KR101627553B1 - Reflection crack resistant, low noise, highly durable asphalt mixture and its thin layer surfacing pavement method - Google Patents

Reflection crack resistant, low noise, highly durable asphalt mixture and its thin layer surfacing pavement method Download PDF

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KR101627553B1
KR101627553B1 KR1020160013376A KR20160013376A KR101627553B1 KR 101627553 B1 KR101627553 B1 KR 101627553B1 KR 1020160013376 A KR1020160013376 A KR 1020160013376A KR 20160013376 A KR20160013376 A KR 20160013376A KR 101627553 B1 KR101627553 B1 KR 101627553B1
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weight
parts
asphalt
aggregate
noise
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박정호
김영상
성기영
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주식회사한수나텍
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    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
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    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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    • C09J195/00Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
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    • E01C11/005Methods or materials for repairing pavings
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/18Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
    • E01C7/187Repairing bituminous covers, e.g. regeneration of the covering material in situ, application of a new bituminous topping
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    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/18Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
    • E01C7/26Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
    • E01C7/262Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with fibrous material, e.g. asbestos; with animal or vegetal admixtures, e.g. leather, cork
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    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/18Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
    • E01C7/26Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
    • E01C7/265Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with rubber or synthetic resin, e.g. with rubber aggregate, with synthetic resin binder
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
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Abstract

Provided are: an economic and eco-friendly asphalt additive for inhibiting reflection crack and enhancing the durability of a road; an asphalt mixture comprising the same; and a method for paving a thin layer using the same. The inventors invents: a plant-type asphalt additive in which plant oil, naphthene-based oil, a mineral fiber, and an organic vulcanization accelerator are mixed; a low-noise asphalt mixture comprising the additive; and a method for paving a reflection crack-resistant, low-noise, and highly durable thin layer using the asphalt mixture.

Description

반사균열 억제형 저소음 고내구성 아스팔트 혼합물 및 이를 이용한 박층 포장 공법 {Reflection crack resistant, low noise, highly durable asphalt mixture and its thin layer surfacing pavement method}TECHNICAL FIELD [0001] The present invention relates to a low-noise, high-durability asphalt mixture,

본 발명은 반사균열 억제형 저소음 고내구성 아스팔트 혼합물 및 이를 이용한 박층 포장 공법에 관한 것이다. The present invention relates to a low-noise, high-durability asphalt mixture and a thin layer packaging method using the same.

국내 아스콘 포장의 설계연수는 20년으로 1회 유지보수를 포함하지만, 실제로는 2~3년마다 보수를 하고 있다. 교통량 및 중차량의 증가로 도로수명이 저하되고 있으며, 도로에 대한 사용자의 기대수준이 높아져 빈번한 재포장으로 인하여 경제적 비용부담이 큰 실정이다.The design training of domestic asbestos packaging includes maintenance once in 20 years, but actually it is paid every 2-3 years. Road life is decreasing due to the increase of traffic volume and heavy vehicles, and the user is expecting a high level of road, and the frequent repacking causes a great economic burden.

도로포장 유지보수공법은 절삭 덧씌우기, 비절삭 덧씌우기로 나눌 수 있고, 비절삭 덧씌우기 공법은 일반적인 덧씌우기와 박층 덧씌우기로 나뉜다.Road pavement maintenance method can be divided into cutting overlay and non - cutting overlaying method, and non - cutting overlaying method is divided into general overlay and thin layer overlay.

아스팔트 덧씌우기 유지보수방법은 기존 노면의 변형에 의해 평탄성이 저하되며, 하부층의 균열이 있던 자리의 덧씌우기 층에서도 균열이 일어나는 반사균열이 발생한다는 문제점이 있다.The asphalt overlay maintenance method has a problem that the flatness is lowered due to the deformation of the existing road surface, and reflection cracks are generated in the overlay layer where the cracks are present in the lower layer.

반사균열 억제공법 중 가장 간단한 방법은 콘크리트 포장 위의 아스팔트 덧씌우기 두께를 두껍게 하여 균열이 뚫고 가야할 두께를 증가시키는 것이다. 이 공법은 반사균열로 인한 파괴까지 걸리는 시간을 지연시킬 수 있으며, 포장의 강도가 증가함으로 인해 교통하중에 의한 줄눈부의 변형을 감소시키는 장점이 있다. 하지만, 포장이 두꺼워질수록 그에 따른 시공비용도 증가하는 단점이 있다 (아스팔트 포장연구회, 1999).The simplest method of reflection crack suppression is to increase the asphalt overlay thickness on the concrete pavement to increase the thickness of the crack to penetrate. This method has the advantage of reducing the deformation of the joint due to the traffic load due to the increase of the strength of the package because it can delay the time taken for the fracture due to the reflection crack. However, there is a disadvantage that the construction cost increases as the package becomes thicker (Asphalt Pavement Research Association, 1999).

토목섬유 적용공법은 차수효과와 반사균열 억제효과에 의한 포장 수명의 연장을 도모하기 위해 1960년대 말부터 아스팔트 덧씌우기 포장에 사용되고 있다. 1975년 이래 미국의 여러 주에서는 연방도로국 (FHWA)과 함께 상이한 기후조건 하에서의 토목섬유 보강 아스팔트 덧씌우기 포장의 시공과 공용성에 관한 연구들이 수행되었는데, 대부분의 연구결과는 토목섬유 보강재가 노후포장 상부로의 반사균열을 상당히 감소시켜 아스팔트 덧씌우기 층의 두께를 줄일 수 있음을 보여주었다 (건설교통부, 2002b).The application of geosynthetic fiber has been used for asphalt pavement pavement since the late 1960s in order to extend the life of the pavement due to the order effect and reflection crack suppression effect. Since 1975, several US states have conducted studies on the construction and commonality of geosynthetically reinforced asphalt overlay pavements under different climatic conditions with the Federal Road Administration (FHWA). Most of the studies have shown that the geotextile reinforcement (2002b) that the thickness of the asphalt overlay layer can be reduced by significantly reducing the reflection cracking of the asphalt pavement layer.

일반적으로 배수성 또는 SMA (Stone Mastic Asphalt) 혼합물은 골재 최대치수가 작을수록 소음감소 효과가 크다. 특히, SMA는 굵은 골재가 차지하는 비율이 높고, 굵은 골재의 맞물림에 의해 형성된 간극을 아스팔트 모르타르로 채운 갭(gap) 입도의 혼합물이다. 포장 표면이 공극을 가지기 때문에 배수성이나 소음저감 등의 기능은 다소 떨어지지만 내구성이 높다.Generally, the smaller the aggregate maximum number is, the greater the noise reduction effect is in a mixture of drainage or SMA (Stone Mastic Asphalt). Particularly, SMA is a mixture of gaps having a high ratio of coarse aggregate and filled with asphalt mortar in a gap formed by meshing of coarse aggregate. Since the pavement surface has pores, the functions such as drainage and noise reduction are somewhat deteriorated, but the durability is high.

절삭 덧씌우기 방법은 기존 노면 파쇄 및 절삭으로 노면의 손상을 야기하기 때문에 덧씌우기 후 노면 내구성 저하의 원인이 될 수 있다. 또한, 파쇄, 절삭한 폐기물 발생 및 처리로 환경적인 문제와 처리비용이 증가하는 문제가 있다.The cutting overlay method can damage the road surface due to the existing road surface crushing and cutting, which may cause the durability of the road surface to be degraded after overlaying. In addition, there is a problem that environmental problems and processing costs are increased due to the generation and processing of waste that has been crushed and cut.

일반 비절삭 덧씌우기 방법은 도로 노면이 상승하여 차량 운행이 불편해지고 우수 처리가 어려워지는 등의 문제가 있어서 도로 구조상 덧씌우기가 가능한 지역이 한정적이다.The general non-cutting overlay method has problems such as inconvenience of driving the vehicle due to the elevation of the road surface and difficulty in the treatment of the road, so that the area where overlaying is possible is limited.

