KR101403468B1 - Resin composition for coating fabrics and coated fabrics using the same - Google Patents

Abstract

In the present invention, the amount of the acrylic emulsion resin relative to 100 parts by weight of the solid content; 1 to 10 parts by weight of an isocyanate-based crosslinking agent; And 5 to 30 parts by weight of a silicone emulsion resin on a solid basis, and a fabric surface-treated with the resin composition.
The fabric to which the resin composition of the present invention is applied is soft, thin, foldable in a small volume, and is suitable for a fabric for easy-to-wear sportswear excellent in dry-cleaning property and washing durability.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a resin composition for fabric coating and a fabric obtained by surface-

More particularly, the present invention relates to a resin composition for fabric coating, and more particularly, to a fabric comprising a silicone emulsion resin and an acrylic emulsion resin, wherein the fabric is coated with a thin film on a fabric such as a fabric or a knitted fabric, The present invention relates to a resin composition for fabric coating, which can improve dry-cleaning properties, washing durability, and the like while maintaining the puddle property, and a fabric surface-treated using the same.

In addition to the advancement of the industry, the spread of the five-day workweek system and the well-being boom have greatly changed the pattern of life, resulting in an increase in leisure time, the liberalization of dress at work, the spread of social atmosphere such as yoga, As sport becomes everyday, the tendency to enjoy sports as a hobby, rather than as a training, is increasing. As a result, there is a demand for sportswear with added functionality and fashion from these consumers. A new casual sportswear (canvas) market is in the growth stage.

As a result of social activities in various fields of new casual wear and diversified fields, there is a tendency to prefer active casual wear rather than existing suit style. In order to meet these consumers' needs, It is necessary to express the emotion for improving the sex and the elasticity for improving the activity.

As the skin of the human body is constantly active in everyday life and repeatedly relaxed and contracted, the clothing that comes into contact with the skin in order to improve the comfort of wearing and activity is also required to be elastic like skin, It is necessary to use a stretchable material having excellent elongation recovery property.

Since the elastic material can be restored to its original shape due to adhesion and expansion, it is possible to give comfort and better activity to the wearer. Recently, attention has been paid to elastic materials, and accordingly, Is required.

The trend of developing and commercializing the clothing for this kind of clothing is to enhance the activity through the `elasticity` of the material to the basic functionality of the product, to satisfy the consumers' sensitivity through `comfort`, and to improve the comfort and ease of handling by adding ` Various developments have been made with focus.

Accordingly, knit materials, which have been attracted by unique elasticity and softness, have been applied to sports apparel. However, the knitted material has limitations in the windproof performance and the breathable waterproof performance, which are basic functions of sportswear and the like, so that various products have not been developed.

Film laminating is one of the processing methods for imparting windproofness, moisture permeability and waterproofness in order to diversify products of stretchable materials. However, the film lamination is excellent in the waterproof property and the windproof property of the manufactured products, But also various problems such as peeling and brittleness of the membrane to be used.

As a result, by applying ultra-thin coating technology using environmentally friendly resin that can exhibit balanced wind and air permeability while maintaining the inherent stretchability of the stretchable material, the problem of air permeability that can not be solved in film laminating processing, It is possible to solve all of the problems and provide various functionalities depending on the use of the functional processing agent to be added to the coating liquid, thereby making a great contribution to the creation of added value.

It is an object of the present invention to provide an acrylic emulsion resin and a silicone emulsion resin which can improve dry-cleaning and durability while maintaining air permeability, wind-resistance and down- To provide a resin composition for fabric coating.

Another object of the present invention is to provide a fabric that is surface-treated with the resin composition.

In order to accomplish the above object, the present invention provides a resin composition for coating a fabric, comprising: 100 parts by weight of a solid component of an acrylic emulsion resin; 1 to 10 parts by weight of an isocyanate-based crosslinking agent; And 5 to 30 parts by weight, based on solids, of the silicone emulsion resin.

