KR101662646B1

KR101662646B1 - Hydrocarbon Reforming System Using Steamplasma

Info

Publication number: KR101662646B1
Application number: KR1020140149956A
Authority: KR
Inventors: 홍용철; 최대현; 천세민; 마숙활
Original assignee: 한국기초과학지원연구원
Priority date: 2014-10-31
Filing date: 2014-10-31
Publication date: 2016-10-07
Also published as: KR20160053146A

Abstract

According to the present invention, there is provided a hydrocarbon reforming system for producing a synthesis gas by reforming a steam plasma and a hydrocarbon body, the steam reforming system comprising: a steam generator (310) for generating and supplying steam; A hydrocarbon-based supply unit 320 for supplying a hydrocarbon-based product; Plasma reformers 100 and 200 that receive steam and hydrocarbon bodies from the steam generator 310 and the hydrocarbon body feeder 320 and generate synthesis gas through a reforming reaction while generating steam plasma P using electromagnetic waves, ; And a heat exchanger (330) for purifying the moisture contained in the synthesis gas, which is located at a gas discharge end of the plasma reformer (100, 200).

Description

[0001] The present invention relates to a hydrocarbon reforming system using Steam Plasma,

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a hydrocarbon reforming system using steam plasma, and more particularly, to a hydrocarbon reforming system for reforming a steam plasma and a hydrocarbon body to produce synthesis gas.

Generally, a steam reforming reaction, which is a reforming method in which a hydrocarbon such as methane is reformed to produce a synthesis gas such as hydrogen and carbon monoxide, provides a high hydrogen generation efficiency as compared with other reforming reactions, .

However, in the case of the conventional wet reforming method, in the case of poor thermal management, deterioration of the catalyst occurs at the time of formation of the high temperature, so that the performance is deteriorated and a large amount of carbon is generated and adsorbed on the catalyst, There is a problem that the system becomes complicated because it requires strict heat maintenance and management for maintaining the catalyst activation temperature due to the endothermic reaction.

Further, when a catalyst of a non-noble metal material is used, the cost of the device can be reduced, but a separate reduction process is required. In the case of using a noble metal catalyst, the reduction process can be omitted, The cost is increased. In addition, when the fuel contains impurities such as sulfur, the active area is drastically lowered due to the poisoning of the catalyst.

Patent Document 10-1401423 (Apr. 25, 2013), Apparatus and Method for Producing Combustible Gas from Carbon Dioxide Using Microwave Plasma-Catalytic Hybrid Process

SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and it is an object of the present invention to provide a reforming catalyst for reforming a hydrocarbon body by using steam plasma to prevent carbon deposition phenomenon or increase in system construction cost, The present invention provides a hydrocarbon body reforming system using steam plasma which maximizes the reforming reaction efficiency of a hydrocarbon body by providing an enlarged space portion in a nozzle portion in which a hydrocarbon body is reformed or preheating a hydrocarbon body using heat of a steam plasma.

According to an aspect of the present invention, there is provided a hydrocarbon reforming system for reforming a steam plasma and a hydrocarbon material to produce a synthesis gas, comprising: a steam generator for generating and supplying steam; A hydrocarbon-based supply unit 320 for supplying a hydrocarbon-based product; Plasma reformers 100 and 200 that receive steam and hydrocarbon bodies from the steam generator 310 and the hydrocarbon body feeder 320 and generate synthesis gas through a reforming reaction while generating steam plasma P using electromagnetic waves, ; And a heat exchanger (330) for purifying moisture contained in the syngas generated by the gas reformer (100, 200).

The plasma reformer 100 includes an electromagnetic wave supply unit 110 for generating an electromagnetic wave having a predetermined frequency, a discharge tube 120 for generating a steam plasma P from the electromagnetic wave, steam, and hydrocarbon substances, A support body 130 provided around the discharge tube 120 and provided with a steam injector 131 for injecting steam into the discharge tube 120 and a first hydrocarbon injector 132 for injecting a hydrocarbon body, And an enlarged space portion 141 which is formed at an upper position of the support body 130 so as to communicate with the discharge tube 120 and has an inner diameter gradually expanded inside thereof, And a nozzle unit 140 having a second hydrocarbon injecting unit 142 injecting a hydrocarbon material for reforming reaction with the steam plasma P into the expansion space 141 can do.

