KR101782466B1 - Secondary battery plate cooling method - Google Patents

Secondary battery plate cooling method Download PDF

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KR101782466B1
KR101782466B1 KR1020160167543A KR20160167543A KR101782466B1 KR 101782466 B1 KR101782466 B1 KR 101782466B1 KR 1020160167543 A KR1020160167543 A KR 1020160167543A KR 20160167543 A KR20160167543 A KR 20160167543A KR 101782466 B1 KR101782466 B1 KR 101782466B1
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chamber
catalyst
electrode plate
cooling
heat
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Korean (ko)
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이인우
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이인우
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • Y02E60/12
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/54

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The present invention relates to a method for cooling an electrode plate for a secondary battery. The method includes the steps of: (A) inputting an electrode plate into an enclosed chamber separated from the outside; (B) injecting 950 to 1000 Torr of a catalyst, which is an inert gas selected from nitrogen, argon, carbonic acid, and helium for accelerating the heat absorption in the chamber; (C) downwardly blowing the catalyst injected to the chamber by using a blowing fan, enabling the catalyst to absorb heat from the electrode plate while passing through the center of the chamber, discharging the catalyst to the outside of the chamber, cooling the heat absorbed in a heat exchanger, and circulating the catalyst in a path for going back into the blowing fan in the chamber to cool the electrode plate while circulating a coolant into the heat exchanger for coming in contact with the catalyst in an indirect manner to absorb the absorbed heat again; and (D) discharging the electrode plate after recovering the catalyst. The present invention can enhance the overall quality and reduce the number of steps in an operation by cooling the catalyst through circulating the catalyst forcefully injected to form air flows and accelerate heat absorption through the inside and the outside in a high-pressure state.

Description

이차 전지용 극판의 냉각방법{Secondary battery plate cooling method}[0001] The present invention relates to a secondary battery plate cooling method for cooling an electrode plate for a secondary battery,

본 발명은 이차 전지용 극판을 냉각하는 방법에 관한 것으로, 보다 구체적으로는 이차 전지용 음극 및 양극판을 제조하는 일련의 과정 중 극판에 도포된 바인더나 용매를 건조하기 위해 열풍으로 가열한 고온의 극판을 신속하고 안정된 상태에서 냉각하는 방법에 관한 것이다.The present invention relates to a method for cooling an electrode plate for a secondary battery, and more particularly, to a method for cooling an electrode plate for a secondary battery and a cathode plate for a secondary battery using a hot plate heated by hot air to dry a binder or a solvent applied to the electrode plate And cooling it in a stable state.

통상적으로, 2차 전지는 양극판, 음극판의 산화, 환원 반응에 의해 충·방전이 이루어지는데 극판 제조 시의 건조 상태에 따라 전지의 품질이 달라진다. 음극이나 양극 극판에 수분이나 기름 및 가스 등의 불순물이 함유될 경우에는 극성의 작용이 불규칙하거나 불량하게 되어 정격 에너지를 발생시키지 못하게 되고, 전지의 수명이 현저하게 줄어들게 된다.Generally, the secondary battery is charged and discharged by the oxidation and reduction reactions of the positive electrode plate and the negative electrode plate, and the quality of the battery varies depending on the drying state at the time of manufacturing the electrode plate. When the negative electrode or the positive electrode plate contains moisture, impurities such as oil and gas, the action of the polarity becomes irregular or poor, and the rated energy is not generated, and the life of the battery is remarkably reduced.

즉, 최근에는 이러한 문제를 해결하기 위해 한국 등록특허공보 제10-1175032호 "극판 건조 장치"와, 한국 등록특허공보 제10-1193169호 "극판 건조장치 및 방법"을 제안하고 있다. 제안된 문헌에 다르면 외부로부터 밀폐 가능한 챔버에 극판을 투입한 다음, 챔버를 진공상태로 전환한 이후 내장된 히터로 기류를 가열하여 내부를 순환하는 열풍으로 건조하였다. 따라서 진공과정에서 기류에 포함된 산소를 제거해줌으로서 산화를 방지해주는 것은 물론, 기류에 포함된 이물질과 함께 극판의 불순물이 제거된 청정상태에서 건조함에 따라 전반적인 품질을 향상할 수가 있다.Recently, Korean Patent Registration No. 10-1175032 "Plate Drying Apparatus" and Korean Patent Registration No. 10-1193169 "Plate Drying Apparatus and Method" have been proposed recently to solve such a problem. In accordance with the proposed document, the electrode plate was put into a sealable chamber from the outside, and after the chamber was changed to a vacuum state, the air flow was heated by a built-in heater and dried by circulating hot air. Therefore, it is possible to improve the overall quality by eliminating the oxygen contained in the air stream in the vacuum process, preventing oxidation, and drying in a clean state in which impurities of the electrode plate are removed together with foreign substances contained in the air stream.

