KR101639767B1 - a manufacturing method of clay composition not hardened using in basalt power and clay composition manufactured - Google Patents

Abstract

The present invention relates to unconsolidated clay using basalt powder, which can improve safety and functionality, and relates to a manufacturing method thereof. The manufacturing method comprises the steps of: heating basalt and crushing the same in fine powder form; (b) mixing cenosphere and an adhesive inside a mixer; (c) inserting a polymer coagulant in the mixture and mixing the same; (d) inserting the mixture mixed with the polymer coagulant and mixing the same; (e) inserting diatomite powder in the basalt powder mixture and mixing the same; (f) inserting an antimicrobial agent in the mixture and mixing the same; and (g) completing unconsolidated clay using basalt.

Description

[0001] The present invention relates to a clay which is not hardened using basalt powder and a method for producing the clay,

An object of the present invention is to provide an antimicrobial agent which can easily penetrate an antibacterial material of an environmentally friendly material between small pores to improve stability and functionality and maintain the viscosity of the clay at a constant level, The clay is not easily adhered to the hand, and the clay is not easily deformed. Further, since the coagulated clay is characterized by the nature of the coagulated clay, the clay is not easily deformed after the manufacture of the clay, Non-hardened clay using basalt powder which is non-toxic to animals and does not harm even when contacted with the skin of young children and can function to protect the skin of young children in a stable manner, and a manufacturing method thereof .

Generally, the uncured cooperating clay has flexibility and can be easily deformed into a desired shape by hand, and when the clay is dried, it is hardened easily and the shape is maintained for a long time.

Such a clay is composed of an inorganic material and water, and the clay itself is heavy, and the moisture is evaporated quickly, so that the desired sculpture is formed in a short time, and the reusable material is not available, .

In order to overcome such disadvantages, water-soluble polymer and various additives are used to make hard clay. However, since such clay is mainly used as a clay for children, environmentally hygienically more stable clay It is a fact that is demanded.

On the other hand, in recent years, a non-hardened clay composition which can be used repeatedly without water without being easily hardened and retaining the same properties for a long time, and a method for producing the same are disclosed in Korean Patent Laid-Open Publication No. 10-2012-0017724.

The technical constitution is as follows: 100 parts by weight of diatomaceous earth powder (first parent material) having a size of 10 to 10,000 mesh; 1 part of hydrophilic and lipophilic propylene glycol (PG), polyethylene glycol (PEG) and glycerin To 70 parts by weight of sand; Shell; Silica sand; ocher; Clay; Cereal; Hard shell of nuts; Cocofit; And 10 to 100 parts by weight of a second base material having a particle size of not more than 1/10 of the diatomite powder selected from the group consisting of sawdust and mixed powder so that the liquid material passes through the pores of the diatomite powder, Kneading and hardening the clay composition.

Accordingly, the clay composition as described above is not hardened even after long use or molding, the same properties are continuously maintained, and repeated use without water is made possible.

However, the diatomaceous earth powder, which is the first base material used as a main component of the clay composition, is made of porous silica and has weak durability of the particles, so that it is easily broken and dust is generated, and a fine particle- , There is a disadvantage in terms of environmental hygiene of children's used clay.

In addition, since the second base material selected from one kind of sand, loess, sawdust or the like having a smaller particle size is mixed with the flocculant in the diatomite powder, which is the first base material, as described above, It is difficult to produce the working clay composition. In addition, in the case of the clay as described above, the clay is not easily united and unfolded more easily than expected, and in particular, the feeling of natural sand can not be reproduced.

Korean Published Patent Application No. 10-2012-0017724 (Publication date: February 29, 2012)

SUMMARY OF THE INVENTION The present invention has been made in order to solve the above-mentioned problems of the prior art. It is an object of the present invention to provide an antimicrobial agent for environmentally friendly materials between small pores by basalt powder, cenosphere powder and diatomaceous earth powder constituting non- So that the viscosity and the viscosity of the clay can be maintained at a constant level, while the properties of the natural sand are soft, and the clay does not easily stick to the hands, In addition to being excellent in the nature of the coagulant, after the preparation of the sculpture, there is no deformation of the shape of the sculpture, so that the non-hardening clay can be easily loosened, To prevent harm and to protect the skin of young children in a stable manner. To provide a non unconsolidated clay with basalt powder that can perform this function.

