KR101922833B1 - Organic fibers with excellent touch and antistaining, clothing manufactured using the same, and method for manufacturing the same - Google Patents

Organic fibers with excellent touch and antistaining, clothing manufactured using the same, and method for manufacturing the same Download PDF

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KR101922833B1
KR101922833B1 KR1020180014499A KR20180014499A KR101922833B1 KR 101922833 B1 KR101922833 B1 KR 101922833B1 KR 1020180014499 A KR1020180014499 A KR 1020180014499A KR 20180014499 A KR20180014499 A KR 20180014499A KR 101922833 B1 KR101922833 B1 KR 101922833B1
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fiber
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fabrics
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권숙영
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권숙영
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/61Liquid ammonia
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15Proteins or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01Stain or soil resistance
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention provides organic fibers with excellent feeling and antistaining properties woven with a fiber coated with a fiber modifying composition containing: 2 to 6 wt% of aqueous ammonia (25%); 4 to 10 wt% of urea; 2 to 5 wt% of a compound represented by chemical formula 1; 5 to 15 wt% of dopamine; and a balance of water, a clothing manufactured using the same, and a manufacturing method thereof.

Description

감촉 및 방오성이 우수한 오가닉 직물, 그를 사용하여 제조된 의류 및 그의 제조방법{Organic fibers with excellent touch and antistaining, clothing manufactured using the same, and method for manufacturing the same} TECHNICAL FIELD [0001] The present invention relates to an organic fabric excellent in texture and antifouling property, a garment manufactured using the same, and a method of manufacturing the same,

본 발명은 감촉 및 방오성이 우수한 오가닉 직물, 그를 사용하여 제조된 의류, 및 그의 제조방법에 관한 것이다. The present invention relates to an organic fabric excellent in texture and antifouling property, a garment produced using the same, and a method of producing the same.

섬유제품은 천연섬유 중 울, 실크 등 고급소재를 사용한 제품과 고급면사를 머서화 처리하여 실크와 같은 광택을 부여한 머서화 제품이 많았으나, 최근에는 리오셀에 울, 실크, 레이온이 복합된 스포츠웨어용 고급 섬유제품에 대한 수요도 증가되고 있다.Most of the textile products are made of high quality materials such as wool and silk among natural fibers, and Mercerized products that have been treated with mercerizing high quality cotton yarn to give a shine like silk. Recently, however, Demand for high-end textile products for wear is also increasing.

현재 생산되고 있는 리오셀 섬유의 최초 원료로는 목재펄프가 주로 사용되고 있으나 목재펄프의 셀룰로스 함량은 40 내지 60% 정도로 낮고 분자량이 작아 고품질의 재생섬유를 제조하는데 어려움이 있다. 또한 목재는 펄프를 얻을 수 있게 되기까지의 생육기간이 매우 길고 근본적으로 환경을 파괴하는 문제점을 가지고 있어 새로운 원료의 개발이 요구되고 있다.Although wood pulp is mainly used as the initial raw material of the currently produced lyocell fiber, the cellulose content of the wood pulp is as low as about 40 to 60% and the molecular weight is low, making it difficult to produce high quality regenerated fiber. In addition, the timber has a very long growth period until the pulp can be obtained and fundamentally destroys the environment, and development of new raw materials is required.

면은 셀룰로스 함량이 90% 이상으로 목재펄프에 비하여 순도가 높고 분자량이 크며 1년 단위의 지속생산이 가능한 천연자원이다. 그러나 면섬유는 잘 오염되고, 세탁 및 가공 중 면직물간의 색이동 문제가 빈번히 일어나는 단점이 있다. Cotton has a cellulose content of 90% or more, which is higher in purity and molecular weight than wood pulp, and is a natural resource capable of continuous production per year. However, the cotton fiber is well contaminated, and the problem of color migration between the cotton fabrics during washing and processing frequently occurs.

면직물과 같은 셀룰로오스성 직물간의 염료 이동은 동일한 조에서 직물을 세탁하거나 가공할 때 발생한다. 염료 이동은 셀룰로오스성 섬유가 음이온성 종의 염료에 약한 인력을 갖기 때문에 발생한다. Dye transfer between cellulosic fabrics such as cotton fabrics occurs when the fabrics are washed or processed in the same bath. Dye migration occurs because cellulosic fibers have weak attraction to dyes of anionic species.

