KR101494421B1

KR101494421B1 - Method for manufacturing sidewalk bock using waste molding sand and the sidewalk bock thereof

Info

Publication number: KR101494421B1
Application number: KR20130018295A
Authority: KR
Inventors: 김성원; 서재문
Original assignee: 김성원; 서재문
Priority date: 2013-02-20
Filing date: 2013-02-20
Publication date: 2015-02-23
Also published as: KR20140104290A

Abstract

The present invention relates to a method for manufacturing a sidewalk block using a waste rubber and a sidewalk block manufactured by the method. A method for manufacturing a sidewalk block using a waste sand column according to the present invention comprises the steps of: pulverizing a waste sand column into a powder form; Mixing the waste maggot powder with a predetermined mixed material; Adding a binder aqueous solution to the mixed state to form a mixture; Press molding the blended material into a desired sidewall block shape; Firing the press-formed sidewall bending force in a heating furnace; And cooling the burned sidewalk block.

Description

TECHNICAL FIELD [0001] The present invention relates to a sidewall block manufacturing method and a sidewalk block manufacturing method,

The present invention relates to a method of manufacturing a sidewalk block, and more particularly, to a method of manufacturing a sidewalk block using a waste sand making machine capable of reducing manufacturing cost and removing harmful substances, And a sidewalk block produced by the method.

Most of the waste products from casting factories are disposed of to outside. The disposal of such waste landfills causes environmental pollution, water pollution caused by leachate, and further damage to the ecosystem. In addition, the waste foundry company also incurs economic losses because it requires a considerable waste collection cost at the time of disposal.

Conventionally, there is an example of recycling of waste sand and sand as a raw material for silica sand of cement factory, a preparation agent of steel mill or metal smelting plant, and recently, it has been expanded to be recycled as building materials and reinforcing materials. However, these examples are still very small, and there is little demand for them, and they are not achieving the purpose of full-scale recycling.

Accordingly, there is a growing demand in the technical field for the development of a technology for recycling the waste rubber material that can reduce the environmental pollution, save resources and increase the recycling effect.

It is an object of the present invention to provide a method of manufacturing a sidewalk block by using a waste magazine and a sidewalk block manufactured by the method.

Another object of the present invention is to provide a sidewalk block reporting method and a sidewalk block using the waste shedding yarn, which can manufacture a sidewall block having high strength and durability without any additional process or cost.

It is another object of the present invention to provide a method for manufacturing a sidewalk block using waste rubber that can reduce carbon emissions during sidewalk block manufacturing and completely remove harmful substances during sintering.

According to an aspect of the present invention, there is provided a method for producing a wastepaper, comprising the steps of: pulverizing a waste paper containing chamoite into 30 to 60 mesh of powder; Removing iron powder contained in the powdered maggot powder; Removing moisture from the iron powder-removed waste paper dust; Mixing the wastepaper powder with moisture removed with a mixed material including a volcanic stone, a feldspar and a glass bead; Adding a binder aqueous solution to the mixed state to form a mixture; Press molding the blended material into a desired sidewall block shape; Firing the press-formed sidewall bending force in a heating furnace; And cooling the burned sidewalk block; Wherein the sidewall block comprises 40 to 60% by weight of chamois, 10 to 20% by weight of feldspar, 20% by weight of glass beads, 6 to 8% by weight of water, By weight based on the total weight of the sidewall.

In the present invention, the mixed material may further include clay.

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In the present invention, the temperature at the time of firing is 850 to 890 캜. More preferably, the firing temperature is maintained at 870 캜 for 12 to 17 minutes.

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In order to accomplish the above object, the present invention provides a sidewalk block manufactured by any one of the above-described manufacturing methods.

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The strength of the sidewalk block is 5 to 7.33 MPa.

The method of manufacturing a sidewalk block using the waste rubber according to the present invention and the sidewalk block having the above-described structure have the following effects.

In other words, according to the present invention, since waste pigments contain a lot of expensive bentonite, a great deal of import substitution effect is expected when the waste is recycled.

In addition, according to the present invention, the waste sand produced in the foundry can be recycled without being disposed of, thereby preventing destruction of the ecosystem and environmental pollution.

