KR101879816B1 - Release paper and its manufacturing method - Google Patents

Abstract

The present invention relates to a release paper having excellent properties of preventing moisture penetration and curling reproduction by coating a solution based on polyvinyl alcohol (PVA) on a paper substrate layer, and an environmentally friendly release paper and a method for producing the same.
A release paper according to the present invention comprises a substrate layer; A first PVA resin layer coated on one surface of the substrate layer; A release layer coated on the upper surface of the first PVA resin layer; And a second PVA resin layer or a PE resin layer coated on the other surface of the base layer.
According to the present invention, it is possible to produce an economical release paper while maintaining the excellent curling prevention and moisture permeation prevention characteristics of the conventional two-sided PE coated release paper, and to provide environmentally friendly paper by reusing paper as a base layer through PVA resin coating. Can be produced.

Description

[0001] RELEASE PAPER AND ITS MANUFACTURING METHOD [0002]

More particularly, the present invention relates to a release paper and a method of manufacturing the same, and more particularly, to a paper-type release paper and a method of manufacturing the same which are excellent in moisture penetration prevention and curling reproduction prevention characteristics by coating a clay solution based on polyvinyl alcohol (PVA) And a method for producing the same.

Release paper is a paper that is attached to the back surface to protect the adhesive surface of the adhesive tape. It is used to protect the surface by contacting the adhesive surface of the adhesive tape, pressure-sensitive adhesive paper, label, The surface is machined to be.

As the release paper, a film or the like is used, and as the release material, silicon is generally used.

The releasing paper is attached to the adhesive tape or the adhesive sheet and is distributed or reworked so that no deformation such as expansion, shrinkage or distortion should occur.

However, due to the characteristics of paper sensitive to changes in humidity and temperature, deformation occurs when the release paper is not subjected to a separate process. This is referred to as curling, and studies for manufacturing release paper having excellent curl- It is going on.

In order to prevent curling of release paper, polyethylene (PE) resin is generally coated on the paper surface during the manufacturing process. The role of PE resin is as follows.

First, preventing the moisture penetration of the paper, which is the base of the release paper, to prevent deformation due to moisture penetration.

Second, the coarse top surface of the paper can be treated by eye dreaming to enable coating of the release material.

Third, the smoothness of the paper is increased to lower the defect rate in the manufacturing process and increase the production efficiency.

The releasing paper based on paper is a non-PE release paper which has not been subjected to the PE resin coating process according to the number of times of coating of the PE resin, a PE resin release process which has been subjected to the PE resin coating process only on the end face of the paper substrate, PE resin-coated double-sided PE release paper. Among these, releasing papers excellent in curling prevention and moisture permeation prevention are evaluated in the order of double-sided PE releasing paper, single-sided PE releasing paper, and non-PE releasing paper.

However, such double-sided PE release paper and single-sided PE release paper have a problem in that the coating process of the PE resin is necessarily required, leading to an increase in the cost of the release paper due to the increase in the manufacturing process and the increase of the raw material cost.

For this reason, as mentioned above, non-PE releasing paper or single-side PE releasing paper is applied in the market or field in spite of the excellent quality of the double-sided PE releasing paper in low-priced products. Therefore, although the double-sided PE release paper has good curling resistance and moisture-proofing property, it is in the market place due to high manufacturing cost.

Patent Registration No. 0315994 Published Patent Publication No. 2011-0016443

SUMMARY OF THE INVENTION It is an object of the present invention to provide an economical release paper and a method of manufacturing the same, while maintaining excellent curling prevention and moisture permeation prevention characteristics of the conventional double-sided PE coated release paper.

The present invention also provides a releasing paper which is capable of recycling paper as a substrate layer and imparting environment friendliness by coating a clay solution based on PVA in a pretreatment process of applying a releasing material to the surface of a paper substrate, .

A release paper according to an embodiment of the present invention includes a base layer; A first PVA resin layer coated on one surface of the substrate layer; A release layer coated on the upper surface of the first PVA resin layer; And a second PVA resin layer or a PE resin layer coated on the other surface of the base layer.

