KR101366581B1 - The manufacturing method for a flooring board - Google Patents

The manufacturing method for a flooring board Download PDF

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KR101366581B1
KR101366581B1 KR1020130124054A KR20130124054A KR101366581B1 KR 101366581 B1 KR101366581 B1 KR 101366581B1 KR 1020130124054 A KR1020130124054 A KR 1020130124054A KR 20130124054 A KR20130124054 A KR 20130124054A KR 101366581 B1 KR101366581 B1 KR 101366581B1
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South Korea
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paper
melamine resin
dipped
mixed
aluminum hydroxide
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KR1020130124054A
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Korean (ko)
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전경탁
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동위기업 (주)
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27MWORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M1/00Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching
    • B27M1/08Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching by multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27MWORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M3/00Manufacture or reconditioning of specific semi-finished or finished articles
    • B27M3/04Manufacture or reconditioning of specific semi-finished or finished articles of flooring elements, e.g. parqueting blocks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Floor Finish (AREA)

Abstract

The present invention relates to a flooring board manufacturing method which is developed for reinforcing the flame resistance, the antibiosis, and the wear resistance of the flooring board utilized as a flooring material as the flooring board is weak for fires and has concern about damage caused by being rotten or being impacted due to the nature of wood. The present invention continuously performs a series of the following steps: a first paper manufacturing step of dipping 25g/m^2 of transparent paper is dipped into 62g/m^2 of a resin which a melamine resin, an aluminum oxide, aluminum hydroxide, chitosan, and a surface-active material are mixed and drying the dipped paper; a second paper manufacturing step of dipping 80g/m^2 of decorative paper or sliced veneer into 62g/m^2 of a resin which a melamine resin, aluminum hydroxide, chitosan, and a surface-active material are mixed and drying the dipped paper; a third paper manufacturing step of dipping 180g/m^2 of colored paper into 84g/m^2 of a resin which a melamine resin and aluminum hydroxide are mixed and drying the dipped paper; a paper bonding step of completing a melamine resin sheet (HPL) by successively stacking 3 to 8 sheets of the dipped colored paper, the decorative paper, and the dipped transparent paper and cooling for 10 minutes after pressing at a pressure of 100kg/cm^2 and a temperature of 130°C for 30 minutes; and a finishing step of bonding the melamine resin sheet manufactured by the paper bonding step on the surface of a plywood. [Reference numerals] (AA) First paper manufacturing step of dipping 25g/m^2 of transparent paper is dipped into 62g/m^2 of a resin which a melamine resin, an aluminum oxide, aluminum hydroxide, chitosan, and a surface-active material are mixed and drying the dipped paper; (BB) Second paper manufacturing step of dipping 80g/m^2 of decorative paper or sliced veneer into 62g/m^2 of a resin which a melamine resin, aluminum hydroxide, chitosan, and a surface-active material are mixed and drying the dipped paper; (CC) Third paper manufacturing step of dipping 180g/m^2 of colored paper into 84g/m^2 of a resin which a melamine resin and aluminum hydroxide are mixed and drying the dipped paper; (DD) Paper bonding step of completing a melamine resin sheet (HPL) by successively stacking 3 to 8 sheets of the dipped colored paper, the decorative paper, and the dipped transparent paper and cooling for 10 minutes after pressing at a pressure of 100kg/cm^2 and a temperature of 130°C for 30 minutes; (EE) Finishing step of bonding the melamine resin sheet manufactured by the paper bonding step on the surface of a plywood.

Description

플로어링 보드 제조방법{The manufacturing method for a flooring board}The manufacturing method for a flooring board}

본 발명은 플로어링 보드 제조방법에 관한 것으로서, 좀더 상세하게 설명하면 바닥재로 주로 사용하는 플로어링 보드는 목재의 특성상 불에 약하며 썩거나 충격에 의하여 손상우려가 있으므로 이를 난연성과 항균성 및 내마모성을 강화시킬 수 있도록 하기 위하여 개발된 플로어링 보드 제조방법에 관한 것이다.
The present invention relates to a flooring board manufacturing method, in more detail, the flooring board mainly used as a flooring material is weak to the fire due to the nature of the wood and may be damaged by rot or impact, so that it can enhance the flame retardancy and antibacterial and wear resistance It relates to a flooring board manufacturing method developed to.

