KR101394061B1 - Quick hardening conservatism mortar composition comprising high-performance flexural strength and constructing methods using thereof - Google Patents
Quick hardening conservatism mortar composition comprising high-performance flexural strength and constructing methods using thereof Download PDFInfo
- Publication number
- KR101394061B1 KR101394061B1 KR20130149166A KR20130149166A KR101394061B1 KR 101394061 B1 KR101394061 B1 KR 101394061B1 KR 20130149166 A KR20130149166 A KR 20130149166A KR 20130149166 A KR20130149166 A KR 20130149166A KR 101394061 B1 KR101394061 B1 KR 101394061B1
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- KR
- South Korea
- Prior art keywords
- weight
- water
- mortar composition
- quick
- slag
- Prior art date
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Classifications
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- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
- C04B14/365—Gypsum
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
- C04B18/141—Slags
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/32—Aluminous cements
- C04B7/323—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04G—SCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
- E04G23/00—Working measures on existing buildings
- E04G23/02—Repairing, e.g. filling cracks; Restoring; Altering; Enlarging
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/34—Flow improvers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/50—Defoamers, air detrainers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/72—Repairing or restoring existing buildings or building materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
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- Architecture (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
본 발명은 마이크로시멘트 20 내지 38중량%; 칼슘설포알루미네이트 10 내지 20중량%; 석고 5 내지 10중량%; 규사 20 내지 35중량%; 슬래그 20 내지 30중량%; 유동화제 0.01 내지 0.1중량%; 소포제 0.1 내지 1중량%; 촉진제 0.1 내지 1중량%; 지연제 0.05 내지 0.2중량%; 및 감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물 및 이를 이용한 시공방법에 관한 것이다.
본 발명은 고성능의 휨강도 특성을 갖고, 탁월한 신구의 부착강도 및 내구성능이 좋으며, 시공시 신속하게 경화되어 시공시간을 단축시킬 수 있는 초속경 보수성 몰탈 조성물을 제공한다.The present invention relates to a cement composition comprising 20 to 38% by weight microcement; From 10 to 20% by weight of calcium sulfoaluminate; 5 to 10% by weight of gypsum; 20 to 35% by weight of silica sand; 20 to 30% by weight of slag; 0.01 to 0.1% by weight of a fluidizing agent; From 0.1 to 1% by weight of an antifoaming agent; From 0.1 to 1% by weight of an accelerator; Retarding agent 0.05 to 0.2% by weight; And 1 to 3% by weight of a water reducing agent, and a construction method using the same.
Disclosed is a quick-setting light-weight mortar composition having a high-performance bending strength property, excellent adhesion strength and durability of an excellent new and old structure, and quick curing upon construction to shorten a construction time.
Description
본 발명은 고성능의 휨강도 특성을 갖는 초속경 보수성 몰탈 조성물 및 이를 이용한 시공방법에 관한 것으로서, 보다 상세하게는 레진계에 준하는 고성능의 휨강도와 몰탈의 특성에 맞는 고성능의 압축강도를 발현 할 수 있도록 하고, 속경성 및 보수성이 요구되는 시공에 적용 가능하도록 한 고성능의 휨강도 특성을 갖는 초속경 보수성 몰탈 조성물 및 이를 이용한 시공방법에 관한 것이다.
More particularly, the present invention relates to a high-speed light-hardenable mortar composition having a high-performance bending strength property and a high-performance compressive strength suitable for a high-performance bending strength similar to a resin system and mortar characteristics , A quick-setting water-repellent mortar composition having a high-performance bending strength property which is applicable to fast-setting and watertight construction, and a construction method using the same.
최근 도시화로 인해 주거, 상업, 공공시설 등이 늘어나면서 조경면적이 공개공지 등으로 전환되어 인공구조물이 증가하면서 도심의 열 축적 현상에 의한 열섬효과현상이 발생하고 있다. Recently urbanization has increased residential, commercial, and public facilities, and the landscape area has been converted to public notice, resulting in the increase of artificial structures.
이러한 현상은 습식공사의 경우 시공면 위에 저류하는 수분을 조기에 증발시켜 정상적인 수화반응에 의한 양생 및 경화과정을 방해할 수 있을 뿐만 아니라, 콘크리트의 강도에 영향을 줄 수 있기 때문에 간과해서는 안 되는 요인으로 이해하여야 한다.This phenomenon can not only prevent the curing and curing process due to normal hydration reaction by evaporating the water stored on the construction surface early in the case of wet construction but also affect the strength of the concrete, .
따라서 열용량이 적고 물을 최소한으로 사용하며, 사용된 물을 기온의 상승에 따라 증발시키지 않으면서도 정상적인 수화반응을 통해 양생 및 경화과정이 이루지고, 짧은 시간에 경화되면서도 강도가 높은 일반몰탈 및 보수용 몰탈의 개발이 요구되고 있다. Therefore, the curing and curing process is accomplished through normal hydration reaction without evaporation of the used water with evaporation of the used water with a low heat capacity and minimum use of water, and the curing in a short time, Development of mortar is required.
한편, 콘크리트나 아스팔트 등의 노면 또는 바닥 포장재에 사용하는 수지로는 에폭시계 수지, 우레탄계 수지 또는 아크릴계 수지 등이 알려져 있다. 그러나 종래 에폭시계 수지 또는 우레탄계 수지 등은 내마모성, 접착력 및 탄성이 우수하나, 콘크리트의 기공을 막아 경화되는 과정에서 발생하는 수분에 의해 박리현상이 생기는 하자가 발생하며 내화성을 기대할 수 없어 화재 발생 시 화재를 확산시킬 수 있는 문제점이 있다.On the other hand, an epoxy resin, a urethane resin, an acrylic resin, or the like is known as a resin used for a road surface or a floor covering material such as concrete or asphalt. Conventionally, epoxy resin or urethane resin is excellent in abrasion resistance, adhesive force and elasticity, but it has a defect that peeling occurs due to moisture generated in the process of curing by blocking pores of concrete, and fire resistance can not be expected. There is a problem in that it can diffuse.
또한, 건축물에는 내진기준이 적용되고 있으나, 도로 등과 같이 철근을 사용하지 않는 구조물의 경우 내진기준을 적용하기 어려운 경우 몰탈 및 콘크리트가 가지고 있는 압축강도와 휨강도의 중요성이 높아져야 할 시점이다. In addition, although the earthquake resistance standard is applied to buildings, it is a point that the importance of compressive strength and bending strength of mortar and concrete should be increased when it is difficult to apply the earthquake-resistant criteria for structures not using reinforcing bars such as roads.
이상에서 살펴본 바와 같이, 최근 들어 습식공사이면서 속경성을 갖는 고강도 몰탈로서, 콘크리트의 기공을 살리면서도 부착강도가 우수하며, 휨강도와 압축강도가 탁월하여 무근구조물에 사용할 수 있는 일반몰탈 및/또는 보수용 몰탈을 개발하는 것이 필요하다.
As mentioned above, recently, as a high-strength mortar having wet strength and quick hardness, it has excellent adhesion strength while maintaining pores of concrete, excellent bending strength and compressive strength, and can be used as general mortar and / It is necessary to develop a mortar for use.
본 발명은 상기와 같은 문제점을 해결하기 위해 창출한 것으로서, 1일 휨강도가 14N/mm2 이상이고, 압축강도가 40N/mm2 이상인 물리적 특성을 갖고, 신구의 탁월한 부착강도 및 내구성능을 향상시킬 수 있는 초속경 보수성 몰탈 조성물, 특정적으로 고성능의 초속경 보수성 몰탈 조성물 및 이를 이용한 시공방법을 제공하고자 한다.