한편, 건조과정을 거친 극판은 후속 과정을 거치기 위해 반듯이 상온까지 냉각하는 과정을 거쳐야 한다. 현재 고온의 극판을 냉각하기 위한 방안으로는 단순히 소정 공간에 방치하는 자연냉각 또는 블레이드로 송풍시키는 강제냉각 방식 중 택일 또는 복합하는 방식을 채택하여 냉각하고 있다.On the other hand, the plate subjected to the drying process must be cooled down to room temperature in order to carry out a subsequent process. At present, as a method for cooling a high temperature plate, cooling or cooling is adopted either by natural cooling which is left in a predetermined space or by forced cooling which is blown by a blade.

따라서 극판이 상온으로 냉각될 때까지 대기해야 하는 시간이 길어지는 것은 물론, 대기에 필요한 공간의 낭비를 초래할뿐더러 대기하는 고온의 극판이 증가될수록 냉각시간이 기하급수적으로 길어져 전반적인 제조성을 저하시키는 문제가 있다.Therefore, it takes a long time to wait until the electrode plate is cooled down to room temperature. In addition to this, the space required for the atmosphere is wasted. Also, as the high temperature plate is increased, the cooling time becomes exponentially longer, have.

한국 등록특허공보 제10-1175032호 "극판 건조 장치"Korean Patent Registration No. 10-1175032 entitled " 한국 등록특허공보 제10-1193169호 "극판 건조장치 및 방법"Korean Patent Registration No. 10-1193169 entitled "

이에 따라 본 발명은 상기와 같은 종래의 문제점을 근본적으로 해결하기 위한 것으로서, 극판을 외부와 밀폐되고 불순물이 제거된 청정상태에서 기류형성과 함께 흡열을 가속하는 촉매제를 강제로 주입한 다음, 챔버의 내외로 열교환하는 과정으로 냉각하여 전반적인 품질은 향상하고 제조시간은 단축할 수가 있는 이차 전지용 극판의 냉각방법을 제공하려는데 그 목적이 있다.SUMMARY OF THE INVENTION Accordingly, the present invention has been made in view of the above problems, and it is an object of the present invention to provide a method of manufacturing a plasma display panel in which a catalyst, which is airtight, The present invention provides a cooling method for an electrode plate for a secondary battery that can be cooled by a heat exchange process inside and outside, thereby improving the overall quality and shortening the manufacturing time.

