KR101412377B1 - 파라자일렌의 정제 방법 - Google Patents

파라자일렌의 정제 방법 Download PDF

Info

Publication number
KR101412377B1
KR101412377B1 KR1020117026968A KR20117026968A KR101412377B1 KR 101412377 B1 KR101412377 B1 KR 101412377B1 KR 1020117026968 A KR1020117026968 A KR 1020117026968A KR 20117026968 A KR20117026968 A KR 20117026968A KR 101412377 B1 KR101412377 B1 KR 101412377B1
Authority
KR
South Korea
Prior art keywords
catalyst
xylene
para
oxide
crystallization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020117026968A
Other languages
English (en)
Korean (ko)
Other versions
KR20120019445A (ko
Inventor
마크 폴 하게마이스터
데이비드 리 존슨
존 조셉 몬슨
Original Assignee
엑손모빌 케미칼 패턴츠 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엑손모빌 케미칼 패턴츠 인코포레이티드 filed Critical 엑손모빌 케미칼 패턴츠 인코포레이티드
Publication of KR20120019445A publication Critical patent/KR20120019445A/ko
Application granted granted Critical
Publication of KR101412377B1 publication Critical patent/KR101412377B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/14—Purification; Separation; Use of additives by crystallisation; Purification or separation of the crystals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020117026968A 2009-04-14 2010-04-08 파라자일렌의 정제 방법 Expired - Fee Related KR101412377B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16907009P 2009-04-14 2009-04-14
US61/169,070 2009-04-14
PCT/US2010/030318 WO2010120616A2 (en) 2009-04-14 2010-04-08 Process for the purification of paraxylene

Publications (2)

Publication Number Publication Date
KR20120019445A KR20120019445A (ko) 2012-03-06
KR101412377B1 true KR101412377B1 (ko) 2014-06-25

Family

ID=42934905

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020117026968A Expired - Fee Related KR101412377B1 (ko) 2009-04-14 2010-04-08 파라자일렌의 정제 방법

Country Status (8)

Country Link
US (3) US8252967B2 (enExample)
JP (3) JP5470448B2 (enExample)
KR (1) KR101412377B1 (enExample)
CN (1) CN102395544B (enExample)
MY (1) MY156267A (enExample)
SG (1) SG174872A1 (enExample)
TW (1) TWI421231B (enExample)
WO (1) WO2010120616A2 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8252967B2 (en) * 2009-04-14 2012-08-28 Exxonmobil Chemical Patents Inc. Process for the purification of paraxylene
WO2012170336A2 (en) * 2011-06-10 2012-12-13 Exxonmobil Chemical Patents Inc. Production of para-xylene
CN103619786B (zh) * 2011-07-11 2016-06-01 埃克森美孚化学专利公司 苯和/或甲苯与甲醇的烷基化
US9006506B2 (en) * 2011-10-07 2015-04-14 Exxonmobil Chemical Patents Inc. Alkylation process
AU2012357512C1 (en) * 2011-12-19 2016-04-21 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Catalyst for preparing paraxylene by mutual conversion of methyl alcohol and/or dimethyl ether and C4 liquefied gas, and preparation method and application therefor
US9012711B2 (en) * 2012-05-31 2015-04-21 Exxonmobil Chemical Patents Inc. Phenol removal in paraxylene recovery process
KR20150006863A (ko) 2012-05-31 2015-01-19 엑손모빌 케미칼 패턴츠 인코포레이티드 파라크실렌 회수 공정에서의 스티렌 제거
US9193645B2 (en) 2012-08-31 2015-11-24 Exxonmobil Chemical Patents Inc. Xylene isomerization process and catalyst therefor
CN103664492A (zh) * 2012-09-05 2014-03-26 中国石油化工股份有限公司 甲苯甲醇烷基化方法
CN103664488B (zh) * 2012-09-05 2015-09-09 中国石油化工股份有限公司 脱除含氧化合物杂质的芳烃甲醇烷基化方法
KR102168050B1 (ko) 2013-03-15 2020-10-20 비피 코포레이션 노쓰 아메리카 인코포레이티드 자일렌 이성질체를 함유하는 둘 이상의 공급물 스트림으로부터의 파라자일렌의 회수 방법
US20140296598A1 (en) * 2013-04-01 2014-10-02 Exxonmobil Chemical Patents Inc. Purification of Aromatic Hydrocarbon Streams
US9422208B2 (en) 2013-05-07 2016-08-23 Exxonmobil Chemical Patents Inc. Treatment of aromatic hydrocarbon stream
US9598332B2 (en) * 2013-12-20 2017-03-21 Exxonmobil Chemical Patents Inc. Production of para-xylene
US10011538B2 (en) 2014-10-27 2018-07-03 Exxonmobil Chemical Patents Inc. Method of making aromatic hydrocarbons
JP6726768B2 (ja) 2016-06-10 2020-07-22 エクソンモービル リサーチ アンド エンジニアリング カンパニーＥｘｘｏｎ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｅｎｇｉｎｅｅｒｉｎｇ Ｃｏｍｐａｎｙ オルガノシリカポリマー触媒およびその製造方法
US10519082B2 (en) 2016-12-20 2019-12-31 Uop Llc Removal of feed treatment units in aromatics complex designs
JP2021506909A (ja) 2017-12-22 2021-02-22 エクソンモービル・ケミカル・パテンツ・インク ベンゼンおよび／またはトルエンのメチル化によるパラキシレンの製造用触媒
CN108359082A (zh) * 2018-01-23 2018-08-03 浙江省现代纺织工业研究院 一种复合改性对二甲苯的制备方法
US11053176B2 (en) 2018-03-30 2021-07-06 Exxonmobil Chemical Patents Inc. Process for co-production of mixed xylenes and high octane C9+ aromatics