The present invention that created to solve the above problems, a bending strength 14N /
본 발명은The present invention
마이크로시멘트 20 내지 38중량%; 20 to 38% by weight of microcement;
칼슘설포알루미네이트 10 내지 20중량%; From 10 to 20% by weight of calcium sulfoaluminate;
석고 5 내지 10중량%; 5 to 10% by weight of gypsum;
규사 20 내지 35중량%; 20 to 35% by weight of silica sand;
슬래그 20 내지 30중량%; 20 to 30% by weight of slag;
유동화제 0.01 내지 0.1중량%; 0.01 to 0.1% by weight of a fluidizing agent;
소포제 0.1 내지 1중량%; From 0.1 to 1% by weight of an antifoaming agent;
촉진제 0.1 내지 1중량%; From 0.1 to 1% by weight of an accelerator;
지연제 0.05 내지 0.2중량%; 및Retarding agent 0.05 to 0.2% by weight; And
감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물을 제공한다.
1 to 3% by weight of a water reducing agent.
또한, 본 발명은 시공 대상표면의 이물질을 제거하는 이물질 제거단계; According to another aspect of the present invention, there is provided a method of manufacturing a semiconductor device,
상기 이물질 제거단계가 종료된 표면에 마이크로시멘트 20 내지 38중량%, 칼슘설포알루미네이트 10 내지 20중량%, 석고 5 내지 10중량%, 규사 20 내지 35중량%, 슬래그 20 내지 30중량%, 유동화제 0.01 내지 0.1중량%, 소포제 0.1 내지 1중량%, 촉진제 0.1 내지 1중량%, 지연제 0.05 내지 0.2중량%; 및 감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물을 적층하는 적층단계; 20 to 38 wt% of microcement, 10 to 20 wt% of calcium sulfoaluminate, 5 to 10 wt% of gypsum, 20 to 35 wt% of silica, 20 to 30 wt% of slag, 0.01 to 0.1 wt.%, Defoamer 0.1 to 1 wt.%, Accelerator 0.1 to 1 wt.%, Retarder 0.05 to 0.2 wt.%; And 1 to 3% by weight of a water reducing agent;
상기 적층단계가 종료된 후 보수성 몰탈 조성물을 경화하는 경화단계; 및 A curing step of curing the water retaining mortar composition after the laminating step is completed; And
경화단계가 종료된 후 시공면을 건조시키는 건조단계를 포함하는 초속경 보수성 몰탈 조성물의 시공방법을 제공한다.
And a drying step of drying the surface to be dried after the curing step is completed.
본 발명에 따른 초속경 보수성 몰탈 조성물은 1일 휨강도가 14N/mm2 이상이고, 압축강도강도가 40N/mm2 이상인 물리적 특성을 갖고, 신구의 탁월한 부착강도 및 내구성능이 좋고, 시공시 신속하게 경화되어 시공시간을 단축시킬 수 있는 효과가 있다.
The quick-setting water-retaining mortar composition according to the present invention has a bending strength of 14 N / mm < 2 > Or more and a compressive strength strength of 40 N / mm 2 or more, excellent excellent adhesion strength and durability of the old and new materials, quick curing at the time of construction, and shortening the construction time.
도 1은 본 발명에 따른 실시예 1에 따라 제조된 초속경 보수성 몰탈 조성물의 시험성적서를 나타내는 도이다.BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a diagram showing a test report of a quick-setting light-weight water-retaining mortar composition prepared according to Example 1 of the present invention. FIG.
이하, 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail.
한 가지 관점에서, 본 발명은 마이크로시멘트 20 내지 38중량%; 칼슘설포알루미네이트 10 내지 20중량%; 석고 5 내지 10중량%; 규사 20 내지 35중량%; 슬래그 20 내지 30중량%; 유동화제 0.01 내지 0.1중량%; 소포제 0.1 내지 1중량%; 촉진제 0.1 내지 1중량%; 지연제 0.05 내지 0.2중량%; 및 감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물을 제공한다.In one aspect, the present invention provides a composition comprising 20 to 38% by weight of microcement; From 10 to 20% by weight of calcium sulfoaluminate; 5 to 10% by weight of gypsum; 20 to 35% by weight of silica sand; 20 to 30% by weight of slag; 0.01 to 0.1% by weight of a fluidizing agent; From 0.1 to 1% by weight of an antifoaming agent; From 0.1 to 1% by weight of an accelerator; Retarding agent 0.05 to 0.2% by weight; And 1 to 3% by weight of a water reducing agent.
다른 관점에서, 본 발명은 시공 대상표면의 이물질을 제거하는 이물질 제거단계; 상기 이물질 제거단계가 종료된 표면에 마이크로시멘트 20 내지 38중량%, 칼슘설포알루미네이트 10 내지 20중량%, 석고 5 내지 10중량%, 규사 20 내지 35중량%, 슬래그 20 내지 30중량%, 유동화제 0.01 내지 0.1중량%, 소포제 0.1 내지 1중량%, 촉진제 0.1 내지 1중량%, 지연제 0.05 내지 0.2중량%; 및 감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물을 적층하는 적층단계; 상기 적층단계가 종료된 후 보수성 몰탈 조성물을 경화하는 경화단계; 및 경화단계가 종료된 후 시공면을 건조시키는 건조단계를 포함하는 초속경 보수성 몰탈 조성물의 시공방법을 제공한다.
According to another aspect of the present invention, there is provided a method of manufacturing a semiconductor device, comprising: a foreign matter removing step of removing foreign matters on a surface to be applied; 20 to 38 wt% of microcement, 10 to 20 wt% of calcium sulfoaluminate, 5 to 10 wt% of gypsum, 20 to 35 wt% of silica, 20 to 30 wt% of slag, 0.01 to 0.1 wt.%, Defoamer 0.1 to 1 wt.%, Accelerator 0.1 to 1 wt.%, Retarder 0.05 to 0.2 wt.%; And 1 to 3% by weight of a water reducing agent; A curing step of curing the water retaining mortar composition after the laminating step is completed; And a drying step of drying the surface to be dried after the curing step is completed.
본 발명에 따른 마이크로시멘트는 시멘트 초기강도 및 시멘트 경화체의 장기강도를 증진시키기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 마이크로시멘트라면 특별히 한정되지 않는다.The microcement according to the present invention is for enhancing the initial strength of cement and the long-term strength of cured cement, and is not particularly limited as long as it is conventional microcement in the art having such an object.
특히, 상기 마이크로시멘트는 보통 포틀랜드 시멘트의 블레인 분말도 약 2,800 내지 3,500㎠/g과 비교하여 매우 미립으로 구성되어 물과 접촉하여 시멘트의 수화반응이 빠르게 진행되기 때문에 시멘트의 초기강도를 증진시킬 수 있을 뿐만 아니라, 시멘트 경화제의 장기강도 역시 증진된다.Particularly, since the microcement usually has very fine grains compared to about 2,800 to 3,500 cm2 / g of the blast powder of the Portland cement, the hydration reaction of the cement rapidly proceeds in contact with water, so that the initial strength of the cement can be enhanced In addition, the long term strength of the cement hardener is also enhanced.
더욱이, 본 발명에 따른 초속경 보수성 몰탈 조성물은 상기 마이크로시멘트를 포함함으로써, 휨강도 및 압축강도가 우수하다.Furthermore, the quick-setting water-retaining mortar composition according to the present invention has excellent bending strength and compressive strength by including the microcement.
상기 마이크로시멘트의 바람직한 블레인(blaine) 비표면적은 4,000 내지 12,000cm2/g, 보다 바람직하게는 7,000 내지 10,000cm2/g, 추천하기로는 약 8,000cm2/g인 것이 좋고, 그 사용량은 초속경 보수성 몰탈 조성물 전체 중량 기준으로 20 내지 38중량%인 것이 좋다.Preferred Blaine (blaine) a specific surface area of 4,000 to 12,000cm 2 / g, more preferably from 7,000 to 10,000cm 2 / g, is supposed to like may be from about 8,000cm 2 / g, the amount of the micro-cement is around zinnia The water-retaining mortar composition is preferably 20 to 38% by weight based on the total weight of the composition.