It is a further object of the present invention to provide a non-hardened clay mixture that can be quickly and uniformly mixed in a short time without the need to coat separate fatty acids with the mixture within the mixer, The present invention also provides a method for producing a non-hardened clay using a basalt powder which can be mixed in a uniform state.

Technical Solution In order to achieve the above object, the present invention provides a non-hardened clay using basalt powder,

A cenosphere, an adhesive, a diatomaceous earth powder having a size of 20 to 200 mash, a powdery basalt powder having a size of 10 to 500 mash, a granular coal dust having a size of 10 to 500 mash, A polymer coagulant, and an antimicrobial agent.

Also, the present invention relates to a method for producing a non-hardened clay mixture comprising 55 to 60% by weight of a basalt powder, 24 to 27% by weight of a cenosphere as a particulate coal dust, 9 to 10% by weight of an adhesive, 5 to 6% 1.5% by weight of a polymer flocculant, and 0.5% by weight of an antibacterial agent.

Further, the present invention is characterized in that the adhesive is composed of glycerin.

Further, the present invention is characterized in that the polymer flocculant is composed of an organic polymer flocculant.

According to another aspect of the present invention, there is provided a method for producing an uncured clay using basalt powder,

(a) heating basalt rocks in a furnace at a temperature of 1000 ° C or higher to produce powdery basalt powder having a size of 10-500 mash;

(b) 24 to 27% by weight of a cenosphere having a size of 10 to 500 mash, which is particulate coal dust, and 9 to 10% by weight of an adhesive for imparting viscosity to the total weight of the clay, Mixing and stirring the mixture;

(c) adding 1.5% by weight of a polymer flocculant to the mixed mixture of step (b), stirring the mixture for a predetermined time, and mixing the mixture;

(d) adding 55 to 60% by weight of pulverized basalt powder from step (a) to the mixture of the polymer flocculant of step (c), stirring and mixing for a predetermined time;

(e) adding 5 to 6% by weight of diatomaceous earth powder having a size of 20 to 200 mash to the mixture of basalt flour in step (d), stirring and mixing the mixture for a predetermined period of time;

(f) adding 0.5 wt% of an antimicrobial agent into the mixture of diatomite powders of step (e), stirring and mixing; And

(g) drying the mixture containing the antimicrobial agent in step (f) at room temperature to complete a clay which is not hardened; and (b) providing a method for producing a hardened clay using the basalt powder .

Further, the present invention is characterized in that the adhesive in step (b) is composed of glycerin.

Also, the polymer flocculant of the step (c) is characterized by being composed of an organic polymer flocculant.

In addition, the present invention is characterized in that the mixing of the mixture and the adhesive in the stirrer of the step (b) is performed by stirring for 10 to 15 minutes.

In addition, the present invention is characterized in that the mixing of the polymer flocculant with the mixture of the adhesive of step (c) to step (b) is performed by stirring for 10 to 15 minutes.

In addition, the pulverized basalt powder is mixed with the mixture of the polymer flocculant of step (d) and step (c), followed by mixing for 10 to 15 minutes.

Meanwhile, the present invention is characterized in that the diatomite powder having a size of 20 to 200 mashes is mixed with the mixture of the basalt powder in the step (e), and the mixture is stirred for 10 to 15 minutes.

According to the non-hardened clay using the basalt powder of the present invention and the method for producing the same, the antimicrobial material of the environmentally friendly material can easily penetrate between the small pores to improve the stability and the functionality, and the viscosity of the clay is always constant So that it is possible to keep the properties of natural sand while being soft and not sticking easily on the hands and to make the feel of the clay even better. In addition, due to the nature of the coagulated clay, after the production of the sculpture, It is a non-toxic, non-toxic, non-toxic, non-hazardous clay that can be easily loosened. It has excellent effect.

In addition, the non-hardened clay mixture can be quickly and uniformly mixed in a short time without the need to coat the mixture with a mixture of fatty acids in the mixer, thereby shortening the production time of the hardened clay and mixing the mixture in a uniform state There is an excellent effect that can be.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart for explaining a method for producing a non-hardened clay using a basalt powder according to the present invention. FIG.
FIG. 2 is a photograph of a non-hardened clay using the basalt powder of the present invention. FIG.
FIG. 3 is a photograph of a state in which a triangular, square, and circular sculpture is completed by using a non-hardened clay using the basalt flour of the present invention.
FIG. 4 is a photograph of a state in which sculptures are stacked and completed using the non-hardened clay of the present invention.