이러한 목적을 달성하기 위해 본 발명은 적어도 하나 이상의 극판이 내·외부로 출입 가능한 터널형의 챔버와, 상기 챔버의 내·외부를 개폐하는 도어로 구성된 본체부; 상기 챔버 상에 극판의 출입을 안내하는 레일과, 상기 극판과 자력으로 연결되어 비접촉으로 출입시키는 이송유닛으로 구성된 이송부; 상기 챔버 상에 기류를 소정 풍속과 풍양으로 순환시키는 송풍팬과, 상기 챔버의 기류를 내·외로 순환시키는 덕트로 구성된 냉각부; 상기 챔버 상에 극판의 흡열을 가속하는 촉매제가 토출되는 주입유로와, 상기 덕트 상에 기류의 냉각을 가속하는 열교환기로 구성된 가속부로 이루어진 냉각장치를 이용하여 이차 전지용 극판을 냉각하는 방법에 있어서: (A) 상기 극판을 외부와 밀폐된 챔버내로 투입하는 단계; (B) 상기 챔버에 흡열을 가속하는 질소, 아르곤, 탄산, 헬륨 중 택일되는 불활성 가스인 촉매제를 950Torr 내지 1000Torr로 주입하는 단계; (C) 상기 챔버에 주입된 촉매제가 송풍팬에 의해 하향으로 송풍되고, 송풍된 촉매제는 챔버의 중앙을 지나면서 극판의 열을 흡수한 다음, 챔버의 외부로 배출되어 열교환기에서 흡수한 열을 냉각한 이후 챔버내의 송풍팬으로 재 흡입되는 경로로 순환시켜 극판을 냉각하되, 상기 열교환기의 내부로 촉매제와 간접적으로 접촉되어 흡수한 열을 재 흡수하는 냉각수가 순환되는 단계; (D) 상기 촉매제를 회수한 다음, 극판을 배출하는 단계;를 포함하여 이루어지는 것을 특징으로 한다.In order to achieve the above object, the present invention provides a plasma processing apparatus comprising: a main body including a tunnel-shaped chamber in which at least one electrode plate is allowed to go in and out, and a door for opening and closing the inside and outside of the chamber; A conveying unit including a rail for guiding the entrance and exit of the electrode plate on the chamber, and a conveying unit connected to the electrode plate by magnetic force to make contact and exit without contact; A cooling unit including a blowing fan for circulating the airflow on the chamber at a predetermined wind speed and a rich atmosphere, and a duct for circulating the airflow of the chamber in and out; A method for cooling an electrode plate for a secondary battery using a cooling device comprising an injection channel on which an electrode catalyst for accelerating the heat absorption of the electrode plate is discharged on the chamber, and an acceleration unit comprising a heat exchanger for accelerating the cooling of the airflow on the duct, A) injecting the electrode plate into an enclosed chamber outside; (B) injecting a catalyst, which is an inert gas selected from nitrogen, argon, carbonic acid, and helium, accelerating endothermic reaction into the chamber at 950 Torr to 1000 Torr; (C) The catalyst injected into the chamber is blown downward by a blowing fan, the blown catalyst absorbs the heat of the plate while passing through the center of the chamber, and then is discharged to the outside of the chamber to absorb heat absorbed by the heat exchanger Circulating the cooling plate through a path where the cooling plate is cooled and then re-sucked into the blowing fan in the chamber to cool the plate, and cooling water circulating inside the heat exchanger indirectly in contact with the catalyst to absorb the absorbed heat; (D) recovering the catalyst and discharging the electrode plate.

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한편, 이에 앞서 본 명세서 및 특허청구범위에 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정해서 해석되어서는 아니 되며, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 한다. 따라서 본 명세서에 기재된 실시예와 도면에 도시된 구성은 본 발명의 가장 바람직한 일 실시예에 불과할 뿐이고, 본 발명의 기술적 사상을 모두 대변하는 것은 아니므로, 본 출원시점에 있어서 이들을 대체할 수 있는 다양한 균등물과 변형예들이 있을 수 있음을 이해하여야 한다.It should be understood, however, that the terminology or words of the present specification and claims should not be construed in an ordinary sense or in a dictionary, and that the inventors shall not be limited to the concept of a term It should be construed in accordance with the meaning and concept consistent with the technical idea of the present invention based on the principle that it can be properly defined. Therefore, the embodiments described in the present specification and the configurations shown in the drawings are merely the most preferred embodiments of the present invention, and not all of the technical ideas of the present invention are described. Therefore, It is to be understood that equivalents and modifications are possible.

이상의 구성 및 작용에서 설명한 바와 같이, 본 발명은 극판을 외부와 밀폐되고 불순물이 제거된 청정상태에서 기류형성과 함께 흡열을 가속하는 촉매제를 강제로 주입한 다음, 열교환기에 순환하는 과정으로 냉각하여 전반적인 품질은 향상하고 제조시간은 단축할 수가 있는 효과를 제공한다.As described in the above construction and operation, according to the present invention, the catalyst is injected by forcefully injecting a catalyst that is enclosed with the outside and impurities removed, and accelerates the endotherm along with the formation of the air stream, and then circulates through the heat exchanger. The quality is improved and the manufacturing time is shortened.

도 1은 본 발명에 따른 냉각방법을 전체적으로 간략하게 나타내는 흐름도.
도 2 내지 도 4는 도 1의 방법을 실시하기 위한 냉각장치를 나타내는 참고도.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart briefly illustrating a cooling method according to the present invention. FIG.
Figs. 2 to 4 are reference views showing a cooling device for carrying out the method of Fig. 1; Fig.

