KR101864983B1 - Supercritical CO2 power generating system - Google Patents
Supercritical CO2 power generating system Download PDFInfo
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- KR101864983B1 KR101864983B1 KR1020170010866A KR20170010866A KR101864983B1 KR 101864983 B1 KR101864983 B1 KR 101864983B1 KR 1020170010866 A KR1020170010866 A KR 1020170010866A KR 20170010866 A KR20170010866 A KR 20170010866A KR 101864983 B1 KR101864983 B1 KR 101864983B1
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- working fluid
- recuperator
- supplied
- pump
- heat exchanger
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
- F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
- F01K25/10—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
- F01K25/103—Carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K3/00—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
- F01K3/18—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein having heaters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K7/00—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating
- F01K7/32—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines using steam of critical or overcritical pressure
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Abstract
Description
The present invention relates to a supercritical carbon dioxide power generation system, and more particularly, to a supercritical carbon dioxide power generation system capable of improving heat exchange efficiency and cycle efficiency.
Internationally, there is a growing need for efficient power generation. As the movement to reduce the generation of pollutants is becoming more and more active, various efforts are being made to increase the production of electricity while reducing the generation of pollutants. Research and development of a supercritical carbon dioxide power generation system using supercritical carbon dioxide as a working fluid has been promoted as disclosed in Registration No. 8869531. [
Since supercritical carbon dioxide has a gas-like viscosity at a density similar to that of a liquid state, it can minimize the power consumption required for compression and circulation of the fluid as well as miniaturization of the apparatus. At the same time, the critical point is 31.4 degrees Celsius, 72.8 atmospheres, and the critical point is much lower than the water at 373.95 degrees Celsius and 217.7 atmospheres, which is easy to handle. The supercritical carbon dioxide power generation system has a net generation efficiency of about 45% when operated at a temperature of 550 ° C. and has an advantage of improving the generation efficiency of the steam cycle by 20% or more and reducing the turbo device.
The conventional supercritical carbon dioxide power generation system as described above has one external heat exchanger that receives heat from an external heat source and heats the working fluid. However, when the number of external heat exchangers is one, the working fluid flow rate of the high temperature recuperator and the working fluid flow rate of the external heat exchanger can not be efficiently distributed, which is inefficient in terms of heat exchange.
It is an object of the present invention to provide a supercritical carbon dioxide power generation system capable of improving heat exchange efficiency and cycle efficiency.
A supercritical carbon dioxide power generation system of the present invention is an RCBC (Recompression Closed Bray Cycle) for recompressing a working fluid among supercritical carbon dioxide power generation systems in which supercritical carbon dioxide is used as a working fluid to produce electric energy, A plurality of recuperators for firstly heating the working fluid that has passed through the pump and a plurality of heat exchangers for reheating the working fluid heated by the recuperator using the waste heat as a heat source, A turbine for driving the pump and the generator, the turbine being connected to the tiller, the pump, and the generator for producing the electric energy in a single shaft, and a heat exchanger for supplying heat to the working fluid through the pump after being supplied to the recuperator And a condenser for cooling the working fluid cooled by the circulation pump On side liqueur and a portion of the working fluid supplied to the buffer radar it characterized in that the heating branches of any one of the heat exchanger.
And the working fluid heated by branching to any one of the heat exchangers is supplied to a front end of the high temperature side recuperator and mixed with the working fluid passed through the pump.
And the working fluid is branched from a downstream end of the low temperature side pump of the pump and is supplied to any one of the heat exchangers.
The working fluid branched from the low temperature side pump and supplied to the low temperature side recuperator of the recuperator is mixed with the working fluid passed through the pump at the front end of the point where the working fluid heated in the heat exchanger is mixed, .
And the working fluid heated by branching to any one of the heat exchangers is supplied to the rear end of the high temperature side recuperator and mixed with the working fluid passed through the high temperature side recuperator.
And the working fluid is branched at a front end of the recuperator and supplied to one of the heat exchangers.
And the working fluid passing through the high temperature side recuperator is supplied to another one of the heat exchangers and reheated and then supplied to the turbine.
The heat exchanger may include any one of a high temperature heat exchanger that performs heat exchange with the high temperature waste heat gas, a medium temperature heat exchanger that performs heat exchange with the middle or low temperature waste gas, or a low temperature heat exchanger.
