KR102271506B1 - Eco-friendly Mortar Composition for Repair Section and Repairing Methods of Repair Section Using Thereof - Google Patents

Eco-friendly Mortar Composition for Repair Section and Repairing Methods of Repair Section Using Thereof Download PDF

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KR102271506B1
KR102271506B1 KR1020210010636A KR20210010636A KR102271506B1 KR 102271506 B1 KR102271506 B1 KR 102271506B1 KR 1020210010636 A KR1020210010636 A KR 1020210010636A KR 20210010636 A KR20210010636 A KR 20210010636A KR 102271506 B1 KR102271506 B1 KR 102271506B1
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parts
weight
cement
mortar composition
composition
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김지태
현경훈
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김지태
(주)코메스코리아
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/26Carbonates
    • C04B14/28Carbonates of calcium
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    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/02Cellulosic materials
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    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/10Burned or pyrolised refuse
    • C04B18/101Burned rice husks or other burned vegetable material
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    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0016Granular materials, e.g. microballoons
    • C04B20/002Hollow or porous granular materials
    • C04B20/0036Microsized or nanosized
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0076Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
    • C04B20/008Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder
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    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/0093Aluminates
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    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641Polyacrylates; Polymethacrylates
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04GSCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
    • E04G23/00Working measures on existing buildings
    • E04G23/02Repairing, e.g. filling cracks; Restoring; Altering; Enlarging
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    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/44Thickening, gelling or viscosity increasing agents
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    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/50Defoamers, air detrainers
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    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/608Anti-oxidants
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
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  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Provided are a mortar composition for repairing a cross-section and a cross-section repairing method using the same. The mortar composition for repairing a cross-section comprises: 5-30 parts by weight of calcium sulfonate aluminate; 5-20 parts by weight of charcoal powder; 1-10 parts by weight of cellulose fibers; 5-30 parts by weight of silica; 1-10 parts by weight of methylmethacrylate; 2-10 parts by weight of limestone; 10-60 parts by weight of fly ash; 1-20 parts by weight of nanoceramic particles; 3-15 parts by weight of an antioxidant; 1-10 parts by weight of an adhesion enhancer; 1-10 parts by weight of a thickener; and 0.5-5 parts by weight of a defoamer with respect to 100 parts by weight of cement. The mortar composition for repairing a cross-section according to the present invention has effects of: improving a working environment; reducing environmental pollution; and having the strength which is the same as or greater than that of conventional cement.

Description

친환경 단면보수용 모르타르 조성물 및 이를 이용한 단면보수공법{Eco-friendly Mortar Composition for Repair Section and Repairing Methods of Repair Section Using Thereof}Eco-friendly Mortar Composition for Repair Section and Repairing Methods of Repair Section Using Thereof

본 발명은 친환경 단면보수용 모르타르 조성물 및 이를 이용한 단면보수공법에 관한 것으로서, 보다 상세하게는 건축물의 보수, 보강, 절개면, 사면정리, 교량, 도로개량, 터널, 댐 등 각종 토목 건축공사를 포함하는 모든 건축공사에서 적용 가능한 친환경 단면보수용 모르타르 조성물 및 이를 이용한 단면보수공법에 관한 것이다.The present invention relates to an eco-friendly cross-section repair mortar composition and a cross-section repair method using the same, and more particularly, it includes various civil construction works such as repair, reinforcement, cut surface, slope preparation, bridges, road improvement, tunnels, dams, etc. It relates to an eco-friendly sectional repair mortar composition applicable to all construction projects and to a sectional repair method using the same.

일반적으로 교량의 바닥판, 도로의 노면 및 건물의 외벽과 같이 부식이나 침식이 많이 일어나는 부위를 보수 및/또는 보강하기 위한 보수공사에는 조강 포틀랜드 시멘트가 사용되고 있다.In general, crude steel Portland cement is used for repair work for repairing and/or reinforcing areas where corrosion or erosion occurs a lot, such as a bridge deck, a road surface, and an exterior wall of a building.

조강 포틀랜드 시멘트는 일반 시멘트에 비하여 시공성이 우수한 장점이 있으나, 투수성이 높아 염화물이나 수분의 침투가 발생하여 콘크리트가 부식되는 문제가 있다.Crude Portland cement has the advantage of superior workability compared to general cement, but has a problem of corrosion of concrete due to infiltration of chloride or moisture due to its high water permeability.

특히, 조강 포틀랜드 시멘트는 그 특성상 콘크리트가 경화되는 양생시간이 오래 소요되기 때문에 작업의 특성상 짧은 시간 내에 마무리하여야 하는 긴급 보수공사에 사용하기 곤란한 점이 있다.In particular, it is difficult to use crude steel Portland cement for emergency repair work that needs to be completed within a short time due to the nature of the concrete, which takes a long time to harden.

최근 긴급 보수공사에 사용되는 조강 포틀랜드 시멘트의 단점을 보완하기 위해 콘크리트에 폴리머 에멀젼을 첨가한 폴리머 시멘트 콘크리트의 사용이 점차 증가하고 있다.Recently, the use of polymer cement concrete with a polymer emulsion added to concrete is gradually increasing in order to compensate for the shortcomings of crude steel portland cement used in emergency repair work.

그러나 기존 폴리머 시멘트 콘크리트는 고가의 폴리머 디스퍼젼을 사용함으로써 공사비의 상승 원인을 제공한다.However, the existing polymer cement concrete uses expensive polymer dispersion, which increases the construction cost.

또한, 초속경 폴리머 시멘트 콘크리트는 그 재료 자체의 특성으로 인해 초기 수분 증발이 신속이 진행되어 초기 플라스틱 균열이 발생할 가능성이 있고, 건조 수축 및 수화열이 높아 균열발생이 용이하다.In addition, super-velocity polymer cement concrete has a possibility of early plastic cracking due to rapid initial moisture evaporation due to the characteristics of the material itself, and cracking is easy due to high drying shrinkage and heat of hydration.

이러한 문제점을 극복하기 위하여, 대한민국특허 제10-1512962호에는 시멘트 100중량부를 기준으로, 시멘트 결합재 7 내지 25중량부; 잔골재 35 내지 1,000중량부; 굵은골재 25 내지 1,000중량부; 감수제 0.05 내지 3중량부; 애쉬 10 내지 30중량부; 칼슘설포알루미네이트 3 내지 15중량부; 메틸메타아크릴레이트 3 내지 15중량부; 고기능 파우더 5 내지 10중량부; 보습제 5 내지 15중량부; 보습보조제 1 내지 5중량부; 광물 5 내지 10중량부; 실리카퓸 3 내지 8중량부; 및 슬래그 5 내지 20중량부를 포함하는 모르타르 조성물이 개시되어 있다.In order to overcome this problem, Korean Patent No. 10-1512962 discloses, based on 100 parts by weight of cement, 7 to 25 parts by weight of a cement binder; 35 to 1,000 parts by weight of fine aggregate; 25 to 1,000 parts by weight of coarse aggregate; 0.05 to 3 parts by weight of a water reducing agent; Ash 10 to 30 parts by weight; 3 to 15 parts by weight of calcium sulfoaluminate; 3 to 15 parts by weight of methyl methacrylate; 5 to 10 parts by weight of high-performance powder; 5 to 15 parts by weight of a moisturizer; 1 to 5 parts by weight of a moisturizing aid; 5 to 10 parts by weight of minerals; 3 to 8 parts by weight of silica fume; and 5 to 20 parts by weight of slag is disclosed.

또한, 신속한 경화를 위해 급결제를 사용하여 콘크리트를 경화시키는 방법을 사용할 수 있다.In addition, for rapid hardening, a method of hardening concrete using a quick-setting agent may be used.

한편, 현재 국내에서 일반적으로 사용되는 급결제로는 소듐실리케이트 및/또는 포타슘실리케이트를 주성분으로 하는 무기염계 급결제가 있고, 하소한 명반석으로 수산화칼슘과 반응하여 칼슘알루미네이트 수화물, 에트링가이트 등을 생성시켜 시멘트를 급결시키는 급경성 광물을 포함하는 급결제가 있으며, 칼슘알루미네이트 및/또는 칼슘설포알루미네이트계를 포함하는 시멘트계 급결제가 있다.On the other hand, as a quick-setting agent generally used in Korea, there is an inorganic salt-based quick-setting agent containing sodium silicate and/or potassium silicate as a main component, and it reacts with calcium hydroxide with calcined alum to produce calcium aluminate hydrate, ettringite, etc. There is a quick-setting admixture containing a sharp-hardening mineral for rapid setting of cement, and there is a cement-based quick-setting admixture containing calcium aluminate and/or calcium sulfoaluminate.

여기서, 상기 시멘트계 급결제는 전술한 무기염계 및 급경성 광물을 포함하는 급결제 보다 장기 강도가 우수하다. Here, the cement-based quick-setting admixture has superior long-term strength than the quick-setting admixture comprising the above-mentioned inorganic salt-based and acute hard mineral.

하지만, 상기 시멘트계 급결제는 알칼리성을 띄므로 이를 다량 사용하면 폐쇄공간 등의 특정장소에서 작업하기 곤란하고, 주변토양을 오염시킬 가능성이 있다.However, since the cement-based quick-setting admixture is alkaline, it is difficult to work in a specific place such as a closed space when a large amount is used, and there is a possibility of contaminating the surrounding soil.

본 발명은 상기와 같은 문제점을 해결하기 위해 창출한 것으로서, 작업환경을 개선하고, 환경오염을 감소시키면서도 종래 시멘트 조성물과 대등하거나 그 이상의 강도를 갖는 단면보수용 모르타르 조성물 및 이를 이용한 단면보수공법을 제공하고자 한다.The present invention was created to solve the above problems, and provides a mortar composition for cross-section repair and a cross-section repair method using the same, which improves the working environment and reduces environmental pollution while having a strength equal to or higher than that of a conventional cement composition want to

본 발명은the present invention

시멘트 100중량부 기준으로,Based on 100 parts by weight of cement,

칼슘설포알루미네이트 5 내지 30중량부;5 to 30 parts by weight of calcium sulfoaluminate;

숯가루 5 내지 20중량부;5 to 20 parts by weight of charcoal powder;

셀룰로오스 섬유 1 내지 10중량부;Cellulose fibers 1 to 10 parts by weight;

규사 5 내지 30중량부;5 to 30 parts by weight of silica sand;

메틸메타아크릴레이트 1 내지 10중량부;1 to 10 parts by weight of methyl methacrylate;

석회석 2 내지 10중량부;Limestone 2 to 10 parts by weight;

플라이애시 10 내지 60중량부;10 to 60 parts by weight of fly ash;

나노세라믹 입자 1 내지 20중량부;1 to 20 parts by weight of nano-ceramic particles;

산화방지제 3 내지 15중량부;3 to 15 parts by weight of an antioxidant;

부착증진제 1 내지 10중량부;1 to 10 parts by weight of an adhesion promoter;

증점제 1 내지 10중량부; 및 1 to 10 parts by weight of a thickener; and

소포제 0.5 내지 5중량부를 포함하는 단면보수용 모르타르 조성물을 제공한다.It provides a mortar composition for cross-section repair comprising 0.5 to 5 parts by weight of an antifoaming agent.

