KR101780417B1 - Composition for spraying to prevent sliping and manufacturing process thereof - Google Patents

Abstract

The present invention relates to a spray composition for slipping prevention which is easily applied to any places to provide excellent non-slip effects and obtain excellent hiding power and abrasion resistance with respect to application places, and which is filled in a spray and sprayed in the form of an aerosol to facilitate the application of the spray composition and enable the spray composition to be simply coated. The spray composition for slipping prevention, as a paint composition which is filled in the spray and sprayed in the form of the aerosol, comprises a paint composition including 30 to 40 wt% of a 2-propenoic acid butyl ester polymer, 20 to 30 wt% of toluene, and 17 to 27 wt% of acetone. The spray composition for slipping prevention further comprises 2 to 5 wt% of a propyltex wax with a particle size corresponding to a mesh size of 100 with respect to 95 to 98 wt% of the paint composition. The spray composition for slipping prevention not only can be easily applied to various places such as concrete floor, metal, wood, tile, marble and the like by providing the spray composition comprising specific constituents with excellent frictional forces at specific ratios, but also can exhibit long-term effects by maintaining excellent hiding power and abrasion resistance as well as excellent frictional force for slipping prevention.

Description

TECHNICAL FIELD [0001] The present invention relates to a composition for a non-slip spray,

The present invention relates to a composition for a non-slip spray, and more particularly, to a non-slip spray composition which is excellent in hiding power against applied parts and abrasion resistance while providing excellent non-slip effect, And spraying it in an aerosol type so that it can be easily and easily applied to a composition for a non-slip spray.

Generally, a floor or a road existing in various living spaces has a high possibility that a pedestrian or a driver who is walking on the slip slides and accident occurs in a slope or a steep curve area. However, the anti-slip technique on the road constructed by using the ascon or the like and various compositions therefor have been continuously developed and applied, but it is necessary to prevent the slip of the indoor space such as the walkway, the stairs, the hallway, Slip sheets are provided, and some anti-slip coatings are provided. Such conventional anti-slip coatings are prepared by mixing a mixture of a base and a hardening agent, and then applying a friction material It is a way to sow. In addition, as shown in FIG. 4, most of the methods of attaching the anti-slip tape to marble, epoxy floor, and concrete floor using an adhesive or anchor are used. However, in the conventional method of spraying the friction material as described above, there is a problem in that the adhesion force is low at portions where there is a water or oil by a method of applying with a roller or a brush, and since it must be applied directly by a specialist at the time of application, There is an inconvenience. Next, the method of attaching the tape has the problem that when it is used in a place where there is a lot of dust or oil in the field, the adhesive force is reduced and the function is lost in a short period of time, and the price is too expensive, which is not economical. In addition, dust, There is a problem in that the adhesive force is lowered even in the place where the adhesive tape is present, the preliminary working and the construction time are long, and the adhesive is left at the place where the tape is detached later. In addition, conventionally, a method of spraying a paint with a spray to prevent slipping has been used. However, there is a problem that the durability is poor and the slip prevention function is not long, and the color is contaminated and the aesthetic appearance is damaged.

