KR101446663B1 - The concrete surface reinforcement and protect from burning construetion methodthereof - Google Patents

The concrete surface reinforcement and protect from burning construetion methodthereof Download PDF

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KR101446663B1
KR101446663B1 KR1020140056987A KR20140056987A KR101446663B1 KR 101446663 B1 KR101446663 B1 KR 101446663B1 KR 1020140056987 A KR1020140056987 A KR 1020140056987A KR 20140056987 A KR20140056987 A KR 20140056987A KR 101446663 B1 KR101446663 B1 KR 101446663B1
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concrete
composition
silane
concrete structure
silicate
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김용석
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김용석
한일피엔티 주식회사
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/045Alkali-metal containing silicates, e.g. petalite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/10Acids or salts thereof containing carbon in the anion
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641Polyacrylates; Polymethacrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/40Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
    • C04B24/42Organo-silicon compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/32Aluminous cements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04GSCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
    • E04G23/00Working measures on existing buildings
    • E04G23/02Repairing, e.g. filling cracks; Restoring; Altering; Enlarging
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Architecture (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Working Measures On Existing Buildindgs (AREA)

Abstract

The present invention relates to a fine crack repairing agent composition of a concrete structure which is characterized by containing 40 wt% of a concrete powder and 60 wt% of a surface reinforcing agent, wherein the concrete powder contains 40 wt% of a mixture mixing 25 kg of Portland cement, 25 kg of alumina cement, 5 kg of sodium carbonate, 3 kg of alunite, and 5 kg of a silicic acid-based compound, and 60 wt% of silica, and the surface reinforcing agent contains 70 kg of silane, 80 kg of an acrylic resin, 5 kg of an emulsifier, and 1 kg of a dispersing agent, and to a method for construction method of the same.

Description

콘크리트 구조물의 미세균열 보수제 조성물 및 그 시공방법{The concrete surface reinforcement and protect from burning construetion methodthereof}Technical Field [0001] The present invention relates to a micro crack repairing composition for a concrete structure,

본 발명은 콘크리트구조물의 미세균열 또는 망상크랙을 보수하는데 사용되며, 콘크리트분체와 표면강화제로 조성된 콘크리트구조물의 미세균열 보수제 조성물 및 그 시공방법에 관한 것이다.
TECHNICAL FIELD The present invention relates to a microcrack repairing composition for a concrete structure made of a concrete powder and a surface strengthening agent, which is used for repairing microcracks or network cracks in a concrete structure, and a method of constructing the same.

일반적으로 시멘트 콘크리트 포장도로, 콘크리트 구조물 측구, 방음벽, 벽체의 표면의 결함을 제거하는 보수 방법으로 결함부위를 제거하거나, 별도의 덧씌우기 층의 형성을 통해 결함부위가 직접적인 차량하중을 받지 않도록 하는 방법, 그리고 결함부위의 파손 진전을 억제하는 방법이 있을 수 있다. 이러한 보수 공법 중에 결함부위의 파손 진전을 억제하는 방법은 상대적으로 파손의 정도가 작은 경우에 유용하게 적용될 수 있는 경제적인 방법으로 판단된다. 즉 표면에 나타난 파손이나 결함을 인정하나, 이러한 파손에 추가적인 진전이 없으면 포장면을 주행하는 차량의 주행성에 대한 영향이 작다는 판단에 적용하는 공법이라고 할 수 있다.
Generally, a repair method that removes defects on the surface of cement concrete pavement, concrete structures, soundproof walls, and walls is used to remove defects or prevent defective parts from being subjected to direct vehicle load by forming a separate overlay layer , And a method of inhibiting breakage of the defective portion. In this repair method, the method of suppressing the breakage progress of the defective portion is considered to be an economical method that can be usefully applied when the degree of breakage is relatively small. In other words, it is recognized that damage or defects appearing on the surface are recognized, but if there is no further progression to such damage, the method is applied to judge that the effect on the running ability of the vehicle running on the pavement side is small.

그러나 국내의 경우에는 시멘트 콘크리트 포장의 표면 보강을 위한 씰러(Sealer)의 적용 사례가 있다. 씰러는 광의로 충전제, 보강제를 의미하고, 협의로는 산업자원부 기술표준원에서 제정한 한국산업규격으로 KS F 4930:2002 "콘크리트 표면도포용 액상형 흡수 방지제"를 말하며, 이러한 액상형 흡수 방지제는 콘크리트 표면의 보호를 목적으로 표층부에 도포하여 함침시킴으로써 흡수방지층을 형성하여 외부로부터의 물 및 염화이온 등의 침투를 억제하여 콘크리트 표면의 동해, 침식 및 철근의 부식을 방지하고자 하는 목적으로 사용하는 재료를 의미한다.
However, in Korea, there is an example of application of sealer for surface reinforcement of cement concrete pavement. KS F 4930: 2002 "Concrete Surface Shaping Liquid Absorbing Agent" refers to a Korean industrial standard established by the Agency for Technology and Standards of the Ministry of Commerce, Industry and Energy, Means a material used for the purpose of preventing permeation of water, chloride ions and the like from the outside to prevent corrosion, erosion of the concrete surface and corrosion of the reinforcing steel by coating the surface layer for protection and impregnating the surface layer .

도로 선진국인 미국의 경우에 뉴욕주, 오하이오주, 일리노이스주, 유타 주 등에서 콘크리트 씰러(Sealer)에 대한 규정을 제정하고 있는 것으로 나타났다. 이러한 씰러는 콘크리트 표면으로서의 수분과 염화물 등의 침투를 억제하여 콘크리트 내부의 철근 부식을 방지하고 콘크리트의 열화를 방지하는 목적으로 사용되는 재료를 말하고, 이러한 규정은 대부분이 노출교면의 콘크리트 상판을 보호하기 위한 목적으로 사용되는 경우인 것으로 수분과 염화물의 침투는 억제하고 공기의 통과(Transfer of water vapor)는 허용하게 하기 위한 목적으로 사용하는 것이다.
In the case of the US, which is a road-developed country, it has been found that regulations for concrete seals are being enacted in New York State, Ohio State, Illinois State, and Utah State. These sealers are materials used to prevent penetration of water and chlorides as concrete surface to prevent corrosion of reinforcing bars in concrete and to prevent deterioration of concrete. These regulations are mostly used to protect the concrete tops of exposed bridges And is intended to be used for the purpose of inhibiting the penetration of water and chloride and allowing the transfer of water vapor.

