KR101765555B1 - Reverse osmosis enrichment water ozone reaction equipment - Google Patents
Reverse osmosis enrichment water ozone reaction equipment Download PDFInfo
- Publication number
- KR101765555B1 KR101765555B1 KR1020150112586A KR20150112586A KR101765555B1 KR 101765555 B1 KR101765555 B1 KR 101765555B1 KR 1020150112586 A KR1020150112586 A KR 1020150112586A KR 20150112586 A KR20150112586 A KR 20150112586A KR 101765555 B1 KR101765555 B1 KR 101765555B1
- Authority
- KR
- South Korea
- Prior art keywords
- ozone
- water
- stopping
- concentrated water
- reaction tank
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 122
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 51
- 238000001223 reverse osmosis Methods 0.000 title abstract description 56
- 238000004090 dissolution Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 17
- 230000001174 ascending effect Effects 0.000 claims description 16
- 239000008213 purified water Substances 0.000 claims description 16
- 230000003028 elevating effect Effects 0.000 claims description 8
- 238000007689 inspection Methods 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- 230000006837 decompression Effects 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 abstract description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- 239000001569 carbon dioxide Substances 0.000 abstract description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 3
- 229910052742 iron Inorganic materials 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 description 8
- 230000008020 evaporation Effects 0.000 description 6
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 230000008878 coupling Effects 0.000 description 4
- 238000010168 coupling process Methods 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/78—Details relating to ozone treatment devices
- C02F2201/782—Ozone generators
Abstract
The present invention relates to an RO concentrated water ozone reactor for introducing ozone into RO concentrated water for purifying iron wastewater. More particularly, the present invention relates to an RO concentrated water ozone reactor having a large amount of RO concentrated water purified by reverse osmosis The RO concentrated water is reacted with a reaction tank and an ozone dissolution means to react the RO concentrated water by reacting the ozonized water to discharge water and carbon dioxide, To an RO-concentrated water ozone reaction device capable of circulating the RO.
Description
The present invention relates to an RO concentrated water ozone reactor for introducing ozone into RO concentrated water for purifying iron wastewater. More particularly, the present invention relates to an RO concentrated water ozone reactor having a large amount of RO concentrated water purified by reverse osmosis The RO concentrated water is reacted with a reaction tank and an ozone dissolution means to react the RO concentrated water by reacting the ozonized water to discharge water and carbon dioxide, To an RO-concentrated water ozone reaction device capable of circulating the RO.
In general, when the iron wastewater is purified by using the reverse osmosis method, RO concentrated water is produced. Such RO concentrated water has a high COD and it should be purified and discharged once more.
Accordingly, various techniques are proposed for purifying the RO concentrated water. Such prior arts include Patent No. 10-1378539 entitled " An apparatus and method for treating concentrated water in a reverse osmosis process using aerobic granular sludge ".
The above-mentioned prior art can stably treat the nitrate nitrogen and organic matter contained in the concentrated water of the reverse osmosis process by introducing the concentrated water of the reverse osmosis process into the anoxic tank filled with aerobic granular sludge, To an anoxic tank, it is possible to operate for a long period of time under a high total dissolved solids concentration, and it is possible to stably treat nitrate nitrogen.
In addition, there is a prior art No. 10-1352364 entitled " Pulsed Ultraviolet Reactor for Reverse Osmosis Device Concentrated Water Treatment "
The prior art is characterized in that the RO concentrated water is treated with ultraviolet rays after reducing the color tone of the RO concentrated water, so that the RO concentrated water of high color intensity can be quickly disassembled and a technique for increasing the water recovery rate is proposed have.
Furthermore, there is a prior art No. 10-1421386 entitled " High Efficiency Seawater Desalination System without Wastewater, Desalination Method Using the System, and Concentrated Water Treatment Method "
In the prior art, the raw water is introduced into the inside of the condensation evaporation tank for evaporating and concentrating the raw water by the heating means, and the steam generated in the condensation evaporation tank is introduced into the condensation evaporation tank to discharge the steam into the high temperature steam A steam turbine as claimed in any one of claims 1 to 3, further comprising: a turbo type steam compressor for heating the raw water by discharging the heat of the high temperature steam discharged from the turbo type steam compressor into the condensation evaporation tank, A process water reservoir connected to the condensed water line to regulate condensed water condensed in the condensed water line as treated water, and an evaporation concentrator for evaporating the concentrated water introduced into the condensed evaporation tank .