Wherein the acrylic emulsion resin is selected from the group consisting of alkyl (meth) acrylates having C1 to C10 alkyl groups or alkoxyalkyl groups; It is preferable that it is a water dispersion containing a copolymer with a functional acrylic derivative in a solid content of 10 to 70% by weight.

The copolymer is particularly preferably a copolymer of alkyl (meth) acrylate, acrylonitrile and acrylic acid.

The isocyanate-based crosslinking agent is preferably blocked isocyanate.

The silicone emulsion resin is a silicone emulsion resin in which a silicon atom of a siloxane (-SiO-) which is a repeating unit is substituted with a C1-C10 alkyl, alkenyl, or halogen, and a polyorganosiloxane whose end is substituted by a reactive substituent is added to a hydrophilic solvent in an emulsion state By weight, based on the solid content, of 10 to 70% by weight.

An optionally reactive substituent is one selected from the group consisting of hydroxy, C 1 to C 10 alkoxy, C 1 to C 10 alkoxyalkoxy, oxime, enoxy, acetoxy, C 1 to C 10 trialkylsilyl, amino, Or more.

The resin composition for fabric coating preferably has a viscosity of 3,000 to 10,000 mps as measured by a leon-type viscometer.

The fabric is preferably water-repellent with a fluorine-based resin.

The water repellency of the water repellent treatment is preferably 90 to 95%.

The fabric provided in the present invention is a surface-coated resin composition for fabric coating.

The resin composition can be used as a thin film to coat fabrics or knitted fabrics. The fabric can be folded into a small volume with a soft and thin structure, and can be easily cleaned and durably washed. Since the fabric is made of eco-friendly coating resin, it has a great advantage not only for the windproof clothing for the single ply touching the skin but also for the winter down wear.

The resin-coated fabric of the present invention has the effect of enabling the advantage of the knitted fabric to be taken advantage of and to compensate for the disadvantages by appropriately applying the coating material. For example, it is possible to use the knitted fabric in waterproof, windproof and cold weather applications, and it is possible to reduce the influence from chemical and physical actions such as washing and the like, so that it can be applied to active sports wear requiring a lot of comfort .

In addition, the present invention has an effect of being applied to a diaper cover, a sanitary napkin, and a midsole because it is provided with moisture permeability and breathability to perform aeration and waterproofing.

The resin composition for textile coating according to the present invention comprises: 100 parts by weight of an acrylic emulsion resin; 1 to 10 parts by weight of an isocyanate-based crosslinking agent; And 5 to 30 parts by weight of a silicone emulsion resin. Each component will be described in detail below.

1. Acrylic emulsion resin

The acrylic emulsion resin has a unique soft touch due to the absence of a urethane functional group that exhibits a repulsive elastic effect as compared with a polyurethane resin when it is coated on a fiber surface, and is excellent in adhesion to fibers and is excellent in peeling in washing Lt; / RTI >

The acrylic emulsion resin used for the above purpose is a (meth) acrylic acid alkyl having C1 to C10 alkyl or alkoxyalkyl groups; A copolymer with a functional acrylic derivative is used.

Examples of the alkyl (meth) acrylate include methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) Butyl (meth) acrylate, n-hexyl (meth) acrylate, n-octyl (meth) acrylate, isooctyl (meth) acrylate, Acrylate, 2-ethylhexyl (meth) acrylate, n-decyl (meth) acrylate, isodecyl (meth) acrylate and the like. These may be used alone or in combination of two or more. Examples of the alkoxyalkyl (meth) acrylate include 2-methoxyethyl (meth) acrylate, 2-ethoxyethyl (meth) acrylate, 2-propoxyethyl (meth) acrylate, 2-butoxyethyl Methoxypropyl (meth) acrylate, 2-methoxypropyl (meth) acrylate and 3-methoxypropyl (meth) acrylate.