씰러는 콘크리트 표면을 침투하여 공극 및 미세균열을 충진하며, 수분 및 염분의 침투를 억제하여 콘크리트의 파손을 방지하는 것을 목적으로 한다. 그리고 재료에 따라서 표면에 막을 형성하여 이러한 작용을 증진시키기도 한다. 이러한 보호 및 방수작용과 더불어 씰러 재료가 강성을 확보하는 경화특성을 갖게 되는 경우 표면을 강화하는 작용을 하기도 한다. 앞서 구분한 바와 같이 표면 보호 특성과 표면 경화 특성은 구분되어져야 하고, 때로는 목적에 맞게 구별하여야 할 것으로 판단된다. 본 검토에서와 같이 표면 보호 및 취약한 표면의 강화를 목적으로 하는 씰링 공법의 적용에서는 이러한 특성을 종합적으로 고려할 필요가 있다. 그러나 지나치게 경화특성이 강한 씰러의 경우에는 표면에 콘크리트 표면을 취성적으로 변화시켜 과도한 차량의 충격하중에 대해 취성파괴을 유발하기도 한다. 이러한 취성은 외부의 자외선에 의해서도 유발되는 것으로 알려져 있어, 이러한 현상에 의한 파손사례로는 과거 시멘트 콘크리트 포장면의 박층 덧씌우기 재료에서의 조기파괴를 통해 경험한 바가 있다고 할 수 있다.
The sealer penetrates the concrete surface to fill voids and microcracks, and is intended to prevent the breakage of concrete by suppressing penetration of moisture and salinity. Depending on the material, a film is formed on the surface to promote such action. In addition to this protection and waterproofing action, the sealer material also acts to strengthen the surface when it has curing properties to ensure rigidity. As mentioned above, the surface protection property and the surface hardening property should be distinguished from each other and sometimes it should be distinguished according to the purpose. As in the present review, it is necessary to comprehensively consider such characteristics in the application of the sealing method for protecting the surface and strengthening the weak surface. However, in the case of an over-hardened sealer, the surface of the concrete may be brittle, which may cause brittle fracture to an excessive impact load on the vehicle. This brittleness is also known to be caused by external ultraviolet rays. As an example of the damage caused by this phenomenon, it can be said that the brittleness has been experienced through the early destruction of the thin layer overlay material on the past cement concrete pavement surface.

최근 들어 씰러가 확보되어야 할 중요한 특성의 하나로 제시되는 것은 통기성의 확보이다. 무기질계의 씰러들이 유기질계 대한 상대적인 장점으로 제시하는 이러한 통기성의 역할은 표면에 살포된 보호 또는 강화층의 하부에 수분을 포함한 공기가 차단되어 집중되는 것을 방지하여, 또 다른 취약층의 형성과 압력 생성을 억제한다는 것이다. 이러한 원인에 의한 파손은 교면포장의 방수층의 파손 등을 통해 경험한 바가 있다고 할 수 있다.
In recent years, one of the important characteristics that seals should be secured is ensuring ventilation. The role of this ventilation, which mineral seals offer as a relative advantage for the organic system, is to prevent the concentration of air containing moisture in the lower part of the protective or reinforcing layer applied on the surface, Thereby suppressing the generation of the virus. Damage due to these causes has been experienced through damage of the waterproof layer of the pavement pavement.

따라서, 일반적으로 씰러와 관련한 문헌들에게서 나타나는 씰러의 특성을 결정짓는 요소로서는 다음과 같은 것들이 있다.Thus, there are generally the following factors that determine the characteristics of the sealer in documents related to the sealer.

침투 깊이(Penetration Depth), 자외선 저항성(Ultraviolet Resistance), 콘크리트의 반응성(Reactivity of Concrete Materials), 내구수명(Service Life), 염화이온 및 물 흡수성(Chloride and Water Absorption), 통기성(Water Vapor Transmission), 균열 봉합(Crack Bridging), 재설염 저항성(Deicer Scaling Resistance)
Water penetration, Water penetration, Penetration Depth, Ultraviolet Resistance, Reactivity of Concrete Materials, Service Life, Chloride and Water Absorption, Crack Bridging, Deicer Scaling Resistance,

콘크리트 표면은 건조하며, 먼지, 오일, 왁스, 양생제, 백화, 레이턴스, 코팅 등과 같은 다른 이물질이 없는 상태이어야 한다. 따라서, 씰러의 포설 전에 취약한 부위나 탈리부에 대한 적절한 보수가 선행되어야 한다.The concrete surface should be dry and free of other foreign matter such as dust, oil, wax, curing agent, whiteness, retardation, coating, Therefore, prior to the installation of the sealer, proper repair of the vulnerable area or tear part should be preceded.

콘크리트의 양생기간 이후에 최소한 5일 이상의 공기 건조가 이루어져야 하며, 그라우팅 작업 후 5일 이상의 공기 건조기간이 경과되어야 한다. 공기 건조가 완전히 이루어지지 않은 상태에서는 씰러를 포설 할 수 없다.At least 5 days of air drying should be done after the curing period of the concrete, and at least 5 days of air drying after the grouting should be over. The sealer can not be installed when air drying is not complete.

촉진 양생에 수행된 프리캐스트 콘크리트의 경우에는 요구되는 표준양생의 28일 강도가 확보된 이후와 공극의 충진이 요구되는 경우에는 충진, 양생 기건 후 5일 이후에 씰링이 수행되어야 한다.
In the case of precast concrete for accelerated curing, sealing shall be carried out after 5 days of filling and curing if the required curing is secured for 28 days after the required curing and when pore filling is required.

시공면의 먼지, 얼룩, 오일, 왁스, 양생제, 백화, 레이턴스, 코팅물질 등과 같은 이물질을 제거한다. 이러한 이물질의 제거에 특수한 화학물질이 필요한 경우에는 제품 공급자가 시방에 따라 이를 수행하며, 시공면의 준비 후 48시간 이내에 씰링을 수행한다.
Remove dirt, stains, oil, wax, curing agent, whiteness, laitance, coating materials, etc. on the construction surface. If special chemicals are required for the removal of these foreign materials, the supplier shall do so according to specifications and perform the sealing within 48 hours after preparation of the construction surface.

국내등록특허공보 등록번호 제10-354135호에는 누수를 방지하고 장기간 침수에 의해 열화부식된 콘크리트 표면을 보수보강 보호하는 지하구조물의 내부복합방수보수하는 방법으로서, 이물질을 제거하고, 바탕면에 폴리아미노(1-옥소-1,6-헥산디일)와, 2,2-(1-메틸에틸리덴)비스(4,1-페닐렌옥시메틸렌)와, 메틸페녹시메틸과 물로 혼합된 침투성접착강화제를 도포하여 표면강화 및 제1방수층을 형성하고, 상기 제1방수층 위에 이소시아네이트로 블록킹된 폴리우레탄과 비정형 실리콘다이옥사이드와 칼슘카보네이트와 트리메틸렌헥사메티렌디아민과 페놀의 알킬술포닉산 에스테르로 혼합된 표면보강방수제를 도포하여 표면보강 및 제2방수층을 형성하는 단계 및 상기 제2방수층위에 폴리이미노(1-옥소-1,6-헥산디일)와, 2,2-(1-메틸에틸리덴)비스(4,1-페닐렌옥시메틸렌)비스 호모폴리머와, 메틸페녹시 메틸과 물을 포함하는 표면보호 및 제3방수층으로 형성하는 콘크리트 내부 벽면의 복합방수 보수방법이 기술되어 있으며,
Korean Patent Registration No. 10-354135 discloses a method for repairing internal reinforced concrete waterproofing of an underground structure for preventing water leakage and repairing and reinforcing the surface of a concrete that has been deteriorated and corroded by prolonged flooding, Permeable adhesive mixed with amino (1-oxo-1,6-hexanediyl), 2,2- (1-methylethylidene) bis (4,1- phenyleneoxymethylene), methylphenoxymethyl and water the surface mixed applying the enhancing agent to form a surface reinforcement and a first waterproof layer, and as said first blocking with an isocyanate on the waterproof layer of polyurethane, and amorphous silicon dioxide and calcium carbonate and trimethylene hexamethylene methicillin diamine and phenol alkylsulfonyl acid ester of applying a reinforcement waterproofing agent to form a surface reinforcement and a second waterproof layer and the second waterproof layer and on the unexposed polyimide (1-oxo-1,6-hexane-diyl), 2,2 (1-methyl butylidene) bis (4,1-phenyleneoxy Ethylene) bis and homopolymers, and the composite waterproof repair method the concrete walls are described for forming a surface protection and the third waterproof layer comprising a-methylphenoxymethyl and water,

