KR101881654B1 - The method of preparing a warm bath water treatedly manufacture process - Google Patents

Abstract

A small amount of magnesium, sodium, potassium, calcium and heavy metals as iron, aluminum, copper, zinc, manganese and poison toxic heavy metals such as arsenic, cadmium , Flow control process, oxidative decomposition process by ozone generator, aeration process, filtration process, chelate resin treatment process, and 1 case of lead, mercury, hexavalent chromium, and mineral water flowing from waste coal mine in which cyan is dissolved The present invention relates to a method for obtaining hot water by treating mineral water with a tea, a secondary precipitation process, a filtration process, and a pH adjustment process.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for preparing a hot bath water,

The present invention relates to a method for obtaining natural hot spring water by treating natural mineral waters, specifically, 411-35 Guryeri, Sungdong-eup, Yeongwol-gun, Gangwon-do, Gangwon-do, and 78-2 Sangdo-dong, Gangwon- as has sulfur compounds underground mineral water of the material, and waste coal mine in _{Al 2 (SO 4) 3,} Al 2 (SO 4) (OH) 10 · 5H 2 O, NH 4 Al (SO 4) 2 · 12H 2 O, Na 4 Type compound such as Al ₆ Si ₈ O ₉₄ , MgAl ₂ (SO ₄ ) ₄揃 22H ₂ O, (K, Na) Al ₃ (OH) ₆ (SO ₄ ) _2, and organic germanium) It is contained as (Ge-132) form of _{"HO-C-CH 2 -Ge} = O-Ge-CH 2 germanium ion (Ge ⁺⁺⁾ having the structure -CH2-C-OH much.

The mineral water contains minerals such as trace amounts of sericin (Se), a large amount of sulfuric acid ions (1300 ~ 250PPM) and minerals such as calcium, magnesium, sodium and potash. The harmful metals include iron, copper, zinc, manganese, Mineral water containing a small amount of mite ions is selected. Mineral water of Geumjeri coal abandoned mine which contains germanium and serenium, which are the most useful components of hot spring water, and which is easy to water treatment, is selected as a mineral water. The present invention relates to a method for obtaining hot water by treating natural mineral waters including a process, an ozone treatment process, an aeration treatment process, a filtration treatment process, a chelate resin treatment process, a first to second precipitation treatment, a filtration treatment and a PH adjustment process.

The present invention has been made in view of the fact that mineral waters are effective for various diseases caused by locally produced mineral waters generated from abandoned coal mines in Jangseon, Gangwon, and Taebaek in Gangwon province, and for many years, Based on the clinical fact that there is a large convergence effect, we choose Bangje-ri mineral water located at 126-2, Bangje-ri, Sangdong-eup, Jeongseon-gun, Gangwon-do, Gangwon-do, Korea. In order to obtain hot water through multi-stage treatment process, Respectively.

1) Analysis of the water quality of Bangjedong mineral water is shown in Table 1.

Analysis result of water quality of Bangje-ri mineral water (analysis result commissioned by Kyungwon University) Test items \ Category unit Drinking water quality standard Analysis Evaporation intervention mg / l 500 3360 Hydrogen ion concentration (25 캜) PH 5.8 to 8.5 4.2 Residual chlorine mg / l 0.2 ND Ammonia nitrogen (NH ₄ -N) mg / l 0.5 0.164 Nitrate nitrogen (NO ₃ -N) mg / l 10 0.710 Chlorine ion (Cl-) mg / l 150 10 Xian (CN-) mg / l ND ND Sulfate ion (SO ₄ ^2- ) mg / l 200 1910 Arsenic (As) mg / l 0.05 ND Cadmium (Cd) mg / l 0.01 0.021 Copper (Cu) mg / l One 0.5 Iron (Fe) mg / l 0.3 0.26 Mercury (Hg) mg / l ND ND Manganese (Mn) mg / l 0.3 49.94 Lead (Pb) mg / l 0.05 ND Selenium (Se) ppb 0.01 57.571 Zinc (Zn) mg / l One 8.22 Germanium (Ge) ppb - 133.16 Calcium (Ca) mg / l - 254.40 Magnesium (Mg) mg / l - 392.38 Potassium (K) mg / l - 21.88 Sodium (Na) mg / l - 4.73 Aluminum (Al) mg / l 0.2 244.95 Hexavalent chromium (Cr) mg / l 0.05 0.01

