KR101739998B1 - Hair care composition containing butyl glycerin ester - Google Patents

Abstract

The present invention relates to a composition for hair, which is characterized by containing butyl glycerin ether. The composition for the hair according to the present invention is excellent in feeling of use such as stickiness while containing a high content of butyl glycerin ether as a moisturizing agent and is superior not only in moistness, softness and smoothness of the hair upon wetting and drying, It can have resistance to microorganisms.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair care composition containing a butyl glycerin ester,

 The present invention relates to a composition for hair containing a specific glycerin derivative, and more particularly to a composition for hair which has improved moisturizing, softness and smoothness of hair when wiped and dried, improved stickiness, .

Moisturization is deeply related to various ingredients such as hair goods, human body products, cosmetics, food, pesticide, feed, medicines, etc. Moisturizing function is well known as one of important quality functions in these products.

Polyhydric alcohols such as glycerin, 1,3-butylene glycol and sorbitol are mainly used as moisturizers for hair products. In addition, pyrrolidone carboxylate and lactate salt, which are the main components of NMF (natural moisturizing factor), are used, and hyaluronic acid sodium produced from microorganisms is also used.

In addition, the moisturizing agent plays an important role not only in the action of the product itself as a moisture retaining agent but also in contributing to the maintenance of the stability of the system. Polyhydric alcohols such as glycerin and sorbitol have excellent moisturizing and water retention ability and are the most versatile moisturizers in terms of safety, stability, and price.

However, in the case of polyhydric alcohols such as glycerin, 1,3-butylene glycol and sorbitol, if the content of the polyhydric alcohol is increased to increase the moisturizing effect, the product quality is deteriorated due to the sticky feel, and the use amount is limited.

In addition, recently, preservatives have been exposed to human hazards, and social and legal regulations on preservatives have been intensified, and new products that do not become contaminated with microorganisms without preservatives are required.

Accordingly, a problem to be solved by the present invention is to provide a hair cosmetic composition having excellent moisturizing ability, low tackiness, and various usefulness, and a composition for hair containing such a component.

In order to solve the above problems, the present invention provides a hair composition comprising butyl glycerin ether of the following formula (1).

In order to solve the problems of the prior art, the inventors of the present invention have tested various components. When the butyl glycerin ether of the above formula (1) is used in the case of using a polyhydric alcohol such as glycerin, 1,3-butylene glycol or sorbitol It was possible to achieve moisturizing effect without tackiness and as a result, it was possible to prevent the limitation of the usage amount of moisturizing agent and deterioration of quality, and as a result, it is possible to provide a composition for hair which is excellent in moistness, smoothness and smoothness of hair when wetted and dried And that such butylglycerin ether has an antibacterial effect suitable for a hair cleansing composition, thereby completing the present invention.

That is, in the hair composition according to the present invention, the butyl glycerin ether not only improves the moistness, softness and smoothness of the hair when wiped and dried, and tackiness but also exhibits an antibacterial effect.

Also, the content of the butyl glycerin ether is preferably 1 to 10% by weight, more preferably 2 to 5% by weight, based on the total amount of the hair composition. When the content of the alkyl glycerin ether is less than 1% by weight, it does not greatly contribute to the moisturizing effect. If the content exceeds 10% by weight, the feeling of use may become sticky.

More preferably, the present invention relates to a composition for hair, comprising a surfactant in an amount of 1-30 wt%, a humectant in an amount of 1-10 wt%, a higher fatty alcohol in an amount of 1-10 wt%, an oil in an amount of 1-10 wt% A composition for hair is provided.

In the hair composition according to the present invention, a nonionic surfactant, a cationic surfactant, an anionic surfactant, a positive surfactant or a mixture thereof may be used as the surfactant.

