KR101310945B1 - Apparatus for purification of polluted air with absorption means attached a catalyst and production method for absorption means attached a catalyst - Google Patents

Apparatus for purification of polluted air with absorption means attached a catalyst and production method for absorption means attached a catalyst Download PDF

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Publication number
KR101310945B1
KR101310945B1 KR1020110044333A KR20110044333A KR101310945B1 KR 101310945 B1 KR101310945 B1 KR 101310945B1 KR 1020110044333 A KR1020110044333 A KR 1020110044333A KR 20110044333 A KR20110044333 A KR 20110044333A KR 101310945 B1 KR101310945 B1 KR 101310945B1
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South Korea
Prior art keywords
catalyst
unit
purifying
adsorption
air
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KR1020110044333A
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Korean (ko)
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KR20120126493A (en
Inventor
이현재
김세중
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주식회사 엔바이온
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Priority to KR1020110044333A priority Critical patent/KR101310945B1/en
Priority to CN201280023029.0A priority patent/CN103517752A/en
Priority to PCT/KR2012/003696 priority patent/WO2012153999A2/en
Publication of KR20120126493A publication Critical patent/KR20120126493A/en
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Publication of KR101310945B1 publication Critical patent/KR101310945B1/en

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
    • F24F8/15—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means
    • F24F8/167—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means using catalytic reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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  • Catalysts (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

본 발명은 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치 및 촉매가 부착된 흡착부의 제조 방법에 관한 것이다. 보다 상세하게는 오염 공기에 포함된 가스상 오염 물질을 효과적으로 정화하는 것이 가능한 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치 및 촉매가 부착된 흡착부의 제조 방법에 관한 것이다. 본 발명은 외부로부터 유입되는 공기에 포함된 가스상 오염 물질을 흡착 및 정화하기 위하여 상기 가스상 오염 물질이 흡착되는 흡착 부재와 상기 흡착된 가스상 오염 물질을 산화 반응에 의해 정화하는 촉매 부재를 포함하는 구조물로 이루어지는 제1 정화부; 상기 제1 정화부 측으로 공기를 공급하여 상기 제1 정화부에 흡착된 가스상 오염 물질을 탈착시키는 탈착 수단; 및 상기 제1 정화부로부터 탈착된 가스상 오염 물질을 포함하는 공기를 유입시켜 정화하는 제2 정화부를 포함하며, 상기 제1 정화부는 회전하며 상기 탈착부에 의해 상기 제1 정화부의 미리 결정된 영역에 흡착된 가스상 오염 물질을 탈착시키는 것을 특징으로 한다. 본 발명에 의하면 유입되는 공기에 포함된 가스상 오염 물질을 1차 정화 및 2차 정화하는 것이 가능하므로 오염 공기 정화 장치의 정화 성능을 향상시킬 수 있는 효과를 갖는다.The present invention relates to a contaminated air purifying apparatus having an adsorbent with a catalyst and a method for producing the adsorbent with a catalyst. More specifically, the present invention relates to a polluted air purification device having a catalyst attached adsorption unit capable of effectively purifying gaseous contaminants contained in polluted air and a method of producing an adsorption unit equipped with a catalyst. The present invention provides a structure including an adsorption member to which the gaseous contaminants are adsorbed and a catalyst member to purify the adsorbed gaseous contaminants by an oxidation reaction in order to adsorb and purify gaseous contaminants contained in air introduced from the outside. A first purifying unit formed; Desorption means for supplying air to the first purifying part to desorb the gaseous contaminants adsorbed to the first purifying part; And a second purifying unit for introducing and purifying air containing gaseous contaminants desorbed from the first purifying unit, wherein the first purifying unit rotates and is adsorbed to a predetermined region of the first purifying unit by the desorption unit. Characterized in that the desorbed gaseous contaminants. According to the present invention, since the gaseous pollutants contained in the incoming air can be purified first and secondly, the purification performance of the polluted air purification device can be improved.

Figure R1020110044333
Figure R1020110044333

Description

촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치 및 촉매가 부착된 흡착부의 제조 방법{Apparatus for purification of polluted air with absorption means attached a catalyst and production method for absorption means attached a catalyst}Apparatus for purification of polluted air with absorption means attached a catalyst and production method for absorption means attached a catalyst}

본 발명은 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치 및 촉매가 부착된 흡착부의 제조 방법에 관한 것이다. 보다 상세하게는 오염 공기에 포함된 가스상 오염 물질을 효과적으로 정화하는 것이 가능한 촉매가 부착돈 흡착부를 갖는 오염 공기 정화 장치 및 촉매가 부착된 흡착부의 제조 방법에 관한 것이다.The present invention relates to a contaminated air purifying apparatus having an adsorbent with a catalyst and a method for producing the adsorbent with a catalyst. More specifically, the present invention relates to a contaminated air purifying device having a catalyst adsorbed portion capable of effectively purifying gaseous contaminants contained in contaminated air, and a method of producing an adsorbed portion with a catalyst.

일반적으로 공기 정화 장치는 가정, 다중 이용시설, 또는 산업현장 등에서 공기에 포함된 세균, 악취, 휘발성 유기화합물, 또는 유해성분 등의 오염 물질을 처리하여 쾌적한 공기를 제공하는 수단으로 폭넓게 활용되고 있다.In general, the air purifier is widely used as a means for providing a pleasant air by treating contaminants such as bacteria, odors, volatile organic compounds, or harmful components contained in the air at home, multi-use facilities, or industrial sites.

이러한 특징을 갖는 공기 정화 장치는 크게 먼지나 세균 등의 입자상 물질을 처리하는 복수의 필터와 악취, 휘발성 유기화합물 및 유해성분 등의 가스상 물질을 처리하는 탈취필터로 구성되며, 입자상 물질을 처리하는 필터의 경우 입자의 체효과(sieving)를 이용하는 필터와 정전기를 이용한 전기 집진기식 정전필터가 주로 활용되고 있다.The air purifying device having such characteristics is composed of a plurality of filters for treating particulate matter such as dust and bacteria, and a deodorizing filter for treating gaseous substances such as odors, volatile organic compounds and harmful components, and a filter for treating particulate matter. In the case of the filter using the sieve (sieving) of the particles and the electrostatic precipitator electrostatic filter using the static electricity is mainly utilized.

또한, 가스상 물질을 처리하는 탈취필터의 경우 활성판과 제올라이트를 이용하는 고정상 흡착필터와 오존을 이용한 오존산화필터 등이 주로 활용되고 있다.In addition, in the case of a deodorizing filter for treating gaseous substances, a fixed bed adsorption filter using an active plate and zeolite and an ozone oxidation filter using ozone are mainly used.