The present invention provides an RO concentrated water ozone reaction apparatus for purifying RO concentrated water using ozone different from the above-
Wherein the RO concentrated water is supplied to the RO concentrated water and the ozone dissolving unit is provided in the RO concentrated water flowing in the RO concentrated water, And an object of the present invention is to provide an RO concentrated water ozone reaction device which decomposes COD by decomposition.
Also, the object of the present invention is to provide an RO concentrated water ozone reaction device which has a plurality of obstruction plates in a zigzag shape in a reaction tank and can increase the waiting time of RO concentrated water and ozone in the reaction tank.
It is another object of the present invention to provide an RO concentrated water ozone reaction device which further includes a decompression means in the inflow portion to solve the problem that the pressure of the RO concentrated water at a high pressure is reduced to make the reaction vessel unstable.
In order to achieve the above object, the RO concentrated water ozone reaction apparatus according to the present invention comprises:
A reaction tank having an inlet through which RO concentrated water (raw water) flows and a discharge unit through which purified RO concentrated water (purified water) is discharged;
Ozone dissolving means provided in the inflow portion for dissolving ozone in raw water to be introduced;
Bypass means provided in the storage tank for moving a part of the raw water to the ozone dissolving means;
, ≪ / RTI >
The method according to claim 1,
In the reaction tank, a plurality of obstruction plates are formed in a staggered shape to increase reaction time between raw water and ozone.
As described above, the RO concentrated water ozone reactor according to the present invention is characterized by comprising an ozone dissolving unit for dissolving ozone in the RO concentrated water in the inflow part, Can react with ozone to discharge water and carbon dioxide, so that RO concentrated water (raw water) can be purified and discharged naturally.
In addition, since a plurality of obstacles are formed in a staggered manner in the reaction tank to reduce the flow rate of the raw water, the time for the raw water to stay in the reaction tank is increased to increase the reaction time with ozone, and thus COD in the raw water can be completely removed have.
Furthermore, the reaction tank further includes a bypass means, and the bypass means is capable of repeatedly supplying ozone and continuously circulating the raw water by transferring the raw water to the ozone dissolution means, thereby improving the purification ability.
1 is a conceptual diagram of an RO concentrated water ozone reaction apparatus according to the present invention.
2 is a modification example of the RO concentrated water ozone reactor according to the present invention
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will now be described in detail with reference to the accompanying drawings.
While the present invention has been described in connection with certain embodiments, it is obvious that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the invention. It is to be understood, however, that the invention is not intended to be limited to the particular forms disclosed, but on the contrary, is intended to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention.
In the drawings, the same reference numerals are used for the same reference numerals, and in particular, the digits of the tens and the digits of the digits, the digits of the digits, the digits of the digits and the alphabets are the same, Members referred to by reference numerals can be identified as members corresponding to these standards.
In the drawings, the components are expressed by exaggeratingly larger (or thicker) or smaller (or thinner) in size or thickness in consideration of the convenience of understanding, etc. However, It should not be.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. The singular expressions include plural expressions unless the context clearly dictates otherwise. In the present application, the term " comprising " or " consisting of ", or the like, refers to the presence of a feature, a number, a step, an operation, an element, a component, But do not preclude the presence or addition of one or more other features, integers, steps, operations, components, parts, or combinations thereof.
Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are to be interpreted as either ideal or overly formal in the sense of the present application Do not.
The RO concentrated water ozone reaction apparatus of the present invention comprises a
In general, steel wastewater needs purification in order to discharge it, and RO (Reverse Osmosis) membrane is mainly used in the process of purifying the wastewater. When the wastewater is purified by this reverse osmosis method, purified water And pollutants gather to make RO concentrated water.