Hereinafter, an embodiment of the non-hardened clay using the basalt powder of the present invention will be described in detail.

The non-hardened clay using the basalt powder according to the present invention is characterized by comprising 55 to 60% by weight of basalt powder in the form of 10 to 500 mash powder, 10 to 500 mash of fine particulate coal dust, a polymer flocculant composed of an organic polymer flocculant, 1.5 wt.% of an antimicrobial agent, 0.5 wt.% of an antimicrobial agent, 10 wt.% of an antimicrobial agent, 9 to 10 wt.% of glycerin as an adhesive, 5 to 6 wt.% of diatomaceous earth powder of 20 to 200 mesh, .

Hereinafter, an embodiment of the method for producing the non-hardened clay using the basalt powder of the present invention will be described in detail.

FIG. 1 is a flow chart for explaining a method for producing a non-hardened clay using a basalt powder according to the present invention. In the first step, a basalt composed of a porous carbon (C) The basalt powder is pulverized into a powder having a size of 10 to 500 mash in a pulverizer to produce a basalt powder.

The basalt is inherently harmless to humans and animals due to its inherent carbon (C) content. Especially, even when it comes into contact with the skin of young children, Thereby improving stability and functionality.

In addition, when the size of the heated basalt is less than 10 mashes, it can not be mixed in a uniform state due to an excessively small size during the mixing process described below. When the size of the basalt rock is 500 mash or more The basalt is preferably pulverized into a powder having a size of 10 to 500 mashes.

Also, in step (b), 24 to 27% by weight of cenosphere, which is particulate coal dust, and 9 to 10% by weight of an adhesive for imparting viscosity are added into the mixer with respect to the total weight% of the clay, Mixed.

In this case, the adhesive is composed of glycerin. When the adhesive is added to the senosphere at a content of 9 wt% or less, the viscosity of the clay which is not hardened becomes weak, so that it can not be easily united and loosened. Is added in an amount of 10 wt% or more, the viscosity of the clay becomes too high due to too high a viscosity, so that it can not be easily loosened. It is preferable that 9 to 10 wt% of an adhesive for imparting viscosity to the coated mixture is added, Mixing for 15 minutes is most preferred.

In step (c), 1.5% by weight of a polymer flocculant composed of an organic polymer flocculant is added to the mixture of the adhesive of step (b) and Senosphere, and the mixture is stirred for 10 to 15 minutes.

At this time, the polymer flocculant is mixed with the mixture of the adhesive and Senosphere, and the resultant mixture is mixed so that the shape of the molding is not deformed after the production of the molding product due to the characteristics of the clay.

Subsequently, in step (d), 55 to 60% by weight of pulverized basalt powder of step (a) is added to the mixture of the polymer flocculant of step (c), stirred and mixed for a certain period of time, To (d) is mixed with 5 to 6 wt% of diatomaceous earth powder having a size of 20 to 200 mash, and the mixture is stirred and mixed for a certain period of time.

24 to 26% by weight of cenosphere, particulate coal dust in step (b), is added to 55 to 60% by weight of the pulverized basalt powder in step (a) The mixture is mixed in a mixer of 20 to 200 mash-sized diatomaceous earth powder and 5 to 6 wt%, and when the basalt powder is 55 wt% or less, carbon and adsorption properties inherent to basalt are degraded, The content of diatomaceous earth composed of cenosphere and amorphous silica becomes high and it becomes difficult to produce clay which is not hardened. When the basalt powder is more than 60 wt%, it is possible to obtain a spherical silica alumina compound, the content of cenosphere and diatomaceous earth powder is so small that natural sand properties can not be obtained and the viscosity of the clay which is not hardened can not always be kept constant. The basalt powder 55 to Seno spear (cenosphere) of fine particles in the form of coal dust to 60% by weight of pulverized, as in the 24 to 27 is most preferable to blend charged into the weight percent of diatomaceous earth powder, 5-6% by weight of the internal mixer.

In addition, in step (f), 0.5% by weight of an antimicrobial agent is added to the mixture of the diatomite powder mixed in step (e) so that the mixture is stirred and mixed, Provide a stable protection for young children's skin.

In step (g), the mixture containing the antimicrobial agent of step (f) is dried at room temperature to complete the non-hardened clay.

