KR101218145B1 - Biaxially-oriented polyester film excellent in formability and manufacturing method thereof - Google Patents
Biaxially-oriented polyester film excellent in formability and manufacturing method thereof Download PDFInfo
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Abstract
The present invention relates to a biaxially stretched polyester film excellent in formability and a method for manufacturing the same, and more particularly, by providing low strength, high elongation, and elongation balance in a random direction, thereby providing excellent moldability and providing various industrial materials. It is not only used for coating the base film of packaging materials, building materials and various containers, but also can be used as a support film for in-mold transfer molding which prints simultaneously with molding. Or it relates to a biaxially stretched polyester film excellent in formability that can improve the problems such as the occurrence of whitening phenomenon due to crystallization and its manufacturing method. To this end, the biaxially stretched polyester film having excellent moldability according to the present invention has a value defined by Equation 1 below at a temperature of 25 ° C. and a relative humidity of 60%: 0.5 to 2.0, and a range of the value is 0 to 0.50. This,
(1)
Here, S Random is the film tensile strength (MPa) in the random direction, E Random is characterized in that the film breaking elongation (%) in the random direction.
Description
The present invention relates to a biaxially stretched polyester film excellent in formability and a method for manufacturing the same, and more particularly, by providing low strength, high elongation, and elongation balance in a random direction, thereby providing excellent moldability and providing various industrial materials. It is not only used for coating the base film of packaging materials, building materials and various containers, but also can be used as a support film for in-mold transfer molding which prints simultaneously with molding. Or it relates to a biaxially stretched polyester film excellent in formability that can improve the problems such as the occurrence of whitening phenomenon due to crystallization and its manufacturing method.
Conventionally, relatively inexpensive polyvinyl chloride films have been used as the film for molding, showing excellent processability.
However, such polyvinyl chloride has a very poor environmental friendliness due to the occurrence of carcinogens such as chlorine gas and dioxins during incineration. Recently, the use of polyvinyl chloride has been regulated by law in Japan and Korea. The trend is decreasing, which requires alternative materials with less environmental load.
In order to satisfy the demand, polyesters, polycarbonates, acrylic resins, and the like are used in a wide range of fields as non-chlorine materials. In particular, polyester resins are notable for their excellent mechanical properties, heat resistance, chemical resistance, transparency, and the like, as well as excellent economic efficiency.
In the case of polyethylene terephthalate, which is the most commonly used among such polyesters, when biaxially stretched by a conventional method, there is a problem in that the crystallinity is strong and the deformation stress is too high during molding, resulting in poor moldability. In addition, the molding direction of the film during molding is formed in all directions in the direction of 0 ° to 360 °, but during biaxial stretching processing, the formability drops sharply due to high strength and low elongation due to stretch crystallization in the stretching direction, or in a random direction. There is a problem that whitening phenomenon due to wrinkles or crystallization of the film occurs due to poor uniformity of the molding.
The present invention has been made to solve the above problems, the object of the present invention is to achieve a low strength, high elongation and elongation balance in the random direction, biaxial stretching excellent moldability that can provide excellent moldability It is to provide a polyester film and a method of manufacturing the same.
These and other objects and advantages of the present invention will become more apparent from the following description of a preferred embodiment thereof.
The object is, under the conditions of temperature 25 ℃, relative humidity 60%, the value defined by the following formula (1) is 0.5 to 2.0, the range of the value is 0 to 0.50,
(1)
Here, S Random is achieved by the biaxially stretched polyester film having excellent moldability, characterized in that the film tensile strength (MPa) in the random direction, E Random is the film breaking elongation (%) in the random direction.
Here, the biaxially stretched polyester film having excellent moldability includes an aromatic dicarboxylic acid component and an aliphatic glycol component, wherein the aromatic dicarboxylic acid component is dimethyl terephthalate, terephthalic acid, isophthalic acid, 2,6-naphthalenedica Carboxylic acid, sebacic acid, adipic acid, diphenyldicarboxylic acid, 5- tert - butylisophthalic acid, 2,2,6,6-tetramethyldiphenyl-4,4'-dicarboxylic acid, 1 , 1,3-trimethyl-3-phenylindane-4,5-dicarboxylic acid, 5-sodium sulfoisophthalic acid, trimellitic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, pimeric acid, azelaic acid , Pyromellitic acid, 1,4-cyclohexanedicarboxylic acid and at least one selected from the group consisting of 1,3-cyclohexanedicarboxylic acid, the aliphatic glycol component is ethylene glycol, neopentyl glycol, 1,4 Cyclohexanedimethanol, diethylene glycol, propanediol, butanediol Characterized in that the at least one selected from the group.