In the results of the analysis of the water quality of Banggyeong Mineral Water in Table 1, it is suggested that the water quality standards of drinking water are stipulated for reference to harmful level of harmful heavy metals and can not be a standard of hot bath water or hot water bath.

Natural mineral waters include sulfur springs containing a large amount of sulfur, carbonate springs containing free carbon dioxide, and alum containing a large amount of alum and alum. These mineral waters are used as hot baths or open bath baths.

As a result of X-ray diffraction analysis of the crude water of Experiment 3 described below, it can be seen that the amount of evaporation residue is 3,360 mg / l, which is 77.8 wt% of the evaporation residue, is of a material having the properties of alum also Single crystal structural formula of the material represented by a on the X-Ray diffraction peaks _{Al 2 (SO 4) (OH} ) 10 · mineral ore, called Basaluminite as the material of 5H ₂ O Is known as a hydrous basic sulphate mineral excavated from Ilchester and Crepton Hill, Northamptonshire, England. It is unlike white and its aqueous solution is hydrolyzed and has a pungent taste. It is also used as water purifying agent and medicines as astringent agent, Also, the structural formula denoted by B on the x-ray diffraction peak in FIG. 1 was identified as Natroalunite, The alveolar minerals in the minerals excavated in the minerals have convergence, hemostasis, and side effects. They are not absorbed by the gastrointestinal membrane but have no effect on the mucous membranes. They are effective as an astringent agent for skin inflammation and 0.02 ~ 1.5% aqueous solution as inhalants or poultices It is also used as a convergent agent such as stomatitis and throat qatar.

, It can be said that it is a mineral water which can be used as a warm bath water or a half bath water bath because the sufficient amount of alum and similar alum are dissolved in the water of the Yangjae mineral water and the effect on the skin is great.

In addition, calcium, potassium, sodium, and magnesium are dissolved in a relatively large amount as minerals in the Yangjae mineral waters, and K, Na and Mg ions in the mineral components are mostly combined with sulfate ions to form metal algae and alum Calcium in the minerals is absorbed by the body to make the bones and teeth that support the body, the muscles and nerves to maintain normal activity and blood coagulation.

Magnesium is involved in contraction in the muscles and maintains normal brain and nervous system in the nerve. Potassium regulates the osmotic pressure in the cells, adjusts the action of the muscles and nerves. It also balances the blood pressure with the sodium and the sodium adjusts the osmotic pressure , The maintenance of moisture equilibrium, the control of PH of body fluids, and the excitement of muscles and nerves, and the reason why the dissolved amount of minerals and sulfate ions in the Kimchi mineral water is relatively high is attributed to the high ratio of alum components in the evaporation residues Mineral content of mineral water is considered to be a substance that can be transported through cells and nerve cell membranes, so that it will have a good effect on hot bathing.

Iron, copper, arsenic, lead, and mercury in these heavy metals are considered to be no problem below the drinking water quality standard. Iron, zinc, copper, manganese, arsenic (As) lead, cadmium, mercury, Although manganese, cadmium and aluminum exceed the drinking water quality standard, aluminum is necessary together with sulfate ion for the amount of alum in the present invention. Even if zinc and manganese are heavy metals, there is not much damage to the human body, It is necessary to drastically reduce the amount of dissolved cadmium through the process and the cadmium which is an extremely toxic heavy metal should be reduced to below the drinking water quality standard through the water treatment process.

In addition, the fact that germanium and serenium are dissolved in the Yangjae mineral spring water is an extremely rare phenomenon in mineral water which is dissolved in a large amount of alum or aluminous alum, which is an epochal phenomenon and gives motivation to develop the hot water of the present invention.