In the present invention, the first PVA resin layer may contain 50 to 75 wt% of PVA, 10 to 15 wt% of adhesive vinyl resin, 10 to 15 wt% of tin powder, 5 to 10.5 wt% of leveling agent, 0.5 to 5% by weight of glacial acetic acid, and a predetermined amount of distilled water.

At this time, the adhesive vinyl resin has a glass transition temperature (Tg) of 10 to 50 DEG C, and the leveling agent includes a surfactant containing a silicone resin as a matrix.

In the present invention, the first PVA resin layer is composed of a composition having a viscosity of 100 to 1000 cps, and the thickness of the first PVA resin layer is 5 to 20 탆.

In the present invention, the release layer comprises 60 to 80% by weight of cyclohexane, 5.5 to 15.5% by weight of silicone resin, 4.5 to 10.5% by weight of catalyst Pt, 0.5 to 3.5% by weight of defoamer and leveling agent .

In the present invention, the PE resin layer includes one selected from polyolefin (PO) resin, high density, low density, ultra low density polyethylene, polypropylene, or a mixture thereof.

In the present invention, the thickness of the PE resin layer is 10 to 40 占 퐉.

According to another aspect of the present invention, there is provided a method of manufacturing a release paper comprising: supplying a substrate layer; Coating a first PVA resin layer on one surface of the substrate layer; Coating a resin layer selected from the second PVA resin layer or the PE resin layer on the other surface of the substrate layer; And coating a release layer on one side of the first PVA resin layer.

In the present invention, the step of coating the first PVA resin layer may include a step of coating the first PVA resin layer with 50 to 75% by weight of PVA, 10 to 15% by weight of an adhesive vinyl resin, 10 to 15% 1 to 3 wt.%, Glacial acetic acid 0.5 to 5 wt.%, And distilled water to 100 to 1000 cps. The coating is applied to one surface of the substrate layer and then heated and dried at a predetermined temperature.

In the present invention, the thickness of the first PVA resin layer after drying is 5 to 20 占 퐉.

In the present invention, the step of coating the release layer comprises: 60 to 80% by weight of cyclohexane, 5.5 to 15.5% by weight of silicone resin, 4.5 to 10.5% by weight of catalyst Pt, a defoaming agent and a leveling agent 0.5 to 3.5% % By weight is applied to the upper surface of the first PVA resin layer and then heated and dried at a predetermined temperature for coating.

In the present invention, the step of coating the second PVA resin layer may include a step of coating the second PVA resin layer with 50 to 75% by weight of PVA, 10 to 15% by weight of an adhesive vinyl resin, 10 to 15% 1 to 3 wt.%, Glacial acetic acid 0.5 to 5 wt.%, And distilled water to 100 to 1000 cps. The coating is applied to one surface of the substrate layer and then heated and dried at a predetermined temperature.

In the present invention, the step of coating the PE resin layer may include: supplying a substrate layer coated with the first PVA resin layer on the substrate layer or one surface thereof; Coating the PE resin layer by supplying a PE resin to the other surface of the substrate layer while the substrate layer is cooled using the first cooling drum; And cooling the PE resin layer using a second cooling drum.

Here, the PE resin includes one selected from polyolefin (PO) resin, high density, low density, ultra low density polyethylene, and polypropylene, or a mixture thereof.

According to the present invention, it is possible to produce economical release paper while maintaining the excellent curling prevention and moisture permeation prevention characteristics of the conventional double-sided PE coated release paper.

In addition, the present invention makes it possible to recycle paper as a main substrate layer through PVA coating in a pretreatment process of coating a surface of a paper substrate with a releasing material, thereby producing a release paper imparting environment friendliness.

1 is a cross-sectional structural view of a release paper according to an embodiment of the present invention;
2 is a view showing a process of coating a PE resin layer in a release paper according to an embodiment of the present invention,
3 is a view illustrating a coating process of a PVA resin layer and a release layer in a release paper according to an embodiment of the present invention.

Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

Referring to FIG. 1, a release paper 100 according to an exemplary embodiment of the present invention includes a base layer 110, a first PVA resin layer 120 coated on one surface thereof, and a first PAV resin layer 120 A release layer 130 is formed on one surface. Also, a second PVA resin layer 140a or a PE resin layer 140b is selectively formed on the other surface of the substrate layer 110. [

The base layer 110 may be formed of paper, for example, a white paper or a paper of a specific color, and preferably a paper of a specific color depending on the application. In the present embodiment, the base layer 110 is not particularly limited, but its thickness is suitably about 50 to 200 mu m. If the thickness is less than 50 탆, it does not have a sufficient supporting force, and since the hardness is low, the self-durability of being damaged by folding or the like is inferior, and if it exceeds 200 탆, the weight of the release paper increases. Also, the base layer 110 is made of paper having excellent strength and excellent holding power. The kind of the paper is generally glassine paper or kraft paper. Preferably, a kraft paper having an economical price can be used in accordance with the purpose of the present invention. However, the present invention is not limited thereto.

The first PVA resin layer 120 is coated on one surface of the substrate layer 110. The process of coating a solution based on PVA is generally referred to as clay coating. The first PVA resin layer 120 smoothes the rough top surface of the base layer 110 to reduce the defective rate of the manufacturing process, thereby improving the manufacturing efficiency and enabling the coating process of the migration material composition.

The first PVA resin layer 120 is made of PVA as a base material and an adhesive resin is added to the base layer 110 to improve the adhesion of the first PVA resin layer 120. Specifically, 10 to 15 wt% of adhesive vinyl resin, 10 to 15 wt% of tin powder, 5 to 10.5 wt% of leveling agent, 1 to 3 wt% of catalyst, 0.5 to 5 wt% of glacial acetic acid and predetermined amount of distilled water do.

At this time, the glass transition temperature (Tg) of the adhesive vinyl resin is suitably in the range of 10 to 50 ° C. If the glass transition temperature (Tg) is out of this range, the adhesion between the first PVA resin layer 120 and the substrate layer 110 may be poor have. The leveling agent is preferably a surfactant using a silicone resin as a matrix, and it is preferable to inject the solvent so that the composition of the first PVA resin layer 120 has a viscosity of 100 to 1000 cps.

Here, the first PVA resin layer 120 is not particularly limited, but its thickness is preferably about 5 to 20 占 퐉. If the coating thickness is thinner than the above range, it is difficult to maintain the smoothness of the base layer 110. If the coating thickness is too small, the processing conditions become difficult and the workability is poor. .

A release layer 130 is formed on one surface of the first PVA resin layer 120. The release layer 130 comprises 60 to 80% by weight of cyclohexane, 5.5 to 15.5% by weight of silicone resin, 4.5 to 10.5% by weight of catalyst Pt, 0.5 to 3.5% by weight of defoamer and leveling agent Is applied on the upper surface of the first PVA resin layer 120 and is formed by heating and drying at a predetermined temperature.

Another resin layer 140 is formed on the other surface of the base layer 110. The resin layer 140 includes any one selected from the second PVA resin layer 140a and the PE resin layer 140b. At this time, the second PVA resin layer 140a or the PE resin layer 140b prevents water penetration into the base layer 110 to prevent deformation and curling of the paper.

The second PVA resin layer 140a coated on the other surface of the base layer 110 is formed through the same coating process with the same composition as the first PVA resin layer 120 coated on one surface of the base layer 110 .

As the PE resin layer 140b, a polyolefin resin (PO) having high chemical stability may be used, and high density polyethylene, low density polyethylene, ultra low density polyethylene, polypropylene or a mixture thereof may be used. The PE resin layer 140b is not particularly limited, but preferably has a thickness of about 10 to 40 占 퐉. More preferably 20 to 30 占 퐉 is advantageous. At this time, if the coating thickness of the PE resin layer 140b is thinner than the above range, it is difficult to maintain the smoothness of the base layer 110, It becomes difficult and workability is lowered, and the manufacturing cost is increased.

