KR101308854B1 - Water-soluble paste having high-adhesive property and manufacturing method for the same - Google Patents

Abstract

PURPOSE: A water leaking prevent high attaching aqueous paste is provided to shorten curing time, to have strong adhesive force with concrete background surface and to prevent leakage by including modified asphalt concrete mixture, emulsifying water, and a specific additive mixture. CONSTITUTION: A water leaking prevent high attaching aqueous paste composition comprises 40-70 wt% of asphalt, 1-10 wt% of thermoplastic elastomer, 1-15 wt% of plasticizer, 0.5-20 wt% of tackifying agent, 0.3-3 wt% of emulsifier, 1-20 wt% of styrene-butadiene latex, 0.5-10 wt% of acryl emulsion, 0.1-10 wt% of polyvinylacetate (PVAc), 0.01-0.1 wt% of antifoaming agent, 5-20 wt% of inorganic filler, 0.1-1 wt% of thickening agent, and 0.1-1 wt% of dispersion stabilizer represented by chemical formula(1),. The dispersion stabilizer forms reactant represented by chemical formula (2) by condensing with diol of raw material having HOROH chemical formula. In the formula (2), R is a hydrocarbon compound having 1-20 carbons.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a water-soluble paste having high adhesion properties and a manufacturing method for the same,

More particularly, the present invention relates to a dispersion stabilizing technology of water-aspheric rubber asphalt and an additive for improving the adhesive strength of the water-resistant rubber asphalt, It is a leak-proof type that can solve the leakage problem fundamentally by forming a composite waterproof layer having the effect of forming a base water-proof type waterproofing material and securing the integration of a base concrete and a waterproofing sheet through a quick curing drying time and securing a strong adhesion force. To an adhesive hydration paste and a manufacturing method thereof.

In concrete structures, waterproofing is a direct influence factor required for residential comfort and comfort. It is used for securing long-term durability of buildings by preventing cracking due to concrete neutralization and corrosion of steel bars. However, The cost is more than three times that of the initial construction cost, resulting in a large economic loss.

Accordingly, the present invention has developed a leak-barrier type high-adhesion water-soluble paste for securing the stability of concrete structure, and formed a leak-barrier layer having a certain thickness on the surface of concrete, and integrated behavior of the concrete and water- To ensure the durability and safety of concrete structures.

Since July 2005, the Special Act on the Improvement of the Atmospheric Environment in the Seoul Metropolitan Area (Article 30) has been applied to the volatile organic compounds (VOCs) of paints in the Seoul metropolitan area in order to supply only 57% less volatile organic compounds (VOC) Since volatile organic compounds (VOCs) have a direct harmful effect on human health such as respiratory irritation, nervous system disorder, carcinogenesis and leukemia induction, Development of waterproof floors using reduced hydration and high solid technology is needed.

Recently, the demand for water-based products has increased rapidly due to the increased interest in the atmospheric environment. However, the technology development for waterproofing type waterproofing products has been insufficient. In order to improve the working conditions of fire workers and construction workers, eco- However, acrylic and water-soluble rubber asphalt products are currently used. However, since the curing time is delayed, it is difficult to form a certain waterproof layer on the surface irregularities, primer construction is required and the concrete is not dried sufficiently, Improvement is needed. Although the asphalt primer is applied to improve the adhesion of the surface concrete and surface waterproofing material, the area of contact between the sheet and the base surface is decreased in the place where the rough surface of the base is rough and the unevenness is large, .

The modified asphalt sheet waterproofing material is heated by a torch at a temperature of 1100 to 1300 degrees centigrade and the lower surface of the sheet is heated to check the melted state of the sheet surface, And adhesion to the substrate is not properly performed depending on the skill of the operator.

In the case of a conventional waterproofing material, it can be classified into a sheet waterproofing material and a coating film waterproofing material, and the characteristics and disadvantages of the waterproofing sheet are as shown in the following table.

division Sheet waterproofing material Coating film waterproofing material Configuration

Characteristic - Constant thickness of waterproof layer
- Quality of waterproof material is uniform
- No curing after construction of waterproof layer
- High tensile strength and elongation - Waterproof construction is convenient
- Formation of integrated waterproof layer without overlap
- Good adhesion to substrate
- Precise construction is possible even in complex areas. Disadvantages - Concerns about defects at joints
- difficult to precise construction such as curve
- Adhesion to substrate by heating with torch
- Adhesion due to lack of adhesion with concrete structure surface - irregular thickness of waterproof layer
- Wet cotton construction is weak.
- Layer separation of waterproof layer occurred
- Curing after application of waterproof layer

Asphalt mastic waterproofing materials have been devised to compensate for these disadvantages. However, since mastic waterproofing materials contain a large amount of hydrocarbon-based solvents as constituents of the waterproofing material, there is a risk of fire, and a volatile odor is peculiar to the workers, Solvents are harmful to the human body and have an adverse effect on the environment. In addition, the conventional mastic waterproofing material shows the properties of the mastic in the state that the solid content of the product is mostly 7085% by weight in the presence of the solvent. However, when the volatile matter, which is a solvent component, flows after the waterproofing material is applied, the fluidity unique to the mastic waterproofing material disappears And the low temperature flexibility and the ability to follow the cracks of the structure are extremely weakened, which causes leakage due to the breakage of the waterproof layer due to cracks in the winter season and structures.