또한, 본 발명은Also, the present invention

시공 대상면의 이물질을 제거한 후 청소하는 이물질 제거-청소단계; Foreign matter removal-cleaning step of cleaning after removing foreign matter on the construction target surface;

상기 이물질 제거-청소단계가 종료된 대상면에 시멘트 100중량부 기준으로, 칼슘설포알루미네이트 5 내지 30중량부, 숯가루 5 내지 20중량부, 셀룰로오스 섬유 1 내지 10중량부, 규사 5 내지 30중량부, 메틸메타아크릴레이트 1 내지 10중량부, 석회석 2 내지 10중량부, 플라이애시 10 내지 60중량부, 나노세라믹 입자 1 내지 20중량부, 산화방지제 3 내지 15중량부, 부착증진제 1 내지 10중량부, 증점제 1 내지 10중량부, 및 소포제 0.5 내지 5중량부를 포함하는 단면보수용 모르타르 조성물을 물과 혼합한 뒤 타설하는 타설단계; 및 Based on 100 parts by weight of cement, 5 to 30 parts by weight of calcium sulfoaluminate, 5 to 20 parts by weight of charcoal powder, 1 to 10 parts by weight of cellulose fiber, 5 to 30 parts by weight of silica sand, based on 100 parts by weight of cement on the target surface where the foreign matter removal-cleaning step is completed Parts, 1 to 10 parts by weight of methyl methacrylate, 2 to 10 parts by weight of limestone, 10 to 60 parts by weight of fly ash, 1 to 20 parts by weight of nano-ceramic particles, 3 to 15 parts by weight of antioxidant, 1 to 10 parts by weight of adhesion promoter A pouring step of mixing a mortar composition for cross-section repair comprising a part, 1 to 10 parts by weight of a thickener, and 0.5 to 5 parts by weight of an antifoaming agent with water and then pouring; and

상기 타설단계가 종료된 후 시멘트 조성물을 양생하는 양생단계를 포함하는 단면보수용 모르타르 조성물의 시공방법을 제공한다.It provides a construction method of a mortar composition for cross-section repair comprising a curing step of curing the cement composition after the pouring step is completed.

본 발명에 따른 단면보수용 모르타르 조성물은 작업환경을 개선하고, 환경오염을 감소시키면서도 종래 시멘트와 대등하거나 그 이상의 강도를 갖도록 하는 효과가 있다.The mortar composition for cross-section repair according to the present invention has the effect of improving the working environment, reducing environmental pollution, and having a strength equal to or higher than that of conventional cement.

이하, 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be specifically described.

한 가지 관점에서, 본 발명은 시멘트 100중량부 기준으로, 칼슘설포알루미네이트 5 내지 30중량부; 숯가루 5 내지 20중량부; 셀룰로오스 섬유 1 내지 10중량부; 규사 5 내지 30중량부; 메틸메타아크릴레이트 1 내지 10중량부; 석회석 2 내지 10중량부; 플라이애시 10 내지 60중량부; 나노세라믹 입자 1 내지 20중량부; 산화방지제 3 내지 15중량부; 부착증진제 1 내지 10중량부; 증점제 1 내지 10중량부; 및 소포제 0.5 내지 5중량부를 포함하는 단면보수용 모르타르 조성물을 제공한다.In one aspect, the present invention, based on 100 parts by weight of cement, 5 to 30 parts by weight of calcium sulfoaluminate; 5 to 20 parts by weight of charcoal powder; Cellulose fibers 1 to 10 parts by weight; 5 to 30 parts by weight of silica sand; 1 to 10 parts by weight of methyl methacrylate; Limestone 2 to 10 parts by weight; 10 to 60 parts by weight of fly ash; 1 to 20 parts by weight of nano-ceramic particles; 3 to 15 parts by weight of an antioxidant; 1 to 10 parts by weight of an adhesion promoter; 1 to 10 parts by weight of a thickener; And it provides a mortar composition for cross-section repair comprising 0.5 to 5 parts by weight of an antifoam.

다른 관점에서, 본 발명은 시공 대상면의 이물질을 제거한 후 청소하는 이물질 제거-청소단계; 상기 이물질 제거-청소단계가 종료된 대상면에 시멘트 100중량부 기준으로, 칼슘설포알루미네이트 5 내지 30중량부, 숯가루 5 내지 20중량부, 셀룰로오스 섬유 1 내지 10중량부, 규사 5 내지 30중량부, 메틸메타아크릴레이트 1 내지 10중량부, 석회석 2 내지 10중량부, 플라이애시 10 내지 60중량부, 나노세라믹 입자 1 내지 20중량부, 산화방지제 3 내지 15중량부, 부착증진제 1 내지 10중량부, 증점제 1 내지 10중량부, 및 소포제 0.5 내지 5중량부를 포함하는 단면보수용 모르타르 조성물을 물과 혼합한 뒤 타설하는 타설단계; 및 상기 타설단계가 종료된 후 시멘트 조성물을 양생하는 양생단계를 포함하는 단면보수용 모르타르 조성물의 시공방법을 제공한다.In another aspect, the present invention is a foreign matter removal-cleaning step of cleaning after removing the foreign matter on the construction target surface; Based on 100 parts by weight of cement, 5 to 30 parts by weight of calcium sulfoaluminate, 5 to 20 parts by weight of charcoal powder, 1 to 10 parts by weight of cellulose fiber, 5 to 30 parts by weight of silica sand, based on 100 parts by weight of cement on the target surface where the foreign matter removal-cleaning step is completed Parts, 1 to 10 parts by weight of methyl methacrylate, 2 to 10 parts by weight of limestone, 10 to 60 parts by weight of fly ash, 1 to 20 parts by weight of nano-ceramic particles, 3 to 15 parts by weight of antioxidant, 1 to 10 parts by weight of adhesion promoter A pouring step of mixing a mortar composition for cross-section repair comprising a part, 1 to 10 parts by weight of a thickener, and 0.5 to 5 parts by weight of an antifoaming agent with water and then pouring; and a curing step of curing the cement composition after the pouring step is completed.

본 발명에 따른 단면보수용 모르타르 조성물은 건축물 및/또는 토목공사, 교량, 도로개량, 터널, 댐 등 각종 토목 건축공사 또는 이들의 보수공사 등을 포함하는 모든 공사에 적용가능하다.The mortar composition for cross-section repair according to the present invention is applicable to all constructions including various civil construction works such as buildings and/or civil works, bridges, road improvement, tunnels, dams, or their repair works.

본 발명에 따른 시멘트는 당업계에서 통상적으로 사용되는 시멘트라면 특별히 한정되지 않지만, 바람직하게는 일반 포틀랜드 시멘트 또는 슬래그시멘트, 초미분말시멘트, 초속경 시멘트 등의 특수 시멘트 등을 사용할 수 있다.The cement according to the present invention is not particularly limited as long as it is a cement commonly used in the art. Preferably, general Portland cement or special cement such as slag cement, ultra-fine powder cement, and ultra-fast cement can be used.

상기 시멘트의 바람직한 분말도는 3,200 내지 6,500cm2/g인 것이 좋다.The preferred fineness of the cement is 3,200 to 6,500 cm 2 /g.

본 발명에 따른 모르타르 조성물, 특정적으로 단면보수용 모르타르 조성물, 보다 특정적으로 친환경 단면보수용 모르타르 조성물을 구성하는 시멘트 외 나머지 성분들의 함량은 시멘트 100중량부 기준으로 한다.The content of the remaining components other than cement constituting the mortar composition according to the present invention, specifically the mortar composition for section repair, and more specifically, the eco-friendly mortar composition for section repair, is based on 100 parts by weight of the cement.

본 발명에 따른 칼슘설포알루미네이트(Calcium Sulfo Aluminate)는 수축보상, 고강도, 예를 들면 높은 압축강도와 휨강도 및 속경성 등을 부여하기 위한 것으로서, 이러한 목적을 갖는 칼슘설포알루미네이트라면 어떠한 것을 사용하여도 무방하며, 그 사용량은 시멘트 100중량부 기준으로 5 내지 30중량부인 것을 추천한다.Calcium sulfoaluminate according to the present invention is intended to provide shrinkage compensation, high strength, for example, high compressive strength, flexural strength, and rapid hardening, and any calcium sulfoaluminate for this purpose can be used. It is also recommended that the amount used is 5 to 30 parts by weight based on 100 parts by weight of cement.

여기서, 상기 칼슘설포알루미네이트의 사용량이 5중량부 미만이면 경화속도가 감소하고 30중량부 이상인 경우 체적이 팽창되는 문제점이 발생할 수 있다.Here, when the amount of the calcium sulfoaluminate used is less than 5 parts by weight, the curing rate is reduced, and when it is 30 parts by weight or more, a problem of volume expansion may occur.

한편, 상기 칼슘설포알루미네이트는 물과 접촉할 경우 순식간에 반응하여 에트린가이트(Ettringite) 수화물을 생성함으로써, 모르타르 조성물의 압축강도를 수분 내지 수 시간 안에 얻을 수 있도록 한다.On the other hand, the calcium sulfoaluminate reacts instantaneously when in contact with water to generate Ettringite hydrate, so that the compressive strength of the mortar composition can be obtained within minutes to hours.

이때, 보다 신속한 수화반응을 위해 초미립 비정질 칼슘설포알루미네이트를 사용할 수도 있다.In this case, ultra-fine amorphous calcium sulfoaluminate may be used for a more rapid hydration reaction.