The physical action of organic germanium having the structure of "HO-C-CH ₂ -Ge = O-Ge-CH ₂ -CH ₂ -C-OH" is as shown in the structural formula, Oxygen can be supplied to the human body, and thus it is known to oxidize and decompose foreign substances, wastes, and toxins in the circulatory system, and exerts its action on urine and skin. It is known to be effective for various kinds of malignant skin diseases such as stomach cancer. It is reported as a substance acting as an enzyme activation, and it can be said that it is a hot water bath which can develop an excellent hot bath effect together with alum and alum alum dissolved in hot water.

2) No bacteria, Escherichia coli or organic substances were detected.

3) Chemical analysis of Bangje-ri mineral waters and evaporation residues

  (1) X-Ray diffraction analysis and chemical analysis

    (1) In order to prevent the chemical structure of the evaporation residue from being altered on a hot plate, about 1 liter of the mineral water sample is evaporated at 40 to 50 ° C., and the white solid is then obtained as a residue, and then dried in an electric oven at 110 ° C. for 2 hours The results of x-ray diffraction analysis are as follows.

② x-ray diffractometer: Model RIGAKU, Model No. : Geigerflex Ⅲ A

③ x-ray diffraction analysis

  In order to investigate the characteristics of the sample, CuKa filter was used as a target, the voltage was 30 kV, the current was 10 mA, and the scanning speed was 2 ° / min.

The results of the x-ray diffraction analysis of the evaporation residue of the mineral water under the above conditions are shown in Fig.

1, the crystal structure of the substance represented by A on the x-ray diffraction peak is as follows.

The structural formula analyzed by the X-ray diffraction index card is Al ₂ (SO ₄ ) (OH) ₁₀ · 5H ₂ O, which is a substance having the molecular formula of aluminum sulfate hydrate hydrate. It is a substance eluted from ore called basaluminite .

This mineral is originally known as hydrobromic sulphate minerals derived from Irchester and Clifton-Hill in Northamptonshire, England. It is not known whitish and its aqueous solution is hydrolyzed and has a pungent taste. It is also used as a water purifying agent and as a medicine for astringent agent. Are reported to have double ply, similar ply, and radial ply.

The X-ray diffraction index card shows the structural formula of the substance marked B on the X-Ray diffraction peak. It is a mineral ore excavated from the Nation Belle mine in Colonado, USA as its original ore,

(K, Na) Al ₃ (OH) ₆ (SO ₄ ) ₂ , which is a mineral of hexagonal crystals. It is translucent from white to transparent. Its excavation process is carried out by sulfuric acid in underground volcanic rocks, Have been reported to have acted on alumina rocks.

In order to identify the components of algae in the underground veins, the compositional analysis results of the evapotranspiration artifacts are shown in Table 2 below.

Analysis of alum components in the evaporation residue of the Yangjae mineral waters ingredient Al ₂ O ₃ K ₂ O Na ₂ O wt% 14.5 0.28 0.08

As shown in Table 2, in the pure form of KAl (SO ₄ ) ₂ , it is estimated that there are about 43% of the aurora in the basement layer.

FIG. 2 shows the result of analyzing the X-ray diffraction angle (2?) Up to 80 °. The material shown in FIG. 2 is Aluminum sulfate, which is represented by Al ₂ (SO ₄ ) ₃ and the material indicated by B is Aluminum sulfate hydrate. Among these, the expected formula is NH ₄ AlSO ₄ ) ₂ · 12H ₂ O as Ammonium Aluminum sulfate.

These substances are most likely to be present as 12-hairs and are ammonia-like aluminous substances. It is estimated that the substance on the peak indicated by C is aluminum sulphide silicate sodium, which has the structural formula of Na ₄ Al ₆ Si ₈ O ₂₃ S ₄ . Material indicated by D was estimated to determine a material having a structural formula of _{MgAl 2 (SO 4) 4 ·} 22H 2 O.