Preferably, the tensile strength of the biaxially stretched polyester film excellent in formability is characterized in that 100 to 300Mpa.
Preferably, the elongation at break of the biaxially stretched polyester film having excellent moldability is 150 to 300%.
Preferably, the biaxially stretched polyester film having excellent moldability is characterized in that the ratio of the stretching ratio in the transverse direction to the longitudinal direction is 0.90 to 1.1, and the ratio of the stretching temperature in the transverse direction to the longitudinal direction is 0.85 to 1.15. .
In addition, the object is a first step of producing a non-stretched sheet and melt-extruded polyester composition consisting of an aromatic dicarboxylic acid component and an aliphatic glycol component in the crystal melting temperature + 10 ℃ to 60 ℃ glass and the unstretched sheet The second step of stretching 2.0 times to 4.5 times in the longitudinal direction (MD) and 2.0 times to 4.5 times in the transverse direction (TD) at a temperature higher than the transition temperature and the stretched film is carried out at a glass transition temperature of + 10 ° C to 250 ° C. It is achieved by a method for producing a biaxially stretched polyester film having excellent moldability, characterized in that it comprises a third step of heat treatment for seconds to 60 seconds.
Preferably, in the second step, the ratio of the stretching ratio in the transverse direction to the longitudinal direction is 0.90 to 1.1, and the ratio of the stretching temperature in the transverse direction to the longitudinal direction is 0.85 to 1.15.
According to the present invention, low strength, high elongation and high elongation balance are achieved in a random direction, thereby providing excellent formability, which is used for surface coating of various industrial materials, packaging materials, building materials, base films and various containers. In particular, it can be used as a support film for in-mold transfer molding which prints simultaneously with molding, and can improve problems such as whitening due to wrinkles or crystallization of the film due to insufficient moldability during molding. Has an effect.
Hereinafter, the present invention will be described in detail with reference to examples of the present invention. These examples are only presented by way of example only to more specifically describe the present invention, it will be apparent to those skilled in the art that the scope of the present invention is not limited by these examples. .
The present invention relates to a biaxially stretched polyester film having excellent moldability, and as a result of efforts to solve the above-described technical problems, copolymerizing raw materials using at least one aromatic dicarboxylic acid and an aliphatic glycol component of polyester, respectively. Alternatively, the present invention has been completed by obtaining a biaxially stretched polyester film having low strength, high elongation and high elongation balance in a random direction and having excellent moldability.
The biaxially stretched polyester film having excellent moldability according to the present invention has a value defined by Equation 1 below at a temperature of 25 ° C. and a relative humidity of 60%, and has a value ranging from 0 to 0.50.
(1)
Wherein S Random is the tensile strength of the film (MPa) in the random direction, E Random is characterized in that the film breaking elongation (%) in the random direction.
Next, the polyester composition according to the present invention will be described below.
The biaxially stretched polyester film according to the present invention is prepared by a polyester composition composed of an aromatic dicarboxylic acid and an aliphatic glycol component, and homo-polyester or copolymerization using at least one dicarboxylic acid component and an aliphatic glycol component, respectively. Polyester is prepared. The polyester composition will be described in more detail. Examples of the aromatic dicarboxylic acid component include dimethyl terephthalate, terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, sebacic acid, adipic acid and diphenyldicarboxyl. Acid, 5-tert-butylisophthalic acid, 2,2,6,6-tetramethyldiphenyl-4,4'-dicarboxylic acid, 1,1,3-trimethyl-3-phenylindane-4,5- Dicarboxylic acid, 5-sodium sulfoisophthalic acid, trimellitic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, pimeric acid, azelaic acid, pyromellitic acid, 1,4-cyclohexanedicarboxylic acid and Used in the group consisting of 1,3-cyclohexanedicarboxylic acid, and used as the aliphatic glycol component as ethylene glycol, neopentyl glycol, 1,4-cyclohexanedimethanol, diethylene glycol, propanediol, butanediol Homo-polyester or copolymerization by condensation polymerization using at least one To prepare a Li ester composition.