위와 같은 절삭 덧씌우기 및 일반 비절삭 덧씌우기의 문제점을 해결하기 위하여 본 발명자들은 박층으로 비절삭 덧씌우기를 하는 방법을 연구하게 되었다. In order to overcome the problems of the cutting overlay and the general overlay overlay, the present inventors have studied a method of overlaying a non-cut overlay layer.

종래 박층포장공법에는 수지계 슬러리실 또는 유화 아스팔트를 이용한 슬러리실을 사용하였다.Conventionally, a slurry chamber using a resin-based slurry chamber or an emulsified asphalt was used for the thin-layer pavement method.

수지계 슬러리실은 에폭시, 폴리에스테르 수지, 아크릴 모노머, 폴리우레탄 및 폴리우레아 수지 등을 이용한 수지계 박층포장으로서, 시공온도에 따른 경화 발현의 차이, 수지와 아스팔트 포장과의 재료역학적인 차이로 인하여 내구성이 저하되고 고가의 재료로서 경제성이 떨어져 보편화되기 어렵다. 또한, 용제를 사용해야 하므로 친환경적이지 않으며, 공용연수가 지나면서 미끄럼방지용 골재의 손실로 수지층의 미끄러운 도로가 형성되는 문제가 발생한다. 뿐만 아니라, 수지계 슬러리실은 재시공이 곤란하고, 공용수명이 끝난 후 폐기물 재활용 문제가 발생한다.The resin-based slurry chamber is a resin-based thin-layered package using epoxy, polyester resin, acrylic monomer, polyurethane, and polyurea resin, and has poor durability due to difference in hardening development depending on the application temperature and mechanical difference between resin and asphalt pavement. And it is difficult to be generalized because it is economical as an expensive material. In addition, since it is necessary to use a solvent, it is not environmentally friendly, and a slippery road of the resin layer is formed due to the loss of the slip-resistant aggregate as the common softening water passes. In addition, the resin-based slurry chamber is difficult to re-work, and there is a problem of waste recycling after the end of the common life.

유화아스팔트를 이용한 슬러리실은 상온 및 저온에서 양생시간 증가로 교통을 통제해야 하는 문제점이 있다. 또한, 유화아스팔트 자체의 물리적 성질로 인해 내구성이 부족하다는 단점이 있다.There is a problem that the slurry room using emulsified asphalt has to control the traffic by increasing the curing time at room temperature and low temperature. In addition, there is a disadvantage that durability is insufficient due to physical properties of emulsified asphalt itself.

본 발명은 위와 같은 종래 기술의 문제점을 해결하여 반사균열을 억제하고 소음을 저감하며, 도로의 내구성을 증강하며, 경제적이고 친환경적인 아스팔트 첨가재 및 이를 포함하는 아스팔트 혼합물, 그리고 이를 이용한 박층 포장공법을 제공하려는 것을 목표로 한다.Disclosure of Invention Technical Problem [10] Accordingly, the present invention has been made to solve the above-mentioned problems of the prior art and to provide an economical and environmentally friendly asphalt additive, an asphalt mixture containing the same, and a thin layer packaging method using the same, which suppresses reflection cracking, reduces noise, improves road durability The goal is to do.

상기 과제를 해결하기 위하여 본 발명자들은 지속적인 연구를 통해 식물성 오일, 나프텐계 오일, 광물성 섬유, 합성고무 및 유기 가황촉진제를 혼합한 플랜트형 아스팔트 첨가재, 이 첨가재를 포함하는 저소음 아스팔트 혼합물 및 이 아스팔트 혼합물을 이용한 박층 포장공법을 발명하였다.In order to solve the above problems, the inventors of the present invention have conducted continuous research to provide a plant-type asphalt additive in which vegetable oil, naphthene oil, mineral fiber, synthetic rubber and organic vulcanization accelerator are mixed, a low-noise asphalt mixture containing the additive, We invented a thin layer pavement method.

본 발명에서 종래 기술의 문제점을 어떤 구성으로 해결하였는지를 살펴본다.In the present invention, the configuration of the prior art is solved.

먼저, 덧씌우기 보수공법에서 반사균열이 발생하는 문제는 갭 입도 및 섬유보강을 통해 해결하였으며, 점착성 및 신도를 개선한 바인더를 이용함으로써 내균열성을 제고하였다. First, the problem of reflection cracking in the overlay repair method is solved through gap size and fiber reinforcement, and crack resistance is improved by using a binder improved in adhesiveness and elongation.

또한, 절삭 덧씌우기 보수공법의 문제점은 비절삭 덧씌우기를 채용함으로써 해결하였고, 일반 비절삭 덧씌우기 공법의 문제점은 박층 포장공법을 이용하여 해결하였다.Also, the problem of the repair method of cutting overlay is solved by adopting non - cutting overlay, and the problem of general non - cutting overlaying method is solved by using thin layer pavement method.

뿐만 아니라, 기존 포장재와 보수포장재의 재료역학적 차이로 인하여 발생하는 문제점은 보수포장재를 아스팔트계로 함으로써 극복하였다.In addition, the problems caused by the mechanical differences between the existing packaging materials and the maintenance materials were overcome by using the asphalt-based materials.

수지계 슬러리실의 미끄럼 저항성 저하 문제는 갭 입도에 의한 표면 공극증가로 해결하였다.The problem of lowering the sliding resistance of the resin-based slurry chamber was solved by increasing the surface void due to the gap size.

또한, 수지계 슬러리실 적용시 발생하는 폐기물 처리 문제는 첨가재를 아스팔트계로 형성함으로써 재생아스팔트로 이용 가능하게 하여 해결하였다.In addition, the problem of waste disposal occurring when applying the resin-based slurry chamber is solved by making the additive material into an asphalt-based resin so as to be usable as a regenerated asphalt.

뿐만 아니라, 본 발명에서는 첨가재를 가한 아스팔트 혼합물이 중온 아스팔트 기능을 하도록 하여 조기 교통개방이 가능하도록 하였으며, 개질 아스팔트 기능을 유지하도록 하여 포장의 내구성을 제고하였고, 저소음 기능이 발휘되도록 함으로써 종래기술의 문제점들을 해결하였다.In addition, in the present invention, the asphalt mixture containing the additive functions as a mesophase asphalt function, thereby enabling early opening of the traffic. By maintaining the modified asphalt function, the durability of the package is enhanced and the low noise function is exhibited, Respectively.

본 발명의 아스팔트 바인더는 신도, 탄성 및 점착성의 기능과 박층포장을 위한 작업성을 확보해야 한다. 열가소성 엘라스토머를 주성분으로 하는 아스팔트 개질재, 좀 더 구체적으로는 멜트플로우 값이 15g/10분 미만인 비닐 방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성 부여 수지 0.1~100중량부, 방향족 성분 함유량이 20~60중량%이고 40℃에서의 동점도가 70~900㎟/s인 프로세스 오일 5~100중량부를 함유하고, 상기 성분들의 합계 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는 아스팔트 개질재 (이하 본 발명에서 "RMC"라 약칭함)는 합성고무계 첨가재로 고탄성 재료이다. 그러나 박층에 적용하기에는 점도가 높기 때문에 작업성이 저하되며, 특히 RMC는 다짐 온도가 160℃ 이상 요구되어 박층 특성상 다짐온도를 유지하기가 어렵다. 이러한 시공성을 보완하기 위하여 프로세스 오일을 검토하였다. 프로세스 오일 중 나프텐계 오일이 RMC 및 아스팔트와의 상용성이 우수하며, 소량으로도 작업성을 극대화할 수 있다. 이에 더하여, 식물성 오일은 나프텐계 오일과 상용성이 우수하며, 특히 유동성 증가로 작업성을 현저히 향상시키며, 대기오염 물질의 발생량을 줄일 수 있고 본 발명의 혼합물에 적합한 것을 확인하였다.The asphalt binder of the present invention is required to have elongation, elasticity and tackiness and workability for thin layer packaging. 0.1 to 100 parts by weight of a tackifier resin is added to 100 parts by weight of an asphalt modifier mainly composed of a thermoplastic elastomer and more specifically a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / And 20 to 60% by weight, and 5 to 100 parts by weight of a process oil having a kinematic viscosity at 40 DEG C of 70 to 900 mm2 / s, and 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components The modifier (hereinafter abbreviated as "RMC" in the present invention) is a synthetic rubber-based additive and is a highly elastic material. However, since the viscosity of the thin layer is high, the workability is deteriorated. In particular, RMC requires a compaction temperature of 160 ° C or more, and it is difficult to maintain the compaction temperature due to the characteristics of the thin layer. The process oil was examined to improve the workability. Naphthenic oil in process oil is excellent in compatibility with RMC and asphalt, and it is possible to maximize workability even in a small amount. In addition, the vegetable oil has excellent compatibility with the naphthenic oil, and it is confirmed that it is possible to remarkably improve the workability by increasing the flowability, reduce the amount of air pollutants generated, and is suitable for the mixture of the present invention.