The first PVA resin layer 120 may be coated on one side of the substrate layer 110 and the second PVA resin layer 140a or the PE resin layer 140b may be coated on the other side The coating process may be carried out in any order. That is, the first PVA resin layer 120 may be coated on one side of the base layer 110, and then the second PVA resin layer 140a or the PE resin layer 140b may be coated on the other side. On the other hand, the first PVA resin layer 120 may be coated on one side of the substrate layer 110 after one of the second PVA resin layer 140a and the PE resin layer 140b is coated. The step of forming the release layer 130 on the first PVA resin layer 120 may be performed at any time after the first PVA resin layer 120 is coated and dried.

Hereinafter, the first PVA resin layer 120, the second PVA resin layer 140a, the PE resin layer 140b, and the release layer 130 of the release paper according to the embodiment of the present invention are described with reference to FIGS. Describe the formation process.

FIG. 2 is a view illustrating a PE resin coating process of release paper according to an embodiment of the present invention.

Referring to FIG. 2, paper for the base layer 110 is fed from the unwinder 10 to coat the PE resin layer 140b on the base layer 110 of the release paper 100. As the base layer 110, for example, grained paper or kraft paper may be used. Of course, as described above, the base layer 110 supplied from the unwinder 10 may be paper or coated with the first PVA resin layer 110 on one side thereof. This is a matter of coating order.

Thereafter, the base layer 110 is supplied with the PE resin for forming the PE resin layer 140b from the resin supply section 12 on the upper surface while being cooled while passing through the first cooling drum 11. The PE resin layer 140b is formed on the upper surface of the base layer 110 and finally wound on the winder 15 through the second cooling drum 13 and the plurality of aging drums 14 as required. The resin of the PE resin layer 140b may be a polyolefin (PO) resin, high density polyethylene, low density polyethylene, ultra low density polyethylene, polypropylene, or a mixture thereof.

3 is a view illustrating a PVA resin layer coating process and a release layer forming process of a release paper according to an embodiment of the present invention.

3, the PVA resin layer coating process may be performed by coating the first PVA resin layer 120 on one side of the substrate layer 110 or by forming a second PVA resin layer 140b on the other side of the substrate layer 110. [ Is applied to all the steps of coating the substrate. The base layer 110 is supplied from the unwinder portion 20 to coat the first PVA resin layer 120 or the second PVA resin layer 140b on the other surface of the base layer 110. [ At this time, as described above, the base layer 110 supplied in this way may be paper or may be coated with the PE resin layer 140b on the other surface. When the first PVA resin layer 120 is coated, the second PVA resin layer 140a may be already coated on the other surface.

The base layer 110 thus fed is conveyed to the coating section 22 through a plurality of guide rolls 21. In the coating portion 22, the composition of the first PVA resin layer 120 is coated on one side of the base layer 110. After the coating of the first PAV resin layer 120 is completed, the dried PAV resin layer 120 is transferred to the thermal drying unit 23 to be dried and cured. Then, it is wound around the winder 25 via the laminating part 24.

Herein, the same process can be repeated as described above in the process of coating the first PVA resin layer 120 on one side of the substrate layer 110 and the process of coating the second PVA resin layer 140a on the other side . In order to form the first PVA resin layer 120 and the second PVA resin layer 140a, the PVA resin composition is coated on the upper surface of the substrate layer 110 in the coating part 22, At a speed of 40 to 60 m / min and heated and dried at a temperature of 120 to 150 ° C., and the thickness of the first PVA resin layer 120 after drying is preferably about 5 to 20 μm. More preferably 10 to 15 占 퐉.

3, the release layer 130 may be coated on one surface of the first PVA resin layer 120. In this case, This is the same as the coating process of the first PVA resin layer 120 or the second PVA resin layer 140a. That is, the first PVA resin layer 120 and the second PVA resin layer 140a are formed on one side of the unwinder portion 20, the base layer 110 coated with the first PVA resin layer 120, Coated substrate layer 110 is supplied. The base layer 110 thus fed is conveyed to the coating section 22 through a plurality of guide rolls 21. In the coating portion 22, a composition for coating the release layer 130 is coated on the upper surface of the first PVA resin layer 120. [ When the coating of the release layer 130 is completed, the release layer 130 is conveyed to the heat drying unit 23 to be dried and cured, and then the final release paper is wound on the winder 25 via the laminating unit 24 do. This completes the manufacturing process of the release paper.

