-ascorbic acid, vitamin D such as el ganciciferol and cholecalciferol,? -Tocopherol,? -Tocopherol , vitamin E such as? -tocopherol, d1-α-tocopherol acetate, d1-α-tocopherol nicotinate and d1-α-tocopherol succinate, nicotinic acid such as vitamin H, vitamin P, nicotinic acid, benzyl nicotinate, nicotinic acid amide, Calcium, D-pantothenyl alcohol, pantothenyl ethyl ether, and acetyl pantothenyl ethyl ether; and biotin.

Any one of them may be used, or one type may be used alone or two or more types may be used at the same time.

The blending amount of the additive is 20 to 40 parts by mass, preferably 20 to 30 parts by mass based on 100 parts by mass of the total of the component (A). If the amount is less than 20 parts by mass, breakage may occur during the manufacturing process or curing may not be performed properly. If the amount is more than 40 parts by mass, physical properties of the film after curing may be significantly decreased.

In the present invention, it is possible to take the form of O / W / O type and W / O / W type emulsions in addition to water-soluble, water type emulsion (O / W type) and water in water type emulsion (W / O type).

The emulsifier in the present invention may be used alone or in combination of two or more.

The content of the emulsifier in the present invention is 1 to 10% by weight based on the total weight.

The emulsifier used in the present invention includes anionic, cationic, nonionic and amphoteric active agents, but is not particularly limited and any emulsifier can be used as long as it is a commonly used emulsifier.

Specific examples of the anionic surfactant include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylic acids and salts thereof, carbonates such as condensation of amino acids with fatty acids, alkylsulfonic acids, alkenesulfonates, fatty acid esters A sulfonate of a fatty acid amide, a sulfonate of an alkylsulfonate and a formalin condensate thereof, an alkylsulfate ester salt, a second-class higher alcohol sulfate ester salt, an alkyl and aryl ether sulfate ester salt, a sulfuric acid ester salt of a fatty acid ester, Sulfuric acid ester salts of fatty acid alkylolamide, sulfuric acid ester salts such as lot oil, alkyl phosphates, ether phosphates, alkylaryl ether phosphates, amide phosphates and N-acyl amino acid type activators;

Examples of the cationic surfactant include alkylamine salts, amine salts such as polyamine and aminoalcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridinium salts, imidazolium salts and the like; Examples of the nonionic surfactant include sorbitan fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, propylene glycol fatty acid esters, polyethylene glycol fatty acid esters, sucrose fatty acid esters, polyoxyethylene alkyl ethers, polyoxypropylene alkyl ethers, Ethers, polyoxyethylene fatty acid esters, polyoxyethylene sorbitan fatty acid esters,

Polyoxyethylene sorbitol fatty acid esters, polyoxyethylene glycerin fatty acid esters, polyoxyethylene propylene glycol fatty acid esters, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene phytosterol ether, polyoxyethylene phytosterol ether, poly Oxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxane, polyoxyalkylene-alkyl-co-modified organopolysiloxane, alkanolamide, sugar ether, and sugar amide .

Among the nonionic surfactants, fluorine-substituted alkyl groups such as polyether-modified silicones containing fluorine alkyl groups, trifluoropropyl groups, nonafluorohexyl groups, and heptadecylfluorodecyl groups are exemplified, and a trifluoropropyl group is particularly preferable .

When the content is less than 0.1 part by mass, the hydrophilicity becomes too low, so that sufficient emulsifying power can not be obtained. If it is larger than 10 parts by mass, the production of the present component becomes difficult or the alkyl group content becomes too low, so that sufficient emulsification power can not be obtained.

Examples of the amphoteric surfactant include betaine, aminocarbonate, and imidazoline derivatives. When the surfactant is used, the blending amount is preferably 0.1 to 20% by weight, more preferably 0.5 to 10% by weight based on the total amount of the additives.

The thickening agent is a silicone resin such as acrylic / silicone grit or a block copolymer or a silicone network compound, but is preferably an acrylic silicone resin. Particularly, the silicone resin is preferably an acrylic silicone resin containing at least one member selected from the group consisting of a pyrrolidone moiety, a long-chain alkyl moiety, a polyoxyalkylene moiety and a fluoroalkyl moiety in the molecule. Further, the silicone resin is preferably a silicone network compound. When a silicone resin such as acrylic / silicone grit or block copolymer or silicone network compound is used, the blending amount is preferably 0.1 to 20.0% by weight, more preferably 1.0 to 10.0% by weight based on the total amount of the additives.

In the present invention, parabens, phenoxyethanol, chlorophenazine and the like are used as most of the chemical preservatives used as a preservative in the present invention. However, these chemical preservatives inhibit the growth of microorganisms, It can also cause skin allergies, environmental hormones and irritants such as dermatitis. In recent years, 1,2-octanediol and 1,2-hexanediol have been used as raw materials for antimicrobial action, among 1,2-alkanediol compounds having self-antibacterial activity. Accordingly, in the present invention, existing parabens, phenoxyethanol, chlorophenesine, and 1,2-alkanediol compounds are used singly or in combination of two or more to maximize the preservation effect.

The blending amount of the preservative is 0.1 to 2.0 parts by mass, preferably 0.4 to 1.0 parts by mass based on 100 parts by mass of the total of the component (A). If the amount is less than 0.1 part by mass, a problem arises in preserving ability, and if it is more than 2.0 parts by mass, skin irritation may be caused, resulting in problems in use.

(B) type,

In the present invention, platinum, platinum chloride, chloroplatinic acid, a reaction product of chloroplatinic acid and a monohydric alcohol, a complex of chloroplatinic acid and olefins, platinum tetramethyl divinyl disiloxane, platinum bisacetoacetate and a platinum catalyst, palladium Based catalyst, a rhodium-based catalyst, and the like.

This compounding amount can be an input amount of platinum, and a compound having a concentration of 500 to 2500 ppm is used. The blending amount of active platinum having a concentration of 500 to 2500 ppm is 0.5 to 2.0 parts by mass, preferably 0.9 to 1.5 parts by mass based on 100 parts by mass of the total of the components (B). If the amount is less than 0.5 part by mass, the curing time between the vinyl polymer-containing silicone polymer and the hydroxy polymer-containing silicone polymer is delayed, and the above-mentioned object can not be achieved. On the other hand, when the amount is 2.0 parts by mass or more, water and hydrogen gas bubbles are generated in a large amount during the addition reaction due to the rapid curing reaction, which can not achieve the object of the present invention.

The silicone polymer of the present invention may be obtained without using a solvent, and if necessary, an organic solvent may be used. Examples of the organic solvent include aliphatic alcohols such as methanol, ethanol, 2-propanol and butanol; Aromatic hydrocarbons such as benzene, toluene and xylene; aliphatic or substituted hydrocarbons such as n-pentane, n-hexane, and cyclohexane; Halogenated hydrocarbons such as dichloromethane, chloroform and carbon tetrachloride; Ketones such as acetone and methyl ethyl ketone; Decamethylcyclopentasiloxane solvent, and the like. However, non-solvent, or ethanol or 2-propanol and butanol, or decamethylcyclopentasiloxane is preferable as it is used for cosmetic applications and quasi-drug applications which can achieve the object of the present invention. Any one of them may be used, or one type may be used alone or two or more types may be used at the same time.

