KR101570995B1 - Gynura procumbens fortified with vanadium - Google Patents

Abstract

More particularly, the present invention relates to a method for producing a vanadium-rich seedling, comprising the steps of: (a) adding a vanadium- Which is suitable for application. According to the present invention, vanadium which is an essential minerals component is firstly absorbed in a form which is easily absorbed by the human body, and therefore, it is useful because it can have nutritional synergy effect of vanadium and myrrh without fear of mineral toxicity.

Description

Vanadium strengthening {Gynura procumbens fortified with vanadium}

The present invention relates to a method for enhancing vanadium growth, and more particularly, to a method for enhancing vanadium content by using cultivated vinarium-enriched cultivated water during cultivation in early May, The proper vanadium strengthening is related to the beginning of the month.

Recently, diabetes mellitus such as obesity, diabetes, hypertension, hyperlipidemia and arteriosclerosis has been rapidly increasing due to changes in dietary habits, and there is a growing interest in medicines that are effective in the treatment or symptom relief. Among them, gynura procumbens has been reported to be effective for diabetes and hypertension.

It is a perennial plant belonging to the genus Bacillus (Bacchus japonica). It has a single stem. It grows in a leaf-like shape based on the stem. Its leaf color is green, its shape is ovate, The upper part of the leaf is pointed and the lower part is elliptical. Leaf edges are flat or wavy. Both sides of leaf are soft and sharp.

The beginning of the month can be grown by cutting, it can be eaten by picking the leaves, the leaves can be eaten with food, or the leaves can be made by car manufacturing.

The beginning of the month is called the first day of the month in China, the first day of life in Japan, and in Korea, it is also called the diabetic period or the third day of the year.

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Vanadium is contained in fish, carrots, and uncooked grains, and may be consumed through them, and vanadium-containing bottled water may be produced and sold.

On the other hand, the mineral strengthening of certain plant components is highly selective, and in plants used as herbs, nutrient and pharmacological effects can be shown when the minerals of a specific component are fortified. Therefore, many studies have been made to transfer or fortify the nutrient and pharmacologically necessary components to the plants so as to be readily absorbed by the human body, but studies on vanadium have been limited.

It is an object of the present invention to provide an effective date of the present invention, in which vanadium, which is an essential minerals component, is transferred to the beginning of the beginning of the year in order to facilitate absorption into the human body by using cultured water containing vanadium.

It is another object of the present invention to provide a food using the menstrual fluid of which the vanadium component is enhanced.

In order to achieve the above object,

Provides an early morning sun with enhanced vanadium content.

Preferably, the content of the vanadium component in the beginning of the period is at least 9 ppb, preferably 20-5000 ppb, more preferably 30-1000 ppb.

In addition, the present invention provides a food using the menstrual fluid of which the vanadium component is enhanced.

In order to facilitate the absorption of vanadium, which is an essential minerals component, in the early May, the vanadium-enriched van der Waals strengthened with the vanadium component according to the present invention makes it possible to produce a nutritionally superior food using vanadium-enhanced sunflower seeds. In addition, vanadium which is essential minerals in the beginning of menstrual cycle is firstly absorbed in the form that is easy to be absorbed by the human body, so that nutritional synergy effect of vanadium and menstrual flow can be obtained without worrying about mineral toxicity.

BRIEF DESCRIPTION OF DRAWINGS FIG. 1 is a view showing a configuration of a vanadium extraction system for selectively extracting vanadium using a cluster of the present invention. FIG.
2 is a view showing a configuration of a first vanadium elution tank in the vanadium extraction system of the present invention.
3 is a view showing a configuration of a second vanadium elution tank in the vanadium extraction system of the present invention.

The inventors of the present invention have found that a plant which can not be reported at all yet, that is, a plant in which the vanadium is selectively absorbed by the mineral component vanadium in the cultivated water and the vanadium is strengthened, And thus the present invention has been completed.

The present invention provides an early-grown early-morning vanadium component which is an essential minerals. It is generally known that the beginning of the first decade of the Korean peninsula contains no vanadium, or contains trace amounts of, and even less than 5 ppb, even in the first declination of the volcanic area. In the case of the early early morning period when the vanadium component according to the present invention is strengthened, the vanadium component is at least 9 ppb, preferably 20-5000 ppb, more preferably 30-1000 ppb. In the present invention, the first and second orders are roots, stems, leaves and flowers.