상기 수화반응성 증대를 위해 사용되는 초미립 비정질 칼슘설포알루미네이트의 블레인 분말도는 5,000 내지 8,000㎠/g 정도인 것이 좋다.The fineness of the ultrafine amorphous calcium sulfoaluminate used to increase the hydration reactivity is preferably about 5,000 to 8,000 cm 2 /g.

특정 양태로서, 본 발명에 따른 칼슘설포알루미네이트는 28 내지 62중량%인 압연종말슬러지와, 19 내지 52중량%인 백운석슬러지와, 9 내지 20중량%인 부산석고가 포함되도록 구성되고, 상기 혼합물의 입도가 88㎛, 잔분이 5 내지 20중량%로 분쇄되어 이루어질 수 있다.In a specific embodiment, the calcium sulfoaluminate according to the present invention is composed of 28 to 62 wt% of rolled finished sludge, 19 to 52 wt% of dolomite sludge, and 9 to 20 wt% of by-product gypsum, and the mixture The particle size of 88㎛, the remainder may be made by pulverizing 5 to 20% by weight.

이후에, 상기 혼합물을 소성로에서 1,000 내지 1,300℃의 소성온도로 1시간 이상 유지한 후 공냉시켜, 칼슘설포알루미네이트를 제조하게 된다. 이때, 소성온도가 낮거나, 백운석슬러지의 함량이 높은 경우에는 미반응 석회의 양이 많아져 팽창성을 나타내므로 붕괴, 파괴의 염려가 있으며, 소성온도가 높거나 석회석 배합량이 적어도 칼슘설포알루미네이트의 생산이 적어져 소기의 목적을 달성할 수 없다.Thereafter, the mixture is maintained at a calcination temperature of 1,000 to 1,300° C. for at least 1 hour in a calcination furnace and then air-cooled to prepare calcium sulfoaluminate. At this time, when the calcination temperature is low or the content of dolomite sludge is high, the amount of unreacted lime increases and exhibits expandability, so there is a risk of collapse and destruction. Production is low and the intended purpose cannot be achieved.

본 발명에 따른 숯가루는 친환경적이면서도 높은 공극율로 인하여 모르타르 조성물을 구성하는 조성물의 분산성을 향상시키는 동시에 결합력을 향상시켜 인장강도를 증가시키도록 하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 숯가루라면 어떠한 것을 사용하여도 무방하며, 바람직하게는 볼밀로 분말화한 숯가루를 사용하는 것이 좋다.Charcoal powder according to the present invention is environmentally friendly and is intended to improve the dispersibility of the composition constituting the mortar composition due to the high porosity and at the same time to improve the bonding force to increase the tensile strength, and a conventional charcoal in the art having this purpose Any powder may be used, and it is preferable to use charcoal powder powdered with a ball mill.

바람직한 숯가루의 사용량은 특별히 한정되는 것은 아니지만, 추천하기로는 시멘트 100중량부 기준으로 5 내지 20중량부인 것이 좋다.The preferred amount of charcoal powder used is not particularly limited, but it is recommended that it be 5 to 20 parts by weight based on 100 parts by weight of cement.

본 발명에 따른 셀룰로오스 섬유는 친환경적이면서도 모르타르 조성물로 형성된 단면보수면의 종-횡 방향으로 가해지는 응력에 의한 인장력 및/또는 경량성 등을 제공하기 위한 것으로서, 이러한 목적을 갖는 셀룰로오스 섬유라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 천연 셀룰로오스 섬유를 사용하는 것이 좋고, 그 사용량은 시멘트 100중량부 기준으로 1 내지 10중량부인 것이 좋다.The cellulose fiber according to the present invention is environmentally friendly and provides tensile strength and/or lightness due to stress applied in the longitudinal-transverse direction of the cross-section repair surface formed of the mortar composition, and any cellulose fiber for this purpose is used. However, it is preferable to use natural cellulose fibers, and the amount used is preferably 1 to 10 parts by weight based on 100 parts by weight of cement.

본 발명에 따른 규사는 치수 안정성 및 내마모성 등을 향상시키기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 규사라면 어떠한 것을 사용하여도 무방하고, 그 사용량은 시멘트 시멘트 100중량부 5 내지 30중량부인 것을 추천한다.The silica sand according to the present invention is for improving dimensional stability and abrasion resistance, and any conventional silica sand in the art for this purpose may be used, and the amount used is 100 parts by weight of cement cement 5 to 30 parts by weight. I recommend you.

본 발명에 따른 메틸메타아크릴레이트(MMA: Methyl MethAcrylate)는 모르타르 조성물, 특정적으로 친환경 단면보수용 모르타르 조성물의 시공시 물리/화학적 안전성을 향상시키기 위한 것으로서, 인체에 무해하고, 환경친화력이 우수할 뿐만 아니라, 우수한 바인더 물성 및 기계적 물성을 유지하여 외부의 충격 또는 환경에 의한 크랙 및 탈락현상을 현저하게 감소시킬 수 있다.Methyl methacrylate (MMA: Methyl MethAcrylate) according to the present invention is intended to improve physical/chemical safety during the construction of a mortar composition, specifically, an eco-friendly sectional repair mortar composition, is harmless to the human body, and has excellent environmental friendliness. In addition, by maintaining excellent binder properties and mechanical properties, it is possible to significantly reduce cracks and drop-offs caused by external impacts or environments.

상기 메틸메타아크릴레이트는 점도가 10 내지 1,000cps인 저점도 메틸메타아크릴레이트 수지 49 내지 70중량%와, 점도가 2,000 내지 20,000cps인 고점도 메틸메타아크릴레이트 20 내지 50중량%를 혼합하여 얻어지는 메틸메타아크릴레이트 혼합물에 SIS(stylene isoprene stylene), SBR(stylene butadiene rubber), SBS(stylene butadiene stylene) 중에서 선택된 하나 이상의 혼합물 1 내지 10중량%를 혼합한 변성 메틸메타아크릴레이트를 사용할 수도 있다.The methyl methacrylate is obtained by mixing 49 to 70 wt% of a low-viscosity methyl methacrylate resin having a viscosity of 10 to 1,000 cps and 20 to 50 wt% of a high-viscosity methyl methacrylate having a viscosity of 2,000 to 20,000 cps. Modified methyl methacrylate obtained by mixing 1 to 10% by weight of at least one mixture selected from stylene isoprene stylene (SIS), stylene butadiene rubber (SBR), and stylene butadiene stylene (SBS) in the acrylate mixture may be used.

이때, 상기 SIS, SBR 및/또는 SBS의 함량이 1중량% 미만인 경우에는 내충격성 저하로 인한 크랙이 발생할 수 있고, 10중량%를 초과하는 경우에는 변성 메틸메타아크릴레이트 수지의 점도상승으로 인하여 작업성에 문제가 발생될 수 있다.At this time, if the content of the SIS, SBR and/or SBS is less than 1% by weight, cracks may occur due to reduced impact resistance, and if it exceeds 10% by weight, the viscosity of the modified methyl methacrylate resin increases due to operation Gender problems may arise.

바람직한 메틸메타아크릴레이트의 사용량은 시멘트 100중량부 기준으로 1 내지 10중량부인 것이 좋다.Preferably, the amount of methyl methacrylate used is 1 to 10 parts by weight based on 100 parts by weight of cement.

본 발명에 따른 석회석은 조성물의 초기강도 발현을 위한 것으로서, 그 사용량은 시멘트 100중량부 기준으로 2 내지 10중량부인 것이 좋다.Limestone according to the present invention is for the expression of initial strength of the composition, and the amount used is preferably 2 to 10 parts by weight based on 100 parts by weight of cement.

이때, 상기 석회석은 초기강도는 향상될 수 있지만, 장기강도 증진을 저하하게 되는 원인을 제공할 수 있으므로, 사용자는 이점을 고려하여 그 사용량을 조절하여야 한다.At this time, although the initial strength of the limestone may be improved, since it may provide a cause of lowering the long-term strength improvement, the user should adjust the amount used in consideration of the advantages.

본 발명에 따른 플라이애시는 단면보수용 모르타르 조성물에 적량 혼합하여 사용하면 가공성이 개선되고 경화열이 완화됨과 더불어 장기적인 강도 및 수밀성을 향상시킬 수 있다.When the fly ash according to the present invention is used by mixing an appropriate amount with the mortar composition for cross-section repair, workability is improved, the heat of curing is relieved, and long-term strength and watertightness can be improved.

이에, 상기 플라이애시는 전술한 목적으로 사용되는 플라이애시라면 특별히 한정되지 않지만, 바람직하게는 미분탄을 연소하는 보일러의 연도 가스로부터 집진기로 채취한 석탄재를 사용하는 것이 좋다.Accordingly, the fly ash is not particularly limited as long as it is fly ash used for the above purpose, but it is preferable to use coal ash collected by a dust collector from the flue gas of a boiler burning pulverized coal.

상기 플라이애시의 입자 크기는 시멘트와 같은 정도이고, 알루미나와 실리카가 주성분이다.The particle size of the fly ash is about the same as that of cement, and alumina and silica are the main components.

특정 양태로서, 본 발명에 따른 플라이애시는 미분쇄한 플라이애시를 사용할 수 있는바, 상기 미분쇄한 플라이애시는 미분쇄하지 않은 플라이애시를 사용하는 것 보다 향상된 고강도성 및/또는 유동성을 제공한다.In a specific embodiment, the fly ash according to the present invention can use pulverized fly ash, the pulverized fly ash provides improved strength and / or fluidity than using unpulverized fly ash. .

이때, 본 발명에 따른 미분쇄한 플라이애시의 분말도는 3,000 내지 3,800cm2/g, 바람직하게는 3,000 내지 3,800cm2/g, 보다 바람직하게는 3,700cm2/g 미만이고, 밀도는 1.5 내지 2.8g/cm3, 바람직하게는 약 2.2g/cm3인 것이 좋다.At this time, the fineness of the pulverized fly ash according to the present invention is 3,000 to 3,800 cm 2 /g, preferably 3,000 to 3,800 cm 2 /g, more preferably less than 3,700 cm 2 /g, and the density is 1.5 to 2.8 g/cm 3 , preferably about 2.2 g/cm 3 .