The nozzle unit 140 is provided with an annular vortex chamber 143 extending along the circumference of the wall and the second hydrocarbon injection unit 142 is connected to one side of the vortex chamber 143 A plurality of injection openings 144 for injecting the hydrocarbon bodies pivoting inward into the expansion space 141 are spaced apart from each other by a predetermined distance at the other side of the vortex chamber 143 .

The second hydrocarbon injecting unit 142 is inclined at a predetermined angle with respect to the wall surface of the nozzle unit 140 so that the hydrocarbon injected into the swirl chamber 143 rotates along the inside of the swirl chamber 143, The second hydrocarbon body injecting part 142 may be formed so as to be inclined in the same direction as the second hydrocarbon body injecting part 142 so that the injected hydrocarbon body is injected while being swirled along the inside of the extended hollow part 141.

The plasma reformer 200 includes an electromagnetic wave supply unit 210 for generating an electromagnetic wave having a predetermined frequency, a discharge tube 220 for generating a steam plasma P from the electromagnetic wave, steam, and hydrocarbon substances, A support 230 provided around the discharge tube 220 and equipped with a steam injector 231 for injecting steam into the discharge tube 220 and a first hydrocarbon injector 232 for injecting the hydrocarbon injected into the discharge tube 220, . And a second hydrocarbon body injecting unit for injecting a hydrocarbon body for reforming reaction with the steam plasma P is disposed at an upper position on the upper side of the support body 230, An inner tube portion 243 formed in a vertically opened tubular shape so as to be vertically disposed inside the outer tube portion 241 so as to communicate with the discharge tube 220, (241) and the inner tube portion (243) by an inner diameter of the inner tube portion (241) and an outer diameter of the inner tube portion (243), and an upper end is communicated with the second hydrocarbon injecting portion (242) And a nozzle section 240 including a preheating conduit 244 formed with an injection port 245 communicating with the inside of the tube section 243.

Wherein the inner tube portion (243) is made of a thermally conductive material and is heated by the steam plasma (P) to preheat the hydrocarbon body passing through the preheating conduit (244) to a predetermined temperature.

According to the hydrocarbon reforming system using steam plasma according to the present invention,

First, the hydrocarbon reforming reaction using the steam plasma (P) does not cause the carbon deposition phenomenon as compared with the wet reforming reaction method using the conventional catalyst, and the catalyst of the noble metal material or the separate reduction process is not necessary Therefore, the system construction cost can be reduced.

Second, the nozzle unit 140 disposed at an upper position of the discharge tube 120 in which the steam plasma P is generated is provided with an extended space portion 141 having an inner diameter gradually expanded. The reaction area between the steam plasma P and the hydrocarbon body can be relatively increased by injecting the hydrocarbon material into the inside of the steam reformer 141 and the reforming reaction can be improved by forming the flame of the steam plasma P longer.

Third, in the wall of the nozzle unit 140, a vortex chamber 143 is formed which is formed in a ring shape extending along the circumference and into which the hydrocarbon material is injected. The vortex chamber 143 is injected into the vortex chamber 143, A plurality of injection openings 144 for injecting the hydrocarbon bodies into the expansion space 141 are formed at a predetermined interval so that the periphery of the steam plasma P generated in the expansion space 141 The reforming reaction can be further improved by uniformly supplying the hydrocarbon bodies.