The blending amount of the solvent is 30 to 50 parts by mass, preferably 30 to 40 parts by mass based on 100 parts by mass of the total amount of the component (B). When the amount is 30 parts by mass or less or 50 parts by mass or more, the curing action is delayed or water and air bubbles are generated on the surface of the film during curing, so that a uniform curing action is not achieved.

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In the present invention, the material with dual curing is a mixture of iron oxides and isopropyl titanyl triisostearate; A mixture of Chromium Oxide Greens and Isopropyl Titanium Triisostearate; A mixture of Chromium Hydroxide Greens and Isopropyl Titanium Triisostearate; A mixture of Ferric Ammonium Ferrocyanide and Isopropyl Titanium Triisostearate; A mixture of iron oxides, talc and isopropyl titanyl triisostearate; A mixture of manganese violet and isopropyl titanyl triisostearate; A mixture of titanium dioxide (Titanium Dioxide) and isopropyl titanium triisostearate; A mixture of titanium dioxide, aluminum hydroxide, isopropyl titanium triisostearate, and iron oxides; A mixture of Titanium Dioxide, Aluminum Hydroxide and Isopropyl Titanium Triisostearate; A mixture of zinc oxide (Zinc Oxide) and isopropyl titanium triisostearate; A mixture of polymethylmethacrylate and isopropyl titanyl triisostearate; A mixture of nylon 12 and isopropyl titanyl triisostearate; A mixture of Mica and isopropyl titanyl triisostearate; A mixture of talc and isopropyl titanyl triisostearate; And a mixture of aluminum starch octenyl succinate and isopropyl titanyl triisostearate; and mixtures of one or more of these.

Further, the ratio of Isopropyl Titanium Triisostearate in the mixture is 0.1 to 10.0 parts by weight.

If the ratio of Isopropyl Titanium Triisostearate in the mixture is less than 0.1 part by weight, the O-Ti bond does not act on the polymer having a hydroxyl group and can not carry out the desired secondary crosslinking. When the ratio is more than 10.0 parts by weight , Uneven surface cross-linking may occur during the secondary crosslinking due to the abrupt reaction as described above.

The present invention is not limited to the additive components, emulsions, film forming agents, oil soluble gelling agents, organic modified clay minerals, resins, humectants, preservatives, antibacterial agents, fragrances, salts, An antioxidant, a pH adjuster, a chelating agent, an ultraviolet screening agent, a refreshing agent and the like may be added.

As the emulsifying agent in the additive, the following are exemplified. Examples of natural animal and vegetable oils and semi-synthetic oils are avocado oil, amanic oil, almond oil, pewter, perilla oil, olive oil, cacao oil, carnauba wax, kaya oil, calnova wax, liver oil, canary lacquer wax, Safflower oil, Safflower oil, Safflower oil, Safflower oil, Safflower oil, Safflower oil, Chrysanthemum oil, Safflower oil, Safflower oil, , Soybean oil, tea oil, camellia oil, colostrum, corn oil, lard, rape oil, Japanese pung oil, rice bran wax, embryo oil, marge oil, palm oil, palm oil, castor oil, hardened castor oil, castor oil fatty acid methyl Bees wax, milk oil, cottonseed oil, cotton wax, Japanese wax, aerosol seed oil, montan wax, coconut oil, hardened coconut oil, tree coconut oil Dissolve glyceride, sunflower, peanut Lanolin, Lanolin, Lanolin, Lanolin, Lanolin, Lanolin, Lanolin Acetate, Lanolin Isopropyl, Lanolin Hexyl, POE Lanolin Alcohol Ether, POE Lanolin Alcohol Acetate, Lanolin Propylene Polyethylene Glycol, POE Hydrogenated Lanolin Alcohol Ether, egg yolk;

Examples of the hydrocarbon oil include zeolite, squalane, squalane, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, vaseline and the like;

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Examples of the higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linolic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) Isostearic acid, 12-hydroxystearic acid and the like;

Examples of the higher alcohol include lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldodecanol, octyldodecanol, Alcohol, 2-decyltetradecinol, cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerin ether (butyl alcohol), monooleyl glyceryl ether (cerakyl alcohol) and the like;

Examples of ester esters include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptyl undecyl adipate, N-alkyl mono isostearate, isosyl isostearate, trimethylolpropane triisostearate, di Ethylhexanoic acid ethylene glycol, 2-ethylhexanoate, tri-2-ethylhexanoate trimethylolpropane, tetra-2-ethylhexanoic acid pentaerythritol, octanoic acid ethyl ester, octyldodecylsulfame ester, , Octyldodecyl oleate, dicapric acid neopentyl glycol, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyl acetate, isosertyl stearate, butyl stearate, diisopropyl sebacate, Hexyldecyl palmitate, 2-heptylundecyl palmitate, 2-heptylundecyl palmitate, 12-hydroxystearyl cholestearyl, 2-ethylhexyl palmitate, Dipentaerythritol fatty acid esters, isopropyl myristate, 2-octyldodecyl myristate, 2-hexyldistyl myristate, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate , N-lauroyl-L-glutamic acid 2-octyldodecyl ester, diisostearyl malate, dextrin palmitate, dextrin stearate, dextrin 2-ethylhexanoate palmitate, sucrose palmitate, sucrose stearate , Monobenzylidene sorbitol, dibenzylidene sorbitol and the like;

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The glyceride oil may be selected from the group consisting of acetoglyceryl, triisooctanoic acid glyceryl, triisostearic acid glyceryl, triisopalmitic acid glyceryl, tri-2-ethylhexanoic acid glyceryl, monostearic acid glyceryl, Trimethylsilyl glyceryl, etc .;

Examples of the silicone oil include organopolysiloxane having a low viscosity to high viscosity such as dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane and dimethylsiloxane / methylphenylsiloxane copolymer, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexane Cyclic siloxane such as siloxane, tetramethyltetrahydrocyclotetrasiloxane and tetramethyltetraphenylcyclotetrasiloxane, gum-like dimethylpolysiloxane with high polymerization degree, silicone rubber such as gum-shaped dimethylsiloxane-methylphenylsiloxane copolymer, Siloxane solution, trimethylsiloxy silicate, cyclic siloxane solution of trimethylsiloxysilicate, higher alkoxy-modified silicone such as stearoxysilicon, higher fatty acid-modified silicone, alkyl-modified silicone, amino-modified silicone, fluorine-modified silicone, silicone resin, silicone resin ;

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Examples of the fluorine-based emulsions include perfluoropolyether, perfluorodecarnine, perfluorooctane, fluorinated pitch, fluoroalcohol and the like;

Examples of alcohols include lower alcohols such as ethanol, propanol and isopropanol; Polyhydric alcohols such as ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin and diglycerin; Alcohols such as ethylene glycol monoalkyl ether and diethylene glycol monoethyl ether; Sugar alcohols such as sorbitol and mannitol; Cholesterol, sitosterol, phytosterol, lanosterol, and the like.