이하, 첨부된 도면을 참조하여 본 발명에 따른 바람직한 실시예를 상세하게 설명한다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

본 발명은 이차 전지용 음극 및 양극판을 제조하는 일련의 과정 중 극판에 도포된 바인더나 용매를 건조하기 위해 열풍으로 가열한 고온의 극판을 신속하고 안정된 상태에서 냉각하는 방법에 관련되며, 도 1처럼 (A)단계 내지 (D)단계를 거쳐 전반적인 향상하고 제조시간은 단축할 수가 있는 이차 전지용 극판의 냉각방법이다.The present invention relates to a method for rapidly cooling a hot plate heated by hot air to dry a binder or a solvent applied to a plate during a series of processes for manufacturing a negative electrode and a positive electrode for a secondary battery, Is a cooling method for an electrode plate for a secondary battery that can be improved overall and shortened in manufacturing time through steps A) to D).

본 발명의 건조방법을 구현하기 위해 도 2와 같은 냉각장치(100)를 이용할 수 있다. 이러한 냉각장치(100)는 본 발명의 이해를 돕기 위한 것뿐이므로 도시된 구조에 국한될 필요는 없다. 일예로, 냉각장치(100)는 크게 본체부(10)와 이송부(20) 및 냉각부(30)와 가속부(40)로 구성된다.To implement the drying method of the present invention, a cooling device 100 as shown in FIG. 2 may be used. The cooling device 100 is only for the purpose of facilitating understanding of the present invention, and thus need not be limited to the structure shown in the drawings. For example, the cooling apparatus 100 includes a main body 10, a transfer unit 20, a cooling unit 30, and an acceleration unit 40.

먼저, 본체부(10)는 적어도 하나 이상의 극판(1)이 내·외부로 출입 가능한 터널형의 챔버(11)와, 챔버(11)의 내·외부를 개폐하는 도어(15)를 구성되고, 이송부(20)는 챔버(11)상에 극판(1)의 출입을 안내하는 레일(21)과, 극판(1)과 자력으로 연결되어 비접촉으로 출입시키는 이송유닛(25)으로 구성된다.First, the main body 10 comprises a tunnel-shaped chamber 11 in which at least one electrode plate 1 can enter and exit from the inside and the outside, and a door 15 for opening and closing the inside and outside of the chamber 11, The transfer unit 20 is constituted by a rail 21 for guiding the entrance and exit of the electrode plate 1 on the chamber 11 and a transfer unit 25 connected to the electrode plate 1 by a magnetic force to make contact and exit in a noncontact manner.

그리고 냉각부(30)는 챔버(11)상에 기류를 소정 풍속과 풍양으로 순환시키는 송풍팬(31)과, 챔버(11)의 기류를 내·외로 순환시키는 덕트(35)로 구성되고, 가속부(40)는 챔버(11)상에 극판(1)의 흡열을 가속하는 촉매제가 토출되는 주입유로(41)와, 덕트(35)상에 기류의 냉각을 가속하는 열교환기(45)로 구성된다.The cooling section 30 is constituted by a blowing fan 31 for circulating the airflow on the chamber 11 at a predetermined wind speed and a rich atmosphere and a duct 35 for circulating the airflow of the chamber 11 inward and outward, The unit 40 includes an injection path 41 through which a catalyst for accelerating the heat absorption of the electrode plate 1 is discharged on the chamber 11 and a heat exchanger 45 that accelerates the cooling of the airflow on the duct 35 do.

이러한 일실시예에 따른 냉각장치(100)의 작동과 역할에 대해서는 후술하는 단계와 함께 설명하겠다.The operation and role of the cooling device 100 according to this embodiment will be described with reference to the steps described later.

먼저, 본 발명에 따른 (A)단계는 도 2처럼 건조를 거친 고온의 극판(1)을 외부와 밀폐된 챔버(11)내로 투입하는 과정이다. 즉, 타 이송부(건조장치)에 의해 전달된 극판(1)은 레일(21)에 안착되고, 하단의 이송유닛(25)을 따라 챔버(11)의 내부로 완전히 진입한다. 그리고 도어(15)가 내려와 챔버(11)를 밀폐한다.First, step (A) according to the present invention is a process of putting the electrode plate 1 having a high temperature, which has been dried, into the chamber 11 which is hermetically sealed with the outside as shown in FIG. That is, the electrode plate 1 transferred by the transfer unit (drying apparatus) is placed on the rail 21 and completely enters the chamber 11 along the transfer unit 25 at the lower end. Then, the door 15 comes down to seal the chamber 11.