그러나, 고정상 흡착필터의 경우, 저농도에서 평형 흡착력이 낮아지고 흡착된 흡착성분이 물리적인 결합에 의해 흡착되어 있어 외부 온도 및 농도 등의 외부환경에 의해 재탈착되는 현상이 일어나고 또한 자체 재생기능을 갖추고 있지 못해 수명도 제한되는 문제점이 있다.However, in the case of the fixed bed adsorption filter, the equilibrium adsorption force is low at low concentrations, and the adsorbed adsorption components are adsorbed by physical bonding, so that the adsorption of the adsorption by external environment such as the external temperature and concentration occurs, and also has its own regeneration function. There is a problem that the life is limited.

또한, 오존을 이용한 오존산화필터의 경우 오존산화력을 이용한 시스템으로 필터의 교체 없이 장기간 사용할 수 있는 장점은 있으나 환경오염물질인 오존을 이용함으로써 미반응된 오존이 외부로 유출될 경우 천식 및 알러지 등을 일으키는 문제점이 있다.In addition, ozone oxidation filter using ozone has the advantage that it can be used for a long time without replacing the filter with ozone oxidation power, but if unreacted ozone is leaked to the outside by using ozone, an environmental pollutant, it can prevent asthma and allergy. There is a problem that causes.

본 발명은 상기와 같은 문제점을 해결하고자 안출된 것으로 유입되는 공기에 포함된 가스상 오염 물질에 대한 정화를 보다 효율적으로 수행함과 동시에 장기간 사용에도 지속적인 정화 효율을 유지할 수 있는 흡착부를 갖는 오염 공기 정화 장치 및 흡착부의 제조 방법을 제공하는 것을 목적으로 한다.The present invention provides a contaminated air purifying apparatus having an adsorption unit capable of more efficiently purifying gaseous contaminants contained in the air introduced to solve the above problems and at the same time maintaining a continuous purifying efficiency even for long-term use. It aims at providing the manufacturing method of an adsorption part.

상기 목적을 달성하기 위한 본 발명에 따른 흡착부를 갖는 오염 공기 정화 장치는 외부로부터 유입되는 공기에 포함된 가스상 오염 물질을 흡착 및 정화하기 위하여 상기 가스상 오염 물질이 흡착되는 흡착 부재와 상기 흡착된 가스상 오염 물질을 산화 반응에 의해 정화하는 촉매 부재를 포함하는 구조물로 이루어지는 제1 정화부; 상기 제1 정화부 측으로 공기를 공급하여 상기 제1 정화부에 흡착된 가스상 오염 물질을 탈착시키는 탈착 수단; 및 상기 제1 정화부로부터 탈착된 가스상 오염 물질을 포함하는 공기를 유입시켜 정화하는 제2 정화부를 포함하며, 상기 제1 정화부는 회전하며 상기 탈착부에 의해 상기 제1 정화부의 미리 결정된 영역에 흡착된 가스상 오염 물질을 탈착시키는 것을 특징으로 한다.Contaminated air purification apparatus having an adsorption unit according to the present invention for achieving the above object is an adsorption member and the adsorbed gaseous pollution adsorbed to the gaseous pollutants in order to adsorb and purify the gaseous pollutants contained in the air flowing from the outside A first purifying unit comprising a structure including a catalyst member for purifying a substance by an oxidation reaction; Desorption means for supplying air to the first purifying part to desorb the gaseous contaminants adsorbed to the first purifying part; And a second purifying unit for introducing and purifying air containing gaseous contaminants desorbed from the first purifying unit, wherein the first purifying unit rotates and is adsorbed to a predetermined region of the first purifying unit by the desorption unit. Characterized in that the desorbed gaseous contaminants.

또한, 상기 촉매 부재는 백금, 로듐, 코발트, 몰리브덴 또는 팔라듐 중 적어도 하나 이상을 포함하여 형성될 수 있다.In addition, the catalyst member may be formed including at least one of platinum, rhodium, cobalt, molybdenum or palladium.

또한, 상기 산화 반응은 상기 탈착 부재에 의한 오염 물질 탈착 시 이루어질 수 있다.In addition, the oxidation reaction may be performed when the pollutant is desorbed by the desorption member.

또한, 상기 흡착 부재는 제올라이트, 활성 알루미나, 또는 다공성 실리카 중 적어도 하나 이상을 포함하여 형성될 수 있다.In addition, the adsorption member may be formed including at least one of zeolite, activated alumina, or porous silica.

또한, 상기 제2 정화부는 상기 제1 정화부로부터 탈착된 상기 가스상 오염 물질을 포함하는 공기가 유입된 후 열교환이 이루어지는 열교환부, 상기 열교환부를 통과한 후 유입된 상기 가스상 오염 물질을 포함하는 공기로부터 상기 가스상 오염 물질과 수분을 획득하는 오염 물질 획득부, 및 상기 오염 물질 획득부를 통과한 후 유입되는 공기를 상기 제1 정화부 측으로 공급하는 공기 공급부를 포함할 수 있다.The second purifying unit may further include a heat exchange unit in which heat is exchanged after the air containing the gaseous pollutant desorbed from the first purifying unit is introduced, and from the air including the gaseous pollutant introduced after passing through the heat exchange unit. It may include a contaminant obtaining unit for obtaining the gaseous pollutant and water, and an air supply unit for supplying air introduced after passing through the pollutant obtaining unit to the first purifying unit.

또한, 상기 오염 물질 획득부는 응축기일 수 있다.In addition, the contaminant obtaining unit may be a condenser.

또한, 상기 제1 정화부의 전측에 위치하여 상기 외부로부터 유입되는 공기에 포함된 입자상 오염 물질을 제거하는 오염 물질 제거부를 더 포함할 수 있다.The apparatus may further include a contaminant removing unit located at the front side of the first purifying unit to remove particulate contaminants contained in the air introduced from the outside.

또한, 상기 목적을 달성하기 위한 본 발명에 따른 촉매가 부착된 흡착부 제조 방법은 (a) 용액에 촉매 부재를 투입한 후 상기 촉매 부재를 용해시키는 단계;(b) 상기 촉매 부재가 용해된 용액에 흡착 부재를 투입하는 단계; (c) 상기 흡착 부재가 투입된 용액을 초음파 처리하여 상기 흡착 부재에 상기 촉매 부재를 부착시키는 단계; (d) 상기 촉매 부재가 부착된 흡착 부재를 건조시키는 단계; 및 (e) 상기 촉매가 부착된 흡착 부재를 촉매 활성화시키는 단계를 포함하는 것을 특징으로 한다.In addition, in order to achieve the above object, there is provided a method for producing a catalyst-attached adsorption unit according to the present invention comprising the steps of: (a) dissolving the catalyst member after adding the catalyst member to a solution; (b) a solution in which the catalyst member is dissolved Injecting an adsorption member into the apparatus; (c) attaching the catalyst member to the adsorption member by sonicating the solution into which the adsorption member is introduced; (d) drying the adsorption member to which the catalyst member is attached; And (e) catalytically activating the adsorption member to which the catalyst is attached.