 Asphalt mastic products are used to prevent water leakage due to cracks in the concrete. However, since the waterproofing material is not cured, the secondary waterproofing layer is lost due to the pressurization due to the pouring of concrete. do.

In addition, a method of applying a gel-state asphalt mastic as a coating waterproofing material on the concrete structure surface and a waterproofing method of applying a sheet waterproofing material on the surface of the concrete structure is used to bond the overlapping portions between the sheets using an asphalt mastic. However, When cracks occur, asphalt mastic in uncured gel state flows out through cone cracks or there is a problem that asphalt mastic is lost by pushing concrete load. Therefore, there is a desperate need for a high adhesion water-soluble paste material which can prevent leakage by ensuring strong adhesion to the concrete base and trackability against cracking.

For example, in the 'spray-type rubberized asphalt mastic waterproofing material and its manufacturing method' of Korean Patent Registration No. 10-0585225, a spray-type rubberized asphalt mastic waterproofing material requires a high-level spraying equipment to apply a waterproofing material, It is difficult to waterproof the narrow and complicated structure in which the spraying machine can not fit, and there is a risk of fire in the process of heating and melting the material, And there is a drawback that the operator can be burnt.

Korean Patent Registration No. 10-0820931 discloses a common mastic waterproofing material and a method for manufacturing the same at room temperature and a rubber mastic asphalt waterproofing material composition and a method for producing the same in Korean Patent Registration No. 10-0850875, Although the waterproofing material has improved many disadvantages of general mastic waterproofing material, since the product is expensive due to high solid content and the viscosity of the product is very high in order to satisfy the heat flow performance, the construction workability can not be secured sufficiently And the like. In addition, since the waterproofing material is not cured, the secondary waterproofing material is lost due to the pressurization due to the pushing concrete pouring, or the secondary defects such that the waterproofing material flows down to the uniform area.

In the aqueous mastic waterproofing material for room temperature application and the method for producing the same, a first liquid comprising a process oil, an asphalt, a modifier, a heat resistant reinforcing agent and an emulsifier, and a first liquid comprising water and an emulsifier A viscosity modifier, a modifier, an inorganic filler, a cryoprotectant, and an emulsion stabilizer are uniformly dispersed in two liquids. However, since the product according to the patent has a high hardening time (low solids content) and does not show the adhesive strength value with respect to the concrete base, the concrete structure is not shrunk / expanded, No storm can occur.

In addition, the waterproofing composition using the waterproofing composition of the present invention and the waterproofing structure of the waterproofing composition include a water-soluble rubber modified substance including water, emulsifier, styrene butadiene copolymer resin, straight asphalt, emulsified asphalt stabilizer, defoamer, It is characterized by asphalt coating. Korean Patent Registration No. 10-0778230 discloses a water-soluble film-forming waterproofing material which comprises asphalt, butadiene butyl rubber and tristyrylated phenol, followed by addition of triethylamine to form a water-soluble rubbery asphalt emulsion containing a neutralized and synthesized elastomer It is characterized by the waterproofing of the film. Korean Patent Laid-Open Publication No. 1998-0062000 discloses a coating film waterproofing material comprising a mixture of molten asphalt and an emulsion obtained by reacting water with emulsified water obtained by melting an anionic emulsifier and an additive solution obtained by mixing a styrene-butadiene latex with a defoaming agent.

However, the products according to the above patents are good in stretchability and resistant to ground cracking, and can form a seamless waterproof layer by continuous construction. However, if there are irregularities on the base surface, it is difficult to obtain a constant film thickness, It is difficult to form a waterproof layer with respect to the unevenness of the surface of the substrate and it is necessary to apply a primer to the concrete, If it is not dried sufficiently, watertight floatation and pinhole phenomenon occur, and technological improvement is needed.

Although the asphalt primer is applied to improve the adhesion of the surface concrete and surface waterproofing material, the area of contact between the sheet and the base surface is decreased in the place where the rough surface of the base is rough and the unevenness is large, .

Accordingly, a problem to be solved by the present invention is to provide a highly adhesive water-resistant paste having a strong adhesive force with a concrete base surface and capable of preventing the occurrence of water leakage, and a method for producing the same.

In order to solve the above-mentioned problems, the present invention provides a high adhesion water-soluble paste composition comprising: 40 to 70% by weight of asphalt; 1-10% thermoplastic elastomer; 1-15% by weight plasticizer; 0.5 to 20% by weight of a tackifier; 0.3-3% by weight of emulsifier; 1-20% by weight of styrene-butadiene latex; 0.5-10% by weight of acrylonitrile; 0.1-10% by weight of polyvinyl acetate (PVAc); Defoamer 0.01-0.1 wt%; 5 to 20% by weight of an inorganic filler; 0.1-1 weight% thickener; 0.1-1% by weight of a dispersion stabilizer; And water of the remainder. The present invention also provides a high adhesion water-soluble paste composition.

In one embodiment of the present invention, the emulsifier comprises a cation emulsifier which is diethyl methyl dodecyl ammonium and a resin acid anion emulsifier of the following structure.

