KR101740730B1 - Method and apparatus for producing glass sheet - Google Patents
Method and apparatus for producing glass sheet Download PDFInfo
- Publication number
- KR101740730B1 KR101740730B1 KR1020100022327A KR20100022327A KR101740730B1 KR 101740730 B1 KR101740730 B1 KR 101740730B1 KR 1020100022327 A KR1020100022327 A KR 1020100022327A KR 20100022327 A KR20100022327 A KR 20100022327A KR 101740730 B1 KR101740730 B1 KR 101740730B1
- Authority
- KR
- South Korea
- Prior art keywords
- glass
- forming apparatus
- heater
- ribbon
- glass plate
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
- C03B17/064—Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Glass Compositions (AREA)
- Cell Separators (AREA)
Abstract
The present invention is characterized in that the molten glass is fused at the lower end 4e of the glass sheet forming apparatus 4 to form a glass ribbon and the glass ribbon 9 is conveyed along a plurality of rollers 6 disposed below the glass sheet forming apparatus 4. [ The glass plate is manufactured by a down-draw method in which the glass plate is conveyed downward. The heater 8 is provided in the space between the lower end 4e of the glass sheet forming apparatus 4 and the roller 6a positioned closest to the glass sheet forming apparatus 4 and the end of the glass ribbon 9 immediately after fusion The glass ribbon 9 is molded and conveyed while being locally heated by the heater 8. [
Description
The present invention relates to a manufacturing method and a manufacturing apparatus for a glass plate. TECHNICAL FIELD The present invention relates to a technique for manufacturing a glass plate by a down-draw method in particular.
The down-draw method is a method in which a molten glass that flows over a groove on the upper side of a wedge-shaped glass sheet forming apparatus is flowed downward along the side wall of the glass sheet forming apparatus and fused at the lower end (root) Method. The glass ribbon is gradually cooled in the furnace while being supported by a roll disposed under the glass plate forming apparatus, and is cut so as to obtain a glass plate of a desired size.
The down-draw method is suitable for the production of flat and thin glass substrates, for example, glass substrates for flat panel displays. For example, Japanese Patent Application Laid-Open No. 2008-133174 discloses a technique for stably producing an ultra-thin glass plate (for example, 0.5 mm or less). Specifically, after the thickness of the glass ribbon is reduced to the initial thickness immediately below the formed body (glass plate forming apparatus), a reheating means (heater) disposed below the regulating means (cooling roller) And the softened glass ribbon is extended downward to further reduce the thickness of the plate.
Further, in order to form a high-quality glass ribbon, it is important to control the temperature in the width direction of the molten glass on the side wall of the glass plate forming apparatus. For example, Japanese Unexamined Patent Publication (Kokai) No. 2007-112665 discloses that a heater, which is densely present in the arrangement of heat generating elements, is provided at a position facing a side wall of a formed article (glass plate forming apparatus) A technique for making the distribution uniform is described. Japanese Patent Application Laid-Open No. 2008-69024 discloses a technique for uniformizing the temperature distribution in the width direction of the molten glass by energizing the platinum film on the surface of the fusion cell (glass plate forming apparatus).
Incidentally, the end portion of the glass ribbon formed by the down-draw method usually has a form shown in Fig. However, the end portion of the glass ribbon is not always limited to this shape, and may be divided into two parts. An end portion having a bifurcated shape may cause difficulty in cutting the glass ribbon or may cause cracks in the glass ribbon. In addition, due to the end portion having a bifurcated shape, the thickness of the central portion (product portion) may be uneven, and the yield may be lowered.
An object of the present invention is to prevent defective shape of the end portion of a glass ribbon.
The present inventors have investigated in detail the cause of defective shape of the end portion of the glass ribbon. As a result, the present inventors have completed the present invention by paying attention to the fact that the viscosity of the glass ribbon immediately after fusion is a main factor determining the final shape of the end portion of the glass ribbon.
That is, the present invention relates to a glass sheet forming apparatus for forming a glass ribbon by fusing a molten glass at the lower end of a glass sheet forming apparatus and for forming a glass sheet by a down-draw method in which the glass ribbon is conveyed downward along a plurality of rolls arranged below the glass sheet- A heater is provided in a space between the lower end of the glass plate forming apparatus and the roll located closest to the glass plate forming apparatus and the end of the glass ribbon immediately after fusion is locally heated with the heater, A method of manufacturing a glass plate for forming and transporting a glass ribbon.
