KR101247944B1 - Using food waste for charcoal fire brown coal - Google Patents
Using food waste for charcoal fire brown coal Download PDFInfo
- Publication number
- KR101247944B1 KR101247944B1 KR20120154246A KR20120154246A KR101247944B1 KR 101247944 B1 KR101247944 B1 KR 101247944B1 KR 20120154246 A KR20120154246 A KR 20120154246A KR 20120154246 A KR20120154246 A KR 20120154246A KR 101247944 B1 KR101247944 B1 KR 101247944B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- parts
- food waste
- charcoal
- powder
- Prior art date
Links
- 239000010794 food waste Substances 0.000 title claims abstract description 51
- 239000003610 charcoal Substances 0.000 title claims description 32
- 239000003077 lignite Substances 0.000 title abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 239000002023 wood Substances 0.000 claims abstract description 20
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 14
- 241001133760 Acoelorraphe Species 0.000 claims abstract description 10
- 229910052622 kaolinite Inorganic materials 0.000 claims abstract description 8
- 235000013379 molasses Nutrition 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 6
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 5
- 230000001954 sterilising effect Effects 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 239000004575 stone Substances 0.000 claims abstract description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 4
- 238000010000 carbonizing Methods 0.000 claims abstract description 3
- 238000007865 diluting Methods 0.000 claims abstract description 3
- 239000011230 binding agent Substances 0.000 claims description 11
- 241000721662 Juniperus Species 0.000 claims description 8
- 239000008139 complexing agent Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 239000008188 pellet Substances 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 235000021055 solid food Nutrition 0.000 claims description 2
- 235000021067 refined food Nutrition 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 14
- 150000001450 anions Chemical class 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 239000003205 fragrance Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 230000001877 deodorizing effect Effects 0.000 abstract description 2
- 235000013372 meat Nutrition 0.000 abstract description 2
- 241000209219 Hordeum Species 0.000 abstract 2
- 235000007340 Hordeum vulgare Nutrition 0.000 abstract 2
- 240000005308 Juniperus chinensis Species 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 238000010298 pulverizing process Methods 0.000 abstract 1
- 239000004449 solid propellant Substances 0.000 description 6
- 235000013305 food Nutrition 0.000 description 5
- 235000019645 odor Nutrition 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000003763 carbonization Methods 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 235000013312 flour Nutrition 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- 235000005135 Micromeria juliana Nutrition 0.000 description 2
- 241000246354 Satureja Species 0.000 description 2
- 235000007315 Satureja hortensis Nutrition 0.000 description 2
- 239000000227 bioadhesive Substances 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000010169 landfilling Methods 0.000 description 1
- 235000021190 leftovers Nutrition 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/46—Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/34—Other details of the shaped fuels, e.g. briquettes
- C10L5/36—Shape
- C10L5/363—Pellets or granulates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/06—Firelighters or wicks, as additive to a solid fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/02—Combustion or pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/545—Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/78—Recycling of wood or furniture waste
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
본 발명은 가정·아파트·음식점·호텔 등에서 배출된 음식물 쓰레기를 효율적으로 재활용하는 방안의 하나로 이들을 수거하여 선별, 건조 및 파쇄한 후 목분, 깻묵 등을 혼합하여 제조된 친환경의 고열량의 숯불구이용 갈탄에 관한 것이다. The present invention is one of the ways to efficiently recycle food waste discharged from homes, apartments, restaurants, hotels, etc., and then collected, sorted, dried and shredded, and then mixed with wood powder, ink, etc. It is about.
음식물쓰레기는 가정이나 식당 등에서 조리 전에 식품재료를 다듬을 때 버리게 되는 생선내장이나 머리, 식품 불량품 등과 식품을 조리하여 먹고 남은 잔반 및 식품의 판매나 유통과정에서 버려지는 음식물 등을 말한다. Food waste refers to fish guts, heads, food defects, etc. that are discarded when the food ingredients are trimmed before cooking at home or in a restaurant, and leftovers that have been left by eating food and discarded during the sale or distribution of food.
이들 음식물 쓰레기는 수분을 80∼90% 함유하고 있어 다른 쓰레기와 섞이면, 수분이 다른 쓰레기로 스며들어 전체 쓰레기의 적절한 처리를 방해할 뿐 아니라 부패 등으로 악취를 유발하고, 이들을 소각할 경우, 음식쓰레기에 함유된 소금성분 등으로 인해 다이옥신 등 환경호로몬을 발생하는 문제점이 있어 사회적 문제로 대두되고 있다.Since these food wastes contain 80 to 90% of moisture, when mixed with other wastes, the moisture permeates into other wastes and prevents the proper disposal of the whole wastes, and causes odors due to decay, etc. Due to the salt component contained in it, there is a problem of generating environmental hormones, such as dioxin, has emerged as a social problem.
