KR101286172B1 - High strength and heat-resistance cold-rolled steel sheet having excellent formability, heat resistance for working and manufacturing method thereof - Google Patents

High strength and heat-resistance cold-rolled steel sheet having excellent formability, heat resistance for working and manufacturing method thereof Download PDF

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KR101286172B1
KR101286172B1 KR1020090120148A KR20090120148A KR101286172B1 KR 101286172 B1 KR101286172 B1 KR 101286172B1 KR 1020090120148 A KR1020090120148 A KR 1020090120148A KR 20090120148 A KR20090120148 A KR 20090120148A KR 101286172 B1 KR101286172 B1 KR 101286172B1
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steel sheet
rolled steel
heat resistance
strength
cold
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KR20110063193A (en
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김재익
김성진
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주식회사 포스코
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0421Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
    • C21D8/0426Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0421Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
    • C21D8/0436Cold rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0447Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
    • C21D8/0473Final recrystallisation annealing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/004Very low carbon steels, i.e. having a carbon content of less than 0,01%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

Abstract

본 발명은 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판 및 그 제조방법에 관한 것으로, 중량%로 C:0.002~0.010%, Mn:0.3~0.6%, P:0.03~0.08%, Al:0.02~0.08%, B:0.001~0.003%, W:0.05~0.30%, N:0.002~0.010%, Nb:0.02~0.08%, S:0.015%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판 및 그 제조방법을 기술적 요지로 한다. 본 발명에 의하면 기존의 스테인레스 강판에 비해 저비용으로 제조 가능하고, 신장 플랜지성, 벤딩성 및 딥드로잉성(deep drawing)의 다양한 가공특성을 갖고 있어 상온 가공성이 우수하며, 고용원소 석출로 내시효성이 증가하여 항복점 연신현상이 발생하지 않아 성형성이 우수할 뿐만 아니라, 고온 강도가 뛰어나 고온 적용 제품의 형상 동결성 확보로 설비 수명이 연장되는 고강도의 가공용 고내열 냉연강판을 제조할 수 있다.The present invention relates to a high-strength, high-temperature cold rolled steel sheet having excellent workability and heat resistance, and a method for manufacturing the same, in weight% of C: 0.002 to 0.010%, Mn: 0.3 to 0.6%, P: 0.03 to 0.08%, and Al: 0.02. ~ 0.08%, B: 0.001 ~ 0.003%, W: 0.05 ~ 0.30%, N: 0.002 ~ 0.010%, Nb: 0.02 ~ 0.08%, S: 0.015% or less, processability and heat resistance including residual Fe and other unavoidable impurities The excellent high strength high heat resistant cold rolled steel sheet and its manufacturing method are made into a technical summary. According to the present invention, it can be manufactured at a lower cost than the conventional stainless steel sheet, and has various processing characteristics such as extension flange, bending property, and deep drawing property, and thus has excellent room temperature processability, and anti-aging property due to precipitation of solid elements. It is possible to produce high strength cold-rolled steel sheet for high-strength processing, which increases the life of the facility by securing the shape freezing property of the high-temperature applied product because it has excellent moldability due to the increase in yield point stretching.

냉연강판, 침상 베이나이트, 내열성, 가공성, 고강도, 내시효성 Cold Rolled Steel Sheet, Needle Bainite, Heat Resistance, Processability, High Strength, Aging Resistance

Description

가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판 및 그 제조방법{HIGH STRENGTH AND HEAT-RESISTANCE COLD-ROLLED STEEL SHEET HAVING EXCELLENT FORMABILITY, HEAT RESISTANCE FOR WORKING AND MANUFACTURING METHOD THEREOF}High-strength, high-temperature cold-rolled steel sheet for processing and its manufacturing method excellent in workability and heat resistance {HIGH STRENGTH AND HEAT-RESISTANCE COLD-ROLLED STEEL SHEET HAVING EXCELLENT FORMABILITY, HEAT RESISTANCE FOR WORKING AND MANUFACTURING METHOD THEREOF}

본 발명은 자동차, 가전제품 및 보일러 등에 사용되는 고강도의 가공용 고내열 냉연강판 및 그 제조방법에 관한 것으로, 보다 상세하게는 강 성분과 공정 조건을 최적화함으로써 제조된 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판 및 그 제조방법에 관한 것이다.The present invention relates to a high strength, high temperature resistant cold rolled steel sheet used in automobiles, home appliances and boilers, and to a method of manufacturing the same. It relates to a heat resistant cold rolled steel sheet and a method of manufacturing the same.

종래부터 자동차 배기계, 가정용 연통, 오븐 및 보일러 등과 같은 제품 부재에는 주철이 사용되는 것이 일반적이었으나, 수백도(℃) 이상의 고온 환경에 지속적으로 노출되어 높은 내열특성(heat resistance)이 요구되므로 이러한 고온 특성을 확보하기 위하여 알루미늄 용융도금강판, 스테인리스 강판 등을 가공하여 사용하게 되었다.In the past, cast iron was generally used in parts of products such as automobile exhaust systems, home communication systems, ovens, boilers, etc., but high heat resistance is required because it is continuously exposed to a high temperature environment of several hundred degrees (° C.) or higher. In order to secure an aluminum hot-dip galvanized steel sheet, stainless steel sheet, etc. were processed and used.

고온 특성이란 가공된 제품이 고온 환경에서 사용될 때의 특성중 하나로서, 자동차 배기계 등의 제품 사용시 국부적인 온도 상승에 의해 제품의 특성이 열화될 수 있으므로 고온 특성, 즉 내새그성 및 고온강도가 요구된다. 이중 내새그성이란 강판이 고온에 반복적으로 노출되어 재질의 변화가 일어나 처지는 현상(sagging)으로서 이러한 현상이 발생하면 성형부의 형상 유지가 곤란하게 되며, 열 응력이 특정 장소로 집중될 경우 고온 내력이 저하되어 제품 형상이 변형되거나 파괴가 일어나므로 형상 동결성 확보를 위해 700℃내외의 고온에서 55MPa이상의 항복강도를 만족할 필요가 있다.The high temperature property is one of the characteristics when the processed product is used in a high temperature environment. The high temperature property, that is, sag resistance and high temperature strength, is required because the product property may be deteriorated by a local temperature rise when using a product such as an automobile exhaust system. . The sag resistance is a phenomenon in which the steel sheet is repeatedly exposed to high temperature and sagging due to changes in the material. When such a phenomenon occurs, it is difficult to maintain the shape of the molded part, and when the thermal stress is concentrated to a specific place, the high temperature strength decreases. Since the product shape is deformed or destroyed, it is necessary to satisfy the yield strength of 55MPa or more at a high temperature of about 700 ° C to secure the shape freezing property.