Most of the analytical results of these materials are characterized by the structure of aluminum sulphate as the main axis molecules, which are similar to those of alum.

Therefore, the molecular structure of this test result can be summarized as follows.

1. Aluminum sulfate (Al ₂ (SO ₄ ) ₃ )

_{2. Aluminium sulfate hydrate (Al 2 (} SO 4) (OH) 10 · 5H 2 O)

3. Ammonium aluminum sulfate (NH ₄ AlSO ₄ ) ₂揃 12H ₂ O)

4. Aminium sulfide silicate sodium (Na ₄ Al ₆ Si ₈ O ₂₃ S ₄ )

5. Magnesium aluminum sulfate (MgAl ₂ (SO ₄ ) ₄ .22H ₂ O)

6. Kalium natrium alum ((K, Na) Al 3 (OH) 6 (SO 4) 2)

Were found to be the main components of mineral water.

Among them, Alum solution of Alum 's solution was analyzed in order to investigate the extent of dissolution of Alum - like substances.

Analytical results of Alum solution of Korean Pharmacopoeia division Mineral water solution Evaporation residue Remarks wt% 0.389 77.8 KAl (SO _{4) 2}

Water treatment can be divided into water treatment, wastewater treatment, ground water treatment, mineral water treatment and various water treatment. The general treatment schemes for water treatment are mainly known as apparatuses and methods for the treatment of surface water such as rainwater, which are used for pretreatment using a screen and a screen, chemical coagulation, precipitation granular media filtration and sterilization treatment such as chlorine And general treatment schemes are also known for treatment of wastewater such as factory wastewater and domestic wastewater. The most common ones are primary and secondary treatment units, tertiary treatment units and physical and chemical units. The primary treatment is a large amount of wastewater , And the removed solids should be treated by appropriate disposal in most cases, and the second treatment is a device and method for biologically oxidizing the remaining organic suspended solids and organically dissolved solids Consists of.

In addition, since groundwater is good in water quality, it is necessary to remove gas such as carbon dioxide which exists in a supersaturated state and softening process by lime-soda process or ion exchange if the hardness is high. If a large amount of iron or manganese is contained, A special method is needed.

Mineral water can be called a sulfur spring, a carbonate spring, or an alum lavender depending on the ingredients contained in large quantities, and there is a big difference in water treatment methods. As in the present invention, the water treatment of a mineral water containing a large amount of alum and alum alum is based on alum, and the loss of alum due to water treatment is small and the loss of germanium and serenium and minerals Minimizes the amount of heavy metals, maximizes the removal of heavy metals, and completely eliminates extreme toxic heavy metals. It is a water treatment method that is characterized by a feature compared to other mineral water treatment.

The present invention provides an economical and efficient small-scale treatment system for treating a large amount of alum and alum aliquot components, minerals, heavy metal components, trace germanium and selenium dissolved from waste coal mines, in an economical and efficient small-scale treatment system, And to provide a method of manufacturing a hot water bath by mineral water treatment which can maximize the warm bath effect.

One-step process to control the inflow volume of mineral water so that a certain amount of inflowing mineral water can be treated continuously

Two-step process to oxidize and decompose heavy metal ions dissolved in mineral water by ozone oxidation method by ozone generator

Three-step process to aeration the mineral water that oxidizes and decomposes heavy metal ions

A four-step process of filtering the aeration water through an aeration-treated mineral water through a filtration tank of a filtration tank

Five-step process for adsorbing and removing metals, especially heavy metal ions, through filtration treated mineral water through a chelate ion-exchange resin

6 step process of filtering the mineral water passing through the chelate ion exchange resin through the first and second settling tank

And a 7 step process for obtaining hot water by adjusting the filtered mineral water in the pH 4.0 to 4.5 range to obtain hot water.