In one embodiment of the present invention, the thickener is cellulose of the formula:

In one embodiment of the present invention, the OH of the cellulose is hydrolyzed to ethylene oxide, and the cellulose is transformed into hydroxethylene cellulose having the formula:

상기 분산안정제는 HOROH 화학식을 갖는 원료의 디올(Diol)과 축합 반응하여, 하기 화학식의 반응물을 형성한다. In one embodiment of the present invention, the dispersion stabilizer has the formula:

The dispersion stabilizer is condensed with a diol of the raw material having the formula HOROH to form a reactant of the following formula.

(Wherein R is a hydrocarbon compound having 1 to 20 carbon atoms)

The present invention also relates to a method for producing asphalt, comprising the steps of: (a) adding 1-10 weight% thermoplastic elastomer, 1-15 weight% plasticizer and 0.5-20 weight% tackifier to 40-70 weight% of asphalt, (Mixed) and maintaining the temperature at 110 ° C to 160 ° C; (b) 0.3 to 3% by weight of an emulsifier, 1 to 20% by weight of SB Latex, 0.5 to 10% by weight of an acrylic emulsion, 0.1 to 10% by weight of PVAc and 0.01 to 0.1% by weight of an antifoaming agent are added to 20 to 40% Lt; 0 > C to 70 [deg.] C to prepare emulsified water; (c) adding 5 to 20% by weight of an inorganic filler, 0.1 to 1% by weight of a thickener, and 0.1 to 1% by weight of a dispersion stabilizer to 10 to 30% by weight of water and mixing at 20 to 40 캜; (d) emulsifying the above (a) and (b) using a colloid mill (high shear, 3,000-4,000 rpm) to prepare a modified asphalt mixture emulsion; And (e) adding the other mixture to the modified asphalt mixture emulsion of (d) and dispersing it in a uniform colloid form on a continuous material by using a colloid mill. A method for preparing a composition is provided.

Conventional water-soluble asphalt coating waterproofing materials have a problem in that it is difficult to obtain a uniform film thickness if there are irregularities on the surface of the substrate, and a waterproof layer is not formed at a constant thickness at one time due to occurrence of slipping in a sloped area. In order to prevent leakage due to cracks in concrete, water-swellable rubber asphalt mastic products are not cured because the waterproofing material is not cured. Pressurization due to concrete pouring causes the waterproof layer to be lost or the waterproofing material to flow into the cracks There is a problem that secondary defects occur.

However, according to the present invention, unlike conventional waterproofing materials, it exhibits excellent low-temperature flexibility due to the appropriate amount of plasticizer, which is a paraffinic synthetic oil, and can be used as an asphalt coating film It has the advantage of quick drying without air pockets or floatation under conditions of 10% or more of substrate surface moisture content by improving tensile strength. It is applied to high solid content, thickener and dispersion stabilizer, It is possible to secure the durability and stability of the concrete structure by forming the dry film with a certain thickness at the first time and forming the integrated behavior with the concrete using the high adhesion performance.

In addition, by selecting an appropriate emulsifier, the asphalt mixture is dispersed in a stable colloid form on the continuous material by the emulsifier. Therefore, it is possible to lower the cost of the construction by eliminating the need for special equipments and specialist, and the environment such as volatile organic compounds It is possible to contribute to environmental protection by securing a technique for obtaining a high-adhesion water-soluble paste free from harmful substances and a manufacturing method thereof.

FIG. 1 is a step diagram of a method for manufacturing a highly adhesive hydrated paste composition according to an embodiment of the present invention.

Hereinafter, the present invention will be described in detail with reference to the drawings. The following embodiments are provided by way of example so that those skilled in the art can fully understand the spirit of the present invention. Therefore, the present invention is not limited to the embodiments described below, but may be embodied in other forms. In the drawings, the width, length, thickness, etc. of the components may be exaggerated for convenience. Like numbers refer to like elements throughout. In addition, abbreviations displayed throughout this specification should be interpreted to the extent that they are known and used in the art unless otherwise indicated herein.

The high adhesion hydration paste according to an embodiment of the present invention comprises (a) a modified asphalt mixture, (b) emulsified water, and (c) other additives.

The modified asphalt mixture (a) according to an embodiment of the present invention comprises asphalt, a plasticizer, a thermoplastic elastomer, a tackifier, and the like. The amount of the asphalt used is preferably 40 to 70%, and if it is less than 40% by weight, the content is too small to cause adhesion failure. If it exceeds 70% by weight, the strength and adhesive strength are increased. And the content thereof is too large, which causes difficulty in dispersing on a continuous material by an emulsifier.

The high adhesion water-soluble paste constituting the present invention includes a thermoplastic elastomer in order to increase physical properties such as elasticity, heat resistance and elongation. The thermoplastic elastomer is mixed with the asphalt to increase the elasticity and elongation of the water-soluble paste. The increase in elasticity can significantly improve the deformation at high temperature and the elongation can significantly improve cracking and breakage due to external impact . The content of the thermoplastic elastomer in the composition of the present invention is preferably 1 to 10% by weight. If the content of the thermoplastic elastomer is less than 1 wt%, the elasticity and elongation of the composition are not substantially improved. If the content of the thermoplastic elastomer is more than 10 wt%, it is difficult to disperse the composition on the continuous material by the emulsifier .

