KR101253323B1 - Manufacturing method of sun-dried salt enhanced mineral and sun-dried salt using the same - Google Patents

Abstract

The present invention relates to a method for producing a mineral salt-enriched natural salt, and to a natural salt using the same, and more specifically, it is possible to enhance minerals while purifying and detoxifying harmful substances in seawater using germanium and suppressing the habitat of harmful bacteria in seawater. It relates to a method for producing a natural salt and a natural salt using the same.
The method for producing the natural salt of the present invention is a spraying step of spraying germanium powder on the salt floor, a plowing step of forming a top plate by mixing the germanium powder and gaepal after grinding the salt bed, and evaporating seawater from salt And a crystallization step of collecting crystals.

Description

Manufacturing method of sun-dried salt enhanced mineral and sun-dried salt using the same}

The present invention relates to a method for producing a mineral salt-enriched natural salt, and to a natural salt using the same, and more specifically, it is possible to enhance minerals while purifying and detoxifying harmful substances in seawater using germanium and suppressing the habitat of harmful bacteria in seawater. It relates to a method for producing a natural salt and a natural salt using the same.

In general, salt is also commonly referred to as salt, and the chemical name is sodium chloride (NaCl), which is widely used in daily life such as coarse salt and salt salt, and is also used in a large amount in industrial fields such as the production of soda (sodium carbonate). .

Salt is a cube with a specific gravity of 2.16. 35.7g at 0 ° C, 35.8g at 20 ° C, and 39.8g at 100 ° C are dissolved in 100g of water.Saturated salt solution does not freeze to -21.2 ° C due to the freezing point drop. For most microorganisms except basophils, they show antiseptic and sterilization at high concentrations, osmotic and dehydrating, determine the osmotic pressure of various somatic cells, enable the movement of body fluids, and dissolve body proteins. In addition to determining its three-dimensional structure, it is an essential body composition essential for the maintenance of life, such as generating a potential difference for signal transmission in nerve cells.

Sources of salts include seawater, rock salt, salt lakes, underground functions, and the like, and may be classified into sun salt, rock salt, mechanical salt, recontaminated salt, and processed salt. About two-thirds of the world's salt production comes from rock salt, but the traditional preference is sun salt, which suits our tastes.

Solar salt is made by confining sea water in salt and drying it with sunlight and wind. When saltwater is confined in salt water, a thin salt film is first formed on the surface of the water, and then the salt crystals grow in size. This is called the flower of salt. As this crystal becomes heavier, it sinks down and the salt crystals stick to it, creating salt. These salts are coarse salts, and before they sink under water, the thin salt film is rolled off and dried separately. Is made.

Sun salt is divided into toppan salt (장 版 鹽) and jangpan salt (壯 版 鹽) according to the type of salt bottom when salt is made in salt. Production salt salt of toppan salt is soil bottom, and production salt salt of entero salt is vinyl sheet.

Jangpan salt is easy to work on because the floor is laid with a floorboard or tile, but the nutritional content is relatively low because various ingredients in the dog pearl are difficult to penetrate into the salt. On the other hand, minerals, amino acids, organic compounds, etc. are much more contained in the salt produced from the topspan, the salt has the advantage of having a unique flavor or soft and sweet.

However, due to the development of the industry, environmental pollution is getting serious and the seawater is gradually being polluted by flowing into the sea, which is the final destination of various wastewater and domestic sewage. Therefore, the natural salt produced in the tidal flat has a problem that pollutants can be introduced from the tidal flat of the coast and the tidal flat of the reservoir.

The present invention is to achieve the above object, by using germanium to purify and detoxify harmful substances in seawater and inhibit the habitat of harmful bacteria in seawater while the method of producing a natural salt that can enhance the minerals contained in the natural salt It relates to the used sun salt.

Method of producing a natural salt of the present invention for achieving the above object is the spraying step of spraying germanium powder on the salt floor; Plowing the ground of salt to form a top plate by mixing the germanium powder and gaepul and arranging them; And a crystallization step of collecting salt crystals by evaporating the seawater in the salt field.

The determining step is characterized in that carried out by the addition of organic germanium to the sea water.

