KR101493037B1 - Natural surfactant containing the extract of polygala tenuifolia willd. sophora root and rose - Google Patents

Abstract

The present invention relates to a natural surfactant composition which is harmless to the human body, has environmental stability, and is excellent in foaming power, cleansing power, dispersing power and emulsifying power.

Description

NATURAL SURFACTANT CONTAINING THE EXTRACT OF POLYGALA TENUIFOLIA WILLD. SOPHORA ROOT AND ROSE}

The present invention relates to a natural surfactant composition, and more particularly to a natural surfactant composition which comprises a mixed extract of raw paper, gossam and rose, is harmless to the human body, has environmental stability, and has excellent foamability, cleansing power, dispersing power and emulsifying power will be.

A surfactant is a material that stabilizes an aqueous phase and an oil phase which have a hydrophilic group and a hydrophilic group at the same time in the molecule. These surfactants are widely used as detergents, emulsifiers, and fiber treatment agents depending on their properties.

On the other hand, chemically synthesized surfactants are currently used in most cosmetics and cleaning products. These synthetic surfactants are harmful to the human body during use and accumulate in the body when they are used for a long period of time. Thus, side effects of promoting cell mutation and skin aging have been reported. In addition, contamination of seawater or river due to synthetic surfactants is also a serious problem Is emerging.

Therefore, recently, in order to reduce the side effects of various synthetic natural surfactants, researches have been actively conducted on substances that exhibit the surfactant action in natural products. In this regard, natural emulsifiers have been disclosed in Korean Patent Publication Nos. 1992-0019332, 1999-009251, 2002-0037205, and 10-0768069, but they have insufficient surfactant functions There was a problem.

On the other hand, the base paper (Polygala tenuifolia Willd.) is a native and perennial plant distributed in Korea (north central), northern China. The leaves are staggered and needle-shaped, and the flowers are mauve, running sporadically from July to August, with stem and branches at the end of the gun. The petal is butterfly shaped, the upper part is opened and the bottom is attached, and the bottom part is split. The operation is 8, and the bottom part is combined. The fruit is flat with seed capsule, split into two pieces, and the seed has many hairs. The major components are saponin, Onjisaponin AG, Tenuifolin, Xanthones, 2,6,7,8-Tetramethoxyxanthone, 3- Hydroxy-2,6,7,8-tetramethoxy polygalitol, and the like. In one room, it is called roots, and it is written as expository, tangible, and kangjeongje.

Sophora flavescens Aition is a perennial plant of soybean which is distributed in Korea, Japan, China and Siberia. The height is 80 ~ 100cm green, but it is black when it is young. Stem is straight, leaves are alternate, odd numbered pinnate compound leaf. Small leaves are 15 ~ 40, long oval or long ovate, 2 ~ 4cm long, 7 ~ 15mm butterfly. The petiole is long and the edge is flat. A flower stem of about 20cm comes out from June to August at the tip of a branch, and a butterfly-shaped light yellow flower blooms with a umbel. Flower length is 15 ~ 18mm. Calyxes are like tubs, with hairy outer surface and shallow ends with 5 ends. The fruit is a bead-like shape. It is short and has a length of 7-8cm and ripens in September-October. The major components are alomatrin ((+) - form) (+) - 5-alpha, 9-alpha-dihydroxymatrine (-) - 9- alpha -hydroxy sulfolamine, (-) - form, and 7,11 - dihydromatrine. The roots are called gossam, and they are used for jaundice, schizophrenia, and hematemesis.

In addition, Rose (Rosa spp . ) Is a generic term for plants belonging to the rose family Rosaceae Rosaceae in the dicotyledonous plants, and wild species are distributed in one of the Northern Hemisphere, the Bottom Zone, the temperate zone, and the subtropical zone, and more than 100 species are known. Today roses are the natural hybrid and modified species of these wild species. Roses are flowers that have been cultivated for ornamental use and fragrance because of the beautiful shape and fragrance of flowers.