According to another aspect of the present invention, there is provided a glass sheet forming apparatus comprising a glass sheet forming apparatus having a wedge-shaped cross section, and a glass sheet forming apparatus arranged below the glass sheet forming apparatus, A plurality of rolls for conveying the glass ribbon formed by fusing to the lower side of the glass plate forming apparatus and a plurality of rolls for feeding the lower end of the glass plate forming apparatus and the glass plate, And a heater provided in a space between the rolls positioned closest to the molding apparatus.
The glass ribbon immediately after the fusion is not completely solidified, but is in the state of viscous fluid and is therefore susceptible to ambient temperature. Normally, the end portion of the glass ribbon is cooled faster than the center portion of the glass ribbon. If the temperature drop at the end portion is too fast as compared with the temperature drop at the center portion, unevenness of the viscosity in the width direction becomes large, and the shape of the end portion is liable to be defective.
On the other hand, according to the present invention, the end portion of the glass ribbon immediately after fusion is locally heated with a heater. That is, only the end portion of the glass ribbon is prevented from being rapidly cooled immediately after being peeled from the glass sheet forming apparatus. As a result, the temperature distribution in the width direction of the glass ribbon, that is, the viscosity distribution becomes uniform, and the defective shape of the end portion becomes less likely to occur. The present invention can be carried out by utilizing an existing apparatus, so that the present invention is also excellent in cost.
In order to obtain the same effect as the present invention, it is also conceivable to raise the atmospheric temperature in the furnace in the vicinity of the lower end of the glass plate forming apparatus. In this way, the same effect as that of the present invention may be obtained. However, the present invention is advantageous in terms of power consumption because it is sufficient to locally heat the end portion of the glass ribbon. In addition, if the atmosphere in the furnace is set to a high temperature, deterioration of various parts rapidly progresses and the life of the device becomes short, which is not preferable.
The "end portion of the glass ribbon" refers, for example, to a region extending from the side surface of the glass ribbon by about 50 mm inward.
1 is a schematic front view of an apparatus for manufacturing a glass plate according to an embodiment of the present invention
2 is a schematic vertical sectional view along the line II-II of the apparatus for producing a glass plate shown in Fig. 1
3 is a partial enlarged view showing a detailed position of the heater
4 is a schematic view showing the dimensional relationship of the guide and the heater;
5 is a schematic view showing a modification example of the heater
6 is a schematic view showing a positional relationship between a glass ribbon and a roll;
[Fig. 7] A sectional view showing a shape of an end portion of a glass ribbon
Hereinafter, an embodiment of the present invention will be described with reference to the accompanying drawings.
1 and 2, an
The
The glass
As shown in Fig. 2, the glass
The
As shown in Fig. 1, the
As is well known, loss of transparency is a phenomenon that crystal grains are formed in glass and transparency of glass is lowered. In the case of producing a glass plate by the down-draw method, loss of transparency tends to occur at the end of the
When the
In this embodiment, the
As shown in Fig. 3, the width of the
2, the
The energization (set temperature) of the
4, a
The output of the
The
The end portion of the
For example, as shown in Fig. 2 of Japanese Patent Application Laid-Open No. 2008-133174, it is also possible to determine the positions of the rolls so that all the rolls do not sandwich the ends of the glass ribbon. In the case where the viscosity of the end portion is high, it is wise to avoid the end portion from being inserted into the roll from the viewpoint of carrying out stable transportation or preventing the glass ribbon from cracking.
On the other hand, according to the present embodiment, since the rise of the viscosity of the
The operation of the glass
The
The viscosity of the molten glass at the
In particular, recently, the demand for large-area glass plates is increasing. For example, the size of a glass substrate for a liquid crystal display of the tenth generation is 2850 mm x 3050 mm. The wider the width of the glass ribbon, the more likely the non-uniformity of the viscosity in the width direction occurs, so that the effect obtained by applying the present invention also increases. A typical glass composition of a glass substrate for a flat panel display is shown below.