Examples of the water-soluble polymer include water-soluble polymers such as gum arabic, tragacanth gum, arabinogalactan, rocarutobin gum, guar gum, karaya gum, carrageenan, pectin, agar, queen seed, Microbial polymers such as xanthan gum, dextran, succinoglucan and furan, animal polymers such as collagen, casein, albumin and gelatin, carboxymethylcellulose such as carboxymethylcellulose, Starch and starch polymers such as methylhydroxypropyl starch, cellulose derivatives such as methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nitrocellulose, sodium cellulose sulfate, carboxymethylcellulose sodium, Cellulose-based polymers such as crystalline cellulose and cellulose, sodium alginate, and propylene glycol alginate Stearic acid and the like, vinyl-based polymers such as polyvinyl methyl ether and carboxyvinyl polymer, polyoxyethylene-based polymers, polyoxyethylene-polyoxypropylene copolymerization system polymers, sodium acrylate, polyethyl acrylate, polyacrylic acid Amide and the like, polyethyleneimine, cationic polymer, bentonite, aluminum magnesium silicate, laponite, hectorite and silicic anhydride.

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Among these, a film forming system such as polyvinyl alcohol or polyvinyl pyrrolidone is included.

Examples of the powders are those which are used in ordinary cosmetics, and their shape (spherical shape, rod shape, needle shape, plate shape, irregular shape, scale shape, Quality, etc.) can be used. Specific examples of the inorganic powder include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, and the like, and examples thereof include inorganic powders, organic powders, surfactant metal salt powders, colored pigments, pearl pigments, metal powder pigments, , Magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, potassium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, muscovite, synthetic mica, gold silver manganese, biotite, lithia mica, silicic acid, Magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, tungstic acid metal salt, hydroxyapatite, vermiculite, hydridite, bentonite, montmorillonite, hectorite, zeolite, heramix powder, Alumina, aluminum hydroxide, boron nitride, silica and the like;

Examples of the organic powder include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane powder, benzoguanamine powder, polymethylbenzoguanamine powder, polytetrafluoroethylene powder, polymethyl methacrylate powder , Nylon powder, 12 nylon, 6 nylon, silicone powder, silicone rubber powder, silicone elastomer spherical powder, styrene-acrylic acid copolymer, divinylbenzene-styrene copolymer, vinyl resin, urea resin, phenol resin, A fluororesin, a silicon resin, an acrylic resin, a melamine resin, an epoxy resin, a polycarbonate resin, a microcrystalline fiber powder, a starch powder, lauroylidine and the like;

In the present invention, ultraviolet ray absorbing agents other than ultraviolet ray scattering agents such as inorganic pigments and metal powders may be used as the ultraviolet ray shielding component. Specific examples include p-aminobenzoic acid, ethyl p-aminobenzoate, p-aminobenzoic acid glyceryl, p-dimethylaminobenzoic acid amyl, p-dimethylaminobenzoate, 4-N, N-di (2-hydroxypropyl) aminobenzoate Benzoic acid ester-based ultraviolet ray absorbers, salicylic acid-based ultraviolet absorbers such as methyl salicylate, ethylene glycol salicylate, phenyl salicylate, octyl salicylate, benzyl salicylate, p-tert-butylphenyl salicylate and homomenthyl salicylate, benzyl cinnamate, Based ultraviolet absorbers such as ethoxyethyl, ethoxyethyl, octyl methoxycinnamate, dipyrromethoxycinnamic acid mono-2-ethylhexanoate and glyceryl; ultraviolet absorbents such as europaquinic acid and ethyl urocannate; ultraviolet absorbers such as hydroxymethoxy Benzophenone, hydroxymethoxybenzophenesulfonic acid, sodium hydroxymethoxybenzophenonesulfonate, dihydroxymethoxybenzophenone, dihydroxydicarboxylic acid Benzophenone-based ultraviolet absorbers such as sodium benzylphenone disulfonate, 2,4-dihydroxybenzophenone and tetrahydroxybenzophenone, dibenzoylmethane such as 4-tert-butyl-4'-methoxy-dibenzoylmethane Anthranilic acid-based ultraviolet absorber such as methyl anthranilate, benzotriazole derivatives such as 2- (2-hydroxy-5-methylphenyl) benzotriazole, etc., and polymer derivatives thereof, silane or siloxane Derivatives thereof.

Of the organic ultraviolet absorbers, 2-ethylhexyl paramethoxy cinnamate and 4-t-butyl-4'-methoxy-dibenzoylmethane are particularly preferably used.

It is also possible to use an organic ultraviolet absorber encapsulated in a polymer powder, and the polymer powder may be hollow. The average primary particle diameter of the polymer powder is preferably in the range of 0.1 to 50 mu m, and the particle size distribution may be wide or narrow. Examples of the polymer include an acrylic resin, a methacrylic resin, a styrene resin, a urethane resin, a polyethylene resin, a polypropylene resin, a polyethylene terephthalate resin, a silicone resin, a nylon resin and an acrylamide resin.

4-t-butyl-4'-methoxy-dibenzoylmethane, which is a UVA absorbent, is preferably blended.

Examples of the oil-soluble gelling agent include metallic soaps such as aluminum stearate, magnesium stearate and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid and?,? - di- Dextrin fatty acid esters such as dextrin stearic acid ester and dextrin 2-ethylhexanoic acid palmitic acid ester, sucrose fatty acid esters such as sucrose palmitic acid ester and sucrose stearic acid ester, benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol, Organic modified clay minerals such as dodecylammonium montmorillonite clay and dimethyldioctadecylammonium montmorillonite clay, and the like, and if necessary, one kind or two or more kinds of gelling agents may be used.

Examples of the moisturizer include glycerin, sorbitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, glucose, xylitol, maltitol, polyethylene glycol, hyaluronic acid, chondroitin sulfate, pyrrolidone carbonates, polyoxyethylene methyl glucoside , Polyoxypropylene methyl glucoside, and the like.

Examples of the pH adjusting agent include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium hydrogencarbonate, ammonium hydrogencarbonate , Chelating agents include alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid and the like,

Examples of the refreshing agent include L-menthol and campo. Examples of anti-inflammatory agents include allantoin, glycyrrhetinic acid, glycyrrhizic acid, tranexamic acid, and azulene acid.

Any one of them may be used, or one type may be used alone or two or more types may be used at the same time.