For example, Korean Patent Registration No. 10-0678603 discloses a formulation of a coating method in order to solve the above-mentioned problems of the prior art. For example, in Korean Patent Publication No. 10-0678603, rigidity of silicate or cement having self-hardening property, , A special color coating system using a combination of cross-linkable polymer technology, combined with flooring, is a packaging technology that expresses various colors without changing the physico-chemical properties of the floor such as ascon, pitcher cones and sidewalk blocks, A base coating agent having a slip function, and an acrylic emulsion resin composition used therefor. The base coating composition may contain a tertiary amine-containing monomer, an acrylic or methacrylic monomer having an aliphatic group, a styrene monomer, an acrylic or methacrylic monomer having an acid group, Or an acrylic or methacrylic monomer having An acrylic emulsion resin composition obtained by dropping a monomer mixture containing a polymerizable monomer, a polymerization initiator and a reactive emulsifier in ion-exchange water, and the like, and discloses a floor coating composition for anti-slip comprising the following: Korean Patent Registration No. 10-1115043, A composition for flooring and a method of applying the same, which comprises 10 to 30% by weight of acrylic acid or methacrylic acid, 2 to 10% by weight of an acrylic or methacrylic monomer having an aliphatic group, 5 to 15% by weight of a styrene monomer, 10 to 20% by weight of silicon dioxide, 10 to 20% by weight of mica having an average particle diameter of 70 to 90 μm, 1 to 20% by weight of at least one pigment selected from organic pigments, fluorescent pigments, phosphorescent pigments and pearl pigments, water 20 1 to 5% by weight of a silicone-based antifoaming agent, 1 to 5% by weight of a silicone-based antifoaming agent, and 1 to 5% by weight of a silicone- It discloses a. Japanese Unexamined Patent Application Publication No. 05-311152 discloses a non-slip composition further comprising a non-slip composition composed of a vinyl polymer emulsion (butyl acrylate), rosin (rosin derivative), wax (polyethylene wax, natural wax) .

However, the coating compositions and compositions disclosed in the above-mentioned inventions not only provide satisfactory sliding resistance, but also have a problem of poor abrasion resistance and hiding power.

Accordingly, the present inventors have recognized a problem to be solved by the above-mentioned prior art, and have proposed a composition capable of forming not only a slip resistant layer but also an abrasion resistance and a hiding power as well as an anti-slip layer by a spraying method, The present inventors have made intensive studies on a method which can be easily produced to complete the present invention.

Patent Document 1: Korean Patent Publication No. 10-0678603 Patent Document 2: Korean Patent Publication No. 10-1115043 Patent Document 3: JP-A-05-311152

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned technical problems in the prior art, and it is a main object of the present invention to provide a spraying method which can be easily applied to various places, And which is excellent in abrasion resistance and hiding power.

Another object of the present invention is to provide a production method which can more easily prepare a composition for a non-slip spray having the above-mentioned characteristics.

The present invention may also be directed to accomplish these and other objects, which can be easily derived by those skilled in the art from the overall description of the present specification, in addition to the above-mentioned and obvious objects.

In order to achieve the above object, the composition for a non-slip spray of the present invention comprises:

1. A coating composition filled in a spray and sprayed in an aerosol form,

The paint composition comprises 30 to 40 parts by weight of 2-propenoic acid butyl ester polymer polymer, 20 to 30 parts by weight of toluene, and 17 to 27 parts by weight of acetone. In 95 to 98 parts by weight of the paint composition, mesh size of 100, and 2 to 5 parts by weight of propyltex waxes.

In order to achieve the above object, the composition for a non-slip spray of the present invention comprises:

1. A coating composition for architectural use which is sprayed in an aerosol form by being filled in a spray,

Wherein the coating composition comprises 20 to 30 parts by weight of a 2-propenoic acid butyl ester polymer, 10 to 20 parts by weight of calcium carbonate, 20 to 30 parts by weight of toluene, 0.1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of an azo compound, 1 to 5 parts by weight of iron hydroxide oxide (Fe (OH) O), and 95 to 98 parts by weight of the coating composition having the mesh size of 100 (Propyltex waxes) in an amount of 2 to 5 parts by weight.

According to another aspect of the present invention, the composition is characterized in that the dimethyl ether is filled together with the gas pressure of 6 bar inside the spray can.

According to another aspect of the present invention, there is provided a method for preparing a composition for a non-slip spray composition,

Blending a mixture of 2-propenoic acid butyl ester polymer and toluene in a predetermined ratio; And

Adding propyltex waxes having a mesh size of 100 to the blended mixture at a predetermined ratio range and mixing them.

