KR101732715B1 - Panel for construction and manufacturing method thereof - Google Patents

Panel for construction and manufacturing method thereof Download PDF

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Publication number
KR101732715B1
KR101732715B1 KR1020160015580A KR20160015580A KR101732715B1 KR 101732715 B1 KR101732715 B1 KR 101732715B1 KR 1020160015580 A KR1020160015580 A KR 1020160015580A KR 20160015580 A KR20160015580 A KR 20160015580A KR 101732715 B1 KR101732715 B1 KR 101732715B1
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KR
South Korea
Prior art keywords
mixture
panel
pulp
blast furnace
glue
Prior art date
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KR1020160015580A
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Korean (ko)
Inventor
김영수
김순복
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김영수
김순복
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Priority to KR1020160015580A priority Critical patent/KR101732715B1/en
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Publication of KR101732715B1 publication Critical patent/KR101732715B1/en

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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • E04B1/80Heat insulating elements slab-shaped
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/44Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials

Abstract

The present invention relates to an insulating panel for construction with stone powder and a manufacturing method thereof and, more specifically, relates to an environmentally friendly construction material and a manufacturing method thereof; wherein as stone powder is used as a main material, when compared to a conventional panel using soil as a main material, high strength and a low expansion contraction rate are provided for the environmentally friendly construction material not to be split and bent. Moreover, functionality such as antibiosis, heat insulation property, incombustibility, or the like are able to be improved.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001]

The present invention relates to a decorative panel for building using a stone and a manufacturing method thereof, and more particularly, to a panel using stone powder as a main material and having a high strength and a low expansion shrinkage as compared with a panel using a conventional soil as a main material And a method of manufacturing the same. The present invention also relates to an eco-friendly building material having improved functions such as antimicrobial property, heat insulation property, and nonflammability.

Conventional heat insulation panels used as building materials such as floors, walls, ceilings and the like generally use quicklime as a main material. However, the above-mentioned quicklime has a problem that not only toxic gas is generated in a fire but mold easily occurs due to the water absorption property inherent in quicklime.

In recent years, attempts have been made to make building materials using soil such as loess as a high-function nonflammable environment-friendly material. However, when soil is used as a main material, strength as a building material is not sufficiently manifested, There is a problem that cracks occur during long-term use due to high expansion / contraction ratio of materials in accordance with the environment.

In addition, when a large amount of other synthetic materials such as an adhesive is mixed in order to reinforce these problems, there is a limitation in that the meaning as a highly functional eco-friendly building material is lost.

On the other hand, building materials made of stone such as marble are used as high-grade building materials due to their unique surface gloss and high strength, And difficulty in mining, processing and moving the stone, which is a disadvantage in that a large amount of cost is required for construction and maintenance.

Therefore, when using incombustible environmentally friendly materials, it is possible to realize high strength while minimizing the amount of synthetic materials used, and it has low volume strain and high absorption capacity against external impact, so there is no cracking or cracking even when used for a long time, It was necessary to develop economical building materials by drastically lowering it.

Korean Patent Publication No. 10-2004-0088705 (published on October 20, 2004)

In order to solve the above problems, it is an object of the present invention to provide a nonflammable eco-friendly material which can realize a high strength while minimizing the amount of synthetic materials used, unlike the conventional building materials using earth as a main material.

In addition, since the present invention has low volume strain due to external environment and high absorption capacity against external impact, there is almost no cracking or cracking even when used for a long time, and the cost of mining, processing and transportation is reduced compared to existing stone, And to provide a building material that can be lowered.

Another object of the present invention is to provide a highly functional building material having a high far infrared ray emissivity and having properties such as deodorization, fungus resistance and antimicrobial properties.

To achieve these and other advantages and in accordance with the purpose of the present invention, as embodied and broadly described herein, there is provided a decorative panel for construction comprising a stone powder, a pulp and a gelatin additive. At this time, the abrasive powder may include any one of blast furnace, marble, elvan, granite, and boulder, and the gelatin additive preferably includes glue.

In addition, it is preferable that the heat insulating panel for construction of the present invention contains 80 to 90 wt% of the limestone, 5 to 10 wt% of the pulp and 5 to 15 wt% of the gelatin additive.

Meanwhile, the thermal insulation panel for construction of the present invention comprises a step of mixing slurry, a pulp mixture solution and a gelatin mixture to prepare a slurry mixture; And shaping the slurry mixture followed by hot air drying.

Preferably, the pulp mixture is a mixture of pulp and water in a ratio of 3: 7 to 5: 5 (w / w), and the gelatin mixture is a mixture of gelatin and water in a ratio of 3: 7 to 5: 5 (w / w) is preferably used.

The thermal insulation panel for construction of the present invention can achieve a high strength while minimizing the amount of synthetic material used by using the stone as a main material and has a low volume strain due to the external environment and a high absorption capacity against an external impact, Can be prevented.

