KR101679888B1 - 시스-1,1,1,4,4,4-헥사플루오로-2-부텐과 1,1,1,3,3-펜타플루오로프로판의 혼합물을 함유하는 폼-형성 조성물 및 폴리아이소시아네이트계 폼의 제조에서의 그의 용도 - Google Patents

시스-1,1,1,4,4,4-헥사플루오로-2-부텐과 1,1,1,3,3-펜타플루오로프로판의 혼합물을 함유하는 폼-형성 조성물 및 폴리아이소시아네이트계 폼의 제조에서의 그의 용도 Download PDF

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KR101679888B1
KR101679888B1 KR1020117020466A KR20117020466A KR101679888B1 KR 101679888 B1 KR101679888 B1 KR 101679888B1 KR 1020117020466 A KR1020117020466 A KR 1020117020466A KR 20117020466 A KR20117020466 A KR 20117020466A KR 101679888 B1 KR101679888 B1 KR 101679888B1
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foam
polyisocyanate
mixture
hfc
1336mzz
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KR20110122163A (ko
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개리 로
조셉 안토니 크레아쪼
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이 아이 듀폰 디 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5033—Polyethers having heteroatoms other than oxygen having nitrogen containing carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
KR1020117020466A 2009-02-03 2010-01-29 시스-1,1,1,4,4,4-헥사플루오로-2-부텐과 1,1,1,3,3-펜타플루오로프로판의 혼합물을 함유하는 폼-형성 조성물 및 폴리아이소시아네이트계 폼의 제조에서의 그의 용도 Active KR101679888B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14947309P 2009-02-03 2009-02-03
US61/149,473 2009-02-03
PCT/US2010/022506 WO2010090951A1 (en) 2009-02-03 2010-01-29 Foam-forming compositions containing mixtures of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane and their uses in the preparation of polyisocyanate-based foams

Publications (2)

Publication Number Publication Date
KR20110122163A KR20110122163A (ko) 2011-11-09
KR101679888B1 true KR101679888B1 (ko) 2016-11-25

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KR1020117020466A Active KR101679888B1 (ko) 2009-02-03 2010-01-29 시스-1,1,1,4,4,4-헥사플루오로-2-부텐과 1,1,1,3,3-펜타플루오로프로판의 혼합물을 함유하는 폼-형성 조성물 및 폴리아이소시아네이트계 폼의 제조에서의 그의 용도

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Country Link
US (1) US20120004336A1 (cg-RX-API-DMAC10.html)
EP (1) EP2393862B1 (cg-RX-API-DMAC10.html)
JP (1) JP5744758B2 (cg-RX-API-DMAC10.html)
KR (1) KR101679888B1 (cg-RX-API-DMAC10.html)
CN (1) CN102300896B (cg-RX-API-DMAC10.html)
AR (1) AR078017A1 (cg-RX-API-DMAC10.html)
AU (1) AU2010210806B2 (cg-RX-API-DMAC10.html)
BR (1) BRPI1005351B1 (cg-RX-API-DMAC10.html)
CA (1) CA2748041C (cg-RX-API-DMAC10.html)
CL (1) CL2011001862A1 (cg-RX-API-DMAC10.html)
ES (1) ES2692332T3 (cg-RX-API-DMAC10.html)
MX (1) MX337646B (cg-RX-API-DMAC10.html)
WO (1) WO2010090951A1 (cg-RX-API-DMAC10.html)

