KR100269772B1 - A transfer film and process for preparing thesame - Google Patents

A transfer film and process for preparing thesame Download PDF

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Publication number
KR100269772B1
KR100269772B1 KR1019980011085A KR19980011085A KR100269772B1 KR 100269772 B1 KR100269772 B1 KR 100269772B1 KR 1019980011085 A KR1019980011085 A KR 1019980011085A KR 19980011085 A KR19980011085 A KR 19980011085A KR 100269772 B1 KR100269772 B1 KR 100269772B1
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transfer
transfer film
film layer
film
thickness
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KR1019980011085A
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Korean (ko)
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KR19980019569A (en
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김명완
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백유현
주식회사예문테크
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/175Transfer using solvent
    • B44C1/1756Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive

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  • Decoration By Transfer Pictures (AREA)

Abstract

PURPOSE: Provided is a transfer film for uneven surfaces of various types of patterns such as steel, aluminum, plastic, ceramic, rubber, or glass, which has good qualities in resistance to alkali, hardness, and thickness. CONSTITUTION: A method for preparing a transfer film for uneven surfaces of various types of patterns comprises the steps of: (i) combining against main film layer water 40-60%, polyvinylalcohol 22.5-33.5%, starch 8-12%, sugar 2-4%, soap 3-7%, glue 1-3%, latex 3-7%, and silicon oil 0.5-2%, melting at 80-100 deg.C, extruding at 5m/min speed through a roller of 20-100μm thickness, drying with hot air of 60-80deg.C and cooling with cool wind; (ii) printing patterns on the main film layer through gravure, offset or silk screen method; and (iii) coating the printed transfer film with transparent paint, lacquer, primer or resin.

Description

다양한 문양의 요철면용 전사필름 및 그의 제조방법Transfer film for uneven surface of various patterns and manufacturing method thereof

본 발명은 다양한 재료의 요철면위에 다양한 문양을 전사할 수 있는 전사필름 및 그의 제조방법에 관한 것이다. 좀 더 구체적으로, 본 발명은 철, 알루미늄, 플라스틱, 세라믹, 고무 및 유리 등의 다양한 요철면에 다양한 문양을 전사할 수 있는 전사필름 및 그의 제조방법에 관한 것이다.The present invention relates to a transfer film and a method for manufacturing the same, which can transfer various patterns on irregularities of various materials. More specifically, the present invention relates to a transfer film capable of transferring various patterns to various uneven surfaces such as iron, aluminum, plastic, ceramic, rubber and glass, and a method of manufacturing the same.

종래의 전사필름에는 시이트상에 박리층, 보호층, 인쇄층 및 접착층이 차례로 적층된 전사필름(참조: 일본 특허공개 제 9-58196)과, 시이트에 박리성 도료의 이형층, 인쇄층, 은폐층 및 접착제층이 차례로 적층하여 형성한 전사필름(참조: 일본 특허공개 제 7-47798호); 및, 수지층, 이형층, 보호프라이마층 및 인쇄층이 차례로 적층된 전사필름(참조: 대한민국 특허공고 제 96-2721호) 등이 알려져 있다. 따라서, 종래의 이러한 전사필름은 베이스층, 이형층, 인쇄층 및 접착제층 등으로 이루어져 있으므로, 수전사시 박리공정이 복잡하며, 열전사시에는 요철면위에 의도하는 문양의 전사가 쉽게 이루어지지 않는 문제점이 있었다. 더구나, 종래의 전사필름은 도막밀착성, 연필경도, 도막두께 및 내알칼리성 등 전사필름으로서의 물성이 열악하여, 산업적으로 응용되는데는 한계가 있었다.Conventional transfer films include transfer films (see Japanese Patent Application Laid-Open No. 9-58196), in which a release layer, a protective layer, a print layer, and an adhesive layer are sequentially stacked on a sheet, and a release layer, a print layer, and a concealment of a release coating on the sheet. A transfer film formed by laminating layers and an adhesive layer in turn (see Japanese Patent Laid-Open No. 7-47798); And transfer films (refer to Korean Patent Publication No. 96-2721) in which a resin layer, a release layer, a protective primer layer, and a printing layer are sequentially stacked are known. Therefore, the conventional transfer film is composed of a base layer, a release layer, a printing layer and an adhesive layer, so that the peeling process is complicated during water transfer, and the transfer of the intended pattern on the uneven surface during heat transfer is not easy. There was this. In addition, the conventional transfer film is poor in physical properties as a transfer film, such as coating film adhesion, pencil hardness, coating film thickness and alkali resistance, there was a limit to industrial applications.