바람직한 플라이애시의 사용량은 시멘트 100중량부 기준으로 10 내지 60중량부인 것이 좋다.Preferably, the amount of fly ash used is 10 to 60 parts by weight based on 100 parts by weight of cement.

본 발명에 따른 나노세라믹 입자는 단면보수용 모르타르 조성물의 양생 중에 보수면의 표면으로 부상하여 치밀하고 경도가 높은 표면을 형성하기 때문에, 수증기와 기타 기체, 액체의 투과를 방지함은 물론, 내습성, 내구성, 내후성, 내충격성, 내약품성이 향상된다.The nano-ceramic particles according to the present invention float to the surface of the repair surface during curing of the mortar composition for cross-section repair and form a dense and high hardness surface, thus preventing the penetration of water vapor and other gases and liquids, as well as moisture resistance. , durability, weather resistance, impact resistance, and chemical resistance are improved.

상기 나노세라믹 입자의 사용량은 시멘트 100중량부를 기준으로 1 내지 20중량부인 것이 좋다.The amount of the nano-ceramic particles used is preferably 1 to 20 parts by weight based on 100 parts by weight of cement.

바람직한 나노세라믹 입자는 실리콘카바이드, 알루미나, 실리카, 지르코니아-실리카, ZnO, TiO2 및/또는 CaCO3가 포함된다. Preferred nanoceramic particles include silicon carbide, alumina, silica, zirconia-silica, ZnO, TiO 2 and/or CaCO 3 .

이들 세라믹입자는 평균 입경이 나노 범위인 것이 바람직한데, 구체적으로 상기 실리콘카바이드의 평균 입경은 300 내지 500nm, 상기 알루미나의 평균 입경은 500 내지 1000nm, 상기 실리카의 평균 입경은 700 내지 1500nm, 상기 지르코니아-실리카의 평균 입경은 500 내지 1000nm, 상기 ZnO의 평균 입경은 500 내지 1000nm, 상기 TiO2의 평균 입경은 100 내지 300nm, 그리고 CaCO3의 평균 입경은 500 내지 1000nm인 것이 바람직하다.It is preferable that these ceramic particles have an average particle diameter in the nano range, specifically, the average particle diameter of the silicon carbide is 300 to 500 nm, the average particle diameter of the alumina is 500 to 1000 nm, the average particle diameter of the silica is 700 to 1500 nm, the zirconia- It is preferable that the average particle diameter of silica is 500 to 1000 nm, the average particle diameter of ZnO is 500 to 1000 nm, the average particle diameter of TiO 2 is 100 to 300 nm, and the average particle diameter of CaCO 3 is 500 to 1000 nm.

이 중에서도 실리콘카바이드는 천연광물로 존재하지 않으므로 인공적으로 합성하며, 고온에서의 화학적 안정성 및 내식성이 뛰어나고 높은 경도를 갖는다.Among them, silicon carbide is artificially synthesized because it does not exist as a natural mineral, and has excellent chemical stability and corrosion resistance at high temperatures and high hardness.

본 발명에 따른 산화방지제는 모르타르 조성물의 산화를 방지하기 위한 것이다.The antioxidant according to the present invention is for preventing oxidation of the mortar composition.

바람직한 산화방지제는 아민계, 비스페놀계, 모노페놀계 및 유황계 산화방지제, 바람직하게는 2.2-메틸렌비스(4-메틸-6-t-부틸페놀)[2 . 2 - M e t h y l e n e b i s ( 4 - m e t h y l - 6 - t - b u t y l p h e n o l )], 2.6-디-t-부틸-4-메틸페놀(2.6-di -t-Butyl-4-methylphenol) 또는 이들의 혼합물이 사용될 수 있고, 그 사용량은 시멘트 100중량부 기준으로 3 내지 15중량부인 것이 좋다.Preferred antioxidants are amine-based, bisphenol-based, monophenol-based and sulfur-based antioxidants, preferably 2.2-methylenebis(4-methyl-6-t-butylphenol)[2. 2 - M ethylenebis ( 4 - methyl - 6 - t - butylphenol )], 2.6-di-t-butyl-4-methylphenol (2.6-di -t-Butyl-4-methylphenol) or a mixture thereof may be used. , the amount used is preferably 3 to 15 parts by weight based on 100 parts by weight of cement.

본 발명에 따른 부착증진제는 단면보수용 모르타르 조성물이 시공되는 시공면에 보다 용이하게 접착할 수 있도록 하기 위한 것으로서, 그 사용량은 시멘트 100중량부 기준으로 1 내지 10중량부인 것이 좋다.The adhesion enhancer according to the present invention is for more easily adhering to the construction surface on which the mortar composition for cross-section repair is constructed, and the amount used is preferably 1 to 10 parts by weight based on 100 parts by weight of cement.

바람직한 부착증진제로는 하이드록시 에틸 아크릴로일 포스페이트, 하이드록시 에틸 메타 아크릴레이트 포스페이트 또는 이들의 혼합물을 사용하는 것이 좋다.As a preferred adhesion promoter, hydroxyethyl acryloyl phosphate, hydroxyethyl methacrylate phosphate, or a mixture thereof is preferably used.

본 발명에 따른 증점제는 단면보수용 모르타르 조성물의 점도를 조절하여 시공시 사용을 용이하게 하기 위한 것으로서, 이러한 목적을 위해 당업계에서 통상적으로 사용되는 증점제라면 특별히 한정되지 않지만, 바람직하게는 하이드록시 에틸 셀룰로오즈(HydroxyEthyl Cellulose), 소수성 우레탄변성계 증점제 또는 이들의 혼합물을 사용하는 것을 추천한다.The thickener according to the present invention is for facilitating use during construction by adjusting the viscosity of the mortar composition for cross-section repair. For this purpose, if it is a thickener commonly used in the art, it is not particularly limited, but preferably hydroxyethyl It is recommended to use cellulose (HydroxyEthyl Cellulose), a hydrophobic urethane-modified thickener, or a mixture thereof.

상기 증점제의 사용량은 시멘트 100중량부를 기준으로 1 내지 10중량부인 것이 바람직하다.The amount of the thickener used is preferably 1 to 10 parts by weight based on 100 parts by weight of cement.

여기서, 상기 증점제로 사용되는 하이드록시 에틸 셀룰로오즈는 보수성을 가질 수 있다.Here, the hydroxyethyl cellulose used as the thickener may have water retention properties.

본 발명에 따른 소포제는 연행공기의 발생으로 인한 공기량의 증가를 감소시키기 위한 것이다.The antifoaming agent according to the present invention is for reducing the increase in the amount of air due to the generation of entrained air.

바람직한 소포제의 사용량은 시멘트 100중량부 기준으로 0.5 내지 5중량부를 사용하는 것을 추천한다.The preferred amount of the antifoaming agent is 0.5 to 5 parts by weight based on 100 parts by weight of cement.

바람직한 소포제로는 등유, 파라핀, 미네랄오일, 에탄올합성오일 등과 같은 광유계 소포제, 동식물유, 참기름, 피마자유와 이들의 알킬렌옥사이드 부가물 등과 같은 유지계 소포제, 올레인산, 스테아린산과 이들의 알킬렌옥사이드 부가물 등과 간은 지방산계 소포제, 글리세린모노리시놀레이트, 알케닐호박산 유동체, 솔비톨모노라울에이트, 솔비톨트리올레이트, 천연 왁스 등과 같은 지방산 에스테르계 소포제, 폴리옥시알킬렌류, (폴리)옥시알킬에테르류, 아세틸렌에테르류, (폴리)옥시알킬렌알킬인산에스테르류, (폴리)옥시알킬렌알킬아민류,(폴리)옥시알킬렌아미드 등과 같은 옥시알킬렌계 소포제, 옥틸알콜, 헥사데실알콜, 아세틸렌알콜, 글리콜류 등과 같은 알콜계 소포제, 아크릴레이트폴리아민 등과 같은 아미드계 소포제, 인산트리부틸, 나트륨옥틸포스페이트 등과 같은 인산에스테르계 소포제, 알루미늄스테아레이트, 칼슘올레이트 등과 같은 금속비누계 소포제, 디메틸실리콘유, 실리콘 페이슷, 실리콘 에멀젼, 유기변성 폴리실록산(디메틸폴리실록산 등의 폴리오르가노실록산). 플루오로실리콘유 등과 같은 실리콘계 소포제로 이루어진 군에서 선택되는 어느 하나 이상이 사용될 수 있으나, 이에 제한되는 것은 아니다.Preferred antifoaming agents include mineral oil-based antifoaming agents such as kerosene, paraffin, mineral oil, ethanol synthetic oil, animal and vegetable oils, sesame oil, castor oil and their alkylene oxide adducts, oleic acid, stearic acid and alkylene oxides thereof. Fatty acid antifoaming agent, glycerin monoricinolate, alkenylsuccinic acid fluid, sorbitol monolaurate, sorbitol trioleate, natural wax, etc. fatty acid ester antifoaming agent, polyoxyalkylenes, (poly)oxyalkyl ether oxyalkylene-based antifoaming agents such as, acetylene ethers, (poly)oxyalkylene alkyl phosphate esters, (poly) oxyalkylene alkylamines, (poly) oxyalkylene amides, octyl alcohol, hexadecyl alcohol, acetylene alcohol, Alcohol-based defoamers such as glycols, amide-based defoamers such as acrylate polyamines, phosphoric acid ester-based defoamers such as tributyl phosphate and sodium octyl phosphate, metal soap-based defoamers such as aluminum stearate and calcium oleate, dimethyl silicone oil, silicone Physop, silicone emulsion, organomodified polysiloxane (polyorganosiloxane such as dimethylpolysiloxane). Any one or more selected from the group consisting of silicone-based antifoaming agents such as fluorosilicone oil may be used, but is not limited thereto.

본 발명에 모르타르 조성물, 특정적으로 단면보수용 모르타르 조성물, 보다 특정적으로 친환경 단면보수용 모르타르 조성물은 하기의 특정 양태의 부가물을 1종 또는 1종 이상 더 포함할 수 있다.In the present invention, the mortar composition, specifically the mortar composition for end-face repair, and more specifically, the eco-friendly mortar composition for end-face repair may further include one or more adducts of the following specific aspects.