본 발명에 따른 칼슘설포알루미네이트(Calcium Sulfo Aluminate)는 수축보상, 고강도, 예를 들면 높은 압축강도와 휨강도 및 초속경을 부여하기 위한 물질로서, 이러한 목적을 갖는 칼슘설포알루미네이트라면 어떠한 것을 사용하여도 무방하며, 그 사용량은 초속경 보수성 몰탈 전체 중량 기준으로 10 내지 20중량%인 것을 추천한다.The calcium sulfoaluminate according to the present invention is a material for imparting shrinkage compensation, high strength, for example, high compressive strength, bending strength and ultrahigh speed, and any of calcium sulfoaluminate having such a purpose can be used And the amount thereof is preferably 10 to 20% by weight based on the total weight of the first-speed light-wettable mortar.
여기서, 상기 칼슘설포알루미네이트의 사용량이 10중량% 미만이면 경화속도가 감소하고 20중량% 이상인 경우 체적이 팽창되는 문제점이 발생할 수 있다.If the calcium sulfoaluminate is used in an amount less than 10% by weight, the curing rate may decrease. If the calcium sulfoaluminate is used in an amount of 20% by weight or more, the volume may expand.
한편, 상기 칼슘설포알루미네이트는 물과 접촉할 경우 순식간에 반응하여 에트린가이트(Ettringite) 수화물을 생성함으로써, 시멘트의 압축강도를 수분 내지 수 시간 안에 얻을 수 있도록 한다.On the other hand, when the calcium sulfoaluminate comes into contact with water, the calcium sulfoaluminate reacts instantaneously to generate an ettringite hydrate, so that the compressive strength of the cement can be obtained within several minutes to several hours.
이때, 보다 신속한 수화반응을 위해 초미립 비정질 칼슘설포알루미네이트를 사용할 수도 있다.At this time, ultrafine amorphous calcium sulfoaluminate may be used for a quick hydration reaction.
상기 수화반응성 증대를 위해 사용되는 초미립 비정질 칼슘설포알루미네이트의 블레인 분말도는 5,000 내지 8,000㎠/g 정도인 것이 좋다.The blast powder of the ultrafine amorphous calcium sulfoaluminate used for increasing hydration reactivity is preferably about 5,000 to 8,000
본 발명에 따른 석고는 상기 칼슘설포알루미네이트 등과 반응하여 신속히 경화가 일어나도록 하기 위한 것으로서, 이러한 목적을 위해 당업계에서 통상적으로 사용하는 석고라면 특별히 한정되지 않는다.The gypsum according to the present invention reacts with calcium sulfoaluminate or the like to cause rapid curing. For this purpose, the gypsum used in the art is not particularly limited.
바람직한 석고로서 무수석고 및/또는 탈황석고를 사용할 수 있고, 보다 바람직하게는 무수석고를 사용하는 것을 추천한다.As the preferable gypsum, anhydrous gypsum and / or desulfurized gypsum can be used, and it is more preferable to use anhydrous gypsum.
여기서, 상기 탈황석고는 탈황공정에서 발생되는 부산석고로서, 황 성분이 배제되어 친환경적이고, 탈황공정의 부산물을 재활용한다는 측면에서 고려될 수 있다.Here, the desulfurized gypsum is a gypsum produced in the desulfurization process, which is environmentally friendly since the sulfur component is excluded, and the by-product of the desulfurization process is recycled.
상기 석고의 사용량은 특별히 한정되는 것은 아니지만, 초속경 보수성 몰탈 조성물 전체 중량 기준으로 5 내지 10중량%인 것이 바람직하다.The amount of the gypsum to be used is not particularly limited, but is preferably 5 to 10% by weight based on the total weight of the quick-setting light-wettable mortar composition.
본 발명에 따른 규사는 초속경 보수성 몰탈 조성물에 포함되어 바인더 역할을 수행하기 위한 것으로서, 이러한 목적을 갖는 당업계에서 통상적으로 사용하는 규사라면 특별히 한정되지 않고, 그 사용량은 초속경 보수성 몰탈 조성물 전체 중량 기준으로 20 내지 35중량%를 사용하는 것을 추천한다.The silica sand according to the present invention is included in the quick-setting water-retaining mortar composition to serve as a binder and is not particularly limited as long as it is a silica sand that is commonly used in the art having such a purpose. It is recommended to use 20 to 35% by weight as a basis.
상기 규사의 바람직한 형태는 파우더 형태인 것이 좋다.The preferred form of the silica sand is a powder form.
상기 파우더 형태의 규사의 입도는 특별히 제한되지 않지만, 수마이크로미터 또는 수나노미터 단위를 갖는 것을 추천한다.The grain size of the powdery silica sand is not particularly limited, but it is recommended to have several micrometers or several nanometers.
본 발명에 따른 슬래그는 유해물질의 용출을 배제시키면서 유동성을 향상시키고, 속성경화가 가능하면서 충분한 압축강도 및 휨강도를 가질 수 있도록 하는 것으로서, 당업계에서 통상적으로 사용하는 슬래그라면 어떠한 것을 사용하여도 무방하다.The slag according to the present invention improves the fluidity while eliminating the release of harmful substances and has a sufficient compressive strength and bending strength while allowing property hardening. It is possible to use any slag as long as it is commonly used in the art Do.
바람직한 슬래그로는 제강 슬래그(PS Ball) 및/또는 고로 슬래그를 사용할 수 있다. The preferred slag may be steel-making slag (PS ball) and / or blast furnace slag.
이때, 상기 제강 슬래그 및/또는 고로 슬래그는 폐기 처분되던 제강 및/또는 고로 슬래그를 회수하여 재활용함으로써 부수적으로 자원 재활용 효과를 얻을 수 있다.At this time, the steelmaking slag and / or the blast furnace slag may be recycled by recycling steelmaking and / or blast furnace slag to be recycled.
특정적으로, 본 발명에 따른 제강 슬래그 및/또는 고로 슬래그는 제철 또는 제강공정에서 부산물로 발생하는 것을 포집하여 사용할 수 있다.Specifically, the steelmaking slag and / or blast furnace slag according to the present invention can be used by collecting what is generated as a by-product in a steelmaking or steelmaking process.
바람직한 슬래그의 사용량은 초속경 보수성 몰탈 조성물 전체 중량 기준으로 20 내지 30중량%인 것이 좋고, 슬래그의 분말도는 3,700 내지 4,000cm2/g, 바람직하게는 약 3,850cm2/g이고, 밀도는 2.9 내지 3.5g/cm3, 바람직하게는 약 3.1g/cm3인 것이 좋다.The amount of the slag is preferred zinnia light water retention mortar composition may be a total weight basis 20 to 30% by weight, the fineness of the slag is 3,700 to 4,000cm 2 / g, preferably from about 3,850cm 2 / g, the density was 2.9 To 3.5 g / cm < 3 >, preferably about 3.1 g / cm < 3 >.
본 발명에 따른 유동화제는 초속경 보수성 몰탈 조성물의 혼합성 및 유동성을 향상시킨다.The fluidizing agent according to the present invention improves the mixing and fluidity of the quick-setting water-retaining mortar composition.
특히, 상기 유동화제는 초속경 보수성 몰탈 조성물에 포함되어 시멘트 입자간의 응집작용을 억제함으로써, 단위수량을 유지한 상태에서 작업성을 향상시킬 수 있다.Particularly, the fluidizing agent is included in the quick-setting water-retaining mortar composition so as to suppress the coagulation action between the cement particles, so that the workability can be improved while maintaining the unit water quantity.