이와 같은 RMC와 프로세스 오일과의 조합은 박층 포장의 작업성을 극대화하였고, 또한 신도를 증가시켜 균열저항성을 극대화하였으나, 바인더의 점도 감소로 인하여 골재 피막 두께가 감소하기 때문에, 혼합물의 탈리저항성을 보완하기 위하여 본 발명자들은 섬유를 보강하는 것을 검토하였다. 섬유의 직경 및 길이는 특별한 제한은 없으나, 1~10 미크론의 직경 및 길이 약 200~1000 미크론 내외의 섬유, 더욱 바람직하게는 4~6 미크론의 직경 및 약 500 미크론 길이의 섬유를 사용할 때 아스팔트와의 분산성이 극대화되었고, 본 발명 혼합물의 적절한 바인더 점도를 확보하기 위하여 첨가량을 결정하였다. 또한, 섬유는 양이온 처리 (cationic sizing)가 되어 있어서, 아스팔트 내부에서 화학적으로는 계면활성 증가로 분산성이 증대되며, 물리적으로는 섬유의 분산과 네트워크 형성으로 아스팔트의 인장력을 증가시킨다. 혼합물 내부에서도 네트워크를 형성하여 상부로부터의 압축응력을 분산시켜서 소성변형을 감소시키며, 하부로부터 올라오는 인장응력을 분산시켜서 반사균열 저항성을 극대화한다.The combination of RMC and process oil maximized the workability of the thin layer packaging and maximized the crack resistance by increasing the elongation. However, since the aggregate film thickness is decreased due to the decrease of the viscosity of the binder, The present inventors have studied reinforcing fibers. Although the diameter and length of the fibers are not particularly limited, it is preferable to use fibers having a diameter of 1 to 10 microns and a fiber length of about 200 to 1000 microns, more preferably a diameter of 4 to 6 microns and a length of about 500 microns, And the addition amount was determined in order to ensure an appropriate binder viscosity of the mixture of the present invention. In addition, the fibers are cationic sizing, which increases the dispersibility by increasing the surfactant chemically inside the asphalt, physically increasing the tensile strength of the asphalt by fiber dispersion and network formation. Inside the mixture, a network is formed to disperse the compressive stress from the top to reduce the plastic deformation, and to disperse tensile stress from the bottom to maximize the reflection crack resistance.

이러한 조합으로 RMC에 의한 탄성 및 탄성회복력 강화, 오일에 의한 작업성, 시공성 및 저온탄성 강화, 섬유에 의한 네트워크 구성 및 반사균열에 대한 저항성을 갖는 바인더를 개발하였다. 그러나, 상기 조합으로는 바인더가 연화되기 때문에 강도 면에서 개선이 필요하다. 본 발명자들은 상기 조합에 유기 가황촉진제를 강도개선제로 사용하는 것이 효과가 있는 것을 확인하였다. 황은 오일, 아스팔트, 합성고무에 포함된 이중결합에 첨가되어 상기 원료들이 화학적인 네트워크를 구성할 수 있도록 하며, 이러한 네트워크 형성으로 아스팔트 바인더의 기계적 성질을 획기적으로 개선할 수 있다.In this combination, we have developed a binder that has elasticity and resilience by RMC, workability by oil, workability and low-temperature elasticity reinforcement, network structure by fiber, and resistance to reflection cracks. However, since the binder is softened with such a combination, improvement in strength is required. The present inventors have confirmed that the use of an organic vulcanization accelerator as the strength improver in the above combination is effective. Sulfur is added to the double bonds contained in oil, asphalt and synthetic rubber so that the raw materials can constitute a chemical network. Such network formation can dramatically improve the mechanical properties of the asphalt binder.

또한, 본 발명의 아스팔트 첨가재를 포함하는 아스팔트 혼합물은 얇은 두께로 포설, 다짐하기 위해서 5mm 이하의 골재를 사용함으로써 15~25mm로 포설, 다짐할 수 있다. 골재로는 아스팔트 혼합물용 골재로서의 물성을 갖고, 특히 포러스용 골재 즉 둥글고 모가 많이 난 형상을 가져 시공 후 골재 간의 맞물림 기능을 유지할 수 있어야 한다. 본 발명의 아스팔트 혼합물은 골재 맞물림 효과와 바인더의 점착성, 탄성 기능으로 소성변형 저항을 극대화하였다 (표 6). 또한, 박층 시공으로 현장에서 혼합물 온도가 급히 식기 때문에 저온 다짐성능을 극대화하였다 (표 7). 또한, 바인더의 점착성 기능으로 골재 탈리에 대한 저항성을 극대화하였다 (표 8). 혼합물은 바인더의 신도, 탄성 및 탄성회복력 기능으로 내균열 성능이 우수하며 반사균열 저항성을 극대화하였다 (표 9). 또한, 본 발명 혼합물은 반사균열 저항성을 극대화하였다 (표 10). 또한, 갭 입도의 표면공극 확보로 미끄럼저항성, 소음 저감성을 극대화하였다 (표 11).In addition, the asphalt mixture containing the asphalt additive of the present invention can be installed and compacted at 15 to 25 mm by using an aggregate of 5 mm or less in order to lay down and compaction with a thin thickness. The aggregate has physical properties as an aggregate for an asphalt mixture, and in particular, it has a shape of a round aggregate, that is, a round aggregate. The asphalt mixture of the present invention maximizes the plastic deformation resistance by the aggregate bonding effect, the adhesive property of the binder, and the elastic function (Table 6). In addition, since the mixture temperature rapidly rises in the field by thin layer construction, the low temperature compaction performance is maximized (Table 7). In addition, the adhesive function of the binder maximizes the resistance to aggregate desorption (Table 8). The mixture was excellent in crack resistance due to the elongation, elasticity and elastic recovery function of the binder and maximized the reflection crack resistance (Table 9). The mixture of the present invention also maximized the reflection crack resistance (Table 10). In addition, securing the surface gap of the gap size maximized the slip resistance and the noise reduction (Table 11).

아래 표 1은 본 발명의 아스팔트 첨가재의 구성성분과 조성비를 나타낸 것이다.Table 1 below shows the composition and composition ratio of the asphalt additive of the present invention.

성분ingredient 조성비(중량%)Composition ratio (% by weight) 아스팔트 개질재 RMCAsphalt modifier RMC 5~155 to 15 나프텐계 오일Naphthenic oil 50~8050 to 80 식물성 오일vegetable oil 5~205-20 광물성 섬유Mineral fiber 5~205-20 유기 가황촉진제Organic vulcanization accelerator 0.1~0.50.1 to 0.5

본 발명의 아스팔트 첨가재를 구성하는 각 구성성분에 대해 아래에서 살펴본다.Each component constituting the asphalt additive of the present invention will be described below.

