KR101754469B1

KR101754469B1 - Method of treatment brush for gel nail polish

Info

Publication number: KR101754469B1
Application number: KR1020150082333A
Authority: KR
Inventors: 김한주
Original assignee: 김한주
Priority date: 2014-11-11
Filing date: 2015-06-11
Publication date: 2017-07-06
Also published as: KR20160056263A

Abstract

The present invention provides a binding agent comprising a binding substance solution comprising a binding substance and a solvent, a step of immersing the solution in a brush portion of the gel for a manicure, and a step of volatilizing the solvent through room temperature or heating and volatilization And a method of treating a brush for manicure.

Description

Technical Field [0001] The present invention relates to a method for treating a gel nail polish,

The techniques disclosed herein relate to brushing techniques for gel nail polish.

Gel nail polish contains ultraviolet absorber, which uses a technique of curing liquid nail polish under the ultraviolet lamp in a solid state over nails. It is more popular with women than conventional nail polish which has to be dried for a long time after putting a collar on the nail have.

Currently used general manicure brushes are manufactured by binding a brush brush using starch powder. However, the brush which is bound with starch powder is not loosened in the gel nail polish, so that it is not usable because of the aggregation phenomenon. A prior art for preventing deformation of the brush for manicure is Korean Patent No. 0331735, which relates to a brush surface-impregnated with acetylated polyvinyl alcohol. However, the above-mentioned prior art document is a brush surface treatment method for nail polish which shows hydrophilicity and is not suitable for use in gel manicure. Therefore, the present gel nail polish brush is used without binding the brush sole, so that the gel contents are filled in the gel nail polish filling bottle and the brush is deformed during the capping of the brush.

Accordingly, a first object of the present invention is to provide a method for improving brush deformation and defects, which is caused by using a brush brush for gel manicure without binding.

A second problem to be solved by the present invention is to provide a binding solution for a gel nail polish which can bind a brush for gel manicure while releasing the binding of the brush in the gel nail polish, thereby exhibiting excellent wetting property of the brush on the nail.

In order to achieve the first object of the present invention, there is provided a method for producing a binding material, comprising the steps of: providing a binding material solution containing binding material and a solvent; Immersing the brush part of the gel manicure brush in the binding material solution; And volatilizing the solvent through room temperature or heating volatilization. The present invention also provides a method for treating a brush for a gel for manicure.

According to an embodiment of the present invention, the binding substance is a disaccharide ester or a polysaccharide ester compound, and the disaccharide or polysaccharide ester compound is esterified with a part or all of hydroxyl groups of a disaccharide or a polysaccharide. Processing method.

According to another embodiment of the present invention, the disaccharide or polysaccharide ester compound is selected from the group consisting of sucrose benzoate (SB), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) The present invention provides a method for treating a gel for a gel for manicure comprising at least one binding substance selected from the group consisting of

According to another embodiment of the present invention, the solvent is selected from the group consisting of butyl acetate (BA), acetone (Ac), ethyl acetate (EA), and ethanol A method for treating a gel for manicure comprising at least one solvent is provided.

According to another embodiment of the present invention, there is provided a method of treating a brush for gel nail polish comprising 5 to 60 wt% of the binding substance with respect to the binding substance solution.

In order to achieve the second object, the present invention provides a binding agent solution for a gel for manicure comprising a binder and a solvent for forming a film on a surface of a fiber of a brush.

According to one embodiment of the present invention, the binding substance is a disaccharide ester or polysaccharide ester compound, and the disaccharide or polysaccharide ester compound is a compound in which a part or all of the hydroxyl groups of the disaccharide or polysaccharide is esterified. Solution.

According to another embodiment of the present invention, the disaccharide or polysaccharide ester compound comprises at least one binding substance selected from the following formulas (1) to (4):

[Chemical Formula 1] < EMI ID =

[Chemical Formula 3]

Wherein R is C ₁ to C ₁₂ alkyl or -COR 'group (acyl group), R' is C ₁ to C ₁₂ alkyl or C ₆ to C ₁₈ aryl, and n is 1 Lt; / RTI > (The R groups in each formula may be different, and at least one of the R groups is -COR 'group).