The petroleum resin serving as a tackifying agent used in the high adhesion water-soluble paste composition of the present invention may be an aromatic petroleum resin, a coumaroneindene resin, an aliphatic petroleum resin, a hydrogenated dicyclopentadiene resin (hydrocarbon resin or petroleum resin) may be selected and used. Particularly, it is most preferable to use a hydrogenated dicyclopentadiene resin having excellent adhesive strength and low brittleness.

The content of the petroleum resin is 0.5 to 20% by weight. If the content is less than 0.5% by weight, the effect of addition is scarce. If the content is more than 20% by weight, the elasticity of the composition is lowered and low temperature embrittlement occurs.

Conventionally used plasticizers such as Bunker-C oil, dioctyl phthalate (DOP), tricresyl phosphate (TCP), paraffinic process oil, aromatic process oil or naphthan process oil have been used. Bunker-C oil, dioctyl phthalate (DOP), and tricresyl phosphate (TCP) are unsuitable because they are poor in low temperature and heat resistance when applied to a sealant composition for protecting a vehicle sensor, and aromatic and naphthenic process oil Although the low temperature is excellent, the viscosity index of the paraffinic process oil is high due to the low viscosity index due to the temperature, and the viscosity index of the paraffinic process oil is high, which is excellent in heat resistance but low in low temperature. Generally, when the process oil is gradually lowered from a high temperature to a low temperature, the fluidity is gradually lost and the fluid is stopped without stopping. The reason for this is twofold.

First, as the temperature decreases, the viscosity gradually increases and does not flow apparently, which can not lower the pour point regardless of the addition of the additive. As a remedy for this, it is important to select a paraffinic oil having a relatively low wax content and good low-temperature flow characteristics.

Second, since the main component of the process oil is a mixture of various hydrocarbons, when the process oil is cooled, the moisture contained in the vicinity of 0 ° C is frozen, and when the process oil is cooled again, the substances having high pour point contained in the process oil are precipitated So that the process oil is blurred. When this is continuously cooled, the precipitated wax grows and coagulates with each other in the form of a net or a sponge. To prevent this, an additive may be added to prepare a paraffinic oil having a low pour point.

Therefore, in the present invention, a paraffinic viscoelastic synthetic oil is used in place of the above-mentioned conventional plasticizer. The paraffinic synthetic oil is a synthetic oil synthesized from 70 to 90% by weight of a mixture of hydrogenated lube base oil and 10 to 30% by weight of a pour point depressant and a viscosity index improver as an additive, A density of 0.8661, a kinematic viscosity index (40 ° C, mm 2 / S) of 124.4, and a flash point of 276 ° C or more.

If the amount of the hydrogenated lubricant oil is less than 70 wt%, the viscosity index of the modified asphalt mixture is high, but the low temperature flexibility is deteriorated. If the amount of the mixture exceeds 80 wt%, the viscosity index It is very low and deteriorates the temperature sensitivity.

The blending ratio of the pour point depressant and the viscosity index improver is preferably in the range of 10 to 30% by weight based on the properties of the final synthetic oil, i.e., the characteristics of the final synthetic oil, namely, the pour point is -40 占 폚, the density is 0.8661, the kinematic viscosity index (40 占 폚, Changes within the range are possible.

In the present invention, the pour point depressant may be a condensate of chlorinated paraffin and naphthalene, a condensate of chlorinated paraffin and phenol, a polyalkyl methacrylate, a condensate of phenol and paraffin and / or a condensate of paraffin and phthalic acid Is preferably used.

The viscosity of the organic materials changes sensitively with temperature change. In general, the viscosity of an organic material is large at a low temperature, and is extremely low at a high temperature. The viscosity index improver is added to the process oil in order to reduce the change of the viscosity according to the temperature in order to improve or supplement such properties.

The viscosity index improver used in the present invention is a high molecular weight compound having a molecular weight of 50,000 to 150,000. The viscosity of the high molecular weight compound increases as the temperature of the high molecular weight compound increases. When the temperature is lowered, Was used to prevent the viscosity from rising sharply.

In other words, when the viscosity index improver, which is a polymer compound, is dissolved in the process oil, the viscosity of the polymer in the lubricating oil is low due to the small volume of the polymer in the lubricating oil, The cohesive force is reduced and released into the process oil, so that the viscosity increases and the viscosity increases. Therefore, the viscosity index improver used in the present invention can prevent a sharp change in viscosity from -40 ° C to 100 ° C.

The viscosity index improver may be selected from the group consisting of poly-iso-butylene, olefin copolymer, ethylene-propylene copolymer, styrene-butadiene copolymer, , Styrene-maleic acid-ester copolymer and / or poly-methacrylate are preferably used.

When the paraffinic synthetic oil is added to the water-borne paste composition constituting the present invention, the adhesion at room temperature is maintained even in the summer, and the flexibility is maintained at a low temperature in winter.

The addition amount of the paraffinic synthetic oil to the water-borne paste composition constituting the present invention is preferably 1-15% by weight, and if it is less than 1% by weight, the effect of addition is scarcely produced. If it exceeds 15% by weight, Tends to oxidize the underlying concrete surface.

Further, antioxidants, light stabilizers (ultraviolet absorbers or HALS light stabilizers), heat stabilizers, and the like may be further added to prevent deterioration of the physical properties of the high adhesion water-soluble paste.