According to another aspect of the present invention, the method comprises:

Propenoic acid butyl ester polymer and toluene in a predetermined ratio. Then, the mixture is mixed with calcium carbonate, titanium dioxide, an azo compound, iron hydroxide oxide (Fe (OH ) ≪ / RTI > O). ≪ / RTI >

According to another aspect of the present invention, the method comprises filling a uniformly mixed composition in an aerosol container with a dimethyl ether at a gas pressure of 6 bar, clamping the nozzle, The method comprising the steps of:

The composition for a non-slip spray of the present invention, which is constituted as described above, can be applied to various places such as concrete floor, metal, wood, tile, and marble by providing a composition for spray containing specific compositions with a certain frictional force It is possible to exhibit long-time effect because of excellent hiding power and abrasion resistance as well as excellent frictional force for slip prevention. In addition, the present invention can easily and easily work with an aerosol type using a spray, and can be easily applied to a handle such as a construction tool or a scaffold in the field, and can be dried for about 10 minutes by toughening hardening, Economy is less.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a test report showing the results of a friction test before and after applying a composition for a non-slip spray according to a preferred embodiment of the present invention,
FIG. 2 is a schematic view schematically illustrating the spraying of an aerosol type composition for a non-slip spray according to a preferred embodiment of the present invention,
3 is a photograph showing a state in which a composition for a non-slip spray prepared according to a preferred embodiment of the present invention is applied to a floor in a state filled with a spray can,
4 is a photograph showing a state in which a conventional anti-slip tape is applied to a stair using an adhesive.

Hereinafter, the present invention will be described in more detail with reference to the preferred embodiments. However, it is needless to say that the scope of the present invention is not limited thereto.

In this specification, the present embodiments are provided to provide a complete disclosure of the present invention and to fully disclose the scope of the invention to a person having ordinary skill in the art to which the present invention belongs. It is only defined by the claims. Thus, in some embodiments, well-known components, well known operations, and well-known techniques are not specifically described to avoid an undesirable interpretation of the present invention.

The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. In the present specification, the singular forms include plural forms unless otherwise specified in the specification. Also, components and acts referred to as " comprising (or comprising) " do not exclude the presence or addition of one or more other components and operations.

The composition for a non-slip spray according to a preferred embodiment of the present invention is sprayed in an aerosol form by being filled in a spray, wherein the coating composition comprises 30 to 40 parts by weight of 2-propenoic acid butyl ester polymer, 20 to 30 parts by weight , 17 to 27 parts by weight of acetone, and 95 to 98 parts by weight of the paint composition thus prepared further comprises 2 to 5 parts by weight of propyltex waxes having a mesh size of 100 .

In addition, the composition for a non-slip spray according to another preferred embodiment of the present invention is sprayed in an aerosol form by being filled in a spray, wherein the coating composition comprises 20 to 30 parts by weight of 2-propenoic acid butyl ester polymer, 10 to 20 parts by weight of a carbonate, 20 to 30 parts by weight of toluene, 0.1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of an azo compound, 1 to 5 parts by weight of iron hydroxide oxide (Fe (OH) And 2 to 5 parts by weight of propyltex waxes having a mesh size of 100 may be further added to 95 to 98 parts by weight of the paint composition.

As described above, it is composed of 30 to 40 parts by weight of 2-propenoic acid butyl ester polymer, 20 to 30 parts by weight of toluene, and 17 to 27 parts by weight of acetone, which are mainly included in the anti-slip composition of the present invention. It is not preferable because the object of the present invention can not be achieved beyond the desired specifications in terms of surface frictional force, concealability and ejectability.

Also, as described above, the Profiltex wax, which is mainly used as a main component of the anti-slip composition of the present invention, is composed of polypropylene wax particles. Especially, since a mesh size of 100 is used, Which is the most effective in terms of both of them. Specifically, when the mesh size or more is used, the frictional force is remarkably lowered and the effect of slip prevention can not be attained significantly. If it is smaller than the above-mentioned size, the adhesion is decreased and the durability is remarkably decreased.