이에, 본 발명자들은 다양한 문양을 어떠한 요철면이라도 간단하게 전사할 수 있는 전사필름을 개발하기 위하여 예의 연구 노력한 결과, 물, 폴리비닐알콜 및 전분을 주성분으로 하고, 설탕, 비누, 아교, 라텍스 및 실리콘오일을 함유하는 전사필름이 종래기술의 단점을 해결할 수 있는 우수한 물성을 가짐을 확인하고, 본 발명을 완성하게 되었다.Accordingly, the present inventors have diligently researched to develop a transfer film that can easily transfer various patterns to any uneven surface. As a result, water, polyvinyl alcohol and starch are the main ingredients, and sugar, soap, glue, latex and silicone. It was confirmed that the transfer film containing oil has excellent physical properties that can solve the disadvantages of the prior art, and completed the present invention.

결국, 본 발명의 목적은 다양한 문양을 다양한 요철면위에 효율적으로 전사할 수 있는 전사필름을 제공하는 것이다.After all, it is an object of the present invention to provide a transfer film capable of efficiently transferring various patterns on various irregularities.

본 발명의 다른 목적은 전기 전사필름의 제조방법을 제공하는 것이다.Another object of the present invention is to provide a method for producing an electrolytic transfer film.

도 1은 본 발명의 전사필름의 확대 종단면도.1 is an enlarged longitudinal sectional view of the transfer film of the present invention.

<도면의 주요 부분에 대한 부호의 설명><Description of the code | symbol about the principal part of drawing>

1....주필름층 2....인쇄층 3....유연성코팅층1 .... main film layer 2 .... printing layer 3 .... flexible coating layer

본 발명의 전사필름은 도 1에서 보듯이, 주필름층(1)을 기본으로 하고, 그 위에 인쇄층(2) 및 유연성코팅층(3)을 구성하여 이루어진다.As shown in Figure 1, the transfer film of the present invention is based on the main film layer (1), it is made by configuring a printing layer (2) and a flexible coating layer (3) thereon.

본 발명의 주필름층(1)은 제조된 주필름층(1)의 전체 중량에 대하여, 물 40 내지 60%, 폴리비닐알콜(polyvinylalcohol, PVA) 22.5 내지 33.5%, 전분 8 내지 12%을 함유하고, 이에, 설탕 2 내지 4%, 비누 3 내지 7%, 아교 1 내지 3%, 라텍스 3 내지 7% 및 실리콘오일 0.5 내지 2%를 추가로 함유하여 제조하는데, 주필름층은 인쇄된 문양을 지지하는 역할을 한다. 전기 주필름층(1)에서 물, 폴리비닐알콜 및 전분은 주필름층의 베이스를 이루며, 설탕, 비누, 아교, 라텍스의 경우는 전사시, 인쇄된 문양의 흐트러짐을 방지하고 실리콘오일의 경우는 이형작용을 목적으로 첨가한다. 인쇄층(2)은 전기 주필름층(1)에 통상의 그라비어, 옵셋 또는 실크스크린 인쇄방법으로 목적하는 문양을 형성하며, 바람직하게는 아크릴계 잉크를 사용하여 인쇄한다. 한편, 유연성코팅층(3)은 문양의 인쇄가 없는 곳에 문양과 문양사이를 흐트러지지 않게 지지하고, 전사하고자 하는 목적물에의 접착성을 향상시킴에 그 목적이 있으며, 목적물에 따라 투명 페인트, 락카, 프라이마 또는 수지로 코팅한다.The main film layer 1 of the present invention contains 40 to 60% water, 22.5 to 33.5% polyvinyl alcohol (polyvinylalcohol (PVA)), and 8 to 12% starch, based on the total weight of the manufactured main film layer 1 In addition, it is prepared by additionally containing 2 to 4% of sugar, 3 to 7% of soap, 1 to 3% of glue, 3 to 7% of latex, and 0.5 to 2% of silicone oil. Play a supportive role. In the main film layer (1), water, polyvinyl alcohol and starch form the base of the main film layer, and in the case of sugar, soap, glue, and latex, it prevents the printed pattern from being disturbed during transfer and in the case of silicone oil Add for release. The printing layer 2 forms the desired pattern on the main film layer 1 by a conventional gravure, offset or silkscreen printing method, and is preferably printed using acrylic ink. On the other hand, the flexible coating layer 3 is to support the pattern between the pattern and the pattern undisturbed where there is no printing of the pattern, and to improve the adhesiveness to the object to be transferred, the purpose of the transparent paint, lacquer, Coated with prima or resin.