이러한 유동화제로 바람직한 것은 리그닌계 화합물 예를 들면 리그닌술폰산염, 나프탈렌계 화합물 예를 들면 나프탈렌술폰산염, 및/또는 폴리카르본산계 화합물 예를 들면 폴리카르복실산염을 사용하는 것이 좋고, 보다 바람직하게는 폴리카르본산계 화합물을 사용하는 것을 추천한다. As such a fluidizing agent, it is preferable to use a lignin-based compound such as a ligninsulfonic acid salt, a naphthalene-based compound such as a naphthalenesulfonic acid salt, and / or a polycarboxylic acid compound such as a polycarboxylic acid salt, It is recommended to use polycarboxylic acid-based compounds.
바람직한 유동화제의 사용량은 초속경 보수성 몰탈 조성물 전체 중량 기준으로 0.01 내지 0.1중량%인 것이 좋다.The preferred amount of the fluidizing agent to be used is 0.01 to 0.1% by weight based on the total weight of the quick-setting water-retaining mortar composition.
본 발명에 따른 소포제는 연행공기의 발생으로 인한 공기량의 증가를 감소시키기 위한 것으로서, 이러한 목적을 갖는 소포제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 바람직한 소포제로는 등유, 파라핀 등과 같은 광유계 소포제, 동식물유, 참기름, 피마자유와 이들의 알킬렌옥사이드 부가물 등과 같은 유지계 소포제, 올레인산, 스테아린산과 이들의 알킬렌옥사이드 부가물 등과 간은 지방산계 소포제, 글리세린모노리시놀레이트, 알케닐호박산 유동체, 솔비톨모노라울에이트, 솔비톨트리올레이트, 천연 왁스 등과 같은 지방산 에스테르계 소포제, 폴리옥시알킬렌류, (폴리)옥시알킬에테르류, 아세틸렌에테르류, (폴리)옥시알킬렌알킬인산에스테르류, (폴리)옥시알킬렌알킬아민류,(폴리)옥시알킬렌아미드 등과 같은 옥시알킬렌계 소포제, 옥틸알콜, 헥사데실알콜, 아세틸렌알콜, 글리콜류 등과 같은 알콜계 소포제, 아크릴레이트폴리아민 등과 같은 아미드계 소포제, 인산트리부틸, 나트륨옥틸포스페이트 등과 같은 인산에스테르계 소포제, 알루미늄스테아레이트, 칼슘올레이트 등과 같은 금속비누계 소포제, 디메틸실리콘유, 실리콘 페이슷, 실리콘 에멀젼, 유기변성 폴리실록산(디메틸폴리실록산 등의 폴리오르가노실록산). 플루오로실리콘유 등과 같은 실리콘계 소포제로 이루어진 군에서 선택되는 어느 하나 이상이 사용될 수 있으나, 이에 제한되는 것은 아니다.The antifoaming agent according to the present invention is intended to reduce an increase in the amount of air due to the generation of entrained air. Any antifoaming agent having such a purpose may be used. Preferably, the antifoaming agent is a mineral oil type antifoaming agent such as kerosene or paraffin , Fats and oils, sesame oil, castor oil defoamers such as castor oil and their alkylene oxide adducts, oleic acid, stearic acid and their alkylene oxide adducts, and the like can be used as a fatty acid defoaming agent, glycerin monoricinolate, , Fatty acid ester defoaming agents such as sorbitol monolaurate, sorbitol trioleate, and natural waxes, polyoxyalkylene ethers such as polyoxyalkylene ethers, acetylene ethers, (poly) oxyalkylene alkyl phosphate esters, ) Oxyalkylene alkylamines such as oxyalkylene alkylamines, (poly) oxyalkylene amides and the like, , Alcohol-based antifoaming agents such as octyl alcohol, hexadecyl alcohol, acetylene alcohol and glycols, amide-based antifoaming agents such as acrylate polyamines, phosphate ester antifoaming agents such as tributyl phosphate and sodium octyl phosphate, aluminum stearate, Such as metal soap based antifoaming agents, dimethyl silicone oils, silicone fats, silicone emulsions, organic modified polysiloxanes (polyorganosiloxanes such as dimethylpolysiloxane). And silicone-based antifoaming agents such as fluorosilicone oil, etc., but is not limited thereto.
바람직한 소포제의 사용량은 초속경 보수성 몰탈 조성물 전체 중량 기준으로 0.1 내지 0.05중량%인 것을 추천한다.The amount of the defoaming agent is preferably 0.1 to 0.05% by weight based on the total weight of the quick-setting light-wettable mortar composition.
본 발명에 따른 촉진제는 칼슘설포알루미네이트가 최초 수화를 시작하도록 촉진시키는 촉매 역할을 하여 초속경 보수성 몰탈 조성물이 조기에 강도를 발현할 수 있도록 하는 동시에, 수화반응의 반응율을 높이기 위한 것이다.The accelerator according to the present invention serves as a catalyst promoting the initial hydration of calcium sulfoaluminate so that the quick-setting water-retaining mortar composition can exhibit early strength and increase the reaction rate of hydration reaction.
상기 촉진제로 사용 가능한 것은 리튬, 나트륨 및 칼륨 등 알칼리금속의 탄산염 또는 중탄산염으로 이루어진 군에서 한 가지 이상을 선택하여 사용할 수 있지만, 추천하기로는 리튬카르보네이트(Li2CO3)를 사용하는 것이 좋다.The accelerator may be selected from the group consisting of a carbonate or a bicarbonate of an alkali metal such as lithium, sodium and potassium. However, it is recommended to use lithium carbonate (Li 2 CO 3 ) .
바람직한 촉진제의 사용량은 특별히 한정되지 않지만, 추천하기로는 초속경 보수성 몰탈 조성물 전체 중량 기준으로 0.1 내지 1중량%인 것이 좋다.The amount of the accelerator to be used is not particularly limited, but it is preferably 0.1 to 1% by weight based on the total weight of the quick-setting light-wettable mortar composition.
본 발명에 따른 지연제는 작업시간 및 강도발현 속도 조절을 위한 것이다.The retarder according to the present invention is for controlling the working time and intensity expression rate.
상기 지연제로서 바람직한 것은 타르타르산, 구연산, 글루콘산 등의 카르복시산 또는 그 염으로 또는 이들로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋다. Preferred as the retarder is a carboxylic acid such as tartaric acid, citric acid, gluconic acid, or a salt thereof, or a mixture of at least one selected from these.
바람직한 지연제의 사용량은 초속경 보수성 몰탈 조성물 전체 중량 기준으로 0.05 내지 0.2중량%인 것이 좋다.The preferred amount of retarding agent to be used is 0.05 to 0.2% by weight based on the total weight of the quick-setting light-wettable mortar composition.
본 발명에 따른 감수제는 시멘트 입자를 대전시켜 각 입자를 분산시키기고, 감수작용으로 단위수량을 저감시켜 강도를 증가시키기 위한 것으로서, 이를 부가함에 따라 시멘트의 사용량을 감소시킬 수 있다.The water reducing agent according to the present invention is intended to disperse each particle by charging cement particles and to reduce the unit water by the water reducing action to increase the strength, and the amount of the cement to be used can be reduced by adding the water reducing agent.
상기 감수제는 당업계에서 통상적으로 사용하는 감수제라면 특별히 한정되지 않지만, 바람직하게는 멜라민형 및/또는 아미노 술폰산형 감수제를 사용하는 것이 좋다.The water reducing agent is not particularly limited as long as it is a water reducing agent usually used in the art, but preferably a melamine type and / or aminosulfonic acid type water reducing agent is used.