In addition, the constructional insulation panel of the present invention can reduce the mining, processing, and moving costs compared to existing stone to realize a high-grade appearance of the stone while drastically reducing the construction cost. Further, the heat insulation panel having high infrared ray emissivity, deodorizing property, And antimicrobial properties. Thus, functional building materials can be realized.

Fig. 1 - photograph showing the result of antifungal test of a building panel made according to the embodiment of the present invention
2a and 2b - photographs showing the result of antibacterial test (2a: Escherichia coli ATCC 25922, 2b: Staphylococcus aureus ATCC 6538) of a building panel manufactured according to the embodiment of the present invention
Figures 3a and 3b - Photographs showing deodorization test results (3a: ammonia, 3b: formaldehyde) of a building panel made according to an embodiment of the present invention
Figs. 4a and 4b - photographs showing far infrared emissivity (4a) and radiant energy (4b) test results of a building panel manufactured according to an embodiment of the present invention

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings, which are intended to illustrate the present invention in a manner that allows a person skilled in the art to easily carry out the invention. The present invention is not limited thereto.

Throughout this specification, when an element is referred to as "including" an element, it is understood that it may include other elements as well, without departing from the other elements unless specifically stated otherwise.

Conventional functional building panels using soil as a main material are not only hard to exhibit sufficient strength as a building material but also have a problem that cracks occur easily during long-term use due to high expansion / contraction ratio of materials due to external environment. Further, when a large amount of an adhesive component is mixed to increase the strength, the content of the soil itself as an environmentally friendly material is lowered.

On the other hand, in the case of a building insulation panel made of a stone such as marble, the strength is high but the absorption power against the external impact is low, and there is a disadvantage that excessive cost for construction and repair is consumed due to difficulty in mining, processing and moving.

In order to solve this problem, the present invention is characterized by using stone powder as a main material of a building panel. Due to the compactness of the particles, the stone can realize high strength without using a large amount of additives, and the volume strain due to the surrounding environment is low, so that cracking does not occur even when used for a long time. In addition, there is no need to maintain the shape of the stone, which can drastically reduce mining, processing and transportation costs.

The powder of the various rocks such as petite, marble, granite, granite, and boulder can be used as the above-mentioned abrasive, and bluffs having various functions such as antimicrobial, antifungal and ultraviolet ray emission can be used.

When the content of the abrasive grains exceeds 90 wt%, the formability of the panel deteriorates. When the content of the abrasive grains is less than 80 wt%, the strength of the panel is lowered, The physical properties are deteriorated.

The above-mentioned stone is easily obtained through various routes such as a mine or a stone processing factory, and it is preferable to carry out a pretreatment process to uniformize particles and remove impurities before being used in a panel. When the particles of the abrasive grains are uneven and contain a large amount of impurities, miscibility and cohesiveness with other components described later may be deteriorated and the physical properties of the panel itself may be lowered.

The pretreatment process may be performed by various methods. However, in one embodiment, the abrasive is removed by removing the impurities by rapid heating of the abrasive supplied through various paths, and the impregnation is performed using a roller mill, a vibrating ball mill, Or the like, to have a uniform particle size.

The rapid heating causes microcracks in the grain boundaries due to the difference in thermal expansion coefficient between the dissimilar elements constituting the stone, thereby separating the impurities and facilitating the subsequent grinding process. The rapid heating may be performed by various methods. Preferably, the rapid heating may be performed by raising the temperature of the abrasive to 700 to 800 ° C. in a short time of 1 to 10 minutes using an electromagnetic wave of 900 MHz to 5 GHz.

Rapidly heated calcareous matter is subjected to hydrothermal treatment in order to remove separated impurities. The hydrothermal treatment is preferably performed at a temperature of 200 to 250 ° C for 20 to 40 hours. The hydrothermal treated stone may have a uniform particle size of 0.1 to 1 mm after drying and pulverization.

Meanwhile, the thermal insulation panel for construction of the present invention is characterized by further comprising pulp and gelatin additives for enhancing the moldability of the stone. The gelatin additive component enhances the cohesive force between the particles of the dust particles and absorbs the external impact. The pulp component sucks the gelatin additive component and acts as a filling material for connecting the particles of the gelatin, Enhances cohesion and further improves cohesion.

As the gelatin additive, various materials including a gelatin ingredient may be used, and preferably glue, which is a natural material, is preferably used. The glue is a substance that solidifies the liquid of an animal such as an animal's skin, tendon, intestines, bones, etc., and is carbonized immediately upon a fire so that a toxic gas generation amount is small and a progress speed of a fire can be lowered.

In addition, the glue can achieve a high adhesive effect even with a small content, and the absorbency against external impact is high due to the specific elasticity of the material, so that cracking due to external impact of the existing stone panel can be prevented.