이하에서는, 본 발명에 의한 전사필름의 제조방법을 공정별로 나누어 보다 구체적으로 설명하고자 한다.Hereinafter, the manufacturing method of the transfer film according to the present invention will be described in more detail by dividing the process.

제 1공정: 주필름층의 제조First step: manufacturing the main film layer

주필름층의 중량에 대하여, 물 40 내지 60%, 폴리비닐알콜(polyvinyl alcohol, PVA) 22.5 내지 33.5, 전분 8 내지 12%, 설탕 2 내지 4%, 비누 3 내지 7%, 아교 1 내지 3%, 라텍스 3 내지 7% 및 실리콘오일 0.5 내지 2%를 배합하여 80 내지 100℃, 가장 바람직하게는 약 100℃에서 용해시킨 후, 두께 약 20 내지 100㎛으로 롤러에 넣고 3 내지 5m/min의 속도로 압인출하여 60 내지 80℃의 열풍조건에서 건조시키고 냉풍으로 냉각시킨다.40 to 60% of water, polyvinyl alcohol (PVA) 22.5 to 33.5, starch 8 to 12%, sugar 2 to 4%, soap 3 to 7%, glue 1 to 3% by weight of the main film layer , 3 to 7% of latex and 0.5 to 2% of silicone oil were mixed and dissolved at 80 to 100 ° C., most preferably about 100 ° C., and then put into a roller at a thickness of about 20 to 100 μm and a speed of 3 to 5 m / min. It is drawn out by using a hot air and dried under hot air conditions of 60 to 80 ℃ and cooled by cold air.

제 2공정: 인쇄Second Process: Printing

전기 제 1공정에서 제조된 주필름층에 당업계에서 통상의 그라비어, 옵셋 또는 실크스크린 인쇄방법으로 목적하는 문양의 인쇄를 한다. 이때, 인쇄 잉크로는 전사대상 물질에 따라 다르나, 일반적으로 아크릴계 잉크를 사용한다.The main film layer produced in the first step is printed with the desired pattern by gravure, offset or silkscreen printing methods conventional in the art. In this case, although the printing ink depends on the material to be transferred, acrylic ink is generally used.

제 3공정: 유연성코팅Third Step: Flexible Coating

전기 제 2공정에서 인쇄된 전사필름에 철, 알루미늄, 플라스틱, 세라믹, 고무 또는 유리 등의 전사시키고자 하는 목적물에 따라, 페인트 또는 수지 등의 유연성 물질을 롤러에 도말한 후, 제 1공정에서와 같은 방법으로 롤러를 이용하여 코팅한다.According to the object to be transferred such as iron, aluminum, plastic, ceramic, rubber or glass to the transfer film printed in the second process, after coating a flexible material such as paint or resin onto the roller, In the same way it is coated using a roller.

본 발명의 전사용 필름은 당업계의 통상의 수전사 또는 열전사 방법에 따라, 전사시키고자 하는 목적물에 전사시켜 인쇄하거나, 보다 바람직하게는 본 출원과 동일자 출원하는 『열팽창 흡착을 이용한 다양한 문양의 전사방법』에 개시된 방법에 따라 인쇄한다.The transfer film of the present invention may be transferred and printed on the target object to be transferred according to the conventional water transfer or thermal transfer method in the art, or more preferably, “A variety of patterns using thermal expansion adsorption, which is the same as the present application. Printing according to the method disclosed in &quot; Transfer method. &Quot;

이하, 실시예에 의하여 본 발명을 보다 구체적으로 설명하고자 한다.Hereinafter, the present invention will be described in more detail with reference to Examples.