As in the present invention, the method of obtaining hot water by water treatment of mineral water in a multistage process is an efficient method of minimizing loss of components useful for the human body and skin dissolved in mineral waters by water treatment and maximizing the removal of heavy metal components, The use of the semiconductor ozonizer system can greatly enhance the oxidative decomposition of heavy metals and thus ensure competitiveness. The hot bath water thus obtained contains a large amount of alum and similar alum components, It is used as an anti-inflammatory agent that gives elasticity to the skin. It is characterized as an inflammatory astringent agent that has the function of water purification and sterilization. It is known that germanium is effective for various kinds of malignant skin diseases such as stomach cancer. Mineral component is also mineral Through cell and nerve cell membrane It is a substance that can be moved, so it can be said that it is a hot bath which can have a good effect on the body and the skin.

Fig. 1 X-ray diffraction diagram of the evaporation residue of mineral waters
Figure 2 X-ray diffraction diagram of the evaporation residue of mineral water
(An analysis result of the X-ray diffraction angle (2?) Of up to 80 °)

The present invention relates to a method for recovering a heavy metal component harmful to the human body in a mineral water containing a large amount of alum and similar alum component, mineral component, heavy metal component, organic germanium and selenium flowing from a waste coal mine located at 126-2, Sangdong- To a method for manufacturing a hot water bath which can reduce or eliminate the loss of the alum and alum, minerals, selenium and germanium components which are useful for the human body and skin by performing a multi-step process,

One-step process to control the inflow volume of mineral water so that a certain amount of inflowing mineral water can be treated continuously

A two-step process for oxidizing and decomposing heavy metal ions dissolved in mineral water by an ozone oxidation method using an ozone generator apparatus having a semiconductor ozone concentration of 4 to 6 wt%

Three-step process to aeration the mineral water that oxidizes and decomposes heavy metal ions

A four-step process of filtering the aeration water through an aeration-treated mineral water through a filtration tank of a filtration tank

5-step process for adsorbing and removing heavy metal ions by passing filtrated mineral water through a chelate ion-exchange resin

6 step process of filtering the mineral water passing through the chelate ion exchange resin through the first and second settling tank

And a seventh step of obtaining a warm bath water by adjusting the filtered mineral water to a pH of 4.2 to 4.5 in the range of pH 4.2 to 4.5.

The ozone generator used in the two-stage process for obtaining the hot bath water uses an air-cooled semiconductor type OZONAIR GENERATOR, and the comparison table and the generated ozone concentration in comparison with other ozone generator devices are shown in Tables 3 and 4, respectively .

Comparison table for ozone generator type Comparison items \ ozone generator type U / V TYPE C.D TYPE OZONAIR CO.
(Semiconductor type) Remarks
AIR method O ₃ method
(95% or more) Ozone concentration 0.001 to 0.1% 1 to 2% 2 to 3% 4 to 6% - O ₃ type 1kg
Production power - 38kW or more 25kW or more 7kW Amenities
Exclude power Oxygen cost - none 33 ~ 50kg none O ₃ method
1kg per production Installation area - plethora plethora Minimal CD TYPE
1/10 to 1/50
area Degree of failure - frequency frequency Almost none - Maintenance - Periodic component replacement none - Breakdown - Field repair none - Generation technique - At high pressure piling semiconductor
Ozone generator - Cooling system - Water cooling system deflation Conventional: frequent breakdown due to humidity Electricity - A. C AC to DC
How transitions are used Installation cost - Exceed Exceed Minimum standards for existing ozone generation Oxidative decomposition ability Not suitable for industrial use Degradable material can not be processed Super oxide decomposition type -

Ozone concentration (%) and dissolved concentration (mg / l) division U / V TYPE CD TYPE
OZONAIR
(week) 254NM 185NM Gas state ozone concentration
(% by weight) 0.001% 0.1% One% 1.5% 2% 3% 4 to 6% concentration ozone
Dissolved concentration
(mg / l) 5 ℃ 0.007 0.74 7.39 11.09 14.79 22.18 31.24 to 36.68 25 ℃ 0.004 0.35 3.53 6.29 7.05 10.58 14.95-17.55 30 ℃ 0.003 0.27 2.70 4.04 6.39 8.09 11.5 to 13.5