국내공개특허공보 공개번호 특2003-74180호에는 탄산나트륨, 염화칼륨, 염화암모늄, 보락스, 증류수로 이루어진 무기경화첨가제와, 규산나트륨, 실리콘, 또는 불소성분이 함유된 계면활성제, 증류수로 이루어진 조성물로 균일하게 도포하며, 상기 도포된 표면에 질산,황산 또는 구연산을 균일하게 도포 하는 단계를 포함하는 콘크리트 무기경화 첨가제용 조성물 및 콘크리트 표면처리방법이 기재되어 있고,
Korean Patent Laid-Open Publication No. 2003-74180 discloses a composition comprising an inorganic curing additive consisting of sodium carbonate, potassium chloride, ammonium chloride, borax and distilled water, a surfactant containing sodium silicate, silicone or fluorine component, And uniformly applying nitric acid, sulfuric acid or citric acid to the applied surface, and a concrete surface treatment method and a composition for a concrete inorganic curing additive,

국내공개특허공보 공개번호 특2003-71231호에는 에폭시수지 또는 변성 에폭시 수지와, 알루미나 또는 수산화 알루미늄, 조강용 시멘트와, 용제를 포함하여 혼합된 혼합물과, 폴리아미드수지 또는 변성 아민수지 또는 변성방향족 아민수지와 이산화티탄과 알루미늄실리케이트와, 물을 포함하여 혼합된 경화제를 혼합하여 하도재를 콘크리트 표면에 도포한후, 아크릴 수지 또는 변성 아크릴 수지, 이산화티탄, 폴리에스테르 수지 또는 변성 폴리에스테르 수지 용제를 포함하여 혼합된 혼합물과 우레탄 수지 또는 변성 우레탄 수지와 용제를 포함하여 혼합된 경화제를 혼합하여 상도재를 상면에 도포하는콘크리트의 중성화 및 열화방지공법이 공개되어 있음을 알 수 있다.
Korean Patent Laid-Open Publication No. 2003-71231 discloses a resin composition comprising a mixture of an epoxy resin or a modified epoxy resin, alumina or aluminum hydroxide, cement for cement, and a solvent, and a mixture of a polyamide resin or a modified amine resin or a modified aromatic amine resin And a mixed curing agent containing titanium dioxide, aluminum silicate and water, and then applying the undercoating material to the surface of the concrete. Thereafter, the surface of the concrete including the acrylic resin or the modified acrylic resin, titanium dioxide, polyester resin or modified polyester resin solvent It can be seen that a method of preventing the neutralization and deterioration of concrete in which a mixed material is mixed with a curing agent including a urethane resin or a modified urethane resin and a solvent to apply the top material to the top surface is disclosed.

1. 국내등록특허공보 등록번호 제10-354135호1. Korean Patent Registration No. 10-354135 2. 국내공개특허공보 공개번호 특2003-74180호2. Published Korean Patent Application Publication No. 2003-74180 3. 국내공개특허공보 공개번호 특2003-71231호3. Published Korean Patent Application No. 2003-71231 4. 국내등록특허공보 등록번호 제10-0601882호4. Korean Patent Registration No. 10-0601882 5. 국내등록특허공보 등록번호 제10-1001112호5. Domestic Patent Registration No. 10-1001112

상기와 같은 종래의 공법들은, 시간이 경과함에 따라 해풍, 해수, 제설용 염화칼슘의 염기가 콘크리트 내에 침투하여 콘크리트를 부식하고, 수분이 있는 상태에서 염기가 침투되어 콘크리트가 팽창하여 균열을 초래하여 수명을 단축하며, 콘크리트가 경화되어 생기는 공극을 충분히 막아주지 못해 고강도, 방수성, 내구성이 요구되는 다양한 구조물의 사용에 충족치 못하여 콘크리트 건축물 특히, 도로에 사용시 강도도 저하되면서 손쉽게 파손되는 빈도가 높으며 나아가, 약품에 대한 내성도 약해져 산이나 알카리, 염, 물, 일광 등에 지속적으로 견디지 못하는 문제점과, In the conventional methods as described above, the bases of sea breeze, sea water, and calcium chloride for snow removal penetrate into the concrete with time, and the concrete is corroded. When the base is infiltrated with moisture, the concrete is inflated to cause crack, And it can not sufficiently cover the pores caused by curing of concrete. Thus, it can not satisfy the use of various structures requiring high strength, waterproofness and durability, so that the strength is easily broken due to a decrease in strength when used in concrete buildings, especially on roads. Furthermore, The resistance to chemicals is also weakened, so that it can not withstand acid, alkali, salt, water and sunlight continuously,

콘크리트구조물의 표면에 생성되는 실금은 기반의 평형에 관한 문제가 아니라 시멘트 배합이 잘못되었거나, 시공상에 혼합상의 문제로 혼합물이 균일하지 못한 관계로 시멘트 양생시에 실금이 형성되어 품질을 떨어뜨리거나, 누수로 인하여 구조물의 노후화 및 중성화를 초래하여 상품가치를 잃게 하는 문제점이 본 발명의 해결 과제인 것이다.
The incontinence generated on the surface of the concrete structure is not a problem about the foundation equilibrium but the cement mixture is wrong or the mixture is not uniform due to the mixing phase on the construction, , And the problem of causing the deterioration and neutralization of the structure due to the leakage and losing the value of the product is a problem of the present invention.

본 발명은 상기와 같은 문제점을 해결하기 위하여, 본 출원인이 선출원한 특허출원번호 제10-2004-0029049호 및 제10-2004-0075597호, 발명의 명칭;균열방지시공방법 및 그에 사용되는 조성물과 콘크리트 표면강화제를 개량한 것으로서, In order to solve the above-mentioned problems, the present invention provides a method for preventing cracks, a composition for use therein, and a method for preventing cracks, which are disclosed in Korean Patent Application Nos. 10-2004-0029049 and 10-2004-0075597 filed by the present applicant, As a concrete surface strengthening agent,

본 발명은 콘크리트분체 40중량%, 표면강화제 60중량%로 조성되며, 상기 콘크리트 분체는 포트랜드시멘트, 25kg, 알루미나시멘트 25kg, 탄산나트륨 5kg, 명반석 3kg, 규산계화합물 5kg로 혼합된 혼합물 40중량%와 규사(직경 0.1~0.2mm) 60중량%로 조성되고, 상기 표면강화제는 실란 70kg, 아크릴수지 80Kg, 유화제 5kg, 분산제 1kg 으로 조성되어 있음을 특징으로 하는 콘크리트 구조물의 미세균열보수제 조성물 및 그 시공방법을 제공하는 것이 본 발명이 이루고자 하는 기술적 과제인 것이다.
The present invention is characterized in that the concrete powder is composed of 40% by weight of a concrete powder and 60% by weight of a surface strengthening agent. The concrete powder is composed of 40% by weight of a mixture of Portland cement, 25 kg, 25 kg of alumina cement, 5 kg of sodium carbonate, Wherein the surface reinforcing agent is composed of 70 kg of silane, 80 kg of acrylic resin, 5 kg of emulsifier and 1 kg of a dispersing agent. The present invention is intended to solve the problems of the prior art.