본 발명에 의하면 유입되는 공기에 포함된 가스상 오염 물질을 1차 정화 및 2차 정화하는 것이 가능하므로 오염 공기 정화 장치의 정화 성능을 향상시킬 수 있는 효과를 갖는다.According to the present invention, since the gaseous pollutants contained in the incoming air can be purified first and secondly, the purification performance of the polluted air purification device can be improved.

또한, 촉매 산화에 의해 이루어지는 가스상 오염 물질의 정화 과정이 저온에서 이루어져 별도의 공기 가열 장치, 산화 장치, 및 온도 유지 장치 등이 요구되지 않으므로 오염 공기 정화 장치의 크기와 제조 비용을 감소시킬 수 있다.In addition, since the purification process of the gaseous contaminants by catalytic oxidation is performed at a low temperature, a separate air heating device, an oxidation device, and a temperature maintaining device are not required, so that the size and manufacturing cost of the polluted air purification device can be reduced.

또한, 가스상 오염 물질을 액화시켜 획득하는 것이 가능하므로 가스상 오염 물질의 회수가 보다 용이하게 이루어질 수 있다.In addition, since it is possible to obtain by liquefying gaseous contaminants, recovery of the gaseous contaminants can be made easier.

또한, 가스상 오염 물질의 정화가 이루어지는 제1 정화부에서 가스상 오염 물질의 흡착 및 탈착이 계속적으로 이루어지므로 제1 정화부의 정화 효율을 지속적으로 유지함과 동시에 제1 정화부의 수명을 크게 향상시킬 수 있는 효과를 갖는다.In addition, since the adsorption and desorption of the gaseous contaminants is continuously performed in the first purifying unit where the gaseous contaminants are purified, the effect of improving the lifespan of the first purifying unit while maintaining the purification efficiency of the first purifying unit continuously. Has

도 1은 본 발명의 제1 실시예에 따른 촉매가 부착된 흡착부를 갖는 오염 공기 처리 장치의 블록도,
도 2와 도 3은 도 1의 제1 정화부의 동작 참고도,
도 4는 본 발명의 제2 실시예에 따른 촉매가 부착된 흡착부를 갖는 오염 공기 처리 장치의 블록도, 및
도 5는 촉매가 부착된 흡착부 제조 방법에 대한 순서도 이다.1 is a block diagram of an apparatus for treating polluted air having an adsorption unit to which a catalyst is attached according to a first embodiment of the present invention;
2 and 3 is a reference diagram of the operation of the first purification unit of FIG.
4 is a block diagram of an apparatus for treating polluted air having an adsorption unit to which a catalyst is attached according to a second embodiment of the present invention, and
5 is a flowchart illustrating a method of manufacturing a catalyst adsorbed portion.

이하, 본 발명의 바람직한 실시예를 첨부한 도면들을 참조하여 상세하게 설명한다. 우선 각 도면의 구성 요소들에 참조 부호를 첨가함에 있어서, 동일한 구성 요소들에 대해서는 비록 다른 도면상에 표시되더라도 가능한 한 동일한 부호를 가지도록 하고 있음에 유의해야 한다. 또한, 본 발명을 설명함에 있어서, 관련된 공지 구성 또는 기능에 대한 구체적인 설명이 본 발명의 요지를 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명은 생략한다. 또한, 이하에서 본 발명의 바람직한 실시예를 설명할 것이나, 본 발명의 기술적 사상은 이에 한정하거나 제한되지 않고 당업자에 의해 실시될 수 있음은 물론이다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. In the drawings, the same reference numerals are used to designate the same or similar components throughout the drawings. In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather unclear. Further, the preferred embodiments of the present invention will be described below, but it is needless to say that the technical idea of the present invention is not limited thereto and can be practiced by those skilled in the art.

도 1은 본 발명의 제1 실시예에 따른 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치에 대한 블록도, 도 2와 도 3은 도 1의 제1 정화부의 동작 참고도이다.1 is a block diagram of a polluted air purifying apparatus having an adsorption unit with a catalyst according to a first embodiment of the present invention, and FIGS. 2 and 3 are reference diagrams of operations of the first purifying unit of FIG. 1.

도 1 내지 도 3에 도시된 바와 같이 본 발명의 제1 실시예에 따른 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치(1)는 제1 정화부(10), 탈착 수단(20), 및 제2 정화부(30)를 포함한다.As shown in FIGS. 1 to 3, the polluted air purifying apparatus 1 having the adsorption unit with the catalyst according to the first embodiment of the present invention includes a first purifying unit 10, a desorption means 20, and a first purifying unit 10. 2, the purification unit 30 is included.

제1 정화부(10)는 외부로부터 유입되는 공기(a1)에 포함된 가스상 오염 물질을 흡착 및 정화한다.The first purifying unit 10 adsorbs and purifies the gaseous pollutant contained in the air a1 introduced from the outside.

이때, 제1 정화부(10)는 유입되는 공기(a1)에 포함된 가스상 오염 물질을 흡착하는 흡착 부재와 상기 흡착 부재에 흡착된 가스상 오염 물질을 산화 반응에 의해 정화하는 촉매 부재를 포함하는 구조물로 이루어질 수 있다.In this case, the first purification unit 10 includes a structure including an adsorption member for adsorbing gaseous contaminants contained in the air a1 introduced therein and a catalyst member for purifying gaseous contaminants adsorbed on the adsorption member by an oxidation reaction. It may be made of.

또한, 제1 정화부(10)는 미리 결정된 방향으로 회전할 수 있으며, 상기 촉매 부재와 상기 가스상 오염 물질의 산화 반응은 저온(예를 들어 20도 내지 200도)에서 이루어질 수 있다.In addition, the first purifying unit 10 may rotate in a predetermined direction, and the oxidation reaction of the catalyst member and the gaseous pollutant may be performed at a low temperature (for example, 20 to 200 degrees).

또한, 상기 흡착 부재는 제올라이트, 활성 알루미나, 또는 다공성 실리카 중 적어도 하나 이상을 포함하여 형성될 수 있고, 상기 촉매 부재는 백금, 로듐, 코발트, 몰리브덴, 또는 팔라듐 중 적어도 하나 이상을 포함하여 형성될 수 있으며, 상기 흡착 부재와 상기 촉매 부재를 포함하는 구조물의 일 예로 상기 흡착 부재가 다공성 실리카인 경우 상기 촉매 부재가 상기 흡착 부재에 형성되는 다수의 홀에 코팅되는 형태로 구성되는 것이 가능하다.In addition, the adsorption member may be formed including at least one or more of zeolite, activated alumina, or porous silica, and the catalyst member may be formed including at least one or more of platinum, rhodium, cobalt, molybdenum, or palladium. And, as an example of a structure including the adsorption member and the catalyst member, when the adsorption member is porous silica, the catalyst member may be configured to be coated in a plurality of holes formed in the adsorption member.