Meanwhile, the inventors of the present invention have made intensive studies on surfactants of natural materials. As a result, they have found that Korean Nos. 10-2011-0112507 (a natural surfactant composition containing extracts of marine extract and a method for producing the same, Korean Patent No. 10-1168301 (Natural Surfactant Containing Gossam Extract, Method for Producing the Same, Cosmetic Composition Comprising the Same, and Cleaning Composition Containing the Same). However, the surfactant alone was not enough to replace the synthetic surfactant with only the extract of Sasa or Gamma alone. Accordingly, the inventors of the present invention have conducted intensive studies on a surfactant having a natural material sufficient to replace a synthetic surfactant, and have completed the present invention.

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made to solve the above-mentioned problems of the conventional synthetic or natural surfactants, and it relates to a natural surfactant composition which is harmless to the human body and has high environmental stability, And to provide the above objects.

It is another object of the present invention to provide a natural surfactant composition which is excellent in bubble power, detergency, dispersibility, emulsification activity and emulsion stability using mixed extracts of raw paper, ginseng and roses, and a process for producing the same.

It is another object of the present invention to provide an optimum extraction condition and an optimum compounding ratio that can optimize the surfactant performance of mixed extracts of raw paper, ginseng and roses.

It is another object of the present invention to provide a cosmetic composition and a cleaning composition containing a natural surfactant composition containing a mixed extract of raw paper, red ginseng and roses.

In order to attain the above object, the present invention provides a natural surfactant composition comprising a mixture of raw paper, ginseng, and roses.

The natural surfactant composition of the present invention comprising a mixture of raw paper, ginseng and roses is harmless to the human body and has environmental stability, and is superior in bubble power, washing power, dispersing power and emulsifying power to conventional natural surfactants, It is highly utilized as material.

Solvent extract alone has good foaming power but not good detergency and dispersibility. Soluble extract of gosam is good in washing power, but has poor foaming power and emulsifying power, and rosin extract alone does not have good bubble power, detergency and dispersibility. However, the mixed extracts of raw paper, ginseng and roses of the present invention are excellent in bubble power, washing power, dispersing power and emulsifying power by mixing raw paper, ginseng and roses. Therefore, extracts of roots, roots, and roses are very low in their utilization as surface active materials, while mixed extracts of roots, roots and roses of the present invention are highly utilized as surface active materials.

Specifically, according to the results of the bubble power test of Experimental Example 1 of the present invention, the mixed extract of the present invention has bubble power equal to that of the synthetic surfactant (positive control). Further, according to the results of the washing power test of Experimental Example 2 of the present invention, the mixed extract of the present invention has better washing power than the synthetic surfactant (positive control). Further, according to the dispersity test result of Experimental Example 3 of the present invention, the mixed extract of the present invention has better dispersing power than Tween 60 (positive control group). Further, according to the emulsification test result of Experimental Example 4 of the present invention, the mixed extract of the present invention has an emulsifying power superior to the sole extract of raw paper, red ginseng or rose. Thus, it can be seen that the mixed extract of the present invention exhibits a very superior surfactant activity than the sole extract of raw paper, red ginseng or roses.

The mixed extract of the present invention is preferably blended in a weight ratio of 0.5-1.5: 0.5-1.5: 0.5-1.5, most preferably in a weight ratio of 1: 1: 1, . According to Experimental Example 8 of the present invention, when the raw paper, gosam and roses were mixed at a mixing ratio of 1: 1: 1, the foaming power was the most excellent and the same effect as the synthetic surfactant was exhibited.

Meanwhile, the method for extracting the mixed extract of the present invention is not particularly limited, and various extracting methods commonly used in the technical field of the present invention can be used. Preferably, solvents such as water, methanol, ethanol, propanol, butanol, glycerol, propylene glycol, 1,3-butylene glycol and the like can be used alone or as a mixture of two or more thereof as an extraction solvent. Preferably water can be used as the extraction solvent.

In addition, according to Experimental Example 9 of the present invention, when extracting at 100 ° C for 1 hour using distilled water as an extraction solvent, it is found that the most excellent effects are obtained in terms of bubble power, washing power and dispersing power.

In addition, in the present invention, raw paper, roasted ginseng, and roses used as materials for extraction may be dried or used as such, preferably dried. As the drying method, a natural drying method or a hot air drying method may be used.