아스팔트 asphalt 개질재Modifier RMCRMC

멜트플로우 값이 15g/10분 미만인 비닐방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성부여 수지 0.1∼100중량부, 방향족성분 함유량이 20∼60중량%이고, 40℃에서의 동점도가 70∼900㎟/s인 것을 특징으로 하는 프로세스유 5∼100중량부를 함유하고, 상기 성분들의 합계량 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는, 아스팔트 개질재 "RMC"는 공용 중 내구성을 강화하고, 바인더의 인장응력 및 회복력을 부여하여 균열저항성을 증대시킨다. 아스팔트 개질재 "RMC"가 5중량% 미만일 때는 탄성이 부족하여 내구성, 바인더의 인장응력 및 회복력을 부여하여 균열저항성을 증대시키기가 어렵고, 15중량%를 초과하면 점도가 상승하여 작업성이 급격히 떨어진다.0.1 to 100 parts by weight of a tackifying resin, 20 to 60% by weight of an aromatic component, and a kinematic viscosity at 40 占 폚 of 70 to 70 parts by weight based on 100 parts by weight of a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / Wherein the asphalt modifier "RMC" comprising 5 to 100 parts by weight of process oil characterized in that the process oil is characterized by the fact that the asphalt modifier "RMC" contains 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components, And the tensile stress and the recovery force of the binder are imparted to increase the crack resistance. When the asphalt modifier "RMC" is less than 5% by weight, the elasticity is insufficient and durability, tensile stress and recovery force of the binder are imparted to increase the crack resistance, and when it exceeds 15% by weight, viscosity increases and workability drops sharply .

나프텐계Naphthenic system 오일 oil

본 발명에 사용하는 나프텐계 오일은 40~50%(w/w)의 나프텐환을 함유하고 고분자량으로 구성되어 있어, RMC와의 섞임성 및 분산성을 증대시킨다. 이 오일은 극성화합물이 6% 이내로 존재하며, 파라핀계 오일에 비하여 점도지수가 낮고, 용해력이 높아 RMC 유화력을 증대시키고 아스팔트 혼합물 내에서 본 첨가재의 분산성을 극대화한다. 50중량% 미만일 때는 RMC와의 섞임성 및 분산성을 증대시키기가 어렵고, 80중량%를 초과하면 과도한 점도 저하로 물리적 강도를 유지하기 어렵다.The naphthenic oil used in the present invention contains 40 to 50% (w / w) naphthene rings and is composed of a high molecular weight, thereby increasing the mixing and dispersibility with RMC. This oil has a polar compound within 6%, has a lower viscosity index than paraffin oil, and has higher solubility, thereby increasing the emulsifying power of RMC and maximizing the dispersibility of the additive in the asphalt mixture. When it is less than 50% by weight, it is difficult to increase the mixing property and dispersibility with RMC, and when it exceeds 80% by weight, it is difficult to maintain physical strength due to excessive viscosity drop.

식물성 오일vegetable oil

본 발명에는 올레산, 리놀산, 리노신산, 대두유, 폐식용유, 유채유, 해바라기유, 팜유, 옥수수유 등과 같은 다양한 식물성 오일 중 1종 이상을 선택하여 이용할 수 있고, 식물성 오일을 이용함으로써 특히 혼합물 생산과정에서의 대기오염물질 (휘발성 유기화합물, VOC) 발생량을 현저히 줄일 수 있다. 40℃ 동점도가 300℃St 이하인 식물성 오일은 혼합물의 유동성을 증가시켜 작업성을 현저히 개선하며, 박층포장으로 인한 온도저하에 따른 작업성 변동을 최소화한다. 다시 말하여, 식물성 오일은 아스팔트 혼합물이 중온화 효과가 나타나도록 한다. 본 발명에 사용하는 식물성 오일은 리놀렌산을 6~10% 함유하며, 리놀렌산 중의 메틸 에스테르에 의하여 유동성이 증가한다. 이 오일은 바인더의 신도를 증대시켜 아스팔트 혼합물에서 균열저항성을 높이며, 자체균열 및 반사균열을 방지하는 성능을 발휘한다. 첨가재 중 함량이 5중량% 미만인 경우 혼합물의 유동성을 증가시키는 효과가 미비하고, 20중량%를 초과하면 과도한 점도 저하로 물리적 강도를 유지하기 어렵다.In the present invention, at least one of various vegetable oils such as oleic acid, linoleic acid, linosinic acid, soybean oil, waste cooking oil, rapeseed oil, sunflower oil, palm oil, corn oil and the like can be selected and used. The amount of air pollutants (volatile organic compounds, VOCs) in the air can be significantly reduced. A vegetable oil having a kinematic viscosity of less than 300 DEG C at 40 DEG C improves the workability by increasing the fluidity of the mixture and minimizes the workability fluctuation due to the temperature drop due to the thin layer packaging. In other words, the vegetable oil causes the asphalt mixture to exhibit a mesophilic effect. The vegetable oil used in the present invention contains 6-10% of linolenic acid, and the fluidity is increased by the methyl ester in linolenic acid. The oil enhances the elongation of the binder to increase the crack resistance in the asphalt mixture and prevents its self-cracking and reflective cracking. When the content of the additive is less than 5% by weight, the effect of increasing the fluidity of the mixture is insufficient. When the content of the additive exceeds 20% by weight, it is difficult to maintain the physical strength due to excessive viscosity drop.

광물성 섬유Mineral fiber

본 발명에 사용하는 광물성 섬유는 현무암, 섬록암, 또는 슬래그에서 만든 강화 섬유이다. 가늘고 균일한 섬유가 연속된 미세 공극을 형성하여 방음 기능을 하고, 본 발명의 첨가재에 사용하는 식물성 오일과 나프텐계 오일을 흡수하여 아스팔트 혼합물 제조시 분산성을 증대시킨다. 섬유는 혼합물 내에서 약 500 미크론 정도의 길이로 분산되어 맞물려 있는 골재 사이에 존재한다. 골재 사이에 존재하는 섬유는 양이온 처리 (cationic sizing)가 되어 있어서, 아스팔트와의 접착력이 좋아지며, 바인더와 혼합되어 골재에 피막을 형성하여 박리 및 균열저항성을 증대시킨다. 광물성 섬유는 가늘고 균일한 섬유가 연속된 미세 공극을 형성하여 소음이 섬유를 통과할 때 음압 에너지가 마찰 에너지로 변화되어 음을 흡수하는 효과가 있다. 이 광물성 섬유는 직경 및 길이에 특별한 제한은 없으나, 바람직하게는 4-6 미크론의 직경 및 길이 약 500 미크론의 무기물 섬유로 아스팔트의 점도증가를 최소화하며, 최적의 혼합성과 분산성을 발휘한다. 국내 철원 등지에 현무암 매장량이 충분하므로, 바잘트 섬유를 사용하는 것이 바람직하다. 5중량% 미만일 때 혼합물에 분산되어 네트워크 형성이 부족하여 박리 및 균열저항성을 증대시키기 어렵고, 20중량%를 초과하면 점도 증가로 작업성이 급격히 떨어진다.The mineral fibers used in the present invention are reinforced fibers made from basalt, diorite, or slag. The thin and uniform fibers form continuous microvoids to function as a soundproofing and absorb the vegetable oil and the naphthenic oil used in the additive of the present invention to increase the dispersibility in the production of the asphalt mixture. The fibers are present in the mixture between aggregates that are dispersed to a length of about 500 microns. The fibers present in the aggregate are cationic sizing, which improves the adhesion to asphalt and mixes with the binder to form a coating on the aggregate, thereby increasing peel and crack resistance. Mineral fibers have the effect of absorbing sound by changing the sound pressure energy into friction energy when the noise passes through the fiber by forming fine micro pores with thin and uniform fibers. There is no particular limitation on the diameter and the length of the mineral fiber, but inorganic fibers having a diameter of about 4 to 6 microns and a length of about 500 microns are preferably used to minimize the viscosity increase of the asphalt and exhibit optimum mixing and dispersibility. Since basalt reserves are sufficient in domestic steel mills, it is preferable to use basalt fibers. When it is less than 5% by weight, it is dispersed in the mixture to form a network, which makes it difficult to increase the peeling and cracking resistance, and when it exceeds 20% by weight, the viscosity increases and the workability drops sharply.