The functional acrylic derivative is an unsaturated group-containing carboxylic acid, an unsaturated group-containing nitrile, or an unsaturated group-containing amide. Examples of the unsaturated group-containing carboxylic acid include monoethylenically unsaturated monovalent carboxylic acids such as (meth) acrylic acid,? -Chloroacrylic acid,? -Chloromethylacrylic acid, crotonic acid and cinnamic acid; Monoethylenically unsaturated polycarboxylic acids such as itaconic acid, itaconic anhydride, maleic acid, maleic anhydride, fumaric acid, citraconic acid and mesaconic acid; . These may be used alone or in combination of two or more.

The unsaturated group-containing nitrile is, for example, acrylonitrile.

The unsaturated group-containing amide is, for example, (meth) acrylamide.

The acrylic resin using the above-mentioned acrylic copolymer uses an emulsion resin in a water-dispersed state containing the acrylic resin in a solid content of 10 to 70% by weight.

The particle size of the acrylic emulsion resin preferably has an average particle size of 500 nm or less. On the other hand, there is no particular limitation on the molecular weight of the acrylic emulsion resin.

The acrylic emulsion resin can be used by purchasing a commercially available product. For example, the XA-5617 product of TOPCO, Japan is a dispersion in which an alkyl acrylate mixture of C2 to C4 and a copolymer of acrylic acid and acrylonitrile are dispersed in an emulsion state at a concentration of 45% by weight.

On the other hand, commercially available acrylic emulsion resins may be pH-regulated. As the pH-adjusting agent to be added for this purpose, any of basic compounds can be used. For example, ammonia water, aqueous potassium hydroxide solution, aqueous sodium hydroxide solution, quaternary alkylammonium hydroxide and the like are used to adjust the pH of the acrylic emulsion resin Can be used for the purpose.

The commercially available acrylic emulsion for textile coating has a viscosity of 1500 mps or less as measured by a leon-type viscometer at 20 ° C. The Rheon-type viscometer is a viscosity meter known in the art. Therefore, when it is used for coating raw coal as it is, the viscosity is low, and the coating thickness before drying or the excessive penetration during the course of work such as drying after immersion coating, Lt; / RTI >

In order to solve the above problems, it is preferable to add a thickener to the acrylic emulsion resin of the present invention. The thickener is usually a dispersion in which a copolymer of an acrylic monomer containing a metal salt of acrylic acid is dispersed in a polar solvent such as water. Except for the metal salt of acrylic acid, the other acrylic monomers are as described above.

A commercially available product may also be used as the thickener, for example, product number XA-3777 manufactured by Toray Industries, Inc. of Japan.

Though not intending to be bound to a particular theory, the principle of thickening of the thickening agent is understood as a principle in which the viscosity of the entire acrylic emulsion is increased by penetration of the thickener between the emulsions and then swelling.

The viscosity of the entire fabric coating composition including the cross-linking agent and the silicone emulsion resin to which the thickener is added as described later is preferably adjusted to a viscosity of 3,000 to 10,000 mps as measured by a Rheon-type viscometer. If the viscosity is less than 3,000 mps, the coating agent may excessively penetrate into the fabric, resulting in a severe stiffness of the touch or a desired coating effect. If the viscosity exceeds 10,000 mps, uniform coating is difficult and the coating amount is excessively large, . ≪ / RTI >

2. Isocyanate crosslinking agent

The isocyanate crosslinking agent of the second composition may be an aliphatic and / or aromatic isocyanate known in the art. Representative examples of the aliphatic isocyanate include hexamethylene diisocyanate (HDI). As aromatic diisocyanates, for example, toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI) and the like are widely known isocyanates in the art. Of these, in the case of TDI and MDI, the substitution positions of two or more isocyanate functional groups substituted on the toluene or benzene ring are arbitrary. As another example of the known isocyanate crosslinking agent, polymeric MDI can be mentioned.