The anionic surfactant is not particularly limited as long as it can be used in a conventional hair composition, and includes, for example, fatty acid soap (sodium laurate, sodium palmitate, etc.); Higher alkyl sulfate ester salts (sodium lauryl sulfate, potassium lauryl sulfate and the like); Alkyl ether sulfuric acid ester salts (POE-laurylsulfuric triethanolamine, POE-laurylsulfate, etc.); N-acyl sarcosinate (such as sodium lauroyl sarcosine); Higher fatty acid amide sulfonates (N-myristoyl-N-methyltaurin sodium, coconut fatty acid methyltauride sodium, laurylmethyltauride sodium and the like); Phosphoric acid ester salts (sodium POE-oleyl ether phosphate, POE-stearyl ether phosphoric acid, etc.); Sulfosuccinic acid salts (sodium di-2-ethylhexylsulfosuccinate, sodium monooroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauroyl polypropylene glycol sulfosuccinic acid and the like); Alkylbenzenesulfonates (sodium linear decylbenzenesulfonate, triethanolamine linear decylbenzenesulfonate, linear decylbenzenesulfonic acid, etc.); Higher fatty acid ester sulfuric acid ester salts (such as hardened coconut oil fatty acid glycerin sodium sulfate); N-acyl glutamate (monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamic acid, etc.); Sulfuric acid oil (lot oil, etc.); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether carboxylate; ? -olefin sulfonate; Higher fatty acid ester sulfonates; Secondary alcohol sulfuric acid ester salts; Higher fatty acid alkylolamide sulfates; Sodium lauroyl monoethanolamide succinate; N-palmitoyl aspartic acid ditriethanolamine; Sodium caseinate, and the like, but is not limited thereto.

As the nonionic surfactant, a lipophilic nonionic surfactant or a hydrophilic nonionic surfactant can be used and is not particularly limited as long as it can be used in a conventional hair composition. For example, as the lipophilic nonionic surfactant, For example, sorbitan fatty acid esters (sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, Oleate, penta-2-ethylhexyl acid diglycerol sorbitan, tetra-2-ethylhexyl acid diglycerol sorbitan and the like); Glycerin polyglycerin fatty acids (monosaccharic fatty acid glycerin, monoelucic acid glycerin, sesquioleic acid glycerin, monostearic acid glycerin,?,? '- oleic acid pyroglutamic acid glycerin, monostearic acid glycerin malic acid, etc.); Propylene glycol fatty acid esters (such as propylene glycol monostearate); Hardened castor oil derivatives; Glycerin alkyl ethers, etc. Examples of the hydrophilic nonionic surfactant include POE-sorbitan fatty acid esters (POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan tetraoleate and the like); POE-sorbit fatty acid esters (POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol monostearate, and the like); POE-glycerin fatty acid esters (POE-glycerin monostearate, POE-glycerin monoisostearate, POE-glycerin triisostearate, etc.); POE-fatty acid esters (POE distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic molds (Pluronic and the like); POE / POP-alkyl ethers (POE / POP-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether and the like); Tetra POE tetra POP-ethylenediamine condensation products (such as Tetronic); POE-castor oil-hardened castor oil derivative (POE-castor oil, POE-hardened castor oil, POE-hardened castor oil free monoisostearate, POE-hardened castor oil free triisostearate, POE-hardened castor oil free monopyrroglutamate monoisoprene Stearic acid diester, POE-hardened castor oil free maleic acid); POE beeswax / lanolin derivatives (POE-sorbitol beeswax); Alkanolamides (coconut fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid esters; POE-alkylamines; POE-fatty acid amide; Sucrose fatty acid esters; Alkylethoxydimethylamine oxides; Trioctylphosphoric acid, trioleylphosphoric acid, and the like, but is not limited thereto.

The cationic surfactant is not particularly limited as long as it can be used in a conventional hair composition, and includes, for example, alkyltrimethylammonium salts (stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); Alkylpyridinium salts (such as cetylpyridinium chloride); Distearyl chloride dimethyl ammonium dialkyl dimethyl ammonium salt: poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride); Alkyl quaternary ammonium salts; Alkyldimethylbenzylammonium salts; Alkyl isoquinolinium salts; Dialkylmorphonium salts; POE-alkylamines; Alkylamine salts; Polyamine fatty acid derivatives; Amyl alcohol fatty acid derivatives; Benzalkonium chloride; Benzethonium chloride, and the like, but not limited thereto.

The amphoteric surfactant is not particularly limited as long as it can be used in a conventional hair composition, and examples thereof include imidazoline-type amphoteric surfactants (2-undecyl-N, N, N- (hydroxyethyl Carboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt and the like); (2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine, sulfobetaine, etc.) .