따라서, 제1 정화부(10)의 경우 가스상 오염 물질에 대한 흡착성이 우수한 제올라이트, 활성 알루미나, 또는 다공성 실리카 중 적어도 하나 이상을 포함하여 형성되는 흡착 부재 의해 외부로부터 유입되는 공기(a1)에 포함된 가스상 오염 물질을 흡착시킬 수 있고, 상기 가스상 오염 물질과의 반응성이 우수한 백금, 로듐, 코발트, 몰리브덴, 또는 팔라듐 중 적어도 하나 이상을 포함하는 촉매 부재가 상기 가스상 오염 물질과 저온에서 산화 반응하여 가스상 오염 물질을 정화할 수 있다.Therefore, in the case of the first purifying unit 10, the air is introduced from the outside by an adsorption member formed of at least one of zeolite, activated alumina, or porous silica having excellent adsorption to gaseous contaminants. A catalyst member which can adsorb gaseous contaminants and which has at least one of platinum, rhodium, cobalt, molybdenum, or palladium, which is excellent in reactivity with the gaseous contaminants, is oxidized with the gaseous contaminants at low temperature to contaminate the gaseous contaminants. Can purify the substance.

탈착 수단(20)은 제1 정화부(10) 측으로 공기를 공급하여 제1 정화부(10)에 흡착된 가스상 오염물질을 제1 정화부(10)로부터 탈착시킨다.The desorption means 20 supplies air to the first purifying unit 10 to desorb the gaseous contaminants adsorbed to the first purifying unit 10 from the first purifying unit 10.

이때, 탈착 수단(20)은 제1 정화부(10)의 미리 결정된 흡착 영역 측으로 공기를 공급하는 방식으로 제1 정화부(10)의 상기 흡착 영역에 흡착된 가스상 오염물질을 제1 정화부(10)로부터 탈착시킬 수 있으며, 탈착 수단(20)에 의한 흡착부(12)에 흡착된 상기 가스상 오염물질의 탈착 과정은 이하 도 2에서 상세하게 설명하도록 한다.At this time, the desorption means 20 is configured to supply the air to the predetermined adsorption region side of the first purifying unit 10 to absorb the gaseous contaminants adsorbed to the adsorption region of the first purifying unit 10. 10), and the desorption process of the gaseous contaminants adsorbed to the adsorption unit 12 by the desorption means 20 will be described in detail with reference to FIG.

또한, 탈착 수단(20)는 제1 정화부(10)의 미리 결정된 영역 측으로 공급되는 공기(a3)를 가열하기 위한 히터 등의 별도의 가열 수단을 포함할 수 있다.In addition, the desorption means 20 may include a separate heating means such as a heater for heating the air a3 supplied to the predetermined region side of the first purification unit 10.

여기에서, 탈착 수단(20)이 제1 정화부(10)의 미리 결정된 탈착 영역 측으로 공급되는 공기(a3)를 가열하기 위한 별도의 가열 수단을 더 포함하는 이유는 상기 탈착 영역 측으로 공급되는 공기(a3)의 온도가 제1 정화부(10)에 상기 가스상 오염 물질이 흡착되는 흡착 온도 이상의 탈착 온도를 갖도록 하여 상기 탈착 영역으로부터 상기 가스상 오염 물질의 탈착과 동시에 촉매 부재에 의한 산화반응이 용이하게 이루어지도록 하기 위함이다.Here, the reason why the desorption means 20 further includes a separate heating means for heating the air a3 supplied to the predetermined desorption area side of the first purifying part 10 is the air supplied to the desorption area side ( A3) has a desorption temperature that is equal to or higher than the adsorption temperature at which the gaseous contaminants are adsorbed to the first purifying unit 10, thereby easily deoxidizing the gaseous contaminants from the desorption region and oxidizing the catalyst by a catalyst member. To lose.

또한, 상기 가열 수단에 의해 가열된 후 상기 탈착 영역 측으로 공급되는 공기(a3)의 온도는 섭씨 50도 내지 500도 일 수 있고, 보다 바람직하게는 섭씨 100도 내지 300도 일 수 있다.In addition, the temperature of the air a3 supplied to the desorption region side after being heated by the heating means may be 50 degrees to 500 degrees, more preferably 100 degrees to 300 degrees.

제2 정화부(30)는 탈착 수단(20)에 의해 제1 정화부(10)로부터 상기 산화반응에 의해 발생되는 부산물, 탈착된 수분, 및 가스상 오염 물질을 포함하는 공기를 유입시킨 후 상기 유입된 공기에 포함된 가스상 오염 물질을 정화한다.The second purifying unit 30 introduces air containing by-products, desorbed water, and gaseous contaminants generated by the oxidation reaction from the first purifying unit 10 by the desorption means 20. Gaseous contaminants contained in the air.

이때, 제2 정화부(30)는 제1 정화부(10)로부터 탈착된 가스상 오염 물질을 포함하는 공기(a4)가 유입된 후 열교환이 이루어지는 열교환부(32), 열교환부(32)를 통과한 후 유입된 가스상 오염 물질을 포함하는 공기(a5)로부터 가스상 오염 물질과 수분을 획득하는 오염 물질 획득부(34), 및 오염 물질 획득부(34)를 통과한 후 유입되는 공기(a6)가 제1 정화부(10) 측으로 공급되도록 하는 공기 공급부(36)를 포함할 수 있다.In this case, the second purification unit 30 passes through the heat exchange unit 32 and the heat exchange unit 32 in which air (a4) containing gaseous contaminants desorbed from the first purification unit 10 flows in and then undergoes heat exchange. After the contaminant acquiring unit 34 to obtain gaseous contaminants and water from the air (a5) containing the gaseous contaminant introduced thereafter, and the air (a6) introduced after passing through the contaminant acquiring unit 34 It may include an air supply unit 36 to be supplied to the first purification unit 10 side.

또한, 오염 물질 획득부(34)는 가스상 오염 물질을 액화시켜 획득할 수 있는 응축기일 수 있다.In addition, the contaminant obtaining unit 34 may be a condenser that can be obtained by liquefying gaseous contaminants.

이와 같이, 제2 정화부(30)는 오염 물질 획득부(34)가 열교환부(32)를 통과한 가스상 오염 물질을 포함한 공기(a5)로부터 상기 가스상 오염 물질을 액화시켜 회수할 수 있고, 공기 공급부(36)가 오염 물질 획득부(34)에서 상기 가스상 오염 물질이 회수된 공기(a6)를 제1 정화부(10) 측으로 유입되도록 하여 제1 정화부(10) 측으로 공급되는 공기(a7)에 포함될 수 있는 잔여 가스상 오염 물질이 제1 정화부(10)에서 다시 정화처리 되도록 할 수 있다.As such, the second purification unit 30 may liquefy and recover the gaseous pollutants from the air a5 including the gaseous pollutants passed through the heat exchange unit 32 by the pollutant acquiring unit 34. The supply unit 36 causes the air a6 from which the gaseous contaminants have been recovered from the pollutant acquiring unit 34 to flow into the first purifying unit 10, so that the air a7 is supplied to the first purifying unit 10. Residual gaseous contaminants that may be included in the first purification unit 10 may be purged again.