바람직한 감수제의 사용량은 초속경 보수성 몰탈 조성물 중량 기준으로 1 내지 3중량%인 것이 좋다.The amount of the water reducing agent to be used is preferably 1 to 3% by weight based on the weight of the quick-setting light-wettable mortar composition.
특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 부가적으로 초속경 보수성 몰탈 조성물 전체 중량부 기준으로 50 내지 100중량부의 골재를 더 포함할 수 있다.In a particular embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 50 to 100 parts by weight of aggregate based on the total weight of the quick-setting water-retaining mortar composition.
상기 골재는 보수성 몰탈 조성물에 포함되어 시공면에 강도를 제공하기 위한 것으로서, 이러한 목적을 위한 당업계의 통상적인 골재라면 특별히 한정되지 않는다.The aggregate is included in the water-retaining mortar composition to provide strength to the construction surface, and is not particularly limited as long as it is an aggregate common in the art for this purpose.
상기 골재의 바람직한 입도는 0.1 내지 3mm, 바람직하게는 0.5 내지 2mm, 보다 바람직하게는 0.7 내지 1.5mm의 크기를 갖는 것이 좋다.The aggregate preferably has a particle size of 0.1 to 3 mm, preferably 0.5 to 2 mm, and more preferably 0.7 to 1.5 mm.
이러한 골재는 상기 입도 범위 내에서 굵은 골재와 잔골재로 구분하여 혼용함으로써, 두 골재(굵은 골재 및 잔골재) 사이에 적절한 크기의 공극을 형성할 뿐만 아니라, 강도의 하락을 방지하기 위한 적정범위에 해당된다.These aggregates are classified into a coarse aggregate and a fine aggregate within the above-mentioned particle size range so as to form an appropriate-sized pore between two aggregates (coarse aggregate and fine aggregate), and fall within a suitable range for preventing a drop in strength .
다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 초속경 보수성 몰탈 조성물 전체 중량부 기준으로 논슬립(Non-Slip)입자 10 내지 30중량부를 더 포함할 수 있다.In another specific embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 10 to 30 parts by weight of non-slip particles based on the total weight of the quick-setting water-retaining mortar composition.
상기 논슬립입자는 보수성 몰탈 조성물에 포함되어 마찰력을 제공함으로써 차량이나 보행자가 미끄러지지 않도록 하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 논슬립입자라면 특별히 한정되지 않지만, 바람직하게는 광물분말입자, 세라믹스입자, 유리분말입자, 금속합금분말 또는 이들로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋고, 추천하기로는 산화알루미늄, 실리콘카바이드, 세라믹골제 또는 이들로부터 선택된 적어도 하나 이상을 사용하는 것이 바람직하다.The non-slip particles are included in the water-retaining mortar composition to provide a friction force to prevent a vehicle or a pedestrian from slipping. The non-slip particles are not particularly limited as long as they are conventional non-slip particles in the related art. , Glass powder particles, metal alloy powder, or a mixture of at least one selected from the foregoing, and it is preferable to use at least one selected from among aluminum oxide, silicon carbide, ceramic bone, and the like.
바람직한 논슬립입자의 다른 일례로서, 본 발명에서는 다이아몬드(Dianmond), 탄화붕소(boron carbide), 에머리(Emery), 알루미나(Alumina), 용융알루미나(Fused alumina), 탄화규소(silicon carbide), 지르코니아(Zirconia), 소결보크사이트(Fused Bauxite), 금강사(Aluminum oxide), 석영(Quartz), 석류석(Garnet) 및/또는 바텀애쉬(Battom ash) 등을 사용할 수 있다.As another example of the preferred non-slip particles, in the present invention, there are used diamond particles such as diamond (Dianmond), boron carbide, emery, alumina, fused alumina, silicon carbide, zirconia Fused Bauxite, Aluminum oxide, Quartz, Garnet and / or Battom ash may be used.
특정적으로, 본 발명에 따른 논슬립 입자는 차별적 시인기능을 위해 투명성 논슬립 입자를 사용할 수 있다.In particular, the non-slip particles according to the present invention can use transparent non-slip particles for differential visualization.
이러한 투명성 논슬립입자는 도로의 시공면의 빛깔에 깊이를 주고, 고휘도의 반사를 가지게 할 수 있어 보다 제어된 색을 연출할 수 있다.These transparency non-slip particles can give a depth to the color of the installation surface of the road, have high brightness reflection, and can produce a more controlled color.
바람직한 투명성 논슬립입자는 투명한 석영계 천연석이나 유리를 분쇄해서 얻은 유리 입자를 사용할 수 있다.Preferable transparent non-slip particles can be transparent quartz-type natural stone or glass particles obtained by grinding glass.
한편, 본 발명에 따른 논슬립입자는 그 크기가 특별히 한정되는 것은 아니지만, 비교적 큰 입경은 60 내지 1,130㎛ 크기의 범위를 가지며, 바람직하게는 140 내지 840㎛의 크기 범위를 갖는 것을 추천한다. On the other hand, the size of the non-slip particles according to the present invention is not particularly limited, but a relatively large particle size is in the range of 60 to 1,130 μm, preferably 140 to 840 μm.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 보수성 몰탈 조성물 전체 중량부 기준으로, 흡수성 폴리머 0.2 내지 10중량부를 더 포함할 수 있다.In another specific embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 0.2 to 10 parts by weight of the water absorbent polymer based on the total weight of the water-retaining mortar composition.
상기 흡수성 폴리머는 몰탈 혼합시 물을 흡수하여 흡수성 폴리머가 팽창하여 볼 베어링과 같은 역할을 수행하여 몰탈의 작업성을 좋게 해 주고, 이로 인하여 콘크리트 중의 단위수량을 감소시켜 강도가 증가하게 된다.The water absorbent polymer absorbs water during mixing of the mortar, and the water absorbent polymer expands to serve as a ball bearing, thereby improving the workability of the mortar, thereby reducing the unit water content of the concrete and increasing the strength.
바람직한 흡수성 폴리머는 폴리아크릴산염 및 그 유도체, 폴리에칠렌옥사이드 유도체 및 흡수성 폴리우레탄류로 이루어진 것으로부터 선택된 적어도 하나 이상의 혼합물이다. Preferred water absorbent polymers are at least one or more mixtures selected from polyacrylate salts and derivatives thereof, polyethylene oxide derivatives and water absorbent polyurethanes.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 보수성 몰탈 조성물 전체 중량부 기준으로, 수용성 폴리머 0.2 내지 10중량부를 더 포함할 수 있다.As another specific embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 0.2 to 10 parts by weight of a water-soluble polymer based on the total weight of the water-retaining mortar composition.
상기 수용성 폴리머는 물에 녹아 시멘트 페이스트의 점성을 향상시키고, 이 점성이 향상된 시멘트 페이스트가 골재와의 접착력을 향상시켜 다공성 및 보수성 몰탈의 최대 약점인 휨 강도를 향상시키는 역할을 하게 된다.The water-soluble polymer is dissolved in water to improve the viscosity of the cement paste, and the cement paste having improved viscosity improves the adhesion with the aggregate, thereby improving the flexural strength, which is the weakest point of the porous and water-retaining mortar.
바람직한 수용성 폴리머로는 폴리비닐알콜, 카르복실메칠셀루로오즈, 하이드록시에칠셀루로오즈 또는 이들로부터 선택된 적어도 하나 이상의 혼합물이다. Preferred water-soluble polymers include polyvinyl alcohol, carboxymethylcellulose, hydroxyethylcellulose, and mixtures of at least one selected from these.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 시공면에 색상을 제공하기 위해 안료를 더 포함할 수 있다.In another particular embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise a pigment to provide a color on the construction surface.