In addition, according to the present invention, since a sidewalk block is produced by using a waste pavement in which distribution is smooth and usage is large but supply price is high and demand is generated only in a specific part, cost competitiveness can be secured by cost reduction and applied to various fields It is possible.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a process diagram of a method for manufacturing a sidewalk block using a waste rubber according to the present invention; FIG.
Fig. 2 is a photograph showing the surface and cross-section of a specimen with less firing according to the present invention. Fig.
3 is a photograph showing the surface and cross-section of the fired and over-reactive specimen according to the present invention.
4 is a photograph showing experimental results of sidewall blocks fired at a low firing temperature according to the present invention.
5 is a cross-sectional structural view of a continuous electric furnace according to an embodiment of the present invention.
Figure 6 is a surface of a sidewalk block fired in a continuous electric furnace according to the present invention.
7 is an exemplary view of a universal testing machine for testing the strength of a board block according to the present invention.
8 to 12 are graphs showing strength test results of a sidewalk block according to each embodiment of the present invention.
13 is a view showing test results of detection of environmentally harmful substances in a sidewalk block according to the present invention.
14 is an experimental example for detecting whitening phenomenon, float, and foreign matter in a sidewalk block according to the present invention.

The present invention is capable of various modifications and various embodiments, and specific embodiments are illustrated in the drawings and described in detail in the detailed description. It should be understood, however, that the invention is not intended to be limited to the specific embodiments, but includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention. In the description of the present invention, the term "% by weight" as used throughout the present specification means the ratio of the weight of the total amount of 100% by weight of the total amount of the material, unless otherwise specified.

1 is a process diagram of a method for manufacturing a sidewalk block using a waste rubber according to the present invention.

Referring to FIG. 1, a method of manufacturing a sidewall block using a waste rubber according to the present invention includes a crushing process 110, a mixing process 120 with a mixed material, a mixing process 130 with a binder aqueous solution, 140, a firing process 150, and a cooling process 160.

In a pulverizing process (110) of a pulverizing and crushing machine, the pulverized pulverizer is pulverized into a powder form. In this process, the pulverized pulverizer is pulverized to a predetermined size using a pulverizer, and then pulverized into a pulverized powder using a pulverizer. At this time, in this embodiment, it is possible to use the raw mortar, but preferably the mortar has a larger amount of silica and clay than the raw mortar, so that it can be easily recycled through a simple grinding process. You can add more coal ash as needed. These biologists and chamoites should have a large amount of silica sand and clay. However, the present invention is not limited to these two types of materials, and other materials containing siliceous and clay-like components may be used. In addition, it is preferable that the pulverized wastepaper is crushed to a size of 30 to 60 mesh. This is because, in the mixing process (120) described later, the powdery waste powder does not mix well with other mixed materials.

Although not shown in the drawing, in another embodiment of the present invention, the process of removing iron powder contained in the powdery waste paper after the crushing process 110 is further performed, and the process of drying the moisture in the waste paper from which the iron powder is removed It is possible. This corresponds to a preprocessing process for smoothly performing the mixing process 120 and the compounding process 130 and for maintaining the strength of the sidewalk block product.

In the mixing process 120, the pulverized waste ash as described above is mixed with a predetermined mixing material. This mixed material in this embodiment includes feldspar and clay. Feldspar acts to make the surface of the sidewalk block hard. If there are many feldspars, the shape of the sidewalk block is small, but if the sidewall is used too much, the hardness of the product may be too high to break the impact. Therefore, it is necessary to appropriately restrict the sidewall depending on the characteristics of the sidewalk block to be manufactured. In addition, when the binder solution is added in the compounding process 130 described below, the feldspar is hardened by the granules of the size of millet, so it is necessary to minimize the proportion of the feldspar or to reduce the specific gravity. In the present embodiment, 10 to 20% by weight is preferable. Since clay contains a considerable amount of water in itself, it clings well to other materials in the vicinity and sucks in water like feldspar and becomes hard in the form of granules. Also, when added with a lot of water, lumps are formed like clay, and there are many problems in press molding and desorption. Therefore, the proportion of the clay should not exceed 10% by weight of the total weight%, and is preferably 5 to 10% by weight in the present invention.