도 2에 도시된 바와 같이 제1 정화부(10)는 외부로부터 유입되는 가스상 오염 물질이 포함된 공기(a1)가 제1 정화부(10)를 통과할 시에 가스상 오염 물질이 흡착될 수 있다.As illustrated in FIG. 2, the first purifying unit 10 may adsorb gaseous contaminants when the air a1 containing gaseous contaminants introduced from the outside passes through the first purifying unit 10. .

이때, 제1 정화부(10)는 미리 결정된 방향으로 지속적으로 회전이 이루어지는데, 제1 정화부(10)의 흡착 영역(d2)에 가스상 오염 물질이 흡착된 후 회전하여 탈착 영역(d1)에 위치하게 되므로, 탈착 영역(d1) 측으로 공급되는 탈착 공기(a3)에 의해 흡착된 가스상 오염 물질이 탈착되는 것이 가능해진다.At this time, the first purifying unit 10 is continuously rotated in a predetermined direction. After the gaseous contaminants are adsorbed to the adsorption region d2 of the first purifying unit 10, the first purifying unit 10 rotates and is rotated in the desorption region d1. Since it is located, the gaseous contaminants adsorbed by the desorption air a3 supplied to the desorption region d1 can be desorbed.

따라서, 제1 정화부(10)의 경우 가스상 오염 물질의 흡착 및 탈착이 지속적으로 이루어지므로 자체 재생이 가능해져 가스상 오염 물질의 정화 효율을 지속적으로 유지함과 동시에 제1 정화부(10)의 수명을 크게 향상시킬 수 있다.Therefore, in the case of the first purifying unit 10, since the adsorption and desorption of the gaseous pollutants is continuously performed, self-regeneration is possible, thereby maintaining the purification efficiency of the gaseous pollutants continuously and at the same time maintaining the life of the first purifying unit 10. It can greatly improve.

또한, 도 3에 도시된 바와 같이 외부로부터 유입되는 가스상 오염 물질이 포함된 공기(a1)가 흡착영역(d2)을 통과한 후 정화되며, 탈착 수단(20)으로부터 탈착 영역(d1) 측으로 공급되는 탈착 공기(a3)에 의해 탈착 영역(d1)에 위치한 가스상 오염 물질을 탈착시키는 것이 가능하다.In addition, as illustrated in FIG. 3, the air a1 containing gaseous contaminants introduced from the outside is purified after passing through the adsorption region d2, and is supplied from the desorption means 20 to the desorption region d1. It is possible to desorb the gaseous contaminants located in the desorption region d1 by the desorption air a3.

이때, 탈착 공기(a3)로써 외부로부터 유입되는 가스상 오염 물질이 포함된 공기의 일부(a11)가 사용될 수 있는데, 이 공기는 탈착 영역(d1)이 흡착 영역(d2)으로 전환하기 전 영역(d3)을 냉각하는 기능을 수행하게 된다.In this case, a portion a11 of air including gaseous contaminants introduced from the outside may be used as the desorption air a3, which is an area d3 before the desorption area d1 is converted into the adsorption area d2. ) Will be cooled.

도 4는 본 발명의 제2 실시예에 따른 흡착부를 갖는 오염 공기 정화 장치의 개념도이다.4 is a conceptual diagram of a polluted air purifying apparatus having an adsorption unit according to a second exemplary embodiment of the present invention.

도 4에 도시된 바와 같이 본 발명의 제2 실시예에 따른 흡착부를 갖는 오염 공기 정화 장치(1)의 경우 제1 정화부(10)의 전측에 외부로부터 유입되는 공기에 포함된 입자상 오염 물질을 제거하는 오염 물질 제거부(40)를 위치시키고, 제2 정화부(10)의 후측에 제1 정화부(10)를 통과한 공기에 포함될 수 있는 잔여분의 입자상 오염 물질과 가스상 오염 물질을 제거하는 후처리부(50)를 위치시킨 구성을 포함한다.As shown in FIG. 4, the polluted air purifying apparatus 1 having the adsorption unit according to the second exemplary embodiment of the present invention includes particulate contaminants contained in air introduced from the outside on the front side of the first purifying unit 10. Positioning the contaminant removal unit 40 to remove, and removes the remaining particulate contaminants and gaseous contaminants that may be included in the air passing through the first purification unit 10 to the rear side of the second purification unit 10. It includes a configuration in which the post-processing unit 50 is located.

이때, 오염 물질 제거부(40)는 에어 필터, 미디움 필터, 헤파 필터, 또는 전기집진식 정전필터일 수 있고 후처리부(50)는 가스상 오염 물질을 제거하기 위한 활성탄 필터와 점착 활성탄 필터 등이거나 또는 입자상 오염 물질을 제거하기 위한 헤파 필터와 정전필터 등일 수 있으며, 도면 상에는 도시되지 않았지만 오염 물질 제거부(40)와 후처리부(50)는 입자상 오염 물질과 가스상 오염 물질의 효과적인 제거를 위해 각각 복수 개가 제1 정화부(10)의 전측 및 후측에 위치할 수 있다.In this case, the contaminant removing unit 40 may be an air filter, a medium filter, a hepa filter, or an electrostatic precipitating electrostatic filter, and the after-treatment unit 50 may be an activated carbon filter and an adhesive activated carbon filter for removing gaseous contaminants, or may be particulate. It may be a HEPA filter and an electrostatic filter for removing contaminants, and although not shown in the drawings, the contaminant removing unit 40 and the post-treatment unit 50 may each be provided in plural to effectively remove particulate contaminants and gaseous contaminants. 1 may be located in the front and rear of the purification unit (10).

도 5는 촉매가 부착된 흡착부 제조 방법에 대한 순서도 이다.5 is a flowchart illustrating a method of manufacturing a catalyst adsorbed portion.

도 5에 도시된 바와 같이 S10에서 용액에 촉매 부재를 투입한 후 촉매 부재를 용해시킨다.As shown in FIG. 5, after the catalyst member is added to the solution in S10, the catalyst member is dissolved.

이때, S10에서 용액은 물, 에탄올, 또는 물과 에탄올의 혼합 용액일 수 있고, 촉매 부재는 백금, 로듐, 코발트, 몰리브덴, 또는 팔라듐 중 적어도 하나 이상을 포함할 수 있으며, 상기 촉매 부재를 기준으로(예를 들어, 금속원소 기준) 미리 결정되는 흡착 부재 무게의 0.01 내지 25 중량비(wt%)로 물, 에탄올, 또는 물과 에탄올의 혼합 용액에 투입될 수 있다.At this time, the solution in S10 may be water, ethanol, or a mixed solution of water and ethanol, the catalyst member may include at least one or more of platinum, rhodium, cobalt, molybdenum, or palladium, based on the catalyst member It may be added to water, ethanol, or a mixed solution of water and ethanol at a weight ratio (wt%) of the predetermined weight of the adsorption member (for example, based on metal elements).