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Publication number Priority date Publication date Assignee Title
US20110269860A1 (en) * 2010-04-28 2011-11-03 E.I. Du Pont De Nemours And Company Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
US9556303B2 (en) * 2011-02-21 2017-01-31 Honeywell International Inc. Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents
CN104262935A (zh) * 2014-09-18 2015-01-07 关志强 一种聚氨酯混合发泡剂
CN106398650B (zh) * 2015-07-01 2018-03-06 西安科技大学 煤矿地热利用中的高温热泵三元混合工质
KR20190109742A (ko) * 2017-01-31 2019-09-26 바스프 에스이 Hfo 함유 pu 제제
MX2020002965A (es) * 2017-09-29 2020-07-22 Chemours Co Fc Llc Composicion de agente de soplado para la preparacion de una espuma.
US11407874B2 (en) 2019-10-07 2022-08-09 Covestro Llc Polyol premixes, thermally insulating rigid polyurethane foams and methods for their production
CN116741432B (zh) * 2022-12-09 2024-11-08 西安近代化学研究所 一种绝缘混合气体及其应用
US12679922B2 (en) 2023-06-15 2026-07-14 Covestro Llc Isocyanate-reactive compositions, rigid polyurethane foams and methods for their production

Citations (1)

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WO2008134061A2 (en) * 2007-04-27 2008-11-06 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene

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JPS56163117A (en) * 1980-05-19 1981-12-15 Takeda Chem Ind Ltd Production of rigid urethane foam
US4394491A (en) 1980-10-08 1983-07-19 The Dow Chemical Company Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate
US5164419A (en) 1991-05-20 1992-11-17 E. I. Du Pont De Nemours And Company Blowing agent and process for preparing polyurethane foam
JPH05179043A (ja) 1991-11-18 1993-07-20 Daikin Ind Ltd フルオロブテンからなる発泡剤およびプラスチック発泡体の製造方法
JPH05239251A (ja) * 1991-11-18 1993-09-17 Daikin Ind Ltd フルオロプロパンからなる発泡剤およびプラスチック発泡体の製造方法
MY145459A (en) * 2005-11-01 2012-02-15 Du Pont Solvent compositions comprising unsaturated fluorinated hydrocarbons
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KR20090087966A (ko) * 2006-12-15 2009-08-18 이 아이 듀폰 디 네모아 앤드 캄파니 냉동 성능을 위하여 최적화된 ζ- 및 ε-이성체 비를 가진 1,2,3,3,3-펜타플루오로프로펜을 포함하는 조성물
MX2010002471A (es) * 2007-09-06 2010-03-26 Du Pont Composiciones azeotropicas y similares a azeotropos de e-1,1,1,4,4,5,5,5-octafluoro-2-penteno.
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CN101878253B (zh) * 2007-11-29 2013-05-29 纳幕尔杜邦公司 包含顺式-1,1,1,4,4,4-六氟-2-丁烯泡沫形成组合物的组合物以及所述组合物制备基于多异氰酸酯的泡沫的用途
CA2708274C (en) * 2007-12-19 2016-10-18 E. I. Du Pont De Nemours And Company Foam-forming compositions containing azeotropic or azeotrope-like mixtures containing z-1,1,1,4,4,4-hexafluoro-2-butene and their uses in the preparation of polyisocyanate-based foams
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US20110269860A1 (en) * 2010-04-28 2011-11-03 E.I. Du Pont De Nemours And Company Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams

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WO2008134061A2 (en) * 2007-04-27 2008-11-06 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene

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CA2748041A1 (en) 2010-08-12
JP2012516931A (ja) 2012-07-26
MX337646B (es) 2016-03-14
ES2692332T3 (es) 2018-12-03
CA2748041C (en) 2017-06-20
EP2393862B1 (en) 2018-08-15
CN102300896B (zh) 2013-11-06
AU2010210806B2 (en) 2015-10-01
MX2011008048A (es) 2011-08-17
US20120004336A1 (en) 2012-01-05
AU2010210806A1 (en) 2011-07-07
KR20110122163A (ko) 2011-11-09
EP2393862A1 (en) 2011-12-14
JP5744758B2 (ja) 2015-07-08
AR078017A1 (es) 2011-10-12
BRPI1005351B1 (pt) 2019-10-22
BRPI1005351A2 (pt) 2017-04-25
WO2010090951A1 (en) 2010-08-12
CL2011001862A1 (es) 2012-01-06
CN102300896A (zh) 2011-12-28

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