According to another embodiment of the present invention, the disaccharide or polysaccharide ester compound is selected from the group consisting of sucrose benzoate (SB), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB ). The binding substance for a gel for manicure according to claim 1, wherein the binding substance comprises a binding substance selected from the group consisting of:

According to another embodiment of the present invention, the solvent is selected from the group consisting of butyl acetate (BA), acetone (Ac), ethyl acetate (EA) and ethanol Of the binding agent solution for gel nail polish.

According to another embodiment of the present invention, the binding material solution for gel nail polish includes 5 to 60 wt% of binding material for the binding material solution.

According to the brushing technique for gel nail polish according to an embodiment of the present invention, it is possible to manufacture a brush for a gel manicure in which the brush does not clump in the gel nail polish and deformation of the brush does not occur. The binding material of the brush for gel nail polish forms a film on the surface of the brush fiber and is widely used for the nail care product. It is harmless to the human body and can give excellent brush binding effect.

FIG. 1 is a process flow chart illustrating a method of processing a brush for a gel nail polish according to an embodiment of the present invention.
FIG. 2 is a view showing a binding state of a brush for gel nail polish according to an embodiment of the present invention.
Fig. 3 shows an embodiment of the binding state of the brush for gel nail polish.

The present invention relates to a method of processing a brush for a gel manicure, which can bind a brush by immersing a brush for gel manicure in a binding substance solution containing a binding substance and a solvent.

FIG. 1 is a process flow chart illustrating a method of processing a brush for a gel nail polish according to an embodiment of the present invention. In step S1, a binding substance solution containing a binding substance and a solvent is provided. The binding substance solution of the brush for gel nail polish includes a binding substance and a solvent which form a film on the fiber surface of the brush.

The binding material may be a substance which is soluble in gel manicure and can form a coating on the surface of the brush fiber to bind the brush. Also, the binding substance is a substance suitable for use in a nail care product, which is harmless to a human body and is dissolved in a gel nail polish solution and does not change the properties of nail polish, and may be a disaccharide ester or polysaccharide ester compound. The above-mentioned disaccharide ester or polysaccharide ester compound means that some or all of the hydroxyl groups of the disaccharide or polysaccharide are esterified. The disaccharide may be sucrose, maltose and lactose, and the polysaccharide may be cellulose.

Wherein the sucrose is a disaccharide to which glucose and fructose are bonded, the maltose is a disaccharide to which two glucose are bonded, and the lactose is a disaccharide to which galactose and glucose are bonded. The following formulas (1) to (3) show that some or all of the hydroxyl groups of sucrose, maltose and lactose are esterified. That is, the hydrogen of the hydroxyl group in the disaccharide may be substituted with an R group.

[Chemical Formula 1] < EMI ID =

(3)

The cellulose is a polysaccharide in which glucose is bonded to several hundred or more through a? (1? 4) glucosidic bond. The following formula (4) indicates that some or all of the hydroxyl groups in cellulose are esterified. That is, the hydrogen of the hydroxyl group in the cellulose may be substituted with an R group.

[Chemical Formula 4]

(n = 100 to 15,000)

In the above Chemical Formulas 1 to 4, the R group may be hydrogen, C ₁ to C ₁₂ alkyl, or -COR 'group (acyl group). Where R 'may be a C ₁ to C ₁₂ alkyl or C ₆ to C ₁₈ aryl. Specifically, the -COR 'group may be acetyl, propionyl, butyryl, valeryl, capryl, benzoyl, and the like. Some or all of the hydroxyl groups in the disaccharide ester or polysaccharide ester compound may be substituted with at least one R group. The R group may be hydrogen, C ₁ to C ₁₂ alkyl or -COR 'group, but at least one hydroxyl group of the R groups in the disaccharide or polysaccharide ester compound is substituted with -COR' group. Each of the hydroxyl groups in the disaccharide or polysaccharide may be substituted with a different R group. That is, the R groups in the disaccharide or polysaccharide may be different from each other. For example, it is meant that different hydroxyl groups in the cellulose may be substituted with acetyl and propionyl, respectively. The polymerization degree of the polysaccharide ester compound may be 100 to 15,000.

