KR101575299B1 - Flame-retardant treatment method using eco-friendly fire retardant composition for wood containing construction material and fire retardant coating wood containing construction material - Google Patents
Flame-retardant treatment method using eco-friendly fire retardant composition for wood containing construction material and fire retardant coating wood containing construction material Download PDFInfo
- Publication number
- KR101575299B1 KR101575299B1 KR1020150068981A KR20150068981A KR101575299B1 KR 101575299 B1 KR101575299 B1 KR 101575299B1 KR 1020150068981 A KR1020150068981 A KR 1020150068981A KR 20150068981 A KR20150068981 A KR 20150068981A KR 101575299 B1 KR101575299 B1 KR 101575299B1
- Authority
- KR
- South Korea
- Prior art keywords
- flame retardant
- composition
- flame
- wood
- silane
- Prior art date
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D15/00—Woodstains
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/02—Polysilicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Forests & Forestry (AREA)
- Paints Or Removers (AREA)
Abstract
Description
The present invention relates to an eco-friendly flame retarding treatment method for wood-containing building materials using an environmentally friendly flame-retardant composition for wood-containing building materials, and a flame-retarded coated timber-containing building material containing flame retardant coating film formed using the method.
Recently, the rapid spread of chemical building materials has resulted in a great deal of toxic gases and smoke. When such a building material is lit, the wood, which is a material, acts as a flare, and a polymer sheet such as a polyvinyl chloride sheet is burned to release toxic gases and smoke. To solve these problems, a flame retardant excellent in flame retardancy and a flame retardant treatment method using the same are required.
Flame retardants used in wood or MDF (medium density fiberboard) generally contain alcoholic solvents, acids and the like. However, due to the above-mentioned components contained as flame retardants, the wood or MDF itself undergoes self-deformation, flame retardancy and flame retardant durability are insufficient, and there is much room for improvement.
Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made to solve the above problems occurring in the prior art, and it is an object of the present invention to provide an environmentally friendly flame-retardant composition for wood-containing building materials having improved flame retardancy.
Another object of the present invention is to provide a method for eco-friendly flame retarding treatment for wood-containing building materials using the environmentally friendly flame retardant composition.
Another object of the present invention is to provide an excellent flame retardant coated wood-containing building material having improved flame retardancy by forming a flame retardant coating film according to the environmentally flame retardant composition and the environmentally friendly flame retardant treatment method.
According to the present invention,
Water glass, distilled water, silane and colloidal silica, and the water glass content is 15 to 45% by weight based on the total weight of the composition, by an environmentally friendly flame retardant coating composition for wood-containing building materials.
According to another aspect of the present invention,
Stirring water glass and distilled water;
Adding colloidal silica to the mixture;
Adding silane to the mixture to obtain the environmentally flame retardant coating composition described above;
Applying the environmentally friendly flame retardant coating composition to a wooden building material; And
And drying the coated resultant.
According to another aspect of the present invention,
And a flame retardant coating film formed by coating and drying the above environmentally flame retardant composition on the surface of wood-containing building material,
The flame retardant coating film comprises a structure comprising: i) a polycondensation reaction product of waterglass present on the surface of the building material and ii) a hydrolytic condensation reaction product of silane present between the surface of the building material and the polycondensation reaction product of water glass Based flame retardant coated timber construction material.
The flame-retardant composition according to one embodiment of the present invention is an environmentally friendly flame retardant composition which is used in wood or wood plywood such as MDF which is required to have flame retardancy.
1 shows the flame retardancy test results for the flame-retarded coated MDF and uncoated MDF prepared according to Example 1. Fig.
Fig. 2 is a photograph showing the state of the flame retardant coating composition prepared according to Example 1. Fig.
Fig. 3 shows the transmittance results of the flame retardant coating composition prepared according to Example 1. Fig.
With reference to the accompanying drawings, an eco-friendly flame retardant coating composition for wood-containing building materials, an eco-friendly flame retarding treatment method using the same, and a construction material containing a flame retarded coated wood formed using the environmentally friendly flame retardant coating composition will be described in detail below.