상기 안료는 당업계에서 통상적으로 사용되는 안료라면 특별히 한정되지 않는다.The pigment is not particularly limited as long as it is a pigment conventionally used in the art.
바람직한 안료로는 산화철, 산화크롬, 유산바륨, 탄산바륨, 이산화티탄, 이산화망간, 이산화 티타늄, 규산 지르코늄, 및 카본 블랙 중 한 가지 이상을 사용할 수 있으며, 이에 따른 색상의 선택은 산화철 등의 적갈색 안료, 수산화철 등의 황색 안료, 산화크롬 등의 녹색 안료, 나트륨알루미노실리케이트 등의 군청색 안료, 산화티탄 등의 백색 안료 등으로서 통상적으로 이 분야에 시판되는 안료가 선택된다.As a preferable pigment, one or more of iron oxide, chromium oxide, barium sulfate, barium carbonate, titanium dioxide, manganese dioxide, titanium dioxide, zirconium silicate and carbon black may be used, Pigments such as yellow pigments such as iron hydroxide, green pigments such as chromium oxide, blue-black pigments such as sodium aluminosilicate, and white pigments such as titanium oxide are usually selected.
바람직한 안료의 사용량은 초속경 보수성 몰탈 조성물 전체 중량부 기준으로 5 내지 10중량부인 것이 좋다.Preferably, the amount of the pigment to be used is 5 to 10 parts by weight based on the total weight of the quick-setting light-wettable mortar composition.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물의 보수능력을 더욱 향상시키기 위해 제지 애쉬를 더 포함할 수 있다.In another specific embodiment, the paper ash may further include a paper ash to further improve the maintenance ability of the quick-setting water-retaining mortar composition according to the present invention.
상기 제지 애쉬는 특별히 한정되지 않지만, 바람직하게는 폐기물로 처리되어 왔던 제지공장 슬러지를 500 내지 1,300℃ 정도의 온도에서 열처리하여 얻은 애쉬를 분말도가 블레인(blaine) 비표면적으로 4,000 내지 12,000cm2/g 정도가 되도록 분쇄한 것을 사용하는 것이 좋다.The papermaking ash is not particularly limited. Preferably, the papermaking sludge, which has been treated with waste, is heat treated at a temperature of about 500 to 1,300 ° C. and the powder is blasted at a blaine specific surface area of 4,000 to 12,000 cm 2 / g or more.
특히, 상기 제지 애쉬는 초속경 보수성 몰탈 조성물에 포함되어 고강도성, 고내구성 및 유동성을 향상시킬 수 있다.In particular, the paper ash can be incorporated into a quick-setting light-water-resistant mortar composition to improve high strength, high durability and fluidity.
상기 제지 애쉬의 사용량은 초속경 보수성 몰탈 조성물 전체 중량부 기준으로 2 내지 8중량부인 것이 바람직하다.The paper ash is preferably used in an amount of 2 to 8 parts by weight based on the total weight of the quick-setting water-retaining mortar composition.
여기서, 상기 제지 애쉬의 사용량이 2중량부 보다 적으면 보수능력이 저하되어 보수성 몰탈로서의 역할이 적어 사용할 수 없으며, 8중량부를 초과하면 강도가 저하되어 제품으로서의 성능을 나타낼 수 없게 된다.If the amount of the paper ash used is less than 2 parts by weight, the water-repellent ability decreases and the water-repellent mortar hardly acts as a mortar. If the amount exceeds 8 parts by weight, the strength decreases and the product can not exhibit its performance.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 전체 초속경 보수성 몰탈 조성물 중량부 기준으로 충진제 10 내지 30중량부를 더 부가할 수 있다.In another specific embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 10 to 30 parts by weight of the filler based on the total weight of the initial quick-keeping water-resistant mortar composition.
여기서, 상기 충진제의 사용량이 10중량부 미만이면 치수 안정성 및 내마모성, 칙소성(Thixotropic)의 저하를 가져와 미끄럼 기능 저하 및 내구성 저하를 가져오고, 30중량부를 초과하는 경우에는 칙소 상승에 의한 작업성 저하 및 내충격성 저하 등의 영향을 가져오므로 바람직하지 못하다.If the amount of the filler used is less than 10 parts by weight, the dimensional stability, abrasion resistance, and thixotropic tend to be lowered, resulting in deterioration of sliding performance and durability. When the amount is more than 30 parts by weight, And deterioration in impact resistance, and the like.
바람직한 충진제로는 벤톤, 실리카, 탄산칼슘, 탈크, 황산바륨, 수산화알루미늄 중에서 선택된 하나 이상을 사용할 수 있다.As a preferable filler, at least one selected from bentone, silica, calcium carbonate, talc, barium sulfate and aluminum hydroxide can be used.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 보수성 몰탈 조성물 전체 중량부 기준으로 1 내지 10중량부의 평활제를 더 포함할 수 있다.As another specific embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 1 to 10 parts by weight of a smoothing agent based on the total weight of the water-retaining mortar composition.
상기 평활제는 페이스트의 셀프 레벨링(자기충전성능)을 개선하기 위하여서 첨가되는 것으로, 폴리옥사이드계, 우레탄계 및 폴리카본산계 중에서 선택된 어느 하나 이상이 사용될 수 있으나, 이에 제한되는 것은 아니며, 당 업계에서 통상적으로 사용되는 종류가 사용될 수 있다.The smoothing agent is added in order to improve the self-leveling (self-charging performance) of the paste, and any one or more selected from the group consisting of a polyoxide system, a urethane system and a polycarboxylic acid system may be used. However, May be used.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 보수성 몰탈 조성물 전체 중량부 기준으로 1 내지 5중량부의 수축저감제를 더 포함할 수 있다. In another specific embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 1 to 5 parts by weight of a shrinkage reducing agent based on the total weight of the water-retaining mortar composition.
상기 수축저감제는 시멘트 경화체의 건조수축을 방지하기 위하여 첨가되는 것으로, 폴리에테르계, 에틸렌글리콜 및 프로필렌글리콜 중에서 선택된 어느 하나 이상이 사용될 수 있으나, 이에 제한되는 것은 아니며, 당 업계에서 통상적으로 사용되는 종류가 사용될 수 있다.The shrinkage reducing agent is added in order to prevent drying shrinkage of the cured product, and any one or more selected from polyether-based, ethylene glycol and propylene glycol may be used, but not limited thereto, Type can be used.
또 다른 특정 양태로서, 본 발명에 따른 초속경 보수성 몰탈 조성물은 보수성 몰탈 조성물 전체 중량부 기준으로 첨가제 0.1 내지 5중량부를 더 포함할 수 있다.In another specific embodiment, the quick-setting water-retaining mortar composition according to the present invention may further comprise 0.1 to 5 parts by weight of an additive based on the total weight of the water-retaining mortar composition.
이때, 상기 첨가제는 당업계에서 통상적으로 사용되는 첨가제라면 특별히 한정되지 않지만, 바람직하게는 안정제, 노화방지제(age-protecting agent), 항산화제, 오존화 방At this time, the additive is not particularly limited as long as it is a commonly used additive in the art, but it is preferably a stabilizer, an age-protecting agent, an antioxidant,
지제, 광 보호제(light protection agent), 자외선 안정제, 자외선 흡수제, 무기 열안정제, 유기 열안정제, 광라이트너(optical lightener), 가공보조제(processing aids), 유동보조제(flow aid), 윤활제, 성형-이형제(mould-release agent), 연화제 또는 이들로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋다.
Light stabilizers, light stabilizers, optical lighteners, processing aids, flow aids, lubricants, shaping agents, light stabilizers, UV stabilizers, UV absorbers, A mold-release agent, a softening agent, or a mixture of at least one selected from these.