그러므로 셀룰로오스성 직물에서 방오성능을 향상시킴과 동시에 피부감촉을 향상시킬 수 있는 효율적인 해결이 요구된다. Therefore, there is a need for an efficient solution to improve the antifouling performance and the skin feel of the cellulose fabric.

대한민국 공개번호 제10-2005-0072927호Korea Publication No. 10-2005-0072927

본 발명은 종래 기술의 상기와 같은 문제를 해결하기 위하여 안출된 것으로서, 섬유의 표면을 개질하여 감촉 및 방오성이 현저하게 향상된 오가닉 직물, 그를 사용하여 제조된 의류, 및 그의 제조방법을 제공하는 것을 목적으로 한다. Disclosure of the Invention The present invention has been conceived to solve the above-mentioned problems of the prior art, and it is an object of the present invention to provide an organic fabric in which the surface of a fiber is modified to significantly improve touch and antifouling property, a garment manufactured using the same, .

본 발명은, 상기 목적을 달성하기 위하여, The present invention, in order to achieve the above object,

2~6 중량%의 암모니아수(25%); 4~10 중량%의 요소; 하기 화학식 1로 표시되는 화합물 2~5 중량%; 도파민 5~15 중량%; 아세트산 5~10 중량%; 및 잔량의 물을 포함하는 것을 특징으로 하는 섬유 개질 조성물로 코팅된 섬유로 직조된 감촉 및 방오성이 우수한 오가닉 직물를 제공한다: 2 to 6 wt% ammonia water (25%); 4 to 10% by weight of element; 2 to 5% by weight of a compound represented by the following formula (1); 5 to 15% by weight of dopamine; 5 to 10% by weight of acetic acid; And a residual amount of water. The organic fabric is excellent in texture and antifouling property, which is woven from fibers coated with the fiber-modifying composition.

[화학식 1][Chemical Formula 1]

Figure 112018013016127-pat00001
Figure 112018013016127-pat00001

[화학식 2](2)

Figure 112018013016127-pat00002
Figure 112018013016127-pat00002

또한, 본 발명은In addition,

상기 오가닉 직물로 제조된 의류를 제공하며, 특히 상기 오가닉 셔츠를 제공한다. The present invention provides clothes made from the organic fabrics, and more particularly, the organic shirts.

또한, 본 발명은 In addition,

a) 섬유를 섬유 개질 조성물로 코팅하는 단계; a) coating the fiber with a fiber modification composition;

b) 상기 코팅 섬유를 건조시키는 단계; 및b) drying the coated fibers; And

c) 상기 섬유를 직조하여 직조 섬유를 제조하는 단계;를 포함하는 감촉 및 방오성이 우수한 오가닉 직물의 제조방법으로서,and c) weaving the fiber to produce a woven fiber, the method comprising the steps of:

상기 섬유 개질 조성물은 2~6 중량%의 암모니아수(25%); 4~10 중량%의 요소; 하기 화학식 1로 표시되는 화합물 2~5 중량%; 도파민 5~15 중량%; 아세트산 5~10 중량%; 및 잔량의 물을 포함하는 것을 특징으로 하는 오가닉 직물의 제조방법을 제공한다: The fiber modifying composition comprises 2 to 6% by weight of ammonia water (25%); 4 to 10% by weight of element; 2 to 5% by weight of a compound represented by the following formula (1); 5 to 15% by weight of dopamine; 5 to 10% by weight of acetic acid; And a balance of water. ≪ RTI ID = 0.0 > A < / RTI >

[화학식 1][Chemical Formula 1]

Figure 112018013016127-pat00003
Figure 112018013016127-pat00003

[화학식 2](2)

Figure 112018013016127-pat00004
Figure 112018013016127-pat00004

본 발명의 오가닉 직물는 섬유의 표면을 새로운 개질 조성물로 개질함으로써 현저하게 향상된 감촉 및 방오성을 제공한다. The organic fabrics of the present invention provide significantly improved feel and stain resistance by modifying the surface of the fibers with a new modifying composition.