The blending amount of the additive is 20 to 40 parts by mass, preferably 20 to 30 parts by mass based on 100 parts by mass of the total of the components (B). If the amount is less than 20 parts by mass, breakage may occur during the manufacturing process or curing may not be performed properly. If the amount is more than 40 parts by mass, physical properties of the film after curing may be significantly decreased.

In the present invention, parabens, phenoxyethanol, chlorophenazine and the like are used as most of the chemical preservatives used as a preservative in the present invention. However, these chemical preservatives inhibit the growth of microorganisms, It can also cause skin allergies, environmental hormones and irritants such as dermatitis. In recent years, 1,2-octanediol and 1,2-hexanediol have been used as raw materials for antimicrobial action, among 1,2-alkanediol compounds having self-antibacterial activity. Accordingly, in the present invention, existing parabens, phenoxyethanol, chlorophenesine, and 1,2-alkanediol compounds are used singly or in combination of two or more to maximize the preservation effect.

The blending amount of the preservative is 0.1 to 2.0 parts by mass, preferably 0.4 to 1.0 parts by mass based on 100 parts by mass of the total amount of the component (B). If the amount is less than 0.1 part by mass, a problem arises in preserving ability, and if it is more than 2.0 parts by mass, skin irritation may be caused, resulting in problems in use.

Water can also be added to the constituent components of the present invention, if necessary. The water content in the present invention is 10 to 50% by weight based on the total weight.

In the present invention, it is possible to take the form of O / W / O type and W / O / W type emulsions in addition to water-soluble, water type emulsion (O / W type) and water in water type emulsion (W / O type).

The emulsifier in the present invention may be used alone or in combination of two or more.

The content of the emulsifier in the present invention is 1 to 10% by weight based on the total weight.

The emulsifier used in the present invention includes anionic, cationic, nonionic and amphoteric active agents, but is not particularly limited and any emulsifier can be used as long as it is a commonly used emulsifier.

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Specific examples of the anionic surfactant include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylic acids and salts thereof, carbonates such as condensation of amino acids with fatty acids, alkylsulfonic acids, alkenesulfonates, fatty acid esters A sulfonate of a fatty acid amide, a sulfonate of an alkylsulfonate and a formalin condensate thereof, an alkylsulfate ester salt, a second-class higher alcohol sulfate ester salt, an alkyl and aryl ether sulfate ester salt, a sulfuric acid ester salt of a fatty acid ester, Sulfuric acid ester salts of fatty acid alkylolamide, sulfuric acid ester salts such as lot oil, alkyl phosphates, ether phosphates, alkylaryl ether phosphates, amide phosphates and N-acyl amino acid type activators;

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Examples of the cationic surfactant include alkylamine salts, amine salts such as polyamine and aminoalcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridinium salts, imidazolium salts and the like; Examples of the nonionic surfactant include sorbitan fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, propylene glycol fatty acid esters, polyethylene glycol fatty acid esters, sucrose fatty acid esters, polyoxyethylene alkyl ethers, polyoxypropylene alkyl ethers, Ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hardened castor oil , Polyoxyethylene phytosterol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxane, polyoxyethylene And the like can be mentioned alkylene and alkyl comodified organopolysiloxane, alkanolamide, an ether, an amide, per each.

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Among the nonionic surfactants, fluorine-substituted alkyl groups such as polyether-modified silicones containing fluorine alkyl groups, trifluoropropyl groups, nonafluorohexyl groups, and heptadecylfluorodecyl groups are exemplified, and a trifluoropropyl group is particularly preferable .

When the content is less than 0.1 part by mass, the hydrophilicity becomes too low, so that sufficient emulsifying power can not be obtained. If it is larger than 10 parts by mass, the production of the present component becomes difficult or the alkyl group content becomes too low, so that sufficient emulsification power can not be obtained.

Examples of the amphoteric surfactant include betaine, aminocarbonate, and imidazoline derivatives. When the surfactant is used, the blending amount is preferably 0.1 to 20% by weight, more preferably 0.5 to 10% by weight based on the total amount of the additives.

The thickening agent is a silicone resin such as acrylic / silicone grit or a block copolymer or a silicone network compound, but is preferably an acrylic silicone resin. Particularly, the silicone resin is preferably an acrylic silicone resin containing at least one member selected from the group consisting of a pyrrolidone moiety, a long-chain alkyl moiety, a polyoxyalkylene moiety and a fluoroalkyl moiety in the molecule. Further, the silicone resin is preferably a silicone network compound. When a silicone resin such as acrylic / silicone grit or block copolymer or silicone network compound is used, the blending amount is preferably 0.1 to 20.0% by weight, more preferably 1.0 to 10.0% by weight based on the total amount of the additives.

Hereinafter, the present invention will be described more specifically by way of specific examples. The following examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited thereto.

Example 1

20 parts by mass based on 100 parts by mass of the total amount of the A component, the hydrogen silicone composition is 5 parts by mass based on 100 parts by mass of the total of the A component, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 2

The ratio of Si-H / Vinyl is 0.1, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 3

The ratio of Si-H / Vinyl is 0.1, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 4

The ratio of Si-H / Vinyl is 0.1, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 5

20 parts by mass based on 100 parts by mass of the total amount of the A component, the hydrogen silicone composition is 5 parts by mass based on 100 parts by mass of the total of the A component, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 6

The ratio of Si-H / Vinyl is 0.1, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 7

The ratio of Si-H / Vinyl is 0.1, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 8

The ratio of Si-H / Vinyl is 0.1, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 9

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 10

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the hydrogen silicone composition is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 11

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 12

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 13

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 14

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the hydrogen silicone composition is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 15

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 16

The ratio of Si-H / Vinyl is 0.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 17

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 18

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 19

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 20

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 21

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 22

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 23

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 24

The ratio of Si-H / Vinyl is 1.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 25

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of the component A, the hydrogen silicone composition is 5 parts by mass with respect to 100 parts by mass of the total of the component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 26

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 27

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 28

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 29

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of the component A, the hydrogen silicone composition is 5 parts by mass with respect to 100 parts by mass of the total of the component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 30

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 31

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 32

The ratio of Si-H / Vinyl is 1.5, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 33

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 34

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 35

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 36

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 37

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 38

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 39

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 40

The ratio of Si-H / Vinyl is 2.0, the amount of polyvinylsiloxane is 50 parts by mass with respect to 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 41

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 42

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 43

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 44

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 45

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 46

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 47

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 48

The ratio of Si-H / Vinyl is 2.5, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 49

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 50

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 51

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 52

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 0.01 to 100 parts by mass based on 100 parts by mass of the total amount of the additive is 20 to 40 parts by mass with respect to 100 parts by mass of the total of the A component and the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the A component, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 53

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 54

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 5 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 55

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 20 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 56

The ratio of Si-H / Vinyl is 3.0, the amount of polyvinylsiloxane is 50 parts by mass based on 100 parts by mass of the total amount of component A, the amount of silica is 20 parts by mass with respect to 100 parts by mass of the total amount of component A, 5.0 parts by mass based on 100 parts by mass of the total amount, the additive is 20 to 40 parts by mass based on 100 parts by mass of the total amount of the component A, the emulsifier is 1 to 10 parts by mass with respect to 100 parts by mass of the total of the component A, 0.1 to 20 parts by mass with respect to 100 parts by mass in total, and the preservative is prepared by using 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the total of the component (A). Other than that, water was used in a total amount of 100 parts by mass of the A component.