상기와 같은 본 발명은 콘크리트 구조물의 미세균열 및 망상크랙을 제거하며, 콘크리트구조물의 표면 강도 저하부의 중성화, 강도증진, 열화방지등의 효과가 있으며, 더불어 콘크리트 중성화에 의한 탈리 방지, 콘크리트 열화부위 부착증대, 염해방지, 콘크리트 표면강도증대 및 마모성 증대의 효과가 있어 토목 및 건축 시공 및 보수분야 등에 다양하게 이용될 수 있는 장점이 있는 것이다.
The present invention as described above removes microcracks and network cracks in concrete structures and has effects such as neutralization, strength enhancement and deterioration prevention of the surface strength deterioration part of the concrete structure. In addition, it prevents deterioration by concrete neutralization, It is advantageous that it can be used variously in civil engineering, building construction and maintenance field because it has the effect of increasing the strength, preventing the salting, increasing the strength of the concrete surface and increasing the abrasion.

상기와 같은 목적을 달성하기 위하여, 본 발명은 포트랜드시멘트 25kg, 알루미나시멘트 25kg, 탄산나트륨 5kg, 명반석 3kg, 규산계화합물 5kg 로 혼합된 혼합물 40중량%와 규사 60중량%를 혼합하여 콘크리트 분체를 제조한 다음, 실란 70kg, 아크릴수지 80Kg, 유화제 5kg, 분산제 1kg 으로 조성된 표면강화제를 제조한 후,In order to achieve the above object, the present invention provides a method for producing a concrete powder by mixing 40 wt% of a mixture of 25 kg of Portland cement, 25 kg of alumina cement, 5 kg of sodium carbonate, 3 kg of alum, and 5 kg of a silicic acid compound and 60 wt% Next, a surface strengthening agent composed of 70 kg of silane, 80 kg of acrylic resin, 5 kg of emulsifier and 1 kg of dispersant was prepared,

상기에서 제조된 콘크리트분체 40중량%, 표면강화제 60중량%, 미세균열보수자재의 조성물을 제조한 다음,40% by weight of the concrete powder, 60% by weight of the surface strengthening agent, and microcrack repairing composition were prepared,

미세균열부를 10mm~20mm 'V'자 형상의 홈으로 커팅 한 다음, 잔재 및 이물질을 깨끗이 제거한 후에 V커팅부위에 콘크리트 구조물의 미세균열 보수제 조성물로 씰링 처리하고, 상기 콘크리트 구조물의 미세균열(망상크랙)보수제의 조성물에 물을 중량대비 1:2로 희석 시킨 다음 붓고, 로울러 및 분사기 중에서 선택된 어느 하나를 이용하여 미세 균열부에 도포(도포량 1kg/2㎟)한 다음, 1시간 경과 후, 건조시켜 미세균열(망상크랙)부의 표면을 강화하고 열화(화학부식)방지하는 콘크리트구조물의 미세균열 보수제 조성물 및 그 시공방법에 관한 것이다..The microcracked portion was cut into a groove having a shape of 10 mm to 20 mm and then the residue and foreign matter were cleanly removed and then the microcracking repair composition of the concrete structure was sealed with the V cutting portion to form microcracks ) Water was diluted 1: 2 by weight with respect to the composition of the filler, and then poured and applied to the micro-cracked portion (coating amount: 1 kg / 2 mm 2) using any one of a roller and an injector and then dried after 1 hour The present invention relates to a microcrack repairing composition for a concrete structure which strengthens the surface of a microcrack (network crack) portion and prevents deterioration (chemical corrosion), and a method of construction thereof.

본 발명의 콘크리트 구조물의 미세균열 보수제 조성물은 콘크리트분체 40중량%, 표면강화제 60중량%로 조성되며,The fine crack repairing composition of the concrete structure of the present invention is composed of 40% by weight of a concrete powder and 60% by weight of a surface strengthening agent,

콘크리트분체는 포트랜드시멘트 25kg, 알루미나시멘트 25kg, 탄산나트륨 5kg, 명반석 3kg, 규산계화합물 5kg 로 혼합된 혼합물 40중량%와 규사(직경 0.1~0.2mm) 60중량%로 조성되어 있으며, 콘크리트 균열보수제, 단면복구재, 신구콘크리트 접착재 등의 용도로 널리 사용하고 있다.The concrete powder is composed of 40 wt% mixture of 25 wt% of Portland cement, 25 kg of alumina cement, 5 kg of sodium carbonate, 3 kg of alum stone and 5 kg of silicic acid compound and 60 wt% of silica sand (diameter 0.1-0.2 mm) Recycled materials, and new and old concrete adhesives.

본 발명의 포트랜드시멘트나 알루미나시멘트는 무기접착제로 사용되며 알루미나시멘트는 팽창제 보조역할을 하며, 경제적이거나, 시멘트 특성상 포트랜트시멘트는 25kg, 알루미나시멘트는 25kg 사용하는 것이 적당하다.The Portland cement or alumina cement of the present invention is used as an inorganic adhesive, and the alumina cement plays an auxiliary role as an expansion agent, and it is economical or suitable to use 25 kg of the portland cement and 25 kg of the alumina cement.

본 발명에서 사용되는 탄산나트륨은 무수물은 백색 분말의 흡습성이 강하며, 5kg이 넘으면 비경제적이며, 5kg 미만이면 탄산나트륨의 특성이 저하되므로 5kg이 적당하다.
The anhydrous sodium carbonate used in the present invention is strong in the hygroscopicity of the white powder, and if it is more than 5 kg, it is not economical. If it is less than 5 kg, the properties of sodium carbonate are lowered.

본 발명의 명반석은 백반석이라고 하며, 육방결정계 광물로, 조각모양, 흙모양으로 백색, 투명에서 반투명 화산암에 화산성 가스의 황이 작용하거나 지하수속에 들어 있는 황산이 알루미나질 암석에 작용하여 생기며, 화학조성은 KAl3(OH)6(SO4)2 으로 팽창제 역할을 하며,The gabbrosite of the present invention is referred to as Baikolseok, and is a hexagonal system minerals. Sulfuric acid in the groundwater acts on the alumina rocks. The sulfuric acid acts on the volcanic rocks in translucent volcanic rocks, The composition is KAl 3 (OH) 6 (SO 4 ) 2 , which acts as a swelling agent,

전체총량 대비 3kg이 넘으면 방수기능이 저하되고, 3kg보다 적으면 증발속도와 용해도가 부족하여 시공시 문제점이 발생하고,If the total amount is more than 3 kg, the waterproof function is deteriorated. If it is less than 3 kg, the evaporation rate and solubility are insufficient,

본 발명의 규산계 화합물은 소듐실리케이트, 포타슘실리케이트,리듐실리케이트,칼슘실리케이트 중에서 선택된 어느 하나의 화합물을 사용하며, 콘크리트 도로의 균열 및 파손된 곳에 깊게 침투하도록 사용하였고, 너무 많으면 규산계화합물의 특성이 강하고 비경제적이며, 너무 적으면 성능이 저하되어 5 kg이 바람직하다.The silicate-based compound of the present invention uses any one compound selected from sodium silicate, potassium silicate, lithium silicate and calcium silicate, and is used to penetrate deeply into cracks and broken parts of the concrete road. It is strong and uneconomical, and if it is too small, the performance deteriorates and 5 kg is preferable.