A composition for a non-slip spray according to another preferred embodiment of the present invention comprises 1 to 5 parts by weight of iron hydroxide oxide (Fe (OH) O) If it is added in an amount of less than 1 part by weight, the durability of the composition is not improved. If it is added in an amount of more than 5 parts by weight, the composition may be deteriorated in sprayability.

The composition of the present invention as described above is a composition that can be applied to a desired site by spraying to prevent slippage occurring in concrete floor, metal, stone, construction site, and the like. Particularly, the present invention is a composition filled in a spray, which is advantageous in that it can be easily and easily applied by being sprayed in an aerosol type as shown in FIG. FIG. 3 is a photograph showing the state where the composition of the present invention as constructed above is applied on the floor in a state filled with a spray can, and it can be applied to various places as shown in the figure. And has an advantage of being quick in drying, excellent in hiding power and abrasion resistance.

According to another embodiment of the present invention, the composition of the present invention is such that Dimethyl Ether is filled together with a gas pressure of 6 bar inside a can for spraying, and the non-slip layer is simply sprayed on the surface of an object to be formed The anti-slip layer having an excellent frictional force can be formed according to the present invention.

According to another preferred embodiment of the present invention, the composition for an anti-slip spray of the present invention comprises: Blending a mixture of 2-propenoic acid butyl ester polymer and toluene in a predetermined ratio; And adding Propyltex waxes having a mesh size of 100 to the blended mixture in a predetermined ratio range and mixing them.

According to another preferred embodiment of the present invention, a coating composition for construction which is filled in a spray and is sprayed in an aerosol form comprises a step of blending a mixture of a 2-propenoic acid butyl ester polymer and toluene at a predetermined ratio; Mixing the compounded mixture with calcium carbonate, titanium dioxide, an azo compound, iron hydroxide oxide (Fe (OH) O); And adding Propyltex waxes having a mesh size of 100 to the blended mixture in a predetermined ratio range and mixing them.

According to another preferred embodiment of the present invention, the uniformly mixed composition is filled in an aerosol container in such a manner that the gas pressure of dimethyl ether is 6 bar, and then the nozzle is clamped to form a non-slip composition Further comprising the step of: preparing a use spray.

As described above, the composition for a non-slip spray of the present invention is constituted at a specific ratio by the above-mentioned specific compositions. Therefore, when the composition for spraying is provided, it is excellent in sprayability and can be used for various places such as concrete floor, metal, wood, And it is excellent in hiding power and abrasion resistance as well as frictional force for excellent non-slip characteristics.

In addition, the present invention having the above-described structure can easily and easily work with an aerosol type using a spray, and can be easily applied to a handle of a construction tool, a scaffold or the like in the field, and sprayed on the sole of a shoe, So that an excellent non-slip effect can be obtained.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to the following Examples.

Example 1

2.5 kg of 2-propenoic acid butyl ester polymer, 1.78 kg of toluene (toluene) and 1.57 kg of acetone (Acetone) were uniformly mixed to obtain a homogeneous mixture. To this mixture, 0.3 kg of Propyltex waxes having a mesh size of 100 was added and homogeneously mixed with stirring to prepare a non-slip spray composition.

Example 2

1.3 kg of 2-propenoic acid butyl ester polymer, and 1.3 kg of toluene (Toluene) were uniformly mixed to obtain a homogeneous mixture. 0.78 kg of calcium carbonate, 0.3 kg of titanium dioxide, 0.3 kg of an azo compound and 0.4 kg of iron hydroxide oxide were mixed with the mixture thus obtained to obtain a homogeneous mixture. To this mixture, 0.3 kg of Propyltex waxes having a mesh size of 100 was added and homogeneously mixed with stirring to prepare a building anti-slip spray composition.

Comparative Example 1

A non-slip spray composition was prepared in the same manner as in Example 1 except that 0.3 kg of Propyltex waxes having a mesh size of 80 was used.