여기서 극판(1)은 전지의 구성에 따라 양극 및 음극의 판들 사이에 세퍼레이터를 개재시킨 상태에서 릴 상으로 감아 구성할 수도 있고, 판상으로 형성된 양극 및 음극의 판을 세퍼레이터가 개재된 상태로 적층하여 구성할 수도 있다.Here, the electrode plate 1 may be constituted by winding a reel-like sheet in a state in which a separator is interposed between the plates of the positive electrode and the negative electrode according to the configuration of the battery, or alternatively, plates of positive and negative plates formed in a plate- .

이어서 본 발명에 따른 (B)단계는 도 3처럼 챔버(11)에 흡열을 가속하는 촉매제를 소정 압력으로 주입하는 과정이다. 즉, 주입유로(41)가 촉매제를 챔버(11)의 내부로 강제로 주입하여 대기압 상태에서 고압상태로 전환한다.Next, step (B) according to the present invention is a process of injecting a catalyst for accelerating the endothermic pressure into the chamber 11 at a predetermined pressure, as shown in FIG. That is, the injection flow path 41 forcibly injects the catalyst into the chamber 11 to switch from the atmospheric pressure state to the high pressure state.

촉매제는 챔버(11)의 내부에 기류를 형성함과 함께 흡열을 가속하는 역할을 수행한다. 이러한 촉매제는 극판(1)과 반응을 야기하지 않는 불활성 가스로 질소, 아르곤, 탄산, 헬륨 중 어느 하나를 이용할 수 있다.The catalyst forms a gas flow inside the chamber 11 and accelerates endothermic reaction. This catalyst may be any one of nitrogen, argon, carbonic acid, and helium as an inert gas that does not cause reaction with the electrode plate (1).

이때, 촉매제는 챔버(11)의 내부로 주입되는 압력이 매우 중요한데, 챔버(11)에 주입되는 촉매제의 압력이 높을수록 역할은 배가된다. 그러나 촉매제의 압력이 너무 보다 높으면 챔버(11)와 함께 내부에 포함되는 이송부(20)와 냉각부(30)를 압력용기에 버금가는 내구성을 가져함은 물론, 극판(1)의 활물질을 변화시키는 문제가 있다.At this time, the pressure of the catalyst injected into the chamber 11 is very important. The higher the pressure of the catalyst injected into the chamber 11, the more the role is doubled. However, if the pressure of the catalytic agent is too high, durability of bringing the transfer part 20 and the cooling part 30 included in the inside of the chamber 11 together with the pressure vessel is provided in addition to the chamber 11, there is a problem.

반대로 촉매제의 압력이 너무 낮으면, 흡열의 부족으로 냉각에 소모되는 시간과 에너지가 증가될 수밖에 없다. 따라서 촉매제는 950Torr 내지 1000Torr로 주입하는 것이 바람직하다.On the other hand, if the pressure of the catalyst is too low, the time and energy consumed for cooling due to the lack of endotherm must be increased. Therefore, the catalyst is preferably injected at 950 Torr to 1000 Torr.

이어서 본 발명에 따른 (C)단계는 도 4처럼 주입된 촉매제를 챔버(11)의 내부에서 외부로 순환시켜 극판(1)을 냉각하는 과정이다. 즉, 챔버(11)에 주입된 촉매제가 송풍팬(31)에 의해 하향으로 송풍되고, 송풍된 촉매제는 챔버(11)의 중앙을 지나면서 극판(1)의 열을 흡수한다.Next, step (C) according to the present invention is a process of cooling the electrode plate 1 by circulating the injected catalyst from the inside of the chamber 11 to the outside as shown in FIG. That is, the catalyst injected into the chamber 11 is blown downward by the blowing fan 31, and the blown catalyst agent absorbs the heat of the electrode plate 1 through the center of the chamber 11.

그리고 열의 흡수로 가열된 촉매제는 챔버(11)의 외부로 연통하는 덕트(35)로 배출되고, 덕트(35)상에 개재된 열교환기(45)를 지나면서 냉각된 이후 챔버(1)내의 송풍팬(31)으로 재 흡입되는 경로로 순환된다. The catalyst heated by the absorption of heat is discharged to the duct 35 which communicates with the outside of the chamber 11 and is cooled after passing through the heat exchanger 45 interposed on the duct 35, And is then recirculated to the fan 31 again.