In order to facilitate extraction, the present invention can also be used by pulverizing raw paper, ginseng and roses in a dry state.

In addition, the mixed extract of the present invention can be used in a liquid state, but may be prepared in powder form by an additional process such as vacuum distillation, freeze-drying or spray drying.

In addition, the mixed extract of the present invention preferably contains 0.01 to 50% by mass, preferably 0.5 to 5% by mass, based on dry solids, of a mixture of raw paper, ginseng and roses. When the above range is satisfied, it is possible to obtain a natural surfactant composition having excellent bubble power, cleaning power, dispersing power and emulsifying power.

In the meantime, the present invention can produce a natural surfactant composition by various methods commonly used in the technical field of the present invention using the mixed extract prepared as described above.

Here, the content of the mixed extract contained in the natural surfactant composition of the present invention is preferably 0.001 to 50% by weight based on the total weight of the composition. When the content is less than 0.001% by weight, it may be difficult to obtain an expected effect. When the content is more than 50% by weight, a remarkable effect increase may not be exhibited by an added amount.

The natural surfactant composition of the present invention thus produced is harmless to the human body, has high stability, and has no environmental problem. In addition, the natural surfactant composition of the present invention is excellent in foam power, cleaning power, dispersing power and emulsifying power, and is a natural surfactant replacing synthetic surfactant, and can be used for various cosmetic compositions and cleaning composition.

The cosmetic composition comprising the natural surfactant composition of the present invention can be prepared into any formulation conventionally produced in the art. Examples of the cosmetic composition include basic cosmetic formulations comprising lotion, gel, water-soluble liquid, cream, essence, oil-in-water type and water-in-oil type, It may be any one selected from formulations for color cosmetics consisting of lipstick, lip gloss, face powder, two way cake, eye shadow, cheek color and eyebrow pencil, and formulations for body lotion, body oil, body essence, .

In addition, the cleaning agent comprising the natural surfactant composition of the present invention can be prepared into any formulation conventionally produced in the art. For example, it may be any one selected from shampoo, rinse, treatment, cleansing foam and body shampoo.

According to the present invention, it is possible to produce a natural surfactant composition having a surfactant activity that is sufficiently high enough to replace a synthetic surfactant.

In addition, according to the present invention, a natural surfactant composition excellent in bubble power, washing power, dispersing power, and emulsifying power can be prepared by mixing raw paper, roasted ginseng and roses at a certain blending ratio and extracting them under specific extraction conditions.

In addition, according to the present invention, it is possible to produce a natural surfactant composition harmless to human body, highly stable, and environmentally friendly.

Also, according to the present invention, a cosmetic composition and a cleaning composition can be prepared using a natural surfactant composition containing a mixed extract of raw materials, ginseng, and roses.

1 is a photograph showing a fish toxicity test of the mixed extract of the present invention.
2 is a photograph showing the results of the bubble strength evaluation of Experimental Example 8 of the present invention.

Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the scope of the present invention is not limited to the following examples, but includes modifications of equivalent technical ideas.

Manufacturing example  1: raw paper, GoSam  And mixed extract of roses

Dried ground raw materials, gosams and roses sold on the market were purchased and prepared into powder using a pulverizer. Raw material: rosin: gosam at a weight ratio of 1: 1: 1. To 20 g of the prepared powder sample, 1 L of distilled water was added to a potter (manufacturer: Daewoong, Standard: DWP-3000M) and extracted for 60 minutes. The extract solution was collected by filtration using a filter paper, and then the filtrate was concentrated under reduced pressure at 45 ° C using a concentrator (Heidolph, LABOROTA 4000) to obtain a mixed extract (concentration of dry solid content: 0.5% .

compare Manufacturing example  1: of paper Heat number  Preparation of extract

(Dry solid concentration: 0.5% by mass) was prepared in the same manner as in the above-mentioned preparation example, except that the raw paper was used alone.

compare Manufacturing example  2 : Gosam Heat number  Preparation of extract

A hot water extract (dried solid concentration: 0.5% by mass) was prepared in the same manner as in the above preparation example, except that the ginseng was used alone.

compare Manufacturing example  3: Rose of Heat number  Preparation of extract

A hot water extract of rose (dry solid concentration: 0.5% by mass) was prepared in the same manner as in the above-mentioned preparation example, except that the rose was used alone.