과거 학교와 같은 곳에서는 교실 바닥과 복도가 천연 목재로 이루어진 마루판으로 제조되었는데 산업화의 영향으로 점차 시멘트로 바닥이 바꿔가고 있었으나 최근에는 다시 목재로 이루어진 바닥이 학교뿐만 아니라 각 가정과 건물에 점차 확대되고 있다.In the past, classrooms and corridors were made of floorboards made of natural wood, but floors were gradually changed to cement due to industrialization. In recent years, wood floors have been gradually expanding not only in schools but also in homes and buildings. .

이는 친환경적인 소재에 대한 인기와 갈수록 증가하는 아토피 질환에 대한 대비책으로 목재는 미려한 무늬와 질감뿐만 아니라 온도나 습도를 조절하고 충격을 흡수하는 등 가장 쾌적하고 인체친화적인 주거용 소재이기 때문이다This is because the wood is the most comfortable and human-friendly residential material such as controlling the temperature and humidity and absorbing shock as well as beautiful patterns and textures as a countermeasure against the popularity of eco-friendly materials and increasing atopic diseases.

이러한 목질마루판은 합판에 천연무늬단판을 표면적층한 합판마루(KS명 : 무늬목치장 합판 플로어링보드), 섬유판에 멜라민수지시트(LPL, Low Pressure Laminate)를 표면적층한 강화마루(KS명 : 치장목질플로어링보드), 합판에 HPL(high Pressure Laminate)를 적층한 강마루(KS명 : 치장목질플로어링보드)가 주종을 이루며, 또한 합판마루와 유사한 형태이지만 무늬목보다는 두꺼운 천연단판을 사용한 원목마루 등 다양한 종류가 있다.These wood floorboards are laminated plywood (KS name: patterned plywood flooring board) laminated with natural patterned veneer on plywood and melamine resin sheet (LPL, Low Pressure Laminate) on fiberboard. Floor board) and steel floor laminated with high pressure laminate (HPL) on the plywood (KS name: stucco flooring board) .They are also similar to plywood flooring, but wood flooring using thick natural veneers rather than veneer. There is.

또한 각 종류의 마루판들은 용도에 따라 판의 두께를 달리하여 온돌용, 중보행용 등으로 사용하고 있다.In addition, each type of floorboards are used for ondol, heavy walking, etc. by varying the thickness of the board according to the use.

그 중에 무늬목치장 마루판이나 원목마루보다 표면 내구성이 뛰어나다고 알려진 치장목질 마루판(멜라민수지쉬트,HPL)은 데코페이퍼라는 인쇄종이를 사용하여 표면 목무늬를 만드는데 이것이 내마모성이 한계가 있어 종국에는 무늬가 닳아 없어져 상공간(학교, 다중이용시설)에는 사용에 주의가 필요하다.Among them, the decorative wood floorboard (melamine resin sheet, HPL), which is known to have better surface durability than the wood veneer or wooden floor, is made of printed paper called deco paper to make the surface wood pattern, which has limited wear resistance. As it disappears, attention must be paid to use in commercial spaces (schools, multi-use facilities).

또한 최근 아토피 질환을 겪고 있는 아이들이 늘어나면서 초등학교 교실 같은 경우 면역력이 취약한 어린이들을 위해서는 자연친화적이면서도 항균력을 가진 바닥재를 사용하는 것이 필수적이고 화재를 대비하여 불에 잘 타지않는 난연성을 가진 플로어링 보드가 필요한 상황이다.
In addition, as the number of children suffering from atopic disease has increased recently, it is essential for children with weak immunity, such as elementary school classrooms, to use nature-friendly and antimicrobial flooring, and need a flooring board with flame retardancy that does not burn well in case of fire. Situation.