SiO 2 : 57 to 70 mass%
Al 2 O 3 : 13 to 19 mass%
B 2 O 3 : 8 to 13 mass%
MgO: 0 to 2 mass%
CaO: 4 to 6 mass%
SrO: 2 to 4 mass%
BaO: 0 to 2 mass%
Na 2 O: 0 to 1 mass%
K 2 O: 0 to 1 mass%
As 2 O 3 : 0 to 1 mass%
Sb 2 O 3 : 0 to 1 mass%
SnO 2 : 0 to 1 mass%
Fe 2 O 3 : 0 to 1 mass%
ZrO 2 : 0 to 1 mass%
<Examples>
A glass raw material which was combined so as to have the following composition was dissolved at 1550 占 폚 and refined at 1600 占 폚 to obtain a glass raw material having a composition of 1550 Lt; 0 > C to obtain a molten glass. The reason why the total mass exceeds 100% is that an error due to rounding is included.
SiO 2 : 60.9 mass%
Al 2 O 3 : 16.9 mass%
B 2 O 3 : 11.6 mass%
MgO: 1.7 mass%
CaO: 5.1 mass%
SrO: 2.6 mass%
BaO: 0.7 mass%
K 2 O: 0.25 mass%
Fe 2 O 3 : 0.15 mass%
SnO 2 : 0.13 mass%
Subsequently, molten glass was supplied to the
The molten glass was continuously supplied, and the molten glass was flowed over from the glass
Claims (10)
A space between the lower end of the glass sheet forming apparatus and the roll positioned closest to the glass sheet forming apparatus and being located outside the guide attached to both ends in the longitudinal direction of the glass sheet forming apparatus, By installing a heater,
Forming and transporting the glass ribbon while locally heating the end of the glass ribbon immediately after the fusion with the heater,
Wherein the heater is in the form of a rod extending in the thickness direction of the glass ribbon.
A plurality of rolls arranged downstream of the glass plate forming apparatus for feeding a glass ribbon formed by melting the molten glass flowing from the groove on the upper side of the glass plate forming apparatus to the lower end of the glass plate forming apparatus, and,
A guide attached to both ends in the longitudinal direction of the glass plate forming apparatus and preventing the molten glass from leaking from the side wall of the glass plate forming apparatus,
A space between the lower end of the glass sheet forming apparatus and the roll positioned closest to the glass sheet forming apparatus so as to locally heat the widthwise end of the glass ribbon immediately after the fusion, The heater installed in the space facing the side of the ribbon
And,
Wherein the heater is in the shape of a rod extending in the thickness direction of the glass ribbon.
A controller for controlling energization of the heater based on the detection result of the temperature sensor;
Further comprising:
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JPJP-P-2009-061290 | 2009-03-13 | ||
JP2009061290A JP5005717B2 (en) | 2009-03-13 | 2009-03-13 | Glass plate manufacturing method and manufacturing apparatus |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20100103423A KR20100103423A (en) | 2010-09-27 |
KR101740730B1 true KR101740730B1 (en) | 2017-05-26 |
Family
ID=42974688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020100022327A KR101740730B1 (en) | 2009-03-13 | 2010-03-12 | Method and apparatus for producing glass sheet |
Country Status (4)
Country | Link |
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JP (1) | JP5005717B2 (en) |
KR (1) | KR101740730B1 (en) |
SG (1) | SG165248A1 (en) |
TW (1) | TWI458689B (en) |
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JP5435394B2 (en) * | 2007-06-08 | 2014-03-05 | 日本電気硝子株式会社 | Tempered glass substrate and manufacturing method thereof |
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2009
- 2009-03-13 JP JP2009061290A patent/JP5005717B2/en active Active
-
2010
- 2010-03-05 TW TW099106400A patent/TWI458689B/en active
- 2010-03-09 SG SG201001646-7A patent/SG165248A1/en unknown
- 2010-03-12 KR KR1020100022327A patent/KR101740730B1/en active IP Right Grant
Patent Citations (4)
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JP2006213579A (en) | 2005-02-07 | 2006-08-17 | Nippon Electric Glass Co Ltd | Apparatus and method for forming plate glass |
JP2006321708A (en) * | 2005-04-20 | 2006-11-30 | Nippon Electric Glass Co Ltd | Apparatus and method of forming plate glass |
JP2007054028A (en) | 2005-08-22 | 2007-03-08 | Setsuya Yamazaki | Hygienic device for capturing and removing cockroach or the like while reducing unpleasant feeling at capturing |
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Also Published As
Publication number | Publication date |
---|---|
TWI458689B (en) | 2014-11-01 |
SG165248A1 (en) | 2010-10-28 |
TW201036923A (en) | 2010-10-16 |
KR20100103423A (en) | 2010-09-27 |
JP2010215428A (en) | 2010-09-30 |
JP5005717B2 (en) | 2012-08-22 |
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