Fourth, the second hydrocarbon injecting unit 142 for supplying the hydrocarbon bodies to the vortex chamber 143 is inclined at a predetermined angle with respect to the wall surface of the nozzle unit 140 so that the hydrocarbon bodies are injected into the vortex chamber 143 And the injection port 144 is inclined in the same direction as the second hydrocarbon injecting part 142 so that the injected hydrocarbon body is injected while being swirled along the inside of the expansion space part 141 , It is possible to uniformly mix the steam plasma (P) and the hydrocarbon body and generate a highly active radical, thereby increasing the reforming reaction efficiency and the chemical reaction rate.

Fifthly, the nozzle unit 240 disposed at the upper position of the discharge tube 220 in which the steam plasma P is generated has an outer tube unit 241 and a tube tube unit 243, And a preheating conduit 244 is formed between the outer tube portion 241 and the inner tube portion 243 to preheat the hydrocarbon body injected using the heat of the steam plasma P to a predetermined temperature. It is possible to mix the hydrocarbon material with the steam plasma P so that the stability of the steam plasma P can be ensured and the efficiency of the reforming reaction can be maximized.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view showing a configuration of a hydrocarbon reforming system according to a preferred embodiment of the present invention;
FIG. 2 is a schematic view showing a configuration of an electromagnetic wave supply unit according to a preferred embodiment of the present invention,
3 is a side cross-sectional view showing a configuration of a plasma reformer according to a first preferred embodiment of the present invention,
4 is a side cross-sectional view showing a configuration of a plasma reformer according to a second preferred embodiment of the present invention.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. Prior to this, terms and words used in the present specification and claims should not be construed as limited to ordinary or dictionary terms, and the inventor should appropriately interpret the concepts of the terms appropriately The present invention should be construed in accordance with the meaning and concept consistent with the technical idea of the present invention.

Therefore, the embodiments described in this specification and the configurations shown in the drawings are merely the most preferred embodiments of the present invention and do not represent all the technical ideas of the present invention. Therefore, It is to be understood that equivalents and modifications are possible.

The hydrocarbon reforming system using the steam plasma according to the preferred embodiment of the present invention prevents the carbon deposition phenomenon or the system construction cost from increasing due to the reforming reaction of the hydrocarbon by using the steam plasma (P) A hydrocarbon substance which maximizes the reforming reaction efficiency of the hydrocarbon substance by providing the extended space portion 141 in the nozzle units 140 and 240 where the hydrocarbon substance is reformed or preheating the hydrocarbon substance using the high temperature of the steam plasma P, The reforming system includes a steam generator 310 for generating and supplying steam as shown in FIG. 1, a hydrocarbon body supplier 320 for supplying a hydrocarbon body, a steam generator 310 and a hydrocarbon body supplier 320, (P) is generated from the inside of the reactor by using the electromagnetic wave and the reforming reaction is performed through the steam plasma It is provided, including the heat exchanger 330 for purifying the water contained in the synthesis gas produced by the reformer is located in the plasma (100,200) and the gas discharge end of the plasma reformer (100,200) for generating a synthesis gas.

The hydrocarbon supply line between the steam generator 310 and the plasma reformers 100 and 200 and between the hydrocarbon feeder 320 and the plasma reformers 100 and 200 is supplied with steam or hydrocarbons supplied to the plasma reformers 100 and 200, It is preferable that the flow rate supply devices 311 and 321 for precisely controlling and supplying the flow rate of the sieve are disposed.

In addition, the flow rate supply devices 311 and 321 can be constructed by an electronic automatic valve system that automatically opens and closes in accordance with a predetermined set value or a control signal and controls the flow rate. In addition, Can be constructed in a controlled manual valve manner.

In addition, as shown in the figure, a steam pressure gauge board 312 is provided on the steam supply line between the flow rate supplying device 311 and the plasma reformers 100 and 200 to indicate a supply pressure of steam supplied from the steam generator 310, It is possible to prevent the supply of steam at a pressure in advance.

The steam and hydrocarbon supplied from the steam generator 310 and the hydrocarbon feeder 320 are injected into the plasma reformers 100 and 200 while the flow rates supplied by the respective flow rate feeders 311 and 321 are adjusted. A synthesis gas such as hydrogen or carbon monoxide can be produced while performing a reforming reaction with the steam plasma P generated in the reformers 100 and 200.