이때, 열교환기(45)의 내부로 촉매제와 간접적으로 접촉되어 흡수한 열을 재 흡수하는 냉각수를 더 순환시키는 것이 좋다. 열교환기(45)는 표면상에 접촉되는 기류 또는 냉각수를 통해 내부를 지나는 촉매제를 냉각할 수 있는데, 냉각수는 냉각효율이 높아 챔버(11)의 용량에 제한 없이 사용이 가능하다. 물론, 냉각수를 순환시키기 위한 별도의 설비가 필요하므로 냉각되는 극판(1)의 수량에 따라 적용하는 것이 좋다.At this time, it is preferable to further cool the cooling water for indirectly contacting the catalyst in the heat exchanger (45) to reabsorb the absorbed heat. The heat exchanger 45 can cool the catalyst passing through the inside through the air stream or the cooling water that is in contact with the surface. The cooling water has a high cooling efficiency and can be used without any limitation on the capacity of the chamber 11. Needless to say, a separate facility for circulating the cooling water is required, so it is preferable to apply it according to the number of the electrode plates 1 to be cooled.

마지막으로 본 발명에 따른 (D)단계는 챔버(1)에 주입된 촉매제를 회수한 다음, 냉각된 극판(1)을 외부로 배출하는 과정이다. 즉, 극판(1)의 냉각이 완료된 이후에는 주입유로(41)가 챔버(11)의 내부에 주입된 촉매제를 본래의 위치로 반출한다. 그리고 도어(15)가 올라가 챔버(11)가 개방되고, 레일(21)에 안착된 극판(1)이 하단의 이송유닛(25)을 따라 외부로 배출된다. 배출된 극판(1)은 조립 과정을 거쳐 완성된다.Finally, step (D) according to the present invention is a process of recovering the catalyst injected into the chamber 1 and then discharging the cooled electrode plate 1 to the outside. That is, after the cooling of the electrode plate 1 is completed, the injection path 41 discharges the catalyst injected into the chamber 11 to its original position. The door 15 is then lifted to open the chamber 11 and the electrode plate 1 seated on the rail 21 is discharged to the outside along the lower transfer unit 25. The discharged electrode plate (1) is completed through an assembling process.

이하, 본 발명의 구체적인 실시예를 살펴보고 실질적인 효과가 유효함을 알아보고자 한다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, a specific embodiment of the present invention will be described, and it will be understood that substantial effects are possible.

<<제1실험>><< First Experiment >>

제1실험은 기존의 진공 상태에서 송풍팬으로 냉각하는 것과, 본 발명과 같이 불활성 가스(질소)를 주입 상태에서 송풍팬으로 냉각하는 것에 따른 차이점을 알아보고자 한다.In the first experiment, it is tried to investigate the difference between cooling of a blowing fan in a conventional vacuum state and cooling of an inert gas (nitrogen) in a blowing fan in the injected state as in the present invention.

<실험방법><Experimental Method>

실험방법은 본 발명의 챔버(11)의 내부를 700Torr로 진공 처리한 실시예1과, 대기압(760Torr) 상태에서 처리한 실시예2와, 촉매제(질소)를 1000Torr(양압)로 주입한 실시예3으로 구분한 다음, 120분간 송풍으로 냉각된 온도를 알아보고자 한다.The experiment was carried out in the same manner as in Example 1 in which the inside of the chamber 11 of the present invention was vacuum-treated at 700 Torr, Example 2 which was treated at the atmospheric pressure (760 Torr) and Example 2 where the catalyst (nitrogen) was injected at 1000 Torr 3, and then to investigate the temperature cooled by air blowing for 120 minutes.

<실험조건><Experimental Conditions>

실험조건은 각 실시예에 사용되는 냉각시료를 아래와 같이 릴 상으로 감은 극판으로 구성하였고, 각 극판의 중심에 온도센서를 개재하여 온도를 측정하였다. 여기서 냉각시료는 모두 동일한 조건하에서 건조된 것으로, 중심온도 130℃ㅁ3로 가열된 상태에서 냉각 처리하였다.Experimental conditions were as follows. The cooling samples used in each example were composed of plate plates wound in a reel shape as shown below, and temperature was measured through a temperature sensor at the center of each plate plate. Here, the cooling samples were all dried under the same conditions and cooled at a center temperature of 130 ° C. ⅓.