(특허 문헌 1) 대한민국공개특허 제10-2004-0085578호 (2004년10월08일)(Patent Document 1) Republic of Korea Patent Publication No. 10-2004-0085578 (October 08, 2004) (특허 문헌 2) 대한민국공개특허 제10-2005-0064516호 (2005년06월29일)(Patent Document 2) Republic of Korea Patent Publication No. 10-2005-0064516 (June 29, 2005) (특허 문헌 3) 대한민국공개특허 제10-2006-0017252호 (2006년02월23일)(Patent Document 3) Korean Patent Publication No. 10-2006-0017252 (February 23, 2006) (특허 문헌 4) 대한민국공개특허 제10-2008-0102076호 (2008년11월24일)(Patent Document 4) Korean Patent Publication No. 10-2008-0102076 (November 24, 2008) (특허 문헌 5) 대한민국특허등록 제10-1299141-0000호 (2013년08월16일)(Patent Document 5) Korean Patent Registration No. 10-1299141-0000 (August 16, 2013)

본 발명은 상기와 같은 문제점을 해결하기 위하여 개발된 것으로서, 그 목적은 플로어링 보드가 기본 목재의 성질에 불에 잘 타지 않는 난연성과 미생물에 의하여 목질이 약화되거나 인체에 해로움을 주는 것을 방지하는 향균성 및 내마모성 등 다양한 부가적인 속성을 가질 수 있도록 하여 기능성과 친환경성을 높일 수 있는 플로어링 보드를 제조하는 방법을 개발하는 것에 있다.
The present invention was developed in order to solve the above problems, the object is that the flooring board is a flame retardant that does not burn well to the properties of the basic wood and the antibacterial to prevent the weakening of the wood or harmful to the human body by microorganisms And it is to develop a method of manufacturing a flooring board that can have a variety of additional properties, such as wear resistance and increase the functionality and environmental friendliness.

상기와 같은 목적을 달성하기 위하여 본 발명은 25g/㎡의 투명페이퍼를 멜라민수지, 산화알루미늄, 수산화알루미늄, 키토산, 계면활성재를 혼합한 수지에 62g/㎡의 양으로 함침한 후 건조하는 제1 페이퍼 제조과정과;In order to achieve the above object, the present invention impregnates 25 g / m 2 transparent paper with a resin mixed with melamine resin, aluminum oxide, aluminum hydroxide, chitosan, and a surfactant in an amount of 62 g / m 2, and then dried. Paper manufacturing process;

80g/㎡의 데코페이퍼 또는 무늬목을 멜라민수지, 수산화알루미늄, 키토산, 계면활성재를 혼합한 수지에 65g/㎡의 양으로 함침한 후 건조하는 제2 페이퍼 제조과정과;A second paper manufacturing process of impregnating 80 g / m 2 of decorative paper or veneer with a resin mixed with melamine resin, aluminum hydroxide, chitosan and a surfactant in an amount of 65 g / m 2 and drying;

180g/㎡의 유색페이퍼를 멜라민수지, 수산화알루미늄을 혼합한 수지에 84g/㎡의 양으로 함침한 후 건조하는 제3 페이퍼 제조과정과;A third paper manufacturing step of impregnating 180 g / m 2 colored paper with a melamine resin and aluminum hydroxide in an amount of 84 g / m 2 and then drying it;

각각의 함침된 유색페이퍼 3 ~ 8 장과 데코페이퍼와 투명페이퍼를 순차적으로 적층한 후 100kg/㎠의 압력과 130℃의 온도로 30분간 프레싱한 후 10분간 냉각하여 멜라민수지시트(HPL)를 완성하는 페이퍼 합지과정과;3-8 sheets of each impregnated colored paper, deco paper and transparent paper were laminated in this order and pressed for 30 minutes at a pressure of 100 kg / ㎠ and a temperature of 130 ° C., followed by cooling for 10 minutes to complete the melamine resin sheet (HPL). Paper lamination process;

상기 페이퍼 합지과정에서 제조된 멜라민수지시트를 합판 표면에 접착하는 마감과정의 일련의 공정이 연속적으로 이루어짐을 특징으로 한다.
The melamine resin sheet prepared in the paper lamination process is characterized in that a series of processes of the finishing process of bonding to the surface of the plywood is made continuously.