In addition, as in the case of waste maggots, the coal ash contains a large amount of silicate. The volcanic stone has the effect of increasing the volume and reducing the weight, as well as imparting permeability and hygroscopicity to the sidewalk block. It can be used as a filler and is excellent in the function of controlling the moisture when blending with the binder aqueous solution in the compounding process 130 described later and maintaining the smoothness of the appearance of the board block molded product. These bentonites absorb moisture up to five times their weight and physically tack, but do not cause chemical changes and do not affect the intrinsic properties of other materials.

In the mixing process 130, the aqueous solution of the binder is mixed and mixed with the mixture of the waste maggot powder and the mixed material as described above. The binder aqueous solution is made by dissolving the binder in water. Such a binder aqueous solution is poured into a mixed material of the waste maggot powder and the mixed material so as to be blended. Here, it is preferable that the binder solution should be introduced after the mixture of the waste maggot powder and the mixed material is completed, but the order of addition may be changed depending on the characteristics of the mixed material. In the present embodiment, it is preferable that the wastepaper can be hardened when it is put in before the mixing of the mixed material, so that the wastepaper is put into the mixing process 120. In this way, water plays a role of organically bonding the respective materials and is used for dissolving the binder, and then is evaporated when heated in the firing process 150 described later. Further, when the melting point of the material is lowered to less than 900 캜 by chemical action, the binder evaporates in the firing process. Further, since the binder serves to lower the melting point of silicate to enable low-temperature firing, the binder is used in accordance with the ratio of the waste sand in the sidewalk block. In particular, the higher the ratio of the waste sand, the more moisture increases.

Here, an important part in the present invention is the specific gravity of the mixed material, the concentration of the binder aqueous solution, the moisture, the firing temperature, and the like. The present invention determines this through many experiments. The concentration of the aqueous solution is in the range of 50 to 110% and the moisture of the blended material is 4 to 20% by weight. At this time, the concentration of the binder aqueous solution is a value that represents the amount (g) of the binder in 100 g of water as a percentage. The moisture content of the material is an important variable in the mixing of materials and press molding. If the water content of the compounded material in the compounding process (130) is large, lumps are formed and all the materials are not mixed uniformly. If press molding is performed in this state, the problem of sticking to the upper or lower plate of the mold, As a result of the continuous operation, the materials adhere to the mold, which may adversely affect the product value of the product. In addition, if the water content is high, the time of the water removal section is delayed during the firing process 150, thereby causing a trouble in the entire process. Likewise, if the moisture is not removed completely, the product may be stained or cracked. In addition, the aqueous binder solution lowers the melting point of silica sand contained in the wastepaper, thereby enabling firing and sintering at low temperatures. When the concentration of the binder aqueous solution is high, the reaction of the silica sand is accelerated, and deformation starts before the other materials, resulting in a problem that the shape of the product is collapsed. On the contrary, if the concentration of the binder aqueous solution is low, the chemical bonding of the materials during firing is less, and if the fines are not completely sintered, there arises a secondary problem of raising the firing temperature in order to make it possible. Therefore, in the present invention, the concentration of the binder aqueous solution is kept within the range of 50 to 110% so as to solve this problem. Also, the moisture content of the compounded material has a great influence on the compounding of the material, and therefore, the control thereof is also necessary. When the water content is high, it becomes clogged or the materials are aggregated into a lump shape, and in case of severe case, it is gelated. On the contrary, if it is too low, the respective materials do not aggregate organically and do not mix sufficiently. Therefore, the moisture content of the blended material is maintained at 4 to 20% by weight to solve this problem. In this embodiment, the water content is 6 to 8 wt%. In order to maximize resource recycling, it is desirable that the waste magazine keeps 40 to 50% by weight of the total weight of the waste water excluding the binder aqueous solution.

In the press forming process 140, the material thus formed is press-molded into a desired sidewall block shape. This allows the shape of the sidewalk block product to be determined by press-molding the sidewall to match the sidewall shape.