이와 같은 구성을 갖는 본 발명에 따른 초속경 보수성 몰탈 조성물의 시공방법을 설명하면 다음과 같다. 여기서, 하기 시공방법은 초속경 보수성 몰탈 조성물의 일 시공양태로서, 이에 한정되지 않고, 당업계의 통상적인 보수성 몰탈 조성물의 시공방법이라면 어떠한 것을 사용하여도 무방하다.A method of constructing the quick-setting water-retaining mortar composition according to the present invention having the above-described structure will be described below. Herein, the following method is one of the construction methods of the first-speed light-hardenable mortar composition, but it is not limited thereto and any method may be used as long as it is a conventional method of constructing a conventional water-retaining mortar composition.
본 발명에 따른 초속경 보수성 몰탈 조성물 시공방법은 시공 대상표면의 이물질을 제거하는 이물질 제거단계;The method for constructing the quick-setting water-retaining mortar composition according to the present invention comprises the steps of removing a foreign matter on the surface of a work to be applied;
상기 이물질 제거단계가 종료된 표면에 마이크로시멘트 20 내지 38중량%, 칼슘설포알루미네이트 10 내지 20중량%, 석고 5 내지 10중량%, 규사 20 내지 35중량%, 슬래그 20 내지 30중량%, 유동화제 0.01 내지 0.1중량%, 소포제 0.1 내지 1중량%, 촉진제 0.1 내지 1중량%, 지연제 0.05 내지 0.2중량%; 및 감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물을 적층하는 적층단계; 20 to 38 wt% of microcement, 10 to 20 wt% of calcium sulfoaluminate, 5 to 10 wt% of gypsum, 20 to 35 wt% of silica, 20 to 30 wt% of slag, 0.01 to 0.1 wt.%, Defoamer 0.1 to 1 wt.%, Accelerator 0.1 to 1 wt.%, Retarder 0.05 to 0.2 wt.%; And 1 to 3% by weight of a water reducing agent;
상기 적층단계가 종료된 후 보수성 몰탈 조성물을 경화하는 경화단계; 및 A curing step of curing the water retaining mortar composition after the laminating step is completed; And
경화단계가 종료된 후 시공면을 건조시키는 건조단계를 포함한다.
And a drying step of drying the construction surface after the curing step is completed.
이하에서 실시예를 통하여 본 발명을 구체적으로 설명하기로 한다. 그러나 하기의 실시예는 오로지 본 발명을 구체적으로 설명하기 위한 것으로 이들 실시예에 의해 본 발명의 범위를 한정하는 것은 아니다.
Hereinafter, the present invention will be described in detail by way of examples. However, the following examples are for illustrative purposes only and are not intended to limit the scope of the present invention.
[실시예 1][Example 1]
마이크로시멘트 30g, 칼슘설포알루미네이트(Calcium Sulfo Aluminate) 15.85g, 무수석고 6g, 규사 23g, 3,850cm2/g의 분말도와 3.1g/cm3의 밀도를 갖는 제강 슬래그[포스코 광양공장에서 수득] 22g, 폴리카르복실산염 0.05, 글리세린모노리시놀레이트 0.5g, 리튬카르보네이트 0.5g, 타르타르산 0.1g 및 아미노술폰산을 포함하는 감수제 2g를 혼합하여 초속경 보수성 몰탈 조성물을 제조하였다.
30 g of microcement, 15.85 g of calcium sulfoaluminate, 6 g of anhydrous gypsum, 23 g of silica sand, 22 g of steel making slag having a density of 3,850 cm 2 / g and a density of 3.1 g / cm 3 (obtained at POSCO Gwangyang Works) , 0.05 g of polycarboxylate, 0.5 g of glycerin monoricinolate, 0.5 g of lithium carbonate, 0.1 g of tartaric acid and 2 g of a water reducing agent containing aminosulfonic acid were mixed to prepare a quick-setting water-retaining mortar composition.
[실시예 2][Example 2]
실시예 1과 동일한 방법으로 실시하되, 상기 3,850cm2/g의 분말도와 3.1g/cm3의 밀도를 갖는 제강 슬래그 22g 대신 3,800cm2/g의 분말도와 3.2g/cm3의 밀도를 갖는 고로 슬래그 22g을 사용하여 실시하였다.
Except that 22 g of the steel slag having a density of 3,850 cm 2 / g and a density of 3.1 g / cm 3 was used in place of the blast furnace slag having a density of 3,800 cm 2 / g and a density of 3.2 g / cm 3 22 g of slag.
[실시예 3][Example 3]
실시예 1과 동일한 방법으로 실시하되, 상기 보수성 몰탈 조성물에 산화알루미늄으로 이루어진 논슬립입자 15g을 더 추가하여 실시하였다.
The same procedure as in Example 1 was carried out except that 15 g of non-slip particles made of aluminum oxide was further added to the water-retaining mortar composition.
[실시예 4][Example 4]
실시예 1과 동일한 방법으로 실시하되, 상기 보수성 몰탈 조성물에 폴리아크릴산염을 포함하는 흡수성 폴리머 5g을 더 추가하여 실시하였다.
The same procedure as in Example 1 was carried out except that 5 g of the water absorbent polymer containing polyacrylate was further added to the water retentive mortar composition.
[실시예 5][Example 5]
실시예 1과 동일한 방법으로 실시하되, 상기 보수성 몰탈 조성물에 폴리비닐알콜을 포함하는 수용성 폴리머 5g을 더 추가하여 실시하였다.
The same procedure as in Example 1 was carried out except that 5 g of a water-soluble polymer containing polyvinyl alcohol was further added to the water-retaining mortar composition.
[실시예 6][Example 6]
실시예 1과 동일한 방법으로 실시하되, 상기 보수성 몰탈 조성물에 제지 애쉬 3g을 더 추가하여 실시하였다.
The same procedure as in Example 1 was carried out except that 3 g of paper ash was further added to the water-retaining mortar composition.
[실시예 7][Example 7]
실시예 1과 동일한 방법으로 실시하되, 상기 보수성 몰탈 조성물에 실리카를 포함하는 충진제 15g을 더 추가하여 실시하였다.
The same procedure as in Example 1 was carried out except that 15 g of silica-containing filler was further added to the water-retaining mortar composition.
[실시예 8][Example 8]
실시예 1과 동일한 방법으로 실시하되, 상기 보수성 몰탈 조성물에 폴리옥사이드계를 포함하는 평활제 3g을 더 추가하여 실시하였다.
Was carried out in the same manner as in Example 1 except that a smoothing agent 3g containing a polyoxide system was further added to the water-retaining mortar composition.
[실시예 9][Example 9]
실시예 1과 동일한 방법으로 실시하되, 상기 보수성 몰탈 조성물에 폴리에테르계를 포함하는 수축저감제 3g을 더 추가하여 실시하였다.
Was carried out in the same manner as in Example 1 except that the shrinkage reducing agent 3g containing a polyether system was further added to the water-retaining mortar composition.
[비교예 1][Comparative Example 1]
실시예 1과 동일한 방법으로 실시하되, 마이크로시멘트 30g 대신 포틀랜트 시멘트 30g을 사용하여 실시하였다.
The same procedure as in Example 1 was carried out except that 30 g of portland cement was used instead of 30 g of micro cement.
[비교예 2][Comparative Example 2]
실시예 1과 동일한 방법으로 실시하되, 칼슘설포알루미네이트(Calcium Sulfo Aluminate) 15.85g를 제외하고, 마이크로시멘트 30g 대신 마이크로시멘트 38g, 규사 23g 대신 규사 30.85g을 사용하여 실시하였다.
Except that 15.85 g of calcium sulfoaluminate (Calcium Sulfo Aluminate) was used instead of 30 g of microcement, and 30.85 g of silica sand instead of 23 g of silica sand and 38 g of silica sand were used.