이와 같은 내열 용도로 스테인리스 강판(stainless steel sheet)이 주로 사용되어 왔지만, 스테인리스 강판은 Cr, Ni 등 고가의 합금원소의 다량 첨가로 제조 비용이 고가일 뿐만 아니라 고온에서 가열시 결정립계의 Cr이 C와 결합하여 입계에 크롬카바이드(chromium carbide)가 석출됨으로써 생긴 Cr 고갈층(chromium depleted zone) 부위에 입계 부식이 발생되어 내식성(corrosion resistance)이 떨어지는 문제점이 있다Stainless steel sheet has been mainly used for such heat-resistance, but stainless steel sheet is not only expensive to manufacture due to the addition of expensive alloy elements such as Cr and Ni, but also has a high Cr and There is a problem in that corrosion resistance (corrosion resistance) is lowered because grain boundary corrosion occurs in the Cr depleted zone region formed by the precipitation of chromium carbide at the grain boundary by bonding.

그리고, 고온에서 내산화성을 확보하기 위하여 알루미늄 용융도금강판을 사용하기도 하나, 이러한 알루미늄 용융도금강판은 400℃이상의 고온으로 가열되는 경우에는 Fe와 Al의 상호 확산반응에 의한 계면의 합금층이 성장하여 단시간에 표면의 광택을 잃어버리고 변색되어 내열특성이 부족하게 되므로 적용될 수 있는 용도가 제한되는 문제점이 있다.Also, in order to secure oxidation resistance at high temperature, an aluminum hot dip galvanized steel sheet may be used. When the aluminum hot dip galvanized sheet is heated to a high temperature of 400 ° C. or higher, an alloy layer of an interface is grown due to the interdiffusion reaction between Fe and Al. There is a problem in that the application can be applied because it loses the gloss of the surface in a short time and the color change is insufficient heat resistance.

또한, 자동차의 배기계, 가정용 연통, 오븐 및 보일러 등과 같은 제품은 한정된 공간에 수용되도록 제조되고, 다양한 방법을 통해 복잡한 형상으로 성형되어 조관후에는 확관하거나 벤딩하는 가공 공정이 필요하므로 상기 고온 특성 이외에도 상온 가공성이 요구될 뿐만 아니라, 사용 부재의 내충격 특성 확보를 위해서는 상 온에서 인장강도 350MPa이상이 요구된다.In addition, products such as automobile exhaust system, home communication, oven, boiler, etc. are manufactured to be accommodated in a limited space, and formed into a complex shape by various methods, so that the processing process to expand or bend after piping is required, in addition to the above high temperature characteristics Not only workability is required, but tensile strength of 350 MPa or more is required at room temperature in order to secure impact characteristics of the use member.

그리하여, 일본 공개특허공보 특개평9-176816은 강중 Al과 고용된 N의 함량을 조정한 강판을 알루미늄 도금후 열처리하여 내열성과 가공성을 향상시키고자 하였으나, 상기 강판은 550℃이상의 온도에서 사용되는 제품의 부재로 적용되기 어렵고, 강 성분의 첨가량 조정이 용이하지 않아 가공성 열화 및 시효에 의한 가공 결함이 우려된다.Thus, Japanese Laid-Open Patent Publication No. 9-176816 attempts to improve heat resistance and workability by heat-treating a steel sheet after adjusting aluminum content of Al and solid solution N in steel, but the steel sheet is used at a temperature of 550 ° C. or higher. It is difficult to be applied to a member of, and it is not easy to adjust the amount of the steel component to be added, which may cause workability deterioration and processing defects due to aging.

또한, 일본 공개특허공보 특개평8-319548은 강판의 표면에 피복층을 형성함에 의해 고온강도 등이 우수한 용융알루미늄 도금강판을 제조하고자 하였으나, 강판의 특성 개선보다는 도금 조건의 개선 방안을 제시하고 있어 도금층 성분 변경시 그 조정이 어려울 뿐만 아니라, 목표로 하는 내열성을 얻기 어려운 문제가 있다.In addition, Japanese Patent Application Laid-open No. Hei 8-319548 attempts to manufacture a hot-dip aluminum plated steel sheet having excellent high temperature strength by forming a coating layer on the surface of the steel sheet, but suggests a method of improving the plating conditions rather than improving the properties of the steel sheet. Not only is the adjustment difficult when the ingredients are changed, but also there is a problem that it is difficult to obtain target heat resistance.

또한, 일본 공개특허공보 특개평9-111396은 페라이트와 마르텐사이트의 2상 조직으로 이루어진 내충격 특성이 우수한 고강도 강판을 제조코자 하였으나, 연신이 충분치 않아 성형성이 좋지 않은 문제가 있다.In addition, Japanese Laid-Open Patent Publication No. Hei 9-111396 intends to manufacture a high strength steel sheet having excellent impact resistance characteristics composed of two-phase structure of ferrite and martensite, but there is a problem in that moldability is not good due to insufficient stretching.

본 발명자는 상기와 같은 문제점을 해결하기 위하여 연구와 실험을 거듭하고 그 결과에 근거하여 본 발명을 제안하게 된 것으로, 본 발명은 자동차 배기계, 가정용 연통, 오븐 및 보일러 등과 같이 고온 및 상온 특성이 동시에 요구되는 용도에 사용하기 위해, 고가의 합금원소의 첨가를 줄이면서 강 성분과 공정 조건을 최적화함으로써 저비용으로 제조 가능한 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판 및 그 제조방법을 제공하는데 그 목적이 있다.The present inventors have repeatedly conducted research and experiments to solve the above problems and propose the present invention based on the results, and the present invention simultaneously exhibits high temperature and room temperature characteristics such as automobile exhaust system, household communication, oven and boiler, etc. The present invention provides a high-strength cold-rolled steel sheet for processing and heat-resistance with excellent workability and heat resistance that can be manufactured at low cost by optimizing steel components and processing conditions while reducing the addition of expensive alloying elements for use in demanding applications. There is this.

본 발명은 중량%로 C:0.002~0.010%, Mn:0.3~0.6%, P:0.03~0.08%, Al:0.02~0.08%, B:0.001~0.003%, W:0.05~0.30%, N:0.002~0.010%, Nb:0.02~0.08%, S:0.015%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판을 제공한다.In the present invention, C: 0.002 to 0.010%, Mn: 0.3 to 0.6%, P: 0.03 to 0.08%, Al: 0.02 to 0.08%, B: 0.001 to 0.003%, W: 0.05 to 0.30%, and N: Provides a high strength, high temperature cold rolled steel sheet for processing having excellent workability and heat resistance including 0.002 to 0.010%, Nb: 0.02 to 0.08%, S: 0.015% or less, balance Fe and other unavoidable impurities.

이때, 상기 Nb와 C의 원자비 Nb/C의 값이 0.8~2.0인 것에도 그 특징이 있다.At this time, the characteristic of the atomic ratio Nb / C of Nb and C is 0.8-2.0, too.

게다가, 상기 냉연강판은 Nb계 탄화 석출물이 형성된 것에도 그 특징이 있다.In addition, the cold rolled steel sheet is characterized in that the Nb-based carbide precipitates are formed.

뿐만 아니라, 상기 B와 N의 원자비 B/N의 값이 0.5~1.5인 것에도 그 특징이 있다.In addition, the characteristic is that the value of the atomic ratio B / N of the B and N is 0.5 ~ 1.5.

그리고, 상기 냉연강판은 B계 질화 석출물이 형성된 것에도 그 특징이 있다.In addition, the cold rolled steel sheet is characterized in that the B-based nitride precipitates are formed.