이들 실시예는 오로지 본 발명을 설명하기 위한 것으로, 본 발명의 요지에 따라 본 발명의 범위가 이들 실시예에 국한되지 않는다는 것은, 당업계에서 통상의 지식을 가진 자에게 있어서 자명할 것이다.These examples are only for illustrating the present invention, and it will be apparent to those skilled in the art that the scope of the present invention is not limited to these examples according to the gist of the present invention.

실시예 1: 전사필름의 제조 및 알루미늄 요철면에 원목문양의 수전사Example 1 Preparation of Transfer Film and Water Transfer of Wood Pattern on Uneven Surface of Aluminum

주필름층의 중량에 대하여, 물 50%, 폴리비닐알콜(polyvinylalcohol, PVA) 24%, 전분 10%, 설탕 3%, 비누 5%, 아교 2%, 라텍스 5% 및 실리콘오일 1%를 배합하여 100℃에서 용해시킨 후, 두께 약 48㎛으로 롤러에 넣고 4m/min의 속도로 압인출하여 70℃의 열풍조건에서 건조시키고 냉풍으로 냉각시켜 주필름층을 제조하였다. 그런 다음, 그라비어 인쇄방법으로 원목문양을 인쇄하여 아크릴 수지로 코팅처리한 전사필름을 수득하였다. 전기에서 제조된 전사필름을 수조위에 띄우고, 목적하는 알루미늄을 서서히 입수시켜 액압에 의해 전사시켰다.50% water, 24% polyvinylalcohol (PVA), 10% starch, 3% sugar, 5% soap, 2% glue, 5% latex and 1% silicone oil After dissolving at 100 ° C., the resultant was placed on a roller with a thickness of about 48 μm, pressed out at a speed of 4 m / min, dried under hot air conditions of 70 ° C., and cooled by cold air to prepare a main film layer. Then, the wood pattern was printed by a gravure printing method to obtain a transfer film coated with an acrylic resin. The transfer film produced in the former was floated on a water tank, and the desired aluminum was gradually obtained and transferred by hydraulic pressure.

실시예 2: 전사필름의 제조 및 강철 요철면에 원목문양의 열팽창 흡착전사Example 2 Preparation of Transfer Film and Thermal Expansion Adsorption Transfer of Wood Pattern on Uneven Steel Surface

주필름층의 중량에 대하여, 물 45%, 폴리비닐알콜 29%, 전분 10%, 설탕 3%, 비누 5%, 아교 2%, 라텍스 5% 및 실리콘오일 1%를 배합하여 100℃에서 용해시킨 후, 두께 약 80㎛으로 롤러에 넣고 4m/min의 속도로 압인출하여 75℃의 열풍조건에서 건조시키고 냉풍으로 냉각시켜 주필름층을 제조하였다. 그런 다음, 그라비어 인쇄방법으로 원목문양을 인쇄하여 전사필름을 제조하였다. 목적하는 강철의 요철면을 위로 하여 열전사 장치안에 올려 놓고 전기의 전사필름을 그 위에 세팅한 후, 약 120℃의 열풍으로 약 1.5배 팽창된 전사필름을 흡착기를 작동시켜 강철에 부착시켰다. 완전히 부착된 것을 확인하고, 강철을 꺼내고 냉풍으로 냉각시켜 전사시켰다.45% of water, 29% of polyvinyl alcohol, 10% of starch, 3% of sugar, 5% of soap, 2% of glue, 5% of latex and 1% of silicone oil were mixed and dissolved at 100 ° C based on the weight of the main film layer. Thereafter, the resultant was placed in a roller having a thickness of about 80 μm, press-drawn at a speed of 4 m / min, dried under hot air conditions at 75 ° C., and cooled by cold air to prepare a main film layer. Then, the wood pattern was printed by the gravure printing method to prepare a transfer film. After placing the uneven surface of the desired steel in the thermal transfer apparatus and setting the transfer film thereon, the transfer film expanded about 1.5 times with hot air at about 120 ° C. was attached to the steel by operating an adsorber. Confirmed that it was completely attached, the steel was taken out and cooled by cold air to be transferred.