Dissolution Concentration: United States E.P.A. Regulation C. T value 0 mg / l (C: C. In mg / l, T: T. In time = C. T VALUE)

SCHOOL: USA 0.GUNIT

As shown in Tables 3 and 4, the ozone generator device used in the present invention has a high ozone concentration in air or in water, thereby oxidizing and decomposing heavy metals in a short time, thereby increasing the heavy metal removal rate and water treatment ability of mineral water, It decomposes degradable pollutants and eliminates bad odors. It excellently disinfects harmful heavy metals and oxidizes and decomposes to remove most or all of them by precipitation and filtration process. It maintains parallelism of minerals, Increases the effect of water and also kills algae microbes in mineral waters and then returns to the biological oxygen demand in the water.

Particularly, the ozone generator apparatus is particularly effective in removing cyan and chromium.

In the three-step process, the mineral water aeration process that has undergone the two-stage process improves the oxidative decomposition effect of heavy metals and improves the filtration efficiency by increasing the coagulation effect of heavy metal oxidative decomposition. In addition, residual chlorine and ammonia in mineral water are removed, An aeration-type aeration device is used.

The filtration phase used in the filtration tank of the 4th step process is a filtration phase in which a coarse sand layer of 3 to 5 mm in size and an artificial enriched soil layer granulated in 3 to 5 mm of a zeolite zeolite granule granulated in 2 to 3 mm, Is a filtration layer formed by laminating a plaster mat layer surrounded by a mesh fabric of a synthetic resin material which can not escape.

The zeolite is granulated to 3 ~ 5mm and washed cleanly in clear water more than 3 times. After heat treatment at 100 ℃ for 30 minutes, clean the zeolite more than 3 times with clean water and use it as a filter medium for more than 10 hours.

Although such zeolite has excellent adsorption, ion exchange and substitution properties, it has a problem of charging 100,000 Won / ton for granular materials. Therefore, 40% of zeolite is used and the voids are secured better than zeolite, It is possible to secure competitiveness by using 60% of culture soil, and the total thickness of laminate is in the range of 30cm ~ 50cm.

The artificial cultivation soil refers to a soil having a mixture of magnesium chloride and calcium chloride while classifying a mixed powder obtained by mixing 70 kg of Fortent cement as a hardening agent and 1 ton of frying oil excellent in self-curing property having a silicon and alumina content of 75 to 95% It is a needle-shaped crystal structure of Bintu (pore) which is processed by Angstrom porosity treatment of granulated specially processed by spraying a topical aqueous solution. It is an artificial enrichment soil which is an aseptic and porous assembly.

The zeolite in the filtration phase is an ion exchangeable substance, which adsorbs and removes heavy metal ions in the mineral water but is effective in softening the hard water.

During the softening process, the gyroidite absorbs and removes calcium and magnesium ions in the mineral water, instead discharges the sodium ion of the sodagiolite into the mineral water, and the artificial cultivation soil is also effective to ion exchange and soften heavy metals like the gyroite.

The mineral water passing through the filtration phase passes through the chelate ion exchange resin and has selective adsorption on specific heavy metal ions, so heavy metals are removed.

The chelating resin is a positive ion exchange resin containing a tertiary amine and an iminodiacetic acid group as a carboxylic acid group and a chelating resin having selectivity for a specific heavy metal ion.

When used, it is used in sodium form. Since it is coordinated with heavy metal ions, the heavy metal is captured, and the coordinated resin is regenerated by treating with mine, and the selectivity for the metal ion of this resin is qualitatively as follows.