Particularly preferably, a blocked isocyanate is used as an isocyanate-based crosslinking agent. The block isoinate refers to one in which at least one -NCO functional group that is an active substituent of an aliphatic / alicyclic diisocyanate is modified with NC (= O) -OR by reacting with an alcohol (ROH). The alcohol may be a monoalcohol or a polyhydric alcohol. The modified block isocyanate is thermally decomposable and has a functional group in the form of a modified form at room temperature, but is dissociated into isocyanate and alcohol again at a high temperature, and dissociated and produced isocyanate functions as a crosslinking agent. A typical dissociation temperature is 90 to 160 占 폚.

In the case of using a block isocyanate as a crosslinking agent in the present invention, there is an additional advantage that it is possible to increase the application time of the coating solution and to minimize the change in the flow characteristics such as viscosity of the resin composition with time.

Commercially available block isocyanates are either in powder form or dispersed in an appropriate solvent in an emulsion. Commercially available block isocyanates include, for example, product number MBX-11 of MIKI RICEN INC., Japan.

The content of the isocyanate crosslinking agent is preferably 1 to 10 parts by weight, more preferably 1 to 5 parts by weight, based on 100 parts by weight of the silicone emulsion resin. The content of the crosslinking agent is based on, for example, the solid content in the emulsion state. If the content of the crosslinking agent is less than 1 part by weight, the bonding between the raw material and the silicone resin and / or the acrylic resin described later is insufficient, and the durability of the fabric to be produced is deteriorated. On the other hand, if it exceeds 10 parts by weight, the bond between the fabric and the components of the composition is excessively excessive, and the stretchability of the fabric is deteriorated, making it unsuitable as a material for a caplet garment.

3. Silicone emulsion resin

In the resin composition for textile coating of the present invention, the silicone emulsion resin constituting the composition is a polyorganosiloxane dispersed in a hydrophilic solvent such as water and / or alcohol in an emulsion state. The silicone emulsion resin generally has a polyorganosiloxane content ranging from 10 to 70% by weight based on solids.

When the acrylic emulsion resin is used alone as a coating composition, it has some stickiness even after drying owing to the sticky nature peculiar to acrylic resin. In the present invention, an appropriate amount of the silicone emulsion is mixed with the acrylic resin without troubles in order to complement the above and to provide the antifouling effect to the fabric coating composition.

In the present invention, the term polyorganosiloxane refers to a polysiloxane in which the silicon atom of the siloxane as the repeating unit is substituted with C1-C10 alkyl, phenyl, alkenyl or halogen, preferably alkyl or phenyl.

The polyorganosiloxane is preferably a polyorganosiloxane end-substituted by a reactive substituent. The reactive substituent includes, for example, hydroxy, C 1 to C 10 alkoxy, C 1 to C 10 alkoxyalkoxy, oxime, enoxy, acetoxy, C 1 to C 10 trialkylsilyl, amino, . They can be used in the form of a mixture. Particularly preferred is a polyorganosiloxane end-substituted by a hydroxy group.

The molecular structure of the polyorganosiloxane may be linear, branched, network or mixed type. Preferably straight-chain or partially branched straight-chain polyorganosiloxane.

In the present invention, the particle size of the emulsion composed of the polyorganosiloxane is 500 nm or less, preferably 300 nm or less.

Commercially available polyorganosiloxanes, on the other hand, may contain, as impurities, small amounts of siloxane oligomers (e.g., octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc.), catalyst residues, ionic or nonionic Emulsifying agents and the like may be included. However, when the content is 10% by weight or less, preferably 5% by weight or less based on the total weight of the solid, the coating strength and adhesion of the fabric coating to which the composition of the present invention is applied are not affected. Representative of such emulsifiers are anionic, cationic or amphoteric surfactants, which are known in the art.

The molecular weight of a commercially available polyorganosiloxane has a weight average molecular weight of 1,000 to 1,000,000, and the molecular weight of the polyorganosiloxane in the composition of the present invention is not particularly limited.