아울러, 상기 제1 페이퍼 제조과정에서는 산화알루미늄, 수산화알루미늄, 키토산, 계면활성제, 멜라민수지를 각각 부피비 3.5%, 16%, 2.5%, 1.8%, 76.2%의 비율로 혼합하고;In addition, in the first paper manufacturing process, aluminum oxide, aluminum hydroxide, chitosan, surfactants, melamine resin is mixed in a ratio of 3.5%, 16%, 2.5%, 1.8%, 76.2% by volume;

상기 제2 페이퍼 제조과정에서는 수산화알루미늄, 키토산, 계면활성제, 멜라민수지를 각각 부피비 15%, 2%, 2%, 81%의 비율로 혼합하며;In the second paper manufacturing process, aluminum hydroxide, chitosan, surfactant, and melamine resin are mixed at a volume ratio of 15%, 2%, 2%, and 81%, respectively;

상기 제3 페이퍼 제조과정에서는 수산화알루미늄, 멜라민수지를 각각 부피비 15%, 85%의 비율로 혼합함을 특징으로 한다.
In the third paper manufacturing process, aluminum hydroxide and melamine resin are mixed at a volume ratio of 15% and 85%, respectively.

상술한 바와 같이 본 발명은 플로어링 보드 중 치장목질 마루판이 표면의 페이퍼가 쉽게 벗겨지지 않고 화재시에도 불에 쉽게 타지 않고 목질에 각종 세균이 번식하는 것을 방지하여 위생적이며, 표면이 쉽게 스크레치가 발생하거나 손상되는 것을 방지할 수 있도록 하여 기능성과 친환경성을 높인 플로어링 보드를 제공하는 효과가 있다.
As described above, the present invention is a hygienic flooring board of the flooring board is not hygienic, the paper is not easily peeled off and does not burn easily in the fire even in the fire and hygienic by preventing the growth of various bacteria on the wood, the surface is easily scratched or It is effective to provide a flooring board with improved functionality and eco-friendliness by preventing damage.

도 1은 본 발명의 일 실시 예에 따른 블록도
도 2는 본 발명의 제1 페이퍼 제조과정을 나타낸 개념도
도 3은 본 발명의 제2 페이퍼 제조과정을 나타낸 개념도
도 4는 본 발명의 제3 페이퍼 제조과정을 나타낸 개념도
도 5는 완성된 플로어링 보드의 구조를 나타낸 개념도
1 is a block diagram according to an embodiment of the present invention.
2 is a conceptual diagram showing a first paper manufacturing process of the present invention
3 is a conceptual diagram showing a second paper manufacturing process of the present invention
4 is a conceptual diagram showing a third paper manufacturing process of the present invention
5 is a conceptual diagram showing the structure of the completed flooring board

이에 본 발명의 구성을 첨부된 도면에 의하여 당업자가 용이하게 이해하고 재현할 수 있도록 상세하게 설명하면 다음과 같다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명의 일 실시 예에 따른 블록도이고, 도 2는 본 발명의 제1 페이퍼 제조과정을 나타낸 개념도이며, 도 3은 본 발명의 제2 페이퍼 제조과정을 나타낸 개념도이고, 도 4는 본 발명의 제3 페이퍼 제조과정을 나타낸 개념도이며, 도 5는 완성된 플로어링 보드의 구조를 나타낸 개념도로서, 25g/㎡의 투명페이퍼(1)를 멜라민수지, 산화알루미늄, 수산화알루미늄, 키토산, 계면활성재를 혼합한 수지에 62g/㎡의 양으로 함침한 후 건조하는 제1 페이퍼 제조과정과;1 is a block diagram according to an embodiment of the present invention, Figure 2 is a conceptual diagram showing a first paper manufacturing process of the present invention, Figure 3 is a conceptual diagram showing a second paper manufacturing process of the present invention, Figure 4 is 5 is a conceptual diagram showing a process for manufacturing a third paper of the present invention, and FIG. 5 is a conceptual diagram showing the structure of a completed flooring board, wherein 25 g / m 2 transparent paper 1 is made of melamine resin, aluminum oxide, aluminum hydroxide, chitosan, and surfactant A first paper manufacturing process of impregnating the resin mixed with ash in an amount of 62 g / m 2 and then drying it;