As described above, when the vanadium component is strengthened, the essential minerals such as vanadium are strengthened by the various pharmacological effects possessed by the menstrual flow, so that it can be directly ingested or supplemented with foods using the same. have.

For example, when used for food, vanadium-enriched mulberry leaves are cut into appropriate sizes to be included in the food, or vanadium-enriched mulberry leaves are dried and powdered, or the banana- Or an alcoholic extract may be added to the food.

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In the present invention, methods for manufacturing known foods, medicines, or cosmetics can be used, except that when the vanadium-enriched menstrual powder is used for foods, medicines, and cosmetics, The content of the enhancer may be adjusted arbitrarily. For example, 0.01 to 20% by weight of water or alcohol extract is suitable for the beginning of menstrual cycle in which vanadium is enhanced in cosmetics.

Particularly, according to the present invention, vanadium is strengthened by using the first absorption of vanadium, which is a mineral component, in a form that is easily absorbed by the human body, so that the nutritional and pharmacological effects It is useful because it can have synergy effect.

Further, the present invention provides a method for cultivating an early-early-morning flowering method using cultivated water, wherein the cultivated water contains a vanadium component.

In the cultivation method of the present invention, any cultivation method other than cultivated water may be applied to all cultivation methods of ordinary sun lightning, and of course, it is also possible to apply the cultivation method including the vanadium component to the soil, Cultivation water containing vanadium is used, cultivation soil to which cultivated cultivar is cultivated is previously cultivated, and cultivation soil contains vanadium in advance.

The production of the cultivated water containing the vanadium component can be carried out by extracting the vanadium component from the mineral containing the vanadium component and adding the vanadium component to the cultivation water. An example of a mineral containing vanadium is scoria.

Preferably, the cultivated water of the present invention comprises: an electrolytic cell for electrolyzing water heated to a predetermined temperature to produce ionized water separated into acidic water and hydrogenated water; A first tank connected to the electrolytic cell and heating the electrolytic ionized water at a predetermined temperature and time to accelerate the reaction between the mushroom and acidic or hydrogen ions to extract the mushroom concentrate from the mushroom; The pit and magnesium are contained in the partitioned space, and are connected to the first tank. The pit and the magnesium from the first tank are reacted with each other to release acidic or hydrogen ions. The acidic or hydrogen ions released and the minerals contained in the pit A second tank in which a selective reaction is induced and a large amount of mineral concentrate is eluted; And a mineral extraction system including a reservoir for introducing the mineral concentrate eluted from the second tank, storing the mineral concentrate by concentration, and supplying the mineral concentrate to the outside.

FIG. 1 is a view showing a configuration of a vanadium extraction system for selectively extracting vanadium using a seedling, and FIG. 2 is a view showing a configuration of a first vanadium elution tank in the vanadium extraction system. And FIG. 3 is a view showing a configuration of a second vanadium elution tank in the vanadium extraction system.

The vanadium extraction system includes a first heating tank 100 having a first instantaneous heating module 102, an electrolytic bath 200, a water heating tank 220, a first vanadium elution tank 300, Tank 400, a low-concentration storage tank 500, a middle-concentration storage tank 600, a high-concentration storage tank 700, a second instantaneous heating module 710, and a control unit (not shown). Here, the control unit controls the plurality of solenoid valves connected to the tank or the storage tank to move the concentrated liquid or ionized water generated by each device, controls the instantaneous heating module installed in the tank, and controls the instantaneous heating of the concentrated liquid or ionized water stored in the tank do.

After the inflow water is filtered through the water purification system, the water is introduced into the first heating tank 100.

The first heating tank 100 heats the filtered raw water to the range of 40-60 ° C using the first instantaneous heating module 102 and supplies it to the electrolytic bath 200. Here, when the temperature is 40 DEG C or lower or 60 DEG C or higher, it is a non-electrolytic temperature condition for producing acidic water and hydrogenated water.

The first instantaneous heating module 102 includes a heating body including a heat generating plate that is electrically connected to a heating wire for electric power to be applied at one end thereof and a heating module controller electrically connected to the heating body.

The electrolytic bath 200 is divided into an anode chamber electrode and a cathode chamber electrode by a diaphragm which can pass only ions having an electrical property. When the voltage is applied, the filtered raw water is electrolyzed and acidic water and strong alkaline water To generate ionized water.

Herein, hydrogen water is in the range of pH 7.1-14 and means hydrogen water containing about 3 ppm or less of dissolved hydrogen.