[실험 1][Experiment 1]
실시예에 따라 제조된 조성물을 시공면에 도포한 후 기계적 물성, 예를 들면 겔타임, 보수성, 압축강도, 휨강도, 부착강도 등을 측정하였다.The composition prepared according to the examples was applied to the surface of the substrate and mechanical properties such as gel time, water retention, compressive strength, bending strength and adhesion strength were measured.
그 결과를 도 1 및 표 1로 나타냈다.
The results are shown in FIG. 1 and Table 1.
도 1 및 표 1에 나타난 바와 같이, 실시예 1 내지 실시예 9에 따라 제조된 초속경 보수성 몰탈 조성물은 30분 내외로 겔화가 진행되어 경화가 신속히 이루어질 뿐만 아니라, 압축강도와 휨강도가 높은 것으로 나타났지만, 비교예1 및 비교예 2는 6시간이 지나도 겔화가 이루어지지 않을 뿐만 아니라, 압축강도와 휨강도가 실시예들과 비교하여 좋지 않은 것으로 나타났다.As shown in FIG. 1 and Table 1, the quick-setting water-retaining mortar composition prepared according to Examples 1 to 9 exhibited gelation progressed to within about 30 minutes so that not only hardening was accelerated but also the compressive strength and flexural strength were high However, in Comparative Example 1 and Comparative Example 2, gelation was not achieved even after 6 hours, and the compressive strength and flexural strength were not as good as those in Examples.
또한, 실시예 1 내지 실시예 9에 나타난 바와 같이, 모든 실시예에서 보수성을 나타내고 있는 것을 알 수 있었다.In addition, as shown in Examples 1 to 9, it was found that all examples showed water retention.
이상에서 설명한 바와 같이, 본 발명이 속하는 기술 분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예는 모두 예시적인 것이며 한정적인 것이 아닌 것으로서 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위의 의미 및 범위 그리고 그 등가개념으로부터 도출되는 모두 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.
As described above, those skilled in the art will understand that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. It is therefore to be understood that the embodiments described above are all illustrative and not restrictive. The scope of the present invention should be construed as being included in the scope of the present invention without departing from the scope of the present invention.
Claims (5)
칼슘설포알루미네이트 10 내지 20중량%;
석고 5 내지 10중량%;
규사 20 내지 35중량%;
슬래그 20 내지 30중량%;
유동화제 0.01 내지 0.1중량%;
소포제 0.1 내지 1중량%;
촉진제 0.1 내지 1중량%;
지연제 0.05 내지 0.2중량%; 및
감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물.
20 to 38% by weight of microcement;
From 10 to 20% by weight of calcium sulfoaluminate;
5 to 10% by weight of gypsum;
20 to 35% by weight of silica sand;
20 to 30% by weight of slag;
0.01 to 0.1% by weight of a fluidizing agent;
From 0.1 to 1% by weight of an antifoaming agent;
From 0.1 to 1% by weight of an accelerator;
Retarding agent 0.05 to 0.2% by weight; And
And 1 to 3% by weight of a water reducing agent.
상기 마이크로시멘트는 블레인 비표면적이 4,000 내지 12,000cm2/g인 것을 포함하는 초속경 보수성 몰탈 조성물.
The method according to claim 1,
Wherein the microcement has a blaine specific surface area of 4,000 to 12,000 cm 2 / g.
상기 칼슘설포알루미네이트는 블레인 분말도가 5,000 내지 8,000㎠/g인 초미립 비정질 칼슘설포알루미네이트인 것을 포함하는 초속경 보수성 몰탈 조성물.
The method according to claim 1,
Wherein the calcium sulfoaluminate is ultrafine amorphous calcium sulfoaluminate having a blast powder of 5,000 to 8,000 cm < 2 > / g.
상기 슬래그는 분말도가 3,700 내지 4,000cm2/g이고, 밀도가 2.9 내지 3.5g/cm3인 제강 슬래그 또는 고로 슬래그 또는 이들의 혼합물인 것을 포함하는 초속경 보수성 몰탈 조성물.
The method according to claim 1,
Wherein the slag is a steel making slag or a blast furnace slag having a powder degree of 3,700 to 4,000 cm 2 / g and a density of 2.9 to 3.5 g / cm 3 or a mixture thereof.
상기 이물질 제거단계가 종료된 표면에 마이크로시멘트 20 내지 38중량%, 칼슘설포알루미네이트 10 내지 20중량%, 석고 5 내지 10중량%, 규사 20 내지 35중량%, 슬래그 20 내지 30중량%, 유동화제 0.01 내지 0.1중량%, 소포제 0.1 내지 1중량%, 촉진제 0.1 내지 1중량%, 지연제 0.05 내지 0.2중량%; 및 감수제 1 내지 3중량%를 포함하는 초속경 보수성 몰탈 조성물을 적층하는 적층단계;
상기 적층단계가 종료된 후 보수성 몰탈 조성물을 경화하는 경화단계; 및
경화단계가 종료된 후 시공면을 건조시키는 건조단계를 포함하는 초속경 보수성 몰탈 조성물의 시공방법.
A foreign matter removing step of removing foreign matter on a surface to be applied;
20 to 38 wt% of microcement, 10 to 20 wt% of calcium sulfoaluminate, 5 to 10 wt% of gypsum, 20 to 35 wt% of silica, 20 to 30 wt% of slag, 0.01 to 0.1 wt.%, Defoamer 0.1 to 1 wt.%, Accelerator 0.1 to 1 wt.%, Retarder 0.05 to 0.2 wt.%; And 1 to 3% by weight of a water reducing agent;
A curing step of curing the water retaining mortar composition after the laminating step is completed; And
And a drying step of drying the construction surface after the curing step is completed.
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CN104402377A (en) * | 2014-10-24 | 2015-03-11 | 河南兴安新型建筑材料有限公司 | Plastering gypsum special for autoclaved aerated concrete products |
KR101530172B1 (en) * | 2014-11-03 | 2015-06-30 | (주)대한하이텍건설 | Non-Shrink Chemical Grout Material Composition and Grouting Methods Using Thereof |
KR101654215B1 (en) * | 2015-11-02 | 2016-09-09 | 주식회사 홍서이엔씨 | Polymer Cement Paste Composition And Road Pavement Method Using The Same |
KR101623150B1 (en) * | 2015-12-16 | 2016-05-20 | (주)코메스코리아 | Eco Friendly Acid-resistant and Alkali-resistant Repairing Mortar Composition and Constructing Methods Using Thereof |
KR101905074B1 (en) * | 2018-06-14 | 2018-10-05 | 씨텍 주식회사 | Preventing detachment type rapid setting mortar composition containing steelmaking slag and rapid setting concrete composition using the same |
KR102000461B1 (en) * | 2018-09-14 | 2019-07-16 | 유지씨 주식회사 | A minerals high elasticity filler for repairing cracks at the crack site where a waterproof coating Waterproof coating is formed when painting outer wall of a concrete building, and a method of repairing and reinforcing cracks using the same |
WO2020054968A1 (en) * | 2018-09-14 | 2020-03-19 | 유지씨 주식회사 | Highly elastic inorganic filler for repairing and reinforcing cracked region to enable formation of waterproofing coating in painting of concrete building exterior wall, and a method for repairing and reinforcing cracked region by using same |
KR101991420B1 (en) * | 2018-10-10 | 2019-06-20 | 하상우 | Cement Mortar Composition For Emergency Repair With Improved Strength and Durability And Method For Repairing And Reinforcing Concrete Structure Using The Same |
KR102374871B1 (en) * | 2021-10-21 | 2022-03-16 | 공병하 | Coating material for surface protection of inorganic concrete and its construction method |
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