F ⁺⁺⁺ > Al ⁺⁺⁺ > La ⁺⁺⁺ > Hg ⁺⁺ > UO ₂ ⁺⁺ > VO ₂ ⁺⁺ > Pb ⁺⁺ > Cd ⁺⁺ > Zn ⁺⁺ > Fe ⁺⁺ > Mn ⁺⁺ > Ca ⁺⁺ > Ba ⁺⁺ > Sr ^{++ It} is difficult to regenerate because of its high chelating ability with respect to trivalent ions, and it can be regenerated by using high concentration mines.

One of the characteristics of the chelate resin is that it can selectively adsorb heavy metal ions even at high concentrations of alkali metal ions such as sodium potassium, and can be used continuously for regeneration. Especially effective for copper, cadmium, zinc, etc. have.

The five-step process of passing the chelate resin body is a very suitable and essential process for obtaining hot bath water in the mineral water of the present invention.

The reason for this is that the mineral water used in the present invention selectively adsorbs zinc in heavy metals exceeding the drinking water quality standard and Cd, which is a highly toxic heavy metal, even though heavy metals such as potassium, sodium and alkali metal ions are dissolved in large amounts The advantage of being able to remove zinc and card hate very effectively and also to reproduce and continuously use chelating resin is also a suitable process for the mineral water treatment of the present invention. The mineral water passing through the chelate resin body is filtered through the primary and the secondary settling tank. The filtration material used in the filtration process is the filtration phase used in the 4th step process. The pH of the treated water is adjusted to 4 ~ 4.5, Thereby producing a half-bath hot water bath.

The treated water obtained by treating the mineral water in the above manner is used as hot bath water or half-bath hot bath water, but a large amount of alum component is dissolved in the hot bath water as such, which can be referred to as hot water bath.

According to the pharmacopoeia, 0.02 ~ 0.5wt% solution is used as an inhalant or poultice. Even if it is underwear, it does not absorb in the gastric mucosa and only causes micro-action in the mucous membrane. Therefore, 0.3wt% .

The aqueous solution of aluminum sulfate dissolved in mineral water is acidic and has a pungent taste. It is used as a medicine for astringent agent. Aluminum ion contained in alum (alum) is used as a convergent agent because it has a property of precipitating foreign matter by binding with protein. It is effective as an astringent agent for skin inflammation and is used as a convergent agent of stomatitis and throat Qatar. It also has a hemostatic effect.

In addition, hot water has sterilization, preservation and deodorizing action, and it is currently under research and development for application to bathing water, special treatment of skin diseases, and wet tissue.

In order to clarify the technical content of the present invention and to examine the treatment effect of the mineral water, the state of the mineral water and the hot bath water were examined by way of example.

Example (1)

The apparatus of the present invention for treating mineral water with hot bath water is capable of continuously treating 3 tons per hour, and it controls the flow rate of the pre-treated mineral water of 50 kg / min continuously to the ozone generator apparatus Ozone oxidizing method using semiconductor ozone generator) oxidizes and decomposes the heavy metals dissolved in the mineral waters. Then, the mineral waters treated by aeration are filtered through the filtration tank of the filtration tank, and the filtered mineral waters are washed with a chelate ion exchange water And the mineral water passed through the first settling tank and the second settling tank was filtered to obtain a PH 5.4 mineral water filtrate.

The PH of the mineral water filtrate was adjusted to obtain 1.5 tons of hot water adjusted to pH 4 to 4.5. In the above embodiment, it takes 1 hour to start the introduction of mineral water at a rate of 50 kg / min to obtain a hot bath water, and a hot bath water of 3 tons per hour can be obtained.

Table 6 shows the results of the process water test results and the mineral water quality analysis table (1), which were analyzed by commissioning the Korea Chemical Fusion Test Institute to the final process water obtained by filtration in the above Example (1).