나아가, 상기 냉연강판은 등축상 페라이트와 침상 베이나이트 조직으로 이루 어진 것에도 그 특징이 있다.Further, the cold rolled steel sheet is also characterized by being made of an equiaxed ferrite and acicular bainite structure.

이때, 상기 냉연강판의 침상 베이나이트 조직의 체적 분율은 10~25%인 것에도 그 특징이 있다.At this time, the volume fraction of the needle-shaped bainite structure of the cold rolled steel sheet is also characterized by 10 to 25%.

또한, 본 발명은 중량%로 C:0.002~0.010%, Mn:0.3~0.6%, P:0.03~0.08%, Al:0.02~0.08%, B:0.001~0.003%, W:0.05~0.30%, N:0.002~0.010%, Nb:0.02~0.08%, S:0.015%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 강슬라브를 가열한 후 열간압연하고, 권취 후 냉간압연한 다음, 냉간압연된 강판을 830℃이상의 온도에서 소둔 처리하고, 소둔 처리된 강판에 대하여 40℃/sec이상의 냉각속도로 냉각하는 것을 특징으로 하는 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판의 제조방법을 제공한다.In addition, the present invention is in the weight% C: 0.002 ~ 0.010%, Mn: 0.3 ~ 0.6%, P: 0.03 ~ 0.08%, Al: 0.02 ~ 0.08%, B: 0.001 ~ 0.003%, W: 0.05 ~ 0.30%, Steel slab containing N: 0.002 ~ 0.010%, Nb: 0.02 ~ 0.08%, S: 0.015% or less, balance Fe and other unavoidable impurities is heated, hot rolled, cold rolled, and then cold rolled steel sheet The annealing treatment at a temperature of 830 ℃ or more, and provides a high-temperature high-temperature cold rolled steel sheet for workability and heat resistance excellent in the processability and heat resistance characterized in that the cooling rate of 40 ℃ / sec or more with respect to the annealed steel sheet.

이때, 상기 강슬라브는 상기 Nb와 C의 원자비 Nb/C의 값이 0.8~2.0인 것에도 그 특징이 있다.At this time, the steel slab is characterized in that the value of the atomic ratio Nb / C of the Nb and C is 0.8 ~ 2.0.

그리고, 상기 강슬라브는 상기 B와 N의 원자비 B/N의 값이 0.5~1.5인 것에도 그 특징이 있다.In addition, the steel slab is characterized in that the value of the atomic ratio B / N of the B and N is 0.5 ~ 1.5.

게다가, 상기 열간압연은 900~950℃에서 마무리 압연하는 것에도 그 특징이 있다.In addition, the hot rolling is also characterized by finish rolling at 900 ~ 950 ℃.

뿐만 아니라, 상기 열간압연은 열간압연된 열연판을 20~80℃/sec의 냉각속도로 냉각하는 단계를 포함하는 것에도 그 특징이 있다.In addition, the hot rolling is characterized in that it comprises the step of cooling the hot rolled hot rolled plate at a cooling rate of 20 ~ 80 ℃ / sec.

나아가, 상기 권취는 560~680℃에서 행하여 지는 것에도 그 특징이 있다.Furthermore, the said winding is also characterized by what is performed at 560-680 degreeC.

아울러, 상기 소둔 처리는 830~900℃에서 행하여 지는 것에도 그 특징이 있 다.In addition, the annealing treatment is characterized in that it is performed at 830 ~ 900 ℃.

상술한 바와 같이 본 발명에 의하면, 기존의 스테인레스 강판에 비해 저비용으로 제조 가능하고, 신장 플랜지성, 벤딩성 및 딥드로잉성(deep drawing)의 다양한 가공특성을 갖고 있어 상온 가공성이 우수하며, 고용원소 석출로 내시효성이 증가하여 항복점 연신현상이 발생하지 않아 성형성이 우수할 뿐만 아니라, 고온 강도가 뛰어나 고온 적용 제품의 형상 동결성 확보로 설비 수명이 연장되는 고강도의 가공용 고내열 냉연강판을 제조할 수 있다.As described above, according to the present invention, it can be manufactured at a lower cost than the conventional stainless steel sheet, and has various processing characteristics of extension flangeability, bending property, and deep drawing property, and thus has excellent room temperature processability, As the precipitation resistance increases the aging resistance, there is no yield point elongation, so it is not only excellent in moldability but also excellent in high temperature strength, so that high-temperature cold-rolled steel sheet for high-strength processing can be manufactured to secure the shape freezing property of high-temperature applications. Can be.

이하, 본 발명의 냉연강판에 대하여 상세히 설명한다.Hereinafter, the cold rolled steel sheet of the present invention will be described in detail.

본 발명자들은 저비용으로 신장 플랜지성(stretch-flangeability), 벤딩성(bendability), 딥드로잉성(deep drawing) 등의 다양한 가공특성과 내시효성(anti-aging properties), 내식성을 만족하면서 700℃에서 55MPa 이상의 항복강도와 상온에서 350MPa이상의 인장강도를 확보하기 위한 연구 및 실험을 거듭하여 본 발명을 완성시켰다. 그 결과로 본 발명은 극저탄소량을 포함시키고, 강 성분중 Mn, P의 함량을 높이며, Nb와 C 및 B와 N의 원자비를 제어하여 미세한 Nb계 탄화 석출물과 B계 질화 석출물을 형성시키고, 소둔 및 냉각 조건을 최적화하여 침상 베이나이트 조직의 체적 분율을 확보함으로써 고온에서의 내열성과 내식성, 상온에서의 내시효성 및 가공성이 우수하여 자동차 배기계, 가정용 연통, 오븐 및 보일러 등의 제품 부재로 적합한 고강도의 가공용 고내열 냉연강판을 제조하는데 그 특징 이 있다.The present inventors have satisfied various processing characteristics such as stretch-flangeability, bendability, deep drawing, etc., anti-aging properties, and corrosion resistance at low cost and 55 MPa at 700 ° C. The present invention was completed by repeating the research and experiment to secure the yield strength and the tensile strength of 350MPa or more at room temperature. As a result, the present invention includes a very low carbon content, increase the content of Mn, P in the steel components, control the atomic ratio of Nb and C and B and N to form a fine Nb-based carbonized precipitate and B-based nitride precipitates By optimizing the annealing and cooling conditions to secure the volume fraction of acicular bainite structure, it has excellent heat resistance and corrosion resistance at high temperature, aging resistance and processability at room temperature, and is suitable for products such as automobile exhaust system, home communication, oven and boiler. It is characterized by the manufacture of high strength, high temperature resistant cold rolled steel sheets.

먼저, 본 발명의 성분 한정 이유에 대하여 설명한다.(이하, 중량%는 간단히 %로 표기함)First, the reasons for limiting components of the present invention will be described.