유기 abandonment 가황촉진제Vulcanization accelerator

고무상 탄성을 나타내는 고분자는 모두 분자 간 상호작용이 약하므로 고무제품을 만드는 데는 반드시 분자 간의 미끄러짐을 막고 물성을 향상시키기 위하여 가황제로 가교(架橋)를 형성한다. 유기 가황촉진제는 가황제의 가황력을 촉진시켜 가황시간을 단축하는 약품이고, 가황함으로써 고무의 물리적 성질을 개선한다. 유기 가황촉진제는 고무원료의 2~3%(w/w)를 첨가하여 탄성 및 회복력을 증진시킨다. 가황량이 많을수록 강도가 상승하고 부서지기 쉽다. 본 발명에서는 아스팔트, 오일, SBS 등의 유기분자 사슬의 이중결합에 황 첨가를 촉진함으로써 단일분자 간을 결합시키거나 각 원료들 간을 연결하여, 탄성 및 회복력 등의 물리적 성질을 개선한다. 0.1중량% 미만일 때 가교(架橋) 형성이 부족하여 물리적 성질을 개선하기 어렵고, 0.5중량%를 초과하면 가교(架橋) 형성이 과도하여 딱딱해져서 탄성이 부족해진다.All of the polymers exhibiting rubber-like elasticity are weak in intermolecular interactions, so that crosslinking is formed with a vulcanizing agent in order to prevent slippage between molecules and to improve physical properties in the production of rubber products. The organic vulcanization accelerator is a chemical agent which accelerates the vulcanizing power of the vulcanizing agent to shorten the vulcanization time, and improves the physical properties of the rubber by vulcanization. Organic vulcanization accelerators increase elasticity and resilience by adding 2 ~ 3% (w / w) of rubber raw materials. The higher the amount of vulcanization, the higher the strength and the more likely it is to break. In the present invention, the addition of sulfur to the double bonds of organic molecular chains such as asphalt, oil, SBS, etc. is promoted to bond single molecules or to connect the respective raw materials to improve physical properties such as elasticity and resilience. When the amount is less than 0.1% by weight, crosslinking (crosslinking) formation is insufficient and physical properties are difficult to improve. When the amount is more than 0.5% by weight, crosslinking (crosslinking) is excessively hardened and elasticity becomes insufficient.

본 발명은 The present invention

열가소성 엘라스토머를 주성분으로 하는 아스팔트 개질재;An asphalt modifier mainly comprising a thermoplastic elastomer;

나프텐계 프로세스 오일;Naphthenic process oil;

식물성 오일;vegetable oil;

광물성 섬유; 및 Mineral fibers; And

유기 가황촉진제;를 포함하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재에 관한 것이다.And an organic vulcanization accelerator. The present invention relates to a low-noise, high-durability asphalt additive.

또한, 본 발명은 In addition,

열가소성 엘라스토머를 주성분으로 하는 아스팔트 개질재 5~15중량%;5 to 15% by weight of an asphalt modifier mainly comprising a thermoplastic elastomer;

나프텐계 프로세스 오일 50~80중량%;50 to 80% by weight of naphthenic process oil;

식물성 오일 5~20중량%;5 to 20% by weight vegetable oil;

광물성 섬유 5~20중량%; 및 5 to 20% by weight of mineral fibers; And

유기 가황촉진제 0.1~0.5중량%를 포함하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재에 관한 것이다.And 0.1 to 0.5% by weight of an organic vulcanization accelerator. The present invention relates to a low-noise, high-durability asphalt additive.

또한, 본 발명은 상기 열가소성 엘라스토머를 주성분으로 하는 아스팔트 개질재가 멜트플로우 값이 15g/10분 미만인 비닐 방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성 부여 수지 0.1~100중량부, 방향족 성분 함유량이 20~60중량%이고, 40℃에서의 동점도가 70~900㎟/s인 프로세스 오일 5~100중량부를 함유하고, 상기 성분들의 합계 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는 아스팔트 개질재임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재에 관한 것이다.Further, the present invention is characterized in that the asphalt modifying material comprising the above thermoplastic elastomer as a main component has a viscosity of 0.1 to 100 parts by weight, a content of aromatic components of 10 to 100 parts by weight per 100 parts by weight of a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / Is 20 to 60% by weight and has a kinematic viscosity at 40 DEG C of 70 to 900 mm < 2 > / s, and further comprises 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components Asphalt modifier, and a low-noise, high-durability asphalt additive.

또한, 본 발명은 상기 나프텐계 오일이 40~50중량%의 나프텐환을 함유하는 것을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재에 관한 것이다.Further, the present invention relates to a reflection-crack-suppressing low noise, high-durability asphalt additive characterized in that the naphthenic oil contains 40 to 50 wt% naphthene rings.

또한, 본 발명은 상기 식물성 오일이 리놀렌산을 6~10% 함유함을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재에 관한 것이다.Further, the present invention relates to a low-noise, high-durability asphalt additive for reflection crack prevention which is characterized in that the vegetable oil contains linoleic acid in an amount of 6 to 10%.

또한, 본 발명은 상기 광물성 섬유가 양이온 처리가 되어 있는 것임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재에 관한 것이다.Further, the present invention relates to a low-noise, high-durability asphalt additive for reflection crack suppression which is characterized in that the mineral fiber is subjected to cation treatment.

또한, 본 발명은 상기 유기 가황촉진제가 알데히드 암모니아계,알데히드 아민계, 구아니딘계, 티오우레아계, 티아졸계, 티우람계, 디티오 카보메이트계, 크산테이트계, 설펜아민드계 중 선택된 1종 이상임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재에 관한 것이다.The present invention also relates to a process for producing the organic vulcanization accelerator, wherein the organic vulcanization accelerator is at least one selected from aldehyde ammonia type, aldehyde amine type, guanidine type, thiourea type, thiazole type, thiuram type, dithiocarbomate type, xanthate type, And a low-noise, high-durability asphalt additive.

또한, 본 발명은 상기 아스팔트 첨가재 2~6중량%; 및 아스팔트 94~98중량%;를 함유하는 반사균열 억제형 저소음 고내구성 아스팔트 바인더에 관한 것이다.Also, the present invention relates to an asphalt admixture comprising 2 to 6% by weight of the asphalt admixture; And 94 to 98 wt% of asphalt; and a low-noise, high-durability asphalt binder.

또한, 본 발명은 상기 아스팔트가 스트레이트 아스팔트, 스트레이트 아스팔트에 멜트플로우 값이 15g/10분 미만인 비닐 방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성 부여 수지 0.1~100중량부, 방향족 성분 함유량이 20~60중량%이고, 40℃에서의 동점도가 70~900㎟/s인 프로세스 오일 5~100중량부를 함유하고, 상기 성분들의 합계 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는 아스팔트 개질재를 첨가하는 개질아스팔트, SBS 개질아스팔트 중 선택된 1종임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 바인더에 관한 것이다.Also, the present invention is characterized in that 0.1 to 100 parts by weight of a tackifying resin is added to 100 parts by weight of a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / 10 min on a straight asphalt and straight asphalt, 20 to 60% by weight, and 5 to 100 parts by weight of a process oil having a kinematic viscosity at 40 占 폚 of 70 to 900 mm2 / s, and 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components Modified asphalt, and modified SBS modified asphalt to which a modifier is added. The present invention relates to a low-noise, high-durability asphalt binder for reflection crack suppression.

또한, 본 발명은 상기 아스팔트 바인더 5~8중량%; 골재 77~92중량%; 및 채움재 3~15중량%;를 포함하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물에 관한 것이다.The present invention also relates to an asphalt binder comprising 5 to 8% by weight of the asphalt binder; 77 to 92% by weight of aggregate; And 3 to 15% by weight of a filler. The present invention relates to a low-noise, high-durability asphalt mixture.

또한, 본 발명은 상기 골재가는 13㎜ 체를 100% 통과하고, 5㎜ 체를 90~100% 통과하고, 2.5㎜ 체를 35~50% 통과하고, 0.3㎜ 체를 15~25% 통과하고, 0.08㎜ 체를 8~13% 통과하는 것임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물에 관한 것이다.In the present invention, the aggregate passes 100% of a 13 mm sieve, passes 90 to 100% of a 5 mm sieve, passes 35 to 50% of a 2.5 mm sieve, passes 15 to 25% of a 0.3 mm sieve, 0.0 > 8% < / RTI > sieve of 0.08 mm sieve. The present invention relates to a low-noise, high-durability asphalt mixture.