또한, 상기 오가닉 직물를 사용하여 제조된 의류는 피부 접촉감이 매우 우수하며, 방오성 및 세탁성이 매우 우수한 특징을 제공한다. In addition, the garment produced using the organic fabric has a very good skin contact feeling, and is excellent in antifouling property and washing property.

이하에서 본 발명을 더욱 상세하게 설명한다.Hereinafter, the present invention will be described in more detail.

본 발명은 2~6 중량%의 암모니아수(25%); 4~10 중량%의 요소; 하기 화학식 1로 표시되는 화합물 2~5 중량%; 도파민 5~15 중량%; 아세트산 5~10 중량%; 및 잔량의 물을 포함하는 것을 특징으로 하는 섬유 개질 조성물로 코팅된 섬유로 직조된 감촉 및 방오성이 우수한 오가닉 직물에 관한 것이다: The present invention relates to a composition comprising 2 to 6% by weight aqueous ammonia (25%); 4 to 10% by weight of element; 2 to 5% by weight of a compound represented by the following formula (1); 5 to 15% by weight of dopamine; 5 to 10% by weight of acetic acid; And a residual amount of water. The organic fabric is excellent in texture and antifouling property. The organic fabric is woven with fibers coated with the fiber-modifying composition.

[화학식 1][Chemical Formula 1]

Figure 112018013016127-pat00005
Figure 112018013016127-pat00005

[화학식 2](2)

Figure 112018013016127-pat00006
Figure 112018013016127-pat00006

상기 화학식 1의 화합물은 4-{[히드록시(4-히드록시페닐)메일]아미노}벤젠-1-술폰산 (4-{[Hydroxy(4-hydroxyphenyl)methyl]amino}benzene-1-sulfonic acid(CAS No.: 62268-55-7))이며, 상기 화학식 2의 화합물은 6-{[(4-아미노-3-히드록시페닐)메틸]아미노}피리딘-3-술폰산(6-{[(4-Amino-3-hydroxyphenyl)methyl]amino}pyridine-3-sulfonic acid(CAS No.: 920512-06-7))으로서, 코팅되는 섬유가 음이온을 띠어 음이온성 착색제가 결합되지 못하게 하 하며, 부드러운 감촉을 가질 수 있게 한다.The compound of Chemical Formula 1 may be prepared by reacting 4 - {[hydroxy (4-hydroxyphenyl) methyl] amino} benzene-1-sulfonic acid (6 - {[(4-amino-3-hydroxyphenyl) methyl] amino} 3-hydroxyphenyl) methyl] amino} pyridine-3-sulfonic acid (CAS No .: 920512-06-7), the coated fibers are anionic to prevent anionic colorants from binding, .

면직물과 같은 셀룰로오스성 직물 간의 염료 이동은 동일한 조에서 직물을 세탁하거나 가공할 때 발생한다. 염료 이동은 셀룰로오스성 섬유가 음이온성 종의 염료(면직물 및 다른 셀룰로오스성 직물 및 블렌드를 염색하는데 현재 사용되는 대부분의 염료임)에 약한 인력을 갖기 때문에 발생한다. 그러므로 상기 화학식 1 또는 화학식 2의 화합물에 의해 섬유의 표면이 술파이트 이온으로 대전되면 염색물이나 다른 이온성 오염물이 결합하는 것을 방지할 수 있다. Dye transfer between cellulosic fabrics such as cotton fabrics occurs when the fabrics are washed or processed in the same bath. Dye migration occurs because cellulosic fibers have a weak attraction to dyes of anionic species (which are the most dyes currently used in dyeing cotton fabrics and other cellulosic fabrics and blends). Therefore, when the surface of the fiber is charged with sulfite ion by the compound of Chemical Formula (1) or (2), binding of dye or other ionic contaminants can be prevented.

또한, 화학식 1 및 2에 포함된 아민기 및 도파민에 의해 섬유의 감촉도 부드럽게 향상된다.Also, the feel of the fibers is smoothly improved by the amine groups and dopamine included in the formulas (1) and (2).