탄소(C)는 강판의 상온 및 고온 강도 향상을 위해 첨가되는 원소로서 본 발명에서는 석출물 형성을 위해 Nb와의 반응에 의해 주로 소비된다. C의 첨가량이 증가할수록 인장 및 항복강도는 증가하나 과잉 첨가되면 시효의 원인이 되고 가공성이 저하되므로 그 상한은 0.010%가 바람직하다. 다만, 0.002% 미만이면 충분한 Nb계 탄화 석출물 생성 효과를 얻을 수 없고 결정립 크기가 증가하여 재질의 급격한 변화가 발생하므로, C의 함량은 0.002~0.010%로 한정한다.Carbon (C) is an element added to improve the strength of room temperature and high temperature of the steel sheet and is mainly consumed by the reaction with Nb in the present invention to form precipitates. As the amount of C added increases, the tensile and yield strength increases, but when added excessively, it causes aging and the workability decreases, so the upper limit is preferably 0.010%. However, if the content is less than 0.002%, sufficient Nb-based carbide precipitates may not be obtained, and the grain size may increase, causing a sudden change in the material. Therefore, the C content is limited to 0.002 to 0.010%.

망간(Mn)은 고용 강화 원소로서 강의 강도를 높이고 열간 가공성을 향상시키지만 MnS 형성에 의해 연성 및 가공성을 저해하는 원소이다. 따라서, Mn이 과잉 첨가되면 연성이 저하되고 합금원소의 다량 첨가에 의한 경제성 저하 및 중심 편석의 발생 요인이 되므로 상한은 0.6%가 바람직하다. 다만, 0.3% 미만이면 가공성은 개선되나 목표로 하는 강도 확보가 곤란하므로, Mn의 함량은 0.3~0.6%로 한정한다.Manganese (Mn) is a solid solution strengthening element that increases the strength of steel and improves hot workability, but is an element that inhibits ductility and workability by MnS formation. Therefore, when Mn is added excessively, ductility falls and it becomes a factor of economical deterioration and center segregation by adding a large amount of alloying elements, and therefore an upper limit is preferably 0.6%. However, if less than 0.3% workability is improved, but the target strength is difficult to secure, the content of Mn is limited to 0.3 ~ 0.6%.

알루미늄(Al)은 용강의 탈산을 위해 첨가되는 원소로서 강중 고용원소와 결합되어 시효 특성을 개선하므로 0.02% 이상 함유되는 것이 바람직하다. 다만, 0.08%를 초과하여 과잉 첨가되면 강중 개재물의 양을 증가시켜 표면 결함을 유발하고 가공성이 저하되므로, Al의 함량은 0.02~0.08%로 한정한다.Aluminum (Al) is an element added for deoxidation of molten steel and is preferably contained in an amount of 0.02% or more because it is combined with solid solution elements in steel to improve aging characteristics. However, excessive addition of more than 0.08% increases the amount of inclusions in the steel, causing surface defects and lowering the workability, Al content is limited to 0.02 ~ 0.08%.

인(P)은 강의 강도 및 내식성을 향상시키는 중요한 원소로서 이들 특성의 확보를 위해서는 0.03% 이상 함유되는 것이 바람직하지만, 그 함량이 0.08%를 초과하 면 주조시 중심 편석을 일으키고 가공성이 저하되므로, P의 함량은 0.03~0.08%로 한정한다.Phosphorus (P) is an important element to improve the strength and corrosion resistance of the steel, it is preferable to contain 0.03% or more in order to secure these properties, but if the content exceeds 0.08%, it causes the center segregation during casting and workability is reduced, The content of P is limited to 0.03 to 0.08%.

질소(N)는 강 내부에 고용 상태로 존재하면서 재질 강화에 유효한 원소로서 0.002% 미만 함유하면 충분한 강성을 얻을 수 없고 석출물 형성 사이트가 감소하게 되며, 그 함량이 0.010%를 초과하면 고용원소 과다로 시효의 원인이 되어 경화가 일어나 성형성을 악화시키는 주원인이 되므로, N의 함량은 0.002~0.010%로 한정한다.Nitrogen (N) exists in solid solution inside the steel and is effective for strengthening the material. If it contains less than 0.002%, sufficient stiffness cannot be obtained, and the precipitate formation site is reduced. Since it causes aging and hardening occurs and deteriorates moldability, N content is limited to 0.002% to 0.010%.

보론(B)은 강 내부에 고용되어 강도 및 인성을 높이고, BN과 같은 보론계 질화 석출물 형성에 의해 내시효성, 가공성을 향상시키며, 고온에서 결정립 성장을 억제하는데 효과적인 바, 이와 같은 효과를 얻기 위해서는 0.001% 이상 첨가되는 것이 바람직하지만, 그 함량이 0.003%를 초과하면 재질 편차가 유발되고 고온에서 재결정을 현저히 지연시켜 작업성을 저하시키는 요인이 되므로, B의 함량은 0.001~0.003%로 한정한다.Boron (B) is dissolved in the steel to increase the strength and toughness, and to improve the aging resistance and workability by forming boron-based nitride precipitates such as BN, effective in suppressing grain growth at high temperature. It is preferable to add more than 0.001%, but if the content exceeds 0.003%, material variation is caused, and retardation of recrystallization at a high temperature is a factor that degrades workability, so the content of B is limited to 0.001 to 0.003%.

황(S)은 강중 Mn과 결합해 부식 개시점 역할을 하는 비금속 개재물을 형성하고 적열취성(red shortness)의 요인이 되므로 가능한 그 함량을 저감시키는 것이 바람직하므로 S의 함량은 0.015%이하로 한정한다.Sulfur (S) combines with Mn in the steel to form non-metallic inclusions that serve as the starting point of corrosion and causes red shortness, so it is desirable to reduce the content as much as possible, so the content of S is limited to 0.015% or less. .

니오븀(Nb)은 강판의 강도 상승과 결정립 미세화에 유효한 원소로서, 본 발명에서는 강중 고용된 C와 결합하여 Nb계 탄화 석출물을 형성하여 시효성 및 성형성을 개선하고 강도가 증가되며, 고온에서의 결정립 성장을 억제하여 입자를 미세화하는 효과를 제공하므로 0.02%이상 함유되는 것이 바람직하지만, 그 함량이 0.08%를 초과하면 재질이 경화되고, 연속소둔 처리시 조업성이 저하되며, 강판의 표면 특성을 열화시키므로, Nb의 함량은 0.02~0.08%로 한정한다.Niobium (Nb) is an effective element for increasing the strength of steel sheet and refining grains. In the present invention, niobium (Nb) is combined with C in solid solution in steel to form Nb-based carbonized precipitates to improve aging and formability and increase strength. It is preferable to contain 0.02% or more because it suppresses grain growth and provides finer particles. However, when the content exceeds 0.08%, the material hardens, and the operability decreases during continuous annealing, and the surface characteristics of the steel sheet are reduced. Since it deteriorates, the content of Nb is limited to 0.02 to 0.08%.

텅스텐(W)은 강내 석출조장 및 고온강도 향상에 효과적인 원소로서, 이와 같은 효과를 얻기 위해서는 최소 0.05% 이상의 첨가가 필요하나, W의 함량이 0.30%를 초과하면 석출 촉진에 대한 기여 효과 보다는 고가의 합금원소 첨가에 따른 제조원가의 상승요인이 되므로, W의 함량은 0.05~0.30%로 한정한다.Tungsten (W) is an effective element to enhance the precipitation precipitation and high temperature strength in steel. To achieve this effect, tungsten (W) needs to be added at least 0.05%. However, when the content of W exceeds 0.30%, it is more expensive than the contribution to the promotion of precipitation. Since it becomes a rising factor of the manufacturing cost according to the addition of alloying elements, the content of W is limited to 0.05 ~ 0.30%.