특정 양태로서, 본 발명에 따른 모르타르 조성물, 특정적으로 단면보수용 모르타르 조성물은 조성물의 강성, 안정성, 결합력 및 보전성 등을 향상시키기 위하여 시멘트 100중량부 기준으로 1 내지 5중량부의 사이클로헥산을 더 포함할 수 있다.In a specific embodiment, the mortar composition according to the present invention, specifically the mortar composition for cross-section repair, further comprises 1 to 5 parts by weight of cyclohexane based on 100 parts by weight of cement in order to improve the rigidity, stability, bonding strength and integrity of the composition. can do.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 접착력 및 내구성을 향상시키기 위하여 시멘트 100중량부 기준으로 5 내지 15중량부의 초산비닐-말레인산디에틸을 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 5 to 15 parts by weight of vinyl acetate-diethyl maleate based on 100 parts by weight of cement in order to improve the adhesion and durability of the composition.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 접착성 및 부착강도 향상을 위하여 옥틸트리에톡시실란을 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include octyltriethoxysilane to improve the adhesion and adhesion strength of the composition.

상기 옥틸트리에톡시실란은 단량체 형태로 사용가능하며, 상기 단량체의 분자량은 특별히 한정되는 것은 아니지만, 바람직하게는 150 내지 450Da인 것이 좋고, 그 사용량은 시멘트 100중량부 기준으로 5 내지 20중량부인 것을 추천한다.The octyltriethoxysilane can be used in the form of a monomer, and the molecular weight of the monomer is not particularly limited, but preferably 150 to 450 Da, and the amount used is 5 to 20 parts by weight based on 100 parts by weight of cement. I recommend you.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 강도를 증진시키고 방수성, 내염해성, 동결융해성 등을 향상시키기 위하여 트리지마이트를 시멘트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 5 parts by weight of trizite based on 100 parts by weight of cement in order to enhance the strength of the composition and improve waterproofness, salt decomposition resistance, freeze-thaw resistance, etc. have.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 시멘트 100중량부 기준으로 0.1 내지 5중량부의 토탄을 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 0.1 to 5 parts by weight of peat based on 100 parts by weight of cement.

여기서, 상기 토탄은 독특한 섬유구조로 인해 통상 10배 정도의 우수한 보수성을 가져 모르타르 조성물의 장기 강도 발현 및 내구성을 향상시키게 된다. Here, the peat has excellent water retention of about 10 times due to its unique fibrous structure, thereby improving long-term strength expression and durability of the mortar composition.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 점도 및 보수성을 개선하기 위하여 시멘트 100중량부 기준으로 1 내지 10중량부의 셀룰로오스 아세테이트 부틸레이트를 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 10 parts by weight of cellulose acetate butyrate based on 100 parts by weight of cement in order to improve the viscosity and water retention of the composition.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물이 수축하는 것을 방지하기 위하여 시멘트 100중량부 기준으로 1 내지 5중량부의 산화마그네슘을 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 5 parts by weight of magnesium oxide based on 100 parts by weight of cement in order to prevent the composition from shrinking.

여기서, 상기 산화마그네슘은 시공시 시공대상면에 수분이 유입이 되었을 때 보수 대상면을 단단하게 개량하는 효과를 제공할 수 있다.Here, the magnesium oxide may provide an effect of improving the surface to be repaired firmly when moisture is introduced into the surface to be constructed during construction.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 가소성 및 보수성을 향상시키고 균열방지와 강도증진을 위하여 코코베타인을 시멘트 100중량부 기준으로 2 내지 8중량부 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 2 to 8 parts by weight of cocobetaine based on 100 parts by weight of cement in order to improve the plasticity and water retention of the composition, and to prevent cracking and enhance strength.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 공극을 치밀하게 하고 누수를 방지하며 강도를 향상시키기 위하여 나트륨벤토나이트를 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 3 parts by weight of sodium bentonite based on 100 parts by weight of cement in order to make pores dense, prevent leakage, and improve strength.

상기 나트륨벤토나이트는 많은 양의 물을 흡수해 원래 부피의 여러 배로 팽창되며 겔과 같은 상태가 되어 조성물의 공극을 치밀하게 메우게 되어 누수를 방지하고 강도를 향상시켜 균열방지에 기여하게 된다.The sodium bentonite absorbs a large amount of water, expands to several times its original volume, becomes a gel-like state, and densely fills the pores of the composition, thereby preventing leakage and improving strength, thereby contributing to crack prevention.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 공극을 메워주어 시공시 공극이 발행하는 것을 방지하기 위하여 시멘트 100중량부 기준으로 0.1 내지 3중량부의 차아염소산염을 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 0.1 to 3 parts by weight of hypochlorite based on 100 parts by weight of cement in order to fill in the pores of the composition to prevent the pores from being generated during construction.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 시멘트 100중량부 기준으로 1 내지 10중량부의 구아검을 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 10 parts by weight of guar gum based on 100 parts by weight of cement.

여기서, 상기 구아검은 수용성 고분자 물질인 천연수지로서, 수화반응에 의한 팽창 및 탈수에 의한 수축작용과, 조성물의 수화반응에 의한 고화시 팽창작용과의 상호작용으로 공극이 발생하며, 이러한 공극과 천연수지인 구아검 고유의 탄성력에 의해 충격흡수작용을 나타낼 수 있다.Here, the guar gum is a natural resin that is a water-soluble polymer material, and voids occur due to the interaction between expansion and dehydration by hydration reaction and expansion action during solidification by hydration reaction of the composition. It can exhibit shock-absorbing action by the inherent elastic force of guar gum, a resin.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 점착성을 증가시키기 위하여 시멘트 100중량부 기준으로 몬모릴로나이트 0.1 내지 5중량부를 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 0.1 to 5 parts by weight of montmorillonite based on 100 parts by weight of cement in order to increase the tackiness of the composition.

여기서, 상기 몬모릴로나이트는 단사정계의 광물로 점토광물의 일종이며, 굳기가 1 내지 1.5이고, 비중은 2 내지 1.5이고, 수분을 흡수하여 7 내지 10배 부피가 증가하는 성질이 있을 뿐만 아니라 이온 교환성이 높으며, 수분과의 반응시 점착성이 발생하여 시공면의 강도를 강화시키면서 안정화시킨다.Here, the montmorillonite is a monoclinic mineral, a kind of clay mineral, has a hardness of 1 to 1.5, a specific gravity of 2 to 1.5, and has a property of increasing the volume by 7 to 10 times by absorbing moisture, as well as ion exchangeability. This is high, and when reacting with moisture, adhesion is generated, and it is stabilized while strengthening the strength of the construction surface.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 결합강도를 증가시키기 위하여 시멘트 100중량부 기준으로 카올리나이트 1 내지 7중량부를 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 7 parts by weight of kaolinite based on 100 parts by weight of cement in order to increase the bonding strength of the composition.

여기서, 상기 카올리나이트는 카올린을 주성분으로 함에 따라 흡수성 및 점성이 우수하여 도자기의 재료로 많이 사용된다. Here, the kaolinite is mainly used as a material for ceramics because of its excellent absorbency and viscosity as it contains kaolin as a main component.

또한, 상기 카올리나이트는 비교적 미립이고, 경도가 2 내지 2.5이므로 조성물이 시공면에 시공될 경우 조성물의 구성성분들의 사이로 침투하여 시공면의 내력을 더욱 강화시킨다.In addition, since the kaolinite is relatively fine and has a hardness of 2 to 2.5, when the composition is applied to the construction surface, it penetrates between the components of the composition to further strengthen the strength of the construction surface.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물의 부식을 억제하고 분산성을 향상시키기 위하여 시멘트 100중량부 기준으로 1 내지 10중량부의 칼슘아질산염을 더 포함할 수 있다.In another specific embodiment, 1 to 10 parts by weight of calcium nitrite may be further included based on 100 parts by weight of cement in order to suppress corrosion and improve dispersibility of the mortar composition according to the present invention.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 성분들 간의 비중차에 따른 재료의 분리 현상을 방지하기 위하여 웰란 검(welan gum)을 시멘트 100중량부 기준으로 0.1 내지 3중량부 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention further contains 0.1 to 3 parts by weight of welan gum based on 100 parts by weight of cement in order to prevent separation of the material due to the specific gravity difference between the components of the composition. can do.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 통기성을 확보하기 위하여 소디윰스테아레이트를 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함할 수 있는데, 시멘트 100중량부 기준으로 1중량부 미만이면 목적한 기능을 얻을 수 없고, 3중량부를 초과하면 조성물의 강도 저하현상을 나타내어 좋지 않다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 3 parts by weight of sodiium stearate based on 100 parts by weight of cement in order to ensure breathability of the composition, 1 weight based on 100 parts by weight of cement If it is less than part, the desired function cannot be obtained, and if it exceeds 3 parts by weight, it is not good because the strength of the composition decreases.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 건조를 촉진하기 위하여 밀도가 낮고 표면적이 큰 규조토를 시멘트 100중량부 기준으로 1 내지 4중량부로 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include diatomaceous earth having a low density and a large surface area in an amount of 1 to 4 parts by weight based on 100 parts by weight of cement in order to promote drying of the composition.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 방수성능을 보다 향상시키기 위하여 하소포졸라나(calcinated pozzolana)를 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있는데, 하소포졸라나는 주로 세립의 적색의 화산성 흙으로 구성되는 천연 포졸라나에 칼슘을 첨가하여 제조되며, 특히, 상기 하소포졸라나는 천연 포졸라나 100중량부에 칼슘 1 내지 20중량부를 혼합한 혼합물을 1000 내지 1200℃의 온도범위에서 0.5 내지 1시간 소성한 후 평균입도가 10 내지 20㎛가 되도록 분쇄한 것을 사용하는 것이 바람직하다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 5 parts by weight of calcinated pozzolana based on 100 parts by weight of cement in order to further improve the waterproofing performance of the composition. I am prepared by adding calcium to natural pozzolana mainly composed of fine-grained red volcanic soil, and in particular, the haso pozzolana is a mixture of 1 to 20 parts by weight of calcium in 100 parts by weight of natural pozzolana, 1000 to 1200 It is preferable to use what is pulverized so as to have an average particle size of 10 to 20 μm after calcination at a temperature range of ℃ 0.5 to 1 hour.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 흡수성, 투과성 및 보습성을 향상시키기 위하여 음이온 변성스타치의 일종인 스타치 포스페이트 에스테르를 더 포함할 수 있는데, 그 사용량은 시멘트 100중량부 기준으로 0.1 내지 2중량부가 좋다.As another specific embodiment, the mortar composition according to the present invention may further include starch phosphate ester, which is a type of anion-modified starch, in order to improve the absorbency, permeability and moisture retention of the composition, the amount of which is based on 100 parts by weight of cement. 0.1 to 2 parts by weight is good.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 충진성 및 내구성을 향상시키기 위하여 암모늄 노니페놀 에테르설페이트(ammonium nonylphenol ether sulfate)를 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.As another specific aspect, the mortar composition according to the present invention may further include 1 to 5 parts by weight of ammonium nonylphenol ether sulfate based on 100 parts by weight of cement in order to improve the filling properties and durability of the composition. have.