And the working fluid passing through the high temperature side recuperator is supplied to the high temperature heat exchanger.
And the working fluid branched to any one of the heat exchangers is branched into the mesothermal heat exchanger or the low temperature heat exchanger.
The present invention also relates to a recompression closed cycle cycle (RCBC) system for recompressing the working fluid in a supercritical carbon dioxide power generation system in which supercritical carbon dioxide is used as a working fluid to produce electric energy, Two recuperators for sequentially heating the working fluid that has passed through the pump, a plurality of heat exchangers for reheating the working fluid heated by the recuperator using waste heat as a heat source, A second turbine for driving the pump, a second turbine for driving the pump, a heat exchanger for exchanging heat with the working fluid that has been supplied to the recuperator through the turbine and then through the pump, And a condenser for cooling the working fluid, wherein the high- A portion of the working fluid supplied to is characterized in that the heating branches of any one of the heat exchanger.
And the working fluid heated by branching to any one of the heat exchangers is supplied to a front end of the high temperature side recuperator and mixed with the working fluid passed through the pump.
And the working fluid is branched from a downstream end of the low temperature side pump of the pump and is supplied to any one of the heat exchangers.
The working fluid branched from the low temperature side pump and supplied to the low temperature side recuperator of the recuperator is mixed with the working fluid passed through the pump at the front end of the point where the working fluid heated in the heat exchanger is mixed, .
And the working fluid heated by branching to any one of the heat exchangers is supplied to the rear end of the high temperature side recuperator and mixed with the working fluid passed through the high temperature side recuperator.
And the working fluid is branched at a front end of the recuperator and supplied to one of the heat exchangers.
And the working fluid passing through the high temperature side recuperator is supplied to another one of the heat exchangers and reheated and then supplied to the turbine.
The heat exchanger may include any one of a high temperature heat exchanger that performs heat exchange with the high temperature waste heat gas, a medium temperature heat exchanger that performs heat exchange with the middle or low temperature waste gas, or a low temperature heat exchanger.
And the working fluid passing through the high temperature side recuperator is supplied to the high temperature heat exchanger.
And the working fluid branched to any one of the heat exchangers is branched into the mesothermal heat exchanger or the low temperature heat exchanger.
The supercritical carbon dioxide power generation system according to an embodiment of the present invention is configured in the form of RCBC in the cycle configuration and the flow rate of the working fluid heated in the high temperature recuperator is divided to improve the heat exchange efficiency of the recuperator, . Thus, the efficiency of the entire cycle is improved.
1 is a schematic diagram showing an RCBC of a supercritical carbon dioxide power generation system according to an embodiment of the present invention,
FIG. 2 and FIG. 3 are schematic diagrams showing a modification of the supercritical carbon dioxide power generation system of FIG. 1,
FIG. 4 is a schematic diagram showing an RCBC of a supercritical carbon dioxide power generation system according to another embodiment of the present invention;
FIGS. 5 and 6 are schematic views showing a modification of the supercritical carbon dioxide power generation system of FIG.
7 shows a TQ diagram of a conventional LCBC-based liquefier with a single recuperator,
8 is a TQ diagram of a recuperator according to the RCBC of the present invention,
9 shows a TQ diagram of an external heat exchanger according to a conventional RCBC with a single recuperator,
10 is a TQ diagram of the external heat exchanger according to the RCBC of the present invention.
Hereinafter, a supercritical carbon dioxide power generation system according to an embodiment of the present invention will be described in detail with reference to the drawings.
Generally, a supercritical carbon dioxide power generation system forms a closed cycle that does not discharge the carbon dioxide used for power generation to the outside, and uses supercritical carbon dioxide as a working fluid to construct a single phase power generation system.
Since the supercritical carbon dioxide power generation system uses carbon dioxide as the working fluid, it can be used not only in a single power generation system but also in a hybrid power generation system with a thermal power generation system, since exhaust gas discharged from a thermal power plant can be used. The working fluid of the supercritical carbon dioxide power generation system may separate carbon dioxide from the exhaust gas and supply the carbon dioxide separately.
The working fluid in the cycle is supercritical carbon dioxide, which passes through a heat source such as a compressor and a heater, and becomes a high-temperature high-pressure working fluid, and supercritical carbon dioxide fluid drives the turbine. The turbine is connected to a generator, which is driven by the turbine to produce power. Alternatively, a turbine and a compressor may be coaxially connected, and a compressor may be provided with a gear box or the like to connect the generator. The working fluid used for the production of electric power is cooled through a heat exchanger such as a heat exchanger and a precooler, and the cooled working fluid is supplied to the compressor again to circulate in the cycle. A plurality of turbines or heat exchangers may be provided.