특히, 런던협약에 따라 정부는 2006년 "육상폐기물 해양투기관리 종합대책"을 수립하여 해양배출 허용물질에 대하여 단계적 감축을 시행해 오고 있다. 즉, 2006년 건설오니, 정수오니에 대해 해양투기 금지화를 시작으로, 올해는 가축분뇨와 하수오니가 해양투기 금지되며, 2013년 1월부터는 음식물 쓰레기의 해양투기를 금지하고 있다. In particular, in accordance with the London Convention, the government has established a 2006 comprehensive measure of land waste disposal at sea, and has phased out the allowable emissions of oceans. In other words, the construction of bans on dumping of marine sludges and sewage sludges in 2006 is prohibited, and manure and sewage sludges are banned from dumping at sea this year.
이에 따라 본 발명은 음식물 쓰레기의 자원화를 위하여 친환경 시스템에서의 가공 과정을 거쳐 30분 이내에 함수율을 90 내지 93% 이상 감소시켜 분쇄한 음식물 쓰레기 고형 분쇄물에 일반 목분, 향나무 목분, 야자나무 목분 및 깻묵을 혼합하여 탄화시켜 음식점 등에서 사용하는 숯탄의 대체연료인 숯불구이용 갈탄을 개발하였다.Accordingly, the present invention is to reduce the water content by 90 to 93% or more within 30 minutes through the process of processing in an environmentally friendly system for the recycling of food waste, general wood powder, juniper wood powder, palm wood powder and ink powder The mixture was carbonized to develop charcoal roasting charcoal, which is an alternative fuel of charcoal used in restaurants.
국내에서 발생하는 음식물쓰레기는 하루 1만5천여톤 정도이며, 국민 1인당 음식물 쓰레기 발생량은 0.35Kg으로 독일 (0.27Kg), 영국(0.26Kg) 등 선진국에 비해 많은 량이 발생하고 있으나, 종래에는 이들 음식물쓰레기의 대부분을 소각이나 매립 또는 해양에 투기하였다. 그러나 2005년부터 직매립을 금지하고 있으며, 2013년부터는 음폐수의 해양 투기도 금지되는 등, 음식물 쓰레기의 처리와 관련한 규제가 강화됨에 따라 소각하는 방법이 주류를 이루고 있으나, 식물 쓰레기를 소각하는 경우, 소각에 드는 비용문제와 소각시 발생하는 다이옥신 등 환경유해물질 및 악취발생으로 심각한 환경문제와 유용한 폐자원을 재활용하지 못하는 단점이 있었다.The amount of food waste generated in Korea is about 15,000 tons per day, and the amount of food waste generated per person is 0.35Kg, which is much higher than in developed countries such as Germany (0.27Kg) and the UK (0.26Kg). Most of the food waste was incinerated, landfilled or dumped at sea. However, since 2005, direct landfilling has been banned, and since 2013, the ban on marine dumping of effluents has been banned. In addition, the costs of incineration and the generation of environmentally harmful substances and odors such as dioxins generated during incineration have serious environmental problems and disadvantages in recycling useful waste resources.
이에 따라 음식물쓰레기의 재활용 방안의 하나로 퇴비나 동물 사료화에 관한 연구가 활발히 진행되고 있으나, 이 역시 각 동물들의 식성이나 취향에 알맞는 형태로의 가공에 어려움이 있고 또한, 일반수요자가 이를 기피하는 까닭으로 그 수요처가 저조한 실정으로 최근에는 음식물쓰레기를 이용한 연료화에 대한 기술개발이 활발하게 진행되고 있다.Accordingly, research on composting and animal feed has been actively conducted as one of the food waste recycling methods, but it is also difficult to process each animal into a form suitable for the diet and taste of each animal. Due to the low demand of consumers, technology development for fueling food waste has been actively conducted in recent years.