또 다른 특정 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 응집력과 재료의 분리를 방지하기 위하여 폴리비닐리덴 플루오라이드 수지를 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.As another specific embodiment, the mortar composition according to the present invention may further include 1 to 5 parts by weight of polyvinylidene fluoride resin based on 100 parts by weight of cement in order to prevent cohesive force of the composition and separation of materials.

또 다른 양태로서, 본 발명에 따른 모르타르 조성물은 조성물의 분산성을 향상시키고 조성물의 혼합 후에도 다시 엉김현상이 발생하지 않도록 하기 위하여 시멘트 100중량부 기준으로 1 내지 3중량부의 로진산 나트륨을 더 포함할 수 있다.In another aspect, the mortar composition according to the present invention may further contain 1 to 3 parts by weight of sodium rosinate based on 100 parts by weight of cement in order to improve the dispersibility of the composition and prevent agglomeration from occurring again even after mixing the composition. can

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 분산성을 향상시키기 위하여 시멘트 100중량부 기준으로 1 내지 5중량부의 이소보닐아크릴레이트를 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 1 to 5 parts by weight of isobornyl acrylate based on 100 parts by weight of cement in order to improve the dispersibility of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 내마모성, 내화학성, 내열성 등을 개선하기 위하여 시멘트 100중량부 기준으로 1 내지 3중량부의 티탄산칼륨을 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 1 to 3 parts by weight of potassium titanate based on 100 parts by weight of cement in order to improve abrasion resistance, chemical resistance, heat resistance, etc. of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 자외선 저항성 및 재료분리 저항성 등을 개선하기 위하여 시멘트 100중량부 기준으로 0.1 내지 4중량부의 포타슘클로라이드를 더 포함 할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 0.1 to 4 parts by weight of potassium chloride based on 100 parts by weight of cement in order to improve the UV resistance and material separation resistance of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 강도, 내마모성 및 작업성을 향상시키기 위하여 시멘트 100중량부 기준으로 0.1 내지 5중량부의 돌로스톤(dolostone)을 더 포함 할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 0.1 to 5 parts by weight of dolostone based on 100 parts by weight of cement in order to improve the strength, abrasion resistance and workability of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 장기강도, 내구성, 방수성능 등을 향상시키기 위하여 시멘트 100중량부 기준으로 1 내지 10중량부의 페그마타이트(pegmatite)를 더 포함 할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 1 to 10 parts by weight of pegmatite based on 100 parts by weight of cement in order to improve the long-term strength, durability, waterproofing performance, etc. of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 초기강도를 발현하고, 내구성을 향상시키기 위하여 시멘트 100중량부 기준으로 1 내지 5중량부의 트리칼슘알루미네이트를 더 포함 할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 1 to 5 parts by weight of tricalcium aluminate based on 100 parts by weight of cement in order to express the initial strength of the composition and improve durability.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 유동성, 응집력 및 재료분리 방지 성능을 향상시키고 조성물에 자기보수기능을 부여하기 위하여 시멘트 100중량부 기준으로 1 내지 5중량부의 폴리아크릴산을 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention further comprises 1 to 5 parts by weight of polyacrylic acid based on 100 parts by weight of cement in order to improve the fluidity, cohesive force and material separation prevention performance of the composition and to give the composition a self-repair function can do.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 유연성, 신축성, 탄성, 및 자외선 저항성 등을 향상시키기 위하여 시멘트 100중량부 기준으로 5 내지 15중량부의 폴리트리메틸렌테레프탈레이트를 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 5 to 15 parts by weight of polytrimethylene terephthalate based on 100 parts by weight of cement in order to improve the flexibility, elasticity, elasticity, and UV resistance of the composition. .

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 내식성, 내열성, 열전도성 등을 개선하기 위하여 시멘트 100중량부 기준으로 1 내지 10중량부의 질화알루미늄을 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 1 to 10 parts by weight of aluminum nitride based on 100 parts by weight of cement in order to improve corrosion resistance, heat resistance, thermal conductivity, etc. of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 반응성을 향상시키기 위하여, 시멘트 100중량부 기준으로 0.1 내지 5중량부의 디부틸틴디라우레이트를 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 0.1 to 5 parts by weight of dibutyltindilaurate based on 100 parts by weight of cement in order to improve the reactivity of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 점도조절을 위하여, 시멘트 100중량부 기준으로 5 내지 20중량부의 에틸 셀로솔브(ethyl cellosolve)를 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 5 to 20 parts by weight of ethyl cellosolve based on 100 parts by weight of cement to control the viscosity of the composition.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 시공면의 내변색, 내구성, 및 내크랙성 등을 유지하기 위하여, 시멘트 100중량부 기준으로 1 내지 5중량부의 설포라판(Sulforaphane)을 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention may further include 1 to 5 parts by weight of sulforaphane based on 100 parts by weight of cement in order to maintain discoloration, durability, and crack resistance of the construction surface. have.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물의 혼합시 입자간 흡착에 의한 공극 감소를 막아 내한성을 향상시키기 위하여, 시멘트 100중량부 기준으로 1 내지 5중량부의 디히드록시부탄디산을 더 포함할 수 있다.As another specific embodiment, the mortar composition of the present invention further comprises 1 to 5 parts by weight of dihydroxybutanedioic acid based on 100 parts by weight of cement in order to improve cold resistance by preventing void reduction due to interparticle adsorption when the composition is mixed. can do.

또 다른 특정 양태로서, 본 발명에 모르타르 조성물은 조성물에 의해 형성되는 단면의 차열 및 단열성을 향상시키기 위하여, 시멘트 100중량부 기준으로 0.01 내지 5중량부의 세슘텅스텐산화물(Cesium tungsten oxide)을 더 포함할 수 있다.As another specific aspect, the mortar composition of the present invention further comprises 0.01 to 5 parts by weight of cesium tungsten oxide based on 100 parts by weight of cement in order to improve the heat shielding and thermal insulation properties of the cross section formed by the composition. can

이와 같은 구성을 갖는 본 발명에 따른 단면보수용 모르타르 조성물, 특정적으로 친환경 단면보수용 모르타르 조성물을 이용한 단면보수방법, 예를 들면 단면보수공법은 당업계에서 통상적으로 사용하는 방법이라면 특별히 한정되지 않지만, 본 발명을 보다 용이하게 설명하기 위해 이러한 일례를 설명하면 다음과 같다.The cross-section repair method, for example, the cross-section repair method using the mortar composition for cross-section repair according to the present invention having such a configuration, specifically, the eco-friendly cross-section repair mortar composition, is not particularly limited as long as it is a method commonly used in the art. In order to more easily explain the present invention, an example of this will be described as follows.

본 발명에 따른 단면보수용 모르타르 조성물을 이용하여 시공하는 방법, 특정적으로 단면 보수를 위한 시공방법은 시공 대상면의 이물질을 제거한 후 청소하는 이물질 제거-청소단계; The construction method using the mortar composition for cross-section repair according to the present invention, specifically, the construction method for cross-section repair includes a foreign matter removal-cleaning step of cleaning after removing foreign substances on the construction target surface;

상기 이물질 제거-청소단계가 종료된 대상면에 시멘트 100중량부 기준으로, 칼슘설포알루미네이트 5 내지 30중량부, 숯가루 5 내지 20중량부, 셀룰로오스 섬유 1 내지 10중량부, 규사 5 내지 30중량부, 메틸메타아크릴레이트 1 내지 10중량부, 석회석 2 내지 10중량부, 플라이애시 10 내지 60중량부, 나노세라믹 입자 1 내지 20중량부, 산화방지제 3 내지 15중량부, 부착증진제 1 내지 10중량부, 증점제 1 내지 10중량부, 및 소포제 0.5 내지 5중량부를 포함하는 단면보수용 모르타르 조성물을 물과 혼합한 뒤 타설하는 타설단계; 및 Based on 100 parts by weight of cement, 5 to 30 parts by weight of calcium sulfoaluminate, 5 to 20 parts by weight of charcoal powder, 1 to 10 parts by weight of cellulose fiber, 5 to 30 parts by weight of silica sand, based on 100 parts by weight of cement on the target surface where the foreign matter removal-cleaning step is completed Parts, 1 to 10 parts by weight of methyl methacrylate, 2 to 10 parts by weight of limestone, 10 to 60 parts by weight of fly ash, 1 to 20 parts by weight of nano-ceramic particles, 3 to 15 parts by weight of antioxidant, 1 to 10 parts by weight of adhesion promoter A pouring step of mixing a mortar composition for cross-section repair comprising a part, 1 to 10 parts by weight of a thickener, and 0.5 to 5 parts by weight of an antifoaming agent with water and then pouring; and

상기 타설단계가 종료된 후 시멘트 조성물을 양생하는 양생단계를 포함한다.and a curing step of curing the cement composition after the pouring step is completed.

이하에서 실시예를 통하여 본 발명을 구체적으로 설명하기로 한다. 그러나 하기의 실시예는 오로지 본 발명을 구체적으로 설명하기 위한 것으로 이들 실시예에 의해 본 발명의 범위를 한정하는 것은 아니다.Hereinafter, the present invention will be described in detail through examples. However, the following examples are for illustrative purposes only and do not limit the scope of the present invention by these examples.