또한, 본 발명은 상기 골재가 둥글고 모가 난 형상의 포러스용 골재임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물에 관한 것이다.Further, the present invention relates to a low-noise and high-durability asphalt mixture for suppressing reflection cracks, characterized in that the aggregate is a porous aggregate having a rounded shape.

또한, 본 발명은 상기 아스팔트 혼합물 100중량부에 대하여 무기안료 1~10중량부를 가하는 것을 특징으로 하는 반사균열 억제형 저소음 고내구성 유색 아스팔트 혼합물에 관한 것이다.Further, the present invention relates to a reflection-crack-suppressing low-noise, high-durability colored asphalt mixture, wherein 1 to 10 parts by weight of an inorganic pigment is added to 100 parts by weight of the asphalt mixture.

또한, 본 발명은 상기 골재 중 10~100중량%이 재생골재임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물에 관한 것이다.Also, the present invention relates to a low-noise, high-durability asphalt mixture for suppressing reflection cracks, wherein 10 to 100% by weight of the aggregate is recycled aggregate.

또한, 본 발명은 상기 골재의 최대치수가 5㎜인 것을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물에 관한 것이다.Further, the present invention relates to a low-noise, high-durability asphalt mixture for suppressing reflection cracks, characterized in that the maximum value of the aggregate is 5 mm.

또한, 본 발명은 상기 골재에 굵은골재를 추가하여 골재 최대치수가 13~8㎜인 것을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물에 관한 것이다.Further, the present invention relates to a low-noise and high-durability asphalt mixture for suppressing reflection cracks, characterized in that a coarse aggregate is added to the aggregate and the maximum aggregate count is 13 to 8 mm.

뿐만 아니라, 본 발명은 상기 아스팔트 혼합물을 15~25㎜로 박층 덧씌우기 포장하는 반사균열 억제형 저소음 고내구성 도로포장 보수방법에 관한 것이다.In addition, the present invention relates to a method of repairing and repairing a low-noise, high-durability anti-reflection cracking type asphalt mixture packed in a thin layer of 15 to 25 mm.

본 발명에 따른 첨가재를 포함하는 아스팔트 혼합물에 대해 물성을 시험한 결과, 내유동성, 균열저항성, 저온 다짐성능, 미끄럼저항성, 마모저항성 등이 모두 비교예에 비하여 우수한 것으로 나타났고, 저소음 기능도 우수한 것으로 나타났다.As a result of testing the physical properties of the asphalt mixture containing the additive according to the present invention, it was found that the fluidity, the crack resistance, the low temperature compaction performance, the slip resistance and the abrasion resistance were all superior to the comparative example, appear.

따라서, 본 발명의 첨가재를 포함하는 아스팔트 혼합물은 반사균열을 억제하고 소음을 줄이는 박층포장에 유용할 것으로 사료된다.Therefore, the asphalt mixture containing the additive of the present invention is considered to be useful for thin layer packaging which suppresses reflection cracking and reduces noise.

아래에서는 구체적인 실시예를 들어 본 발명의 구성을 좀 더 자세히 설명한다. 그러나, 본 발명의 범위가 실시예의 기재에 한정되는 것이 아님은 본 발명이 속한 기술분야에서 통상의 지식을 가진 자에게 자명하다.Hereinafter, the configuration of the present invention will be described in more detail with reference to specific embodiments. However, it should be apparent to those skilled in the art that the scope of the present invention is not limited to the description of the embodiments.

아래 표 2는 상기 본 발명의 아스팔트 첨가재를 이용한 아스팔트 바인더의 조성비를 나타낸다. 본 발명의 첨가재를 가하지 않은 것을 비교예로 사용하였다.Table 2 below shows composition ratios of the asphalt binder using the asphalt additive of the present invention. Those without the addition of the present invention were used as comparative examples.

  조성비 (중량%)Composition ratio (% by weight) 실시예 1Example 1 비교예 1Comparative Example 1 본 발명의 첨가재The additive 2~62 to 6 3.53.5 -- 개질 아스팔트Modified asphalt 94~9894 ~ 98 96.596.5 100100

본 발명의 아스팔트 바인더에서 첨가재가 2중량% 미만인 경우에는 본 첨가제의 기능을 충분히 발휘하기 어렵고, 6중량% 범위를 초과한 경우 과도한 유동성으로 바인더의 물리적 성질이 저하된다.In the asphalt binder of the present invention, when the additive is less than 2% by weight, the function of the additive is not sufficiently exhibited. When the additive exceeds 6% by weight, the physical properties of the binder are deteriorated due to excessive flowability.

아래 표 3은 상기 표 2의 실시예 1과 비교예 1에 대한 침입도, 신도, 연화점, 저온 휨에너지 시험 결과이다.Table 3 below shows the penetration, elongation, softening point and low temperature bending energy test results for Example 1 and Comparative Example 1 in Table 2 above.

바인더 시험Binder test -- 실시예 1Example 1 개질 아스팔트
(비교예 1)
Modified asphalt
(Comparative Example 1)
--
시험항목Test Items 단위unit 시험결과Test result 시험결과Test result 시험방법Test Methods 침입도Intrusion 1/10mm1 / 10mm 5858 4040 KS M 2252KS M 2252 15℃ 신도15 ° C elongation cmcm 100 이상100 or more 6868 KS M 2254KS M 2254 연화점Softening point 6262 5555 KS M 2250KS M 2250 휨에너지 (-10℃)Bending energy (-10 ℃) kPakPa 17001700 14001400 KS M 2491KS M 2491 휨에너지 (-20℃)Bending energy (-20 ℃) kPakPa 800800 480480 KS M 2491KS M 2491

상기 표 3의 연화점 시험 결과로부터 본 발명의 아스팔트 바인더가 고온특성 즉, 내유동성이 우수함을 알 수 있다. 또한, 신도 및 저온 휨에너지 시험 결과를 보면, 본 발명의 아스팔트 바인더가 저온특성 즉, 균열 저항성이 우수함을 알 수 있다.From the results of the softening point test shown in Table 3, it can be seen that the asphalt binder of the present invention has excellent high-temperature characteristics, i.e., fluidity resistance. In addition, from the results of the elongation and low-temperature bending energy test, it can be seen that the asphalt binder of the present invention has excellent low-temperature characteristics, that is, crack resistance.

아래 표 4는 본 발명의 아스팔트 첨가재를 함유하는 아스팔트 혼합물 ("Ro-Facing") 조성비를 나타낸다.Table 4 below shows the composition ratio of the asphalt mixture ("Ro-Facing") containing the asphalt additive of the present invention.

  조성비 (중량%)Composition ratio (% by weight) 실시예 2Example 2 비교예 2Comparative Example 2 아스팔트 바인더Asphalt binder 5.0~8.05.0 to 8.0 5.9 (실시예 1)5.9 (Example 1) 5.4 (비교예 1)5.4 (Comparative Example 1) 골재aggregate 80~9280 ~ 92 88.188.1 90.690.6 채움재Filler 3~153 to 15 6.06.0 4.04.0

아스팔트 바인더가 5중량% 미만일 경우 바인더 피막 부족 및 피복 부족으로 내구성이 저하될 가능성이 있으며, 8중량% 범위를 초과한 경우는 과도한 바인더로 표면에 블리 등 발생 또는 혼합물의 물리적 성능이 저하될 가능성이 있다.If the amount of the asphalt binder is less than 5 wt%, the durability of the asphalt binder may be insufficient due to the lack of the binder coat or the coating. If the amount of the binder is more than 8 wt%, the excessive binder may cause blistering on the surface, have.

아래 표 5의 실시예 2 및 비교예 2의 아스팔트 혼합물 합성 입도는 국토해양부 2011.11 통합지침의 WC-2를 적용하였다.The composite particle size of the asphalt mixture of Example 2 and Comparative Example 2 shown in Table 5 was applied to WC-2 of 2011.11 integrated guide of Ministry of Land, Transport and Maritime Affairs.