The composition of the release layer 130 is coated on the upper surface of the first PVA resin layer 120 in the coating section 22 to form the release layer 130 and then dried at 80 to 100 m / min, heated and dried at a temperature of 150 to 180 캜, and the thickness of the release layer 130 after drying is preferably 0.5 to 3 탆. If the thickness of the release layer 130 is less than 0.5 mu m, the holding performance of the releasing performance may be weakened and the peeling failure may occur. If the thickness exceeds 3 mu m, the processing efficiency is lowered and the working unit cost is increased.

Hereinafter, the present invention will be described in detail with reference to the following examples. It should be understood, however, that these examples are for the purpose of illustrating the present invention more clearly and do not limit the scope of protection of the present invention.

[ Example  One]

20 wt% of PVA, 20 wt% of adhesive vinyl resin (BASF, B15N), 15 wt% of tin powder, 5 wt% of a leveling agent (BYK Corp. BYK333), 3 wt% 2% by weight of glacial acetic acid, and an appropriate amount of distilled water were mixed, followed by thorough stirring using a stirrer for 2 hours to prepare a PVA coating layer composition.

The thus-prepared coating solution was coated on a kraft paper having a thickness of 140 탆 coated with PE resin on the back of the paper by a gravure coating method and dried for 3 minutes by hot air at 120 캜 to have a thickness of 15 탆, The composition was coated in a gravure manner to prepare a release paper. Two types of diced and two-sided dyed papers were produced (excellent in properties but increased in cost).

[ Example  2]

20 wt% of PVA, 20 wt% of adhesive vinyl resin (BASF, B15N), 15 wt% of tin powder, 5 wt% of a leveling agent (BYK Corp. BYK333), 3 wt% 2% by weight of glacial acetic acid, and an appropriate amount of distilled water were mixed, followed by thorough stirring using a stirrer for 2 hours to prepare a PVA coating layer composition.

The thus prepared coating solution was coated on the top, back and both sides of a kraft paper having a thickness of 140 탆 by a gravure coating method and dried for 3 minutes by hot air at 120 캜 to have a thickness of 15 탆. To prepare a release paper.

[ Comparative Example  One]

, 25 wt% of PVA, 25 wt% of adhesive vinyl resin (BASF, B15N), 5 wt% of a leveling agent (BYK Corp. BYK333), 3 wt% of a catalyst (vaso 56ws), 2 wt% And the mixture was thoroughly mixed using a stirrer for 2 hours to prepare a PVA coating layer composition.

The coating solution thus prepared was coated on a kraft paper having a thickness of 140 mu m which was not coated with a PE resin by a gravure coating method and dried for 3 minutes by hot air at 120 DEG C to give a thickness of 10 mu m. To prepare a release paper.

[ Comparative Example  2]

A releasing paper was prepared by coating a releasing composition on the top surface of a PE resin layer of a kraft paper having a thickness of 140 탆 coated with a PE resin by a gravure coating method.

[evaluation]

The release paper prepared according to Examples 1 to 2 and Comparative Example 1-2 was evaluated for the recurrence of the curling phenomenon and the moisture barrier property. The results of evaluating the curling phenomenon of these release sheets are shown in Table 1 below.

1) Evaluation of release paper alone

The specimens of Examples 1 and 2 and Comparative Examples 1 and 2 were cut into A4 size, cross-cut in a cross shape, and then allowed to stand for 24 hours at 60 ° C / 90% temperature and humidity. Take out the retained specimen and visually observe the occurrence of curling with the naked eye.

2) Evaluation after adhesion sheet

The specimens of Examples 1 and 2 and Comparative Examples 1 and 2 were attached to a pressure-sensitive adhesive sheet, and then they were allowed to stand for 24 hours in a constant-temperature and humidity chamber at 60 ° C / 90%. Take out the retained specimen and visually observe the occurrence of curling with the naked eye.