80g/㎡의 데코페이퍼(2) 또는 무늬목을 멜라민수지, 수산화알루미늄, 키토산, 계면활성재를 혼합한 수지에 65g/㎡의 양으로 함침한 후 건조하는 제2 페이퍼 제조과정과;A second paper manufacturing process of impregnating 80 g / m 2 of decorative paper 2 or veneer with a resin mixed with melamine resin, aluminum hydroxide, chitosan and a surfactant in an amount of 65 g / m 2 and drying;

180g/㎡의 유색페이퍼(3)를 멜라민수지, 수산화알루미늄을 혼합한 수지에 84g/㎡의 양으로 함침한 후 건조하는 제3 페이퍼 제조과정과;A third paper manufacturing process of impregnating 180 g / m 2 colored paper 3 with a resin mixed with melamine resin and aluminum hydroxide in an amount of 84 g / m 2 and drying;

각각의 함침된 유색페이퍼(3) 3 ~ 8 장과 데코페이퍼(2)와 투명페이퍼(1)를 순차적으로 적층한 후 100kg/㎠의 압력과 130℃의 온도로 30분간 프레싱한 후 10분간 냉각하여 멜라민수지시트(HPL)를 완성하는 페이퍼 합지과정과;3-8 sheets of each impregnated colored paper (3), deco paper (2) and transparent paper (1) were sequentially stacked and pressed for 30 minutes at a pressure of 100 kg / ㎠ and a temperature of 130 ° C., followed by cooling for 10 minutes. And paper lamination process to complete the melamine resin sheet (HPL);

상기 페이퍼 합지과정에서 제조된 멜라민수지시트를 합판(4) 표면에 접착하는 마감과정의 일련의 공정이 연속적으로 이루어짐을 특징으로 하는 플로어링 보드 제조방법을 나타내었다.
The method of manufacturing a flooring board is characterized in that a series of finishing processes of adhering the melamine resin sheet prepared in the paper lamination process to the surface of the plywood 4 is successively performed.

본원에서 첨가된 산화알루미늄은 높은 경도(15 ~ 19GPa)를 가진 것으로 가장 외측 표면을 이루는 투명페이퍼(1)에 함침시키도록 하여 표면 내구성을 증대시켜 내마모성을 크게 늘리며, 높은 기계강도(300 ~ 630MPa)와 압축강도(2000 ~ 4000MPa)를 얻을 수 있으며 찍힘과 긁힘 및 스크래치에 강한 특성을 제공한다.Aluminum oxide added in the present application has a high hardness (15 ~ 19GPa) to be impregnated into the transparent paper (1) forming the outermost surface to increase the surface durability to greatly increase the wear resistance, high mechanical strength (300 ~ 630MPa) And compressive strength (2000 ~ 4000MPa) can be obtained, and it is strong against scratches, scratches and scratches.

또한 우수한 전기 절연성을 가진 것으로 건조한 겨울철 바닥으로부터 정전기 방지 및 생체불활성을 가지며 무독성으로 인체에 무해한 특성을 가지고 있다.In addition, it has excellent electrical insulation and has antistatic and bioinert properties from dry winter floors and is non-toxic and harmless to humans.

시험항목 Test Items 기준 standard 시 험 결 과     Test result 일반HPLGeneral HPL 본원의HPLHPL herein 내마모성Wear resistance KS F 3126 7000회 이상KS F 3126 More than 7000 times 85008500 2500025000 내충격성Impact resistance 방사상의 균열,파괴 치장재의 박리가 생기지 않을것No radial cracking or deterioration of the decorative material 이상없음clear 이상없음clear 스크래치경도Scratch hardness 3N이상      3N or more 7.27.2 19.319.3 전기절연 (대전방지)Electrical Insulation (Antistatic) 1X101X10 1X10 1X10 항균성Antimicrobial activity 시험균액을 35 RH 90%에서 24시간 정치 배양후 균수 측정Test bacteria were counted after standing for 24 hours at 35 RH 90% 균감소율 68%Average reduction rate 68% 균감소율 99%99% reduction rate