Experimental Example  1: Bubble strength test

In the case of the surfactant component, the surface tension of the water is lowered to easily foam in an aqueous solution. Therefore, the measurement of the bubble force is an indicator for visually confirming the surfactant ability. In this Experimental Example, the hot-water extracts of the above Preparation Examples and Comparative Preparations 1 to 3 were subjected to a foaming test in the following manner.

(KS M 2709), 200 ml of the solution was dropped from the height of 1200 mm at a room temperature for 20 seconds, and the height thereof was measured in mm units immediately after the bubbles were generated. Respectively. The positive control (comparative example) used a mixture of four synthetic surfactants (Micopol LDE / Micolin T430 / Micolin ES 430 / Mitaine CA) at a concentration of 0.5%.

Test sample Comparative Example (positive control group) Comparative Preparation Example 1 Comparative Production Example 2 Comparative Production Example 3 Manufacturing example Synthetic surfactant Origin GoSam rose mix Bubble level (mm) 25 21 3 18 20

As shown in Table 1 above, the mixed extract of the present preparation example exhibited a very high degree of bubble formation and had an effect equivalent to that of the synthetic surfactant, together with the extract of the original preparation of Comparative Preparation Example 1. [

Experimental Example  2: Cleaning power test

Cleaning is the process by which the surfactant is adsorbed by the contaminants and separates the contaminants. The detergency is a major factor for determining the surfactant activity, and it can be judged that the detergent surfactant is a good surfactant. In this Experimental Example, the hydrothermal extracts of the above Preparation Examples and Comparative Preparations 1 to 3 were subjected to a washing power test in the following manner.

Pollutants were prepared from the contents of Table 2 below, 0.05 ml was uniformly applied to the glass specimens, and then dried at room temperature for 12 hours. 30 ml of distilled water and 30 ml of distilled water in a 50 ml container were mixed with 10 ml of a mixture of four kinds of synthetic surfactants (Micopol LDE / Micolin T430 / Micolin ES 430 / Mitaine CA) Were washed with a platform shaker for 3 minutes and then dried at room temperature for 12 hours. The amount of residual oil red (Sudan III) was determined by measuring the absorbance of the residual oil contamination remaining in the glass specimen in 5 mL of tetrachloroethylene and measuring the absorbance of the remaining oil red (Sudan III) using an extruder (manufacturer: Bio-tek KONTRON INSTRUMENTS, standard: UVIKON923) The wavelength of the peak point was selected after measuring the propagation field. The measured absorbance was converted into detergency by the following equation (1).

Composition component Condition Palmitic acid Oleic acid Colorant (Means III) chloroform The hardness of the water to be used 1g 9g 0.05 g 30 mL 50 ppm

The amount of applied oil red is the absorbance of a mixed solution of 0.05 ml of the contaminant and 5 ml of tetrachlorethylene, and the residual amount is the absorbance of the contaminant remaining after washing and the mixed solution of 5 ml of tetrachlorethylene.

Here, the amount of the residual contaminants is confirmed by the absorbance, and the lower the absorbance, the smaller the amount of the contaminants remaining, which indicates that the detergency is excellent. The results of the cleaning power test are shown in Table 3 below.

Test sample Comparative Example
(Positive control group) Comparative Preparation Example 1 Comparative Production Example 2 Comparative Production Example 3 Manufacturing example Synthetic surfactant Origin GoSam rose mix Absorbance 1.427 1.475 0.82 1.52 0.912 Cleaning power (%) 32.21 31.16 59.24 28.56 48.96

As shown in Table 3, it was found that the mixed extract of the present example had better cleaning power than the synthetic surfactant in addition to the extract of Gossam gum in Comparative Preparation Example 2.

Experimental Example  3: Dispersibility  Test

Dispersion is a phenomenon in which the dispersibility is greatly changed by the addition of a surfactant to a suspension or emulsion, which causes aggregation or stabilization. This dispersion effect is due to the strong adsorption property of the surfactant, which decreases the interfacial energy and reduces the thermodynamic instability of the system .