Unlike existing waterproofing materials, it does not generate environmentally harmful substances such as volatile organic compounds (VOC) and it includes water to develop environmentally friendly products that can be applied at room temperature. Therefore, it is possible to reduce the construction cost without using special equipment have.

The emulsion number (b) of the present invention will be described as follows.

Water is preferred to be purified water or ionized water in a high-adhesion hydrated paste, but general water, e.g. tap water or ground water, has chemical ionic constituents, which can have a beneficial or detrimental effect on stable hydrated pastes .

For example, the presence of calcium and magnesium ions in water is beneficial to the stable cationic hydration paste composition (improves storage stability). However, the presence of carbonate or bicarbonate ions in water can be detrimental to a stable cationic hydration paste composition (more insoluble salts are usually in crystalline form due to their reaction with water-soluble amine hydrochlorides used as cationic emulsifiers do). Conversely, the presence of carbonate or bicarbonate ions in the anionic wetting paste composition can be said to be beneficial because of the foam effect.

The particulate material present in water can be detrimental to the cationic hydration paste composition due to the rapid adsorption of the cationic surfactant by the normally counter-charged colloidal material. (Such electrochemical adsorption may be due to the reduction of the cationic surfactant in the aqueous solution Of the emulsion application and the properties of the finished hydrated paste. Therefore, water containing various impurities is preferably purified and used.

The water content in the aqueous paste composition of the present invention is preferably 20-40 wt%. If the content of water is less than 20% by weight, it is difficult to disperse the modified asphalt mixture in colloidal form on the continuous material, and it is difficult to achieve the desired purpose. When the water content exceeds 40% by weight, the modified asphalt mixture is dispersed in colloidal form , It is necessary to evaporate the water when applying it in the field so that the physical property as a repair material for cracks is obtained. In this process, the volume of the waterproofing material may be decreased by the volume of water, that is, there may be contraction. And the water content is excessively excessive, so that the curing speed is slowed, which may cause a delay in the construction period.

The aqueous hydration paste composition according to the present invention is preferably added to water in an amount of 0.3 to 3% by weight of an emulsifier to disperse the modified asphalt mixture in a uniform colloidal form on a continuous basis.

Most asphalt emulsifiers are made from renewable resources such as natural fats, oils, woody. Because asphalt emulsifiers have lipophilic, hydrophilic parts at the interface between water and asphalt. They also reduce the energy required to emulsify the asphalt and prevent the coalescence of the once formed particles.

The emulsifier structure constituting the present invention is a surfactant moiety (hydrophilic (polar)) which dissolves in an asphalt-soluble surfactant moiety (lipophilic (nonpolar), hydrophilic or other polar liquid). In the present invention, a cationic emulsifier, Is used.

The cationic emulsifier is an emulsifier prepared to emulsify the modified asphalt mixture in colloidal form on the water. Its constituent is diethyl methyl dodecyl ammonium, which is insoluble in water, For example, the addition of hydrochloric acid (HCl) makes the water-based paste so that the water-soluble paste becomes acidic.

[Formula 1]

For reference, the reaction between the emulsifier and the acid is shown in the following Reaction Scheme 1.

[Reaction Scheme 1]

RNH ₂ + HCl = RNH ³⁺ + Cl ^-

The emulsion type of cationic emulsifier has a fast curing and very tenacious asphalt film form regardless of atmospheric moisture. Some excess acid is used as an organic base in the preparation of cationic hydrated paste. This excess acid is present in the water and the hydration paste is acidic.

In the present invention, PH is preferably 1-3, and when PH 3 is exceeded, the amount of the acid to react with the water-insoluble emulsifier is small and the emulsifier is not water-soluble. As a result, the asphalt mixture is difficult to be dispersed in colloidal form If the pH is less than 1, even if the modified asphalt mixture is dispersed in the form of colloids in the form of water, the flocculation or coalescence between the colloids existing in the water due to the reverse reaction of the water and the colloid occurs quickly, And the like.

(1) an alkali component such as Ligin-type material (57%), polymerized rosin acids (28%), dimethoxystilbene (15%) (2) NaOH, : (2) is 91: 9 and has the following formula.

[Formula 2]

 For reference, the reaction between the emulsifier and the base is shown in the following reaction formula (2).

[Reaction Scheme 2]

RCOOH + NaOH = RCOOH ^- + Na ⁺ + H ₂ O

When the anionic emulsifier resin acid salt is dissolved in water, the molecule is charged at the negative charge portion as an oleophilic portion or a hydrophilic portion. The positively charged region is a hydrophilic group that is highly water soluble and allows other substances to be strongly dispersed in water. The anionic emulsifier emulsion type is excellent in emulsion stability and has the advantage of securing the working time because the curing time is slower than the cation type.

In the present invention, the pH is preferably 8 to 10, and when the pH is less than 8, the amount of the base to be reacted with the water-insoluble emulsifier is small and the emulsifier is not water-soluble. As a result, the asphalt mixture is difficult to be dispersed in colloidal form If the pH is more than 10, the flocculation or coalescence of the colloids existing on the water due to the reverse reaction of the water phase and the colloid occurs rapidly, even if the modified asphalt mixture is dispersed in the colloid form on the water. There is a tendency to cause stability problems.