Water-white, distilled water, silane, and colloidal silica, wherein the water glass content is 15 to 45% by weight, based on the total weight of the composition, of an environmentally friendly flame retardant coating composition for wood-containing building materials.
Water glass plays a role of flame retardant. Sodium silicate (Na 2 O · SiO 2 ) is the most commonly used raw material among these water glasses. It exists in a silicate state. When the acid is reacted, sodium silicate has a strong alkaline property and causes a violent reaction. However, when a large amount of acid is reacted, sodium oxide and silicon dioxide are separated from each other and lose stickiness, flame retardancy and flame retardancy. This is accompanied by a transition between low- and high-temperature-type or homogeneous-polygonal phase, and most of the Na 2 O coexisting in the amorphous phase is oxide, and SiO 2 , Sb 2 O 3 , P 2 O 5 And the like are conveniently arranged in a three-dimensional arrangement of the basic oxygen which forms the glass phase conveniently and forms the structure.
Water glass has a tetrahedral structure common to many other forms of silica and crystalline silica. It has a polymeric form by sharing oxygen in the form of silicate tetrahedral mono-molecules or Si-O-Si bridges. However, the overall structure of the water-soluble sodium silicate is an irregular arrangement of the shared cations Na 2 O and SiO 4 molecules. Since it has such a structure, water glass shows a characteristic of expanding during the expansion process, and foaming occurs.
In the process of producing a flame retardant and curable composition using water glass in general, the neutralization reaction exhibits an exothermic reaction to form a salt and expands as water glass is foamed. However, in the present invention, since the flame-retardant composition does not contain inorganic acid, the above-mentioned exothermic reaction does not occur, and the flame retardant composition can be produced at room temperature and atmospheric pressure, and therefore, it is easy to produce.
When water glass is used to form a flame retardant coating film on the surface of a conventional timber-containing building material, it is common to use acid, alcohol or the like for neutralizing it. However, in the case of using an acid, heat is generated due to the neutralization reaction of water glass and acid as described above. In the case of containing alcohol, since the flame retardant coating film is formed, the wood- There is a lot of room for improvement in terms of environment by using organic materials such as alcohol without using it.
On the contrary, the flame retardant composition of the present invention contains a water-soluble, nature-friendly material using water as a solvent.
The content of water glass is, for example, 25 to 35% by weight.
The term " wood-containing construction material " as used in the present invention refers to a building material containing wood, for example, wood itself, or medium density fiberboard (MDF). Medium density fiber boards are, for example, MDF with laminated wood, MDF with laminated wood, MDF with plywood, or MDF with PVC film.
The silane contained in the composition is a hydrophilic substance and acts as an adhesive which is an intermediate medium connecting the wood-containing construction material, which is an organic material, and the water glass, which is an inorganic material. The content of silane is from 1 to 10% by weight, for example from 3 to 8% by weight, based on the total weight of the composition. When the content of silane is in the above range, when the flame retardant composition is applied to a wood-containing construction material such as MDF or wood, the adhesive strength is excellent and the flame retardancy can be maintained even after a lapse of time.
The silane may be selected from the group consisting of glycidoxypropylsilane, vinyltrimethoxysilane, vinyltriethoxysilane, methyltrimethoxysilane, methyltriethoxysilane, trichloromethylsilane, aminopropyltrimethoxysilane, aminopropyltriethoxy Silane, tetramethoxyorthosilane, tetraethoxyorthosilane, and methacrylpropyltrimethoxysilane. The term " silane "
The colloidal silica can serve as a flame retardant aid, and the content of colloidal silica is 0.5 to 5% by weight, for example, 1 to 3% by weight.
The content of the distilled water is 50 to 75% by weight, for example, 50 to 70% by weight, based on the total weight of the composition. The flame retardant composition of the present invention contains distilled water and when it is applied to a building material such as wood, deformation of the building material hardly occurs.
When the flame retardant composition is coated on the surface of the wood-containing construction material, the composition may be contained in the pores of the wood-containing construction material. When the composition is contained in the pores of the wood-containing construction material, it is possible to prevent fire secondarily along with the flame retardant coating film formed on the surface. Since the composition contained in the pores of the wood-containing building material is water-based, it hardly causes the change of the wood, so it is preferable to maintain the color of the wood as it is and to make it look good.