Preferred surfactants include polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene stearyl ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene lauryl ether, polyoxyethylene hexyl decyl ether, polyoxyethylene iso Stearyl ether, polyoxyethylene octyldodecyl ether, polyoxyethylene behenyl ether, polyoxyethylene cholesteryl ether, polyoxyethylene hydrogenated castor oil, sorbitan ester, mono fatty acid glycerin, tri fatty acid glycerin, polyglycerin fatty acid ester , Polyoxyethylene glycerin isostearate, polyoxyethylene glycerin triisostearate, polyoxyethylene glycerin monostearate, polyoxyethylene glyceryl distearate, and polyoxyethylene glyceryl tristearate may be used. It is not limited.

In the hair composition according to the present invention, as the humectant, other than the butyl glycerin ether according to the present invention, glycols such as propylene glycol, butylene glycol, dipropylene glycol, and polyethylene glycol within the range not hindering the object of the present invention; Glycerol such as glycerin, diglycerin and polyglycerin; Sugars such as sorbitol, multitol, sucrose, starch sugar, and raquitiol; Hyaluronic acid; A water-soluble component such as betaine may be further used. However, it is preferable that the moisturizing agent is butyl glycerin ether of the above formula 1 for the purpose of the present invention.

As the higher alcohol contained in the hair cosmetic composition of the present invention, an alcohol having 12 to 32 carbon atoms can be used, and examples thereof include linear alcohols (such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol , Oleyl alcohol, cetostearyl alcohol and the like); Branched alcohol such as monostearyl glycerin ether (butyl alcohol), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol etc.) and the like can be used.

In the composition for hair according to the present invention, the kind of the oil is not particularly limited, and a common oil used for a hair composition can be used. Specifically, hydrocarbon oils such as squalane and mineral oil; Caprylic / capric triglyceride, neopentyl glycol dicaprate, 2-octyldodecyl myristate, isopropyl myristate, isocetyl ethyl hexanoate, pentaerythritol tetraethyl hexanoate, butylene glycol dicapryl Ester-based oils such as lactate caprate, hexyl laurate, distearyl malate, cetyl 2-ethylhexanoate, octyldodecanol, and glyceryl triethylhexanoate; Vegetable oils such as olive oil, avocado oil, jojoba oil, and macadamia oil; Animal oils such as lanolin; Silicone oils such as dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, methyltrimethicone, phenyltrimethicone, cyclomethicone and dimethicone may be used alone or in combination.

The composition for hair of the present invention may further contain a flavoring agent, a coloring agent, a preservative, and the like within the range not hindering the object of the present invention, and they may be selected and used in the conventional art.

The composition for hair according to the present invention may be, but not limited to, shampoo, hair conditioner, hair treatment, hair tonic, hair cream, hair spray, hair mousse and the like.

By using butylglycerol ether as a component of hair composition, it is possible to improve the moisturizing, softness and smoothness of hair during wetting and dryness even when a high moisture content agent is applied.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

<Example 1-2 and Comparative Example 1-3>

A hair shampoo composition was prepared by a conventional method using the composition components and contents shown in Table 1 below.

Category (% by weight) Example 1 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 Purified water to 100 to 100 to 100 to 100 to 100 Butyl glycerin ether 2 One - - - glycerin - One 2 - - 1,3-butylene glycol - - - 2 - Sorbitol - - - - 2 Tree sodium 0.05 0.05 0.05 0.05 0.05 Sodium lauryl sulfate (30%) 3 3 3 3 3 Sodium polyoxyethylene lauryl sulfate (30%) 2 2 2 2 2 Coconut fatty acid diethanol
Amide 3 3 3 3 3 Polyquaternium 0.5 0.5 0.5 0.5 0.5 antiseptic q.s. q.s. q.s. q.s. q.s. incense q.s. q.s. q.s. q.s. q.s.

&Lt; Test Example 1 >

For 40 men and women who were randomly selected from the usual scalp patients, the shampoo shown in Table 1 was used once every 2 days for 8 weeks. The degree of stickiness of the scalp and hair was measured when the product was used through interview. The subjects' subjective ratings were evaluated by the following criteria, and the results were averaged to evaluate the effects. The results are shown in Table 2 below.