Here, the synthesis gas may be generated as gas components other than hydrogen or carbon monoxide depending on the material of the hydrocarbon material to be injected.

The syngas generated and discharged through the plasma reformers 100 and 200 is purified through the heat exchanger 330 while the moisture contained in the reforming reaction is purified. The purified water is supplied to the condenser buffer (not shown) disposed at one side of the heat exchanger 330 340), so that only the dry synthesis gas can be produced.

As described above, the hydrocarbon reforming reaction using the steam plasma (P) does not cause the carbon deposition phenomenon as compared with the wet reforming reaction system using the conventional catalyst, and does not require a noble metal catalyst or a separate reduction process The system construction cost can be reduced.

Hereinafter, referring to FIG. 2 to FIG. 4, description will be given of functions and characteristics of the plasma reformers 100 and 200 according to the structure for enhancing the reforming reaction of the plasma reformers 100 and 200 that generate steam plasma P to reform the hydrocarbon bodies. .

First, a plasma reformer 100 according to a first preferred embodiment of the present invention is a plasma reformer 100 that expands a space where a hydrocarbon material is injected to carry out a reforming reaction to increase the reforming efficiency. As shown in FIGS. 2 and 3 An electromagnetic wave supplying unit 110, a discharge tube 120, a supporting body 130, and a nozzle unit 140.

First, the electromagnetic wave supplier 110 supplies the electromagnetic waves required to generate the steam plasma P in the plasma reformer 100. The electromagnetic wave supplier 110 supplies the electromagnetic waves required to generate the steam plasma P to the plasma reformer 100. The electric power supplier 111, the electromagnetic wave oscillator 112, the circulator 113, 114, and a waveguide 115. [

The power supply unit 111 receives drive power from the outside and supplies power required for driving the electromagnetic wave supply unit 110. The electromagnetic wave oscillator 112 is connected to the power supply unit 111 and receives power from the power supply unit 111 The electromagnetic wave is oscillated.

Here, in this embodiment, a microwave oscillator (magnetron) having a commercial frequency is used. For example, an electromagnetic wave oscillator having a frequency of 2.45 GHz or an electromagnetic wave oscillator capable of oscillating electromagnetic waves having a frequency range of 902 to 928 MHz ((915 MHz magnetron) or 886 to 896 MHz (896 MHz magnetron) can be used.

The circulator 113 is connected to the electromagnetic wave oscillator 112 to output an electromagnetic wave oscillated by the electromagnetic wave oscillator 112 and to protect the electromagnetic wave oscillator 113 by extinguishing the electromagnetic wave energy reflected by the impedance mismatch.

The tuner 114 is connected to the circulator 113 and adjusts the intensity of the incident wave and the reflected wave of the electromagnetic wave outputted from the circulator 113 to induce impedance matching so that the electric field induced by the electromagnetic wave is maximized within the discharge tube 120 And the waveguide 115 is connected between the tuner 114 and the discharge tube 120 to transmit the electromagnetic wave inputted from the tuner 114 to the discharge tube 120.

The discharge tube 120 is a means for generating a steam plasma P from electromagnetic waves, steam, and hydrocarbon substances. The wave tube 115 is connected to one side of the discharge tube 120 to receive electromagnetic waves emitted from the electromagnetic wave supply unit 110, The steam is injected from the first hydrocarbon injecting unit 132 as a fuel source, and steam plasma P is generated from the injected steam. Although not shown in the drawing, an igniter is provided at a lower portion of the discharge tube 120 to ignite the hydrocarbon body.

As a hydrocarbon material to be used as the fuel source, a gaseous or liquid hydrocarbon fuel may be used. As the material of the hydrocarbon fuel, gaseous methane, ethane, propane, butane, etc. may be used. Light oil, kerosene, Bunker C oil, refined waste oil, and the like may be used.