이들 음식물쓰레기의 연료화 기술들의 일례로 국내공개특허 제10-2000-0012514호에 “음식물쓰레기를 이용한 고체연료 제조방법”, 국내공개특허 제10-2005-0032057호에 “음식물 쓰레기를 숯 원료화하는 방법”, 국내공개특허 제10-2008-0042060호에는 “음식물 쓰레기를 이용한 고체연료 제조방법”등이 공개되어 있고, 국내등록특허 제10-0453878호에는 “음식물 쓰레기를 이용한 숯 제작장치 및 방법 및 장치”, 국내등록특허 제10-0532624호에는 “음식물 쓰레기를 이용한 고체연료 제조방법”,국내등록특허 제10-0557471호에는 “음식물 쓰레기를 이용한 숯 제조방법 및 장치”, 국내등록특허 제10-0729816호에는 “음식물 쓰레기를 이용한 고형 대체 연료 및 가탄제의제조방법”, 국내등록특허 제10-0735543호에는 “음식물쓰레기와 폐합성수지를 이용하여 고체연료를 제조하는 방법”, 국내등록특허 제10-0930055호에는“음식물 쓰레기를 이용한 고체연료 제조방법” , 국내등록특허 제10-0974312호에는“음식물 쓰레기를 이용한 활성탄 제조방법”, 국내등록특허 제10-0991719호에는“음식물쓰레기를 이용한 고형연료 제조방법”, 국내등록특허 제10-1042619호에는“음식물쓰레기를 이용한 압축성형 숯연료 제조방법”및 국내등록특허 제10-0443899호에는 "음식물쓰레기를 이용한 고체연료 제조방법”등의 기술이 개시되어 있으나 상기의 선행기술들은 단순히 음식물 쓰레기 그 자체를 그대로 고형 연료화하거나 또는 화력의 증진을 위하여 화학성분들을 첨가한 것에 불과하여 음식점 등에서 사용하는 숯탄으로의 기능을 갖추지 못하여 활용용도가 미흡한 실정이다.As an example of fueling technology of these food wastes, Korean Patent Publication No. 10-2000-0012514, "Method of manufacturing solid fuel using food waste", and Korean Patent Publication No. 10-2005-0032057, "Food waste is charcoal raw material. Method ", Korean Patent Publication No. 10-2008-0042060 discloses" a method of manufacturing solid fuel using food waste ", etc., and Korean Patent Registration No. 10-0453878" charcoal manufacturing apparatus and method using food waste and Apparatus ", Korean Patent No. 10-0532624," Method of manufacturing solid fuel using food waste ", Domestic Patent No. 10-0557471," Method and apparatus for manufacturing charcoal using food waste ", Domestic Patent No. 10- No. 0729816, "Manufacturing Method of Solid Alternative Fuels and Garment Agents Using Food Waste", and Korean Patent Registration No. 10-0735543, "Food waste and solid synthetic resins are used to remove solid fuel. How to ", Korean Patent No. 10-0930055," Method of manufacturing solid fuel using food waste ", Domestic Patent No. 10-0974312," Method of manufacturing activated carbon using food waste ", Domestic Patent No. 10-0991719 No. "Method of manufacturing solid fuel using food waste", Korean Patent No. 10-1042619 No. "Method of manufacturing compressed molded charcoal fuel using food waste" and No. 10-0443899, "Korean solid waste using food waste" Fuel manufacturing method ”and the like, but the above-mentioned prior arts merely solidify food waste as it is or add chemical components to enhance firepower, and thus have a function as charcoal used in restaurants. There is a lack of practical use.
본 발명의 목적은 음식물 쓰레기를 이용하여 친환경적이고, 발열량이 높은 숯불구이용 갈탄을 제공함에 있다. An object of the present invention is to provide an environment-friendly, high calorific value charcoal roast coal using food waste.
본 발명의 다른 목적은 음식물 쓰레기의 대량처리가 가능하여 환경오염을 미연에 방지할 수 있고, 저렴하면서도 양질의 숯불구이용 갈탄의 제조가 가능하여 자원확보는 물론 숯탄의 수입대체 효과를 기대할 수 있으며, 또한 지방자치단체의 음식물쓰레기의 처리비용을 절감할 수 있어 지방재정에 기여할 수 있다.Another object of the present invention can be processed in large quantities of food waste to prevent environmental pollution in advance, it is possible to produce cheap and high-quality charcoal roasting lignite can secure the resources as well as expect the import substitution effect of charcoal, In addition, the municipal government can reduce the disposal cost of food waste, which can contribute to local finance.