On the other hand, the glue may be used by adding glycerin in an amount of 1 to 10 parts by weight based on the total weight of the glue to improve the rheological properties of the glue and, in particular, to improve the miscibility with the glue. It is preferable that the glycerin is mixed and introduced into the glue mixture in the preparation step.

The content of the gelatin additive is preferably 5 to 15 wt%, and when the content of the gelatin additive is more than 15 wt%, the panel may bend. When the content of the gelatin additive is less than 5 wt% Molding is difficult to be performed.

When the content of the pulp exceeds 10 wt%, the flame retardancy of the panel and the physical properties of the panel deteriorate. When the pulp content is less than 5 wt%, the content of the pulp is less than 5 wt% And the coagulability of the gelatin additive and the cohesion of the granules are lowered.

Meanwhile, the heat insulating panel for construction of the present invention may be manufactured by mixing slurry, pulp mixture and gelatin mixture to prepare a slurry mixture, and molding the slurry mixture followed by hot air drying.

First, the mixture of pulp and solvent at a ratio of 3: 7 to 5: 5 (w / w), preferably 4: 6, and a mixture of gelatin and solvent at a ratio of 3: 7 to 5: (w / w), preferably in a ratio of 4: 6, is prepared, and then the mixture is mixed with the abrasive powder to prepare a slurry-type mixture. The solvent may be water or an organic solvent which can be removed by drying.

The slurry mixture thus prepared is shaped using a standard frame, and then dried with hot air to dry all of the solvent to finally complete the panel.

Hereinafter, embodiments and experimental examples of the present invention will be described. However, the scope of the present invention is not limited to the following preferred embodiments, and a person skilled in the art can carry out various modifications of the contents described in the present invention within the scope of the present invention.

[Example]

Manufacture of insulating panels

A blend mixture of blast furnace powder, pulp and water at a ratio of 4: 6 (w / w), and a mixture of glue and water at a ratio of 4: 6 (w / w) were mixed to prepare a slurry- Respectively. Then, the slurry-type mixture was formed using a specimen frame (50x50x50mm) having a predetermined size, and then hot-air dried at 700-800 ° C to produce a blast furnace panel having the composition shown in Table 1 below.

Comparative Example 1 Example 1 Example 2 Example 3 Comparative Example 2 Blast furnace powder 65 80 85 90 95 pulp 15 10 7 5 3 glue 20 10 8 5 2

[Experimental Example 1]

Compressive strength measurement

The compression strength, specific gravity and water absorption ratio of the above Examples and Comparative Examples were measured according to KS F 2519: 2000 and KS F 2518: 2005, and the results are shown in Table 2 below. (In the case of Comparative Example 2, molding was difficult and measurement was impossible)

Comparative Example 1 Example 1 Example 2 Example 3 Comparative Example 2 Compressive strength (MPa) 55 90 95 98 - importance 1.89 2.56 2.55 2.57 - Absorption Rate (%) 3.5 1.58 1.54 1.50 -

[Experimental Example 2]

Antifungality measurement

The anti-fungal properties of the above Examples and Comparative Examples were measured according to ASTM G 21: 2003 and shown in Table 3 and FIG. 1 (Example 2). In this study, we used a mixed strain of Aspergillus niger ATCC 9642, Penicillium pinophilum ATCC 11797, Chaetomium globosum ATCC 6205, Gliockadium virens ATCC 9645 and Aureobasidium pullulans ATCC 15233. The temperature was (29.1 ± 0.2) ± 1.0)% RH and the results were measured 4 weeks after inoculation.

("Grade": "0" means that the growth of mycelium is not recognized in the inoculated portion of the test specimen. "1" means that the area of hyphae part recognized in the inoculated portion of the test specimen is less than 10% of the whole area. "Refers to the area of mycelial growth perceived in the inoculated portion of the test specimen is 10 to 30% of the total area," 3 "means the area of the mycelial growth perceived in the inoculated portion of the test specimen is 30 to 60% "4" means that the area of mycelial growth area recognized on the inoculated portion of the test specimen is 60% or more of the total area.)

Comparative Example 1 Example 1 Example 2 Example 3 Rating One 0 0 0

[Experimental Example 3]

Antimicrobial activity measurement

Antimicrobial activity was measured by KCL-FIR-1002: 2011 for the above Examples and Comparative Examples, and it is shown in Table 4 and Figs. 2a and 2b (Comparative Example 1 and Example 2). The strains were Escherichia coli ATCC 25922 (1.6 × 10 6 CFU / ml) and Staphylococcus aureus ATCC 6538 (1.2 × 10 6 CFU / ml) 0.3)% RH.