Such RO concentrated water contains a very high amount of COD material, and a separate purification process is required to purify such RO concentrated water.
Accordingly, the present invention is directed to a method of purifying RO concentrated water, comprising the steps of: introducing a RO concentrated water (raw water) into a reaction vessel (11) having a RO concentrated water (purified water) 10 are provided.
The RO concentrated water is concentrated water of a high pressure (about 8 Bar). When such high pressure concentrated water flows into the
At this time, the higher the pressure of the raw water, the higher the solubility of ozone from the ozone dissolution means described later. Therefore, the
In the RO concentrated water ozone reactor (A) according to the present invention, the ozone dissolving means 20 is installed in the
Reaction formula
COD + O 3 - > H 2 O + CO 2
It is also important that the time for which the raw water stays in the reaction tank 10 (reaction time) increases in order for the raw water to react as described above. To this end, the
More specifically, it is preferable that the
The COD amount and the ozone amount of the purified water discharged through the
The RO concentrated ozone reaction apparatus A further includes a bypass means 30. More specifically, the
This is because when the purified water discharged through the
Therefore, the raw water can be circulated to the
2 shows a modification of the ozone reaction device according to the present invention, wherein the ozone dissolving means comprises a housing and an ozone generating film provided in the housing, wherein the ozone generating film has a plurality of pores As the incoming raw water passes through the pores, the ozone melts.
At this time, the housing is further provided with a dustproof means to prevent problems such as the bias of the housing depending on the flow of raw water and raw water flowing into the housing.
More specifically, it is arranged between a
First, the
The first and
Therefore, the vibration of the housing 20 'installed on the upper surface of the
It is preferable that the
The first and
It is preferable that at least one of the
The stopping means 50 of the present invention includes a
The
Therefore, since the shrink height of the
That is, the present invention introduces a strong
When a large load is concentrated on the
The
When the
The stopping means 50 of the present invention includes an ascending / descending
The ascending and descending
The ascending and descending
Particularly, the stopping means 50 constituted by the ascending / descending
The stopping means 50 constituted by the ascending / descending
The stopping means 50 of the present invention further includes a stopping
The
The lifting
The fixing
The stopping
The stopping
When the housing 20 'is pushed to one side, the ascending / descending
The
The spacing distance between the stopping
2A shows that the stopping
2, when the
In the case of [B] in Fig. 2, when the
In addition, a plurality of anti-skid means are further provided between the support frame and the bottom frame.
More specifically, the first
While the present invention has been described with reference to the accompanying drawings, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims. , Changes and substitutions are to be construed as falling within the scope of protection of the present invention.
A: RO concentrated water reactor 10: Reactor
11: inlet portion 111: decompression means
13: exhaust part 131: exhaust path
133: inspection means 135: UV reaction tank
15: Disturbance plate 17: Euro
20: ozone dissolving means 20 ': housing
29: ozone generating film 291: porosity
21: support frame 211: first-
213: first-second fastening part 23: bottom frame
231:
233: 2-2 fastening part 30: bypass means
31: bypass discharge part 40: anti-vibration means
41: coil spring 42: upper receptor
43: lower receptor 50: stopping means
51: stopper 52: stopping bolt
53: Stopping nut 54: Fixing nut
55: ascending / descending
55B: contact portion 57:
57A: connecting
59: anti-jamming means 59A: first anti-jamming member
59B: the second slide member
Claims (4)
Ozone dissolving means (20) provided in the inlet (11) and dissolving ozone in raw water to be introduced; And
Bypass means (30) provided in the reaction tank (10) for moving part of the raw water to the ozone dissolution means (20);
≪ / RTI >
The ozone dissolving means 20 includes a bottom frame 23, a support frame 21 arranged on the bottom frame 23 and provided with ozone dissolution means 20, frames 21, A plurality of dustproof means 40 including a coil spring 41 which is arranged between the support frame 21 and which absorbs vibrations of the housing 20 ' Further comprising stopping means (50) including a stopper (51) for restricting the overpressure of the coil spring (41)