In the predetermined process 150, the press-molded sidewalk block is fired in a heating furnace. In this embodiment, an electric furnace can be used as the heating furnace. For example, a continuous electric furnace or a small electric furnace can be used. The continuous electric furnace takes up to 24 hours to 48 hours to raise and maintain the target temperature, which is advantageous for mass production because of the large amount of power consumed during this period. Small electric furnaces are convenient for temperature control and maintenance, suitable for producing small quantities of products, and can provide continuous heat in an enclosed space. On the other hand, unlike a continuous electric furnace, the product is fixed and heat is not suitable for actual mass production. Important in the firing process 150 is the firing temperature. In this embodiment, proper sintering temperature is determined by determining the sintering state, surface color, breakage degree, cross section, etc. of the manufactured sidewall block and determining the sintering time and sintering temperature. If the firing temperature is too low, the binder aqueous solution and the material do not react with each other as shown in Fig. 2, but the strength and hardness are weak, the granules of the clay and the clay are not combined with the silica sand, No reaction occurs. On the contrary, if the firing temperature is too high, excessive reaction occurs as shown in FIG. 3, so that the produced sidewalk block is swollen or the pores are formed on the surface and inside, so that the product does not have sufficient strength. In this case, if the binder is reduced, it is possible to prevent the bulge, but the strength becomes insufficient, and if the binder is increased, the reaction rate increases rapidly, resulting in a lot of pores on the surface and inside. The firing temperature determined from these experimental results is preferably 850 to 890 ° C. Particularly preferably, it is maintained at 870 캜 for 12 to 17 minutes optimally.

In the embodiment according to the present invention, when the continuous electric furnace is used, the sidewall block formed in the press is fired on the SIC plate while being passed over the ceramic rod connected to the roller. In this case, the total duration of the electric furnace is 160-180 minutes on average, and the speed is divided into four sections. It is composed of room temperature ~ 350 ℃ range where the inlet and water evaporate, 350 ~ 870 ℃ heating zone where firing starts, 870 ℃ maintenance zone which is sintering, and cooling zone. The low temperature sintering is complete sintering when passing the 870 캜 range. For this, water evaporation must be done at the proper temperature and location, and the movement speed should not be too fast or too slow. 4 is a photograph showing experimental results of a sidewalk block when the firing temperature according to the present invention is 830 to 840 ° C. In this case, the materials did not react completely, so the color was red and the shape was good, but the strength was weak, and some cracked the surface. From these experiments, it can be seen that the firing temperature is preferably maintained at 850 to 890 ° C.

5, a heater rod 41 is positioned at the upper and lower portions of the electric furnace, and the sidewalk block product 42 is mounted on the roller 43 connected to the ceramic rod Move. The heat insulating material 44 has a double structure and is mainly composed of refractory bricks. The thermometer 45 is located at the upper end of the center portion and is disposed at the center of each temperature control period. A sidewalk block product made in this continuous electric furnace is shown in Fig. As shown in the drawing, pores are formed up to the edge of the edge. What happens to the end of the pore is that the binder solution and materials have reacted in all parts. Also, it can be confirmed that the shape is not collapsed, the color is darkened, and it is made closer to the feeling of a natural stone. This resulted in complete sintering at 870 ° C, below 900 ° C, demonstrating the ability to produce large quantities of products of the same or better quality than those made in the test furnace, in continuous electric furnaces.

Thereafter, in the cooling process 160, the sidewalk block completed as described above is slowly cooled. When the cooling is completed in this way, the manufacturing of the sidewalk block is completed. At this time, the temperature may be cooled down gradually.

The present invention provides a sidewalk block manufactured through the various processes 110 to 160 described above. Such a sidewalk block has a strength of 5 MPa or more. To this end, the sintering temperature is maintained at 850 to 890 ° C, more preferably 870 ° C, and the conditions such as the concentration of the mixed material, aqueous binder solution, moisture, etc. are adjusted as described above, The strength test of the specimens was carried out. The strength test was conducted using an IDTNT universal testing machine (see FIG. 7) purchased for the research facility of the eco-design product technology development project. A three-point bend test was carried out by using the equipment to adjust the distance of the support according to the material, thickness and size, and to terminate the test immediately at the breaking point. Table 1 shows the composition ratios of the sidewalk blocks according to the examples used in the test. Here, as described above, the weight% shown in Table 1 means the ratio of the weight of the material to the total 100 weight%. These weight percentages are the same in all the following tables.