본 발명의 규사는 직경의 크기가 0.1~0.2mm 이며, 경화제 역할을 하도록 하며 너무 많으면 경화되고, 너무 적으면 연화되므로 전체 중량대비 60중량%가 적당하다.The silica sand according to the present invention has a diameter of 0.1 to 0.2 mm and serves as a curing agent. When it is too large, it is hardened. When it is too small, it is softened.

본 발명의 표면강화제는 실란 70kg, 아크릴수지 80Kg, 유화제 5kg, 분산제 1kg 으로 조성되어 있으며, 실란은 내충격과 내마모성을 높이는 기능을 하며, 아크릴 수지는 침투성과 방수성을 증진시키는 역할을 하며, 계면활성제는 무기물과 유기물을 혼합시키는 역할을 하기 위하여 사용되는 것이다.
The surface strengthening agent of the present invention is composed of 70 kg of silane, 80 kg of acrylic resin, 5 kg of emulsifier and 1 kg of dispersant. The silane serves to enhance impact resistance and abrasion resistance, acrylic resin enhances permeability and water resistance, It is used to mix minerals and organic matter.

실란이란 수소화 규소 SinH₂n

Figure 112014044681990-pat00001
₂의 총칭. 단순히 실란이라 할 때는 n = 1의 화합물 SiH₄를 지칭한다. n = 2, 3 등의 화합물은 디실란, 트리실란 등이라 한다. SiH₄의 수소원자가 탄화수소기 등으로 치환한 유기 화합물을 총칭할 때도 실란이란 명칭이 사용된다. 어느 것이나 공기 중에서는 자연 발화하지만 공기를 차단하고 보존하면 상온에서도 안정하다. 대응하는 파라핀계 탄화수소에 비해서 뚜렷하게 불안정하여, 물수산화 알칼리 용액 등과 반응하거나 열분해를 받기 쉽다. 보통은 마그네슘의 분말과 규사의 고운 분말의 혼합물에 점화하여 생기는 규소화 마그네슘 Mg₂Si를 산으로 분해시키면 수소와 함께 혼합물이 생긴다. 수소를 알킬기할로겐수산기 등으로 치환한 유도체를 만들며, 유기 규소화합물의 모체로서 매우 중요하다. 극히 유독하다. SiH₄는 특이한 냄새가 나는 무색 기체로, 녹는점 -184.7℃, 끓는점 -112℃이다. 공기 중에서는 자연 발화한다. 수산화 알칼리 용액과 작용하여 수소를 발생하고 규산알칼리가 된다. 가열하면 분해하여 수소와 규소가 된다. 상온에서는 안정하다.[네이버 지식백과] 실란(실레인) [silane] (화학용어사전, 2011.1.15, 일진사)
Silane is a silicon hydride < RTI ID = 0.0 &
Figure 112014044681990-pat00001
₂ collectively. When silane is simply referred to, the compound SiH4 is n = 1. The compound of n = 2, 3, etc. is called disilane, trisilane and the like. The term silane is also used when organic compounds in which hydrogen atoms of SiH4 are substituted with hydrocarbon groups or the like. All are spontaneously ignited in the air, but they are stable at room temperature if air is blocked and preserved. Is significantly unstable as compared with the corresponding paraffinic hydrocarbons, and is liable to react with water, an alkali hydroxide solution or the like or to undergo thermal decomposition. Normally, decomposition of magnesium silicate Mg2Si, which is produced by ignition of a mixture of magnesium powder and silica powder, with an acid results in a mixture with hydrogen. Hydrogen is substituted with an alkyl group halogen hydroxyl group, etc., and a derivative is very important as a host of an organosilicon compound. It is extremely toxic. SiH4 is a colorless gas with a characteristic odor, melting point -184.7 ℃, boiling point -112 ℃. It spontaneously ignites in the air. It reacts with an alkali hydroxide solution to generate hydrogen and become alkali silicate. When heated, it decomposes to hydrogen and silicon. Silane (Silane) (Chemical Dictionary, January 15, 2011, Iljin History)

본 발명에서 사용되는 실란은 에틸트리에톡시실란, 에틸트리메톡시실란, 에틸트리-n-프로폭시실란, 프로필트리에톡시실란, 프로필트리디메틸아미노실란, 부틸트리에톡시실란, 부틸트리메톡시실란, 이소부틸에톡시실란, 이소부틸트리메톡시실란, 이소부틸트리아세톡시실란, n-헥실트리메톡시실란, 6-클로로트리에톡시실란, 사이클로헥실트리에톡시실란, 벤질트리에톡시실란, 페닐트리에톡시실란, 비닐트리에톡시실란, 페닐트리메톡시실란, 옥틸트리에톡시실란, 옥틸메틸디이소프로폭시실란, 라우릴트리메톡시실란, 2-에틸헥실트리메톡시실란, 데실트리에톡시실란, 도데실트리브로모실란, 테트라데실트리메톡시실란, 헥사데실트리에톡시실란, 옥타데실트리에톡시실란, 이들의 이량체와 삼량체 및 이들의 올리고머를 1종 이상 혼합하여 사용하며 사용량은 전체 중량대비 70kg 이 적당하다.
The silane used in the present invention may be at least one selected from the group consisting of ethyltriethoxysilane, ethyltrimethoxysilane, ethyltri-n-propoxysilane, propyltriethoxysilane, propyltrimethylaminosilane, butyltriethoxysilane, Silane, isobutylethoxysilane, isobutyltrimethoxysilane, isobutyltriacetoxysilane, n-hexyltrimethoxysilane, 6-chlorotriethoxysilane, cyclohexyltriethoxysilane, benzyltriethoxysilane , Phenyltriethoxysilane, vinyltriethoxysilane, phenyltrimethoxysilane, octyltriethoxysilane, octylmethyldiisopropoxysilane, lauryltrimethoxysilane, 2-ethylhexyltrimethoxysilane, decyl Triethoxysilane, dodecyltribromosilane, tetradecyltrimethoxysilane, hexadecyltriethoxysilane, octadecyltriethoxysilane, dimer and trimer thereof, and oligomers thereof may be used in combination, four The capacity is 70 kg of the total weight.

본 발명에서 사용되는 유화제는 유화역할과, 균열방지제를 안정한 상태로 장기간 보관하고 분산능력을 향상시켜 균일한배합과 작업성을 좋게한다.The emulsifier used in the present invention acts as an emulsifying agent and keeps the anti-cracking agent in a stable state for a long period of time and improves the dispersing ability to improve uniform mixing and workability.