Therefore, if the amount of the emulsifier contained in the water-borne paste composition of the present invention is less than 0.3 weight, the modified asphalt mixture is not dispersed in a uniform colloid form on a continuous basis, If more than 3% by weight of water is evaporated, the physical properties of the remaining crack repair agent may be changed. If the emulsifier content is larger, the dispersed indenter and the double layer of the water become closer to each other and the zeta potential is lowered Resulting in a problem of storage stability.

In order to improve the adhesiveness, the low-temperature flexibility and the heat resistance, the synthetic polymer emulsion is preferably added in an amount of 1 to 10% by weight. Such a synthetic polymer emulsion can be used alone or in combination with SB latex (styrene-butadiene latex), acrylic emulsion, PVAc, and the like. A small amount of antifoaming agent can be added to remove the bubbles generated during emulsification. Hydrocarbon polyglycol type, silicone type and the like can be selectively used.

The other additive mixture (c) of the present invention is composed of 10-30% by weight of water, 5-20% by weight of an inorganic filler, 0.1-1% by weight of a thickener and 0.1-1% by weight of a dispersion stabilizer.

The other additive mixture (c) is used as an additive to improve the physical properties of the modified asphalt mixture emulsion (a) modified asphalt mixture and (b) emulsified water emulsified using a colloid mill.

In the other additive mixture (c), the inorganic filler is preferably added in an amount of 5-20% by weight as a material for increasing the strength and heat resistance of the waterproofing material, lowering the cost, and controlling the viscosity when the inorganic filler is dispersed and hardened in the high- . As the type thereof, talc, silica, dolomite, magnesium hydroxide, abrasive, steelmaking slag, etc. may be used alone or in combination. Among the inorganic fillers, it is preferable to use talc, calcium carbonate or silica alone, and two or more of talc, calcium carbonate or silica may be used in combination depending on the use. The average particle size of talc, calcium carbonate or silica is advantageous as it is smaller, but it is suitable if it is between 20-2,000 mesh.

In the aqueous paste of the present invention, the inorganic filler is added in an amount of 5-20% by weight. When the amount of the inorganic filler is less than 5% by weight, the effect is insufficient for controlling the strength, product cost and viscosity. There is a disadvantage that the emulsified state of the product is destroyed or the stability thereof is rapidly deteriorated.

In addition, (d) the thickener in the other additive mixture is dispersed in the high adhesion water-soluble paste and is used to control the storage stability and the work performance by controlling the viscosity so as not to flow when applied to the vertical wall or inclined surface By weight, preferably 0.1 to 1% by weight.

As the thickening agent, ethyl cellulose, methallylulose, aqueous EVA, cellulose fiber, synthetic fiber, etc. may be used. One or two or more of the above materials may be mixed and used. If the addition amount is less than 0.1% by weight, the amount thereof used is too small to control the viscosity, so that the stability and workability of the product can not be ensured. If the addition amount exceeds 1% by weight, It is destroyed and a problem occurs in stability.

In one embodiment of the present invention, the thickener is a cellulose of the formula:

The OH of the cellulose is hydrolyzed to ethylene oxide, and the cellulose is transformed into a hydroethylene cellulosic of the following formula.

And (c) the dispersion stabilizer in the other additive mixture is preferably 0.1 to 1% by weight as an additive which prevents the precipitation and stably disperses when the inorganic filler is applied to the high-adhesion hydration paste. In the present invention, Phosphate Ester type TH-100 from ASHLAND was used.

The dispersion stabilizer is in the form of a phosphoric acid having the formula:

The dispersion stabilizer is condensed with a diol of the raw material having the formula HOROH to form a reactant of the following formula.

(Wherein R is a hydrocarbon compound having 1 to 20 carbon atoms)

The high adhesion water-soluble paste composition of the present invention can be prepared in a batch or continuous manner in the order of an impeller mixer and a colloid mill, but it is preferable to use a continuous method in order to obtain a more stable and uniformly dispersed composition.

FIG. 1 is a step diagram of a method for manufacturing a highly adhesive hydrated paste composition according to an embodiment of the present invention.

Referring to Figure 1, the method comprises: (a) preparing a modified asphalt mixture; (b) an emulsifying water producing step; (c) other additive mixture preparation step; (d) preparing a modified asphalt mixture emulsion using (a) a modified asphalt mixture and (b) emulsified water using a colloid mill; (e) (d) adding the other additive mixture (c) to the modified asphalt mixture emulsion, and then using the colloid mill to prepare a highly adhesive hydrated paste composition.

The modified asphalt mixture (a) is composed of 40 to 70% by weight of asphalt and 0.5 to 10% by weight of the paraffinic synthetic oil to make the asphalt have a constitution called "asphaltene" The thermoplastic elastomer and the petroleum resin are mixed at a temperature of 150 to 180 DEG C for the purpose of improving the brittleness by dispersing the plasticizer and the softening agent in the composition, and then 1 to 10% by weight of the thermoplastic elastomer and 0.5 to 20% Is homogenized by stirring at a temperature of 150 to 200 DEG C so as to shorten the dispersing time with the asphalt at a high temperature and then emulsified at a minimum temperature having fluidity so as to disperse the homogenized modified asphalt mixture in colloidal form on the continuous product In order to prevent the evaporation of water, it is necessary to maintain the temperature at 110 to 160 ° C.