The binding substance is preferably selected from the group consisting of sucrose benzoate (SB), cellulose acetate, cellulose propionate, cellulose butyrate, cellulose acetate propionate, CAP) and cellulose acetate butyrate (CAB).

The binding substance contained in the binding substance solution may be at least one binding substance selected from the group consisting of a disaccharide or a polysaccharide ester compound, and the binding substance may be 5 to 60 wt% relative to the binding substance solution, Is less than 5 to 30 wt%, the formation of a film on the surface of the brush fibers is not evenly performed and the binding effect of the brush can be lowered. If the ratio is above the range, the binding force between the brush fibers is too strong and it is difficult to apply the nail polish on the nail .

The solvent may be a substance such as alcohols, ketones, amines, etc. which can easily dissolve the binding substance and can be volatilized at room temperature or a warmed state. The solvent may be polar or polar solvent. Preferred examples are butyl acetate, acetone, ac, ethyl acetate, ethanol and the like which are high in solubility and low in cost. These solvents may be used in combination of two or more. The time and temperature necessary to dissolve the binding substance in the solvent may vary depending on the solubility of the binding substance in the solvent, the concentration of the binding substance to the solution, and the like.

In step S2, the brush part of the gel for manicure is immersed in the solution. Gel brushes for nail polish can use synthetic mosquito brushes made of nylon and natural mosquito brushes made of animal hair. The immersion time can be sufficiently secured even for a few seconds.

In step S3, the solvent is volatilized through room temperature or heated volatilization. The temperature for the volatilization of the solvent and the treatment time may vary depending on the type of the solvent. For example, when acetone solvent is used, it can be treated at room temperature or higher and 60 ° C or lower, and when ethyl acetate is used, it can be treated at room temperature or higher and 80 ° C or lower. FIG. 2 is a view showing a binding state of a brush for gel nail polish according to an embodiment of the present invention.

While the present invention will be described with reference to the following examples, the technical idea of the present invention is not limited to the following examples.

[Example]

Experiment of binding effect of brush

Example 1

100 g of butyl acetate (BA) was added to four flasks. Acetone (Ac) and ethyl acetate (EA) were added to four flasks each in an amount of 100 g each. 5 g, 20 g, 40 g and 60 g of sucrose benzoate (SB) were added to each flask containing butyl acetate to give final concentrations of the binding substance solutions of 5 wt%, 20 wt%, 40 wt% and 60 wt%, respectively Respectively. 5 g, 20 g, 40 g, and 60 g of sucrose benzoate were added to the flask equipped with acetone and ethanol. The mixture was stirred at room temperature for 30 minutes to dissolve sucrose benzoate. After the brush for gel nail polish was immersed in the finished binding material solution, it was taken out from the solution and the solvent in the brush was volatilized at a temperature higher than the volatilization temperature of the solvent as shown in Table 1 below. Table 1 below shows the treatment time of the binding substance solution required for brush binding. The percentages of the solution concentrations in Tables 1 to 6 all indicate% by weight.

5% 20% 40% 60% SB (Ba) One 2 3 5 SB (Ac) One 2 3 5 SB (Et) One 2 3.5 6

(Unit: Sealing and Drying Time, Hour)

Example 2

100 g of the same solvent as in Example 1 was prepared in four flasks, and 5 g, 10 g, 15 g and 20 g of a binding substance cellulose acetate butyrate (CAB) Were added so that the final concentrations were 5 wt%, 10 wt%, 15 wt%, and 20 wt%, respectively. And the mixture was stirred at room temperature for 30 minutes until the binding substance was dissolved. The brush for gel nail polish was immersed in the resulting binding substance solution, and immediately taken out from the solution, the solvent in the brush was volatilized at a temperature higher than the volatilization temperature of the solvent. Table 2 below shows the treatment time of the binding substance solution required for brush binding.