Nb와 B의 경우 단독으로 관리하는 것도 중요하지만, 본 발명에서 목표로 하는 고온 및 상온 특성을 확보하기 위해서는 석출물 형성 및 강중 고용원소의 효과를 고려해야 한다. 이를 위해서는 Nb와 C의 원자비 Nb/C와, B와 N의 원자비 B/N을 일정 범위로 유지하여 상온 내시효성과 가공성 및 고온 강도를 동시에 확보하는 것이 중요하다.In the case of Nb and B, it is also important to manage alone, but in order to secure the high temperature and room temperature characteristics targeted by the present invention, the effects of precipitate formation and solid solution elements in the steel should be considered. To this end, it is important to maintain room temperature aging resistance, processability and high temperature strength simultaneously by maintaining the atomic ratio Nb / C of Nb and C and the atomic ratio B / N of B and N in a certain range.

Nb와 C의 원자비 Nb/C의 값이 0.8~2.0인 경우에는 Nb계 탄화 석출물의 형성으로 강중 고용원소 C가 고착되어 상온 내시효성과 가공성을 확보할 수 있고, 소둔 및 냉각 조건을 적절히 제어함에 의해 미세한 Nb계 탄화 석출물 형성을 통해 고온에서 결정립 성장을 억제하여 미세조직을 제어함으로써 우수한 고온특성을 확보할 수 있다.When the atomic ratio Nb / C of Nb and C is 0.8 to 2.0, Nb-based carbonized precipitates form solid element solids C in the steel to ensure room temperature aging resistance and processability, and to properly control annealing and cooling conditions. By suppressing grain growth at high temperatures through the formation of fine Nb-based carbide precipitates, it is possible to secure excellent high temperature characteristics by controlling the microstructure.

그러나, Nb/C의 값이 0.8 미만인 경우에는 강중 고용원소 과다로 상온 내시효성 및 가공성이 열화되는 문제가 있고, Nb계 탄화 석출물의 양이 미미하기 때문에 우수한 고온강도를 확보할 수 없다. 또한, 그 값이 2.0을 초과하는 경우에는 재질이 경화되고, 재결정의 온도를 급격히 상승시키며, 표면 특성이 열화되어 후공정 의 작업성을 저하시키는 문제가 있으므로, Nb/C의 값은 0.8~2.0으로 한정한다.However, when the value of Nb / C is less than 0.8, there is a problem of deterioration of room temperature aging resistance and workability due to excessive solid solution elements in the steel, and excellent high temperature strength cannot be secured because the amount of Nb-based carbide precipitates is insignificant. In addition, when the value exceeds 2.0, the material hardens, the temperature of the recrystallization is rapidly increased, the surface properties deteriorate and the workability of the post-process is lowered. Therefore, the value of Nb / C is 0.8 to 2.0. It is limited to.

그리고, 상온에서의 내시효성과 가공성 및 고온에서의 결정립 성장의 억제 효과를 최적화 하기 위해서는 B와 N의 원자비 B/N의 값을 0.5~1.5로 유지할 필요가 있다. 상기 B/N 값이 0.5 미만에서는 강중 고용원소 과다로 상온 내시효성이 열화되고, 고온에서 결정립 억제 효과가 미흡하며, B/N 값이 1.5를 초과하면 연성이 저하되고 가공성이 감소하는 문제가 있으므로, B/N의 값은 0.5~1.5로 한정한다.In order to optimize the aging resistance at room temperature, the workability, and the effect of inhibiting grain growth at high temperature, it is necessary to keep the values of the atomic ratio B / N of B and N at 0.5 to 1.5. When the B / N value is less than 0.5, there is a problem that the room temperature resistance is degraded due to excessive solid solution in steel, the grain suppression effect is insufficient at high temperature, and when the B / N value exceeds 1.5, the ductility is lowered and the workability is decreased. , The value of B / N is limited to 0.5 to 1.5.

본 발명의 냉연강판은 상기 성분을 포함하면서 잔부Fe와 기타 불가피한 불순물로 이루어진다. 그리고 필요에 따라 본 냉연강판의 특성 향상을 위해 합금원소가 더 첨가될 수 있으며, 본 발명의 실시예에서 밝히지 않은 합금원소가 첨가되었다 하여 본 발명의 범위에서 제외되는 것으로 해석되지는 않는다.The cold rolled steel sheet of the present invention comprises the above components and consists of the remainder Fe and other unavoidable impurities. And alloy elements may be further added to improve the properties of the present cold-rolled steel, if necessary, it is not interpreted to be excluded from the scope of the present invention because the alloy element is not added in the embodiment of the present invention.

한편, 본 발명의 냉연강판은 등축상 페라이트(polygonal ferrite)와 침상 베이나이트(acicular bainite) 조직으로 이루어진 것을 특징으로 하는데, 상기 침상 베이나이트는 내부에 탄화물을 가진 판상의 페라이트 조직으로 전위밀도가 높으며, 인성이 우수하다.On the other hand, the cold-rolled steel sheet of the present invention is characterized by consisting of an equiaxed ferrite (polygonal ferrite) and acicular bainite structure, the acicular bainite is a plate-like ferrite structure having a carbide therein and has a high dislocation density. , Toughness is excellent.

본 발명은 소둔 및 냉각 공정의 조건을 적절히 제어함에 의해 이러한 침상 베이나이트 조직의 체적 분율을 10~25% 확보하여 고전위밀도형 미세조직을 형성함으로써 고온에서 결정립의 이상 성장을 억제하여 상온 및 고온 강도를 향상시킬 수 있다. 그러나, 상기 침상 베이나이트 조직의 체적 분율이 10% 미만인 경우에는 상온 및 고온 강도의 확보가 곤란하여 우수한 내열성을 얻기 어렵고, 침상 베이나이트 조직의 체적 분율이 25%를 초과하는 경우에는 재질 경화에 의해 가공성이 열화 되는 문제가 있어, 침상 베이나이트의 체적 분율을 10~25%로 한정한다.The present invention, by appropriately controlling the conditions of the annealing and cooling process to secure a volume fraction of the needle-like bainite tissue 10 to 25% to form a high-potential-density type microstructure to suppress abnormal growth of crystal grains at high temperature to room temperature and high temperature Strength can be improved. However, when the volume fraction of the acicular bainite structure is less than 10%, it is difficult to secure room temperature and high temperature strength, so that it is difficult to obtain excellent heat resistance. When the volume fraction of the acicular bainite structure is more than 25%, it is hardened by material hardening. There is a problem that workability deteriorates, and the volume fraction of acicular bainite is limited to 10 to 25%.

이하, 본 발명의 내열성 및 가공성이 우수한 고강도의 가공용 고내열 냉연강판의 제조방법에 대하여 상세히 설명한다.Hereinafter, the manufacturing method of the high-strength high temperature resistant cold rolled steel sheet excellent in heat resistance and workability of this invention is demonstrated in detail.