본 발명에서 오가닉 직물란 오가닉 코튼(Organic Cotton)과 같이 농약이나 화학비료의 사용 없이 재배된 목화를 이용하고 방적과 같은 제사 및 제직 과정에서 화학합성물질의 사용을 엄격히 제한하여 제조되는 제품으로서, 촉감이 부드럽고 자극이 없어 안전한 섬유를 의미한다. 섬유 분야에서 오가닉 직물라는 용어는 흔하게 사용되고 있다. In the present invention, the organic fabric is manufactured by strictly restricting the use of chemical synthetic materials in the process of making and weaving such as spinning, using cotton cultivated without the use of agricultural chemicals or chemical fertilizers such as organic cotton, It means soft, non-irritating and safe fibers. In the field of textiles, the term organic fabrics is commonly used.

그러나, 본 발명에서 오가닉 직물라는 용어가 불명료한 경우에는 '섬유'로 수정할 수 있다.However, in the present invention, when the term organic fabric is unclear, it can be modified into 'fiber'.

또한, 본 발명은 상기 오가닉 직물로 제조된 의류에 관한 것이다. The present invention also relates to garments made from the said organic fabrics.

상기 오가닉 직물를 사용하여 제조된 의류는 피부 접촉감이 매우 우수하며, 방오성 및 세탁성이 매우 우수한 특징을 제공한다. The garment produced by using the organic fabric has a very good skin contact feeling, and is excellent in antifouling property and washing property.

특히, 상기 오가닉 직물는 오가닉 셔츠용으로 유용하게 사용될 수 있다. In particular, the organic fabrics can be usefully used for organic shirts.

본 발명은 또한, The present invention also relates to

a) 섬유를 섬유 개질 조성물로 코팅하는 단계; a) coating the fiber with a fiber modification composition;

b) 상기 코팅 섬유를 건조시키는 단계; 및b) drying the coated fibers; And

c) 상기 섬유를 직조하여 직조 섬유를 제조하는 단계;를 포함하는 감촉 및 방오성이 우수한 오가닉 직물의 제조방법으로서,and c) weaving the fiber to produce a woven fiber, the method comprising the steps of:

상기 섬유 개질 조성물은 2~6 중량%의 암모니아수(25%); 4~10 중량%의 요소; 하기 화학식 1로 표시되는 화합물 2~5 중량%; 도파민 5~15 중량%; 아세트산 5~10 중량%; 및 잔량의 물을 포함하는 것을 특징으로 하는 오가닉 직물의 제조방법에 관한 것이다: The fiber modifying composition comprises 2 to 6% by weight of ammonia water (25%); 4 to 10% by weight of element; 2 to 5% by weight of a compound represented by the following formula (1); 5 to 15% by weight of dopamine; 5 to 10% by weight of acetic acid; And a remaining amount of water. ≪ RTI ID = 0.0 > [0004] < / RTI >

[화학식 1][Chemical Formula 1]

Figure 112018013016127-pat00007
Figure 112018013016127-pat00007

[화학식 2](2)

Figure 112018013016127-pat00008
Figure 112018013016127-pat00008

상기 화학식 1의 화합물은 4-{[히드록시(4-히드록시페닐)메일]아미노}벤젠-1-술폰산 (4-{[Hydroxy(4-hydroxyphenyl)methyl]amino}benzene-1-sulfonic acid(CAS No.: 62268-55-7))이며, 상기 화학식 2의 화합물은 6-{[(4-아미노-3-히드록시페닐)메틸]아미노}피리딘-3-술폰산(6-{[(4-Amino-3-hydroxyphenyl)methyl]amino}pyridine-3-sulfonic acid(CAS No.: 920512-06-7))으로서, 코팅되는 섬유가 음이온을 띠어 음이온성 착색제가 결합되지 못하게 하 하며, 부드러운 감촉을 가질 수 있게 한다.The compound of Chemical Formula 1 may be prepared by reacting 4 - {[hydroxy (4-hydroxyphenyl) methyl] amino} benzene-1-sulfonic acid (6 - {[(4-amino-3-hydroxyphenyl) methyl] amino} 3-hydroxyphenyl) methyl] amino} pyridine-3-sulfonic acid (CAS No .: 920512-06-7), the coated fibers are anionic to prevent anionic colorants from binding, .

상기 오가닉 직물에서 기술된 내용은 상기 오가닉 직물의 제조방법에 모두 적용될 수 있다. The contents described in the organic fabrics can be applied to all the production methods of the organic fabrics.