5% 10% 15% 20% CAB (Ba) 1.5 3 3.5 6 CAB (Ac) 1.5 3 3.5 6 CAB (Et) 1.5 3 4 6.5

(Unit: Sealing and Drying Time, Hour)

Example 3

100 g of the same solvent as in Example 1 was prepared in four flasks, and 5 g, 10 g, 15 g, and 20 g of a binding substance cellulose acetate propionate (CAP) were placed in four flasks of each solvent, And the final concentrations of the solutions were 5 wt%, 10 wt%, 15 wt%, and 20 wt%, respectively. And the mixture was stirred at room temperature for 30 minutes until the binding substance was dissolved. The brush for gel nail polish was immersed in the resulting binding substance solution, and immediately taken out from the solution, the solvent in the brush was volatilized at a temperature higher than the volatilization temperature of the solvent. Table 3 below shows the treatment time of the binding substance solution required for brush binding.

5% 10% 15% 20% CAP (Ba) 1.5 3 3 5 CAP (Ac) 1.5 3 3 5 CAP (Et) 1.5 3 3.5 5

(Unit: Sealing and Drying Time, Hour)

Bonding loosening experiment of color gel nail polish

Comparative Example 1

Starch used as a binding material for general manicure was treated with a brush for color gel nail polish and stored for 6, 12, 18 and 24 hours in a color gel nail polish. O when the binding of the brush is released, and X when the binding is not released are shown in Table 4 below.

Example 4

Each of the brushes bound with sucrose benzoate in Examples 1 to 3 was stored in color gel nail polish for 6, 12, 18 and 24 hours, respectively, and binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 4 below. Fig. 3 is an embodiment of the binding-release state of the brush for gel nail polish.

Example 5

Each of the brushes bound with cellulose acetate butyrate in Examples 1 to 3 was stored in color gel nail polish for 6, 12, 18, and 24 hours, respectively, and binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 4 below.

Example 6

Each of the brushes bound with cellulose acetate propionate in Examples 1 to 3 was stored in a color gel nail polish for 6, 12, 18 and 24 hours, respectively, and binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 4 below.

6 hours 12 hours 18 hours 24 hours Comparative Example 1 Starch processing brush X X X X Example 4 Binding processing
Brush (SB / Ba) 5% X O O O 20% X X O O 40% X X X X 60% X X X X Binding processing
brush
(SB / Ac) 5% X O O O 20% X O O O 40% X X X X 60% X X X X Binding processing
brush
(SB / Et) 5% X O O O 20% X X O O 40% X X X X 60% X X X X Example 5 Binding processing
brush
(CAB / Ba) 5% O O O O 10% X O O O 15% X X O O 20% X X X O Binding processing
brush
(CAB / Ac) 5% O O O O 10% X O O O 15% X X O O 20% X X O O Binding processing
brush
(CAB / Et) 5% X O O O 10% X X O O 15% X X X O 20% X X X O Example 6 Binding processing
brush
(CAP / Ba) 5% O O O O 10% X O O O 15% X X O O 20% X X X O Binding processing
brush
(CAP / Ac) 5% O O O O 10% X O O O 15% X X O O 20% X X O O Binding processing
brush
(CAP / Et) 5% X O O O 10% X X O O 15% X X X O 20% X X X O

Experiment of binding loosening of pearl gel manicure

Comparative Example 2

Starch used as binding material for general manicure was treated with a brush for pearl gel nail polish and stored for 6, 12, 18, and 24 hours in a pearl gel manicure, followed by binding loosening. O when the binding of the brush is released, and X when the binding is not released are shown in Table 5 below.

Example 7

Each of the brushes which were bound with sucrose benzoate in Examples 1 to 3 was stored in a pearl gel manicure for 6, 12, 18 and 24 hours, respectively, and then the binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 5 below.

Example 8

Each of the brushes bound with cellulose acetate butyrate in Examples 1 to 3 was stored in a pearl gel manicure for 6, 12, 18, and 24 hours, respectively, and binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 5 below.