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001524069A (ja) * 1996-10-02 2001-11-27 モービル・オイル・コーポレーション トルエンのメチル化によるパラ―キシレンの選択的製造

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3462508A (en) 1967-05-22 1969-08-19 Sinclair Research Inc Separation of p-xylene from a c8 aromatic hydrocarbon mixture by crystallization
US3558730A (en) 1968-06-24 1971-01-26 Universal Oil Prod Co Aromatic hydrocarbon separation by adsorption
JPS5920648B1 (enExample) * 1968-06-24 1984-05-15 Uop Inc
US3643453A (en) 1968-12-26 1972-02-22 Shell Oil Co Selective crystallization of paraxylene in a water-alkanol mixture
US3662013A (en) 1970-02-03 1972-05-09 Mobil Oil Corp Single stage crystallization process for separating high purity paraxylene
US3686343A (en) 1970-10-01 1972-08-22 Exxon Research Engineering Co Paraxylene recovery with zeolite adsorbent
CA976092A (en) 1971-07-02 1975-10-14 Chevron Research And Technology Company Method of concentrating a slurry containing a solid particulate component
US4002698A (en) 1975-08-19 1977-01-11 Mobil Oil Corporation Methylation of toluene in the presence of a phosphorus-modified activated crystalline aluminosilicate catalyst
NZ178543A (en) * 1974-09-23 1978-04-03 Mobil Oil Corp Conversion catalyst, crystalline alumin osilicate zeolite containing phosphorus
US4029716A (en) 1975-12-08 1977-06-14 Mobil Oil Corporation Selective production of para-xylene
JPS54106435A (en) * 1978-02-08 1979-08-21 Mitsui Petrochem Ind Ltd Preparation of mixed xylene isomers
US4356338A (en) 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4423266A (en) 1980-10-08 1983-12-27 Mobil Oil Corporation Extending isomerization catalyst life by treating with phosphorous and/or steam
US5476823A (en) 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
US5939597A (en) 1994-11-10 1999-08-17 Mobil Oil Corporation Fluid bed process for para-xylene production
FR2728893A1 (fr) * 1994-12-29 1996-07-05 Inst Francais Du Petrole Procede de separation de paraxylene comportant au moins un etage de cristallisation a haute temperature et au moins un traitement a la terre situe en amont de la zone d'adsorption
FR2729660A1 (fr) 1995-01-20 1996-07-26 Inst Francais Du Petrole Procede de production de paraxylene comportant une cristallisation a haute temperature a au moins un etage et une fusion partielle des cristaux
FR2739097B1 (fr) 1995-09-22 1997-12-19 Rattheon Engineers & Construct Procede de purification de paraxylene par cristallisation fractionnee
US5804690A (en) 1995-12-14 1998-09-08 Mobil Oil Corporation Selective monomethylation of aromatics with dimethylcarbonate
US6048816A (en) 1996-10-02 2000-04-11 Mobil Oil Corporation Catalyst and process for converting methanol to hydrocarbons
US6538167B1 (en) 1996-10-02 2003-03-25 Exxonmobil Chemical Patents Inc. Process for producing light olefins
US6046372A (en) 1996-10-02 2000-04-04 Mobil Oil Corporation Process for producing light olefins
US6423879B1 (en) 1997-10-02 2002-07-23 Exxonmobil Oil Corporation Selective para-xylene production by toluene methylation
US6028238A (en) 1998-04-14 2000-02-22 Mobil Oil Corporation Xylene isomerization
US6642426B1 (en) 1998-10-05 2003-11-04 David L. Johnson Fluid-bed aromatics alkylation with staged injection of alkylating agents
US6156949A (en) 1998-12-28 2000-12-05 Mobil Oil Corporation Selective pseudocumene production by xylene methylation
US6388156B1 (en) 1999-05-14 2002-05-14 Exxonmobil Chemical Patents Inc. Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2
US6506954B1 (en) 2000-04-11 2003-01-14 Exxon Mobil Chemical Patents, Inc. Process for producing chemicals from oxygenate
TWI240716B (en) * 2000-07-10 2005-10-01 Bp Corp North America Inc Pressure swing adsorption process for separating paraxylene and ethylbenzene from mixed C8 aromatics
GB0303659D0 (en) 2003-02-18 2003-03-19 Johnson Matthey Plc Process
WO2007127049A2 (en) 2006-04-25 2007-11-08 Exxonmobil Chemical Patents Inc. Process for producing para-xylene
JP5463281B2 (ja) 2007-04-04 2014-04-09 エクソンモービル・ケミカル・パテンツ・インク パラキシレン製造プロセス及び装置
US8252967B2 (en) * 2009-04-14 2012-08-28 Exxonmobil Chemical Patents Inc. Process for the purification of paraxylene