The content of the silicone emulsion resin added to the fabric coating composition of the present invention is preferably 5 to 30 parts by weight based on 100 parts by weight of the acrylic emulsion resin based on the solid content. When the amount of the silicone emulsion resin is less than 5 parts by weight, the coated surface tends to sticky. When the amount is more than 30 parts by weight, not only the adhesion durability is weakened but also the cost may increase.

4. Fabric to be coated, coating method

The fabric to be coated in the present invention includes products made of fiber yarns, such as woven, knitted, felt, and the like. Particularly, the resin composition of the present invention is intended to be applied to fabrics suitable for clothes for capots. The material of the fabric used in the clothes for the cap is usually nylon, polyester, urethane spandex, and the like, but is not limited thereto.

Of the fabrics, materials such as nylon, spandex, and polyester have a reactive functional group in the molecule as a material. In addition to these materials, hydrophilic sizing agents, surfactants, emulsions, and the like are adhered to the surface of the fabrics such as woven fabrics and knitted fabrics, which are commercially available and commercially available, so that it is difficult to obtain water repellency and washing resistance do.

Therefore, when the surface treatment is performed using the above-described composition for fabric coating, the bonding strength and bonding amount thereof are excessively excessive, resulting in loss of elasticity over the material of the fabric, resulting in poor wash durability and air permeability. Accordingly, it is preferable that water-repellent treatment is performed on the surfaces of the fabrics based on the above-mentioned material before the composition of the present invention is coated to limit the reactivity with the composition to an appropriate level.

A technique known in the art can be applied to the water-repellent treatment of the fabric. Typically, a fluorocarbon-based emulsion resin (fluorine resin) is coated on the surface of a fabric by a method such as deposition and spraying. In this connection, reference may be made to the techniques disclosed in PCT / US2002 / 033718, Korean Patent Publication No. 1996-0015813, and the like.

Commercially available products for water repellent coatings include, for example, fluorine resin products such as Asahi Guard # 7605 from Asahi Chemical.

On the other hand, in the above-mentioned water-repellent treatment, it is preferable to improve the durability of washing by adjusting the water-repellency to about 90 to 95 points as evaluated by the spray test method. The water repellency evaluation method according to the spray test method is a known evaluation method for water repellency or water resistance of a fabric. The foot water of about 90 to 95 points means that the water repellent performance against rainwater is obtained. From a microscopic point of view, there is a part that can act as a kind of anchor capable of adhering firmly to the fiber surface because the resin composition partially lacks the water repellent component. When the water repellency is 90 or less, the water repellency which is usually acceptable falls short of the performance, and when the water repellency is 95 or more, there is a problem that the adhesion performance is deteriorated for the reasons mentioned above.

As a method of applying the composition of the present invention to the fabric, the direct coating method is particularly preferable. That is, the present invention relates to a device for holding a predetermined width by moving a fixing device (such as a knitted fabric) having excellent stretchability (hereinafter, simply referred to as knitted fabric) It is preferable to use a direct coating apparatus for coating a resin composition on a fabric through a coating means. INDUSTRIAL APPLICABILITY The resin composition for textile coating of the present invention can appropriately design the viscous behavior of the resin composition to be applied to the direct coating, thereby making it possible to uniformly apply the thin film to the textile or knitted fabric with softness.

Hereinafter, the present invention will be described in more detail with reference to Examples. This is for further illustrating the present invention, and the scope of the present invention is not limited to these examples.