At this time, when the degree of deformation of the molding is low (Equation 1 is 1.2 to 2.0) can be prepared with a homo-polyester composition, such as polyethylene terephthalate, but when the degree of deformation is very large (Equation 1 is 0.5 to 1.2), in the case of homo-polyesters, crystal structures are easily formed by the regular arrangement of aromatics in the polymer chain, and thus high crystallinity cannot obtain the desired deformation. Therefore, as described above, it is necessary to make two or more kinds of aromatic dicarboxylic acid components or two or more kinds of aliphatic glycol components to solve the regular arrangement of the aromatics and to crystallize the polymer.
(1)
Here, S Random is film tensile strength (MPa) in random direction, and E Random is film breaking elongation (%) in random direction.
In addition, the polyester composition may contain inorganic or organic particles during condensation polymerization in order to facilitate slip, winding and processability in film production, and examples of the inorganic particles include silica, aluminum silicate, alumina, and oxidation. Titanium, potassium phosphate, barium sulfate, and the like can be used, and as the organic particles, polyimide, polymethyl methacrylate, polyamideimide, or the like can be used. In particular, in order to be used as a support film for in-mold transfer molding, the content of the particles in the polyester composition is preferably 0.001% by weight to 10.0% by weight, more preferably 0.01% by weight to 1.0% by weight, and the like It may contain particles in the range of 1.0% to 10.0% by weight for the purpose of. If the particle content is less than 0.001% by weight, the slipperiness, runability, and workability of the produced film are remarkably poor, which may cause problems such as winding troubles and surface defects, such as scratches, and transparency when the particle content exceeds 10.0% by weight. This has a problem of deterioration. The average diameter of the particles is preferably 0.01 μm to 10 μm. If the average diameter is less than 0.01 μm, the effect of improving the slip property, the winding property, and the workability of the film is insufficient. If the average diameter exceeds 10 μm, coarse protrusions are used. It is not preferable because it can cause film defects.
In addition, the glass transition temperature (Tg) of the polyester composition is preferably -30 ℃ to 90 ℃. In the case of various industrial materials, packaging materials, and coating materials processed at room temperature, a glass transition temperature of -30 ° C to 10 ° C may show good moldability. In the case of thermoforming such as in-mold transfer molding, glass transition The temperature of 10 ° C to 90 ° C has the advantage of ensuring moldability and heat resistance. When the glass transition temperature is less than -30 ℃, there is a disadvantage in that the supportability of the molded body is inferior, when the glass transition temperature exceeds 90 ℃, the moldability is low at low temperatures, the problem of low commerciality because it must be molded at a higher temperature There is.
In addition, the polyester composition preferably has a crystal melting temperature (Tm) of 160 ° C to 250 ° C in terms of heat resistance and moldability. If the crystal melting temperature is less than 160 ℃ heat resistance is poor, there is a problem that the adhesion occurs to the molded body, if the crystal melting temperature exceeds 250 ℃ may be preferable in terms of heat resistance, but the formability of the produced film is inferior, high temperature Since the molding must be performed in the wrinkles of the film due to softening, there is a problem that the transparency is reduced due to the whitening caused by the crystallization. The crystal melting temperature can be designed in the range of 160 ℃ to 250 ℃ according to the crystal melting temperature of the injection molding product.
Moreover, it is preferable that the intrinsic viscosity (IV) of the said copolyester composition is 0.5-1.2 dL / g, More preferably, it is 0.6-0.9 dL / g. If the intrinsic viscosity is less than 0.5 dℓ / g, there is a problem that the breakage occurs when stretching the film due to the lack of cohesion of the resin due to the decrease in mechanical properties, and if the excess viscosity exceeds 1.2 dℓ / g, it is difficult to stretch itself due to excessive stretching stress Or, there is a problem in that the deformation stress is high after the film production is poor in formability.
Next, the manufacturing method of the biaxially stretched polyester film for shaping | molding concerning this invention is demonstrated below.
Method for producing a biaxially stretched polyester film excellent in formability according to the present invention is melt extrusion of the polyester composition in the crystal melting temperature + 10 ℃ to 60 ℃ range using an extruder in the first step, and from the T-die The extruded polymer is cooled and solidified to produce an unstretched sheet. The unstretched sheet obtained in the first step is subjected to the second step of stretching 2.0 times to 4.5 times in the longitudinal direction (MD) and 2.0 times to 4.5 times in the transverse direction (TD) at a temperature higher than the glass transition temperature. The film is subjected to a third step of heat treatment for 5 seconds to 60 seconds at the glass transition temperature + 10 ℃ to 250 ℃.