상기의 목적을 달성하기 위한 본 발명은 비닐이나 금속 등의 이물질 제거, 염분 희석, 악취제거 및 살균 소독 후 수분함유량이 8-10 중량% 정도로 건조시켜 파쇄하는 전처리공정을 거친 음식물 쓰레기 고형 분쇄물 100중량부에 대하여 일반 목분 80 내지 150중량부, 향나무 목분 20 내지 30중량부, 야자나무 목분 30 내지 50중량부 및 깻묵 10 내지 15중량부를 혼합하여 밀폐된 반응로에서 600~800℃로 간접가열에 의해 전체를 균일하게 탄화시킨 탄화 혼합물을 얻는다.The present invention for achieving the above object is a food waste solid crushed product 100 that has been subjected to a pre-treatment step of drying and crushing water content of 8-10% by weight after removing foreign substances, such as vinyl or metal, salt dilution, odor removal and sterilization sterilization. 80 to 150 parts by weight of ordinary wood powder, 20 to 30 parts by weight of juniper wood powder, 30 to 50 parts by weight of palm tree wood powder and 10 to 15 parts by weight of ink is mixed with indirect heating at 600 to 800 ° C. in a closed reactor. The carbonized mixture obtained by carbonizing the whole uniformly is obtained.
상기 탄화 혼합물 중 향나무 목분의 함유량이 20중량부 이하인 경우, 연소 시 향나무의 은은한 향을 제대로 느낄 수 없으며, 30중량부 이상인 경우 독특한 향내로 인하여 자극을 줄 수 있어 이를 기피하는 사람들에게 불쾌감을 유발할 수 있고, 제조원가가 높아지는 단점이 있다. 또한, 야자나무의 각질은 세포막을 구성하고 있는 고분자 화합물의 일종으로서 강력한 천연 접착제인 리그닌성분이 압축 탄화 과정에서 자연 용출시켜 입자 간의 결속력을 발휘하고 일체화시킴으로써 강도 및 경도가 매우 높아 운반이나 보관시 부서지거나 손에 숯가루가 묻지 않고 점화 후 일반 숯에 비하여 연소시간이 길어지는 특징이 있어 본 발명에서는 야자나무 목분 30 내지 50중량부를 혼합한다. 또한 본 발명에서는 깻묵을 혼합하므로 숯불구이용 갈탄의 연소시 깻묵의 고소한 향을 느낄 수 있어, 고 품질의 갈탄을 제조할 수 있다.When the content of juniper wood flour in the carbonized mixture is 20 parts by weight or less, the fragrance of juniper may not be properly felt when burning, and when it is 30 parts by weight or more, it may cause irritation due to its unique scent, thereby causing discomfort to those who avoid it. And, there is a disadvantage that the manufacturing cost increases. In addition, the keratin of palm tree is a kind of high-molecular compound constituting the cell membrane. The lignin component, a powerful natural adhesive, is eluted naturally during compression carbonization to show the unity and integration between particles, so that the strength and hardness are very high. Charcoal powder is not put on the hand or burned, and the burning time is longer than that of ordinary charcoal after ignition. In the present invention, 30 to 50 parts by weight of palm tree flour is mixed. In addition, in the present invention, since the coal is mixed, the burnt lignite for burning charcoal can feel the savory aroma of the coal, and thus, high quality lignite can be produced.
본 발명은 상기의 탄화 혼합물 100중량부와 맥반석 분말 3 내지 8중량부, 점결제로서 유기점결제인 식용당밀 3 내지 5 중량부, 무기 점토질 점결제인 고령토(Kaolinite) 5 내지 10중량부 및 소량의 착화제를 0.05~0.1 중량부를 혼합한 혼합물을 펠렛압출기에 투입되어 압출 성형시켜 80 내지 120℃에서 압출성형하여 숯불구이용 갈탄을 제조한다. 이렇게 제조된 숯불구이용 갈탄은 발열량이 4,700 kcal/kg을 갖으며, 400℃ 이상의 고열 및 연소지속시간은 1kg 당 2시간 이상 지속되므로 숯탄의 대체연료로서의 기능을 충분히 발휘할 뿐 아니라 연소 중에 악취나 연기가 나지 않아 대기오염의 우려가 없고 도리어 은은하고 고소한 향과 원적외선 및 음이온이 발생하여 공기를 정화시켜 줌으로 육류를 굽을 경우 냄새를 제거하는 탁월한 기능을 갖는다.The present invention is 100 parts by weight of the carbonized mixture and 3 to 8 parts by weight of ganban stone powder, 3 to 5 parts by weight of edible molasses as an organic binder as a binder, 5 to 10 parts by weight of kaolinite as an inorganic clay binder and a small amount. A mixture of 0.05 to 0.1 parts by weight of the complexing agent was introduced into a pellet extruder and extruded to produce an charcoal roasted lignite by extrusion molding at 80 to 120 ℃. The charcoal roasted lignite has a calorific value of 4,700 kcal / kg, and the high heat and combustion duration of more than 400 ° C. lasts more than 2 hours per kg. There is no fear of air pollution, and it has a superior function of removing odors when grilling meat by purifying the air by producing a soft and savory fragrance, far infrared rays and anions.