상기의 조성을 지닌 강슬라브를 재가열한 후 열간압연하고, 권취 후 냉간압연하며, 830℃ 이상의 온도에서 소둔 처리된 강판에 대하여 40℃/sec 이상의 냉각속도로 냉각하여 내열성 및 가공성이 우수한 고강도의 가공용 고내열 냉연강판을 제조할 수 있다.After reheating the steel slab having the above composition, hot rolling, cold rolling after winding, and cooling the steel sheet annealed at a temperature of 830 ° C. or higher at a cooling rate of 40 ° C./sec or higher to achieve high strength and high workability. Heat-resistant cold rolled steel sheet can be produced.

상술한 성분계와 같이 조성되는 강 슬라브를 통상의 온도에서 재가열한 후 열간압연시 마무리 압연 온도는 900~950℃인데, 상기 마무리 압연 온도가 900℃ 미만이면 상대적으로 저온 영역에서 열간압연이 종료됨에 따라 최종 형성된 결정립의 혼립화가 발생되어 가공성 및 압연성이 저하되고, 마무리 압연 온도가 950℃를 초과하면 두께 전반에 걸쳐 균일한 열간압연이 이루어지지 않아 결정립 미세화가 불충분하게 되고 이에따라 결정립 조대화에 기인해 충격인성이 저하되므로, 마무리 압연 온도는 900~950℃로 제한한다.After reheating the steel slab formed as the above-described component system at a normal temperature, the finish rolling temperature during hot rolling is 900 to 950 ° C., and when the finish rolling temperature is less than 900 ° C., the hot rolling is completed in a relatively low temperature region. Due to the occurrence of hybridization of the finally formed crystal grains, the workability and rolling properties are lowered, and if the finish rolling temperature exceeds 950 ° C, uniform hot rolling is not performed throughout the thickness, resulting in insufficient grain refinement, resulting in grain coarsening. Since impact toughness falls, finish rolling temperature is restrict | limited to 900-950 degreeC.

상기 열간 마무리 압연을 한 후에는 런아웃테이블(run-out table)에서 연간압연된 강판을 냉각속도 20~80℃/sec로 냉각하는데, 상기 냉각속도가 20℃/sec 미만이면 결정립 성장의 촉진에 의해 상대적으로 조대 결정립이 형성되어 강도 및 가공성 저하의 요인이 될 수 있고, 냉각속도가 80℃/sec를 초과하면 폭방향 냉각 불균일에 의한 재질의 편차 발생 요인으로 작용하기 때문이다.After the hot finish rolling, the annually rolled steel sheet is cooled at a run-out table at a cooling rate of 20 to 80 ° C./sec. If the cooling rate is less than 20 ° C./sec, the grain growth is promoted. This is because coarse grains are formed, which may be a cause of deterioration in strength and workability, and when the cooling rate exceeds 80 ° C / sec, it acts as a cause of variation in materials due to widthwise cooling unevenness.

상기 런아웃테이블에서 냉각후, 상기 열연강판은 560~680℃의 온도에서 권취 가 이루어진다. 상기 권취온도가 560℃ 미만이면 열간압연재의 재질이 다소 경화되어 차공정인 냉간압연 공정에서의 부하가 커져 압연성 확보가 어렵고, 폭방향 온도의 불균일 정도가 증가하여 저온 석출물의 생성 거동 차이로 인해 재질 편차가 유발됨으로써 가공성이 저하되며, 고온 특성이 악화되는 문제가 있다. 또한 권취온도가 680℃를 초과하면 최종 제품의 조직이 조대하게 생성되어 가공성 및 내식성이 저하되는 문제가 있기 때문에, 권취온도는 560~680℃로 제한한다.After cooling in the runout table, the hot rolled steel sheet is wound at a temperature of 560 ~ 680 ℃. If the coiling temperature is less than 560 ℃, the material of the hot rolled material is somewhat hardened to increase the load in the cold rolling process, which is the next process, and thus it is difficult to secure rolling property, and the nonuniformity of the widthwise temperature increases, resulting in a difference in the production behavior of low temperature precipitates. Due to this material variation is caused workability is lowered, there is a problem that the high temperature characteristics are deteriorated. In addition, when the coiling temperature exceeds 680 ℃, there is a problem that the structure of the final product is produced coarse, deterioration of workability and corrosion resistance, the coiling temperature is limited to 560 ~ 680 ℃.

상기 권취가 끝난 강판은 산세 처리 및 목표 두께로 냉간압연하는 단계를 거친 후에 재결정 및 미세 조직 제어를 위해 고온으로 연속소둔 공정을 거치게 된다. 이때 침상 베이나이트 조직의 변태 구동력을 충분히 확보하기 위해서는 소둔 온도가 830℃ 이상인 것이 바람직한데, 소둔 온도가 830℃ 미만인 경우에는 목표로 하는 강판의 미세조직에 존재하는 침상 베이나이트의 체적 분율을 얻을 수 없어 우수한 고온특성의 확보가 곤란하기 때문이다. 다만, 너무 고온에서 소둔시 강판의 표면 결함이 증가할 수 있으므로 소둔온도는 900℃이하로 관리하는 것이 바람직하다.After the wound steel sheet is subjected to pickling treatment and cold rolling to a target thickness, the steel sheet is subjected to continuous annealing at high temperature for recrystallization and microstructure control. At this time, in order to sufficiently secure the transformation driving force of the needle-shaped bainite structure, the annealing temperature is preferably 830 ° C or higher. If the annealing temperature is lower than 830 ° C, the volume fraction of the needle-shaped bainite present in the microstructure of the target steel sheet can be obtained. This is because it is difficult to secure excellent high temperature characteristics. However, since annealing at too high temperature may increase the surface defects of the steel sheet, the annealing temperature is preferably managed at 900 ° C. or lower.

상기 소둔 처리된 강판은 냉각 공정을 통해 목표로 하는 침상 베이나이트 조직의 체적 분율을 확보할 수 있는데, 이를 위해서는 냉각속도를 40℃/sec 이상으로 유지한다. 상기 냉각속도가 40℃/sec 미만인 경우에는 서냉으로 인해 목표로 하는 침상 베이나이트 조직의 체적 분율을 얻기 곤란하기 때문이다.The annealed steel sheet can secure a volume fraction of the target acicular bainite structure through a cooling process, for which the cooling rate is maintained at 40 ° C / sec or more. This is because when the cooling rate is less than 40 ° C / sec, it is difficult to obtain the volume fraction of the target acicular bainite structure due to slow cooling.

이하에서는 실시예를 통하여 본 발명에 대하여 보다 구체적으로 설명한다.Hereinafter, the present invention will be described in more detail with reference to Examples.