In this case, when the stretching ratio in the longitudinal direction and the transverse direction is less than 2.0 times, the present invention can obtain a low tensile strength and a high elongation at break, but the value defined by the following Equation 1 becomes less than 0.5, resulting in the thickness of the prepared film. Low uniformity, low mechanical strength, poor support of the molded article, which is not commercially desirable, and when the stretching ratio in the longitudinal and transverse directions exceeds 4.5 times, high tensile strength and low elongation at break The value defined as is greater than 2.0, high molding stress does not meet the purpose of this patent.
(1)
Where S Random is the film tensile strength (MPa) in the random direction and E Random is the film breaking elongation (%) in the random direction.
Further, in the method for producing a biaxially stretched polyester film having excellent moldability according to the present invention, the ratio of the stretching ratio in the transverse direction to the longitudinal direction is 0.90 to 1.1, and the ratio of the stretching temperature in the transverse direction to the longitudinal direction is 0.85 to 1.15. Only, the range of the value defined by Equation 1 desired in the present patent may be 0.50 or less. In the range beyond the ratio of the draw ratio and the draw temperature, it was confirmed that the random direction balance of the elongation property is not achieved and does not meet the purpose of the present patent.
The biaxially stretched polyester film having excellent moldability according to the present invention may form an antistatic layer or an easily adhesive layer on one or both sides of the base film, particularly when used as a support film for in-mold transfer molding. The antistatic layer may prevent contamination in the mold during in-mold molding, prevent mixing of foreign matter during the processing process, and prevent blocking phenomenon between the base film and the hard coating layer (or printing layer) or the adhesive layer. In addition, the in-mold transfer film has a release layer in the layer structure for transferring the printing layer, and an adhesive layer is required on one surface of the base film to increase the interfacial adhesion between the base film and the release layer. Such an antistatic layer and an adhesive layer can be carried out through an inline process and offline coating.
In addition, the biaxially stretched polyester film having excellent moldability according to the present invention preferably has a tensile strength of 100 to 300 MPa and an elongation at break of 150 to 300% at room temperature. If the tensile strength is less than 100MPa, the supportability of the molded body is not preferable, and if the tensile strength exceeds 300MPa, there is a problem that the deformation stress of the film is too high, resulting in poor moldability, and when the elongation at break is less than 150%. In the product having high molding bending degree, sufficient moldability cannot be obtained, and when the elongation at break exceeds 300%, the moldability may be excellent, but there is a problem that the thickness uniformity is low due to the low draw ratio.
In addition, the biaxially stretched polyester film having excellent moldability according to the present invention preferably has a heat shrinkage in the longitudinal and transverse directions of -5% to 5% at 150 ° C, more preferably -3% to 3%. It is preferable that it is%. If the heat shrinkage is less than -5 or more than 5%, it is not preferable because there is a problem that the defective rate of the molded product is increased by causing a dimensional change in the printing process and the thermoforming process.
In addition, the thickness of the polyester film for molding is preferably 10 to 500㎛ in consideration of formability and processability.
Hereinafter, the configuration and effects of the present invention will be described in more detail with reference to Examples and Comparative Examples. However, this embodiment is intended to illustrate the present invention in more detail, and the scope of the present invention is not limited to these examples.
[Example]
Preparation Example 1 Preparation of Homo-Polyester Composition (A)
Into an autoclave equipped with a stirrer and a distillation column, 180 mol% of ethylene glycol was added as a diol component, 100 mol% of dimethyl terephthalate as an acid component, and 0.07 mol% of manganese acetate was added as a transesterification catalyst to dimethyl terephthalate. The ester exchange reaction was carried out while removing the methanol flowing out while raising the temperature to 240 ° C. After the transesterification reaction, trimethyl phosphate was added 0.03 mol% to dimethyl terephthalate as a thermal safety agent, and after 5 minutes, 0.04 mol% of antimony trioxide was added as a polymerization catalyst, stirred for 5 minutes, and then transferred to a second reactor equipped with a vacuum facility. The polymer was polymerized for about 4 hours while removing excess ethylene glycol while gradually depressurizing while increasing the temperature to 280 ° C to obtain a homo-polyester composition (A) having an intrinsic viscosity of 0.70 dL / g.