위 시험결과에서 나타나듯이 내마모성, 스크래치경도, 전기절연 등은 3배 이상의 성능향상을 보였고 내충격성은 수치상으로 나타나지는 않았지만 반복충격에는 잘견디는 것으로 나타났으며 항균성도 향상된 성능을 보였다.
As shown in the above test results, wear resistance, scratch hardness, electrical insulation, etc. showed a three times improvement in performance, and the impact resistance did not appear numerically, but it was found to withstand repeated shocks and antibacterial performance was also improved.

또한, 수산화알루미늄은 대표적인 무기질계 난연 소재로 유기계열의 소재처럼 열에 의해 휘발되지 않으며 분해되어 물, 이산화탄소, 이산화황, 염화수소와 같은 불연성 기체를 방출하게 되어 흡열반응을 한다.In addition, aluminum hydroxide is a representative inorganic flame retardant material, which is not volatilized by heat like organic materials, and decomposes to release an incombustible gas such as water, carbon dioxide, sulfur dioxide, and hydrogen chloride.

또한 화학내열성, 투명성, 특히 난연성 등의 특성이 우수한 무독성 무기화학재료로 나노급 분말로 첨가하여 함침하면 우수한 난연성능을 발휘한다.In addition, non-toxic inorganic chemical material with excellent chemical heat resistance, transparency, and especially flame retardancy, exhibits excellent flame retardant performance when added as a nano-grade powder and impregnated.

방염시험항목       Flameproof Test Items 기준          standard 시 험 결 과      Test result 일반HPLGeneral HPL 본원의 HPLHPL of the present 잔염시간        Afterglow time 5초이내       Within 5 seconds 4.7   4.7 0    0 잔신시간        Burst time 20초이내       Within 20 seconds 18.5   18.5 0    0 탄화면적        Ammunition 40cm이내     Within 40cm 36.1   36.1 12.7  12.7 탄화길이        Carbonization length 20cm이내      Within 20cm 11    11 4.9   4.9 접염횟수        Number of folds 3회이상      3 or more times

위 시험결과에서 나타나듯이 일반 HPL은 최초에 인화되어 잔염이 발생했으나 본원의 HPL은 인화되지 않았고 탄화면적도 일반 HPL보다 3배정도 작았다
As shown in the above test results, the general HPL was first printed, and afterglow occurred, but the HPL of the present application was not printed and the burn area was about three times smaller than the general HPL.

또한, 키토산은 전기적으로 양(+)전하를 가진 폴리머로 분자량이 200,000이상인 불용성 고분자로 키토산의 아미노기(NH2+)의 (+)이온이 미생물의 (-)이온의 성질을 가지고 있는 세포막과 결합하여 미생물의 증식을 억제하는 항균작용을 하는 천연항균 물질로 인체에 무해하며 방부 효과도 있다.In addition, chitosan is an electrically charged polymer that has a molecular weight of 200,000 or more. The chitosan is an insoluble polymer. It is a natural antibacterial substance that acts as an antimicrobial agent to suppress the growth of, harmless to the human body and also has an antiseptic effect.

즉, 세균의 번식을 방지하여 세균에 의하여 목질에 약해지거나 증식된 세균이 인체에 영향을 주는 것을 방지하기 위한 것이다.
That is, to prevent the growth of bacteria to prevent the weakened or multiplied bacteria by wood to affect the human body.