The determining step is characterized in that it is carried out by the addition of organic sulfur.

The natural salt of the present invention for achieving the above object is characterized in that it is produced by any one of the above-described method.

As described above, according to the present invention, germanium is added to the salt floor to purify and detoxify the seawater, thereby suppressing the growth of harmful bacteria in the seawater and providing a safe natural salt. In addition, it is possible to greatly increase the population of microorganisms by improving the habitat conditions.

In addition, the present invention can produce a high quality natural salt rich in minerals.

1 and 2 are photographs each measured the total number of bacteria of seawater collected from the crystallized land of Example 1 and Comparative Example,
3 and 4 are test reports showing the salt components of Example 2 and the comparison, respectively,
5 is a test report showing the content of germanium contained in the salt of Example 2.

Hereinafter, a method for preparing a mineral-enriched natural salt according to a preferred embodiment of the present invention will be described in detail.

First, seawater is introduced into the reservoir and stored in the reservoir for a period of time. Examples of seawater introduced into the reservoir are NaCl 27.21g / kg, MgCl₂3.81g / kg, MgSO₂1.66g / kg, CaSO₄1.26g / kg, calcium carbonate CaCO₃0.12g / kg, K ₂ SO₄0.86g / kg, MgBr₂0. It is formulated at 08 g / kg and has an average salinity of about 3 to 5%.

Next, the seawater of the reservoir is transferred to the evaporation zone and the seawater is evaporated until it is concentrated to a constant salinity.

The evaporation process in the evaporation can be divided into primary, secondary, and tertiary. For example, a) evaporating seawater from a reservoir to a salinity of 5 to 10% by evaporating it in a primary evaporator, b) evaporating seawater to a salinity of 10 to 20% by evaporating it in a secondary evaporation pond, c The water may be evaporated in a tertiary evaporator to evaporate the salt to 23 to 25%.

When the work is completed in the evaporator, the concentrated seawater from the evaporator is introduced into the crystal field, and the salt water is evaporated by the wind and sunlight to collect salt crystals. After dyeing, the process of removing and packaging the brine and water may be further performed.

Preferably, a bottom plate is formed at the bottom of the crystallization paper after the completion of the work in the evaporation pond and before the seawater is introduced into the crystallization paper. When making the sun salt, it is divided into top plate (土 版) made of soil floor and floor plate (壯 版) made of vinyl or tile according to the type of bottom of crystal paper. Although it is easy to dye in jangpan, the various ingredients in sea flakes are difficult to penetrate into salt.

The formation of the top plate preferably comprises a) spraying germanium powder on the bottom of the crystallized paper, and b) grinding the bottom of the crystallized paper to a depth of 10 to 20 cm, mixing the germanium powder with sapphire and then arranging it. Germanium powder is sprinkled evenly with about 0.2 kg per 3.3 m ² of the crystallized floor area. Here, germanium uses a natural germanium mineral. Natural germanium mineral refers to the ore containing inorganic germanium (GeO / GeO ₂ ), which varies depending on the place and time of mineral collection, it consists of about 50 or more components. Besides inorganic germanium, like other minerals, SiO ₂ , Al ₂ O ₃ , Fe ₂ O ₃ , CaO, MgO, K ₂ O, Na ₂ O and the like are contained.

Natural germanium minerals are ground to a particle size of 300 to 350 mesh in order to improve uniform sparging and contact area with seawater. Natural germanium mineral powder added to the bottom of the crystallization cleanses various contaminants in the seawater and seawater that form the bottom of the crystallization and suppresses harmful bacteria.

On the other hand, in addition to the natural germanium mineral, sulfur may be added to the crystallization bottom. Sulfur is preferably added if the evaporation of about 3.3m 0.01kg per ^second relative to the floor area.

Sulfur may use inorganic sulfur obtained from minerals. Sulfur is known to be excellent in detoxification of heavy metals and pesticides. Sulfur is used by grinding to a particle size of 300 to 350 mesh. It is preferable to use sulfur for which sulfur has been removed. Commercially available sulfur can be used.