라우릴에테르에틸렌옥시드 부가물, 세틸에테르에틸렌옥시드 부가물, 스테아릴에테르에틸렌옥시드 부가물, 올레일에테르에틸렌옥시드 부가물, 옥틸페닐에테르에틸렌옥시드 부가물, 노닐페닐에테르에틸렌옥시드 부가물, 솔비탄모노라우레이트, 솔비탄모노팔미테이트, 솔비탄모노스테아레이트, 솔비탄트리스테아레이트, 솔비탄모노올레이트, 솔비탄트리올레이트, 솔비탄세스퀴올레이트, 솔비탄디스테아레이트, 솔비탄모노라우레이트에틸렌옥시드 부가물, 솔비탄모노팔미테이트에틸렌옥시드 부가물, 솔비탄모노스테아레이트에틸렌옥시드 부가물, 솔비탄트리스테아레이트에틸렌옥시드 부가물,솔비탄모노올레이트에틸렌옥시드 부가물, 솔비탄트리올레이트에틸렌옥시드 부가물, 테트라올레인산폴리옥시에틸렌솔비톨, 글리세롤모노스테아레이트, 폴리에틸렌글리콜모노라우레이트, 폴리에틸렌글리콜모노스테아레이트, 폴리에틸렌글리콜디스테아레이트, 폴리에틸렌글리콜모노올레이트, 폴리에틸렌알킬아민, 피마자유에틸렌옥시드 부가물, 경화피마자유에틸렌옥시드 부가물 또는 이들을 폴리이소시아네이트 화합물로 축합한 축합물 등의 비이온계 계면활성제; 지방산염, 고급알콜의 황산에스테르염, 액체지방유의 황산에스테르염, 지방족아민 및 지방족아마이드의 황산염, 지방족알콜의 인산에스테르, 이염기성산성지방산에스테르의 술폰산염, 지방산아미드의 술폰산염, 알킬알릴술폰산, 포르말린축합나프탈린산염 등의 음이온계 계면활성제; 제1아민염, 제2아민염, 제3아민염, 제4급아민염, 피리디늄염 등의 양이온계 계면활성제; 베타인형, 황산에스테르형, 술폰산형 등의 양쪽성 계면활성제 등에서 선택된 어느 하나의 화합물을 들 수 있다.Lauryl ether ethylene oxide adduct, cetyl ether ethylene oxide adduct, stearyl ether ethylene oxide adduct, oleyl ether ethylene oxide adduct, octyl phenyl ether ethylene oxide adduct, nonyl phenyl ether ethylene oxide Adipic acid, adducts, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan tristearate, sorbitan monooleate, sorbitan trioleate, sorbitan sesquioleate, sorbitan distearate , Sorbitan monolaurate ethylene oxide adduct, sorbitan monopalmitate ethylene oxide adduct, sorbitan monostearate ethylene oxide adduct, sorbitan tristearate ethylene oxide adduct, sorbitan monooleate Ethylene oxide adducts, sorbitan trioleate ethylene oxide adducts, tetraoleic acid polyoxyethylene sorbitol, glycerol monostearate, Polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol distearate, polyethylene glycol monooleate, polyethylene alkylamine, castor oil ethylene oxide adduct, hydrogenated castor oil ethylene oxide adduct or a mixture thereof with a polyisocyanate compound Non-ionic surfactants such as condensed condensates; Sulfuric acid ester salts of liquid fatty acids, sulfuric acid salts of aliphatic amines and aliphatic amides, phosphoric acid esters of aliphatic alcohols, sulfonic acid salts of dibasic acidic fatty acid esters, sulfonic acid salts of fatty acid amides, alkylarylsulfonic acids, Anionic surfactants such as formalin condensed naphthalate; Cationic surfactants such as primary amine salts, secondary amine salts, tertiary amine salts, quaternary amine salts, and pyridinium salts; An amphoteric surfactant such as a betaine type, a sulfuric acid ester type, and a sulfonic acid type, and the like.

이들 유화제의 배합량은 너무 많거나 적으면, 유화제로서의 기능을 충분히 발휘 할 수 없고 물성의 변화가 우려되어, 5kg 사용하는 것이 바람직하다.
If the blending amount of these emulsifiers is too much or too small, the function as an emulsifier can not be sufficiently exhibited, and a change in physical properties is a concern, and it is preferable to use 5 kg.

본 발명에서 사용되는 아크릴수지는 메틸아크릴레이트, 에틸아크릴레이트, 이소부틸아크릴레이트, 메틸메타클릴레이트, 에틸메타크릴레이트, 아크릴로니트릴중에서 선택된 어느 하나의 화합물 80kg 사용하며,
The acrylic resin used in the present invention is 80 kg of a compound selected from the group consisting of methyl acrylate, ethyl acrylate, isobutyl acrylate, methyl methacrylate, ethyl methacrylate and acrylonitrile,

본 발명에서 사용되는 분산제는 고분자량의 축합 나프탈렌 술폰산 나트륨염, 나프탈렌 술폰산 칼슘염을 1kg 사용하는 것이다.
The dispersant used in the present invention is a high molecular weight condensed naphthalenesulfonic acid sodium salt or naphthalenesulfonic acid calcium salt of 1 kg.

물은 분사기 또는 도포기에 사용시 액상으로 하기 위하여 사용하며, 배합량이 적을 때에는 수분산물로서의 안정성을 유지할 수 없게 될 우려가있다. 또한, 물의 배합량의 상한에 관해서는 특히 제한되는 것은 아니지만 용도에 따라서는 이것을 희석하여 사용할 수가 있다
Water is used to make a liquid phase when used in an injector or applicator, and when the compounding amount is small, stability as a water dispersion product may not be maintained. The upper limit of the amount of water to be blended is not particularly limited, but it may be diluted depending on the application

본 발명을 실시예를 통하여 상세히 설명하면 다음과 같다.
Hereinafter, the present invention will be described in detail with reference to Examples.

실시예
Example

제1공정First step

포트랜드시멘트, 25kg, 알루미나시멘트 25kg, 탄산나트륨 5kg, 명반석 3kg, 규산계화합물로 소?실리게이트 5kg 로 혼합된 혼합물 40중량%와25 kg of Portland cement, 25 kg of alumina cement, 5 kg of sodium carbonate, 3 kg of alum stone and 40 kg of a mixture mixed with 5 kg of silicic acid-based compound

규사(직경 0.1~0.2mm) 60중량%를 혼합하여 콘크리트 분체를 제조한 다음,And 60 wt% of silica sand (diameter 0.1 to 0.2 mm) were mixed to prepare a concrete powder,

실란으로 에틸트리에톡시실란 70kg, 아크릴수지로 메틸메타클릴레이트 80Kg, 유화제로 솔비탄모노라우레이트 5kg, 분산제로 나프탈렌 술폰산 칼슘염을 1kg 으로 조성된 표면강화제를 제조한 후, 70 kg of ethyltriethoxysilane as a silane, 80 kg of methyl methacrylate as an acrylic resin, 5 kg of sorbitan monolaurate as an emulsifier, and 1 kg of a calcium salt of naphthalenesulfonic acid as a dispersant were prepared,

콘크리트분체 40kg, 표면강화제 60kg 을 혼합기에 교반기로 30분, 300RPM으로 교반시켜 조성된 콘크리트 구조물의 미세균열 보수제 조성물을 제조한 다음,
40 kg of the concrete powder and 60 kg of the surface strengthening agent were stirred in a mixer for 30 minutes at 300 RPM with a stirrer to prepare a micro crack repair composition of the concrete structure,

제2공정Second Step

미세균열부를 약 10mm~20mm'V'자 형상의 홈으로 커팅 한 다음, 잔재 및 이물질을 깨끗이 제거한 후에 V커팅부위에 콘크리트 구조물의 미세균열 보수제 조성물로 씰링 처리하고, 상기 콘크리트 구조물의 미세균열 보수제 조성물에 물을 중량대비 1:2로 희석 시킨 다음, 붓고, 로울러 분사기 중에서 선택된 어느 하나를 이용하여 미세 균열부에 도포(도포량 1kg/2㎟)한 다음, 1시간 경과 후, 건조시켜 건축물구조물의 미세균열(망상크랙)부의 표면을 강화하고 열화(화학부식)방지하며 시공하여 콘크리트 구조물의 미세균열(망상크랙)을 보수 시공을 하였다.
After the microcracks were cut into grooves having a shape of about 10 mm to 20 mm'V ', the residues and foreign substances were cleanly removed, and the microcracks were sealed with a microcracking repair composition of the concrete structure at the V-cutting site. (1 kg / 2 mm 2) was applied to the microcracked portion by using any one selected from the group consisting of water, water, diluted 1: 2 by weight and then poured and roller sprayer. It strengthened the surface of the crack (network crack) part and prevented the deterioration (chemical corrosion) and installed it to repair the micro crack (network crack) of the concrete structure.