In this experimental example, for the adsorption test of the hot-water extracts of the above Preparation Examples and Comparative Production Examples 1 to 3, Fe ₂ O ₃ having a red color was added, followed by using a light absorber (manufacturer: Bio-tek KONTRON INSTRUMENTS, specification: UVIKON 923) And the absorbance was measured. The dispersibility test was carried out in the following manner.

Tween 60 (positive control) and 50 ml of the extracts of the above Preparation Examples and Comparative Examples 1 to 3 were added to 0.15 g of Fe ₂ O ₃ in a beaker, followed by stirring at 500 rpm for 20 minutes using a stirrer (manufacturer: Heidolph, Followed by stirring for a minute to disperse Fe ₂ O ₃ evenly. The dispersed solution was placed in a fraction funnel, 2 ml of the suspension was taken from the bottom of 20 ml, diluted with 100 ml of distilled water, and absorbance was measured at 705 nm.

The results of the dispersity test are shown in Table 4 below. Since the experiment confirms the degree of dispersion of Fe ₂ O ₃ , the higher the absorbance, the better the dispersibility.

Test sample Comparative Example
(Positive control group) Comparative Preparation Example 1 Comparative Production Example 2 Comparative Production Example 3 Manufacturing example Tween 60 Origin GoSam rose mix Measures 0.599 0.348 0.530 0.512 0.612

As shown in Table 4, it was found that the mixed extract of the present example had a dispersing power which was much better than that of the positive control, and had better dispersing power than the raw paper, the roasted or roasted extract.

Experimental Example  4 : Emulsifying power  Test

In this Experimental Example, emulsion performance tests of the Preparation Examples and Comparative Production Examples 1 to 3 were carried out in the following manner.

2.5 ml (0.1 wt%) of the hot-water extract of Comparative Preparation Examples 1 to 3 was added to 0.1 ml of the same amount mixture of hexadecane and 2-methyl naphthalene, and 50 mM Tris- The pH was adjusted to 8 with 7.4 ml of HCl buffer solution, and the mixture was shaken for 1 hour at 25 ° C at 150 rpm, then allowed to stand for 10 minutes, and absorbance was measured at 620 nm.

The results of emulsification test are shown in Table 5 below, which means that the higher the absorbance, the better the emulsifying power.

Test sample Comparative Preparation Example 1 Comparative Production Example 2 Comparative Production Example 3 Manufacturing example Origin GoSam rose mix Measures 1.50 1.43 1.50 1.610

As shown in Table 5, it was found that the mixed extract of the present example exhibited superior emulsifying power than the raw paper, gosam and rose extract.

Experimental Example  5: Evaluation of skin irritation of mixed extracts

In this Experimental Example, to evaluate the safety of the mixed extract of the above Preparation Example, the first stimulation test was performed on the human body through a human patch test.

Ten healthy adult men and women were enrolled according to the CTFA guidelines (Reference: The Cosmetic, Toility and Fragrance Association, Inc., Washington, DC, 20036, 1991). 20 μl of sample was dropped into a Finn chamber, placed on the inside of the human arm of the test site, and fixed with a tape. The primary skin irritation test was carried out for 24 hours, and after removing the patch, the skin reaction of the test site was judged according to the following criteria after 4 hours and 24 hours elapsed, and the results are shown in Table 6 below.

<Criteria>

-; No erythema or unusual symptoms

+ -; Slightly reddish than around

+; Remarkably reddened than surrounding

++; More reddened and swollen than around

sample Tested embroidery Judgment result Irritation degree ++ + + - - Manufacturing example
(Mixed extract) 10 - - - 5 0

As shown in Table 6, it was found that the mixed extract of the present example had very little skin irritation and was very safe for human body.

Experimental Example  6: Mixture of extracts Toxicity to fish  evaluation

In this Experimental Example, fish toxicity was evaluated for the environmental harmfulness of the mixed extract of the above Preparation Example.