이때 본 발명에서는 첨가하는 물질의 비율을 상기 제1 페이퍼 제조과정에서는 산화알루미늄, 수산화알루미늄, 키토산, 계면활성제, 멜라민수지를 각각 부피비 3.5%, 16%, 2.5%, 1.8%, 76.2%의 비율로 혼합하고;At this time, in the present invention, the proportion of the material to be added is in the ratio of 3.5%, 16%, 2.5%, 1.8%, and 76.2% by volume of aluminum oxide, aluminum hydroxide, chitosan, surfactant, and melamine resin, respectively, in the first paper manufacturing process. To mix;

상기 제2 페이퍼 제조과정에서는 수산화알루미늄, 키토산, 계면활성제, 멜라민수지를 각각 부피비 15%, 2%, 2%, 81%의 비율로 혼합하며;In the second paper manufacturing process, aluminum hydroxide, chitosan, surfactant, and melamine resin are mixed at a volume ratio of 15%, 2%, 2%, and 81%, respectively;

상기 제3 페이퍼 제조과정에서는 수산화알루미늄, 멜라민수지를 각각 부피비 15%, 85%의 비율로 혼합하도록 하는 보다 구체적인 실시 예를 제시하였다.In the third paper manufacturing process, a more specific embodiment for mixing aluminum hydroxide and melamine resin at a volume ratio of 15% and 85% was presented.

상기 실시 예에 의하여 각 물질이 최적의 기능을 가질 수 있도록 하며 혼합은 키토산의 유화작용이 우수하여 멜라민 수지에 먼저 배합 후 나머지 재료들을 서서히 첨가하여 교반하는 것으로 본원의 계면활성재는 침전물이 생기지 않도록 하는 역할을 하는 것이다.
According to the above embodiment, each material may have an optimal function, and the mixing is excellent in emulsification of chitosan, and then mixed with melamine resin first, and then the remaining materials are slowly added and stirred so that the surfactant of the present application does not generate a precipitate. It is to play a role.

또한 본원을 적용함에 있어서, 별도로 구비되는 혼합탱크(5)에서 각 물질을 혼합한 후 함침탱크(6) 혼합액을 수용하도록 하고, 각 페이퍼는 롤의 형태로 공급된 후 함침탱크(6)에 순차적으로 거치도록 한 후 별도로 제작되는 드라이어(7)를 통과하여 건조되도록 함이 바람직하다.
In addition, in applying the present application, after mixing each material in the mixing tank (5) provided separately to accommodate the mixed solution of the impregnation tank (6), each paper is supplied in the form of a roll and sequentially in the impregnation tank (6) After passing through it is preferable to pass through the dryer 7 is produced separately.

1 : 투명페이퍼
2 : 데코페이퍼
3 : 유색페이퍼
4 : 합판
5 : 혼합탱크
6 : 함침탱크
7 : 드라이어
1: transparent paper
2: Deco Paper
3: colored paper
4: plywood
5: mixing tank
6: impregnation tank
7: dryer

Claims (2)