Example  One

(1) Preparation of resin composition for coating

A resin composition for fabric coating comprising the following composition was prepared.

a. An emulsion water dispersion of an acrylonitrile-acrylic acid-alkyl acrylate copolymer (solid content: 45% by weight) (XS-5618 Rev. 7, Japan)

b. Isocyanate crosslinking agent: a block isocyanate crosslinking agent (MBX-11, MIKI RIKEN, Japan) having a concentration of 70 to 79% by weight and a polyisocyanate component, 2 kg

c. Ammonia water at a concentration of 18% by weight, 1 kg,

d. Silicone emulsion resin: Silicone emulsion water dispersion having a silicone resin content of 23 wt.% (XS-5560A, TOPCO, Japan), 30 kg

Each of the above compositions was added to a stirrer, and the mixture was thoroughly mixed for 10 minutes. Viscosity was adjusted using an acrylic thickener (XA-3777, TOPCO, Japan) so that the viscosity became 5,000 mps with a Rion type viscometer , And screened with a 100-mesh filter screen to prepare a resin composition for fabric coating.

(2) Direct coating of resin composition by knife coating method

The fabric was woven and dyed with 50 denier nylon spun fabrics (nylon yarn: spandex yarn = 90: 10), and then water repellent with 95 water repellency using a fluorinated water repellent (Asahi Chemical Co., Ltd., Asahi Guard # 7605) The coating was carried out by a direct coating method using a 1 mm thick knife coater by hanging it on a pin tenter coater. At this time, the resin composition prepared in the above (1) was used as the coating resin composition.

The water repellent material unwound from the roll was passed through the coating head of the bed type so that the coating resin composition was uniformly applied between the tissues. The surface-coated fabric was then passed through a hot air drying chamber to dry the emulsion resin coating. The hot air temperature in the 5 chamber was 100, 110, 120, 130 ℃ and 150 ℃, respectively, and the velocity through the chamber was 10m / min. .

Example 2

Resin compositions were prepared for each composition in the following manner.

a. An emulsion water dispersion of an acrylonitrile-acrylic acid-alkyl acrylate copolymer (solid content: 45 wt.%, Japan), 80 kg of XS-5618 Rev. 7)

b. Isocyanate crosslinking agent: a block isocyanate crosslinking agent (MBX-11, MIKI RIKEN, Japan) having a concentration of 70 to 79% by weight and a polyisocyanate component, 2 kg

c. Ammonia water at a concentration of 18% by weight, 1 kg,

d. Silicone emulsion resin: Silicone emulsion water dispersion having a silicone resin content of 23% by weight (Japan, TOPCO, XS-5560A), 20 kg

Each of the above compositions was added to a stirrer, and the mixture was thoroughly mixed for 10 minutes. The viscosity of the composition was adjusted to 5,000 mps by using a Rion type viscometer using the same acrylic thickener. .

Next, in the same manner as in Example 1, a nylon spun fabric was coated by a direct coating method.

Example 3

Resin compositions were prepared for each composition in the following manner.

a. An emulsion water dispersion of an acrylonitrile-acrylic acid-alkyl acrylate copolymer (solid content: 45% by weight, manufactured by TOPCO, Japan, XS-5618 Rev. 7)

b. Isocyanate crosslinking agent: a block isocyanate crosslinking agent (MBX-11, MIKI RIKEN, Japan) having a concentration of 70 to 79% by weight and a polyisocyanate component, 2 kg

c. Ammonia water at a concentration of 18% by weight, 1 kg,

d. Silicone-based emulsion resin: Silicone emulsion water dispersion having a silicone resin content of 23% by weight (Japan, TOPCO, XS-5560A), 10 kg

Each of the above compositions was added to a stirrer, and the mixture was thoroughly mixed for 10 minutes. The viscosity of the composition was adjusted to 5,000 mps by using a Rion type viscometer using the same acrylic thickener. .

Next, in the same manner as in Example 1, a nylon spun fabric was coated by a direct coating method.

Comparative Example 1

The procedure of Example 1 was repeated except that the silicone emulsion was dispensed at 100 kg instead of silicone in Example 1.

In the above Examples and Comparative Examples, the water pressure, air permeability and moisture permeability of coated fabrics were evaluated and summarized below. The water pressure was measured according to the method of ISO 0811, the air permeability according to JIS-L1096, and the moisture permeability according to JISL-1099 (A-1 method).