The supercritical carbon dioxide power generation system according to various embodiments of the present invention includes not only a system in which all of the working fluid flowing in a cycle is in a supercritical state but also a system in which most of the working fluid is supercritical and the rest is subcritical It is used as a meaning.
Also, in various embodiments of the present invention, carbon dioxide is used as the working fluid, wherein carbon dioxide refers to pure carbon dioxide in the chemical sense, carbon dioxide in a state where the impurities are somewhat contained in general terms, and carbon dioxide in which at least one fluid is mixed Is used to mean a fluid in a state where the fluid is in a state of being fluidized.
In the present invention, cycles are formed based on a recompression closed-brayton cycle (RCBC). The power generation cycle of the present invention is to propose a supercritical carbon dioxide power generation system composed of a pair of recuperators, a plurality of external heat exchangers, one or more turbines connected in a single shaft or a separate shaft, and a plurality of pumps and a single condenser do.
1 is a schematic diagram showing an RCBC of a supercritical carbon dioxide power generation system according to an embodiment of the present invention.
1, the supercritical carbon dioxide power generation system according to an embodiment of the present invention is based on RCBC having two compressors or
Each configuration of the present invention is connected by a transfer pipe through which a working fluid flows (a line corresponding to the
In addition, since the temperature or pressure of the working fluid described in the present invention is described by taking one of the cases as an example, it should not be understood as an absolute value.
The details of the cycle are as follows.
The
The
The
When a plurality of
In the present embodiment, the
The
The
The flow of the working fluid according to the cycle configuration is as follows.
The compressed low-temperature high-pressure working fluid passing through the
A part of the working fluid that has passed through the
The working fluid flowing through the
The working fluid heated and mixed in the
The high temperature working fluid expands while passing through the
The firstly cooled working fluid is sent to the
The
As described above, by distributing the flow rate of the working fluid heated in the hot recuperator, it is possible to improve the heat exchange efficiency of the recuperator and to enable additional heat absorption. Thus, the efficiency of the entire cycle is improved.
Hereinafter, a modified example of the above-described embodiment will be described (detailed description about the same configuration as the above-described embodiment will be omitted).
FIG. 2 and FIG. 3 are schematic diagrams showing a modification of the supercritical carbon dioxide power generation system of FIG.
As shown in FIG. 2, in constructing the cycle of the supercritical carbon dioxide power generation system, a
At this time, the low-temperature high-pressure working fluid passing through the
The working fluid having passed through the
The working fluid heated to a high temperature in the
In the embodiment of FIG. 1, the working fluid supplied to the
3, the
In the embodiments of FIGS. 1 to 3, the cycle configuration in which the turbine for driving the pump is driven also has been described, but a cycle including the turbine for driving the generator and the turbine for driving the pump may be separately provided The detailed description of the same constitution as the embodiment will be omitted).
FIG. 4 is a schematic view showing an RCBC of a supercritical carbon dioxide power generation system according to another embodiment of the present invention, and FIGS. 5 and 6 are schematic diagrams showing a modification of the supercritical carbon dioxide power generation system of FIG.
4, the
Also, as shown in FIG. 5, the cycle may be configured in the same manner as the embodiment of FIG. 2, and a
Alternatively, as shown in FIG. 6, a cycle may be constructed in the same manner as the embodiment of FIG. 3, and a
The cycle shown in Figs. 4 to 6 also distributes the flow rate of the working fluid heated in the hot recuperator, as in the above-described embodiments, thereby improving the heat exchange efficiency of the recuperator and enabling further heat absorption. Thus, the efficiency of the entire cycle is improved.
Also, the shaft power required by the first pump and the second pump can be efficiently managed by adjusting the rotational speed (rpm) of the second turbine. Generally, in case of a turbine connected to a generator, it is not possible to adjust the rotational speed of the pump through the corresponding turbine because the rotational speed can not be controlled. However, there is an advantage that the rotational speed can be adjusted when a separate second turbine is driven. This makes it possible to control the power of the pump according to the variation of the heat source and the ambient temperature condition, and the efficiency is improved even in the partial load aspect.