(B) emulsified water is added to 20 to 40% by weight of water in an amount of 0.3 to 3% by weight of an emulsifier and optionally various other additives (SB-Latex 1-20% by weight, acrylic emulsion 0.5-10% by weight, PVAc 0.1 -10 wt.%, Defoamer 0.01-0. 1 wt.%) Is added to the preheated modified asphalt mixture (to have fluidity) and the emulsification must be preheated in order to successfully emulsify and evaporation of water may occur at too high a temperature At a temperature of 30 to 70 캜 to prepare emulsified water separately from the modified asphalt mixture.

(C) the other additive mixture is mixed at 10 to 30 wt% with water at 20 to 40 DEG C in an amount of 5 to 20 wt% of an inorganic filler, 0.1 to 1 wt% of a thickener, and 0.1 to 1 wt% Asphalt mixture, and emulsified water.

The prepared asphalt mixture and emulsified water are added little by little using a flow pump to uniformly disperse the asphalt mixture in colloidal form on a continuous basis with a colloid mill (3,000 to 4,000 rpm) to obtain a modified asphalt mixture emulsion .

A uniform and stable high-adhesion hydration paste composition is prepared by using (c) the other additive mixture in the emulsion of modified (d) modified asphalt mixture prepared above using a colloid mill.

The high adhesion water-soluble paste composition of the present invention exhibits excellent low temperature flexibility due to an appropriate amount of a plasticizer, which is a paraffinic synthetic oil, unlike a conventional waterproofing material. By selectively applying acrylic emulsion and PVAc, the tensile strength of the asphalt coating film is improved It has the advantage of quick drying without air pockets or lifting at the surface water content of 10% or more, and it does not flow down from the vertical wall or sloping place due to application of high solid content, thickener and dispersion stabilizer. And it is possible to secure the durability and stability of the concrete structure by forming integrated behavior with the concrete, which utilizes the adhesive property.

In addition, by selecting an appropriate emulsifier, the asphalt mixture is dispersed in a stable colloid form on the continuous material by the emulsifier. Therefore, it is possible to lower the cost of construction by eliminating the need for special equipments and specialist. In addition, It is possible to contribute to environmental protection by securing a technique for obtaining a high-adhesion water-soluble paste free from harmful substances and a manufacturing method thereof.

Hereinafter, the present invention will be described in detail with reference to the paste-applied hydrated paste composition of the present invention. However, the present invention is not limited only to the following examples.

Production Example 1

(A condensation product of chlorinated paraffin and phenol) and a viscosity index improver (olefin copolymer) in a weight ratio of 1: 1 to 80 wt% of a hydrotreated lubricating oil (SK-Lubutek, Cas No. 64741-88-44) 20% by weight of a mixture was synthesized to prepare a paraffinic synthetic oil.

The paraffinic synthetic oil has a density of 0.08861, a kinematic viscosity index (40 ° C, mm 2 / S) of 124.4, a pour point of -40 ° C and a flash point of 276 ° C.

Example 1

(a) preparing a modified asphalt mixture;

7.7% by weight of paraffinic synthetic oil was added to 49.7% by weight of superfat (SK Energy) which is an asphalt having an invasion degree of about 70 dmm and a softening point of 70 캜, and the mixture was mixed at 180 캜 for 30 minutes. Then, a thermoplastic elastomer ( , 9.3% by weight of a tackifier (Kolon Oil Co., Ltd., SU-120) and 0.5% by weight of an antioxidant (SONGNOX 21B, Songwon Industrial Co., Ltd.) , Stirring was carried out at a stirring speed of about 600 rpm for 2 hours, and the temperature was maintained at 140 캜.

(b) an emulsifying water producing step;

1% by weight of a nitrone-based emulsifier (Indus QTS) by Meadwestvaco Co., 3% by weight of SB latex (KKP 341 KK), acrylic emulsion (CM- 6000) and 1% by weight of PVAc (Daeheung Specialty Chemicals, D-450D) were added and mixed at 40 캜. Finally, hydrochloric acid (35% HCl) was added to adjust the emulsified water to PH 1-3 .

(c) other additive mixture preparation step;

5.6% by weight of an inorganic filler (Omia, Talc), 0.5% by weight of a thickener (NHS-300, ASHLAND) and 0.5% by weight of a dispersion stabilizer (TH-100, ASHLAND) were added to 3.4% by weight of water containing no impurities Lt; 0 > C and 30 [deg.] C.

(d) an emulsification step;

70 wt% of the modified asphalt mixture (a) maintained at 140 캜 was added in small portions of 20 wt% of emulsified water (b) maintained at 40 캜 using a colloid mill for 30 minutes to prepare a modified asphalt mixture (a) Was dispersed in colloidal form on a continuous basis to prepare a modified asphalt mixture emulsion.

(e) a high-build hydration paste manufacturing step;

The other additives (c) were added to the modified asphalt mixture emulsion (d) using a colloid mill to prepare a uniform and stable high-adhesion water-soluble paste.

Example 2

The procedure of Example 1 was repeated except that the emulsifier was replaced with an anionic emulsifier (Vinsol NVX, Pinova, lnc) instead of a nitrone-based cationic emulsifier (Indulin QTS, Meadwestvaco). NaOH is added to the emulsified water to adjust pH to 8-10.