NO Main material Part fee burglar Chamote Coal ash One 40 wt% 40 wt% 3.93 2 60 wt% 20 wt% 2.51

Table 1 is an experiment to confirm the possibility of substituting sandalwood with coal ash. Chamote 40% by weight or more, and the sum of chamoite and coal ash constitutes 80% of the total weight. The characteristics of the specimen are shown in Table 2 below. As shown in Table 2 and FIG. 8, the test result shows that the addition of coal ash enhances the strength.

No Specimen Characteristic Operating state Maximum point Breaking point width thickness Sectional area Span length Test speed 1 weight burglar weight burglar One 300.00 15.00 4500.00 240.00 20.00 736.89 3.93 0.04 0.00 2 300.00 15.00 4500.00 240.00 20.00 471.35 2.51 0.45 0.00 Average 300.00 15.00 4500.00 240.00 20.00 604.12 3.22 0.25 0.00 unit Mm Mm ㎟ Mm Mm / min N N / mm < 2 & N N / mm < 2 &

In addition, as shown in Table 3 below, an experiment was conducted to compare the strengths of specimens containing a large amount of coal ash and adding chamoite and ash. The experimental results are shown in Table 4 and FIG. 9, and the total strength was increased by increasing the amount of coal ash, but the difference in strength according to the chamois and ash was about 0.6 MPa.

No Main material Part fee burglar Coal ash Chamote Ash One 65 wt% 15 wt% 0 wt% 4.21 2 65 wt% 0 wt% 15 wt% 4.84

No Specimen Characteristic Operating state Maximum point Breaking point width thickness Sectional area Span length Test speed 1 weight burglar weight burglar One 300.00 10.00 3000.00 240.00 20.00 350.65 4.21 9.14 0.11 2 300.00 10.00 3000.00 240.00 20.00 405.92 4.84 32.80 0.39 Average 300.00 10.00 3000.00 240.00 20.00 376.79 4.53 20.97 0.25 unit Mm Mm ㎟ Mm Mm / min N N / mm < 2 & N N / mm < 2 &

In the above experiment, it was confirmed that chamoite and coal ash can function as a substitute material of silica sand. In another experiment, the strength was measured by adding glass beads and changing water content in order to increase the strength of the product Experiments were conducted. As shown in Table 5, the higher the moisture content, the higher the strength.

No Main material Part fee moisture burglar Chamote Coal ash Glass bead One 40 wt% 30 wt% 20 wt% 6 wt% 4.24 2 40 wt% 30 wt% 20 wt% 8 wt% 5.02

Thereafter, a method of fixing the water content at 6% by weight and increasing the strength was further studied, and feldspar was charged instead of coal as shown in Table 6 below to develop a specimen having an intensity of 5.74 MPa.

No Main material Part fee moisture burglar Chamote feldspar Glass bead One 40 wt% 30 wt% 20 wt% 6 wt% 5.74

Experimental results of these specimens are shown in Table 7 and FIG.

No Specimen Characteristic Operating state Maximum point Breaking point width thickness Sectional area Span length Test speed 1 weight burglar weight burglar One 300.00 8.00 2400.00 240.00 20.00 306.26 5.74 97.30 1.82 Average 300.00 8.00 2400.00 240.00 20.00 306.26 5.74 97.30 1.82 unit Mm Mm ㎟ Mm Mm / min N N / mm < 2 & N N / mm < 2 &

Finally, as a result of analyzing the strength according to the change of the material composition, it was confirmed that the strength varies depending on the ratio of chamoite, coal ash, feldspar and glass beads as shown in Table 8 below. I made a sidewalk block product that surpasses ㎫. 10% by weight of coal as a recycled material, 20% by weight of feldspar and 20% by weight of glass beads were added, and 10% by weight of clay was added as a raw material The strength of the board block specimen baked at 870 캜 was determined to be 7.33 MPa, as shown in Table 9 and Fig. 11, by determining the blending ratio and fixing the foamed formulated water to 6% by weight.

No Main material Part fee moisture burglar Chamote feldspar Glass bead Coal ash One 40 wt% 20 wt% 20 wt% 10 wt% 6 wt% 7.33

Experimental results of these specimens are shown in Table 9 and FIG.