In the supercritical carbon dioxide power generation system according to the above-described embodiments, the temperature distribution of each heat exchanger will be described as follows.
FIG. 7 is a TQ diagram of a conventional recirculator with a single recuperator; and FIG. 8 is a TQ diagram of a recuperator according to the RCBC of the present invention. FIG. 9 is a T-Q diagram of an external heat exchanger according to a conventional RCBC with a single recuperator, and FIG. 10 is a T-Q diagram of an external heat exchanger according to the RCBC of the present invention.
In FIGS. 7 and 8, the range from the zero point to about 7000 kW is the low temperature recuperator area, and the higher temperature corresponds to the high temperature recuperator area. The low temperature recuperator means a recuperator, such as the second recuperator of the above-described embodiments, which is supplied with the working fluid supplied through the turbine after passing through another recuperator. Therefore, the high temperature recuperator becomes the first recuperator.
7, in the case of a conventional RCBC having a single external heat exchanger, the hot side outlet temperature at which the high temperature working fluid is discharged from the hot recuperator and the cold side outlet temperature at which the low temperature working fluid is discharged are several tens It shows the temperature difference of the figure.
However, as shown in FIG. 8, the temperature of the cold side outlet of the hot recuperator is increased by about 10% or more by controlling the flow rate of the working fluid flowing into the hot recuperator. This means that the thermal regeneration efficiency is improved.
9 and 10, the red solid line represents the TQ heat transfer of the waste heat gas at the rear end of the boiler, and the blue solid line represents the TQ heat transfer of the working fluid supplied to the external heat exchanger. As shown in FIG. 9, in the case of the conventional RCBC having a single external heat exchanger, since the working fluid passing through the high temperature recuperator is supplied to the external heat exchanger, there is a limit to absorb heat from the external heat exchanger.
However, when a new heat exchanger is added as shown in Fig. 10 (broken line portion), since a relatively low working fluid before being passed through the high temperature recuperator is supplied to the new heat exchanger, The absorption amount is increased. Therefore, when the new heat exchanger is added, the heat transfer area of the heat exchanger can be reduced, thereby reducing the cycle construction cost. Therefore, there is an advantage that the cycle can be selectively applied to the effect of increasing the efficiency of the cycle or reducing the economic cost.
One embodiment of the present invention described above and shown in the drawings should not be construed as limiting the technical spirit of the present invention. The scope of the present invention is limited only by the matters described in the claims, and those skilled in the art can improve and modify the technical spirit of the present invention in various forms. Accordingly, it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.
100 to 100e:
300 to 300e:
500 ~ 500e: capacitor
Claims (20)
Two pumps for compressing and circulating the working fluid,
A plurality of recupillators for primarily heating the working fluid that has passed through the pump,
A plurality of heat exchangers which use waste heat as a heat source and reheat the working fluid heated by the recuperator,
A turbine connected to the pump and the generator for generating the electric energy in a single shaft to drive the pump and the generator,
And a condenser for cooling the working fluid cooled by heat exchange with the working fluid supplied through the turbine and supplied to the recuperator,
A part of the working fluid supplied to the high-temperature-side recirculator of the recuperator is branched to one of the heat exchangers and heated, or a part of the working fluid is supplied to the heat exchanger at a rear end of the low- And the heating is performed in one branch,
A working fluid which is branched from the working fluid supplied to the high temperature side recuperator and sent to one of the heat exchangers is sent to the rear end of the high temperature side recuperator and is branched at the rear end of the low temperature side pump, And the working fluid sent to any one of the first and second heat exchangers is sent to a front end of the high temperature side recuperator.
The working fluid supplied to the low temperature side recuperator of the recuperator through the low temperature side pump of the pump is mixed with the working fluid passing through the high temperature side pump of the pump and then branched at the downstream end of the low temperature side pump, And the mixed gas is supplied to the high-temperature side recirculator of the recuperator.
And the working fluid passing through the high temperature side recuperator is supplied to the other of the heat exchangers and reheated and then supplied to the turbine.
Wherein the heat exchanger includes any one of a high temperature heat exchanger that performs heat exchange with the high temperature waste heat gas and a medium temperature heat exchanger or a low temperature heat exchanger that performs heat exchange with the middle or low temperature waste gas.
And the working fluid having passed through the high temperature side recuperator is supplied to the high temperature heat exchanger.