The electrolytic bath 200 supplies the generated acidic water to the acidic water storage tank 210 and supplies the hydrogen water to the hydrous water heating tank 220.

The hydrothermal heating tank 220 is provided with a heating module and is connected to the first vanadium elution tank 300 to supply the hot water to the first vanadium elution tank 300 by heating the hydrothermal water to a range of 50-90 ° C.

The first vanadium elution tank 300 is provided with a first heater rod 340 and is connected to the second vanadium elution tank 400 and connected to the low concentration storage tank 500, the middle density storage tank 600 and the high concentration storage tank 700 .

The second vanadium elution tank 400 is provided with a second heater rod 440 and is connected to the low concentration storage tank 500, the intermediate concentration storage tank 600 and the high concentration storage tank 700.

The first vanadium elution tank 300 includes a cylindrical first mesh-type basket 310 forming a certain space capable of containing clusters and a second space 330 formed in the lower space of the first mesh- The first stirring bar 330 for heating the electrolytic water and the first heater bar 340 for heating the electrolyzed hydrogen water are positioned.

The first mesh-type basket 310 includes a first mesh-type separation plate 320 in the form of a flat plate that divides the space to form a plurality of storage spaces in the internal space.

The first mesh-type basket 310 and the first mesh-type separation plate 320 are made of a porous material for facilitating movement of ions and solutions.

The second vanadium elution tank 400 includes a cylindrical second mesh-type basket 410 and a second mesh-type basket 410 which form a certain space capable of containing magnesium and magnesium, A second stirring screw 430 for promoting the reaction of the electrolytic water and a second heater rod 440 for heating the electrolyzed hydrogenated water.

The second mesh-type basket 410 includes a second mesh-type separator plate 420 in the form of a flat plate that divides the space to form a plurality of storage spaces in the internal space.

In each storage space, magnesium is placed underneath the cluster.

The second mesh-type basket 410 and the second mesh-type separation plate 420 are made of a porous material for facilitating movement of ions and solutions.

In order to maximize the contact area with the electrolyzed hydrogenated water, the shape of magnesium should be a chip type or a porous sponge having a size of 0.01 to 20 mm in order to accelerate dissociation rate of hydrogen ions and to secure a large amount of hydrogen ions. Includes the type of material. The purity of magnesium is made of a metal material having a purity of 99.0-99.99%.

Here, the first and second mesh type modules include upper and lower sides, left and right sides, and are formed in a porous structure along a circular rim structure so that the number of the hydrogen molecules can easily move into the space inside the module.

In addition, the shape of the clusters shows a granular shape and particle shape of 5 μm-20 mm so that the contact area with the electrolyzed hydrogenated water is maximized and the substitution reaction of vanadium and hydrogen ions is actively performed.

The first vanadium elution tank 300 heats the electrolyzed hydrogenated water in the pH 7.1-14 range, which has passed through the hydrothermal heating tank 220, at a certain temperature and for a certain time to accelerate the reaction between the hydrogen ions and the hydrogen ions, ≪ / RTI >

The second vanadium elution tank 400 reacts with magnesium introduced from the primary vanadium elution tank and reacts with magnesium to induce the selective reaction of the released hydrogen ions and the vanadium contained in the cluster to elute a large amount of vanadium .

The control unit selectively extracts low concentration concentrated vanadium, medium concentration concentrated vanadium and high concentration concentrated vanadium from the cluster using electrolyzed hydrogen water in the range of pH 7.1-14.

Hereinafter, a method of extracting low concentration vanadium from a cluster is described.

The first vanadium elution tank 300 heats the electrolyzed hydrogenated water having a pH in the range of 7.1-14 introduced from the hydroheating tank 220 at a temperature of 60 ° C or lower for 1 hour or longer.

Here, the pH 7.1-14 range of hydrogen peroxide is optimized for the extraction of vanadium from the cluster.

The control unit closes the solenoid valves 900, 920, 930 and 940 of the a, c, d and e and opens the solenoid valves 910 and 950 of the b and c to remove the vanadium concentrate from the first vanadium elution tank 300 To the low concentration storage tank 500.

The reason for heating the first heater rod 340 at a temperature of 60 ° C or less for 1 hour or more is to suppress the volatilization of the hydrogen ions while increasing the reaction temperature of the hydrogen ions and the vanadium contained in the clusters.

A method of extracting concentrated vanadium from the medium is described as follows.