상기 실시예와 같이 제조된 본 발명의 콘크리트 구조물의 미세균열 보수제 조성물은 콘크리트분체 40중량%, 표면강화제 60중량%로 조성되며,The microcrack repairing composition of the concrete structure of the present invention manufactured as in the above embodiment is composed of 40% by weight of a concrete powder and 60% by weight of a surface strengthening agent,

상기 콘크리트 분체는 포트랜드시멘트, 25kg, 알루미나시멘트 25kg, 탄산나트륨 5kg, 명반석 3kg, 소듐실리케이트, 포타슘실리케이트,리듐실리케이트,칼슘실리케이트 중에서 선택된 어느 하나의 화합물인 규산계화합물 5kg로 혼합된 혼합물 40중량%와 규사(직경 0.1~0.2mm) 60중량%로 조성되고,The concrete powder was mixed with 40 kg of a mixture of 5 kg of a silicate compound, which is a compound selected from Portland cement, 25 kg, 25 kg of alumina cement, 5 kg of sodium carbonate, 3 kg of alum, sodium silicate, potassium silicate, lithium silicate and calcium silicate, (Diameter 0.1 to 0.2 mm) of 60% by weight,

상기 표면강화제는 실란 70kg, 메틸아크릴레이트, 에틸아크릴레이트, 이소부틸아크릴레이트, 메틸메타클릴레이트, 에틸메타크릴레이트, 아크릴로니트릴중에서 선택된 어느 하나의 화합물인 아크릴수지 80Kg, 유화제 5kg, 분산제 1kg 으로 조성되어 있음을 알 수 있다.
The surface strengthening agent was prepared by mixing 70 kg of silane, 80 kg of an acrylic resin which is one of compounds selected from methyl acrylate, ethyl acrylate, isobutyl acrylate, methyl methacrylate, ethyl methacrylate and acrylonitrile, 5 kg of an emulsifier, As shown in FIG.

실험예 1
Experimental Example 1

실시예와 같이 콘크리트구조물의 미세균열 보수제 조성물로 시공된 콘크리트구조물을 한국화학시험연구원에서 실험하였으며, 실험결과는 표1 및 표2와 같다.
As shown in Table 1 and Table 2, the concrete structure constructed with the micro crack repair composition of the concrete structure was tested by the Korea Research Institute of Chemical Technology.

업 체 명 : 한일피엔티(주)Company name: Hanil Pienti Co., Ltd.

주 소 : 충북 옥천군 군북면 증약리 420-5번지Address: 420-5, Sujeong-ri, Kunbuk-myeon, Okcheon-gun, Chungbuk

시험결과 Test result 시험항목Test Items 단위unit 시료구분Sample classification 결과치Results 시험방법Test Methods 부착강도Bond strength N/㎟N / mm < 2 & 7272 KS F 4916 : 2004 KS F 4916: 2004 인장강도(28일)Tensile strength (28 days) N/㎟N / mm < 2 & 2.42.4 KS L 5104 : 2006 KS L 5104: 2006 길이변화율Length change rate %% 0.0050.005 KS F 4916 : 1999 KS F 4916: 1999 흡수율Absorption rate %% 44 KS F 4916 : 2004 KS F 4916: 2004 내충격성Impact resistance -- 이상없음 clear KS F 4716 : 2001 KS F 4716: 2001 내알카리성My alkalinity -- 이상없음 clear KS L 1001 : 2003 KS L 1001: 2003

배합표(kg)Formulation (kg)

물 : 시멘트 : 모래 : HP200Water: Cement: Sand: HP200

w/c=42% : 1 : 3 : C

Figure 112014044681990-pat00002
10%
w / c = 42%: 1: 3: C
Figure 112014044681990-pat00002
10%

성적서번호 : TAS-011690 접수 일자 :2014년 02월 20일Certificate Number: TAS-011690 Received on: February 20, 2014

대 표 자 : 김정애 시험완료일자:2014년 03월 14일Key words: Kim Jae Ae test completion date: March 14, 2014

업 체 명 : 한일피엔티(주)Company name: Hanil Pienti Co., Ltd.

주 소 : 충북 옥천군 군북면 증약리 420-5번지Address: 420-5, Sujeong-ri, Kunbuk-myeon, Okcheon-gun, Chungbuk

시험결과 Test result 시험항목Test Items 단위unit 시료구분Sample classification 결과치Results 시험방법Test Methods 응결시간(초결)Condensation time (seconds) minute -- 77 KS F 5108 : 2007 KS F 5108: 2007 응결시간(종결)Condensation time (Closing) minute -- 1010 KS F 5108 : 2007 KS F 5108: 2007 압축강도(2시간)Compressive strength (2 hours) N/㎟N / mm < 2 & -- 16.616.6 KS F 4042 : 2012 KS F 4042: 2012 압축강도(4시간)Compressive strength (4 hours) N/㎟N / mm < 2 & -- 18.918.9 KS F 4042 : 2012 KS F 4042: 2012 압축강도(24시간)Compressive strength (24 hours) N/㎟N / mm < 2 & -- 22.222.2 KS F 4042 : 2012 KS F 4042: 2012 압축강도(3일)Compressive strength (3 days) N/㎟N / mm < 2 & -- 40.240.2 KS F 4042 : 2012 KS F 4042: 2012 부착강도(3일)Bond strength (3 days) N/㎟N / mm < 2 & -- 1.81.8 KS F 4042 : 2012 KS F 4042: 2012

상기와 같이 실험결과에 따라, 본 발명은 침투성, 내흡수성, 내투수성 등이 KS 표준규격 시험 기준치에 합격하는 것을 나타내고 있다.
According to the results of the experiment as described above, the present invention shows that the permeability, the water absorption property, the water permeability and the like pass the KS standard specification test standard.