또한, S10에 이어서 촉매 부재가 투입된 물, 에탄올, 또는 물과 에탄올의 혼합 용액을 10분 내지 30분 교반하는 단계를 더 포함할 수 있다.Further, the method may further include a step of stirring water, ethanol, or a mixed solution of water and ethanol for 10 minutes to 30 minutes, following S10.

S20에서 촉매 부재가 용해된 용액에 흡착 부재를 투입한다.In S20, the adsorption member is introduced into the solution in which the catalyst member is dissolved.

이때, S20에서 흡착 부재는 제올라이트, 활성 알루미나, 또는 다공성 실리카 중 적어도 하나 이상을 포함할 수 있다.At this time, the adsorption member in S20 may include at least one or more of zeolite, activated alumina, or porous silica.

S30에서 흡착 부재가 투입된 용액을 초음파 처리하여 촉매 부재를 흡착 부재에 부착시킨다.In S30, the solution into which the adsorption member is added is ultrasonicated to attach the catalyst member to the adsorption member.

이때, S30에서 흡착 부재의 초음파 처리는 초음파 파쇄기(Sonicator)에 의해 이루어질 수 있고, 초음파 처리 시간은 2시간 이내 일 수 있으며 보다 바람직하는 20분 내지 60분 사이일 수 있다.In this case, in S30, the ultrasonic treatment of the adsorption member may be performed by an ultrasonic crusher, and the ultrasonic treatment time may be within 2 hours, and more preferably between 20 minutes and 60 minutes.

S40에서 촉매 부재가 부착된 흡착 부재를 인출한 후 건조시킨다.In S40, the adsorption member to which the catalyst member is attached is taken out and dried.

이때, S40에서 촉매 부재가 부착된 흡착 부재의 건조는 섭씨 50도 내지 200도에서 로터 건조기에 의해 이루어질 수 있으며, 이와 같이 S40에서 촉매 부재가 부착된 흡착 부재를 건조시키는 이유는 흡착 부재에 포함될 수 있는 잔류 슬러리를 제거 및 건조하기 위함이다.In this case, drying of the adsorption member to which the catalyst member is attached in S40 may be performed by a rotor dryer at 50 to 200 degrees Celsius. Thus, the reason for drying the adsorption member to which the catalyst member is attached in S40 may be included in the adsorption member. To remove residual slurry and to dry.

S50에서 건조된 흡착 부재를 헬륨 또는 질소와 같은 비활성 기체 도는 수소를 이용하여 촉매활성화시킨다.The adsorbed member dried at S50 is catalytically activated using an inert gas or hydrogen such as helium or nitrogen.

이때, S50에서 촉매활성화 온도는 섭씨 100도 내지 500도 일 수 있으며, 보다 바람직하게는 섭씨 200도 내지 300도일 수 있고, S50에서 촉매활성화 시간은 5시간 이내 일 수 있으며, 보다 바람직하게는 2시간일 수 있다.At this time, the catalyst activation temperature in S50 may be 100 degrees to 500 degrees Celsius, more preferably may be 200 degrees to 300 degrees Celsius, the catalyst activation time in S50 may be within 5 hours, more preferably 2 hours Can be.

또한, S50에서 촉매 부재가 부착된 흡착 부재를 촉매활성화시키면 본 발명의 바람직한 실시예에 따른 촉매가 부착된 흡착부 제조가 완료될 수 있으며, 상기 촉매가 부착된 흡착부는 제올라이트, 활성 알루미나, 또는 다공성 실리카 중 적어도 하나 이상을 포함하는 흡착 부재와 백금, 로듐, 코발트, 몰리브덴, 또는 팔라듐 중 적어도 하나 이상을 포함하는 촉매 부재를 포함하는 구조물일 수 있다.In addition, when the catalyst is activated by the adsorption member attached to the catalyst member in S50 can be completed the production of the catalyst attached adsorption portion according to a preferred embodiment of the present invention, the adsorption portion attached to the catalyst is zeolite, activated alumina, or porous It may be a structure including an adsorption member including at least one or more of silica and a catalyst member including at least one or more of platinum, rhodium, cobalt, molybdenum, or palladium.

본 발명의 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치(1)는 유입되는 공기에 포함된 가스상 오염 물질을 제1 정화부(10)가 흡착 및 정화하여 1차적으로 정화하고 탈착부(20)에 의해 제1 정화부(10)로부터 탈착되는 가스상 오염 물질을 제2 정화부(20)가 가스상 오염 물질을 액화시켜 회수하는 방식으로 2차적으로 정화하므로 오염 공기 정화 장치의 정화 성능을 향상시킬 수 있다.The polluted air purifying apparatus 1 having the adsorption unit to which the catalyst of the present invention is attached is first purified by the first purifying unit 10 to purify gaseous contaminants contained in the incoming air and the desorbing unit 20. Secondary purification of the gaseous pollutants desorbed from the first purification unit 10 by the second purification unit 20 by liquefying and recovering the gaseous pollutants can improve the purification performance of the polluted air purification device. have.

또한, 흡착 부재에 흡착된 가스상 오염 물질과 촉매 부재의 촉매 산화에 의해 이루어지는 가스상 오염 물질의 정화 과정이 상온에서 이루어지므로 가스상 오염 물질의 촉매 산화를 위한 별도의 공기 가열 장치, 산화 반응 장치, 및 온도 유지 장치 등이 요구되지 않아 오염 공기 정화 장치의 크기와 제조 비용을 감소시킬 수 있다.In addition, since the purification process of the gaseous contaminants adsorbed on the adsorption member and the gaseous contaminants by the catalytic oxidation of the catalyst member is performed at room temperature, a separate air heating device, an oxidation reaction device, and a temperature for catalytic oxidation of the gaseous contaminants are performed. No maintenance device or the like is required to reduce the size and manufacturing cost of the contaminated air purification device.

또한, 오염 물질 획득부(34)에서 가스상 오염 물질과 수분을 응축시켜 획득하는 것이 가능하므로 가스상 오염 물질의 제거가 보다 용이하게 이루어질 수 있다.In addition, since it is possible to condense and acquire the gaseous contaminants and water in the contaminant acquiring unit 34, the gaseous contaminants may be more easily removed.

또한, 제1 정화부(10)에서 가스상 오염 물질의 흡착 및 탈착이 계속적으로 이루어져 제1 정화부(10)의 자체 재생이 가능하므로 제1 정화부(10)의 정화 효율을 지속적으로 유지함과 동시에 제1 정화부(10)의 수명을 크게 향상시킬 수 있는 효과를 갖는다.In addition, since the adsorption and desorption of the gaseous contaminants is continuously performed in the first purifying unit 10, the first purifying unit 10 can be self-regenerated, thereby maintaining the purification efficiency of the first purifying unit 10 continuously. It has an effect which can greatly improve the lifetime of the 1st purification part 10.