Example 57

0.5 parts by mass based on 100 parts by mass of the total amount of the components B, using a mixture having an active platinum content of 500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass per 100 parts by mass of the total amount of the components B, The isopropyl titanyl triisostearate mixture is 0.1 part by mass based on 100 parts by mass of the total amount of the component B, the additive is 20 to 40 parts by mass with respect to the total 100 parts by mass of the component B, and the preservative is 0.1 to 2.0 parts by mass with respect to the total 100 parts by mass of the component B. 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 58

0.5 parts by mass based on 100 parts by mass of the total amount of the components B, using a mixture having an active platinum content of 2500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass per 100 parts by mass of the total amount of the components B, The isopropyl titanyl triisostearate mixture is 0.1 part by mass based on 100 parts by mass of the total amount of the component B, the additive is 20 to 40 parts by mass with respect to the total 100 parts by mass of the component B, and the preservative is 0.1 to 2.0 parts by mass with respect to the total 100 parts by mass of the component B. 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 59

2.0 parts by mass based on 100 parts by mass of the total of the components B using a mixture having an active platinum content of 500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass based on 100 parts by mass of the total of the components B, The isopropyl titanyl triisostearate mixture is 0.1 part by mass based on 100 parts by mass of the total amount of the component B, the additive is 20 to 40 parts by mass with respect to the total 100 parts by mass of the component B, and the preservative is 0.1 to 2.0 parts by mass with respect to the total 100 parts by mass of the component B. 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 60

2.0 parts by mass based on 100 parts by mass of the total of the components B using a mixture having an active platinum content of 2500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass based on 100 parts by mass of the total amount of the components B, The isopropyl titanyl triisostearate mixture is 0.1 part by mass based on 100 parts by mass of the total amount of the component B, the additive is 20 to 40 parts by mass with respect to the total 100 parts by mass of the component B, and the preservative is 0.1 to 2.0 parts by mass with respect to the total 100 parts by mass of the component B. 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 61

0.5 parts by mass based on 100 parts by mass of the total amount of the components B, using a mixture having an active platinum content of 500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass per 100 parts by mass of the total amount of the components B, The isopropyl titanyl triisostearate mixture is added in an amount of 10 parts by mass based on 100 parts by mass of the total amount of the component B, the additive is added in an amount of 20 to 40 parts by mass with respect to 100 parts by mass of the total amount of the component B, 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 62

0.5 parts by mass based on 100 parts by mass of the total amount of the components B, using a mixture having an active platinum content of 2500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass per 100 parts by mass of the total amount of the components B, The isopropyl titanyl triisostearate mixture is added in an amount of 10 parts by mass based on 100 parts by mass of the total amount of the component B, the additive is added in an amount of 20 to 40 parts by mass with respect to 100 parts by mass of the total amount of the component B, 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 63

2.0 parts by mass based on 100 parts by mass of the total of the components B using a mixture having an active platinum content of 500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass based on 100 parts by mass of the total of the components B, The isopropyl titanyl triisostearate mixture is added in an amount of 10 parts by mass based on 100 parts by mass of the total amount of the component B, the additive is added in an amount of 20 to 40 parts by mass with respect to 100 parts by mass of the total amount of the component B, 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 64

2.0 parts by mass based on 100 parts by mass of the total amount of the components B using a mixture having a platinum catalyst content of 2500 ppm, and the solvent is used in an amount of 30 to 50 parts by mass per 100 parts by mass of the total amount of the components B, The isopropyl titanyl triisostearate mixture is added in an amount of 10 parts by mass based on 100 parts by mass of the total amount of the component B, the additive is added in an amount of 20 to 40 parts by mass with respect to 100 parts by mass of the total amount of the component B, 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the total amount of the component B, and 0.1 to 20 parts by mass with respect to the total amount of the additive. Other than that, water was used in a ratio of 100 parts by mass in total of the components B. [

Example 65

A mixture prepared in each of Examples 17 to 24 was used, and a B mixture was prepared in Examples 60 and 64, respectively. 0.01 part by weight of the fine powder silica is used as the A mixture.

Example 66

A mixture prepared in each of Examples 17 to 24 was used, and a B mixture was prepared in Examples 60 and 64, respectively. 0.5 part by weight of the fine powdery silica is added to the prepared mixture A, respectively.

Example 67

A mixture prepared in each of Examples 17 to 24 was used, and a B mixture was prepared in Examples 60 and 64, respectively. 1.0 part by weight of the fine powdery silica is used as the A mixture.

Example 68

A mixture prepared in each of Examples 17 to 24 was used, and a B mixture was prepared in Examples 60 and 64, respectively. And 2.0 parts by weight, based on the total weight of the A mixture, of the fine powder silica is used for the A mixture.

Example 69

A mixture prepared in each of Examples 17 to 24 was used, and a B mixture was prepared in Examples 60 and 64, respectively. To each of the prepared mixture A, 3.0 parts by weight of fine powder silica was used based on the total weight of the mixture A.

Example 70

A mixture prepared in each of Examples 17 to 24 was used, and a B mixture was prepared in Examples 60 and 64, respectively. 4.0 parts by weight of the fine powder silica is used as the A mixture.

Example 71

A mixture prepared in each of Examples 17 to 24 was used, and a B mixture was prepared in Examples 60 and 64, respectively. 5.0 parts by weight of fine powder silica is used as the A mixture.

Test Example 1: Measurement of tensile strength and permanent strain according to Si-H / Vinyl ratio

Si-H / Vinyl ratio Tensile strength
(MPa) Permanent deformation
(%) Dimensional change
(%) 0.1 2.48 ± 0.12 0.41 + 0.08 0.09 0.02 0.5 2.92 ± 0.28 0.37 + - 0.12 0.10 0.03 1.0 2.60 0.30 0.36 ± 0.09 0.13 + 0.04 1.5 2.47 ± 0.23 0.41 + 0.15 0.12 + - 0.01 2.0 2.60 ± 0.27 0.27 + 0.04 0.09 0.02 2.5 2.35 ± 0.13 0.25 + 0.07 0.09 ± 0.01 3.0 2.16 ± 0.17 0.34 + 0.07 0.09 ± 0.05

In this experiment, the Si-H / Vinyl ratio of the composition of 0.04mmol of vinyl and 0.07mmol of Si-H content showed a significant increase of tensile strength compared to the case of low polymer content, , And lower values were obtained when the polymer content was increased more than that. This phenomenon should include a certain amount of polymer in order to have a proper tensile strength. However, if it is added more than the above, it is considered that the toughness is lowered because the hardness is increased more than necessary and the brittleness is increased.