[실시예][Example]

아래의 표 1과 같은 조성으로 용해하여 제조한 발명강1,2와 비교강1 내지 5 를 아래의 표 2와 같은 공정 조건하에서 작업하여 냉연강판 발명재1 내지5와 비교재1 내지 10을 제조한 후, 상기 제조된 각 냉연강판 소재에 대하여 침상 베이나이트 조직의 체적 분율 및 상온과 고온에서의 특성을 평가하여 표 3에 나타내었다.Invented steels 1 and 2 and Comparative steels 1 to 5 prepared by melting the composition shown in Table 1 below under the process conditions as shown in Table 2 to produce cold rolled steel invention materials 1 to 5 and Comparative materials 1 to 10 After that, the volume fraction of the acicular bainite structure and the characteristics at room temperature and high temperature were evaluated for each of the prepared cold rolled steel sheets.

표 3에 기재된 특성중 항복점 연신(yield elongation) 현상은 항복점 연신율을 측정하여 연신이 발생된 경우에는 발생으로, 연신이 발생되지 않은 경우에는 미발생으로 표시하였고, 내꺾임성 시험은 강판 가공후 표면 꺾임이 발생하는 정도에 따라 구분하였으며, 이를 표현하는 꺾임성 지수를 5단계로 나누어 비교적 꺾임 현상이 미미한 1~2 단계를 양호로, 육안관찰이 가능한 정도로 꺾임 현상이 발생한 3~5단계를 불량으로 판정하였다. Yield elongation phenomenon of the characteristics described in Table 3 is expressed as occurrence when the elongation is generated by measuring the yield point elongation, and not occurred when the elongation is not generated, and the bending resistance test is performed after the steel sheet processing. The degree of bending was divided according to the degree of occurrence, and the bending index representing this was divided into five stages, and 1 to 2 stages with relatively small bending were good, and 3 to 5 stages where the bending occurred as bad as possible for visual observation. Determined.

또한, 상온 인장강도 시험은 상온에서 인장강도 350MPa 이상이면 양호, 그 미만이면 불량으로 판정하였고, 내새그성 시험은 전장 250mm, 폭 30mm의 소재를 열처리 설비를 이용하여 700℃에서 100시간 동안 가열한 후 강판의 처짐(sagging)을 측정하여 그 처짐 정도가 5mm 이상인 경우에 불량으로, 5mm 미만이면 양호로 판정하였으며, 고온 항복강도 시험은 700℃에서 항복강도가 55MPa 이상이면 양호, 그 미만이면 불량으로 판정하였다. 그리고, 가공성 시험은 상온 가공시 가공 균열(crack)이 발생하는 경우에 불량으로 판정하였다.In addition, the room temperature tensile strength test was determined to be good if the tensile strength of 350MPa or more at room temperature, less than that, the sag resistance test after heating the material of 250mm in length, 30mm in width using a heat treatment equipment for 100 hours at 700 ℃ Sagging of the steel plate was measured and it was judged to be bad when the deflection degree was 5 mm or more and less than 5 mm. The high temperature yield strength test was good when the yield strength was 55 MPa or more at 700 ° C., and less than that. It was. In addition, the workability test was judged to be defective when a work crack occurred during normal temperature processing.

이때, 표 1에서 Nb와 C의 원자비 Nb/C의 값 및 B와 N의 원자비 B/N의 값은 각 원소 성분의 중량%를 각각 그 원자량으로 나눈 값의 비를 말한다.At this time, in Table 1, the value of the atomic ratio Nb / C of Nb and C and the value of the atomic ratio B / N of B and N refer to the ratio of the value obtained by dividing the weight percentage of each element by its atomic weight.

[표1] 발명강과 비교강의 성분Table 1 Components of Inventive and Comparative Steels

Figure 112009075179440-pat00001
Figure 112009075179440-pat00001

[표2] 강판별 제조공정의 조건[Table 2] Condition of Manufacturing Process by Steel Plate

Figure 112009075179440-pat00002
Figure 112009075179440-pat00002

[표3] 강판별 특성 평가[Table 3] Evaluation of properties by steel plate

Figure 112009075179440-pat00003
Figure 112009075179440-pat00003

상기 표 3에 나타난 바와 같이, 강 성분 및 공정 조건이 본 발명의 범위를 만족하는 발명재1 내지 5는 항복점 연신 현상이 발생하지 않았고 내꺾임성이 양호하여 내시효성이 우수하였고, 인장강도 또한 상온에서 350MPa 이상으로 양호하였으며, Nb계 탄화 석출물 및 B계 질화 석출물의 생성 및 침상 베이나이트 조직의 체적 분율의 최적화에 의해 고온에서의 항복강도 및 열처리후 처짐정도(내새그성)도 양호하였고, 상온 가공시 가공 균열 등이 발생하지 않아 상온 가공성도 우수하였다.As shown in Table 3, Inventive Materials 1 to 5 in which the steel component and the process conditions satisfy the scope of the present invention did not occur in the yield point stretching phenomenon, good bending resistance and excellent aging resistance, tensile strength is also room temperature The yield strength was satisfactory at 350 MPa or more at, and the yield strength at high temperature and the sag resistance after heat treatment (sag resistance) were also good due to the formation of Nb-based carbide and B-nitride precipitates and optimization of the volume fraction of acicular bainite structure. There was no work cracking at the time, so the workability at room temperature was also excellent.

반면에, 표 1의 강 성분 등이 본 발명의 범위를 만족하는 발명강이지만 표 2 의 공정 조건중 일부가 본 발명의 범위를 벗어나는 비교재1 내지 5는 대부분 침상 베이나이트 조직의 체적 분율이 낮아 우수한 고온강도을 갖기 못하였고, 상온 인장강도 뿐만 아니라 가공성 및 내시효성도 불량한 경우가 많았다. On the other hand, although the steel components of Table 1 and the like are invention steels satisfying the scope of the present invention, Comparative Materials 1 to 5 in which some of the process conditions of Table 2 are out of the scope of the present invention are mostly low in volume fraction of acicular bainite structure. It did not have excellent high temperature strength, and it was often poor workability and aging resistance as well as room temperature tensile strength.

또한, 표 2의 공정 조건은 본 발명의 범위를 만족하나, 표 1의 강 성분 등이 본 발명의 범위를 벗어나는 비교재6 내지 10은 가공성 및 내시효성이 불량한 경우가 많았고, 침상 베이나이트 조직의 체적 분율이 낮아 고온특성이 대부분 불량하였으며, W가 미첨가되고 Mn과 P의 함량이 낮아 상온 인장강도가 저하되는 경우가 많아 상온 특성과 고온특성을 동시에 만족하는 것이 곤란하였다.In addition, although the process conditions of Table 2 satisfy the scope of the present invention, Comparative Materials 6 to 10 in which the steel components of Table 1 and the like are outside the scope of the present invention were often poor in workability and aging resistance, Due to the low volume fraction, most of the high temperature properties were poor, and because W was not added and the contents of Mn and P were low, the tensile strength of the room temperature was often lowered.