또한, 종래의 오염 공기 정화 장치와 본 발명에 따른 흡착부(백금을 0.1 중량비(wt%) 이상 포함)를 갖는 오염 공기 정화 장치(1)의 정화 성능 비교 결과는 아래의 표 1과 같고, 본 발명에 따른 흡착부를 갖는 공기 정화 장치(1)의 정화 성능 측정 결과는 아래의 표 2와 같다.In addition, the comparison results of the purification performance of the conventional polluted air purification device and the polluted air purification device 1 having an adsorption unit (including platinum containing 0.1 weight ratio (wt%) or more) according to the present invention are shown in Table 1 below. The purification performance measurement results of the air purification device 1 having the adsorption unit according to the present invention are shown in Table 2 below.

가스상
오염 물질Gas phase
pollutant 입구(ppm)Inlet (ppm) 출구(ppm)Outlet (ppm) 최종 처리율
(%)Final throughput
(%) 운전 시간
(Hr)Driving time
(Hr) 종 래Species C7H8 C 7 H 8 10.710.7 55 53.253.2 5050 본발명Invention C7H8 C 7 H 8 10.410.4 2.62.6 75.075.0 5050

가스상 오염물질Gaseous contaminants 입구(ppm)Inlet (ppm) 출구(ppm)Outlet (ppm) 최종 처리율(%)Final Throughput% 운전 시간(Hr)Driving time (Hr) HCHOHCHO 5.25.2 0.80.8 84.684.6 5050 H2SH 2 S 12.512.5 2.52.5 80.080.0 5050 NH3 NH 3 13.513.5 0.60.6 95.695.6 5050 COCO 4.24.2 00 100.0100.0 5050 O3 O 3 5.55.5 00 100.0100.0 5050

표 1에서와 같이 종래의 공기 정화 장치와 본 발명에 따른 흡착부를 갖는 오염 공기 정화 장치를 50시간 동안 작동시킨 후 가스상 오염 물질 중 C7H5(톨루엔)에 대한 정화 성능을 비교한 결과 본 발명에 따른 흡착부를 갖는 오염 공기 정화 장치의 경우 종래에 비해 약 50%의 정화 성능 향상을 확인할 수 있다.As shown in Table 1, after the conventional air purifier and the polluted air purifier having the adsorption unit according to the present invention were operated for 50 hours, the purification performance of C 7 H 5 (toluene) in gaseous pollutants was compared. In the case of the polluted air purifier having an adsorption unit according to the present invention, it can be confirmed that the purification performance is improved by about 50% compared with the related art.

또한, 표 2에서와 같이 본 발명에 따른 흡착부를 갖는 오염 공기 정화 장치를 50시간 동안 작동시킨 후 가스상 오염 물질 중 HCHO(포름알데히드), H2S(황화수소), NH3(암모니아), CO(일산화탄소), 및 O3(오존)에 대한 정화 성능을 비교한 결과 각각 84.6%, 80%, 95.6%, 100%, 및 100%의 정화 성능을 갖는 것을 확인할 수 있다.In addition, as shown in Table 2, after operating the contaminated air purifying device having an adsorption unit according to the present invention for 50 hours, HCHO (formaldehyde), H 2 S (hydrogen sulfide), NH 3 (ammonia), CO ( Comparing the purification performance for carbon monoxide), and O 3 (ozone), it can be seen that the purification performance of 84.6%, 80%, 95.6%, 100%, and 100%, respectively.

이상의 설명은 본 발명의 기술 사상을 예시적으로 설명한 것에 불과한 것으로서, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 본 발명의 본질적인 특성에서 벗어나지 않는 범위 내에서 다양한 수정, 변경, 및 치환이 가능할 것이다. 따라서 본 발명에 개시된 실시예 및 첨부된 도면들은 본 발명의 기술 사상을 한정하기 위한 것이 아니라 설명하기 위한 것이고, 이러한 실시예 및 첨부된 도면들에 의해서 본 발명의 기술 사상의 범위가 한정되는 것은 아니다. 본 발명의 보호 범위는 아래의 청구 범위에 의해서 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술 사상은 본 발명의 권리 범위에 포함되는 것으로 해석되어야 할 것이다.It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. It will be possible. Therefore, the embodiments disclosed in the present invention and the accompanying drawings are intended to illustrate and not to limit the technical spirit of the present invention, and the scope of the technical idea of the present invention is not limited by these embodiments and the accompanying drawings . The scope of protection of the present invention should be construed according to the following claims, and all technical ideas within the scope of equivalents thereof should be construed as being included in the scope of the present invention.

(1) : 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치
(10) : 제 1 정화부 (20) : 탈착 수단
(30) : 제2 정화부 (32) : 열교환부
(34) : 오염 물질 획득부 (36) : 공기 공급부
(40) : 오염 물질 제거부 (50) : 후처리부(1): polluted air purification device having adsorption unit with catalyst attached
10: first purification unit 20: desorption means
30: second purification section 32: heat exchange section
(34): pollutant acquisition section 36: air supply section
40: pollutant removal unit 50: post-treatment unit

Claims (14)