H / Vinyl ratio of 0.1 was used in Examples 1 to 8, Si-H / Vinyl ratio was 0.5 in Examples 9 to 16, Si-H / Vinyl ratio was 1.0 in Examples 17 to 24, Si-H / Vinyl The Si-H / Vinyl ratio is 2.5 is Examples 25 to 32, the Si-H / Vinyl ratio is 2.0 is Examples 33 to 40, the Si-H / Examples 49-56. In addition, examples of the same Si-H / Vinyl ratio are shown by calculating an average value.

The permanent strain was not significantly different at the Si-H / Vinyl ratio of 0.1 to 1.5, but the Si-H / Vinyl ratio of 2.0 and 2.5 showed an increase in the permanent strain at an insignificant level compared to 1.5. This result shows that when the Si-H / Vinyl ratio is increased from 2.0 to 2.5, as the Si-H ratio increases, the elastic recovery of the material becomes better, and when the Si-H / Vinyl ratio increases to more than 3.0, It appears that the component acts as a plasticizer to lower the resilience of elasticity.

Test Example 2: Measurement of change in viscosity (curing time) according to the content of active platinum and the material with double crosslinking

Si-H / Vinyl ratio A type Type B Viscosity (30 sec, cps) Viscosity (180 sec, cps) 0.1 Examples 1 to 8 Example 57 5200 ± 300 23000 ± 600 Example 58 6800 ± 350 24000 ± 750 0.5 Examples 9 to 16 Example 57 5600 ± 310 23600 ± 650 Example 58 6900 ± 340 24500 ± 730 1.0 Examples 17 to 24 Example 57 5800 ± 320 23900 ± 640 Example 58 7200 ± 310 25000 ± 740 1.5 Examples 25 to 32 Example 57 6200 ± 320 24200 ± 650 Example 58 7600 ± 310 25400 ± 750 2.0 Examples 33 to 40 Example 57 4300 ± 330 15000 ± 620 Example 58 5100 ± 320 17000 + 710 2.5 Examples 41 to 48 Example 57 4100 ± 310 14900 ± 660 Example 58 4900 ± 300 16500 ± 720 3.0 Examples 49 to 56 Example 57 3600 ± 310 14900 ± 640 Example 58 4100 ± 300 16000 + - 720

Test Example 3: Measurement of Tensile Strength Change (Curing Time) According to the Content of Substances Containing Dual Curing

Si-H / Vinyl ratio A type Type B After 3min
(MPa) After 60min
(MPa) After 180min
(MPa) 0.1 Examples 1 to 8 Example 60 2.5 3.7 3.8 Example 64 2.7 3.8 3.8 0.5 Examples 9 to 16 Example 60 3.0 3.9 4.0 Example 64 3.2 3.5 3.7 1.0 Examples 17 to 24 Example 60 2.7 3.2 3.4 Example 64 2.8 3.4 3.5 1.5 Examples 25 to 32 Example 60 2.4 3.0 3.1 Example 64 2.6 2.9 3.0 2.0 Examples 33 to 40 Example 60 2.6 3.2 3.3 Example 64 2.9 3.4 3.5 2.5 Examples 41 to 48 Example 60 2.5 3.1 3.2 Example 64 2.7 3.2 3.4 3.0 Examples 49 to 56 Example 60 2.3 2.9 3.2 Example 64 2.5 2.9 2.9

In the present experiment (Table 2), B compounds having different catalyst concentrations were mixed in a uniform amount in an A compound having a Si-H / Vinyl ratio of 0.1 to 3.0 with a composition of 0.04 mmol of a vinyl content and 0.07 mmol of an Si-H content It measures the viscosity at 30 seconds and 180 seconds.

In this experiment, it was measured by ISO 2884 method.

Tables 2 and 3 showed significant tensile strength increase compared to the low polymer examples and showed the highest tensile strength values in the experimental group and lower values when the cross-linking agent was more than that. This phenomenon should include a certain amount of polymer in order to have a proper tensile strength. However, if it is added more than this, it is considered that toughness is lowered because crosslinking occurs more than necessary and brittleness is increased.

H / Vinyl ratio of 0.1 was used in Examples 1 to 8, Si-H / Vinyl ratio was 0.5 in Examples 9 to 16, Si-H / Vinyl ratio was 1.0 in Examples 17 to 24, Si-H / Vinyl The Si-H / Vinyl ratio is 2.5 is Examples 25 to 32, the Si-H / Vinyl ratio is 2.0 is Examples 33 to 40, the Si-H / Examples 49-56. In addition, examples of the same Si-H / Vinyl ratio are shown by calculating an average value.

The permanent strain was not significantly different at the Si-H / Vinyl ratio of 0.1 to 1.5, but the Si-H / Vinyl ratio of 2.0 and 2.5 showed an increase in the permanent strain at an insignificant level compared to 1.5. These results show that when the ratio of Si-H / Vinyl is increased from 2.0 to 2.5, the elastic recovery of the material becomes better and the Si-H / Vinyl ratio is increased to 3.0 or more, It appears that the component acts as a plasticizer to lower the resilience of elasticity.

Also, as shown in the above table, the content of the active platinum and the double curing agent also influences the increase of physical properties when used.

Test Example 4: Measurement of torque value (curing rate) according to the content of the active platinum and the substance accompanied by double curing

Si-H / Vinyl ratio A type Type B Torque (g.cm) Torque (g.cm) Elapsed time
60 sec Elapsed time
180 sec 0.1 Examples 1 to 8 Example 57 3.0 5.2 Example 58 4.2 6.1 0.5 Examples 9 to 16 Example 57 3.2 10.0 Example 58 4.9 11.3 1.0 Examples 17 to 24 Example 57 5.0 15.2 Example 58 5.6 16.9 1.5 Examples 25 to 32 Example 57 5.2 16.4 Example 58 6.0 17.8 2.0 Examples 33 to 40 Example 57 5.9 17.1 Example 58 6.5 18.9 2.5 Examples 41 to 48 Example 57 6.3 17.5 Example 58 7.0 19.2 3.0 Examples 49 to 56 Example 57 6.7 17.9 Example 58 7.7 19.8

Si-H / Vinyl ratio A type Type B Torque (g.cm) Torque (g.cm) Elapsed time
60 sec Elapsed time
180 sec 0.1 Examples 1 to 8 Example 60 3.4 5.8 Example 64 4.5 6.6 0.5 Examples 9 to 16 Example 60 3.9 11.3 Example 64 4.8 12.1 1.0 Examples 17 to 24 Example 60 5.7 15.8 Example 64 6.2 16.5 1.5 Examples 25 to 32 Example 60 6.2 16.9 Example 64 7.1 17.9 2.0 Examples 33 to 40 Example 60 6.4 17.2 Example 64 7.5 18.2 2.5 Examples 41 to 48 Example 60 6.9 17.5 Example 64 7.7 18.6 3.0 Examples 49 to 56 Example 60 7.0 17.8 Example 64 7.9 18.8

Test Example 5: Change of physical properties according to changes of additive contents

20, 30, 40 parts by mass based on 100 parts by mass of the total of the mixture components of A and B according to the examples of Table 4 and Table 5, the emulsifier is added in an amount of 1 to 10 Mass part and thickening agent are used in an amount of 0.1 to 20 parts by mass based on 100 parts by mass of the total amount of the component A and 0.1 to 2.0 parts by mass based on 100 parts by mass of the total of the component A, respectively.