Preparation Example 2 Preparation of Homo-Polyester Composition (B)
20 mol% of 1,4-cyclohexanedimethanol and 10 mol% butanediol 150 mol ethylene glycol with respect to 85 mol% of dimethyl terephthalate and 15 mol% of isophthalic acid as an acid component in the autoclave with a stirrer and a distillation column % Was added, and 0.07 mol% of manganese acetate was added to the dimethyl terephthalate as a transesterification catalyst, and the transesterification reaction was carried out while removing the methanol which was discharged while raising the temperature to 240 ° C. After the transesterification reaction, trimethyl phosphate was added 0.03 mol% to dimethyl terephthalate as a thermal safety agent, and after 5 minutes, 0.04 mol% of antimony trioxide was added as a polymerization catalyst, stirred for 5 minutes, and then transferred to a second reactor equipped with a vacuum facility. The polymer was polymerized for about 5 hours while the excess diol component was removed while gradually depressurizing while increasing the temperature to 280 ° C to obtain a homo-polyester composition (B) having an intrinsic viscosity of 0.70 dL / g.
Example 1
The polyester composition (A) prepared in Preparation Example 1 was melted at 280 ° C. and extruded from a T-die, and then quenched by casting or calendar method to obtain an unstretched sheet, followed by cooling to a temperature of 115 ° C. After extending | stretching 3.7 times in the direction, it extended | stretched 3.8 times in the horizontal direction at the temperature of 120 degreeC. After the heat treatment for 10 seconds at a temperature of 250 ℃ to prepare a polyester film for molding 50㎛ thickness.
[Example 2]
The polyester composition (B) prepared in Preparation Example 2 of Example 1 was melted at 240 ° C. and extruded from a T-die, followed by rapid cooling by casting or calendar method to obtain an unstretched sheet, followed by 75 ° C. The film was stretched 3.4 times in the longitudinal direction at a temperature of and then stretched 3.6 times in the transverse direction at a temperature of 80 ° C. After the heat treatment for 10 seconds at a temperature of 200 ℃ to prepare a polyester film for molding 50㎛ thickness.
Comparative Example 1
A polyester film for molding was prepared in the same manner as in Example 1, except that the longitudinal draw ratio was 4.1 times and the lateral stretch ratio was 3.4 times.
Comparative Example 2
A polyester film for molding was prepared in the same manner as in Example 1 except that the product was prepared at a longitudinal stretching temperature of 105 ° C and a transverse stretching temperature of 130 ° C.
[Comparative Example 3]
A polyester film for molding was prepared in the same manner as in Example 1, except that the product was prepared at a longitudinal draw ratio of 3.3 times and a transverse draw ratio of 4.0 times.
[Comparative Example 4]
A polyester film for molding was prepared in the same manner as in Example 2, except that the product was prepared at a longitudinal stretching temperature of 96 ° C and a transverse stretching temperature of 78 ° C.
[Comparative Example 5]
A polyester film for molding was prepared in the same manner as in Example 1, except that the film was produced at a longitudinal stretching ratio of 5.0 times and a transverse stretching ratio of 5.0 times at a longitudinal stretching temperature of 120 ° C. and at a transverse stretching temperature of 120 ° C.
Physical properties of the biaxially stretched polyester films according to Examples 1 and 2 and Comparative Examples 1 to 5 were measured through the following experimental examples, and the results are shown in Table 1 below.
[Experimental Example]
1. Measurement of glass transition temperature and crystal melting temperature
Using a differential scanning calorimeter (Seiko Instruments DSC, RDC220) and a data analyzer (Seiko Instruments disk station, SSC / 5200), 5 mg of sample was placed on an aluminum pedestal and nitrogen gas was flown at a flow rate of 40 ml / min. The temperature was increased from 25 ° C to 280 ° C at a temperature increase rate of 20 ° C / min, and the glass transition temperature and crystal melting temperature were measured according to JIS K 7121-1987.