Example 9

Each of the brushes bound with cellulose acetate propionate in Examples 1 to 3 was stored in a pearl gel manicure for 6, 12, 18 and 24 hours, respectively, and binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 5 below.

6 hours 12 hours 18 hours 24 hours Comparative Example 2 Starch processing brush X X X X Example 7 Binding processing
Brush (SB / Ba) 5% X O O O 20% X X O O 40% X X X X 60% X X X X Binding processing
brush
(SB / Ac) 5% X O O O 20% X X O O 40% X X X X 60% X X X X Binding processing
brush
(SB / Et) 5% X O O O 20% X O O O 40% X X X X 60% X X X X Example 8 Binding processing
brush
(CAB / Ba) 5% O O O O 10% X O O O 15% X X O O 20% X X X O Binding processing
brush
(CAB / Ac) 5% O O O O 10% X O O O 15% X X O O 20% X X O O Binding processing
brush
(CAB / Et) 5% X O O O 10% X X O O 15% X X X O 20% X X X O Example 9 Binding processing
brush
(CAP / Ba) 5% O O O O 10% X O O O 15% X X O O 20% X X X O Binding processing
brush
(CAP / Ac) 5% O O O O 10% X O O O 15% X X O O 20% X X O O Binding processing
brush
(CAP / Et) 5% X O O O 10% X X O O 15% X X X O 20% X X X O

Glue-gel nail polish bond loosening experiment

Comparative Example 3

Starch used as a binding agent for general manicure was treated with a brush for a glitter gel nail polish, and then kept in a pearl gel manicure for 6, 12, 18, and 24 hours, respectively, and then the binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 6 below.

Example 10

Each of the brushes bound with sucrose benzoate in Examples 1 to 3 was stored in a gel-gel manicure for 6, 12, 18, and 24 hours, respectively, and binding cohesion was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 6 below.

Example 11

Each of the brushes bound with cellulose acetate butyrate in Examples 1 to 3 was stored in a glycol gel manicure for 6, 12, 18, and 24 hours, respectively, and binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 6 below.

Example 12

Each of the brushes bound with cellulose acetate propionate in Examples 1 to 3 was stored in a gel-gel manicure for 6, 12, 18, and 24 hours, respectively, and binding loosening was observed. O when the binding of the brush is released, and X when the binding is not released are shown in Table 6 below.

6 hours 12 hours 18 hours 24 hours Comparative Example 3 Starch processing brush X X X X Example 10 Binding processing
Brush (SB / Ba) 5% X O O O 20% X X O O 40% X X X X 60% X X X X Binding processing
brush
(SB / Ac) 5% X O O O 20% X O O O 40% X X X X 60% X X X X Binding processing
brush
(SB / Et) 5% X O O O 20% X X O O 40% X X X X 60% X X X X Example 11 Binding processing
brush
(CAB / Ba) 5% O O O O 10% X O O O 15% X X X O 20% X X X - Binding processing
brush
(CAB / Ac) 5% O O O O 10% X O O O 15% X X X X 20% X X X X Binding processing
brush
(CAB / Et) 5% X O O O 10% X X O O 15% X X X O 20% X X X X Example 12 Binding processing
brush
(CAP / Ba) 5% O O O O 10% X O O O 15% X X X X 20% X X X X Binding processing
brush
(CAP / Ac) 5% O O O O 10% X O O O 15% X X O O 20% X X O O Binding processing
brush
(CAP / Et) 5% X O O O 10% X X O O 15% X X X O 20% X X X X

Regardless of the type of binding material, the higher the concentration of binding material, the greater the drying time of the brush bar after binding. In the case of brushes which were bound to starch used as a binding material in a general manicure when a bundled brush was stored in collar, gel or glitter gel nail polish respectively and binding loosening was observed, binding loosening was observed in any gel manicure It was not. Brushes treated with binding substances sucrose benzoate (SB), cellulose acetate butyrate (CABB) and cellulose acetate propionate (CAP) showed binding loosening after a certain period of time in the gel nail polish.