3) Evaluation of moisture penetration prevention characteristics

The specimens of Examples 1 and 2 and Comparative Examples 1 and 2 were attached to a pressure-sensitive adhesive sheet, and then they were allowed to stand for 24 hours in a constant-temperature and humidity chamber at 60 ° C / 90%. The retained specimen was taken out and the weight increment of the specimen was measured.

division Example 1 Example 2 Comparative Example 1 Comparative Example 2 Evaluation of release paper alone Not occurring Not occurring Occur Occur Evaluation of adhesion sheet Not occurring Not occurring Occur Occur Moisture penetration prevention property evaluation 2.4 g 3.1 g 5.9 g 9.8 g

As shown in Table 1, the release paper according to Examples 1 and 2 had excellent curling resistance and moisture permeation prevention properties as compared with Comparative Examples 1 and 2.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, Of course.

It is to be understood that the terms "comprises", "comprising", "having", and the like as used herein to describe the embodiments of the present invention are meant to imply that the components are inherent unless otherwise stated , It is to be understood that the present invention can include other components than the other components. All terms, including technical and scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs, unless otherwise defined. Commonly used terms, such as predefined terms, should be interpreted to be consistent with the contextual meanings of the related art, and are not to be construed as ideal or overly formal, unless expressly defined to the contrary.

The foregoing description is merely illustrative of the technical idea of the present invention, and various changes and modifications may be made by those skilled in the art without departing from the essential characteristics of the present invention. Therefore, the embodiments disclosed in the present invention are intended to illustrate rather than limit the scope of the present invention, and the scope of the technical idea of the present invention is not limited by these embodiments. The scope of protection of the present invention should be construed according to the following claims, and all technical ideas within the scope of equivalents should be construed as falling within the scope of the present invention.

110: base layer 120: first PVA resin layer
130: release layer 140a: second PVA resin layer
140b: PE resin layer

Claims (16)

A base material layer made of paper having a thickness of 50 to 200 mu m;
10 to 15% by weight of an adhesive vinyl resin having a PVA of 50 to 70% by weight and a glass transition temperature (Tg) of 10 to 50 ° C, 10 to 15% by weight of a strontium powder and a surfactant containing a silicone resin as a matrix 5 to 10.5% by weight of a catalyst, 1 to 3% by weight of a catalyst, 0.5 to 5% by weight of glacial acetic acid, and a predetermined amount of distilled water, wherein a viscosity of 100 to 1000 cps and a thickness A first PVA resin layer coated with the first PVA resin;
A mixture comprising 60 to 80% by weight of a cyclohexane, 5.5 to 15.5% by weight of a silicone resin, 4.5 to 10.5% by weight of a platinum (Pt) catalyst, 0.5 to 3.5% by weight of a defoaming agent and a leveling agent, A release layer coated on the upper surface of the PVA resin layer to a thickness of 0.5 to 3 탆; And
And a second PVA resin layer coated on the other surface of the base layer with the same component, viscosity and thickness as the first PVA resin layer. delete delete delete delete delete delete delete delete Supplying a substrate layer of paper having a thickness of 50 to 200 占 퐉;
Wherein 10 to 15% by weight of an adhesive vinyl resin having a PVA of 50 to 70% by weight and a glass transition temperature (Tg) of 10 to 50 ° C, 10 to 15% by weight of a tin powder, A first PVA resin layer made of a mixture containing 5 to 10.5% by weight of a leveling agent containing an activator, 1 to 3% by weight of a catalyst, 0.5 to 5% by weight of glacial acetic acid and a predetermined amount of distilled water is mixed with 100 to 1000 cps in viscosity, To 15 占 퐉, and heating and drying at a temperature of 120 to 150 占 폚 and a moving speed of 40 to 60 m / min for coating;
Coating a second PVA resin layer on the other surface of the substrate layer under the same conditions as the first PVA resin layer; And
Wherein the first PVA resin layer comprises 60 to 80 wt% of cyclohexane, 5.5 to 15.5 wt% of silicon resin, 4.5 to 10.5 wt% of a platinum (Pt) catalyst, 0.5 to 3.5 wt% of a defoaming agent and a leveling agent, To a thickness of 0.5 to 3 탆, and heating and drying at a temperature of 150 to 180 캜 at a moving speed of 80 to 100 m / min to coat the releasing layer. delete delete delete delete delete delete

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