본 발명의 숯불구이용 갈탄은 선별 및 분쇄하여 건조시킨 음식물 쓰레기 분말과 일반 목분, 향나무 목분 및 야자나무 목분 및 깻묵을 혼합하여 밀폐된 탄화로에서 600~800℃로 간접가열에 의해 전체를 균일하게 탄화시킨 탄화 분쇄물에 맥반석 분말, 점결제로서 유기점결제인 식용당밀과 무기 점토질 점결제인 고령토(Kaolinite) 및 착화제를 혼합한 혼합물을 펠렛 압출기에 투입되어 압출 성형시켜 300 내지 800℃에서 압출 성형한 숯불구이용 갈탄으로 연소시 은은한 향을 느낄 수 있으며, 야자나무 목분을 사용함으로써 세포막을 구성하고 있는 고분자 화합물의 일종인 각질에 의해 강력한 천연 접착제인 리그닌 성분을 압축 탄화 과정에서 자연 용출시켜 입자 간의 결속력을 발휘하고 일체화시킴으로써 강도 및 경도가 매우 높아 운반이나 보관시 부서지거나 손에 숯가루가 묻지 않고 점화 후 일반 숯에 비하여 연소시간이 길어지며, 맥반석 및 무기 점토질 점결제인 고령토(Kaolinite)에 의해 원적외선 및 음이온이 발생하여 공기를 정화시키는 등의 효과가 있다.The charcoal roasted lignite of the present invention is carbonized whole by uniformly indirect heating at 600 ~ 800 ℃ in a closed carbonization furnace by mixing the food waste powder and ordinary wood powder, juniper wood powder and palm wood powder and ink dried by screening and grinding. The mixture of carbonized pulverized crushed gannetite powder, edible molasses as an organic binder, kaolinite as an inorganic clay binder, and a complexing agent was put into a pellet extruder and extruded to be extruded at 300 to 800 ° C. It is a charcoal-grilled lignite, which gives a gentle scent when burning. Coconut cohesion between particles is achieved by natural dissolution of lignin, a powerful natural adhesive, during compression carbonization by keratin, a high-molecular compound that forms the cell membrane. Strength and hardness by breaking down and integrating Without a charcoal powder adhere to the hand becomes a combustion time longer than normal char after ignition, there is an effect, such as to purify the air and the far-infrared ray and anion generated by the quartz porphyry, and an inorganic clay binder of china clay (Kaolinite).
도 1은 수거한 음식물쓰레기의 전처리공정도.
도 2는 본 발명에 따른 음식물 쓰레기를 이용하여 제조된 숯불구이용 갈탄.1 is a pre-treatment process of the collected food waste.
Figure 2 is charcoal grilled lignite prepared using food waste according to the present invention.
본 발명은 음식물쓰레기를 수거하여 금속이나 비닐 등의 이물질을 선별기로 선별한 후 염분 희석, 악취제거 및 살균 소독하여 수분함수량이 8-10 중량% 이하가 되도록 180∼200℃의 온도로 30분간 1차 건조시켜 음식물 쓰레기 고형분을 얻는 전처리공정을 거친다. 상기의 전처리공정은 주식회사 푸드에너지가 보유하고 있는 국내특허 제10-1088014호 및 10-1114315호의 음식물쓰레기 장치 및 음식물 재활용 방법에서 사용하는 장치를 이용하였다. 상기의 건조된 음식물 쓰레기 분말에 일반목분과 향나무 목분, 야자나무 목분 및 깻묵을 혼합한 혼합물을 Rotary kiln 반응로에 넣고 간접가열방식에 의해 탄화시킨다. 이때 탄화온도는 600 내지 1000℃를 유지한다. 상기의 탄화혼합물의 성분 및 조성비율은 표 1과 같다.The present invention collects food waste and sorts foreign substances such as metals and vinyls with a sorter, and then dilutes salts, removes odors, and sterilizes them for 30 minutes at a temperature of 180 to 200 ° C. such that water content is 8-10% by weight or less. The tea is dried and pretreated to get food waste solids. The pretreatment process was used in the food waste device and food recycling method of the domestic patent Nos. 10-1088014 and 10-1114315 owned by Food Energy. The dried food waste powder was mixed with ordinary wood powder, juniper wood powder, palm wood powder and ink in a rotary kiln reactor and carbonized by indirect heating. At this time, the carbonization temperature is maintained at 600 to 1000 ℃. The components and composition ratios of the carbonized mixtures are shown in Table 1.