Comparison table of water quality analysis table of Bangje-ri mineral water and analysis table of process water quality Item \ Category
Test result unit Drinking water quality standard Mineral water (Gamjeri) Processed water Test Methods Fe mg / l 0.3 0.26 0.05




APHA STANDARD METHOD
2012







Zn mg / l One 8.22 0.97 Cu mg / l One 0.5 0.00 As mg / l 0.05 ND 0.00 Pb mg / l 0.05 ND 0.00 Mn mg / l 0.3 49.94 12.2 PH (25 DEG C) mg / l 5.8 to 8.5 4.2 5.4 SO ₄ ^-2 mg / l 200 1910.0 1590.0 Al mg / l 0.2 244.95 15.0 Ca mg / l - 254.40 231.0 Mg mg / l - 392.38 138.0 K mg / l - 21.88 16.7 Na mg / l - 4.73 2.32 Ge mg / l - 133.16 ppb 0.014 Se mg / l 0.01 57.571ppb 0.00

In Table 3, heavy metals, such as iron, zinc, copper, manganese, and aluminum in mineral water, which do not cause much damage to human body, Chromium did not cause any problem below the drinking water quality standard value, but cadmium exceeded the drinking water standard value, but it was removed in the water treatment process, so it did not appear in the process result analysis result.

As shown in Table 5, the fact that the hydrogen ion concentration of the mineral water increased to pH 5.4 after the water treatment at the pH of 4.2, suggests that the amount of acidic alum and similar alum was decreased, In fact, the fact that aluminum ions in alum and alum are reduced from 244.95 mg / l to 15 mg / l and that the sulfate ion is reduced from 1950 mg / l to 1590 g / l, Was 4.73 mg / l, but it increased to 232 mg / l after the treatment.

This is because when Ca and Mg ions are adsorbed by adsorption of soda ash (soda-type geolite) deposited on the filtration bed, sodium ions are dissolved and dissolved in the mineral water from the gypsum, and sodium type kills It is believed that the sodium ion is increased by the adsorption of the heavy metal by the resin and the sodium ion is dissolved in the treatment water instead of the sodium ion, and the aluminized alum is reduced to the generated alum, and the sodium alum and aluminum sodium alum or X-ray diffraction analysis results showed that the similar alum was increased.

In addition, germanium was significantly reduced during mineral waters treatment and selenium was not detected.

In addition, PH of the process water treated by the filtration in the step 6 of Example 1 was 5.4, and the acidic alum and alum alum obtained from the Kimchi mineral water were added in order to enhance the effect of the hot water by the hot water bath or the hot water bath And pH is adjusted by adding PH 4 ~ 4.5 or concentrated water obtained by water treatment of mineral water.

Claims (4)

One-step process to control the inflow volume of mineral water so that a certain amount of inflowing mineral water can be treated continuously
A two-step process for oxidizing and decomposing heavy metal ions dissolved in mineral water by an ozone oxidation method using an ozone generator having a semiconductor ozone concentration of 4 to 6 wt%
Three-step process to aeration the mineral water that oxidizes and decomposes heavy metal ions
A four-step process of filtering the aeration water through an aeration-treated mineral water through a filtration tank of a filtration tank
5-step process for adsorbing and removing heavy metal ions by passing filtrated mineral water through a chelate ion-exchange resin
6 step process of filtering the mineral water passing through the chelate ion exchange resin through the first and second settling tank
A method of obtaining a hot bath water by treating natural mineral water including a seven-step process of obtaining hot bath water by adjusting the filtered mineral water PH to a range of 4.0 to 4.5
[Claim 4] The filtration apparatus of claim 1, wherein the filtration phase of the filtration tank is formed of a coarse sand bed of 3 to 5 mm, a soda-lime zeolite bed of 2 to 3 mm, and an artificial soil bed granulated to 3 to 5 mm, A method of obtaining hot water by treating natural mineral waters characterized by a filtration layer in which a plaster mat layer surrounded by a mesh fabric of a synthetic resin material can not come out
The chelating ion-exchange resin according to claim 1, wherein the chelate ion-exchange resin contains a tertiary amine and a carboxylic acid group and is used in a sodium form.
The method according to claim 1, wherein the pH of the process water is adjusted by adding a concentrate of the process water obtained by treating the alum and alum or mineral water produced from the mineral water to adjust PH, How to get

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