건조시료Dry sample 센서위치Sensor location

Figure 112016120931401-pat00001
Figure 112016120931401-pat00001
Figure 112016120931401-pat00002
Figure 112016120931401-pat00002

<측정결과>&Lt; Measurement result >

Figure 112016120931401-pat00003
Figure 112016120931401-pat00003

<실험결과> 단위 : ℃               <Results> Unit: ℃ 실시예1Example 1 실시예2Example 2 실시예3Example 3 9090 6969 6060

측정결과를 살펴본 바, 실시예1의 온도는 90℃이고, 실시예2의 온도는 69℃이며, 실시예3의 온도는 60℃로 측정되었다. 즉, 챔버(11)내에 촉매제(질소)를 강제로 주입한 실시예3의 냉각방법이 가장 우수한 것을 알 수가 있다.As a result of the measurement, the temperature of Example 1 was 90 ° C, the temperature of Example 2 was 69 ° C, and the temperature of Example 3 was 60 ° C. That is, it can be seen that the cooling method of Embodiment 3 in which the catalyst (nitrogen) is injected into the chamber 11 is most excellent.

<제2실험>&Lt; Second Experiment &

제2실험은 챔버(11)내에 강제로 주입되는 촉매제(질소)의 압력에 따른 냉각성능을 알아보고자 한다.In the second experiment, the cooling performance according to the pressure of the catalyst (nitrogen) forced into the chamber 11 is investigated.

<실험방법><Experimental Method>

실험방법은 본 발명의 챔버(11)내에 촉매제(질소)를 950Torr로 주입한 실시예1과, 900Torr로 주입한 실시예2와, 800Torr로 주입한 실시예3으로 구분한 다음, 120분간 송풍으로 냉각된 온도를 알아보고자 한다.The experimental method was as follows: Example 1 in which the catalyst (nitrogen) was injected at 950 Torr, Example 2 injected at 900 Torr, and Example 3 injected at 800 Torr into the chamber 11 of the present invention, We want to know the cooled temperature.

<실험조건><Experimental Conditions>

실험조건은 각 실시예에 사용되는 냉각시료를 아래와 같이 릴 상으로 감은 극판으로 구성하였고, 각 극판의 중심에 온도센서를 개재하여 온도를 측정하였다. 여기서 냉각시료는 모두 동일한 조건하에서 건조된 것으로, 중심온도 130℃ㅁ3로 가열된 상태에서 냉각 처리하였다.Experimental conditions were as follows. The cooling samples used in each example were composed of plate plates wound in a reel shape as shown below, and temperature was measured through a temperature sensor at the center of each plate plate. Here, the cooling samples were all dried under the same conditions and cooled at a center temperature of 130 ° C. ⅓.

건조시료Dry sample 센서위치Sensor location

Figure 112016120931401-pat00004
Figure 112016120931401-pat00004
Figure 112016120931401-pat00005
Figure 112016120931401-pat00005

<측정결과>&Lt; Measurement result >

Figure 112016120931401-pat00006
Figure 112016120931401-pat00006

<실험결과> 단위 : ℃                            <Results> Unit: ℃ 실시예1Example 1 실시예2Example 2 실시예3Example 3 4848 6565 8787

측정결과를 살펴본 바, 실시예1의 온도는 48℃이고, 실시예2의 온도는 65℃이며, 실시예3의 온도는 87℃로 측정되었다. 즉, 챔버(11)내에 촉매제(질소)를 950Torr로 주입한 실시예1의 냉각방법이 가장 우수한 것을 알 수가 있다.As a result of the measurement, the temperature of Example 1 was 48 ° C, the temperature of Example 2 was 65 ° C, and the temperature of Example 3 was 87 ° C. That is, it can be seen that the cooling method of Example 1 in which the catalyst (nitrogen) is injected into the chamber 11 at 950 Torr is the most excellent.

한편, 제1실험과 제2실험에서 알 수 있듯이 챔버(11)내에 질소를 강제로 주입하되, 950 내지 1000Torr의 범주로 주입할 때만이 비로소 최적의 냉각성능을 발휘할 수가 있다.On the other hand, as can be seen from the first experiment and the second experiment, nitrogen can be forcibly injected into the chamber 11, and the optimum cooling performance can be achieved only when injected in the range of 950 to 1000 Torr.

본 발명은 기재된 실시예에 한정되는 것은 아니고, 본 발명의 사상 및 범위를 벗어나지 않고 다양하게 수정 및 변형할 수 있음은 이 기술의 분야에서 통상의 지식을 가진 자에게 자명하다. 따라서 그러한 변형예 또는 수정예들은 본 발명의 특허청구범위에 속한다 해야 할 것이다.It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention as defined by the appended claims. It is therefore intended that such variations and modifications fall within the scope of the appended claims.