25g/㎡의 투명페이퍼(1)를 멜라민수지, 산화알루미늄, 수산화알루미늄, 키토산, 계면활성재를 혼합한 수지에 62g/㎡의 양으로 함침한 후 건조하는 제1 페이퍼 제조과정과;
80g/㎡의 데코페이퍼(2) 또는 무늬목을 멜라민수지, 수산화알루미늄, 키토산, 계면활성재를 혼합한 수지에 65g/㎡의 양으로 함침한 후 건조하는 제2 페이퍼 제조과정과;
180g/㎡의 유색페이퍼(3)를 멜라민수지, 수산화알루미늄을 혼합한 수지에 84g/㎡의 양으로 함침한 후 건조하는 제3 페이퍼 제조과정과;
각각의 함침된 유색페이퍼(3) 3 ~ 8 장과 데코페이퍼(2)와 투명페이퍼(1)를 순차적으로 적층한 후 100kg/㎠의 압력과 130℃의 온도로 30분간 프레싱한 후 10분간 냉각하여 멜라민수지시트(HPL)를 완성하는 페이퍼 합지과정과;
상기 페이퍼 합지과정에서 제조된 멜라민수지시트를 합판(4) 표면에 접착하는 마감과정의 일련의 공정이 연속적으로 이루어짐을 특징으로 하는 플로어링 보드 제조방법.
A first paper manufacturing process of impregnating 25 g / m 2 transparent paper 1 with a resin mixed with melamine resin, aluminum oxide, aluminum hydroxide, chitosan, and a surfactant in an amount of 62 g / m 2 and drying;
A second paper manufacturing process of impregnating 80 g / m 2 of decorative paper 2 or veneer with a resin mixed with melamine resin, aluminum hydroxide, chitosan and a surfactant in an amount of 65 g / m 2 and drying;
A third paper manufacturing process of impregnating 180 g / m 2 colored paper 3 with a resin mixed with melamine resin and aluminum hydroxide in an amount of 84 g / m 2 and drying;
3-8 sheets of each impregnated colored paper (3), deco paper (2) and transparent paper (1) were sequentially stacked and pressed for 30 minutes at a pressure of 100 kg / ㎠ and a temperature of 130 ° C., followed by cooling for 10 minutes. And paper lamination process to complete the melamine resin sheet (HPL);
The method of manufacturing a flooring board, characterized in that the series of finishing the process of adhering the melamine resin sheet prepared in the paper lamination process to the surface of the plywood (4) is made continuously.
제 1항에 있어서, 상기 제1 페이퍼 제조과정에서는 산화알루미늄, 수산화알루미늄, 키토산, 계면활성제, 멜라민수지를 각각 부피비 3.5%, 16%, 2.5%, 1.8%, 76.2%의 비율로 혼합하고;
상기 제2 페이퍼 제조과정에서는 수산화알루미늄, 키토산, 계면활성제, 멜라민수지를 각각 부피비 15%, 2%, 2%, 81%의 비율로 혼합하며;
상기 제3 페이퍼 제조과정에서는 수산화알루미늄, 멜라민수지를 각각 부피비 15%, 85%의 비율로 혼합함을 특징으로 하는 플로어링 보드 제조방법.
The method of claim 1, wherein in the manufacturing process of the first paper, aluminum oxide, aluminum hydroxide, chitosan, surfactant, melamine resin are mixed at a volume ratio of 3.5%, 16%, 2.5%, 1.8%, and 76.2%, respectively;
In the second paper manufacturing process, aluminum hydroxide, chitosan, surfactant, and melamine resin are mixed at a volume ratio of 15%, 2%, 2%, and 81%, respectively;
In the third paper manufacturing process, flooring board manufacturing method, characterized in that the aluminum hydroxide and melamine resin is mixed in a volume ratio of 15%, 85% respectively.
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Publication number Priority date Publication date Assignee Title
KR101439941B1 (en) 2014-04-25 2014-09-12 제이더블유우드텍(주) Manufacturing method high pressure laminate sheet
KR101557058B1 (en) 2014-05-22 2015-10-05 (주) 미래 The manufacturing method for a flooring board
CN106346567A (en) * 2016-11-18 2017-01-25 南京林业大学 Manufacturing method for outdoor wood-bamboo product
CN109774285A (en) * 2017-11-10 2019-05-21 丹阳市博元安全生产服务有限公司 A kind of plywood without formaldehyde release

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KR200384030Y1 (en) 2005-01-14 2005-05-11 황기용 The quasi-incombustibility decorative plywood mosaic floor board
JP2010106654A (en) 2008-09-30 2010-05-13 Dainippon Printing Co Ltd Decorative sheet for floor material, and decorative material for flooring

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JP2000303393A (en) 1998-12-11 2000-10-31 Ibiden Co Ltd Composite hardened body and composite building material
KR20020030291A (en) * 2000-10-17 2002-04-25 성재갑 Waterproof Plywood Flooring Laminated with High Pressure Melamine Laminate Reinforced with Glass Fiber Layer and the Method for the Manufacturing thereof
KR200384030Y1 (en) 2005-01-14 2005-05-11 황기용 The quasi-incombustibility decorative plywood mosaic floor board
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101439941B1 (en) 2014-04-25 2014-09-12 제이더블유우드텍(주) Manufacturing method high pressure laminate sheet
KR101557058B1 (en) 2014-05-22 2015-10-05 (주) 미래 The manufacturing method for a flooring board
CN106346567A (en) * 2016-11-18 2017-01-25 南京林业大学 Manufacturing method for outdoor wood-bamboo product
CN109774285A (en) * 2017-11-10 2019-05-21 丹阳市博元安全生产服务有限公司 A kind of plywood without formaldehyde release

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