The support 130 supports the discharge tube 120 so that the discharge tube 120 can be mounted on the support tube 130 and the hydrocarbon body that serves as a source of steam and fuel is supplied into the discharge tube 120. The periphery of the discharge tube 120 A steam injector 131 for injecting steam into the discharge tube 120 is provided at one side of the discharge tube 120 and a first injector 131 for injecting a hydrocarbon material that is a fuel source required to generate the steam plasma P And a hydrocarbon body injecting section 132 is provided.

As shown in the figure, the first hydrocarbon injecting unit 132 is formed at an angle inclined upwards in a direction in which the steam plasma P is generated, that is, in a direction in which the synthesis gas is discharged, Although not shown, a plurality of first hydrocarbon body injecting parts 132 are formed at predetermined intervals along the periphery of the supporting body 130 and are inclined at an angle to the wall surface of the supporting body 130, So as to pivot along the inside of the support body 130. This makes it possible to uniformly mix the ignited steam plasma P and the hydrocarbon body and to protect the support 130 and the inner wall of the discharge tube 120 from the flame of the high temperature steam plasma P. [

The nozzle unit 140 supplies the hydrocarbon gas for reforming reaction to the steam plasma P generated by the discharge tube 120 and discharges the generated synthesis gas through the discharge port 145, As shown in the figure, the support member 130 is formed in a vertically open tubular shape and is disposed on the support 130 so that the inner portion thereof communicates with the discharge tube 120. The expanded space portion 141 has an inner diameter gradually expanded. And a second hydrocarbon injecting unit 142 injecting a hydrocarbon material into the steam plasma P for reforming reaction is provided at a peripheral side thereof.

The nozzle unit 140 disposed at the upper position of the discharge tube 120 in which the steam plasma P is generated is provided with an extended space portion 141 having an inner diameter gradually expanded. The reaction area between the steam plasma P and the hydrocarbon substance can be relatively increased by injecting the hydrocarbon substance into the interior of the reaction zone 141 and the reforming reaction can be improved by forming the flame of the steam plasma P longer.

Here, the hydrocarbon material injected through the second hydrocarbon injecting unit 142 may be a gaseous hydrocarbon such as methane, ethane, propane, butane or the like, which is injected through the first hydrocarbon injecting unit 132 Gasoline, diesel, kerosene, bunker C oil and refined waste oil which can be used and are in a liquid state can be used.

Also, as shown in the drawing, the upper portion of the extended space portion 141 may be formed so that the expanded inner diameter gradually decreases to increase the discharge pressure of the syngas discharged through the discharge port 145.

In addition, the nozzle unit 140 is provided with an annular vortex chamber 143 extending along the circumference of the wall, and the second hydrocarbon injection unit 142 is communicated with one side of the vortex chamber 143, A plurality of injection openings 144 for injecting the hydrocarbon bodies pivoting inward into the expansion space 141 are formed at a predetermined distance from the other side of the vortex chamber 143 . With this configuration, the reforming reaction can be further improved by uniformly supplying the hydrocarbon material along the periphery of the steam plasma P generated in the expansion space portion 141.

3, the second hydrocarbon injecting unit 142 is inclined at a predetermined angle with respect to the wall surface of the nozzle unit 140 so that the hydrocarbon body is injected into the vortex chamber 143 The injection port 144 is inclined in the same direction as the second hydrocarbon injecting part 142 so that the hydrocarbon injected into the expansion space 141 is injected along the inside of the extension space 141 . Accordingly, the steam plasma (P) and the hydrocarbon body can be uniformly mixed, and highly active radicals can be generated to increase the reforming reaction efficiency and the chemical reaction rate.

Next, the configuration and function of the plasma reactor 200 according to the second preferred embodiment of the present invention will be described.

The plasma reformer 200 according to the second preferred embodiment of the present invention is a plasma reformer 100 in which a reforming efficiency is increased by preheating a hydrocarbon material for reforming reaction and injecting the reformed gas into a steam plasma P, 4, an electromagnetic wave supply unit 210, a discharge tube 220, a support 230, and a nozzle unit 240 are provided.