외부로부터 유입되는 공기에 포함된 가스상 오염 물질을 흡착 및 정화하기 위하여 상기 가스상 오염 물질이 흡착되는 흡착 부재와 상기 흡착된 가스상 오염 물질을 산화 반응에 의해 정화하는 촉매 부재를 포함하는 구조물로 이루어지는 제1 정화부;
상기 제1 정화부 측으로 공기를 공급하여 상기 제1 정화부에 흡착된 가스상 오염 물질을 탈착시키는 탈착 수단; 및
상기 제1 정화부로부터 탈착된 가스상 오염 물질을 포함하는 공기를 유입시켜 정화하는 제2 정화부를 포함하며,
상기 제1 정화부는 회전하며 상기 탈착 수단에 의해 상기 제1 정화부의 미리 결정된 영역에 흡착된 가스상 오염 물질을 탈착시키고,
상기 제1 정화부는 상기 흡착 부재를 상기 촉매 부재가 용해된 용액에 투입한 후 초음파 처리에 의해 상기 촉매 부재를 상기 흡착 부재에 부착시키고 상기 촉매 부재가 부착된 상기 흡착 부재를 건조 및 촉매 활성화하여 형성되는 것을 특징으로 하는 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치.A first structure comprising an adsorbing member to which the gaseous contaminants are adsorbed and a catalyst member to purify the adsorbed gaseous contaminants by an oxidation reaction to adsorb and purify the gaseous contaminants contained in air introduced from the outside Purification unit;
Desorption means for supplying air to the first purifying part to desorb the gaseous contaminants adsorbed to the first purifying part; And
A second purifying unit configured to introduce and purify air containing gaseous pollutants desorbed from the first purifying unit,
The first purifier rotates to desorb gaseous contaminants adsorbed to a predetermined region of the first purifier by the desorption means,
The first purifying unit is formed by inserting the adsorption member into a solution in which the catalyst member is dissolved, attaching the catalyst member to the adsorption member by ultrasonic treatment, and drying and catalytically activating the adsorption member to which the catalyst member is attached. Polluted air purification apparatus having an adsorption unit attached to the catalyst, characterized in that. 제 1항에 있어서,
상기 촉매 부재는 백금, 로듐, 코발트, 몰리브덴 또는 팔라듐 중 적어도 하나 이상을 포함하여 형성되는 것을 특징으로 하는 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치.The method of claim 1,
And the catalyst member comprises at least one of platinum, rhodium, cobalt, molybdenum or palladium. 제 1항에 있어서,
상기 산화 반응은 상기 탈착 수단에 의한 오염물질 탈착 시 이루어지는 것을 특징으로 하는 흡착부를 갖는 오염 공기 정화 장치.The method of claim 1,
And the oxidation reaction is carried out when the pollutant is desorbed by the desorption means. 제 1항에 있어서,
상기 흡착 부재는 제올라이트, 활성 알루미나, 또는 다공성 실리카 중 적어도 하나 이상을 포함하여 형성되는 것을 특징으로 하는 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치.The method of claim 1,
And the adsorption member comprises at least one of zeolite, activated alumina, or porous silica. 제 1항에 있어서,
상기 제2 정화부는 상기 제1 정화부로부터 탈착된 상기 가스상 오염 물질을 포함하는 공기가 유입된 후 열교환이 이루어지는 열교환부, 상기 열교환부를 통과한 후 유입되는 상기 가스상 오염 물질을 포함하는 공기로부터 상기 가스상 오염 물질과 수분을 획득하는 오염 물질 획득부, 및 상기 오염 물질 획득부를 통과한 후 유입되는 공기를 상기 제1 정화부 측으로 공급하는 공기 공급부를 포함하는 것을 특징으로 하는 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치.The method of claim 1,
The second purifying part may be a heat exchange part in which heat is exchanged after the air containing the gaseous contaminants desorbed from the first purifying part is introduced, and the gaseous phase is separated from the air containing the gaseous contaminant introduced after passing through the heat exchange part. Pollution having a catalyst adsorbing unit comprising a pollutant obtaining unit for obtaining pollutants and water, and an air supply unit for supplying air introduced after passing through the pollutant obtaining unit to the first purification unit side. Air filter. 제 5항에 있어서,
상기 오염 물질 획득부는 응축기인 것을 특징으로 하는 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치.6. The method of claim 5,
The contaminant acquiring unit is a condenser condenser air purification apparatus having a adsorption unit with a catalyst, characterized in that. 제 1항에 있어서,
상기 제1 정화부의 전측에 위치하여 상기 외부로부터 유입되는 공기에 포함된 입자상 오염 물질을 제거하는 오염 물질 제거부를 더 포함하는 것을 특징으로 하는 촉매가 부착된 흡착부를 갖는 오염 공기 정화 장치.The method of claim 1,
And a contaminant removing unit positioned at the front side of the first purifying unit to remove particulate contaminants contained in the air introduced from the outside. (a) 용액에 촉매 부재를 투입한 후 상기 촉매 부재를 용해시키는 단계;
(b) 상기 촉매 부재가 용해된 용액에 흡착 부재를 투입하는 단계;
(c) 상기 흡착 부재가 투입된 용액을 초음파 처리하여 상기 흡착 부재에 상기 촉매 부재를 부착시키는 단계;
(d) 상기 촉매 부재가 부착된 흡착 부재를 건조시키는 단계; 및
(e) 상기 촉매가 부착된 흡착 부재를 촉매 활성화시키는 단계를 포함하는 것을 특징으로 하는 촉매가 부착된 흡착부 제조 방법.(a) injecting a catalyst member into a solution and then dissolving the catalyst member;
(b) injecting an adsorption member into a solution in which the catalyst member is dissolved;
(c) attaching the catalyst member to the adsorption member by sonicating the solution into which the adsorption member is introduced;
(d) drying the adsorption member to which the catalyst member is attached; And
(e) catalytically adsorbing the production method comprising the step of catalytically activating the adsorption member to which the catalyst is attached. 제 8항에 있어서,
상기 (a) 단계에서 상기 촉매 부재는 백금, 로듐, 코발트, 몰리브덴, 또는 팔라듐 중 적어도 하나 이상을 포함하는 것을 특징으로 하는 촉매가 부착된 흡착부 제조 방법.The method of claim 8,
The method of claim 1, wherein the catalyst member comprises at least one of platinum, rhodium, cobalt, molybdenum, or palladium. 제 8항에 있어서,
상기 (a) 단계에서 상기 촉매 부재는 상기 촉매 부재에 따라 미리 결정되는 상기 흡착 부재 무게의 0.01 내지 25 중량비(wt%)를 갖는 것을 특징으로 하는 촉매가 부착된 흡착부 제조 방법.The method of claim 8,
The method of claim 1, wherein the catalyst member has a weight ratio of 0.01 to 25 weight percent (wt%) of the weight of the adsorption member, which is predetermined according to the catalyst member. 제 8항에 있어서,
상기 (b) 단계에서 상기 흡착 부재는 제올라이트, 활성 알루미나, 또는 다공성 실리카 중 적어도 하나 이상을 포함하는 것을 특징으로 하는 촉매가 부착된 흡착부 제조 방법.The method of claim 8,
The method of claim (b) wherein the adsorption member is at least one of zeolite, activated alumina, or porous silica, characterized in that the catalyst adsorbed part manufacturing method. 제 8항에 있어서,
상기 (c) 단계에서 상기 초음파 처리는 20분 내지 60분 동안 이루어지는 것을 특징으로 하는 촉매가 부착된 흡착부 제조 방법.The method of claim 8,
In the step (c), the ultrasonic treatment is carried out for 20 minutes to 60 minutes, characterized in that the catalyst adsorbed part manufacturing method. 제 8항에 있어서,
상기 (d) 단계에서 상기 촉매 부재가 부착된 흡착 부재의 건조는 섭씨 50도 내지 200도에서 이루어지는 것을 특징으로 하는 촉매가 부착된 흡착부 제조 방법.The method of claim 8,
Drying of the adsorption member to which the catalyst member is attached in the step (d) is made of a catalyst adsorbed portion, characterized in that at 50 to 200 degrees Celsius. 제 8항에 있어서,
상기 (e) 단계에서 상기 촉매 활성화는 헬륨, 질소, 또는 수소를 이용하여 섭씨 100도 내지 500도에서 이루어지는 것을 특징으로 하는 촉매가 부착된 흡착부 제조 방법.The method of claim 8,
In the step (e), the catalyst activation is performed using a helium, nitrogen, or hydrogen at 100 degrees to 500 degrees Celsius, characterized in that the catalyst adsorption unit manufacturing method.
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