[실시예 1][Example 1]

분말도가 약 4,500cm2/g인 포틀랜드 시멘트 100g, 블레인 분말도가 약 6500㎠/g인 초미립 비정질 칼슘설포알루미네이트 18g, 볼밀로 분말화한 숯가루 12g, 천연 셀룰로오스 섬유 5g, 규사 20g, 메틸메타아크릴레이트 6g, 석회석 6g, 분말도가 약 3,500cm2/g이고 밀도가 약 2.2g/cm3인 플라이애시 30g, 평균입경이 약 450nm인 실리콘카바이드 12g, 2.2-메틸렌비스(4-메틸-6-t-부틸페놀) 8g, 하이드록시 에틸 아크릴로일 포스페이트 5g, 하이드록시 에틸 셀룰로오즈 6g, 및 솔비톨모노라울에이트 2g을 혼합하여 단면보수용 모르타르 조성물을 제조하였다.100 g of Portland cement with a fineness of about 4,500 cm 2 /g, 18 g of ultra-fine amorphous calcium sulfoaluminate with a fineness of about 6500 cm 2 /g, 12 g of charcoal powder pulverized with a ball mill, 5 g of natural cellulose fiber, 20 g of silica sand, 6 g of methyl methacrylate, 6 g of limestone, 30 g of fly ash having a fineness of about 3,500 cm 2 /g and a density of about 2.2 g/cm 3 , 12 g of silicon carbide with an average particle size of about 450 nm, 2.2-methylenebis (4-methyl -6-t-butylphenol) 8 g, hydroxyethyl acryloyl phosphate 5 g, hydroxy ethyl cellulose 6 g, and sorbitol monolauate 2 g were mixed to prepare a mortar composition for cross-section repair.

[실시예 2][Example 2]

실시예 1과 동일한 방법으로 실시하되, 사이클로헥산 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of cyclohexane was further added.

[실시예 3][Example 3]

실시예 1과 동일한 방법으로 실시하되, 초산비닐-말레인산디에틸 9g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 9 g of vinyl acetate-diethyl maleate was further added.

[실시예 4][Example 4]

실시예 1과 동일한 방법으로 실시하되, 옥틸트리에톡시실란 5g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 5 g of octyltriethoxysilane was further added.

[실시예 5][Example 5]

실시예 1과 동일한 방법으로 실시하되, 트리지마이트 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of trimite was further added.

[실시예 6][Example 6]

실시예 1과 동일한 방법으로 실시하되, 토탄 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of peat was further added.

[실시예 7][Example 7]

실시예 1과 동일한 방법으로 실시하되, 셀룰로오스 아세테이트 부틸레이트 4g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 4 g of cellulose acetate butyrate was further added.

[실시예 8][Example 8]

실시예 1과 동일한 방법으로 실시하되, 산화마그네슘 4g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 4 g of magnesium oxide was further added.

[실시예 9][Example 9]

실시예 1과 동일한 방법으로 실시하되, 코코베타인 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of cocobetaine was further added.

[실시예 10][Example 10]

실시예 1과 동일한 방법으로 실시하되, 나트륨벤토나이트 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but by adding 2 g of sodium bentonite.

[실시예 11][Example 11]

실시예 1과 동일한 방법으로 실시하되, 차아염소산염 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 1 g of hypochlorite was further added.

[실시예 12][Example 12]

실시예 1과 동일한 방법으로 실시하되, 구아검 5g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 5 g of guar gum was further added.

[실시예 13][Example 13]

실시예 1과 동일한 방법으로 실시하되, 몬모릴로나이트 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of montmorillonite was further added.

[실시예 14][Example 14]

실시예 1과 동일한 방법으로 실시하되, 카올리나이트 4g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but by adding 4 g of kaolinite.

[실시예 15][Example 15]

실시예 1과 동일한 방법으로 실시하되, 칼슘아질산염 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but by adding 3 g of calcium nitrite.

[실시예 16][Example 16]

실시예 1과 동일한 방법으로 실시하되, 웰란 검 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of Welan gum was further added.

[실시예 17][Example 17]

실시예 1과 동일한 방법으로 실시하되, 소디윰스테아레이트 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of sodium stearate was further added.

[실시예 18][Example 18]

실시예 1과 동일한 방법으로 실시하되, 규조토 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of diatomaceous earth was further added.

[실시예 19][Example 19]

실시예 1과 동일한 방법으로 실시하되, 천연 포졸라나 100g에 칼슘 10g을 혼합한 후, 1100℃에서 0.5시간 소성하여 분쇄한 평균입도가 15㎛인 하소포졸라나 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 10 g of calcium was mixed with 100 g of natural pozzolana, and then 2 g of calcined pozzolana having an average particle size of 15 μm, which was calcined at 1100° C. for 0.5 hours and pulverized, was further added.

[실시예 20][Example 20]

실시예 1과 동일한 방법으로 실시하되, 스타치 포스페이트 에스테르 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 1 g of starch phosphate ester was further added.

[실시예 21][Example 21]

실시예 1과 동일한 방법으로 실시하되, 암모늄 노니페놀 에테르설페이트 4g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 4 g of ammonium noniphenol ether sulfate was further added.

[실시예 22][Example 22]

실시예 1과 동일한 방법으로 실시하되, 폴리비닐리덴 플루오라이드 수지 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of polyvinylidene fluoride resin was further added.

[실시예 23][Example 23]

실시예 1과 동일한 방법으로 실시하되, 로진산 나트륨 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of sodium rosinate was further added.

[실시예 24][Example 24]

실시예 1과 동일한 방법으로 실시하되, 이소보닐아크릴레이트 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of isobornyl acrylate was further added.

[실시예 25][Example 25]

실시예 1과 동일한 방법으로 실시하되, 티탄산칼륨 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of potassium titanate was further added.

[실시예 26][Example 26]

실시예 1과 동일한 방법으로 실시하되, 포타슘클로라이드 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of potassium chloride was further added.

[실시예 27][Example 27]

실시예 1과 동일한 방법으로 실시하되, 돌로스톤 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of Dolostone was further added.

[실시예 28][Example 28]

실시예 1과 동일한 방법으로 실시하되, 페그마타이트 5g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 5 g of pegmatite was further added.

[실시예 29][Example 29]

실시예 1과 동일한 방법으로 실시하되, 트리칼슘알루미네이트 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of tricalcium aluminate was further added.

[실시예 30][Example 30]

실시예 1과 동일한 방법으로 실시하되, 폴리아크릴산 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of polyacrylic acid was further added.

[실시예 31][Example 31]

실시예 1과 동일한 방법으로 실시하되, 폴리트리메틸렌테레프탈레이트 10g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 10 g of polytrimethylene terephthalate was further added.

[실시예 32][Example 32]

실시예 1과 동일한 방법으로 실시하되, 질화알루미늄 5g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 5 g of aluminum nitride was further added.

[실시예 33][Example 33]

실시예 1과 동일한 방법으로 실시하되, 디부틸틴디라우레이트 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 2 g of dibutyltin dilaurate was further added.

[실시예 34][Example 34]

실시예 1과 동일한 방법으로 실시하되, 에틸 셀로솔브 12g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 12 g of ethyl cellosolve was further added.

[실시예 35][Example 35]

실시예 1과 동일한 방법으로 실시하되, 설포라판 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of sulforaphane was further added.

[실시예 36][Example 36]

실시예 1과 동일한 방법으로 실시하되, 디히드록시부탄디산 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 3 g of dihydroxybutanedioic acid was further added.

[실시예 37][Example 37]

실시예 1과 동일한 방법으로 실시하되, 세슘텅스텐산화물 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that 1 g of cesium tungsten oxide was further added.

[실시예 38][Example 38]

실시예 1과 동일한 방법으로 실시하되, 실시예 2 내지 실시예 37에 따라 부가된 부가물을 모두 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, except that all the additives added according to Examples 2 to 37 were further added.

[실 험][Experiment]

실시예에 따라 제조된 조성물을 물과 혼합하여 콘크리트를 제조한 후 기계적 물성, 예를 들면 오염물질 용출정도, 경화시간, 화학적 경화시간, 압축강도 등을 측정하였다.After preparing concrete by mixing the composition prepared according to the example with water, mechanical properties, for example, the degree of dissolution of contaminants, curing time, chemical curing time, compressive strength, etc. were measured.

그 결과를 표 1로 나타냈다. The results are shown in Table 1.

오염물질 용출Contaminant Elution 경화 시간(hr)Curing time (hr) 화학적 경화시간(day)Chemical curing time (day) 압축강도(MPa)Compressive strength (MPa) 실시예 1Example 1 없음none 3535 1414 7474 실시예 2Example 2 없음none 3434 1515 7676 실시예 3Example 3 없음none 3434 1414 7676 실시예 4Example 4 없음none 3232 1414 7676 실시예 6Example 6 없음none 3333 1515 7777 실시예 7Example 7 없음none 3838 1414 7575 실시예 8Example 8 없음none 3939 1616 7676 실시예 9Example 9 없음none 3737 1414 7474 실시예 10Example 10 없음none 3939 1414 7777 실시예 11Example 11 없음none 3838 1515 7878 실시예 12Example 12 없음none 3939 1515 7676 실시예 13Example 13 없음none 3535 1313 7676 실시예 14Example 14 없음none 3434 1414 7676 실시예 15Example 15 없음none 3939 1414 7575 실시예 16Example 16 없음none 3434 1515 7676 실시예 17Example 17 없음none 3737 1414 7575 실시예 18Example 18 없음none 4141 1313 7474 실시예 19Example 19 없음none 3838 1414 7676 실시예 20Example 20 없음none 3939 1515 7777 실시예 21Example 21 없음none 4242 1515 7575 실시예 22Example 22 없음none 3939 1414 7474 실시예 23Example 23 없음none 3737 1515 7676 실시예 24Example 24 없음none 3737 1414 7575 실시예 25Example 25 없음none 3535 1515 7676 실시예 26Example 26 없음none 3838 1414 7676 실시예 27Example 27 없음none 3838 1313 7676 실시예 28Example 28 없음none 3737 1515 7777 실시예 29Example 29 없음none 3636 1616 7575 실시예 30Example 30 없음none 3737 1616 7676 실시예 31Example 31 없음none 3939 1515 7777 실시예 32Example 32 없음none 4141 1616 7676 실시예 33Example 33 없음none 3939 1313 7777 실시예 34Example 34 없음none 4040 1515 7777 실시예 35Example 35 없음none 3939 1414 7575 실시예 36Example 36 없음none 3939 1616 7676 실시예 37Example 37 없음none 3939 1515 7777

표 1에 나타난 바와 같이, 실시예들에 따라 제조된 단면보수용 모르타르 조성물은 오염물질의 용출이 없으며, 경화시간이 매우 신속한 것은 아니지만 적어도 3일 안에 경화되고, 압축강도가 단면보수용 모르타르가 요구하는 물성을 충분히 만족하는 것으로 나타났다.As shown in Table 1, the mortar compositions for section repair prepared according to the Examples do not elute contaminants, cure time is not very fast, but cure within at least 3 days, and compressive strength is required for section repair mortar It was found that the properties were sufficiently satisfied.