The touch sensory evaluation evaluated the degree of stickiness by touching the surface of the hand-coated fabric. In the table below, ⊚ (excellent) is a dry touch feeling, ◯ (good) is almost no stickiness, △ , And X (bad) are the results of the relative evaluation of the tackiness at the level of excessive discomfort.

Example 1 Example 2 Example 3 Comparative Example Water pressure
(mmH2O)
ISO 0811 Early 260 310 320 340 10 times of laundry 250 300 330 290 30 times of laundry 245 305 340 360 Breathability
(cc / cm < ² > / sec)
JIS-L1096 Early 2.3 1.0 0.5 0.5 10 times of laundry 2.9 1.2 0.6 0.5 30 times of laundry 3.5 1.5 0.8 0.7 Moisture permeability
(g / m ² * ²⁴ hrs)
JISL-1099 (method A-1) Early 4,700 2,810 2,500 2450 10 times of laundry 5,060 3,150 2,650 2500 30 times of laundry 4,900 3,640 3,000 2750 Touch sensory evaluation ◎ ○ △ x

Referring to Table 1, it can be confirmed that the fabric coated with the resin composition of the present invention can be used as waterproof and / or weatherproof clothing since the variation of water pressure, air permeability and moisture permeability is not large even after 30 times of washing. In addition, since physical and chemical changes due to washing are small, it can be confirmed that the fabric coated with the resin composition of the present invention is suitable for active sports wear requiring comfort.

On the other hand, in the comparative example, it is confirmed that the coated surface is sticky because the silicone is not contained, and the coated surface touches the skin, which is uncomfortable, and the dust adheres well.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be evident that many changes and modifications may be made without departing from the spirit and scope of the invention as defined in the appended claims. It is obvious that the present invention belongs to the claims.

Claims (10)

Based on 100 parts by weight of the solid content of the acrylic emulsion resin;
1 to 10 parts by weight of an isocyanate-based crosslinking agent; And
And 5 to 30 parts by weight of a silicone emulsion resin on a solid basis. The acrylic emulsion resin according to claim 1, wherein the acrylic emulsion resin is selected from the group consisting of alkyl (meth) acrylates having C1 to C10 alkyl groups or alkoxyalkyl groups; Functional acrylic resin is in the form of a water dispersion containing 10 to 70% by weight of a copolymer with a functional acrylic derivative as a solid content. The resin composition for textile coating according to claim 2, wherein the copolymer is a copolymer of alkyl (meth) acrylate, acrylonitrile and acrylic acid. The resin composition for textile coating according to claim 1, wherein the isocyanate crosslinking agent is blocked isocyanate. The silicone emulsion resin according to claim 1, wherein the silicon-based emulsion resin is a siloxane (-SiO-) in which the silicon atom of the repeating unit is substituted with a C1-C10 alkyl, alkenyl, Is dispersed in the hydrophilic solvent in an emulsion state in the range of 10 to 70% by weight based on the solid content. 6. The compound of claim 5 wherein said reactive substituent is selected from the group consisting of hydroxy, C1-C10 alkoxy, C1-C10 alkoxyalkoxy, oxime, enoxy, acetoxy, C1-C10 trialkylsilyl, amino, And the resin composition for fabric coating is at least one selected from the group consisting of the resin composition for fabric coating. The resin composition for textile coating according to claim 1, wherein the resin composition for textile coating has a viscosity of 3,000 to 10,000 mps as measured by a Rheon-type viscometer. The fabric of claim 1 wherein the resin composition is coated on the surface of a fabric, knitted or felt fabric. The cloth for clothing of claim 8, wherein the fabric, the knitted fabric or the felt fabric is water-repellent with a fluorine-based resin. The cloth for clothing according to claim 9, wherein the water-repellent treatment is performed so that the water-repellency of the water-repellent layer is 90 to 95 by spray test.