본 발명의 제조방법은 직조된 섬유를 상기 섬유 개질 조성물로 코팅하여 오가닉 직물를 제조하는 방법도 포함할 수 있다.The manufacturing method of the present invention can also include a method of manufacturing an organic fabric by coating the woven fiber with the fiber modification composition.

상기에서 특별히 기술되지 않은 내용은 이 분야의 공지의 기술에 의해 실시될 수 있다.The contents not specifically described above can be implemented by known techniques in this field.

이하에서, 실시예를 통하여 본 발명을 보다 상세히 설명한다. 그러나, 하기의 실시예는 본 발명을 더욱 구체적으로 설명하기 위한 것으로서, 본 발명의 범위가 하기의 실시예에 의하여 한정되는 것은 아니다. 하기의 실시예는 본 발명의 범위 내에서 당업자에 의해 적절히 수정, 변경될 수 있다. Hereinafter, the present invention will be described in more detail by way of examples. However, the following examples are intended to further illustrate the present invention, and the scope of the present invention is not limited by the following examples. The following examples can be appropriately modified and changed by those skilled in the art within the scope of the present invention.

제조예 1: 섬유 개질 조성물의 제조Production Example 1: Preparation of fiber-modified composition

4 중량%의 암모니아수(25%); 6 중량%의 요소; 4 중량%의 4-{[히드록시(4-히드록시페닐)메일]아미노}벤젠-1-술폰산(ChemTik 사 제조); 도파민 6 중량%; 아세트산 7 중량%; 및 잔량의 물을 혼합하여 섬유 개질 조성물을 제조하였다. 4% by weight ammonia water (25%); 6% by weight of element; 4% by weight of 4 - {[hydroxy (4-hydroxyphenyl) mail] amino} benzene-1-sulfonic acid (manufactured by ChemTik); 6% by weight of dopamine; 7% by weight acetic acid; And a residual amount of water were mixed to prepare a fiber modification composition.

제조예 2: 섬유 개질 조성물의 제조Production Example 2: Preparation of fiber-modified composition

4 중량%의 암모니아수(25%); 6 중량%의 요소; 4 중량%의 6-{[(4-아미노-3-히드록시페닐)메틸]아미노}피리딘-3-술폰산(Chemsrc 사 제조); 도파민 10 중량%; 아세트산 7 중량%; 및 잔량의 물을 혼합하여 섬유 개질 조성물을 제조하였다. 4% by weight ammonia water (25%); 6% by weight of element; 4% by weight of 6 - {[(4-amino-3-hydroxyphenyl) methyl] amino} pyridine-3-sulfonic acid (Chemsrc); 10% by weight of dopamine; 7% by weight acetic acid; And a residual amount of water were mixed to prepare a fiber modification composition.

실시예 1: 오가닉 직물의 제조Example 1: Production of organic fabrics

제조예 1에서 제조된 섬유 개질 조성물을 패더 M/C에 넣고, Wet Pick-up을 100%로 조정한 상태에서 면 셀룰로스 섬유에 패딩하고 건조시켰다.The fiber-modifying composition prepared in Preparation Example 1 was placed in a fader M / C, padded on cotton cellulose fibers with the wet pick-up adjusted to 100%, and dried.

상기 건조된 섬유를 직조하여 오가닉 직물를 제조하였다. The dried fibers were woven to produce an organic fabric.

실시예 2: 오가닉 직물의 제조Example 2: Production of organic fabrics

제조예 2에서 제조된 섬유 개질 조성물을 패더 M/C에 넣고, Wet Pick-up을 100%로 조정한 상태에서 면 셀룰로스 섬유에 패딩하고 건조시켰다.The fiber-modifying composition prepared in Preparation Example 2 was placed in a fader M / C, padded on the cotton cellulose fibers while the wet pick-up was adjusted to 100%, and dried.

상기 건조된 섬유를 직조하여 오가닉 직물를 제조하였다. The dried fibers were woven to produce an organic fabric.

실시예 3: 오가닉 직물의 제조Example 3: Fabrication of organic fabrics

면 셀룰로스 섬유를 직조하여 제조된 오가닉 직물를 상기 제조예 1에서 제조된 섬유 개질 조성물에 침지시켜서 표면을 코팅한 후 건져서 건조시켜서 오가닉 직물를 제조하였다. The organic fabric prepared by weaving cotton cellulose fibers was immersed in the fiber modification composition prepared in Preparation Example 1, coated on the surface, dried and dried to prepare an organic fabric.