The tensile and curing rate, and the viscosity change with time were examined, and it was found that there was no significant difference from the values in Tables 4 and 5 above.

Test Example 6: Property change according to the content of fine powder silica

Si-H / Vinyl ratio A type Type B Fine powder silica
content (%) Torque (g.cm) Elapsed time
180 sec 1.0 Examples 17 to 24 Example 57 0.01 14.6 Example 58 0.01 15.4 Example 57 0.5 15.2 Example 58 0.5 16.9 Example 57 1.0 17.9 Example 58 1.0 18.7 Example 57 2.0 21.1 Example 58 2.0 23.2 Example 57 3.0 24.5 Example 58 3.0 25.4 Example 57 4.0 24.7 Example 58 4.0 26.3 Example 57 5.0 24.5 Example 58 5.0 25.9

Si-H / Vinyl ratio A type Type B Fine powder silica
content (%) Torque (g.cm) Elapsed time
180 sec 1.0 Examples 17 to 24 Example 60 0.01 12.4 Example 64 0.01 13.2 Example 60 0.5 15.8 Example 64 0.5 16.5 Example 60 1.0 17.6 Example 64 1.0 18.5 Example 60 2.0 19.2 Example 64 2.0 20.2 Example 60 3.0 21.3 Example 64 3.0 23.1 Example 60 4.0 23.5 Example 64 4.0 25.3 Example 60 5.0 23.3 Example 64 5.0 25.1

Si-H / Vinyl ratio A type Type B Fine powder silica content
(%) After 3min
(MPa) After 60min
(MPa) 1.0 Examples 17 to 24 Example 60 0.01 2.7 3.2 Example 64 0.01 2.9 2.9 Example 60 0.5 3.2 3.4 Example 64 0.5 3.4 3.5 Example 60 1.0 4.1 4.3 Example 64 1.0 4.3 4.5 Example 60 2.0 4.6 4.8 Example 64 2.0 5.1 5.3 Example 60 3.0 4.8 5.1 Example 64 3.0 5.3 5.3 Example 60 4.0 5.2 5.7 Example 64 4.0 5.5 5.6 Example 60 5.0 5.1 5.4 Example 64 5.0 5.4 5.3

Test Example 7: Transdermal permeation drug release test

The skin permeability of the preparations prepared in the examples was evaluated using human cadaver skin (3 x 3 cm &lt; 2 &gt;). The skin permeability test was carried out using a Franz type diffusion cell having a diffusion area of 1.77 cm &lt; 2 &gt;. The volume of the storage chamber solution was 12.5 ml. Each formulation was applied to the skin and cured. The skin / preparation laminate was clamped between the feeding chamber and the receiving chamber of the Franz cell against the skin surface of the chamber solution. The temperature of the diffusion apparatus was maintained at 32.0 ° C by adding phosphate buffer solution (pH 7.4) to the storage chamber of Franzcell. The buffer solution in the storage chamber was stirred at a constant rate of 600 rpm. At each time point, 0.2 ml of the sample was taken from the storage chamber and the same volume of fresh phosphate buffer solution was filled in to maintain the sink condition. The accumulated amount of active ingredient permeated through the skin was analyzed by high performance liquid chromatography.

Si-H / Vinyl ratio A type Type B Drug release
(ug / 1hr.cm2) Drug release
(ug / 2hr.cm2) 0.1 Examples 1 to 8 Example 57 200 250 Example 58 230 280 0.5 Examples 9 to 16 Example 57 210 250 Example 58 220 270 1.0 Examples 17 to 24 Example 57 210 260 Example 58 230 260 1.5 Examples 25 to 32 Example 57 250 280 Example 58 250 290 2.0 Examples 33 to 40 Example 57 230 270 Example 58 240 280 2.5 Examples 41 to 48 Example 57 220 270 Example 58 230 270 3.0 Examples 49 to 56 Example 57 220 240 Example 58 230 250

Si-H / Vinyl ratio A type Type B Drug release
(ug / 1hr.cm2) Drug release
(ug / 2hr.cm2) 0.1 Examples 1 to 8 Example 60 200 230 Example 64 220 250 0.5 Examples 9 to 16 Example 60 200 240 Example 64 220 270 1.0 Examples 17 to 24 Example 60 210 260 Example 64 220 250 1.5 Examples 25 to 32 Example 60 250 280 Example 64 240 270 2.0 Examples 33 to 40 Example 60 230 270 Example 64 250 280 2.5 Examples 41 to 48 Example 60 210 260 Example 64 230 270 3.0 Examples 49 to 56 Example 60 210 230 Example 64 230 250

In this test example, as shown in Tables 9 to 10, there was no difference in the release of the active ingredient after one hour, but in Table 10, after 12 hours, the release of the active ingredient decreased by about 60% of the release amount after the initial one hour. However, in Table 9, release of active ingredient after 12 hours showed a tendency to decrease by about 90% or more of the release amount after the initial one hour.

In the range other than the present invention, almost no release of the active ingredient occurred.

Test Example 8: Contact angle measurement according to si-H content

Si-H / Vinyl ratio A type Type B Contact angle (°) 0.1 Examples 1 to 8 Example 57 60 Example 58 62 0.5 Examples 9 to 16 Example 57 61 Example 58 60 1.0 Examples 17 to 24 Example 57 59 Example 58 61 1.5 Examples 25 to 32 Example 57 58 Example 58 61 2.0 Examples 33 to 40 Example 57 60 Example 58 61 2.5 Examples 41 to 48 Example 57 60 Example 58 59 3.0 Examples 49 to 56 Example 57 59 Example 58 60

Si-H / Vinyl ratio A type Type B Contact angle (°) 0.1 Examples 1 to 8 Example 60 51 Example 64 50 0.5 Examples 9 to 16 Example 60 53 Example 64 52 1.0 Examples 17 to 24 Example 60 50 Example 64 49 1.5 Examples 25 to 32 Example 60 51 Example 64 50 2.0 Examples 33 to 40 Example 60 48 Example 64 51 2.5 Examples 41 to 48 Example 60 50 Example 64 51 3.0 Examples 49 to 56 Example 60 49 Example 64 49