상기의 탄화 혼합물에 맥반석 분말과 점결제로서 유기점결제인 식용당밀 및 무기 점토질 점결제인 고령토(Kaolinite)와 당분야에서 일반적으로 사용하는 통상의 착화제 소량을 잘 혼합한 후 이를 펠렛 압출기에 투입하여 압출 성형시켜 본 발명의 숯불구이용 갈탄을 제조한다. 상기의 숯불구이용 갈탄은 연소지속시간은 1kg 당 2시간이며, 발열량이 4,700 kcal/kg을 갖으며, 그 조성성분 및 조성비율은 표 2와 같다.In the above carbonized mixture, small amounts of organic rock edible molasses and kaolinite as inorganic binders and kaolinite as inorganic binders are mixed well with a small amount of a complexing agent commonly used in the art, and then put into a pellet extruder. By extrusion molding to produce lignite charcoal of the present invention. The charcoal roasted lignite has a combustion duration of 2 hours per kg, has a calorific value of 4,700 kcal / kg, and its composition and composition ratio are shown in Table 2.
상기 맥반석 분말의 함유량이 8중량부 초과하고, 고령토의 함유량이 10중량부를 초과할 경우, 연소가 지연되며 발열량이 자하될 우려가 있고,When the content of the above-mentioned elvan rock powder exceeds 8 parts by weight and the content of kaolin exceeds 10 parts by weight, combustion may be delayed and the calorific value may be lowered.
맥반석의 함유량이 3중량부 미만이고 고령토의 함유량이 5중량부 미만일 경우 원적외선이나 음이온의 발생량이 줄어 공기정화가 미흡하므로 맥반석 분말의 함유량은 3-5중량부, 고령토의 함유량은 4-6중량부가 바람직하다. If the content of elvan is less than 3 parts by weight and the content of kaolin is less than 5 parts by weight, the amount of far-infrared rays or anions is reduced and air purification is insufficient. Therefore, the content of elvan is 3 to 5 parts by weight, and the content of kaolin is 4 to 6 parts by weight. desirable.
이하 본 발명의 구체적인 실시예를 설명하되, 하기의 실시예는 본 발명을 예시하기 위한 것으로 본 발명의 권리범위가 하기의 설명에 한정되는 것은 아니며, 통상적인 당업자 수준에서의 응용 또한 본 발명의 범위에 포함된다. 그리고 본 발명에서는 이미 주지된 기술적 부분에 대한 설명의 간결함을 위해 생략하거나 압축하기로 한다.DETAILED DESCRIPTION Hereinafter, specific examples of the present invention will be described, but the following examples are provided to illustrate the present invention, and the scope of the present invention is not limited to the following descriptions. Included in In the present invention, for the sake of brevity of the description of the well-known technical parts will be omitted or compressed.
<실시예> <Examples>
숯불구이용 갈탄의 제조Production of lignite charcoal
수거된 음식물 쓰레기는 이물질을 제거하고 물로 염분을 희석시킨 후 악취제거 및 살균 소독하여 건조 및 파쇄하는 전처리 과정을 거쳐 10 중량%의 수분을 함유한 고형분의 음식물 쓰레기 분쇄물을 얻는다. 상기의 음식물 쓰레기 분쇄물 50Kg과 일반 목분 50Kg, 향나무 목분 15Kg, 야자나무 목분 20Kg 및 깻묵 8Kg을 혼합하여 반응로로 이송시킨다. 상기 반응로에서는 공기를 차단 밀폐상태에서 100㎖/min의 비율로 질소가스를 주입하면서 12℃/min 속도로 승온하여 800℃까지 간접 가열하여 혼합물 전체가 균일하게 탄화되도록 탄화시켜 탄화 혼합물을 얻는다. The collected food waste is subjected to a pretreatment process of removing foreign substances, diluting salts with water, deodorizing, sterilizing, drying and crushing to obtain a solid food waste pulverized containing 10% by weight of water. 50 Kg of the food waste pulverized product and 50 Kg of ordinary wood powder, 15 Kg of cedar wood powder, 20 Kg of palm tree powder and 8 Kg of coal are mixed and transferred to the reactor. In the reactor, air is heated at a rate of 12 ° C./min while injecting nitrogen gas at a rate of 100 ml / min in a closed state, and indirectly heated to 800 ° C. to carbonize the mixture so that the entire mixture is carbonized uniformly.