전사필름의 물성시험Physical property test of transfer film

본 발명의 실시예 1에서 제조된 전사필름과 종래기술의 전사필름을 사용하여 알루미늄 목적물에 실시예 1의 수전사 방법으로 우드문양을 전사한 다음, 전사된 상태의 전사필름의 도막밀착성, 연필경도, 도막두께 및 내 알칼리성을 측정하였으며, 그 결과를 하기 표 1에 나타내었다. 전기에서, 종래의 전사필름은 폴리에스테르(PE, polyester) 베이스에 풀 도막을 형성한 후, 글라비아 인쇄방법으로 우드문양을 인쇄하고, 투명라카로 도장하여 제조하였다.Using the transfer film prepared in Example 1 of the present invention and the transfer film of the prior art, the wood pattern is transferred to the aluminum object by the method of transfer of water in Example 1, and then the coating film adhesion and pencil hardness of the transferred film in the transferred state. , Coating thickness and alkali resistance were measured, and the results are shown in Table 1 below. In the former, the conventional transfer film was formed by forming a full coating film on a polyester (PE, polyester) base, and then printed a wood pattern by the gravure printing method, and coated with a transparent laca.

본 발명의 전사필름과 종래의 전사필름의 물성 비교Comparison of properties of transfer film of the present invention and conventional transfer film 시 험 항 목Test Items 시 험 결 과Test result 본 발명The present invention 종래 기술Prior art 도막밀착성Film adhesion 100/100100/100 65/10065/100 연 필 경 도Pencil hardness 2H2H 2H2H 도막두께(㎛)Coating thickness (㎛) 4848 190190 내알칼리성Alkali resistance 색 및 광택의 변화, 부풀음, 박리 등 없음No change in color and gloss, swelling, peeling, etc. 색 및 광택의 변화, 부풀음, 박리 등 없음No change in color and gloss, swelling, peeling, etc. 시 험 방 법Test Methods KS D 6711-92KS D 6711-92

* 한국생활용품시험연구원 시험성적서* Test report of Korea Household Products Testing Institute

상기 표 1에서 보듯이, 본 발명의 전사필름은 내알칼리성 및 연필경도에서는 종래의 필름과 동일하였으나, 도막두께는 얇게 제조될 수 있으므로 상품성이 제고됨을 알 수 있었으며, 도막밀착성 또한 종래의 필름에 대하여 우수하였다.As shown in Table 1, the transfer film of the present invention was the same as the conventional film in the alkali resistance and pencil hardness, it can be seen that the coating film thickness can be manufactured to improve the commercial property, the coating film adhesion also for the conventional film Excellent.

이상에서 상세히 설명하고 입증하였듯이, 본 발명은 철, 알루미늄, 플라스틱, 세라믹, 고무 및 유리 등의 다양한 요철면에 다양한 문양을 효율적으로 전사할 수 있는 전사필름 및 그의 제조방법을 제공한다. 본 발명의 전사필름은 내알칼리서, 연필경도, 도막두께 및 내알칼리성 등의 물성에서 우수한 성질을 나타내었으므로, 철, 알루미늄, 플라스틱, 세라믹, 고무 및 유리 등을 전사하는데 널리 이용될 수 있을 것이다.As described and demonstrated in detail above, the present invention provides a transfer film and a method for manufacturing the same, which can efficiently transfer various patterns on various uneven surfaces such as iron, aluminum, plastic, ceramic, rubber, and glass. Since the transfer film of the present invention has excellent properties in physical properties such as alkali resistance, pencil hardness, coating thickness, and alkali resistance, it may be widely used for transferring iron, aluminum, plastic, ceramic, rubber, glass, and the like. .