Claims (4)

콘크리트구조물의 미세균열 보수제 조성물에 있어서,
콘크리트분체 40중량%와, 표면강화제 60중량%로 조성되며,
상기 콘크리트 분체는 포트랜드시멘트 25kg, 알루미나시멘트 25kg, 탄산나트륨 5kg, 명반석 3kg, 소듐실리케이트, 포타슘실리케이트,리듐실리케이트,칼슘실리케이트 중에서 선택된 어느 하나의 화합물인 규산계화합물 5kg로 혼합된 혼합물 40중량%와 규사 60중량%로 조성되고,
상기 표면강화제는 실란 70kg, 메틸아크릴레이트, 에틸아크릴레이트, 이소부틸아크릴레이트, 메틸메타클릴레이트, 에틸메타크릴레이트, 아크릴로니트릴중에서 선택된 어느 하나의 화합물인 아크릴수지 80Kg, 유화제 5kg, 분산제 1kg 으로 조성되어 있음을 특징으로 하는 콘크리트 구조물의 미세균열보수제 조성물.
In a micro crack repair composition of a concrete structure,
40% by weight of a concrete powder and 60% by weight of a surface strengthening agent,
The concrete powder is Portland cement 25kg, alumina cement, 25kg, sodium carbonate 5kg, myeongbanseok 3kg, sodium silicate, potassium silicate, lithium silicate, any of the compounds of silicate-based a mixture of 40% by weight of silica mixed in the compound 5kg selected from the group consisting of calcium silicate, 60 % & Lt; / RTI >
The surface strengthening agent was prepared by mixing 70 kg of silane, 80 kg of an acrylic resin which is one of compounds selected from methyl acrylate, ethyl acrylate, isobutyl acrylate, methyl methacrylate, ethyl methacrylate and acrylonitrile, 5 kg of an emulsifier, Wherein the microcrack-repairing composition of claim 1,
청구항 1에 있어서, 상기 실란은 에틸트리에톡시실란, 에틸트리메톡시실란, 에틸트리-n-프로폭시실란, 프로필트리에톡시실란, 프로필트리디메틸아미노실란, 부틸트리에톡시실란, 부틸트리메톡시실란, 이소부틸에톡시실란, 이소부틸트리메톡시실란, 이소부틸트리아세톡시실란, n-헥실트리메톡시실란, 6-클로로트리에톡시실란, 사이클로헥실트리에톡시실란, 벤질트리에톡시실란, 페닐트리에톡시실란, 비닐트리에톡시실란, 페닐트리메톡시실란, 옥틸트리에톡시실란, 옥틸메틸디이소프로폭시실란, 라우릴트리메톡시실란, 2-에틸헥실트리메톡시실란, 데실트리에톡시실란, 도데실트리브로모실란, 테트라데실트리메톡시실란, 헥사데실트리에톡시실란, 옥타데실트리에톡시실란, 이들의 이량체와 삼량체 및 이들의 올리고머를 1종 이상 혼합하여 사용함을 특징으로 하는 미세균열보수제 조성물.
[3] The method of claim 1, wherein the silane is selected from the group consisting of ethyltriethoxysilane, ethyltrimethoxysilane, ethyltri-n-propoxysilane, propyltriethoxysilane, propyltrimethylaminosilane, butyltriethoxysilane, Hexyltrimethoxysilane, isobutyltrimethoxysilane, isobutyltrimethoxysilane, isobutyltriethoxysilane, n-hexyltrimethoxysilane, 6-chlorotriethoxysilane, cyclohexyltriethoxysilane, benzyltriethoxy Silane, phenyltriethoxysilane, vinyltriethoxysilane, phenyltrimethoxysilane, octyltriethoxysilane, octylmethyldiisopropoxysilane, lauryltrimethoxysilane, 2-ethylhexyltrimethoxysilane, Decyltriethoxysilane, dodecyltribromosilane, tetradecyltrimethoxysilane, hexadecyltriethoxysilane, octadecyltriethoxysilane, dimer and trimer thereof, and oligomers thereof may be used in combination. To Wherein the fine crack repairing composition is a micro crack repairing composition.
삭제delete 콘크리트구조물의 미세균열 보수 시공방법에 있어서,
포트랜드시멘트 25kg, 알루미나시멘트 25kg, 탄산나트륨 5kg, 명반석 3kg, 규산계화합물 5kg 로 혼합된 혼합물 40중량%와 규사 60중량%를 혼합하여 콘크리트 분체를 제조한 다음,
실란 70kg, 아크릴수지 80Kg, 유화제 5kg, 분산제 1kg 으로 조성된 표면강화제를 제조한 후,
상기에서 제조된 콘크리트분체 40중량%, 표면강화제 60중량%, 미세균열보수제의 조성물을 제조한 다음,
미세균열부를 10mm~20mm 'V'자 형상의 홈으로 커팅 한 다음, 잔재 및 이물질을 깨끗이 제거한 후에 V커팅부위에 콘크리트 구조물의 미세균열 보수제 조성물로 씰링 처리하고, 상기 콘크리트 구조물의 미세균열보수제의 조성물에 물을 중량대비 1:2로 희석 시킨 다음, 붓고, 로울러 또는 분사기 중에서 선택된 어느 하나로 균열부에 분사하여 도포(도포량 1kg/2㎟)한 다음, 1시간 경과후, 건조시켜 미세균열부의 표면을 강화하고 열화를 방지하며 시공함을 특징으로 하는 콘크리트구조물의 미세균열 보수 시공방법.
A method of repairing and installing fine cracks in a concrete structure,
40 wt% of a mixture of 25 kg of Portland cement, 25 kg of alumina cement, 5 kg of sodium carbonate, 3 kg of alum, and 5 kg of a silicic acid compound was mixed with 60 wt% of silica sand to prepare a concrete powder,
70 kg of silane, 80 kg of acrylic resin, 5 kg of emulsifier and 1 kg of dispersant were prepared,
A composition of 40 wt% of the concrete powder, 60 wt% of the surface strengthening agent, and microcrack repairing agent was prepared,
The microcracked portion was cut into a groove having a shape of 10 mm to 20 mm and then the residue and foreign matter were cleanly removed and then the microcracking repair composition of the concrete structure was sealed with the V cut portion to form the microcrack repairing composition of the concrete structure (1 kg / 2 mm 2) was sprayed onto the cracked portion by any one of pouring, roller or spraying, and then dried after 1 hour to remove the surface of the microcracked portion Reinforcing and preventing deterioration of the concrete structure.
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KR20200105577A (en) 2019-02-28 2020-09-08 김윤아 Mortar composition using cement mixture and constructing method using it
KR20200105575A (en) 2019-02-28 2020-09-08 김윤아 Slip-resistant non-slip composition using cement mixture and slip-resistant construction method using it
KR20200117102A (en) 2019-04-02 2020-10-14 김윤아 Cement composition for section repair and construction method using it
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KR100601882B1 (en) 2005-09-30 2006-07-19 김용석 The concrete surface reinforcement and protect from burning construetion methodthereof
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Cited By (8)

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Publication number Priority date Publication date Assignee Title
CN108751919A (en) * 2018-07-26 2018-11-06 湖南峰航新材料科技有限公司 A kind of concrete fine fisssure patching material and the preparation method and application thereof
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KR20200105577A (en) 2019-02-28 2020-09-08 김윤아 Mortar composition using cement mixture and constructing method using it
KR20200105575A (en) 2019-02-28 2020-09-08 김윤아 Slip-resistant non-slip composition using cement mixture and slip-resistant construction method using it
KR20200117102A (en) 2019-04-02 2020-10-14 김윤아 Cement composition for section repair and construction method using it
KR102119460B1 (en) 2020-05-06 2020-06-08 주식회사 이레하이테크이앤씨 Injection composition for filling cracks of road pavement and repairing method for crack of road pavement using the same
CN111848063A (en) * 2020-07-10 2020-10-30 黑龙江泽林科技有限公司 High belite sulphoaluminate cement-based hardener for concrete ground and preparation method thereof
CN111848063B (en) * 2020-07-10 2022-03-04 黑龙江泽林科技有限公司 High belite sulphoaluminate cement-based hardener for concrete ground and preparation method thereof

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