비교예 1: 오가닉 직물의 제조Comparative Example 1: Production of organic fabrics

섬유 개질 조성물을 사용하지 않은 점을 제외하고는 실시예 1과 동일하게 직조하여 오가닉 직물를 제조하였다.An organic fabric was produced by weaving in the same manner as in Example 1, except that the fiber modification composition was not used.

시험예 1: 오가닉 직물의 오염에 대한 평가Test Example 1: Evaluation of contamination of organic fabrics

상기 실시예 및 비교예에서 제조된 섬유에 대한 오염을 이 분야에서 통상적으로 사용되는 AATCC 색 전이 스케일 또는 오염용 무채색 스케일을 이용하여 평가하였다. The fouling of the fibers prepared in the above Examples and Comparative Examples was evaluated using the AATCC color transition scale or achromatic scale for contamination which is commonly used in this field.

<평가기준><Evaluation Criteria>

클래스 5 - 무시가능 또는 무오염Class 5 - negligible or uncontaminated

클래스 4 - AATCC 스케일에서 4열 또는 오염 스케일에서 단계 4와 동등한 오염Class 4 - Contamination equivalent to Stage 4 at 4 rows or contaminant scale at AATCC scale

클래스 3 - AATCC 스케일에서 3열 또는 오염 스케일에서 단계 3과 동등한 오염Class 3 - Contamination equivalent to step 3 in three rows or contaminant scale at AATCC scale

클래스 2 - AATCC 스케일에서 2열 또는 오염 스케일에서 단계 2과 동등한 오염Class 2 - Contamination equivalent to Stage 2 in AATCC scale at 2 rows or contaminant scale

클래스 1 - AATCC 스케일에서 1열 또는 오염 스케일에서 단계 1과 동등한 오염Class 1 - Contamination equivalent to Stage 1 in column 1 or contaminant scale at AATCC scale

2% 다이렉트 레드 79비염색 면 상의 오염2% Direct red 79 Contamination on non-stained surface 2% 다이렉트 블루 80비염색 면 상의 오염2% Direct Blue 80 Contamination on non-stained surface 비교예 1Comparative Example 1 1One 1One 실시예 1Example 1 3-43-4 3-43-4 실시예 2Example 2 44 44 실시예 3Example 3 3-43-4 3-43-4

상기한 바와 같이, 섬유 개질 조성물로 처리되지 않은 비교예 1의 섬유는 시험 동안 진한 핑크색으로 심하게 색이 이동되었다. 그러나 본 발명에 따라 섬유 개질 조성물로 처리된 실시예 1 내지 3의 직물은 훨씬 색이동에 의한 오염 크게 감소되었다.As described above, the fibers of Comparative Example 1, which had not been treated with the fiber modification composition, were heavily colored to dark pink during the test. However, the fabrics of Examples 1 to 3 treated with the fiber modifying composition according to the present invention were significantly reduced in contamination by color shift.

시험예 2: 오가닉 직물의 감촉 평가Test Example 2: Evaluation of texture of organic fabrics

성인 남녀 각 5명씩을 체험군으로 하여 상기 실시예 1 내지 3 및 비교예 1에서 제조된 오가닉 직물의 감촉에 대한 체험 테스트를 실시하였다.Experimental tests on the texture of the organic fabrics prepared in Examples 1 to 3 and Comparative Example 1 were conducted using five adult persons as an experiential group.

체험군은 실시예 1 내지 3의 오가닉 직물를 터치해 보고 감촉에 대하여 각각 1~10 점의 점수를 부여하였다. 실험결과는 하기 표 1과 같았다.In the experiential group, organic fabrics of Examples 1 to 3 were touched and scores of 1 to 10 points were given to the feelings. The experimental results are shown in Table 1 below.