Hereinafter, a process for producing a wood-containing wood-based construction material using the environmentally flame-retardant composition will be described.
First, water glass and distilled water are stirred, and then colloidal silica is added thereto.
Silane is added to the mixture to obtain an environmentally flame retardant composition for wood-containing building material.
As described above, the environmentally flame-retardant composition of the present invention can be easily produced by simple physical stirring at room temperature and atmospheric pressure. Therefore, the manufacturing process is simplified and the manufacturing cost is reduced as compared with the conventional flame retardant manufacturing process. As the time passes, the flame retardancy is maintained as it is and the flame retardant durability is greatly improved.
The green flame retardant coating composition is applied to the wood-containing construction material,
Dry the resultant.
In the production of the flame retardant composition, the order of addition and mixing of the components is very important as described above. As described above, the silane is finally added to the composition and mixed to obtain an environmentally flame retardant composition having desired flame retardancy and flame retardancy.
If the silane is first mixed with the other components during the preparation of the composition or after the silane is first applied to the surface of the building material and then the waterglass and the composition containing the colloidal silica are subjected to the hydrolysis and polycondensation The reaction product is formed first. However, even though the reaction product of the silane is mixed with other components, it is difficult to obtain a flame retardant coated wood-containing construction material having a desired structure, and thus the improvement of the flame retardancy is insignificant.
The present invention relates to a flame retardant coating film formed by applying and drying the environmentally flame retardant composition described above on the surface of wood-containing building material according to the above-mentioned method, wherein the flame retardant coating film comprises: i) polycondensation reaction of water glass present on the surface of the building material ) Product; And ii) a hydrolytic condensation reaction product of silane present between the surface of the building material and the polycondensation reaction product of water glass. Herein, the hydrolysis-polycondensation reaction product of silane means a product obtained by hydrolysis of silane through polycondensation reaction.
The mixing weight ratio of the hydrolyzed polycondensation reaction product of the silane to the polycondensation reaction product of the water glass in the finally obtained flame retardant coating film is in the range of 1: 1.5 to 1:40. When these ranges are satisfied, the flame retardancy is excellent.
The colloidal silica may coexist in at least one selected from the polycondensation reaction product of the water glass and / or the hydrolytic condensation reaction product of the silane.
As described above, when the hydrolyzed polycondensation reaction product of silane exists between the polycondensation reaction product of the wood-containing building material and water glass, it acts as an adhesive and a linker, and thereby, the polycondensation reaction product of the organic building material and the inorganic water- It keeps the adhesion force excellent. In order to have the flame retardant coating film structure as described above, the addition order of each constituent component is very important in the production of the flame retardant composition. If the condensation reaction product of waterglass is present on the surface of the building material and the hydrolyzed polycondensation reaction product of silane is present on the surface of the building material, the effect of improving the flame retardancy is not only insignificant but also the adhesion of the flame retardant coating film to the surface of the building material is insufficient, Durability may be deteriorated.
It is preferable that the silane has a structure such that the hydrolysis-polycondensation reaction product of silane can perform well as an adhesive. As the silane suitable for this purpose, glycidoxypropylsilane is most preferable.
If the silane is first mixed with other components in the preparation of the flame retardant composition, the hydrolytic condensation reaction product of the silane becomes difficult to perform as an adhesive present between the polycondensation product of the building material and the water glass. Therefore, the flame retardancy of the flame-retardant coated building material may deteriorate with time.
The green flame retardant composition is applied to the top of the building material and then dried. The drying is carried out at room temperature or at a temperature of 300 ° C or lower, for example, at 20 to 150 ° C.
Methods of applying the environmentally flame retardant composition to a building material include, but are not limited to, spray coating, dip coating, spin coating, bar coating, slot coating, knife coating, curtain coating, or flow coating.
When drying is carried out at room temperature, drying is carried out for 1 to 3 days. If the drying is carried out in the temperature range of 80 to 100 ° C, the drying time is reduced.