1) Fish Toxicity test: Fish (Oryzias latipes, Medaka, Killifish)

Average body weight 0.25g, 2.5 ~ 4cm body length is used as experimental material

For the experiment, move the birds adapted for one week in another tank

Use 10 animals per experimental group

2) Breeding and management

Number of Breeding: After 1 day of standing,

Condition Water temperature pH 20 ° C to 25 ° C 7 to 7.5

Generation of similar environments through microbial activators

3) Test method

Ten healthy dogs fasted for 24 hours were used as one group, and each of the water tanks treated with the mixed extract (0.2% based on the total water volume) and the synthetic surfactant (0.2% based on the total water volume) I moved it. The control group is a water tank filled with tap water for one day, the experimental group 1 is a water tank treated with a synthetic surfactant, and the experimental group 2 is a water tank treated with the mixed extract of the above production example. We observed general poisoning symptoms and number of deaths every hour from 1 hour to 4 hours after treatment and 24, 48, 72 and 96 hours thereafter. During the course of the test, the dead animals were taken out immediately after the experiment, and the survival of the survivors was observed. During the experimental period, the water quality was checked by measuring the pH in the water tank. The lethality of the test fish according to the sample treatment was observed every measurement time after the sample treatment. And immediately recovered the lethality.

4) Results

The results are shown in FIG. 1. In the case of treating the mixed extract of the present example, all the fish survived after 4 days of the fish toxicity test, whereas when the synthetic surfactant was treated, 10 minutes after the treatment, All of them died. Thus, it was found that the mixed extract of the present example had very low environmental hazard.

Experimental Example  7: Mixed Chastisement  Sensory evaluation of applied product

In this Experimental Example, it was confirmed by sensory evaluation that the difference in the use of the mixed extract of the above Preparation Example as a surfactant was easy to apply to the finished product.

20 persons in their 20s and 30s were selected and used shampoo made of a synthetic surfactant (Micopol LDE / Micolin T430 / Micolin ES 430 / Mitaine CA) and a mixed extract of the above preparation example. Evaluation sheets according to the evaluation criteria of Table 8 below relating to the surfactant action were prepared.

Evaluation items grade 5 points 4 points 3 points 2 points 1 point Degree of bubble generation
(Bubble force) There are so many. A little more It is suitable A little less Very few Cleaning degree (cleaning power) Very well wiped It is slightly wiped. is average A little less clean Very little wipe

Table 9 shows the average value of the evaluation points per each evaluation item in Table 8 as the sensory evaluation of the applied product of the finished product.

Evaluation items medium Shampoos made from mixed extract Shampoos made from synthetic surfactants Degree of bubble generation (bubble power) 2.9 3 Cleaning degree (cleaning power) 2.7 4

As shown in Table 9, the shampoo prepared with the mixed extract of the present example had a similar bubble power and cleaning power as the shampoo prepared with the synthetic surfactant. Therefore, it was found that the mixed extract of the present invention is highly utilized as a natural surfactant substitute for a synthetic surfactant.

Production Examples 2 to 8: Preparation of Mixed Extracts of Rice, Gosam and Roses

In the present example, mixed powders were prepared so as to have a final weight of 600 g by mixing powders, roots and roses as shown in the following table.

Mixing ratio Production Example 2 Origin: Gosam: Roses = 100g: 200g: 300g = 0.5: 1.0: 1.5 Production Example 3 Origin: Gosam: Roses = 200g: 100g: 300g = 1.0: 0.5: 1.5 Production Example 4 Origin: Gosam: Roses = 300g: 200g: 100g = 1.5: 1.0: 0.5 Production Example 5 Origin: Gosam: Roses = 100g: 300g: 200g = 0.5: 1.5: 1.0 Production Example 6 Origin: Gosam: Roses = 200g: 300g: 100g = 1.0: 1.5: 0.5 Production Example 7 Origin: Gosam: Roses = 300g: 100g: 200g = 1.5: 0.5: 1.0 Production Example 8 Origin: Gosam: Roses = 200g: 200g: 200g = 1.0: 1.0: 1.0

To apply the hot water extraction method, 12 L of distilled water and the mixed powder were placed in a hot water bath and extracted at 105 ° C for 3 hours. Then, the extract was firstly filtered at 23 ° C using a nonwoven fabric (at this time, dry solid concentration: 2.5 wt%), and the solvent was removed by concentrating the extract with a vacuum concentrator. At this time, the temperature of the water bath was 47 ° C, the concentration of the concentrate flask was 110 rpm, and the concentration of the concentrate was gradually reduced from 120 mbar to 40 mbar. Thereafter, the concentrate was centrifuged at 4,500 rpm for 30 minutes, and then subjected to secondary filtration using Filer paper. The obtained concentrate was mixed with distilled water and glycerin (dry solid concentration: 1 wt%).