체험군Experience group 비교예 1
오가닉 직물
Comparative Example 1
Organic fabrics
실시예 1
오가닉 직물
Example 1
Organic fabrics
실시예 2 오가닉 직물Example 2 Organic fabrics 실시예 3
오가닉 직물
Example 3
Organic fabrics
남자 1Male 1 55 77 88 88 남자 2Male 2 66 66 77 77 남자 3Male 3 77 88 77 88 남자 4Male 4 77 77 88 77 남자 5Male 5 77 88 88 88 여자 1Woman 1 88 88 77 77 여자 2Woman 2 66 77 88 66 여자 3Woman 3 66 77 77 77 여자 4Women 4 55 66 66 88 여자 5Women 5 77 88 77 88 평균Average 6.46.4 7.27.2 7.37.3 7.47.4

상기 표 2로부터 확인되는 바와 같이, 본 발명의 실시예 1 내지 3의 오가닉 직물는 감촉이 비교예 1의 오가닉 직물보다 우수한 것으로 평가되었다.As can be seen from the above Table 2, the organic fabrics of Examples 1 to 3 of the present invention were evaluated to be superior to the organic fabrics of Comparative Example 1 in feeling.

Claims (4)

2~6 중량%의 암모니아수(25%); 4~10 중량%의 요소; 하기 화학식 1로 표시되는 화합물 2~5 중량%; 도파민 5~15 중량%; 아세트산 5~10 중량%; 및 잔량의 물을 포함하는 것을 특징으로 하는 섬유 개질 조성물로 코팅된 섬유로 직조된 감촉 및 방오성이 우수한 오가닉 직물:
[화학식 1]
Figure 112018055034808-pat00009
2 to 6 wt% ammonia water (25%); 4 to 10% by weight of element; 2 to 5% by weight of a compound represented by the following formula (1); 5 to 15% by weight of dopamine; 5 to 10% by weight of acetic acid; And a residual amount of water. The organic fabric is excellent in texture and antifouling property and is woven with fibers coated with the fiber-modified composition.
[Chemical Formula 1]
Figure 112018055034808-pat00009
제1항의 오가닉 직물로 제조된 의류.Clothes made from the organic fabric of claim 1. 제2항에 있어서
상기 의류는 오가닉 셔츠인 것을 특징으로 하는 의류.
The method according to claim 2, wherein
Wherein the garment is an organic shirt.
a) 섬유를 섬유 개질 조성물로 코팅하는 단계;
b) 상기 코팅 섬유를 건조시키는 단계; 및
c) 상기 섬유를 직조하여 직조 섬유를 제조하는 단계;를 포함하는 감촉 및 방오성이 우수한 오가닉 직물의 제조방법으로서,
상기 섬유 개질 조성물은 2~6 중량%의 암모니아수(25%); 4~10 중량%의 요소; 하기 화학식 1로 표시되는 화합물 2~5 중량%; 도파민 5~15 중량%; 아세트산 5~10 중량%; 및 잔량의 물을 포함하는 것을 특징으로 하는 오가닉 직물의 제조방법:
[화학식 1]
Figure 112018055034808-pat00011
a) coating the fiber with a fiber modification composition;
b) drying the coated fibers; And
and c) weaving the fiber to produce a woven fiber, the method comprising the steps of:
The fiber modifying composition comprises 2 to 6% by weight of ammonia water (25%); 4 to 10% by weight of element; 2 to 5% by weight of a compound represented by the following formula (1); 5 to 15% by weight of dopamine; 5 to 10% by weight of acetic acid; And a remaining amount of water.
[Chemical Formula 1]
Figure 112018055034808-pat00011
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100397654B1 (en) * 2000-07-18 2003-09-13 박건용 Dyeing Method for Silk Fabrics
KR101409491B1 (en) 2014-01-24 2014-08-06 김정현 Eco-Friendly Fabrics for Clothing Comprising Functions of Antibacterial and Deodorization and Manufacturing Methods Thereof
KR101822141B1 (en) 2017-01-11 2018-01-25 (주)재화 Manufacturing method for functional fiber and functional fiber manufactured by the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100397654B1 (en) * 2000-07-18 2003-09-13 박건용 Dyeing Method for Silk Fabrics
KR101409491B1 (en) 2014-01-24 2014-08-06 김정현 Eco-Friendly Fabrics for Clothing Comprising Functions of Antibacterial and Deodorization and Manufacturing Methods Thereof
KR101822141B1 (en) 2017-01-11 2018-01-25 (주)재화 Manufacturing method for functional fiber and functional fiber manufactured by the same

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