이상에서 설명한 바와 같이, 본 발명이 속하는 기술 분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예는 모두 예시적인 것이며 한정적인 것이 아닌 것으로서 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위의 의미 및 범위 그리고 그 등가개념으로부터 도출되는 모두 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.As described above, those skilled in the art to which the present invention pertains will understand that the present invention may be implemented in other specific forms without changing the technical spirit or essential characteristics thereof. Therefore, it should be understood that all of the embodiments described above are illustrative and not restrictive. The scope of the present invention should be construed as being included in the scope of the present invention, rather than the above detailed description, all changes or modifications derived from the meaning and scope of the claims described below and their equivalents.

Claims (5)

시멘트 100중량부 기준으로,
칼슘설포알루미네이트 5 내지 30중량부;
숯가루 5 내지 20중량부;
셀룰로오스 섬유 1 내지 10중량부;
규사 5 내지 30중량부;
메틸메타아크릴레이트 1 내지 10중량부;
석회석 2 내지 10중량부;
플라이애시 10 내지 60중량부;
나노세라믹 입자 1 내지 20중량부;
산화방지제 3 내지 15중량부;
부착증진제 1 내지 10중량부;
증점제 1 내지 10중량부; 및
소포제 0.5 내지 5중량부를 포함하는 단면보수용 모르타르 조성물에,
초산비닐-말레인산디에틸을 시멘트 100중량부 기준으로 5 내지 15중량부로 더 포함하고,
코코베타인을 시멘트 100중량부 기준으로 2 내지 8중량부로 더 포함하며,
나트륨벤토나이트를 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하고,
웰란 검을 시멘트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며,
소디윰스테아레이트를 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하고,
스타치 포스페이트 에스테르를 시멘트 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며,
암모늄 노니페놀 에테르설페이트를 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함하고,
로진산 나트륨을 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하며,
설포라판을 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함하고,
티탄산칼륨을 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하며,
포타슘클로라이드를 시멘트 100중량부 기준으로 0.1 내지 4중량부로 더 포함하고,
돌로스톤을 시멘트 100중량부 기준으로 0.1 내지 5중량부로 더 포함하며,
페그마타이트를 시멘트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
트리칼슘알루미네이트를 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함하며,
질화알루미늄을 시멘트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
에틸 셀로솔브를 시멘트 100중량부 기준으로 5 내지 20중량부로 더 포함하는 단면보수용 모르타르 조성물.
Based on 100 parts by weight of cement,
5 to 30 parts by weight of calcium sulfoaluminate;
5 to 20 parts by weight of charcoal powder;
Cellulose fibers 1 to 10 parts by weight;
5 to 30 parts by weight of silica sand;
1 to 10 parts by weight of methyl methacrylate;
Limestone 2 to 10 parts by weight;
10 to 60 parts by weight of fly ash;
1 to 20 parts by weight of nano-ceramic particles;
3 to 15 parts by weight of an antioxidant;
1 to 10 parts by weight of an adhesion promoter;
1 to 10 parts by weight of a thickener; and
In a mortar composition for cross-section repair comprising 0.5 to 5 parts by weight of an antifoam,
Vinyl acetate-diethyl maleate is further included in an amount of 5 to 15 parts by weight based on 100 parts by weight of cement,
It further comprises 2 to 8 parts by weight of cocobetaine based on 100 parts by weight of cement,
Further comprising 1 to 3 parts by weight of sodium bentonite based on 100 parts by weight of cement,
It further comprises 0.1 to 3 parts by weight of Welan gum based on 100 parts by weight of cement,
Sodium stearate further comprises 1 to 3 parts by weight based on 100 parts by weight of cement,
It further comprises 0.1 to 2 parts by weight of starch phosphate ester based on 100 parts by weight of cement,
Further comprising 1 to 5 parts by weight of ammonium noniphenol ether sulfate based on 100 parts by weight of cement,
Further comprising 1 to 3 parts by weight of sodium rosinate based on 100 parts by weight of cement,
Further comprising 1 to 5 parts by weight of sulforaphane based on 100 parts by weight of cement,
It further comprises 1 to 3 parts by weight of potassium titanate based on 100 parts by weight of cement,
Potassium chloride is further included in an amount of 0.1 to 4 parts by weight based on 100 parts by weight of cement,
Dolostone further comprises 0.1 to 5 parts by weight based on 100 parts by weight of cement,
It further comprises 1 to 10 parts by weight of pegmatite based on 100 parts by weight of cement,
Tricalcium aluminate is further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of cement,
Further comprising 1 to 10 parts by weight of aluminum nitride based on 100 parts by weight of cement,
A mortar composition for cross-section repair further comprising 5 to 20 parts by weight of ethyl cellosolve based on 100 parts by weight of cement.
삭제delete 삭제delete 삭제delete 시공 대상면의 이물질을 제거한 후 청소하는 이물질 제거-청소단계;
상기 이물질 제거-청소단계가 종료된 대상면에 시멘트 100중량부 기준으로, 칼슘설포알루미네이트 5 내지 30중량부, 숯가루 5 내지 20중량부, 셀룰로오스 섬유 1 내지 10중량부, 규사 5 내지 30중량부, 메틸메타아크릴레이트 1 내지 10중량부, 석회석 2 내지 10중량부, 플라이애시 10 내지 60중량부, 나노세라믹 입자 1 내지 20중량부, 산화방지제 3 내지 15중량부, 부착증진제 1 내지 10중량부, 증점제 1 내지 10중량부, 및 소포제 0.5 내지 5중량부를 포함하는 단면보수용 모르타르 조성물에, 초산비닐-말레인산디에틸을 시멘트 100중량부 기준으로 5 내지 15중량부로 더 포함하고, 코코베타인을 시멘트 100중량부 기준으로 2 내지 8중량부로 더 포함하며, 나트륨벤토나이트를 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하고, 웰란 검을 시멘트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며, 소디윰스테아레이트를 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하고, 스타치 포스페이트 에스테르를 시멘트 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며, 암모늄 노니페놀 에테르설페이트를 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함하고, 로진산 나트륨을 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하며, 설포라판을 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함하고, 티탄산칼륨을 시멘트 100중량부 기준으로 1 내지 3중량부로 더 포함하며, 포타슘클로라이드를 시멘트 100중량부 기준으로 0.1 내지 4중량부로 더 포함하고, 돌로스톤을 시멘트 100중량부 기준으로 0.1 내지 5중량부로 더 포함하며, 페그마타이트를 시멘트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 트리칼슘알루미네이트를 시멘트 100중량부 기준으로 1 내지 5중량부로 더 포함하며, 질화알루미늄을 시멘트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 에틸 셀로솔브를 시멘트 100중량부 기준으로 5 내지 20중량부로 더 포함하는 단면보수용 모르타르 조성물을 물과 혼합한 뒤 타설하는 타설단계; 및
상기 타설단계가 종료된 후 시멘트 조성물을 양생하는 양생단계를 포함하는 단면보수용 모르타르 조성물의 시공방법.
Foreign matter removal-cleaning step of cleaning after removing foreign matter on the construction target surface;
Based on 100 parts by weight of cement, 5 to 30 parts by weight of calcium sulfoaluminate, 5 to 20 parts by weight of charcoal powder, 1 to 10 parts by weight of cellulose fiber, 5 to 30 parts by weight of silica sand Parts, 1 to 10 parts by weight of methyl methacrylate, 2 to 10 parts by weight of limestone, 10 to 60 parts by weight of fly ash, 1 to 20 parts by weight of nano-ceramic particles, 3 to 15 parts by weight of antioxidant, 1 to 10 parts by weight of adhesion promoter Parts, 1 to 10 parts by weight of a thickener, and 0.5 to 5 parts by weight of an antifoaming agent, in a mortar composition for cross-section repair, vinyl acetate-diethyl maleate is further included in an amount of 5 to 15 parts by weight based on 100 parts by weight of cement, and cocobetaine It further comprises 2 to 8 parts by weight based on 100 parts by weight of cement, further comprises 1 to 3 parts by weight of sodium bentonite based on 100 parts by weight of cement, and 0.1 to 3 parts by weight of Welan gum based on 100 parts by weight of cement, Sodium stearate is further included in an amount of 1 to 3 parts by weight based on 100 parts by weight of cement, starch phosphate ester is further included in an amount of 0.1 to 2 parts by weight based on 100 parts by weight of cement, and ammonium noniphenol ether sulfate is added in an amount of 100 parts by weight of cement. It further comprises 1 to 5 parts by weight based on 100 parts by weight of sodium rosinate, 1 to 3 parts by weight based on 100 parts by weight of cement, 1 to 5 parts by weight of sulforaphane based on 100 parts by weight of cement, and potassium titanate. It further comprises 1 to 3 parts by weight based on 100 parts by weight of cement, 0.1 to 4 parts by weight of potassium chloride based on 100 parts by weight of cement, and 0.1 to 5 parts by weight of dolostone based on 100 parts by weight of cement. , further comprising 1 to 10 parts by weight of pegmatite based on 100 parts by weight of cement, 1 to 5 parts by weight of tricalcium aluminate based on 100 parts by weight of cement, and 1 to 10 parts by weight of aluminum nitride based on 100 parts by weight of cement 5 parts by weight, and ethyl cellosolve 5 based on 100 parts by weight of cement A pouring step of mixing the mortar composition for cross-section repair, further comprising 20 parts by weight, with water, and then pouring; and
A construction method of a mortar composition for cross-section repair comprising a curing step of curing the cement composition after the pouring step is completed.
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KR102624383B1 (en) * 2023-04-20 2024-01-15 이혜옥 Eco-friendly Polymer Mortar Composition for Repair Section and Repairing Methods of Repair Section Using Thereof

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