In another embodiment of the present invention, the process of spraying the natural germanium mineral powder on the bottom of the evaporation paper may be further performed. Natural germanium mineral powder is sprayed at about 0.2 kg per 3.3 m ² based on the bottom area of the evaporation basin. Natural germanium minerals are spread evenly over the bottom of the evaporation area. Then, the bottom of the evaporator is ground to a depth of 10 to 20 cm so that the natural germanium mineral powder is mixed well with gaepal, and the bottom is cleaned. When the bottom is cleared, the seawater of the reservoir is transferred to the evaporation zone, and the seawater is concentrated by evaporating the salinity to 23 to 25% using wind and sunlight.

The natural germanium mineral powder injected into the bottom of the evaporation paper purifies various contaminants in the falcon that forms the bottom of the evaporation paper. In addition, by detoxifying harmful substances concentrated in the evaporator to prevent harmful substances into the sea water.

Sulfur may be further added to the bottom of the evaporator in addition to the above-described natural germanium mineral powder. At this time, sulfur is preferably added to 0.01kg per 3.3m ² based on the bottom area of the evaporator.

As another embodiment of the present invention, after introducing the concentrated seawater from the evaporation paper into the crystallographic paper, the organic salt may be added to the seawater to prepare the sun salt. In this case, the organic germanium is added in an amount of 0.1 to 1 g per tonne of seawater having a salt level of 23 to 25%. Organic germanium added to seawater is incorporated into crystals of salt.

Organic Germanium ((GeCH ₂ CH ₂ COOH) ₂ O ₃ ) Is a form combined with an organic compound to be absorbed by the human body, is known to be very useful to the human body. The efficacy of organic germanium is as follows.

Organic germanium enters the body to produce pure oxygen and provides it to cells, which increases endorphins, activating T-lymphocytes. It also plays a role in cell activation, nutrient binding, and supply promotion.It is completely combined with impurities of inorganic substances or heavy metals in the body within 24 ~ 48 hours to be discharged into the urine and cleans all organs of the human body. . The University of Tokyo's Akiba Pharmacy Professor has an excellent therapeutic effect on early cancer because eating or injecting organic germanium removes cancer cells within 48-72 hours by inducing interferon, which enhances natural healing power and induces interferon that suppresses viruses. It has announced that it decomposes and oxidizes heavy metals, toxic and pollutants by supplying oxygen, and then discharges them with the waste in vitro.

In the present invention, organic germanium obtained by artificially synthesizing with organic germanium or organic germanium obtained from nature can be used. The synthetic organic germanium can use a commercially available thing.

Alternatively, a plant extract obtained by freeze-drying the juice of a plant containing organic germanium under reduced pressure may be used. That is, by introducing inorganic germanium into the soil in which vegetables such as lettuce and Chinese cabbage can be grown, the vegetables are absorbed by inorganic germanium and are converted into organic germanium in the body. Vegetables thus grown are juiced to obtain a juice, and the juice is lyophilized to obtain a plant extract containing organic germanium. As another example, 0.001 to 0.005 parts by weight of inorganic germanium may be mixed with 100 parts by weight of Gaepearl, and the seaweed may be cultivated on the Gaepulle to juice the juice to obtain a juice, and the juice may be concentrated under reduced pressure and lyophilized to obtain a seaweed extract.

In this way, the plant extract containing organic germanium is added to the seawater according to the concentration of the organic germanium. By adding plant extracts to seawater to crystallize seawater, there is an advantage in that salts can be added to organic germanium and other useful components of plants.

In another embodiment of the present invention, after introducing the concentrated seawater from the evaporator into the crystallization, natural dietary sulfur may be further added to the seawater together with the organic germanium. Preferably, sulfur is extracted from pine with natural dietary sulfur and sulfur is used in combination with organic compounds. An example of organosulfur is methylsulfonylmethane ((CH ₃ ) ₂ SO ₂ ). The amount of natural dietary sulfur added may be the same as or less than the amount of organic germanium added. Sulfur is known to be very good for the body when taken in moderation. For your reference, agreeing that sulfur is highly toxic but has a lot of heat to drive cold air in the body to help nourish the lack of energy, to control the capture and fraud of the heart and to release the solitary (丹毒).