The stopper 51 is disposed at a height between the lower surface of the support frame 21 and the upper surface of the bottom frame 23,
The stopping means 50 further includes an ascending and descending member 55 provided on the supporting frame 21 to descend the descending linkage and a fixing member 57 provided on the bottom frame 23,
The stopper (51) is disposed between the elevating member (55) and the fixing body (57)
The ascending and descending member 55 and the fixing member 57 are connected to each other by connecting portions 55A and 57A which are connected to the side surfaces of the tubes of the frames 21 and 23 as a bracket member, And the contact portions 55B and 57B are bent symmetrically with respect to the upper and lower ends of the lifting body 55A and the upper and lower ends of the lifting body 55A, Is provided on the upper surface of the contact portion 57B of the fixture 57,
The stopping means (50) includes a stopping bolt (52) inserted through the elevating body (55) and the fixing body (57)
The stopper 51 is composed of a stopping nut 53 coupled to the stopping bolt 52,
The stopping nut 53 is engaged to be biased in the direction of the end of the head portion 52a or the screw portion 52b of the stopping bolt 52,
A plurality of anti-skid means (59) are further provided between the support frame (21) and the bottom frame (23)
Wherein the anti-skid means (59) comprises a first anti-skid member (59A) and a second anti-skid member (59B) configured to be inclined so as to face each other toward the center.
Wherein a plurality of baffles (15) are formed in a zigzag manner in the reaction tank (10) to increase the reaction time between raw water and ozone.
The inlet (11) is provided with decompression means (111) for decompressing the raw water,
Wherein the discharge unit (13) further includes a UV reaction tank (135) to sterilize the discharged purified water by ultraviolet rays.
The discharge unit 13 is provided with an inspection unit 133 for measuring the amount of COD and the amount of ozone of the purified water discharged through the discharge unit 13,
When the COD of the reference value or more is checked in the purified water, purified water is sent to the flow path 17 connected to the ozone dissolution means 20 so that the purified water flows into the reaction tank 10 through the inlet portion 11,
Wherein the COD is discharged through the discharge passage (131) of the discharge unit (13) when the COD is below the reference value in the purified water.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020150112586A KR101765555B1 (en) | 2015-08-10 | 2015-08-10 | Reverse osmosis enrichment water ozone reaction equipment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020150112586A KR101765555B1 (en) | 2015-08-10 | 2015-08-10 | Reverse osmosis enrichment water ozone reaction equipment |
Publications (2)
Publication Number | Publication Date |
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KR20170018664A KR20170018664A (en) | 2017-02-20 |
KR101765555B1 true KR101765555B1 (en) | 2017-08-07 |
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KR1020150112586A KR101765555B1 (en) | 2015-08-10 | 2015-08-10 | Reverse osmosis enrichment water ozone reaction equipment |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102441596B1 (en) * | 2022-01-07 | 2022-09-07 | (주)엔키이앤씨 | water treatment system using the ozone oxidation |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3698093B2 (en) * | 2001-11-22 | 2005-09-21 | 東レ株式会社 | Water treatment method and water treatment apparatus |
KR100925531B1 (en) * | 2009-01-14 | 2009-11-05 | 임찬호 | Micro Bubble Reactor for Treatment of Wastewater |
KR101360019B1 (en) * | 2013-03-15 | 2014-02-12 | 재단법인 한국계면공학연구소 | Method of reusing reverse osmosis concentrated water and system using the same |
-
2015
- 2015-08-10 KR KR1020150112586A patent/KR101765555B1/en active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3698093B2 (en) * | 2001-11-22 | 2005-09-21 | 東レ株式会社 | Water treatment method and water treatment apparatus |
KR100925531B1 (en) * | 2009-01-14 | 2009-11-05 | 임찬호 | Micro Bubble Reactor for Treatment of Wastewater |
KR101360019B1 (en) * | 2013-03-15 | 2014-02-12 | 재단법인 한국계면공학연구소 | Method of reusing reverse osmosis concentrated water and system using the same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102441596B1 (en) * | 2022-01-07 | 2022-09-07 | (주)엔키이앤씨 | water treatment system using the ozone oxidation |
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