When the drying is carried out in the above-mentioned temperature range, it is possible to manufacture a flame retarded coating construction material excellent in flame retardancy.
Example 1: Flame retardant composition and flame retardant coating MDF Manufacturing
30 g of water glass was mixed with 62 g of secondary distilled water to dilute the water glass. 2 g of colloidal silica was mixed with the diluted aqueous water solution.
6 g of glycidoxypropylsilane was added to and mixed with the mixture to obtain a flame retardant composition. In the flame retardant composition, the content of water glass was 30% by weight, the content of glycidoxypropylsilane was 6% by weight, the content of secondary distilled water was 62% by weight, and the content of colloidal silica was about 2% by weight.
The flame retardant composition was spray coated on the MDF surface and dried at 60 ° C for 1 hour to prepare a flame retarded coated MDF sample A.
Example 2: Flame retardant composition and flame retardant coating MDF Manufacturing
The content of water glass in the flame retardant composition was 15 wt%, the content of glycidoxypropylsilane was 8 wt%, the content of secondary distilled water was 75 wt%, and the content of colloidal silica was changed to about 2 wt% , A flame-retardant composition and a flame-retardant coated MDF B were prepared in the same manner as in Example 1.
Example 3: Flame retardant composition and flame retardant coating MDF Manufacturing
The content of water glass in the flame retardant composition is 45% by weight, the content of glycidoxypropylsilane is 4% by weight, the content of secondary distilled water is 50% by weight, and the content of colloidal silica is changed to about 1% by weight , A flame retardant composition and a flame-retardant coated MDF C were prepared in the same manner as in Example 1.
Comparative Example 1: Flame retardant composition and flame retardant coating MDF Manufacturing
30 g of water glass was mixed with 4 g of ethanol to obtain a flame retardant composition. The composition was spray coated on the MDF surface and dried, followed by spray coating 2 g of acetic acid on the MDF surface and drying it to obtain a flame retarded coated MDF sample D.
Evaluation example 1: Flammability test
The flame retardant coated MDF samples A-C and D were tested for flammability according to KS K ISO 14184-1: 2009.
The specimens were cut to a width of 29 cm and a length of 19 cm, and the flame retardancy was evaluated by a direct heat treatment with a torch for 1 minute.
The flame retardancy evaluation results of the flame retarded coated MDF A and the uncoated MDF prepared according to Example 1 are as shown in FIG. 1, and the time of the residual flame obtained from this is shown in Table 1 below. The time of the flame decay refers to the time from when the flame is removed from the burner to when the flame is raised and the combustion state is stopped.
As shown in Table 1 and FIG. 1, the flame retardant-coated MDF using the flame retardant compositions of Examples 1 to 3 had a flame retardancy of very excellent as compared with the flame retardant composition of Comparative Example 1, Giving. The flame retardant composition of Example 1 is an aqueous base composition containing water, which contains a water-containing composition in the pores present in the wood, so that the primary coating film has flame retardancy in the flame retardancy test and contains a composition in the wood pore, There was a blocking effect.
On the contrary, the uncoated MDF had a very poor residual time of about 60 seconds.
Evaluation example 2: the state of the flame retardant composition, color, transparency, viscosity and Refractive index Test
The state, color, transparency, viscosity and refractive index of the composition of the flame retardant composition prepared according to Example 1 were investigated according to the following methods. The results are shown in FIG. 2 and Table 2 below.
(1) Status and color of flame retardant composition
And examined visually.
(2) Transparency of flame retardant composition
It was measured according to ISO 8980-3.
(3) Viscosity of flame retardant composition
And measured using a Brookfield viscometer.
(4) Refractive index of the flame retardant composition
Abbe refractometer.
As shown in FIG. 2 and Table 2, the flame retardant composition prepared in Example 1 was very transparent and colorless. Also, the flame retardant composition has a viscosity which is easy to apply to a building material, and the refractive index is also in an appropriate range.
Evaluation example 3: transmittance
The transmittance of the flame retardant composition prepared according to Example 1 was examined and the results are shown in Fig.