상기 탄화혼합물 분말 100Kg과 맥반석 분말 5 Kg, 점결제인 식용당밀 4Kg, 고령토(Kaolinite) 6Kg 및 착화제 0.1Kg을 넣은 후 이들을 잘 혼합한 후 펠렛 압출기에 투입시켜 압출 성형시켜 숯불구이용 갈탄을 제조하였다. 이때, 점결제인 당밀 등이 잘 호화할 수 있도록 펠렛 압출기의 내부 온도는 100℃을 유지한다,100 Kg of the carbonized mixture powder, 5 Kg of gannetite powder, 4Kg of edible molasses as a binder, 6Kg of kaolinite, and 0.1Kg of a complexing agent were added and mixed well. . At this time, the internal temperature of the pellet extruder is maintained at 100 ℃ so that the molasses, such as the caking agent can be gelatinized well,
Claims (4)
상기 탄화 혼합물 100중량부와 맥반석 분말 3 내지 8중량부, 점결제로서 유기점결제인 식용당밀 3 내지 5 중량부, 무기 점토질 점결제인 고령토(Kaolinite) 5 내지 10중량부 및 착화제를 0.05~0.1 중량부로 조성된 혼합물을 펠렛 압출기에 투입하여 압출 성형시키는 것을 특징으로 하는 음식물 쓰레기를 이용한 숯불구이용 갈탄.100 parts by weight of solid food waste and 80 to 150 parts by weight of pre-processed food waste, which is dried and crushed after removing foreign substances such as vinyl or metal, diluting salt, removing odor and sterilizing To obtain a carbonized mixture obtained by carbonizing a mixture consisting of 20-30 parts by weight of juniper wood powder, 30-50 parts by weight of palm tree powder, and 10-15 parts by weight of ink, by indirect heating,
100 parts by weight of the carbonized mixture and 3 to 8 parts by weight of gannetite powder, 3 to 5 parts by weight of edible molasses as an organic binder, 5 to 10 parts by weight of kaolinite as an inorganic clay binder, and a complexing agent, Charcoal roasted charcoal using food waste, characterized in that the extrusion composition is put into a pellet extruder to 0.1 parts by weight.
간접가열시 가열온도는 600~800℃ 이고, 압출성형시의 온도는 80 내지 120℃인 것을 특징으로 하는 음식물 쓰레기를 이용한 숯불구이용 갈탄.The method of claim 1,
Charcoal roasting charcoal using food waste, characterized in that the heating temperature during indirect heating is 600 ~ 800 ℃, the temperature during extrusion molding is 80 to 120 ℃.
연소지속시간은 1kg 당 2시간이며, 발열량이 4,700 kcal/kg인 것을 특징으로 하는 음식물 쓰레기를 이용한 숯불구이용 갈탄.The method according to claim 1 or 2,
The burning duration is 2 hours per 1kg, charcoal roasting charcoal using food waste, characterized in that the calorific value is 4,700 kcal / kg.