[Evaluation criteria (degree of stickiness)]

Not very much: 5 points

No: 4 points

Medium: 3 points

There are: 2 points

There is very: 1 point

Evaluation items Example Comparative Example One 2 One 2 3 Degree of scalp and hair stickiness 4.4 4.0 3.8 3.2 3.2

As shown in Table 2, when butyl glycerin ether was used, the effect of reducing stickiness was much better than that of using glycerin, butylene glycol and sorbitol.

&Lt; Example 3-4 and Comparative Example 4-6 >

A hair conditioner composition for hair was prepared by a conventional method using the composition components and the contents shown in Table 3 below.

Category (% by weight) Example 3 Example 4 Comparative Example 4 Comparative Example 5 Comparative Example 6 Purified water to 100 to 100 to 100 to 100 to 100 Butyl glycerin ether 3 1.5 - - - glycerin - 1.5 3 - - 1,3-butylene glycol - - - 3 - Sorbitol - - - - 3 Stearamidopropyl di-methyl
Glyceryl ammonium chloride 2 2 2 2 2 Behenyldimethylglyceryl
Ammonium chloride 2 2 2 2 2 Cetyl alcohol 2 2 2 2 2 Stearyl alcohol 4 4 4 4 4 Cyclomethicone 3 3 3 3 3 antiseptic q.s. q.s. q.s. q.s. q.s. incense q.s. q.s. q.s. q.s. q.s.

&Lt; Test Example 2 &

60 persons were selected for each of the men and women in the 20-40 age group, and the products of the Examples and Comparative Examples were used once every 2 days for 4 weeks. The conditioning effect was then evaluated according to the following evaluation items and evaluation criteria, and the results are shown in Table 4.

[Evaluation Items]

Massage sensation during use, texture during rinse, softness in wet state, softness in dry state

[Evaluation standard]

Very good: 5 points

Good: 4 points

Medium: 3 points

Poor: 2 points

Very bad: 1 point

Evaluation items Example Comparative Example 3 4 4 5 6 Massage feeling when using 4.4 4.2 3.9 4.1 3.0 Rinse texture 4.2 4.2 3.8 3.8 3.1 Softness in wet conditions 4.2 4.0 3.7 3.7 3.2 Softness in dry condition 4.6 4.2 4.0 4.0 3.4

As shown in Table 4, it was confirmed that the compositions of Examples 3 and 4 exhibited superior hair conditioning effects as compared to the compositions of Comparative Examples 4-6.

&Lt; Examples 5-6 and Comparative Example 7-9 >

In order to examine the antibacterial activity, a composition for a hair without antiseptic was prepared by a conventional method using the composition components and contents shown in Table 5 below.

Category (% by weight) Example 5 Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Purified water to 100 to 100 to 100 to 100 to 100 Butyl glycerin ether 2 One - - - glycerin - One 2 - - 1,3-butylene glycol - - - 2 - Sorbitol - - - - 2 Tree sodium 0.05 0.05 0.05 0.05 0.05 Sodium lauryl sulfate (30%) 3 3 3 3 3 Sodium polyoxyethylene lauryl sulfate (30%) 2 2 2 2 2 Coconut fatty acid diethanol
Amide 3 3 3 3 3 Polyquaternium 0.5 0.5 0.5 0.5 0.5 antiseptic - - - - - incense q.s. q.s. q.s. q.s. q.s.

&Lt; Test Example 3 >

In order to test the antimicrobial activity of Examples 5-6 and 7-9, the day when the number of fungi or bacteria started to become 20 CFU / g or less was recorded and shown in Table 6 below. Up to 28 days.

Evaluation items Example Comparative Example 5 6 7 8 9 Germ 7 days More than 18 days More than 28 days More than 28 days More than 28 days Fungus 7 days More than 20 days More than 28 days More than 28 days More than 28 days

As shown in Table 7, in the case of Comparative Example 7-9, there was no antimicrobial activity against fungi and bacteria. In Example 5, the number of fungi and bacteria was sharply decreased, and from the 7th day, 20 CFU / g The number of fungi or bacteria indicating the presence of antibacterial activity.

Claims (3)

A composition for an antifungal agent for use in a composition for hair, which comprises butyl glycerin ether of the following formula (1) as an active ingredient, and butyl glycerin ether is used so as to have a final concentration of 2 to 5% by weight based on the total weight of the composition.
&Lt; Formula 1 >

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