Test Example 9: Contact angle measurement according to silica content

Si-H / Vinyl ratio A type Type B Fine powder silica
content (%) Contact angle (°) 1.0 Examples 17 to 24 Example 57 0.01 49 Example 58 0.01 47 Example 57 0.5 38 Example 58 0.5 32 Example 57 1.0 36 Example 58 1.0 34 Example 57 2.0 35 Example 58 2.0 34 Example 57 3.0 32 Example 58 3.0 34 Example 57 4.0 31 Example 58 4.0 31 Example 57 5.0 32 Example 58 5.0 31

Si-H / Vinyl ratio A type Type B Fine powder silica
content (%) Contact angle (°) 1.0 Examples 17 to 24 Example 60 0.01 50 Example 64 0.01 46 Example 60 0.5 38 Example 64 0.5 32 Example 60 1.0 35 Example 64 1.0 33 Example 60 2.0 33 Example 64 2.0 34 Example 60 3.0 33 Example 64 3.0 32 Example 60 4.0 31 Example 64 4.0 31 Example 60 5.0 32 Example 64 5.0 31

Si-H / Vinyl ratio A type Type B Fine powder silica content
(%) After 3min
(°) After 60min
(°) 1.0 Examples 17 to 24 Example 60 0.01 50 51 Example 64 0.01 49 49 Example 60 0.5 38 39 Example 64 0.5 35 36 Example 60 1.0 34 33 Example 64 1.0 33 32 Example 60 2.0 33 32 Example 64 2.0 32 31 Example 60 3.0 30 31 Example 64 3.0 31 32 Example 60 4.0 30 31 Example 64 4.0 31 32 Example 60 5.0 32 32 Example 64 5.0 34 33

Tests 8 and 9 are experiments for measuring surface hydrophobicity after film curing.

Test Example 8 shows weak hydrophobicity regardless of Si-H / Vinyl ratio, catalyst, and secondary curing agent, but Test Example 9 in which silica is contained shows partial hydrophilicity after film curing. As shown in FIGS. 6 to 9, the contact angle of the water is reduced due to the fine pores on the surface of the film. Therefore, the film of the present invention is an elastin compound finely imparted with air permeability.

Test Example 10: Morphology examination

Ⅹ100 Measured with LV100NPOL. After curing, the surface was cut with a length of 1 cm.

As shown in FIGS. 6 to 9, it is shown that the air gap after the curing is formed is finely formed. It can also be seen that the effective component is uniformly distributed in the surface.

Test Example 11: Validation Test

This test was a visual test in which the mixtures A and B described in the present invention were tested in women in their late 50s who had a lot of eyebrows and then applied to the eyes after confirming the skin allergic reaction. As shown in Fig. 2, there was a clear difference between before and after use (1 hr).

While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, It will be understood. It is therefore to be understood that the above-described embodiments are illustrative and non-restrictive in every respect.

Claims (8)

A skin-care kit, comprising: a kit comprising:
(a) a polymer composite composition comprising polyvinylsiloxane, hydrosiloxane, silica, additives, emulsifiers, thickeners and preservatives as Composition A;
(b) an active platinum or platinum catalyst as composition B; Organic solvent; Substances with dual curing; additive; Preservatives; Emulsifiers; And a thickening agent; And
(c) instructions for applying the composition A to the skin and applying the composition B to the layer A coated with the composition,
The polyvinylsiloxane of the composition A has a molar concentration of the vinyl group of 0.015 to 3.00 mmoles / gm,
The hydrosiloxane of the composition A has a molar concentration of Si-H of 0.10 to 9.00 mmoles / gm,
The Si-H / Vinyl ratio of the composition A is 0.3 to 0.8,
The material with the double cure of the composition B is a mixture of iron oxides and isopropyl titanyl triisostearate; A mixture of Chromium Oxide Greens and Isopropyl Titanium Triisostearate; A mixture of Chromium Hydroxide Greens and Isopropyl Titanium Triisostearate; A mixture of Ferric Ammonium Ferrocyanide and Isopropyl Titanium Triisostearate; A mixture of iron oxides, talc and isopropyl titanyl triisostearate; A mixture of manganese violet and isopropyl titanyl triisostearate; A mixture of titanium dioxide (Titanium Dioxide) and isopropyl titanium triisostearate; A mixture of titanium dioxide, aluminum hydroxide, isopropyl titanium triisostearate, and iron oxides; A mixture of Titanium Dioxide, Aluminum Hydroxide and Isopropyl Titanium Triisostearate; A mixture of zinc oxide (Zinc Oxide) and isopropyl titanium triisostearate; A mixture of polymethylmethacrylate and isopropyl titanyl triisostearate; A mixture of nylon 12 and isopropyl titanyl triisostearate; A mixture of Mica and isopropyl titanyl triisostearate; A mixture of talc and isopropyl titanyl triisostearate; And a mixture of Aluminum Starch Octenylsuccinate and Isopropyl Titanium Triisostearate, and a mixture of Aluminum Starch Octenylsuccinate and Isopropyl Titanium Triisostearate.
Skin skin care kit.
The method according to claim 1,
The polyvinylsiloxane of the composition A is a polydimethylsiloxane having a vinyl group molar concentration of 0.015 to 3.00 mmoles / gm, and a copolymer or a cyclic copolymer thereof, a polydimethylsiloxane diphenylsiloxane copolymer and a cyclic copolymer thereof, 2 , 4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane, and copolymers thereof,
Wherein the polyvinylsiloxane is contained in an amount of 20 to 50 parts by weight based on 100 parts by weight of the composition A.
The method according to claim 1,
Wherein the hydrosiloxane of the composition A is at least one of a polydimethylsiloxane methylhydrosiloxane copolymer, a polydimethylsiloxane and a copolymer thereof,
The molar concentration of Si-H is 0.10 to 9.00 mmoles / gm,
And 5 to 20 parts by weight based on 100 parts by weight of the composition A.
The method according to claim 1,
The silica of the composition A is at least one of fumed silica, precipitated silica, diatomaceous earth, ground quartz, and fused quartz,
And 0.01 to 8.0 parts by weight based on 100 parts by weight of Composition A.
The method according to claim 1,
The platinum catalyst of the composition B includes at least one of chloroplatinic acid, a reaction product of chloroplatinic acid and a monohydric alcohol, a complex of chloroplatinic acid and olefins, platinum tetramethyl divinyl disiloxane and platinum bis acetoacetate,
And 0.5 to 2.0 parts by weight based on 100 parts by weight of the B composition.
The method according to claim 1,
The organic solvent of the composition B may be any one or more of an aliphatic alcohol, an aromatic hydrocarbon, an aliphatic or a substituted hydrocarbon, a halogenated hydrocarbon,
And 30 to 50 parts by weight per 100 parts by weight of the composition B.
The method according to claim 1,
Wherein the material of the composition B that accompanies the double curing is 0.1 to 10 parts by weight based on 100 parts by weight of the composition B.

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