And the working fluid branched to any one of the heat exchangers is branched into the intermediate-temperature heat exchanger or the low-temperature heat exchanger.
Two pumps for compressing and circulating the working fluid,
Two recuplators for firstly heating the working fluid that has passed through the pump,
A plurality of heat exchangers which use waste heat as a heat source and reheat the working fluid heated by the recuperator,
A first turbine connected to a generator for generating the electric energy to drive the generator,
A second turbine for driving the pump,
And a condenser for sequentially cooling the first and second cooled working fluids through the first and second turbines,
A part of the working fluid supplied to the high-temperature-side recirculator of the recuperator is branched to one of the heat exchangers and heated, or a part of the working fluid is supplied to the heat exchanger at a rear end of the low- And the heating is performed in one branch,
A working fluid which is branched from the working fluid supplied to the high temperature side recuperator and sent to one of the heat exchangers is sent to the rear end of the high temperature side recuperator and is branched at the rear end of the low temperature side pump, And the working fluid sent to any one of the first and second heat exchangers is sent to a front end of the high temperature side recuperator.
The working fluid supplied to the low temperature side recuperator of the recuperator through the low temperature side pump of the pump is mixed with the working fluid passing through the high temperature side pump of the pump and then branched at the downstream end of the low temperature side pump, And the mixed gas is supplied to the high-temperature side recirculator of the recuperator.
Wherein the working fluid passing through the high temperature side recuperator is supplied to another one of the heat exchangers and reheated, and then supplied to one of the first turbine and the second turbine.
Wherein the heat exchanger includes any one of a high temperature heat exchanger that performs heat exchange with the high temperature waste heat gas and a medium temperature heat exchanger or a low temperature heat exchanger that performs heat exchange with the middle or low temperature waste gas.
And the working fluid having passed through the high temperature side recuperator is supplied to the high temperature heat exchanger.
And the working fluid branched to any one of the heat exchangers is branched into the intermediate-temperature heat exchanger or the low-temperature heat exchanger.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109026236A (en) * | 2018-08-07 | 2018-12-18 | 西安热工研究院有限公司 | A kind of efficient supercritical carbon dioxide hot dry rock electricity generation system |
KR20210046045A (en) | 2018-09-05 | 2021-04-27 | 상하이 파워 이큅먼트 리서치 인스티튜트 컴퍼니 리미티드 | Compact gas-gas heat exchange tube and its manufacturing and use method |
CN114198173A (en) * | 2021-11-04 | 2022-03-18 | 合肥通用机械研究院有限公司 | Full-backheating Brayton cycle and absorption refrigeration integrated electricity-cold combined supply system |
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US8869531B2 (en) | 2009-09-17 | 2014-10-28 | Echogen Power Systems, Llc | Heat engines with cascade cycles |
KR20160037570A (en) * | 2014-09-29 | 2016-04-06 | 한국전력공사 | Power Generating System Using Supercritical Carbon Dioxide |
US9359919B1 (en) * | 2015-03-23 | 2016-06-07 | James E. Berry | Recuperated Rankine boost cycle |
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2017
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US8869531B2 (en) | 2009-09-17 | 2014-10-28 | Echogen Power Systems, Llc | Heat engines with cascade cycles |
KR20160037570A (en) * | 2014-09-29 | 2016-04-06 | 한국전력공사 | Power Generating System Using Supercritical Carbon Dioxide |
US9359919B1 (en) * | 2015-03-23 | 2016-06-07 | James E. Berry | Recuperated Rankine boost cycle |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109026236A (en) * | 2018-08-07 | 2018-12-18 | 西安热工研究院有限公司 | A kind of efficient supercritical carbon dioxide hot dry rock electricity generation system |
KR20210046045A (en) | 2018-09-05 | 2021-04-27 | 상하이 파워 이큅먼트 리서치 인스티튜트 컴퍼니 리미티드 | Compact gas-gas heat exchange tube and its manufacturing and use method |
CN114198173A (en) * | 2021-11-04 | 2022-03-18 | 合肥通用机械研究院有限公司 | Full-backheating Brayton cycle and absorption refrigeration integrated electricity-cold combined supply system |
CN114198173B (en) * | 2021-11-04 | 2023-10-13 | 合肥通用机械研究院有限公司 | Electric cooling combined supply system integrating full-regenerative brayton cycle and absorption refrigeration |
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