When the brushes bound to the color gel nail polish with SB were stored for 6, 12, 18 and 24 hours, the brushes bound with 5% SB showed binding loosening after 12 hours and the brushes bound with 20% After 18 hours, cohesion loosening appeared. 40, and 60% SB, the binding loosening did not occur within 24 hours.

The higher the concentration of the binding substance treated in the brush, the longer the time required for binding. In the case of brushes bound with 5% SB, binding loosening occurred after 12 hours in color gel nail polish. When 20% SB was bound, binding loosening occurred after 18 hours. In the case of a brush bound to SB of 40% or more, no binding loosening phenomenon was observed within 24 hours.

The CAB and CAP bound brushes had the same binding loosening effect in the color gel nail polish. Brushes bound with CAB and CAP showed better binding loosening effect than brushes bound with SB. The brushes bound with 5% SB showed binding loosening effect after 12 hours in color gel nail polish, while the brushes bound with CAB and CAP with same concentration showed binding loosening effect after 6 hours.

The brushes bound with SB showed the same binding releasing effect regardless of the type of gel manicure. However, the solution of 20% SB binding agent dissolved in ethanol showed binding loosening effect after 18 hours in color gel nail polish, while in the case of pearl gel manicure and glitter gel nail polish, binding loosening effect appeared after 12 hours. The binding loosening effect of the brushes bound to SB was found to be largely unaffected by the type of gel manicure.

The CAB and CAP bound brushes had the same binding loosening effect in color gel manicure and pulp gel manicure. However, the binding loosening effect in the glitter gel manicure was decreased when the binding substance concentration was 15% or more as compared with the color and the pulp gel manicure. Compared to the brushes bound to SB, the binding loosening effect of CAB and CAP was influenced by the type of gel nail polish.

While the present invention has been described in connection with what is presently considered to be the most practical and preferred embodiment, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the invention. Therefore, the embodiments described in the present invention are not intended to limit the scope of the present invention but to limit the scope of the present invention. The scope of protection of the present invention should be construed according to the claims, and all technical ideas within the scope of equivalents should be construed as falling within the scope of the present invention.

Claims

Providing a binding material solution comprising a binding material and a solvent;
Immersing the brush part of the gel manicure brush in the binding material solution;
And volatilizing said solvent through ambient or warmed volatilization,
The binding substance is a disaccharide ester or polysaccharide ester compound, and the disaccharide or polysaccharide ester compound is obtained by esterifying a part or all of the hydroxyl groups of the disaccharide or polysaccharide,
The solvent is selected from the group consisting of butyl acetate (BA), acetone (Ac),
Wherein the at least one solvent comprises at least one solvent selected from the group consisting of ethyl acetate (EA) and ethanol.

delete

The method according to claim 1,
The disaccharide or polysaccharide ester compound may be at least one selected from the group consisting of sucrose benzoate (SB), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) A method of treating a brush for a gel curing gel of UV curing type comprising a binding substance.

delete

The method of claim 1,
Wherein the binding substance is contained in an amount of 5 to 60 wt% with respect to the binding substance solution.

In a binding substance solution of a brush for a gel nail polish,
Form a film on the fiber surface of the brush and dissolve in UV curing gel manicure
A binding substance and a solvent,
Wherein the binding substance is a disaccharide ester or polysaccharide ester compound,
The disaccharide or polysaccharide ester compound may be a disaccharide or polysaccharide having a hydroxyl group
Some or all of which are esterified,
Wherein the solvent comprises at least one solvent selected from the group consisting of butyl acetate (BA), acetone (Ac), ethyl acetate (EA) and ethanol. Binding material solution.

delete

The method according to claim 6,
Wherein the disaccharide or polysaccharide ester compound comprises at least one binding substance selected from the following Formulas 1 to 4:
[Chemical Formula 1] < EMI ID =

[Chemical Formula 3]

The method according to claim 6,
The disaccharide or polysaccharide ester compound may be at least one selected from the group consisting of sucrose benzoate (SB), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) UV curing gel containing binding substance. Binding agent solution for manicure.

delete

The method according to claim 6,
Wherein the binding substance is contained in an amount of 5 to 60 wt% with respect to the binding substance solution.