No Specimen Characteristic Operating state Maximum point Breaking point width thickness Sectional area Span length Test speed 1 weight burglar weight burglar One 300.00 9.00 2700.00 240.00 20.00 494.99 7.33 464.14 6.88 Average 300.00 9.00 2700.00 240.00 20.00 494.99 7.33 464.14 6.88 unit Mm Mm ㎟ Mm Mm / min N N / mm < 2 & N N / mm < 2 &

Further, in the continuous experiment, a sidewall block having a strength of 7 MPa or more could be manufactured. The blending ratio at this time is shown in Table 10 below, and the results of the strength measurement are shown in Table 11 and FIG.

No Chamote feldspar Coal ash Glass bead clay bookbinder water burglar One 40 wt% 15 wt% 5 wt% 20 wt% 5 wt% 5 wt% 6 wt% 7.33 2 40 wt% 10 wt% 10 wt% 20 wt% 5 wt% 5 wt% 6 wt% 7.09

Meanwhile, in the whole process of producing the sidewalk block according to the present invention, eco-friendly process technology is developed by reducing energy wastage and eliminating elements harmful to the environment. Chamote, which is used as a main material, was subjected to a test for detecting environmentally hazardous substances in Korea Chemical Fusion Test Institute, and the results were as shown in Fig. In addition, an experiment was conducted to verify whether there is a whitening phenomenon that occurs when the float material is left out of the sidewalk block manufactured according to the present invention. First, the manufactured sidewalk block was left outside and the state of the sidewalk block was observed at intervals of two weeks. The photograph on the left side of FIG. 14 is a photograph of the sidewalk block after 8 weeks, and the whitening phenomenon of the surface could not be found. The photograph on the right is an experiment to detect floating matter or foreign matter generated when the sidewalk block is immersed in water. It was also after 8 weeks and no floating matter or foreign matter was detected.

While the invention has been shown and described with reference to certain preferred embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments. Those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope of the appended claims, The genius will be so self-evident. Accordingly, the true scope of the present invention should be determined by the technical idea of the appended claims.

Most of the waste found in the casting factory is landfilled or disposed of, which causes environmental pollution and ecosystem breakdown. In addition, the sidewalk block is in good circulation and usage, but the products made from recycled materials are extremely rare, and the supply price is high, so demand is only in certain parts.

In view of the above, the present invention makes it possible to manufacture a sidewalk block by recycling a waste rubber material without disposing of the waste rubber material, thereby reducing costs due to recycling of resources, preventing environmental pollution due to landfill waste disposal and disposal, Thereby reducing environmental impact and manufacturing eco-friendly sidewall blocks. Therefore, the present invention can be very usefully used in the field of environment, in the field of sidewalk block manufacturing.

110: crushing process of waste rock material 120: mixing process of mixed materials
130: Blending process with binder aqueous solution 140: Press forming process
150: firing process 160: cooling process

Claims

Pulverizing the waste sand containing the chamois into a powder of 30 to 60mesh;
Removing iron powder contained in the powdered maggot powder;
Removing moisture from the iron powder-removed waste paper dust;
Mixing the iron powder and the waste paper dust with moisture removed with a mixed material including a volcanic stone, a feldspar and a glass bead;
Adding a binder aqueous solution to the mixed state to form a mixture;
Press molding the blended material into a desired sidewall block shape;
Firing the press-formed sidewall bending force in a heating furnace; And
Cooling the burned sidewalk block; Lt; / RTI >
The concentration of the binder aqueous solution is 50 to 80%, and the sidewalk block contains 40 to 60% by weight of chamois, 10 to 20% by weight of feldspar, 20% by weight of glass beads and 6 to 8% by weight of water in a total of 100% A method for manufacturing a sidewalk block using a waste sand column.

The method according to claim 1,
Wherein the blended material further comprises clay. &Lt; RTI ID = 0.0 > 8. < / RTI >

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The method according to claim 1,
Wherein the sintering temperature is 850 to 890 ° C.

12. The method of claim 11,
Wherein the sintering temperature is maintained at 870 캜 for 12 to 17 minutes.

A sidewalk block using a waste rubber product manufactured by the method of manufacturing a sidewalk block using the waste sludge as set forth in any one of claims 1, 2, 11 to 12.

14. The sidewalk block according to claim 13, wherein the strength of the sidewalk block is 5 to 7.33 MPa.

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