표준체(mm)Standard (mm) 13.013.0 5.05.0 2.52.5 0.30.3 0.080.08 입도범위(%)Particle size range (%) 100100 90~10090-100 35~5035 to 50 15~2515-25 8~138-13 중앙입도(%)Central granularity (%) 100.0100.0 95.095.0 42.542.5 20.020.0 10.510.5

아래 표 6은 실시예 2와 비교예 2의 아스팔트 혼합물의 물성을 시험한 결과이다.Table 6 below shows the results of testing the physical properties of the asphalt mixture of Example 2 and Comparative Example 2.

아스팔트 혼합물 시험Asphalt mixture test -- 실시예 2Example 2 비교예 2Comparative Example 2 -- 시험항목Test Items 단위unit 시험결과Test result 시험결과Test result 시험방법Test Methods 마샬안정도Marshall stability NN 14,80014,800 10,20010,200 KS F 2337KS F 2337 간접인장강도Indirect tensile strength MPaMPa 1.221.22 1.031.03 KS F 2382KS F 2382 동적안정도Dynamic stability 회/mmTimes / mm 5,1405,140 3,5303,530 KS F 2374KS F 2374 휨강도 (25℃)Bending strength (25 ℃) MPaMPa 3.453.45 2.882.88 KS F 2395KS F 2395 휨강도 (-10℃)Bending strength (-10 ℃) MPaMPa 11.311.3 7.227.22 KS F 2395KS F 2395

상기 표 6을 살펴보면, 마샬안정도, 간접인장강도 및 동적안정도 시험결과, 본 발명의 아스팔트 혼합물의 개질아스팔트 성능 즉, 내유동성이 우수함을 알 수 있다. 또한, 상온 및 저온 휨강도 시험결과, 본 발명의 아스팔트 혼합물의 균열저항성이 우수함을 알 수 있다.As a result of the Marshall stability, the indirect tensile strength and the dynamic stability test, the modified asphalt performance of the asphalt mixture of the present invention, that is, the fluidity resistance is excellent. Also, as a result of the test of the room temperature and low temperature bending strength, the crack resistance of the asphalt mixture of the present invention is excellent.

아래 표 7에서는 본 발명 실시예 2의 아스팔트 혼합물의 온도에 따른 다짐율을 나타내었다.Table 7 below shows the compaction ratio of the asphalt mixture according to Example 2 according to the temperature.

아스팔트 혼합물 시험Asphalt mixture test -- 실시예 2Example 2 -- 시험항목Test Items 단위unit 시험결과Test result 시험방법Test Methods 160℃ 다짐율Compaction rate at 160 ℃ %% 100100 KS F 2337KS F 2337 130℃ 다짐율130 ° C compaction rate %% 99.799.7 KS F 2353KS F 2353 100℃ 다짐율Compaction rate at 100 ℃ %% 98.198.1 KS F 2364KS F 2364

아래 표 8에서는 본 발명 실시예 2의 아스팔트 혼합물의 온도에 따른 칸타브로 손실률을 나타내었다.Table 8 below shows the cantablo loss ratio according to the temperature of the asphalt mixture of Example 2 of the present invention.

혼합물 시험Mixture test -- 실시예 2Example 2 -- 시험항목Test Items 단위unit 시험결과Test result 시험방법Test Methods 칸타브로 손실률(20℃)Cantabro loss rate (20 캜) %% 0.90.9 KS F 2492KS F 2492 칸타브로 손실률(-20℃)Cantabro loss rate (-20 캜) %% 8.78.7 KS F 2492KS F 2492

아래 표 9에서는 본 발명 실시예 2의 아스팔트 혼합물에 대한 피로시험 결과를 나타내었다.Table 9 below shows the fatigue test results for the asphalt mixture of Example 2 of the present invention.

아스팔트 혼합물 시험Asphalt mixture test -- 실시예 2Example 2 비교예 2Comparative Example 2 -- 시험항목Test Items 단위unit 시험결과Test result 시험결과Test result 시험방법Test Methods 피로시험(0℃, 500㎛)Fatigue test (0 캜, 500 탆) time 20,00020,000 15,00015,000 KS F 2378KS F 2378 피로시험(10℃, 500㎛)Fatigue test (10 캜, 500 탆) time 45,00045,000 30,00030,000 KS F 2378KS F 2378 피로시험(20℃, 500㎛)Fatigue test (20 캜, 500 탆) time 90,00090,000 65,00065,000 KS F 2378KS F 2378

피로시험 결과, 본 발명의 아스팔트 혼합물은 여러 온도범위에서 비교예보다 우수함을 알 수 있다.As a result of the fatigue test, it can be seen that the asphalt mixture of the present invention is superior to the comparative example in various temperature ranges.

아스팔트 혼합물 시험Asphalt mixture test -- 실시예 2Example 2 비교예 2Comparative Example 2 -- 시험항목Test Items 단위unit 시험결과Test result 시험결과Test result 시험방법Test Methods 균열 5mm 진행까지 횟수Crack 5mm Number of times to progress time 3,0243,024 2,0162,016 KS F 2374KS F 2374

균열이 5mm까지 진행되었을 때의 하중륜 왕복회수를 측정한 결과, 표 10과 같이 본 발명의 실시예가 비교예보다 약 1.5배 우수함을 알 수 있다.As a result of measuring the number of reciprocations of the load wheel when the crack progressed to 5 mm, it can be seen that the embodiment of the present invention is about 1.5 times better than that of the comparative example as shown in Table 10.

포장노면 시험Packing road test -- 실시예 2Example 2 비교예 2Comparative Example 2 -- 시험항목Test Items 단위unit 시험결과Test result 시험결과Test result 시험방법Test Methods 미끄럼저항성(BPN)Slip resistance (BPN) -- 6262 5353 KS F 2375KS F 2375 소음측정Noise measurement dBdB 89.789.7 96.896.8 소음측정기 실측Measured noise meter

상기 표 11과 같이 미끄럼저항성 시험 결과, 본 발명의 실시예 2는 평지 40BPN, 완경사 45BPN, 급경사 50BPN 이상의 기준치에 비하여 미끄럼저항성이 우수함을 알 수 있다. 그리고, 소음측정 시험 결과, 일반 도로의 소음 측정치 96.8dB에 비하여 본 발명 실시예 2의 시험 결과는 7.1dB 감소하여 소음저감 기능이 우수함을 알 수 있다.As a result of the slip resistance test as shown in Table 11, it can be seen that Example 2 of the present invention is superior in slip resistance to a reference value of 40 BPN, mild 45 BPN, and steep slope of 50 BPN or more. As a result of the noise measurement test, the test result of the second embodiment of the present invention is reduced by 7.1 dB compared to the noise measurement value of 96.8 dB of the general road, indicating that the noise reduction function is excellent.

Claims (17)