The electromagnetic wave supplying unit 210 supplies the electromagnetic waves required to generate the steam plasma P in the plasma reformer 200 and includes a power source unit 211, an electromagnetic wave oscillator 212, a circulator 213, a toner 214, and a waveguide 215. [

The discharge tube 220 is a means for generating a steam plasma P from electromagnetic waves, steam and hydrocarbon bodies. The support body 230 supports the discharge tube 220 so that the discharge tube 220 can be mounted thereon, Which is a support structure for supplying steam and a hydrocarbon body as a fuel source.

The electromagnetic wave supplying unit 210, the discharge tube 220 and the supporting body 230 perform the same function as the electromagnetic wave supplying unit 110, the discharge tube 120 and the supporting body 130 in the first embodiment Since the constitution is also the same, a duplicate description will be omitted.

The nozzle unit 240 supplies the hydrocarbon gas for reforming reaction to the steam plasma P generated by the discharge tube 220 and discharges the generated synthesis gas to the discharge port 247, And includes an outer tube portion 241, an inner tube portion 243, and a preheating tube 244 as shown.

The outer tube portion 241 is formed in a vertically opened tubular shape and is disposed on the upper portion of the supporter 230. A hydrocarbon substance for reforming reaction with the steam plasma P is injected into the upper portion of the outer tube portion 241, The second hydrocarbon body injecting section 242 is provided.

The inner tube portion 243 is formed in the shape of a tube that opens upward and downward like the outer tube portion 241 and is disposed upright inside the outer tube portion 241 so as to communicate with the discharge tube 220. The inner tube portion 243 is made of a heat conductive material, It is preferable to preheat the hydrocarbon body passing through the preheating conduit 244 to a predetermined temperature while being heated by the preheating conduit P.

The preheating conduit 244 is formed between the outer tube portion 241 and the inner tube portion 243 by an inner diameter of the outer tube portion 241 and a difference in outer diameter of the inner tube portion 243, And an injection port 245 communicating with the inside of the inner tube portion 243 is formed at a lower end thereof.

Therefore, the hydrocarbon material injected into the interior of the preheating conduit 244 from the second hydrocarbon injecting portion 142 disposed at the upper end of the outer tubular portion 241 flows in the direction of generating the steam plasma P, that is, The steam plasma P contacts the inner tube portion 243 heated by the high temperature to receive heat and is heated to a predetermined temperature And heated.

And is discharged toward the steam plasma P through the inlet 245 disposed at the lower end of the preheating conduit 244 in a heated state.

The nozzle unit 240 disposed at the upper position of the discharge tube 220 in which the steam plasma P is generated has an outer tubular portion 241 and a tubular inner tubular portion 243, And a preheating conduit 244 is formed between the outer tube portion 241 and the inner tube portion 243 to preheat the hydrocarbon body injected using the heat of the steam plasma P to a predetermined temperature. Since the hydrocarbon material can be mixed with the steam plasma P in a state where the heat amount is secured, the stability of the steam plasma P can be ensured and the efficiency of the reforming reaction can be maximized.

In addition, although not shown, the second hydrocarbon injection unit 242 for supplying the hydrocarbon material to the interior of the preheating duct 244 has a structure in which the hydrocarbon material formed at an angle to the wall surface of the nozzle unit 240 is preheated by the preheating duct 244 The injection port 245 is inclined in the same direction as that of the second hydrocarbon injecting part 242 so that the injected hydrocarbon body is injected while being rotated around the inside of the inner tube part 243 The steam plasma P and the hydrocarbon body can be uniformly mixed and highly active radicals can be generated to increase the reforming reaction efficiency and the chemical reaction rate.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. It is to be understood that various modifications and changes may be made without departing from the scope of the appended claims.