Test Items Initial concentration
(CFU / mL)
Concentration after 24 hours
(CFU / mL)
Bacterial reduction rate
(%)
Antibacterial test with Escherichia coli ATCC 25922 Comparative Example 1 1.6 x 10 ^ 4 5.8 x 10 ^ 4 - Example 1 1.6 x 10 ^ 4 <10 99.9 Example 2 1.6 x 10 ^ 4 <10 99.9 Example 3 1.6 x 10 ^ 4 <10 99.9 Antibacterial test by Staphylococcus aureus ATCC 6538 Comparative Example 1 1.2x10 ^ 4 4.3 x 10 ^ 4 - Example 1 1.2x10 ^ 4 <10 99.9 Example 2 1.2x10 ^ 4 <10 99.9 Example 3 1.2x10 ^ 4 <10 99.9

[Experimental Example 4]

Deodorization performance measurement

The sample of Example 2 was placed in a 5 L reactor and sealed. The initial concentration of the test gas was injected at 50 占 퐉 ol / mol and the concentration of the test gas was measured at the initial (0 minute), 30 minutes, 60 minutes, 90 minutes, 120 minutes, and the changes are shown in Tables 5 and 6 and Figs. 3A and 3B.

The concentration of the test gas was measured by KS I 2218: 2009, the temperature during the test was (20.6 ± 0.3) ℃ and the humidity was maintained at (52.1 ± 0.4)% R.H. The same test was carried out in the absence of a sample and expressed as a concentration of balnk. The removal rate of test gas for each hourly period was calculated by the following equation.

(%) = [{(Blank concentration) - (sample concentration)} / (blank concentration)] X100

Test Items Blank concentration
Sample concentration
Deodorization rate (%)
Ammonia (NH3)
0 minutes 50 50 0.0
30 minutes 49 4 91.8 60 minutes 49 2 95.9 90 minutes 49 2 95.9 120 minutes 49 One 98.0

Test Items Blank concentration
Sample concentration
Deodorization rate (%)
Formaldehyde (HCHO)
0 minutes 50 50 0.0
30 minutes 49 18 63.3 60 minutes 49 17 65.3 90 minutes 49 17 65.3 120 minutes 49 17 65.3

[Experimental Example 5]

Measurement of far-infrared emissivity and radiant energy

Far infrared emissivity and far-infrared radiation energy were measured by KCL-FIR-1005: 2011 for the sample of Example 2 and are shown in Table 7 and Figs. 4A and 4B. The test results were maintained at (22.5 ± 0.1) ℃ during the test and at (23.3 ± 0.3)% R.H.

Test Items unit Test result Far-infrared emissivity
(Measurement temperature: 40 占 폚, measurement wavelength: 5 占 퐉 to 20 占 퐉)

-

0.907
Far-infrared radiation energy
(Measurement temperature: 40 占 폚, measurement wavelength: 5 占 퐉 to 20 占 퐉)
W / m 2 3.66x10 2

As can be seen from the above experimental results, the present invention can provide a highly functional building material having a variety of functions such as deodorizing property, fungicidal property, antimicrobial property and the like, which has a high far infrared ray emissivity and radiant energy by using the stone.

The present invention is not limited to the above-described specific embodiments and descriptions, and various modifications can be made to those skilled in the art without departing from the gist of the present invention claimed in the claims. And such modifications are within the scope of protection of the present invention.

Claims (7)

delete delete delete delete A pretreatment step of preparing the blast furnace slag by rapidly heating, hydrothermally treating and finely pulverizing the blast furnace;
Mixing the blast furnace slag, pulp mixture and glue mixture to prepare a slurry mixture; And
Shaping the slurry mixture, followed by hot air drying,
The rapid heating is carried out by raising the temperature of the abrasive to 700 to 800 ° C for 1 to 10 minutes using an electromagnetic wave of 900 MHz to 5 GHz,
The hydrothermal treatment is performed at a temperature of 200 to 250 ° C for 20 to 40 hours,
Wherein the pulverization is carried out through a roller mill, a vibrating ball mill, a jet mill, a turbo mill or a pot mill, wherein the blast furnace fraction has a uniform particle size of 0.1 to 1 mm .
6. The method of claim 5,
Wherein the pulp mixture is a mixture of pulp and water in a ratio of 3: 7 to 5: 5 (w / w).
6. The method of claim 5,
Wherein the glue mixture is a mixture of a glue component and water in a ratio of 3: 7 to 5: 5 (w / w).
KR1020160015580A 2016-02-11 2016-02-11 Panel for construction and manufacturing method thereof KR101732715B1 (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100814740B1 (en) * 2006-12-07 2008-03-19 백태현 Method for manufacturing the insulating material having sound-proofing effects

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100814740B1 (en) * 2006-12-07 2008-03-19 백태현 Method for manufacturing the insulating material having sound-proofing effects

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