그 중 비교재7은 항복점 연신 현상이 미발생하고, 내꺾임성이 양호하여 내시효성 및 가공성이 우수하고, 상온 인장강도가 350MPa 이상으로 양호하였으나, 내새그성 및 고온 항복강도는 불량하였는데, 이는 Nb의 다첨가와 W의 미첨가로 소둔시 조업성이 나빠지고, 강판 표면의 특성이 열화되어 목표로 하는 고온 특성을 확보할 수 없었기 때문이다. 그리고, 비교재8 내지 10은 강중 고용 탄소량이 많아 가공성 및 내시효성이 불량하였을 뿐만 아니라, Nb/C의 값이 낮아 Nb계 탄화 석출물의 양이 미미하고 침상 페라이트 조직의 체적 분율도 낮아 고온 특성이 불량하였다. Among them, Comparative Material 7 had no yield point stretching phenomenon, good bending resistance, excellent aging resistance and workability, and good tensile strength of 350 MPa or more, but poor sag resistance and high temperature yield strength. This is because when the annealing is performed due to the polyaddition and no addition of W, the operability deteriorates and the surface properties of the steel sheet are deteriorated, so that the target high temperature characteristics cannot be obtained. In addition, Comparative Materials 8 to 10 had a high amount of solid solution carbon in steel, which was poor in workability and aging resistance, and had a low Nb / C value, which resulted in insignificant amounts of Nb-based carbide precipitates and low volume fraction of acicular ferrite structure. It was poor.

결국, 강의 성분 조건과 제조공정의 조건(특히, 소둔 및 냉각 조건)을 최적화하여 미세한 Nb계 탄화 석출물 및 B계 질화 석출물을 형성하고, 침상 베이나이트 조직의 체적 분율을 제어할 수 있으며, W을 일정량 강내 고용시키고, Mn과 P의 함량을 높여 저비용으로 가공성, 내열성 및 고강도를 동시에 만족시키는 가공용 고내열 냉연강판을 제조할 수 있었다.Eventually, the compositional conditions of the steel and the conditions of the manufacturing process (especially annealing and cooling conditions) can be optimized to form fine Nb-based carbide and B-nitride precipitates, and the volume fraction of the needle-shaped bainite structure can be controlled. By employing a certain amount of steel and increasing the content of Mn and P, it was possible to manufacture a high-temperature cold-rolled steel sheet for processing that satisfies workability, heat resistance and high strength at low cost.

본 발명에서 상기 실시 형태는 하나의 예시로서 본 발명이 여기에 한정되는 것은 아니다. 본 발명의 특허청구범위에 기재된 기술적 사상과 실질적으로 동일한 구성을 갖고 동일한 작용효과를 이루는 것은 어떠한 것이라도 본 발명의 기술적 범위에 포함된다.The present invention is not limited to the above-described embodiments. Anything having substantially the same constitution as the technical idea described in the claims of the present invention and achieving the same operational effect is included in the technical scope of the present invention.

Claims (14)

중량%로 C:0.002~0.010%, Mn:0.3~0.6%, P:0.03~0.08%, Al:0.02~0.08%, B:0.001~0.003%, W:0.05~0.30%, N:0.002~0.010%, Nb:0.02~0.08%, S:0.015%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하며,By weight% C: 0.002 ~ 0.010%, Mn: 0.3 ~ 0.6%, P: 0.03 ~ 0.08%, Al: 0.02 ~ 0.08%, B: 0.001 ~ 0.003%, W: 0.05 ~ 0.30%, N: 0.002 ~ 0.010 %, Nb: 0.02 ~ 0.08%, S: 0.015% or less, balance Fe and other unavoidable impurities, 등축상 페라이트와 침상 베이나이트 조직으로 이루어지고, 침상 베이나이트 조직의 체적 분율은 10~25%인, 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판.A high strength cold-rolled steel sheet for processing of high strength, excellent in workability and heat resistance, consisting of an equiaxed ferrite and acicular bainite structure, and having a volume fraction of acicular bainite structure of 10 to 25%. 제1항에 있어서,The method of claim 1, 상기 Nb와 C의 원자비 Nb/C의 값이 0.8~2.0인 것을 특징으로 하는 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판.The high heat resistance cold rolled steel sheet for processing having high workability and heat resistance, wherein the atomic ratio Nb / C of Nb and C is 0.8 to 2.0. 제1항에 있어서,The method of claim 1, 상기 냉연강판은 Nb계 탄화 석출물이 형성된 것을 특징으로 하는 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판.The cold rolled steel sheet is a high heat resistant cold rolled steel sheet for processing of high strength and excellent heat resistance, characterized in that the Nb-based carbide precipitates are formed. 제1항에 있어서,The method of claim 1, 상기 B와 N의 원자비 B/N의 값이 0.5~1.5인 것을 특징으로 하는 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판.The high-temperature cold-rolled steel sheet for processing of high strength and excellent heat resistance, characterized in that the value of the atomic ratio B / N of the B and N is 0.5 ~ 1.5. 제1항에 있어서,The method of claim 1, 상기 냉연강판은 B계 질화 석출물이 형성된 것을 특징으로 하는 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판.The cold rolled steel sheet is a high heat resistant cold rolled steel sheet for processing of high strength and excellent heat resistance, characterized in that the B-based nitride precipitates are formed. 삭제delete 삭제delete 중량%로 C:0.002~0.010%, Mn:0.3~0.6%, P:0.03~0.08%, Al:0.02~0.08%, B:0.001~0.003%, W:0.05~0.30%, N:0.002~0.010%, Nb:0.02~0.08%, S:0.015%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하며 상기 Nb와 C의 원자비 Nb/C의 값이 0.8~2.0이고 상기 B와 N의 원자비 B/N의 값이 0.5~1.5인 강슬라브를, 가열한 후 900~950℃에서 마무리 압연하고 압연된 열연판을 20~80℃/sec의 냉각속도로 냉각하며, 560~680℃에서 권취 후 냉간압연한 다음, 냉간압연된 강판을 830~900℃의 온도에서 소둔 처리하고, 소둔 처리된 강판에 대하여 40℃/sec이상의 냉각속도로 냉각하여, 등축상 페라이트와 침상 베이나이트 조직을 형성하고 침상 베이나이트 조직의 체적 분율을 10~25%로 조절하는, 가공성 및 내열성이 우수한 고강도의 가공용 고내열 냉연강판의 제조방법.By weight% C: 0.002 ~ 0.010%, Mn: 0.3 ~ 0.6%, P: 0.03 ~ 0.08%, Al: 0.02 ~ 0.08%, B: 0.001 ~ 0.003%, W: 0.05 ~ 0.30%, N: 0.002 ~ 0.010 %, Nb: 0.02 to 0.08%, S: 0.015% or less, balance Fe and other unavoidable impurities, and the atomic ratio Nb / C of Nb and C is 0.8-2.0 and the atomic ratio B / N of B and N After heating the steel slab with N value of 0.5 ~ 1.5, finish rolling at 900 ~ 950 ℃ and cooling the rolled hot rolled sheet at a cooling rate of 20 ~ 80 ℃ / sec, and cold rolling after winding at 560 ~ 680 ℃ The cold rolled steel sheet was then annealed at a temperature of 830 to 900 ° C., and cooled to a cooling rate of 40 ° C./sec or more for the annealed steel sheet to form an equiaxed ferrite and acicular bainite structure and to form acicular bainite. A method for producing a high strength, high temperature cold rolled steel sheet for processing having high workability and heat resistance, which adjusts the volume fraction of the tissue to 10-25%. 삭제delete 삭제delete 삭제delete 삭제delete 삭제delete 삭제delete
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