100, 200 ... Plasma reformer 110, 210 ... Electromagnetic wave supply unit
120, 210 ... discharge tube 130, 230 ... support
131, 231 ... Steam injecting part 132, 232 ... First hydrocarbon injecting part
140, 240 ... Nozzle parts 142, 242 ... Second hydrocarbon body injection part
143 ... vortex chamber 144, 245 ... inlet
241 ... exterior part 242 ... injection part
243 ... inner tube 244 ... preheated tube
P ... Steam plasma

Claims

A hydrocarbon reforming system for producing a synthesis gas by reforming a steam plasma and a hydrocarbon material,
A steam generator 310 for generating and supplying steam;
A hydrocarbon-based supply unit 320 for supplying a hydrocarbon-based product;
Plasma reformers 100 and 200 that receive steam and hydrocarbon bodies from the steam generator 310 and the hydrocarbon body feeder 320 and generate synthesis gas through a reforming reaction while generating steam plasma P using electromagnetic waves, ; And
And a heat exchanger (330) disposed at a gas discharge end of the plasma reformers (100, 200) for purifying moisture contained in the produced syngas,
The plasma reformer (100)
An electromagnetic wave supply unit 110 for generating electromagnetic waves of a predetermined frequency,
A discharge tube 120 for generating a steam plasma P from the electromagnetic wave, the steam, and the hydrocarbon body,
A steam injector 131 for injecting steam into the discharge tube 120 and a first hydrocarbon injector 132 for injecting the hydrocarbon injected into the discharge tube 120 are installed around the discharge tube 120, (130)
And is formed at an upper position of the support 130 so that the inside thereof communicates with the discharge tube 120. An expanded space portion 141 having an inner diameter gradually expanded is provided in the inside of the support body 130 And a nozzle unit 140 having a second hydrocarbon injecting unit 142 injecting a hydrocarbon species for reforming reaction with the steam plasma P into the expansion space 141 at one side thereof Wherein the hydrocarbon reforming system comprises:

delete

The method according to claim 1,
The nozzle unit 140 is provided with an annular vortex chamber 143 extending around the inside of the wall,
The second hydrocarbon injecting unit 142 communicates with one side of the vortex chamber 143 to inject the hydrocarbon into the chamber,
Wherein a plurality of injection ports (144) for injecting a hydrocarbon material pivoting inward into the expansion space (141) are formed at a predetermined distance from the other side of the vortex chamber (143).

The method of claim 3,
The second hydrocarbon injecting unit 142 is inclined at a predetermined angle with respect to the wall surface of the nozzle unit 140 so that the hydrocarbon injected into the vortex chamber 143 rotates along the inside of the vortex chamber 143,
The injection port 144 is formed so as to be inclined in the same direction as the second hydrocarbon injector 142 so that the injected hydrocarbon may be injected while being swirled along the interior of the extension space 141 Hydrocarbon body reforming system.

The method according to claim 1,
The plasma reformer 200 includes:
An electromagnetic wave supply unit 210 for generating electromagnetic waves of a predetermined frequency,
A discharge tube 220 for generating a steam plasma P from the electromagnetic wave, steam, and hydrocarbon material,
A steam injector 231 for injecting steam into the discharge tube 220 and a first hydrocarbon injector 232 for injecting the hydrocarbon injected into the discharge tube 220, 230) and.
And a second hydrocarbon body injecting unit for injecting a hydrocarbon body for reforming reaction with the steam plasma P is disposed at an upper position on the upper side of the support body 230, An inner tube portion 243 formed in a vertically opened tubular shape so as to be vertically disposed inside the outer tube portion 241 so as to communicate with the discharge tube 220, (241) and the inner tube portion (243) by an inner diameter of the inner tube portion (241) and an outer diameter of the inner tube portion (243), and an upper end is communicated with the second hydrocarbon injecting portion (242) And a nozzle section (240) including a preheating conduit (244) having an inlet (245) communicating with the interior of the conduit (243).

6. The method of claim 5,
The inner tube portion (243)
Wherein the hydrocarbon body is heated by the steam plasma (P) and is preheated to a predetermined temperature through the preheating conduit (244).