Experimental Example 8: Evaluation of foaming power according to mixing ratio of raw paper,

In this Experimental Example, the bubble power was tested for the mixed extracts of Preparation Examples 2 to 8 in the same manner as in Experimental Example 1 above. In the control group, a mixture of 4 kinds of Lauric Diethanolamide, TEA Lauryl Sulfate, Sodium Laureth Sulfate and Cocamidopropyl Betaine was used at a concentration of 0.5%. The results are shown in Table 11 below.

Bubble force according to mixing ratio (mm) Production Example 2 31 Production Example 3 30 Production Example 4 32 Production Example 5 28 Production Example 6 32 Production Example 7 35 Production Example 8 41 Control (synthetic surfactant) 47

According to the above Table 11, when the raw paper, gosam and roses are mixed at a mixing ratio of 1: 1: 1, the foaming power is the most excellent and the effect is equivalent to that of the synthetic surfactant.

Production Examples 9 to 20: Preparation of mixed extracts of raw paper, gosam and roses

In this Preparation Example, a mixed extract was prepared in the same manner as in Preparation Example 8, except that extraction conditions were changed as shown in the following table.

Extraction solvent Extraction time Extraction temperature Production Example 9 Distilled water 1 hours 60 ° C Production Example 10 Distilled water 1 hours 100 ℃ Production Example 11 Distilled water 3 hours 60 ° C Production Example 12 Distilled water 3 hours 100 ℃ Production Example 13 Distilled water 6 hours 60 ° C Production Example 14 Distilled water 6 hours 100 ℃ Production Example 15 50% ethanol 1 hours 25 ℃ Production Example 16 50% ethanol 1 hours 60 ° C Production Example 17 50% ethanol 3 hours 25 ℃ Production Example 18 50% ethanol 3 hours 60 ° C Production Example 19 50% ethanol 6 hours 25 ℃ Production example 20 50% ethanol 6 hours 60 ° C

Experimental Example 9 Comparative Evaluation of Bubble Power, Cleansing Power, and Dispersing Ability According to Extraction Conditions of Mixed Extracts of Origin, Gosam and Rose

In this Experimental Example, foaming power, washing power and dispersing power were measured and compared with the mixed extracts of Preparation Examples 9 to 20 in the same manner as in Experimental Examples 1 to 3 above.

The results are shown in Table 13 below.

Bubble force (mm) Cleaning power (%) Dispersing force (Abs) Production Example 9 38 37 0.5 Production Example 10 42 48 0.6 Production Example 11 41 47 0.6 Production Example 12 39 48 0.7 Production Example 13 42 39 0.7 Production Example 14 39 40 0.6 Production Example 15 11 21 0.5 Production Example 16 15 22 0.4 Production Example 17 14 20 0.5 Production Example 18 12 19 0.6 Production Example 19 13 21 0.7 Production example 20 14 23 0.6

According to the above Table 13, it was found that bubble power, washing power, and dispersing power were both excellent when extracted with distilled water for 1 hour at 100 ° C.

Claims (5)

Includes mixed extracts of raw paper, gosam and roses,
Wherein the mixed extract is mixed at a weight ratio of raw silk: rosemary: rose of 0.5-1.5: 0.5-1.5: 0.5-1.5.
delete The method according to claim 1,
Wherein the extraction solvent of the mixed extract is at least one selected from the group consisting of water, methanol, ethanol, propanol, butanol, glycerol, propylene glycol, and 1,3-butylene glycol.
A cosmetic composition comprising the natural surfactant composition according to claim 1.
A cleaning composition comprising the natural surfactant composition according to claim 1.

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