Claims (2)

(ⅰ) 주필름층의 중량에 대하여, 물 40 내지 60%, 폴리비닐알콜(polyvinylalcohol, PVA) 22.5 내지 33.5%, 전분 8 내지 12%, 설탕 2 내지 4%, 비누 3 내지 7%, 아교 1 내지 3%, 라텍스 3 내지 7% 및 실리콘오일 0.5 내지 2%를 배합하여 80 내지 100℃에서 용해시킨 후, 두께 약 20 내지 100㎛으로 롤러에 넣고 3 내지 5m/min의 속도로 압인출하여 60 내지 80℃의 열풍조건에서 건조시키고 냉풍으로 냉각시키는 공정;(Iii) 40 to 60% of water, 22.5 to 33.5% of polyvinylalcohol (PVA), 8 to 12% of starch, 2 to 4% of sugar, 3 to 7% of soap, glue 1 based on the weight of the main film layer 3% to 3%, latex 3 to 7% and silicone oil 0.5 to 2% were mixed and dissolved at 80 to 100 ° C., put into a roller at a thickness of about 20 to 100 μm, and withdrawn at a speed of 3 to 5 m / min to 60 Drying in hot air conditions of 80 ° C. to 80 ° C. and cooling with cold air; (ⅱ) 전기 주필름층에 그라비어, 옵셋 또는 실크스크린 인쇄방법으로 목적하는 문양을 인쇄하는 공정; 및,(Ii) printing a desired pattern on the electric main film layer by a gravure, offset or silkscreen printing method; And, (ⅲ) 전기 인쇄된 전사필름에 투명 페인트, 락카, 프라이마 또는 수지의 유연성 물질을 코팅하는 공정을 포함하는 전사필름의 제조방법.(Iii) A method of manufacturing a transfer film, comprising the step of coating a flexible material of transparent paint, lacquer, prima or resin on the electroprinted transfer film. 주필름층의 중량에 대하여, 물 40 내지 60%, 폴리비닐알콜(polyvinyl alcohol, PVA) 22.5 내지 33.5%, 전분 8 내지 12%, 설탕 2 내지 4%, 비누 3 내지 7%, 아교 1 내지 3%, 라텍스 3 내지 7% 및 실리콘오일 0.5 내지 2%를 배합하여 80 내지 100℃에서 용해시킨 후, 두께 약 20 내지 100㎛으로 롤러에 넣고 3 내지 5m/min의 속도로 압인출하여 60 내지 80℃의 열풍조건에서 건조시키고 냉풍으로 냉각시킨 주필름층에 그라비어, 옵셋 또는 실크스크린 인쇄 방법으로 목적하는 문양의 인쇄한 후에, 투명 페인트, 락카, 프라이마 또는 수지의유연성 물질을 코팅하여 제조된 전사필름.40 to 60% of water, polyvinyl alcohol (PVA) 22.5 to 33.5%, starch 8 to 12%, sugar 2 to 4%, soap 3 to 7%, glue 1 to 3, based on the weight of the main film layer %, Latex 3 to 7% and silicone oil 0.5 to 2% were mixed and dissolved at 80 to 100 ° C., put into a roller with a thickness of about 20 to 100 μm, and withdrawn at a speed of 3 to 5 m / min to 60 to 80 After transfer of the desired pattern by gravure, offset or silkscreen printing on the main film layer dried under hot air condition and cooled by cold air, transfer prepared by coating a flexible material of transparent paint, lacquer, prima or resin film.
KR1019980011085A 1998-03-30 1998-03-30 A transfer film and process for preparing thesame KR100269772B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6428647B1 (en) 1999-09-28 2002-08-06 Yemoon Tech Co., Ltd. Organic solvent composition for film transfer and a method for wet transferring of transfer film
KR100903354B1 (en) 2007-10-24 2009-06-22 주식회사 엘지생활건강 Transparent substrates and method for coating back side thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115349805A (en) * 2022-07-25 2022-11-18 东莞市雅力德科技有限公司 Adhesive rolling brush and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6428647B1 (en) 1999-09-28 2002-08-06 Yemoon Tech Co., Ltd. Organic solvent composition for film transfer and a method for wet transferring of transfer film
KR100903354B1 (en) 2007-10-24 2009-06-22 주식회사 엘지생활건강 Transparent substrates and method for coating back side thereof

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