As a result, it was found that the transmittance characteristics of the composition were excellent.
Evaluation example 4: Volatile organic compounds ( volatile organic compound : VOC ) Detection test
The flame retardant composition prepared according to Example 1 was subjected to VOC detection test according to the KSM ISO 11890-2: 2012 (Gas chromatography / flame ionization detector: GC / FID) method.
As a result of the test, the flame retardant composition prepared according to Example 1 was found to be almost no VOCRK of 0.01 g / L or less. As a result, it was confirmed that the flame retardant composition prepared according to Example 1 was a dental environmental material.
Evaluation example 5: Wood deformation test
The degree of deformation of the MDF was examined after 30 days passed from the flame retardant coating sample AC prepared according to Examples 1 to 3 and the flame retardant coating sample D prepared according to Comparative Example 1. Here, the degree of deformation of the MDF means that some of the MDF is twisted, contracted, or changed in dimension.
As a result, wood deformation of flame retardant coating D was observed while flame retardant coating sample A-C had little deformation of wood.
Evaluation example 6: Flame retardant durability test
After 7 days from the flame retardant coating sample AC prepared according to Examples 1 to 3 and the flame retardant coating sample D prepared according to Comparative Example 1, the flame retardancy test of Evaluation Example 1 was carried out after the lapse of 30 days , A to D to investigate the time of the decontamination.
As a result, the flame retardant coating sample D had a poor flame retardant durability due to an increase in the time of residual flame due to ethanol and the like. However, the sample A-C of the flame retardant coating was excellent in flame-retardant durability due to a small increase in the residual time.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the exemplary embodiments or constructions. It will be apparent to those skilled in the art that various modifications and variations are possible in light of the above teachings will be. Accordingly, the scope of protection of the present invention should be determined by the appended claims.
Claims (8)
Adding colloidal silica to the first mixture to obtain a second mixture;
Adding silane to the second mixture to obtain an environmentally flame retardant coating composition;
Applying the environmentally friendly flame retardant coating composition to a wooden building material; And
And drying the coated product,
The green flame retardant composition comprises water glass, distilled water, silane, and colloidal silica. The water glass content is 25 to 35 wt% based on the total weight of the composition, the silane content is 3 to 8 wt%, the colloidal silica Wherein the content is 1 to 3% by weight.
The wood-containing construction material is wood or a medium density fiberboard (MDF).
The flame retardant coating film comprises a structure comprising: i) a polycondensation reaction product of waterglass present on the surface of the building material and ii) a hydrolytic condensation reaction product of silane present between the surface of the building material and the polycondensation reaction product of water glass Have,
The environmentally flame retardant composition is composed of water glass, distilled water, silane and colloidal silica,
Wherein the waterglass content is 25 to 35 wt.%, The silane content is 3 to 8 wt.%, And the colloidal silica content is 1 to 3 wt.% Based on the total weight of the composition.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020150068981A KR101575299B1 (en) | 2015-05-18 | 2015-05-18 | Flame-retardant treatment method using eco-friendly fire retardant composition for wood containing construction material and fire retardant coating wood containing construction material |
| PCT/KR2016/005268 WO2016186450A1 (en) | 2015-05-18 | 2016-05-18 | Eco-friendly flame retardant coating composition for wood-containing construction material, eco-friendly flame-retardant treatment method using same, and flame retardant coated wood-containing construction material formed using eco-friendly flame retardant coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020150068981A KR101575299B1 (en) | 2015-05-18 | 2015-05-18 | Flame-retardant treatment method using eco-friendly fire retardant composition for wood containing construction material and fire retardant coating wood containing construction material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR101575299B1 true KR101575299B1 (en) | 2015-12-08 |