Comparative Example 2

A non-slip spray composition was prepared in the same manner as in Example 1 except that 0.3 kg of Propyltex waxes having a mesh size of 120 was used.

Comparative Example 3

A non-slip spray composition was prepared in the same manner as in Example 1, except that 0.1 kg of Propyltex waxes having a mesh size of 100 was used.

Comparative Example 4

A non-slip spray composition was prepared in the same manner as in Example 2 except that 0.3 kg of Propyltex waxes having a mesh size of 80 was used.

Comparative Example 5

A non-slip spray composition was prepared in the same manner as in Example 2 except that 0.3 kg of Propyltex waxes having a mesh size of 120 was used.

Comparative Example 6

A non-slip spray composition was prepared in the same manner as in Example 2, except that 0.1 kg of Propyltex waxes having a mesh size of 100 was used.

Comparative Example 7

A composition for a non-slip spray was prepared in the same manner as in Example 2, except that iron hydroxide hydroxide was not used.

Experimental Example

The friction force, durability, concealability and sprayability of the composition for non-slip spray prepared according to each of the above Examples and Comparative Examples were examined. As a result, when the composition according to Examples 1 and 2 was sprayed as shown in FIG. 1, excellent friction force improvement was shown from 27 BPN before application to 56 BPN after application according to the BPN (British Penholdt Test) regulating method, , The compositions of Comparative Examples 1 to 7 did not exceed 40 BPN after application, and the improvement in frictional force was weak. For reference, a BPN rating of 40 or better may be considered good. In particular, the composition of Comparative Example 7 showed weak hiding power and durability.

As described above, the technical idea of the composition for a non-slip spray according to the present invention and the method of manufacturing the same is specifically described in the preferred embodiments, but the embodiments are described for the purpose of illustration, . It will be apparent to those skilled in the art that various modifications and variations are possible within the spirit and scope of the present invention, and it is therefore intended that such variations and modifications fall within the scope of the appended claims.

Claims (6)

1. A coating composition filled in a spray and sprayed in an aerosol form,
The paint composition comprises 30 to 40 parts by weight of 2-propenoic acid butyl ester polymer, 20 to 30 parts by weight of toluene, and 17 to 27 parts by weight of acetone. In 95 to 98 parts by weight of the paint composition, 2 to 5 parts by weight of Propyltex waxes consisting of 100 parts by weight of propyltex waxes.
1. A coating composition for architectural use which is sprayed in an aerosol form by being filled in a spray,
Wherein the coating composition comprises 20 to 30 parts by weight of a 2-propenoic acid butyl ester polymer, 10 to 20 parts by weight of calcium carbonate, 20 to 30 parts by weight of toluene, 0.1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of an azo compound, 1 to 5 parts by weight of iron hydroxide oxide (Fe (OH) O), and 95 to 98 parts by weight of the coating composition having the mesh size of 100 (Propyltex 2 to 5 parts by weight of waxes are added to the composition.
The composition according to any one of the preceding claims, wherein the composition is filled together with dimethyl ether in a spray can with a gas pressure of 6 bar.
Blending a mixture of 2-propenoic acid butyl ester polymer and toluene in a predetermined ratio; And
And adding Propyltex waxes having a mesh size of 100 to the blended mixture at a predetermined ratio range and mixing them. The method for preparing a composition for a non-slip spray according to claim 1, wherein the propyltex waxes have a mesh size of 100.
5. The method of claim 4, wherein the method comprises:
Propenoic acid butyl ester polymer and toluene in a predetermined ratio. Then, the mixture is mixed with calcium carbonate, titanium dioxide, an azo compound, iron hydroxide oxide (Fe (OH ) ≪ / RTI > O). ≪ / RTI >
The method according to any one of claims 4 and 5, wherein the uniformly mixed composition is filled in an aerosol container in such a manner that a gas pressure of 6 bar is met in the inside of the aerosol container, and then the nozzle is clamped Characterized in that the method further comprises the step of preparing a spray for spraying a non-slip composition.

Images