Therefore, the non-hardened clay using the basalt powder dried at room temperature as described above can be easily united and loosened. As a result of the nature of the coagulated clay, there is no deformation of the shape of the molding, and sufficient elasticity It is not sticky while keeping it.

FIG. 2 is a photograph of a non-hardened clay using the basalt powder of the present invention. FIG. 3 is a photograph of a triangular, square, and circular shaped finished product using the hardened clay using the basalt powder of the present invention. As shown in the photographs of FIG. 2 and FIG. 3, it can be confirmed that the clay is in a state of fine natural sand which does not harden. In addition, the clay can be used to easily complete a molding such as a triangle, a square or a circle.

FIG. 4 is a photograph of a state in which sculptures are piled up using the non-hardened clay of the present invention, and the sculptures such as a triangle, a square, and a circle are piled up by using the clay as described above.

The foregoing description is merely illustrative of the technical idea of the present invention, and various changes and modifications may be made by those skilled in the art without departing from the essential characteristics of the present invention. Therefore, the embodiments disclosed in the present invention are intended to illustrate rather than limit the scope of the present invention, and the scope of the technical idea of the present invention is not limited by these embodiments. The scope of protection of the present invention should be construed according to the following claims, and all technical ideas within the scope of equivalents should be construed as falling within the scope of the present invention.

Claims (11)

In non-hardened clay using basalt powder,
A cenosphere, an adhesive, a diatomaceous earth powder having a size of 20 to 200 mash, a powdery basalt powder having a size of 10 to 500 mash, a granular coal dust having a size of 10 to 500 mash, A polymer flocculant, and an antimicrobial agent.
The method according to claim 1, wherein the non-hardened clay mixture comprises 55 to 60 wt.% Of basalt powder, 24 to 27 wt.% Of cenosphere as fine particulate coal dust, 9 to 10 wt.% Of adhesive, 5 to 6 wt. %, 1.5% by weight of a polymer flocculant, and 0.5% by weight of an antimicrobial agent.
The uncured clay according to claim 1, wherein the adhesive is composed of glycerin.
The uncured clay according to claim 1, wherein the polymer flocculant is composed of an organic polymer flocculant.
A method for producing a non-hardened clay using basalt powder,
(a) heating basalt rocks in a furnace at a temperature of 1000 ° C or higher to produce powdery basalt powder having a size of 10-500 mash;
(b) 24 to 27% by weight of a cenosphere having a size of 10 to 500 mash, which is particulate coal dust, and 9 to 10% by weight of an adhesive for imparting viscosity to the total weight of the clay, Mixing and stirring the mixture;
(c) adding 1.5% by weight of a polymer flocculant to the mixed mixture of step (b), stirring the mixture for a predetermined time, and mixing the mixture;
(d) adding 55 to 60% by weight of pulverized basalt powder from step (a) to the mixture of the polymer flocculant of step (c), stirring and mixing for a predetermined time;
(e) adding 5 to 6% by weight of diatomaceous earth powder having a size of 20 to 200 mash to the mixture of basalt flour in step (d), stirring and mixing the mixture for a predetermined period of time;
(f) adding 0.5 wt% of an antimicrobial agent into the mixture of diatomite powders of step (e), stirring and mixing; And
and (g) drying the mixture containing the antimicrobial agent of step (f) at room temperature to complete the clay which is not hardened. [5] The method for producing the hardened clay using the basalt powder according to claim 1,
[6] The method of claim 5, wherein the adhesive in step (b) comprises glycerin.
[6] The method of claim 5, wherein the polymer flocculant in step (c) comprises an organic polymer flocculant.
[7] The method of claim 5, wherein the mixing of the mixture and the polymer coagulant in the agitator of step (c) is performed by stirring for 10 to 15 minutes.
[7] The method of claim 5, wherein the mixing of the polymer flocculant to the mixture of the adhesive of step (c) and step (b) is performed by stirring for 10 to 15 minutes.
[7] The method according to claim 5, wherein the basecoat pulverized in step (d) is mixed with the polymer coagulant in step (c) by stirring for 10 to 15 minutes. ≪ / RTI >
[7] The method of claim 5, wherein the diatomite powder having a mash size of 20 to 200 m.sup.2 is mixed with the basalt powder mixed in step (d) with stirring for 10 to 15 minutes. Process for the production of hardened clay using basalt powder.

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