1: 극판 10: 본체부
11: 챔버 15: 도어
20: 이송부 21: 안내레일
25: 이송유닛 30: 냉각부
31: 송풍팬 35: 덕트
40: 가속부 41: 주입유로
45: 열교환기 100: 냉각장치
1: electrode plate 10:
11: chamber 15: door
20: feed part 21: guide rail
25: transfer unit 30: cooling unit
31: blower fan 35: duct
40: acceleration part 41:
45: heat exchanger 100: cooling device

Claims (5)

적어도 하나 이상의 극판이 내·외부로 출입 가능한 터널형의 챔버와, 상기 챔버의 내·외부를 개폐하는 도어로 구성된 본체부; 상기 챔버 상에 극판의 출입을 안내하는 레일과, 상기 극판과 자력으로 연결되어 비접촉으로 출입시키는 이송유닛으로 구성된 이송부; 상기 챔버 상에 기류를 소정 풍속과 풍양으로 순환시키는 송풍팬과, 상기 챔버의 기류를 내·외로 순환시키는 덕트로 구성된 냉각부; 상기 챔버 상에 극판의 흡열을 가속하는 촉매제가 토출되는 주입유로와, 상기 덕트 상에 기류의 냉각을 가속하는 열교환기로 구성된 가속부로 이루어진 냉각장치를 이용하여 이차 전지용 극판을 냉각하는 방법에 있어서:
(A) 상기 극판을 외부와 밀폐된 챔버내로 투입하는 단계;
(B) 상기 챔버에 흡열을 가속하는 질소, 아르곤, 탄산, 헬륨 중 택일되는 불활성 가스인 촉매제를 950Torr 내지 1000Torr로 주입하는 단계;
(C) 상기 챔버에 주입된 촉매제가 송풍팬에 의해 하향으로 송풍되고, 송풍된 촉매제는 챔버의 중앙을 지나면서 극판의 열을 흡수한 다음, 챔버의 외부로 배출되어 열교환기에서 흡수한 열을 냉각한 이후 챔버내의 송풍팬으로 재 흡입되는 경로로 순환시켜 극판을 냉각하되, 상기 열교환기의 내부로 촉매제와 간접적으로 접촉되어 흡수한 열을 재 흡수하는 냉각수가 순환되는 단계;
(D) 상기 촉매제를 회수한 다음, 극판을 배출하는 단계;를 포함하여 이루어지는 것을 특징으로 하는 이차 전지용 극판의 냉각방법.
A main body including a tunnel-shaped chamber in which at least one electrode plate is allowed to go in and out, and a door which opens and closes the inside and outside of the chamber; A conveying unit including a rail for guiding the entrance and exit of the electrode plate on the chamber, and a conveying unit connected to the electrode plate by magnetic force to make contact and exit without contact; A cooling unit including a blowing fan for circulating the airflow on the chamber at a predetermined wind speed and a rich atmosphere, and a duct for circulating the airflow of the chamber in and out; A method for cooling an electrode plate for a secondary battery by using a cooling device comprising an injection passage on which an accelerator for accelerating the heat absorption of the electrode plate is injected on the chamber and an acceleration portion including a heat exchanger for accelerating the cooling of the airflow on the duct,
(A) injecting the electrode plate into an enclosed chamber outside;
(B) injecting a catalyst, which is an inert gas selected from nitrogen, argon, carbonic acid, and helium, accelerating endothermic reaction into the chamber at 950 Torr to 1000 Torr;
(C) The catalyst injected into the chamber is blown downward by a blowing fan, the blown catalyst absorbs the heat of the plate while passing through the center of the chamber, and then is discharged to the outside of the chamber to absorb heat absorbed by the heat exchanger Circulating the cooling plate through a path where the cooling plate is cooled and then re-sucked into the blowing fan in the chamber to cool the plate, and cooling water circulating inside the heat exchanger indirectly in contact with the catalyst to absorb the absorbed heat;
(D) recovering the catalyst, and then discharging the electrode plate.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019212515B3 (en) * 2019-08-21 2020-10-01 Volkswagen Aktiengesellschaft Battery designed to terminate an undesirable thermal event

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019212515B3 (en) * 2019-08-21 2020-10-01 Volkswagen Aktiengesellschaft Battery designed to terminate an undesirable thermal event

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