Family
ID=54872995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020150068981A KR101575299B1 (en) | 2015-05-18 | 2015-05-18 | Flame-retardant treatment method using eco-friendly fire retardant composition for wood containing construction material and fire retardant coating wood containing construction material |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR101575299B1 (en) |
| WO (1) | WO2016186450A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200061259A (en) | 2018-11-23 | 2020-06-02 | 금오공과대학교 산학협력단 | Automatic system for fire resistant coating of traditional construction material and Manufacturing method thereof |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10290004B1 (en) | 2017-12-02 | 2019-05-14 | M-Fire Suppression, Inc. | Supply chain management system for supplying clean fire inhibiting chemical (CFIC) totes to a network of wood-treating lumber and prefabrication panel factories and wood-framed building construction job sites |
| US11395931B2 (en) | 2017-12-02 | 2022-07-26 | Mighty Fire Breaker Llc | Method of and system network for managing the application of fire and smoke inhibiting compositions on ground surfaces before the incidence of wild-fires, and also thereafter, upon smoldering ambers and ashes to reduce smoke and suppress fire re-ignition |
| US10653904B2 (en) | 2017-12-02 | 2020-05-19 | M-Fire Holdings, Llc | Methods of suppressing wild fires raging across regions of land in the direction of prevailing winds by forming anti-fire (AF) chemical fire-breaking systems using environmentally clean anti-fire (AF) liquid spray applied using GPS-tracking techniques |
| US10814150B2 (en) | 2017-12-02 | 2020-10-27 | M-Fire Holdings Llc | Methods of and system networks for wireless management of GPS-tracked spraying systems deployed to spray property and ground surfaces with environmentally-clean wildfire inhibitor to protect and defend against wildfires |
| US10430757B2 (en) | 2017-12-02 | 2019-10-01 | N-Fire Suppression, Inc. | Mass timber building factory system for producing prefabricated class-A fire-protected mass timber building components for use in constructing prefabricated class-A fire-protected mass timber buildings |
| US10332222B1 (en) | 2017-12-02 | 2019-06-25 | M-Fire Supression, Inc. | Just-in-time factory methods, system and network for prefabricating class-A fire-protected wood-framed buildings and components used to construct the same |
| US10260232B1 (en) | 2017-12-02 | 2019-04-16 | M-Fire Supression, Inc. | Methods of designing and constructing Class-A fire-protected multi-story wood-framed buildings |
| US11836807B2 (en) | 2017-12-02 | 2023-12-05 | Mighty Fire Breaker Llc | System, network and methods for estimating and recording quantities of carbon securely stored in class-A fire-protected wood-framed and mass-timber buildings on construction job-sites, and class-A fire-protected wood-framed and mass timber components in factory environments |
| US10311444B1 (en) | 2017-12-02 | 2019-06-04 | M-Fire Suppression, Inc. | Method of providing class-A fire-protection to wood-framed buildings using on-site spraying of clean fire inhibiting chemical liquid on exposed interior wood surfaces of the wood-framed buildings, and mobile computing systems for uploading fire-protection certifications and status information to a central database and remote access thereof by firefighters on job site locations during fire outbreaks on construction sites |
| US10695597B2 (en) | 2017-12-02 | 2020-06-30 | M-Fire Holdings Llc | Method of and apparatus for applying fire and smoke inhibiting compositions on ground surfaces before the incidence of wild-fires, and also thereafter, upon smoldering ambers and ashes to reduce smoke and suppress fire re-ignition |
| US11865390B2 (en) | 2017-12-03 | 2024-01-09 | Mighty Fire Breaker Llc | Environmentally-clean water-based fire inhibiting biochemical compositions, and methods of and apparatus for applying the same to protect property against wildfire |
| US11865394B2 (en) | 2017-12-03 | 2024-01-09 | Mighty Fire Breaker Llc | Environmentally-clean biodegradable water-based concentrates for producing fire inhibiting and fire extinguishing liquids for fighting class A and class B fires |
| US11826592B2 (en) | 2018-01-09 | 2023-11-28 | Mighty Fire Breaker Llc | Process of forming strategic chemical-type wildfire breaks on ground surfaces to proactively prevent fire ignition and flame spread, and reduce the production of smoke in the presence of a wild fire |