The first vanadium elution tank 300 is supplied with electrolyzed hydrogen water having a pH in the range of 7.1-14 from the hydroheating tank 220, preheated to a predetermined temperature, and then transferred to the second vanadium elution tank 400 .

The second vanadium elution tank 400 operates the second heater rod 440 to heat the concentrated elongate flowing from the first vanadium elution tank 300 at a temperature of 60-80 ° C. for 1 hour or more.

The second vanadium elution tank 400 is made of a mixture of hydrogen ions released by reacting magnesium (or a concentrated aqueous solution) (or a basic aqueous solution) introduced from the first vanadium elution tank 300 with a solution of vanadium Selective reaction is induced to elute heavy concentrated vanadium.

The control unit closes the solenoid valves 910, 930 and 950 of b, d and t and opens the solenoid valves 900, 920 and 940 of the valves a, c and e to remove the vanadium concentrate from the second vanadium elution tank 400 To the medium concentration reservoir (600).

A method for extracting concentrated vanadium from a cluster is described as follows.

The first vanadium elution tank 300 flows electrolyzed hydrogenated water having a pH in the range of 7.1-14 from the hydrothermal heating tank 220 to preheat to a predetermined temperature and then to the second vanadium elution tank 400 .

The second vanadium elution tank 400 operates the second heater rod 440 so as to heat the concentrated eluate flowing from the first vanadium elution tank 300 at a temperature of 70-100 ° C for about 6 hours or more.

The second vanadium elution tank 400 is made of a mixture of hydrogen ions released by reacting magnesium (or a concentrated aqueous solution) (or a basic aqueous solution) introduced from the first vanadium elution tank 300 with a solution of vanadium Selective reaction is induced to elute the concentrated vanadium at a high concentration.

The control unit closes the solenoid valves 910, 940 and 950 of b, e and t and opens the solenoid valves 900, 920 and 930 of the valves a, c and d to remove the vanadium concentrate from the second vanadium elution tank 400 To the medium concentration reservoir (600).

The control unit passes the stored vanadium concentrate from the low concentration reservoir 500, the intermediate concentration reservoir 600 and the high concentration reservoir 700 through an instantaneous temperature module (cooling or heating)

The temperature is adjusted to the final storage tank.

The method of extracting the vanadium concentrate from the cluster described above extracts the vanadium concentrate of low concentration, medium concentration and high concentration through the components such as temperature, time, and magnesium.

As another example, the concentration of the vanadium concentrate can be adjusted according to the mixing ratio of magnesium in the second vanadium elution tank 400.

That is, in the case of pumice: magnesium = 50: 50, the high-concentration vanadium concentrate is extracted in a short time and supplied to the high-concentration storage tank 700. In the case of 60:30 (or 70:30), the concentrated vanadium concentrate is extracted, (Or 90: 10), and then the concentrated vanadium concentrate is extracted and supplied to the intermediate concentration storage tank 600.

The control unit moves the electrolyzed hydrogenated water to the tanks (the first vanadium elution tank 300 and the second vanadium elution tank 400) in which clusters suitable for each use are stored to adjust the concentration by contact time, and the concentration of the vanadium concentrate Before the supply, the electrolytic acidic water is diluted and supplied at a proper mixing ratio to adjust the titratable acidity of the vanadium concentrate.

The vanadium-containing cultivated water stored in the storage tanks (500, 600, 700) of the system can be used as cultivated water for cultivation at the beginning of the first day of the present invention or can be used as cultivated water by dilution. The content of the vanadium component in the cultivated water is 0.5-100 ppb, and the content of the vanadium can be arbitrarily adjusted. Preferably, the content of vanadium is in the range of 1 to 20 ppb, more preferably 2-5. When cultivated soil is cultivated, it is preferable that it is in the range of 3 to 100 ppb.

In addition, in the cultivation method of the present invention, the cultivated water containing vanadium may be mixed with a conventional fertilizer or a nutrient component to be fertilized on a foliar surface or soil. Preferably, it may be used in combination with a known fungicidal extract or natural insecticidal extract when applied to foliar fertilization or soil application. For example, the natural bactericidal extract may be a vinegar extract, a green tea extract, a green tea extract, a polyphenol, a rosemary extract, a rosemary extract, a cinnamon extract, or a tangle extract. When mixed with the natural bactericidal extract, the mixing ratio can be arbitrarily controlled and diluted. The content of vanadium in the mixture to be tested is preferably 5 to 200 ppb.

Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the scope of the present invention is not limited to the following examples.

Example  One Early  culture

Mineral extraction system was used to produce cultivated water containing 1-5 ppb of vanadium from the moss.

Using the above-mentioned cultivated water, cultivated perennials were grown.

After the cuttings were cultivated with the above-mentioned vanadium-containing cultivated water, at 2 and 3 months after the beginning of each month, the content of vanadium contained in the beginning of each month was measured and the results are shown in Table 1 below. The contents of barbium were in the order of root, stem and leaf, and the content of baraldium was increased according to the cultivation period.

Cultivation period Vanadium content (ppb) Immediately after cutting Less than 1 After two months of cultivation, 25.76 After 2 months cultivation, 11.32 After 2 months of cultivation, 9.63 After three months of cultivation, 612.08 After three months cultivation, 108.75 After three months of cultivation, 141.39

Example  2 Early  Hydroponics

Mineral extraction system was used to produce cultivated water containing 1-5 ppb of vanadium from the moss.

Using the above-mentioned cultivated water, mulberry sowing was hydroponically cultivated.

The content of vanadium contained in the perennial leaf was determined by collecting the beginning of each month at 10 days, 15 days, 30 days, and 30 days while cultivating with the above-mentioned vanadium-containing cultivated water after cutting, Respectively. The content of vanadium in the bar showed an increase in the content of vanadium during the cultivation period. When the leaves were collected through hydroponics using 1 to 5 ppb of vanadium content, they were collected after 15 days Respectively.

Cultivation period Vanadium content (ppb) Immediately after cutting Less than 1 After 10 days, 6.23 After 15 days, 12.10 After 20 days hardening, 22.52 After 30 days, 322.35

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Example 4 Radical scavenging ability of vanadium strengthening in early May

The radical scavenging ability was measured by lyophilization of the leaves grown in the same manner as in Example 2 for 30 days with vanadium-containing cultivated water.

The experimental method was the DPPH method. Specifically, 1 ml of ethanol was added to 1 ml of a 0.2 mM DPPH solution dissolved in methanol, and 1 ml of the extract shown in Table 3 was added thereto. The mixture was allowed to stand at room temperature for 10 minutes, and the absorbance at 517 nm was measured with a spectrometer. The activity of DPPH was determined by the following formula (1), (2), (3) and (4). The scavenging activity was expressed as the concentration of the sample required to reduce the concentration of DPPH by 50% (free radical scavenging activity: FSC50, ug / mL).

Freeze-dried Absorbance average Deviation y (%) Primary Secondary control 0.925 0.929 0.927 0.003 Control Sample Blank scavenging 1000 ug / mL 0.155 0.157 0.156 0.001 1000 ug / mL 0.927 0.156 0.075 91.262 500 ug / mL 0.380 0.358 0.369 0.016 500 ug / mL 0.927 0.369 0.056 66.235 200 ug / mL 0.716 0.725 0.721 0.006 200 ug / mL 0.927 0.721 0.052 27.886 100 ug / mL 0.830 0.853 0.842 0.016 100 ug / mL 0.927 0.842 0.048 14.401 50 ug / mL 0.863 0.905 0.884 0.030 50 ug / mL 0.927 0.884 0.045 9.493

As shown in Table 3, it was confirmed that the vanadium-enriched Namhae extract of the present invention had an excellent radical scavenging ability of SC ₅₀ (ug / ml) of 373.6.

Claims (6)

An electrolytic cell for electrolyzing water heated to a predetermined temperature to produce ionized water separated into acidic water and hydrogenated water;
A scoria is placed in a partitioned space, and the electrolyzed ion water is connected to the electrolytic cell, and the electrolyzed ion water is heated at a certain temperature and time to accelerate the reaction between the clathrate and acidic or hydrogen ions, A first tank for storing the first tank;
The method of claim 1, further comprising the steps of: storing the clay and magnesium in a compartmented space; reacting the magnesium chloride with the clay concentrate that is connected to the first tank and introduced from the first tank to release acidic or hydrogen ions; A second tank in which a selective reaction of the minerals contained in the cluster is induced to elute a large amount of mineral concentrate; And
A mineral concentrate eluted from the second tank is introduced and stored for each concentration,
Wherein the content of the vanadium component is in the range of 20-612.08 ppb, and the content of the vanadium component is in the range of 0.5-100 ppb. delete delete The food according to claim 1, wherein the vanadium component is strengthened. delete delete

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