멜트플로우 값이 15g/10분 미만인 비닐 방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성 부여 수지 0.1~100중량부, 방향족 성분 함유량이 20~60중량%이고, 40℃에서의 동점도가 70~900㎟/s인 프로세스 오일 5~100중량부를 함유하고, 상기 성분들의 합계 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는 아스팔트 개질재 5~15중량%;
나프텐계 프로세스 오일 50~80중량%;
식물성 오일 5~20중량%;
광물성 섬유 5~20중량%; 및
유기 가황촉진제 0.1~0.5중량%;로 구성되는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재.
0.1 to 100 parts by weight of a tackiness-imparting resin, 20 to 60% by weight of an aromatic component, and a kinematic viscosity at 40 DEG C of 70 to 70 parts by weight based on 100 parts by weight of a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / 5 to 15 parts by weight of an asphalt modifier further containing 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components;
50 to 80% by weight of naphthenic process oil;
5 to 20% by weight vegetable oil;
5 to 20% by weight of mineral fibers; And
0.1 to 0.5% by weight of an organic vulcanization accelerator; and a low-noise, high-durability asphalt additive.
청구항 1에 있어서,
상기 나프텐계 프로세스 오일은 40~50중량%의 나프텐환을 함유하는 것임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재.
The method according to claim 1,
Wherein the naphthenic process oil contains 40 to 50% by weight of a naphthene ring.
청구항 1에 있어서,
상기 식물성 오일은 리놀렌산을 6~10% 함유함을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재.
The method according to claim 1,
Wherein the vegetable oil contains 6-10% of linolenic acid.
청구항 1에 있어서,
상기 광물성 섬유는 양이온 처리가 되어 있는 것임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재.
The method according to claim 1,
Wherein the mineral fiber is subjected to cationic treatment, wherein the mineral fiber is cationically treated.
청구항 1에 있어서,
상기 유기 가황촉진제는 알데히드 암모니아계,알데히드 아민계, 구아니딘계, 티오우레아계, 티아졸계, 티우람계, 디티오 카보메이트계, 크산테이트계, 설펜아민드계 중 선택된 1종 이상임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재.
The method according to claim 1,
Wherein the organic vulcanization accelerator is at least one selected from the group consisting of aldehyde ammonia, aldehyde amine, guanidine, thiourea, thiazole, thiuram, dithiocarbomate, xanthate and sulfenamines. Crack suppression type Low noise and durable asphalt additive.
청구항 1 내지 청구항 5 중 선택된 어느 한 항의 아스팔트 첨가재 2~6중량%; 및
스트레이트 아스팔트, 스트레이트 아스팔트에 멜트플로우 값이 15g/10분 미만인 비닐 방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성 부여 수지 0.1~100중량부, 방향족 성분 함유량이 20~60중량%이고, 40℃에서의 동점도가 70~900㎟/s인 프로세스 오일 5~100중량부를 함유하고, 상기 성분들의 합계 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는 아스팔트 개질재를 첨가하는 개질아스팔트, SBS 개질아스팔트 중 선택된 1종의 아스팔트 94~98중량%;를 함유하는 반사균열 억제형 저소음 고내구성 아스팔트 바인더.
2 to 6% by weight of the asphalt admixture of any one of claims 1 to 5; And
0.1 to 100 parts by weight of a tackifier resin, 20 to 60 parts by weight of an aromatic component and 20 to 60% by weight of a tackifier resin, based on 100 parts by weight of a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / To 5 parts by weight of a process oil having a kinematic viscosity at 70 to 900 mm < 2 > / s and 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components, 94 to 98 wt.% Of one selected from among SBS modified asphalt; and a reflective anti-cracking type low noise and durable asphalt binder.
아스팔트 바인더 5~8중량%;
골재 77~92중량%; 및
채움재 3~15중량%;를 포함하는 아스팔트 혼합물에 있어서,
상기 아스팔트 바인더는
멜트플로우 값이 15g/10분 미만인 비닐 방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성 부여 수지 0.1~100중량부, 방향족 성분 함유량이 20~60중량%이고, 40℃에서의 동점도가 70~900㎟/s인 프로세스 오일 5~100중량부를 함유하고, 상기 성분들의 합계 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는 아스팔트 개질재 5~15중량%;
나프텐계 프로세스 오일 50~80중량%;
식물성 오일 5~20중량%;
광물성 섬유 5~20중량%; 및
유기 가황촉진제 0.1~0.5중량%;로 구성되는 반사균열 억제형 저소음 고내구성 아스팔트 첨가재 2~6중량%; 및
스트레이트 아스팔트, 스트레이트 아스팔트에 멜트플로우 값이 15g/10분 미만인 비닐 방향족 탄화수소·공역 디엔 블록공중합체 100중량부에 대하여 점착성 부여 수지 0.1~100중량부, 방향족 성분 함유량이 20~60중량%이고, 40℃에서의 동점도가 70~900㎟/s인 프로세스 오일 5~100중량부를 함유하고, 상기 성분들의 합계 100중량부에 대하여 0.1~40중량부의 고무를 더 포함하는 아스팔트 개질재를 첨가하는 개질아스팔트, SBS 개질아스팔트 중 선택된 1종의 아스팔트 94~98중량%;를 함유하는 반사균열 억제형 저소음 고내구성 아스팔트 바인더임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물.
5 to 8 wt% asphalt binder;
77 to 92% by weight of aggregate; And
And 3 to 15% by weight of a filler;
The asphalt binder
0.1 to 100 parts by weight of a tackiness-imparting resin, 20 to 60% by weight of an aromatic component, and a kinematic viscosity at 40 DEG C of 70 to 70 parts by weight based on 100 parts by weight of a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / 5 to 15 parts by weight of an asphalt modifier further containing 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components;
50 to 80% by weight of naphthenic process oil;
5 to 20% by weight vegetable oil;
5 to 20% by weight of mineral fibers; And
2 to 6% by weight of a low-noise, high-durability asphalt admixture with a reflection-cracking-inhibiting type consisting of 0.1 to 0.5% by weight of an organic vulcanization accelerator; And
0.1 to 100 parts by weight of a tackifier resin, 20 to 60 parts by weight of an aromatic component and 20 to 60% by weight of a tackifier resin, based on 100 parts by weight of a vinyl aromatic hydrocarbon-conjugated diene block copolymer having a melt flow rate of less than 15 g / To 5 parts by weight of a process oil having a kinematic viscosity at 70 to 900 mm < 2 > / s and 0.1 to 40 parts by weight of rubber per 100 parts by weight of the total amount of the components, And a refractory crack-inhibiting low-noise and high-durability asphalt binder containing 94 to 98 wt% of one kind of asphalt selected from SBS-modified asphalt.
청구항 7에 있어서,
상기 골재는 13㎜ 체를 100% 통과하고, 5㎜ 체를 90~100% 통과하고, 2.5㎜ 체를 35~50% 통과하고, 0.3㎜ 체를 15~25% 통과하고, 0.08㎜ 체를 8~13% 통과하는 것임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물.
The method of claim 7,
The aggregate passed 100% of a 13 mm sieve, passed 90 to 100% of a 5 mm sieve, passed 35 to 50% of a 2.5 mm sieve, passed 15 to 25% of a 0.3 mm sieve, To 13% of the asphalt mixture.
청구항 7에 있어서,
상기 골재는 둥글고 모가 난 형상의 포러스용 골재임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물.
The method of claim 7,
Wherein the aggregate is a porous aggregate having a rounded shape, and the aggregate is a round aggregate.
청구항 7에 있어서,
상기 아스팔트 혼합물 100중량부에 대하여 무기안료 1~10중량부를 가하는 것을 특징으로 하는 유색의 반사균열 억제형 저소음 고내구성 아스팔트 혼합물.
The method of claim 7,
Characterized in that 1 to 10 parts by weight of an inorganic pigment is added to 100 parts by weight of the asphalt mixture, and a colorless reflection crack prevention type low noise and durable asphalt mixture.
청구항 7에 있어서,
상기 골재 중 10~100중량%이 재생골재임을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물.
The method of claim 7,
Wherein 10 to 100% by weight of the aggregate is recycled aggregate, and a low-noise, high-durability asphalt mixture.
청구항 7에 있어서,
상기 골재는 골재 최대치수가 5㎜인 것을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물.
The method of claim 7,
Wherein the aggregate has a maximum aggregate count of 5 mm.
청구항 12에 있어서,
상기 골재는 굵은골재를 추가하여 골재 최대치수가 13~8㎜인 것을 특징으로 하는 반사균열 억제형 저소음 고내구성 아스팔트 혼합물.
The method of claim 12,
Wherein the aggregate has a maximum aggregate count of 13 to 8 mm by adding coarse aggregate, and the low-noise and high-durability asphalt mixture of the reflection crack suppression type.
청구항 7 내지 청구항 13 중 선택된 어느 한 항의 아스팔트 혼합물을 15~25㎜로 박층 덧씌우기 포장하는 반사균열 억제형 저소음 고내구성 도로포장 보수방법.Claims [1] A method of repairing and repairing a low-noise, high-durability anti-reflective cracking type asphalt mixture of any one of claims 7 to 13 packed in a thin layer of 15 to 25 mm. 삭제delete 삭제delete 삭제delete
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