상기 맥반석 분말의 함유량은 3-5중량부이고, 고령토의 함유량은 4-6중량부인 것을 특징으로 하는 음식물 쓰레기를 이용한 숯불구이용 갈탄.The method according to claim 1 or 2,
Charcoal roasting charcoal using food waste, characterized in that the content of the ganban stone powder is 3-5 parts by weight, and the content of kaolin is 4-6 parts by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20120154246A KR101247944B1 (en) | 2012-12-27 | 2012-12-27 | Using food waste for charcoal fire brown coal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20120154246A KR101247944B1 (en) | 2012-12-27 | 2012-12-27 | Using food waste for charcoal fire brown coal |
Publications (1)
Publication Number | Publication Date |
---|---|
KR101247944B1 true KR101247944B1 (en) | 2013-04-03 |
Family
ID=48441891
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR20120154246A KR101247944B1 (en) | 2012-12-27 | 2012-12-27 | Using food waste for charcoal fire brown coal |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR101247944B1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200083880A (en) * | 2018-12-31 | 2020-07-09 | 충남대학교산학협력단 | Briquette having reduced toxic gas and ash and manufacturing method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20060096392A (en) * | 2006-08-10 | 2006-09-11 | 코리아에너지 주식회사 | A solid fuel manufacturing method and its device use of the food waste and the plastic waste |
KR20070076557A (en) * | 2007-05-28 | 2007-07-24 | 김형식 | A solid fuel manufacturing method use of the sewage sludge and food wastes and inflammable wastes |
KR20090077663A (en) * | 2008-01-11 | 2009-07-15 | 주식회사 케너텍 | Cokes-alternative solid carbonized fuels and method for preparing thereof |
KR100912663B1 (en) | 2008-09-05 | 2009-08-17 | 주식회사 우일 이알에스 | Charcoal using coconut shells and method for manufacturing the same |
-
2012
- 2012-12-27 KR KR20120154246A patent/KR101247944B1/en not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20060096392A (en) * | 2006-08-10 | 2006-09-11 | 코리아에너지 주식회사 | A solid fuel manufacturing method and its device use of the food waste and the plastic waste |
KR20070076557A (en) * | 2007-05-28 | 2007-07-24 | 김형식 | A solid fuel manufacturing method use of the sewage sludge and food wastes and inflammable wastes |
KR20090077663A (en) * | 2008-01-11 | 2009-07-15 | 주식회사 케너텍 | Cokes-alternative solid carbonized fuels and method for preparing thereof |
KR100912663B1 (en) | 2008-09-05 | 2009-08-17 | 주식회사 우일 이알에스 | Charcoal using coconut shells and method for manufacturing the same |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200083880A (en) * | 2018-12-31 | 2020-07-09 | 충남대학교산학협력단 | Briquette having reduced toxic gas and ash and manufacturing method thereof |
KR102156482B1 (en) | 2018-12-31 | 2020-09-16 | 충남대학교산학협력단 | Briquette having reduced toxic gas and ash and manufacturing method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101539224B1 (en) | Method for preparing biomass solid refuse fuel | |
KR101293642B1 (en) | Manufacturing method of solid fuel from sludge and solid fuel from sludge | |
CN102161897B (en) | Method for preparing charcoal activated carbon flammable gas biological oil by utilizing crop straws | |
CN101810165B (en) | Smokeless mosquito incense blank and preparation method thereof | |
KR100912663B1 (en) | Charcoal using coconut shells and method for manufacturing the same | |
Ugwu et al. | Briquetting of palm kernel shell | |
KR102155762B1 (en) | Ecological solid fuel and process for preparing the same | |
NZ582990A (en) | Disposal method for entirely recycling solid refuse | |
KR101705612B1 (en) | Method for manufacturing solid fuel using coffee by-products | |
KR101713495B1 (en) | Foaming charcoal and manufacturing method thereof | |
KR20150019243A (en) | Method for preparing high density pellet or block using waste including coffee waste | |
KR101247944B1 (en) | Using food waste for charcoal fire brown coal | |
KR101042619B1 (en) | Method for producing compressed charcoal fuel using food waste | |
KR101611939B1 (en) | Method for manufacturing briquette using red clay and chestnuts | |
KR101995756B1 (en) | Wood Briquet Using Wooden Wastes and Manufacturing Method Thereof | |
KR100981418B1 (en) | Wood pellet containing shell powder and manufacturing method thereof | |
KR102315534B1 (en) | Solid fuel composition and manufacturing method of the same | |
CN103820189A (en) | Compound bamboo biomass granular fuel and preparation method thereof | |
KR101530552B1 (en) | Refused Derived Fuel Produced by Mixing Chaff Powder and Paper Sludge | |
KR20220099624A (en) | High-efficiency solid fuel containing recycled coffee waste and half-carbonized rice husks and manufacturing method thereof | |
CN107286970B (en) | Tea residue smokeless carbon and preparation method thereof | |
KR100843165B1 (en) | Method for preparing a charcoal using combustible organic waste matters | |
CN114306055A (en) | Making smokeless moxibustion stick, incense stick and mosquito-repellent incense with inorganic substance | |
KR20160135050A (en) | Wood briquette and method for preparing the same | |
TWI776507B (en) | Manufacturing method of bio-fuel by using waste utensils as binders and a composition of bio-fuel |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
A302 | Request for accelerated examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
LAPS | Lapse due to unpaid annual fee |