| US11911643B2 (en) | 2021-02-04 | 2024-02-27 | Mighty Fire Breaker Llc | Environmentally-clean fire inhibiting and extinguishing compositions and products for sorbing flammable liquids while inhibiting ignition and extinguishing fire |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101131802B1 (en) * | 2010-10-15 | 2012-03-30 | 주식회사 젠트로 | Functional paint composition, manufacturing method for the same and coating method using the same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100501797B1 (en) * | 2003-01-15 | 2005-07-20 | 정은정 | Fireproofing treatment method using water glass |
| KR100873652B1 (en) * | 2008-05-01 | 2008-12-15 | 주식회사 에이스산업 | Coating material for retarding flame, manufacturing method of the same, and flame-retarding method of expanded polystyrene particle using the same |
| KR101153782B1 (en) * | 2009-10-28 | 2012-06-13 | 주식회사 젠트로 | Functional paint composition and manufacturing method for the same |
| KR101153784B1 (en) * | 2010-07-27 | 2012-06-13 | 주식회사 젠트로 | Functional paint composition and manufacturing method for the same |
-
2015
- 2015-05-18 KR KR1020150068981A patent/KR101575299B1/en not_active IP Right Cessation
-
2016
- 2016-05-18 WO PCT/KR2016/005268 patent/WO2016186450A1/en active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101131802B1 (en) * | 2010-10-15 | 2012-03-30 | 주식회사 젠트로 | Functional paint composition, manufacturing method for the same and coating method using the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200061259A (en) | 2018-11-23 | 2020-06-02 | 금오공과대학교 산학협력단 | Automatic system for fire resistant coating of traditional construction material and Manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2016186450A1 (en) | 2016-11-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101575299B1 (en) | Flame-retardant treatment method using eco-friendly fire retardant composition for wood containing construction material and fire retardant coating wood containing construction material | |
| US7482395B2 (en) | Intumescent fire retardant latex paint with mold inhibitor | |
| US6982049B1 (en) | Fire retardant with mold inhibitor | |
| CA2719511C (en) | Fire resistant timber coating compositions and methods of manufacture | |
| US20120040093A1 (en) | Alginate-based building materials | |
| CN102975251B (en) | Flame retardant for wood as well as preparation method and applications of flame retardant for wood | |
| KR102113031B1 (en) | Method for manufacturing inorganic thermal insulation paint compositon with anti-condensation furction comprising aerogel, and inorganic thermal insulation paint compositon with anti-condensation furction comprising aerogel manufactured by the same | |
| KR20190030148A (en) | Panels Formed with Nonflammable Coated Layer for Buildings and Method of Forming Nonflammable Coated Layer on Panels | |
| EP2313178B1 (en) | Aldehyde reducing compositions | |
| WO2012029787A1 (en) | Formaldehyde scavenger | |
| KR101703886B1 (en) | An inorganic nonflammable painting composition for anti sweating having functions deodorizing toxic substances and dehydration | |
| CN108441003A (en) | A kind of facing intumescent silicon sol water woodware fireproof paint | |
| KR20190012430A (en) | Flame retardant composition for wood and method for flame retarding treatment of wood | |
| CN101623886B (en) | Loss-resistance and high-efficiency flame-retarding wood and processing method thereof | |
| JPH07186333A (en) | Fire retardant decorative material and fire retardant paint composition | |
| US6894099B2 (en) | Stabilized borax based fire retardant system | |
| EP0570233A1 (en) | Fire retardant and intumescent compositions for cellulosic material | |
| CN102975253B (en) | Wood fire retardant, preparation method and applications thereof | |
| JP2006001267A (en) | Nonflammable mdf and its manufacturing method | |
| KR100644770B1 (en) | Transparent fireproofing coating composition and method of fireproofing an object using the same | |
| JP2014144540A (en) | Method of imparting fire resistance to lumber | |
| KR20230040649A (en) | Method for making enviromental heat insulating resin | |
| JP6740101B2 (en) | Flame-retardant composition, flame-retardant substrate containing the same, and method for producing flame-retardant substrate | |
| RU2174527C1 (en) | Fireproof swelling paint | |
| Yildirim | Design of adhesive-free bio-based suspended ceiling tiles using nanocellulose |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| LAPS | Lapse due to unpaid annual fee |