In another embodiment of the present invention, a natural salt may be prepared by adding natural germanium mineral powder to seawater stored in a reservoir. The natural germanium mineral powder utilizes a particle size of 300 to 350 mesh in order to be evenly dispersed in seawater and to improve the contact area with seawater. Natural germanium mineral powder is preferably added to 0.05kg to 0.1kg per 1 ton of sea water.

After the natural germanium mineral is added to the reservoir, it is allowed to stand for about 1 to 2 days. Natural germanium minerals injected into seawater purify various pollutants in seawater by the decomposition effect of pollutants, adsorption effect, and anion exchange capacity by porous structure.

Hereinafter, the present invention will be described through examples. However, the following examples are intended to illustrate the present invention in detail, and the scope of the present invention is not limited to the following examples.

(Example 1)

The Jeonnam Shinan sinuimyeon grind "azure salt, salt from 325 mesh particle size of the natural mineral powder germanium crystals floor after the sow if 0.2kg per 3.3m ² evenly relative to the floor area to a depth of 15cm lagoon natural germanium mineral powder After mixing with the bottom was cleaned to form a top plate. In addition, after introducing the seawater concentrated in the evaporation of 24% salinity into the crystallization, salt crystals were collected by evaporating the seawater.

(Example 2)

In the same manner as in Example 1, after forming the top plate on the crystallization, 0.6 g of organic germanium (OXY-Germanium, Germanium Inc, USA) was added per ton of seawater introduced into the crystallization, and salt crystals were collected by evaporating the seawater. .

(Comparative Example)

The saltwater was collected by introducing saltwater with a salt concentration of 24% in the salt sky salt of Sinui-myeon, Sinui-gun, Jeollanam-do, into a crystallization base of a conventional top plate structure.

<Example 1 Experiment: Determination of Total Cell Number>

Seawater immediately before the salt crystals are formed in the crystallization paper of Example 1 and Comparative Example was commissioned by Sunchon National University Food Industry Research Institute to measure the total number of bacteria and the results are shown in Table 1 and FIG. 1 and FIG. 2. In the following Table 1, the treatment zone uses the seawater of Example 1, and the control zone uses seawater of the comparative example.

division Treatment Control Before incubation 2.2 × 10 1.08 × 10 ³ After 7 days incubation 1.4 × 10 3.1 x 10 ³

Referring to Table 1, it was confirmed that the total number of bacteria in the treatment immediately after collection is significantly lower than the total number of bacteria in the control. In addition, after 7 days of incubation, the total number of bacteria was decreased in the control, while the total number of bacteria was increased in the control. This is because the treatment has the effect of suppressing the growth of bacteria. 1 is a photograph of the treatment after 7 days incubation, Figure 2 is a photograph of the control.

<Example 2 Experiment: Component Analysis>

Salt collected from the crystallized paper of Example 2 and Comparative Example was commissioned by Miradenhan Research Co., Ltd. to analyze the general components, and the results are shown in FIGS. 3 and 4, respectively.

3 and 4, the salt of Example 2 was found to be much higher in the anion, cation, trace elements than the salt of the comparative example. In particular, as shown in Figure 5 it was confirmed that the salt of Example 2 contained 32.4ppm germanium.

Therefore, the present invention is expected to be able to produce a high quality natural salt rich in various minerals.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation.

 Therefore, the true scope of protection of the present invention should be defined only by the appended claims.

Claims (4)

delete Concentrating step of evaporating the sea water in the evaporator to a salinity of 23 to 25%;
A spraying step of spraying the natural germanium mineral powder having a particle size of 300 to 350 mesh on the salt floor;
Plowing the ground of the saltwater sprayed with the natural germanium mineral powder to a depth of 10 to 20 cm, mixing the natural germanium mineral powder with gaepal and then arranging to form a top plate;
And a crystal step of collecting salt crystals by introducing the seawater concentrated in the evaporator into the salt field and then evaporating the seawater.
The determination step is a method for producing a mineral-enriched sun salt, characterized in that the addition of 0.1 to 1 g of organic germanium per ton of seawater. The method of claim 2, wherein the determining step is performed by adding organic sulfur. delete

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