Comparative Example 1

was prepared in the same manner as in Example 1 except that (a) 50% by weight of the modified asphalt mixture, (b) 40% by weight of the cationic emulsified water and (c) 10% by weight of the other additives mixture.

Comparative Example 2

was prepared in the same manner as in Example 1 except that (a) 50% by weight of the modified asphalt mixture, (b) 40% by weight of anionic emulsified water, and (c)

Comparative Example 3

High Adhesion Water Paste Specification Value

The nonvolatile matter, crack resistance, adhesion strength, resistance to water permeation, spill resistance, and VOC of the water-borne paste compositions of Examples 1-2 and 1-2 prepared as described above were measured as follows The results are shown in Table 2 below.

Example and Comparative Example Measurement Method

1) Non-volatile matter: KS M 5000

2) Cracking resistance: KS F 4936

3) Bond strength: KS F 3211

4) Permeability: KS F 4934

5) Flow resistance: KS F 3211

6) VOC: indoor air quality process test standard

7) Touch dry time: KS F 4932

Test Items Comparative Example 3 Example 1 Example 2 Comparative Example 1 Comparative Example 2 Non-volatile matter (%) More than 80 82 81 60 62 Crack resistance (-20 ℃) No problem clear clear clear clear Bond strength (N / mm2) 0.5 or more 0.6 0.5 0.4 0.3 Shooting performance Not to pitch clear clear clear clear Dripping
Resistance performance mm 2 or less 0 0 5 3 No wrinkles No wrinkles clear clear Wrinkles Wrinkles VOC (g / L) Less than 50 10 10 10 10 Touch dry time (hr) 3 or less 2 3 5 7 PH - 1.5 10 2 9 Thickness (mm) - 2 2 2 2 Viscosity (cps) - 12000 15000 7500 8000

As can be seen from the above-mentioned experimental results, the high adhesion water-soluble paste of Examples 1 and 2 of the present invention exhibited excellent non-volatile matter, crack resistance, adhesion strength, resistance to permeability, spill resistance performance, VOC, It was confirmed that all the values of this standard were satisfied.

However, in Comparative Examples 1 and 2, it was found that the values of the tack-free drying time, the falling resistance and the adhesion strength were below the standard values because the solid content was small.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments.

Claims (7)

As a high adhesion hydrating paste composition,
40-70 wt% asphalt; 1-10% thermoplastic elastomer; 1-15% by weight plasticizer; 0.5 to 20% by weight of a tackifier; 0.3-3% by weight of emulsifier; 1-20% by weight of styrene-butadiene latex; 0.5-10% by weight of acrylonitrile; 0.1-10% by weight of polyvinyl acetate (PVAc); Defoamer 0.01-0.1 wt%; 5 to 20% by weight of an inorganic filler; 0.1-1 weight% thickener; 0.1-1% by weight of a dispersion stabilizer; And balance water,
The dispersion stabilizer has the following formula,

Wherein the dispersion stabilizer is condensed with a diol of a raw material having the formula of HOROH to form a reactant of the following formula.

(Wherein R is a hydrocarbon compound having 1 to 20 carbon atoms) The method of claim 1,
Wherein the emulsifier comprises a cationic emulsifier that is diethyl methyl dodecyl ammonium. The composition according to claim 2, wherein the emulsifier further comprises a resin acid salt anionic emulsifier having the following structural formula.

4. The composition according to claim 3, wherein the thickening agent is cellulose having the following formula:

(Where n is an integer) 5. The method of claim 4,
Wherein the OH of the cellulose is hydrolyzed to ethylene oxide so that the cellulose is modified with hydroxymethylcellulose of the formula:

delete (a) 1-10 weight% of thermoplastic elastomer, 1-15 weight% of plasticizer and 0.5-20 weight% of tackifier are added to 40-70 weight% of asphalt and homogeneously dispersed (mixed) in asphalt at 150-180 Lt; RTI ID = 0.0 > 110 C < / RTI >
(b) 0.3 to 3% by weight of an emulsifier, 1 to 20% by weight of SB Latex, 0.5 to 10% by weight of an acrylic emulsion, 0.1 to 10% by weight of PVAc and 0.01 to 0.1% by weight of an antifoaming agent are added to 20 to 40% Lt; 0 > C to 70 [deg.] C to prepare emulsified water;
(c) adding 5 to 20% by weight of an inorganic filler, 0.1 to 1% by weight of a thickener, and 0.1 to 1% by weight of a dispersion stabilizer to 10 to 30% by weight of water and mixing at 20 to 40 캜;
(d) emulsifying the above (a) and (b) using a colloid mill (high shear, 3,000-4,000 rpm) to prepare a modified asphalt mixture emulsion; And
(e) adding (c) other mixtures to the modified asphalt mixture emulsion of (d) and dispersing it in a uniform colloidal form on a continuous water using a colloid mill,
The dispersion stabilizer has the following formula,

The dispersion stabilizer is a condensation reaction with a diol (Diol) of the raw material having a HOROH formula, to form a reactant of the following formula to form a highly adherent aqueous paste composition.

(Wherein R is a hydrocarbon compound having 1 to 20 carbon atoms)

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