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001524069A (ja) * 1996-10-02 2001-11-27 モービル・オイル・コーポレーション トルエンのメチル化によるパラ―キシレンの選択的製造

Also Published As

Publication number Publication date
JP5470448B2 (ja) 2014-04-16
JP2014031376A (ja) 2014-02-20
SG174872A1 (en) 2011-11-28
JP2014132005A (ja) 2014-07-17
MY156267A (en) 2016-01-29
US8981171B2 (en) 2015-03-17
CN102395544A (zh) 2012-03-28
US8507744B2 (en) 2013-08-13
JP5803044B2 (ja) 2015-11-04
CN102395544B (zh) 2014-08-27
US20120296143A1 (en) 2012-11-22
WO2010120616A3 (en) 2011-01-13
KR20120019445A (ko) 2012-03-06
JP2012522810A (ja) 2012-09-27
JP5705285B2 (ja) 2015-04-22
WO2010120616A2 (en) 2010-10-21
US20100261941A1 (en) 2010-10-14
US20130237737A1 (en) 2013-09-12
US8252967B2 (en) 2012-08-28
TW201107271A (en) 2011-03-01
TWI421231B (zh) 2014-01-01

Similar Documents

Publication Publication Date Title
JP5705285B2 (ja) パラキシレンの精製方法
US9295962B2 (en) Production of para-xylene
TWI483933B (zh) 於對二甲苯回收製程中除去苯乙烯之方法
KR102120885B1 (ko) 톨루엔 및/또는 벤젠의 메틸화에 의한 파라-자일렌의 제조에서의 오프 가스의 처리
WO2011049765A2 (en) Production of para-xylene by the methylation of benzene and/or toluene
WO2014058609A1 (en) Recovery of olefins from para-xylene process
US20130217940A1 (en) Alkylation of Benzene and/or Toluene with Methanol
CN111406042B (zh) 用于芳族烷基化的系统和方法
CN109906213A (zh) 轻质气体副产物在通过甲苯和/或苯的甲基化制备对二甲苯中的用途
JPH0138535B2 (enExample)

Legal Events

Date Code Title Description
A201 Request for examination
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20170330

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20180329

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

FPAY Annual fee payment

Payment date: 20190327

Year of fee payment: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20210620

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20210620