2. Tensile strength, elongation at break
Films made using the universal testing machine (UnitTM, SSTM-5KN) are longitudinal, transverse and random (30 °, 45 °, 70 °, 90 °, 120 °, 135 when viewed in the longitudinal direction). 160 °), a length of 100 mm and a width of 12.65 mm were cut and stretched at a tensile speed of 100 mm / min to obtain a stress-strain curve until fracture occurred. In this case, the force (MPa) applied when the fracture occurred was called tensile strength, and the increased length (%) was defined as the fracture elongation.
3. Intrinsic viscosity measurement
2 g of a polyester sample prepared according to JIS K 7367-1 was dissolved in 25 ml of o-chlorophenol and measured at 25 ° C.
4. Measurement of heat shrinkage
The film was cut into 300 mm in the longitudinal direction and 200 mm in the lateral direction, and then heat-treated in a hot air oven maintained at 150 ° C. for 30 minutes, and the length thereof was measured. The heat shrinkage was measured according to Equation 2 below.
(2)
Thermal contraction rate (%) = 100 X (length before heat treatment-length after heat treatment) / (length before heat treatment)
5. Formability Measurement
The moldability was visually determined with a compression molding machine while the molding temperature was changed from 80 ° C. to 160 ° C., and measured in the following grades.
(Double-circle): It shape | molds to the corner part clearly, and the thickness uniformity after molding is favorable.
(Circle): It was shape | molded a little round to corner part, and the thickness uniformity after molding is favorable.
(Triangle | delta): It shape | molded a little round to the corner part, and thickness uniformity is somewhat bad after molding.
X: Wrinkles and whitening occurred after molding, and thickness uniformity was poor.
(MPa)
(%)
(MPa)
(%)
As shown in Tables 1 and 2, the polyester film has a ratio of the stretching ratio in the transverse direction to the longitudinal direction of 0.90 to 1.1 and the ratio of the stretching temperature in the transverse direction to the longitudinal direction of 0.85 to 1.15. By achieving low strength, high elongation and high elongation balance in a random direction to be desired, excellent moldability can be secured, whereas moldability is significantly degraded when out of the stretching range or excessive stretching. have.
It is to be understood that the present invention is not limited to the above embodiments and various changes and modifications may be made by those skilled in the art without departing from the spirit and scope of the invention.
The biaxially stretched polyester film having excellent moldability according to the present invention has a lower tensile strength and higher elongation at break than the conventional polyester film, so that the deformation stress at the time of molding is low, so that the thermoforming to the desired shape is easy. In particular, it is balanced in strength in a random direction and has excellent molding uniformity. It is used not only for the surface coating of various industrial materials, packaging materials, building materials, base films and various containers, but also for molding and printing at the same time. It can also be utilized as a support film for molding.
Claims (7)
Stretched 2.0-4.5 times in the longitudinal direction (MD) and 2.0-4.5 times in the transverse direction (TD),
Under the condition of a temperature of 25 ° C. and a relative humidity of 60%, a value defined by the following Equation 1 is 0.5 to 2.0, and the range of the value is 0 to 0.50,
(1)
Here, S Random is the film tensile strength (MPa) in the random direction, E Random is the film breaking elongation (%) in the random direction, biaxially stretched polyester film excellent in formability.
The biaxially stretched polyester film having excellent moldability includes an aromatic dicarboxylic acid component and an aliphatic glycol component, wherein the aromatic dicarboxylic acid component is dimethyl terephthalate, terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxyl. Acid, sebacic acid, adipic acid, diphenyldicarboxylic acid, 5- tert - butylisophthalic acid, 2,2,6,6-tetramethyldiphenyl-4,4'-dicarboxylic acid, 1,1 , 3-trimethyl-3-phenylindan-4,5-dicarboxylic acid, 5-sodium sulfoisophthalic acid, trimellitic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, pimeric acid, azelaic acid, pyro At least one selected from the group consisting of merit acid, 1,4-cyclohexanedicarboxylic acid and 1,3-cyclohexanedicarboxylic acid, wherein the aliphatic glycol component is ethylene glycol, neopentyl glycol, 1,4-cyclo In the group consisting of hexane dimethanol, diethylene glycol, propanediol and butanediol It is at least one selected, biaxially stretched polyester film excellent in formability.
The biaxially stretched polyester film having excellent moldability is characterized in that the tensile strength is 100 to 300Mpa, biaxially stretched polyester film excellent in moldability.
The elongation at break of the biaxially stretched polyester film excellent in moldability is 150 to 300%, wherein the biaxially stretched polyester film excellent in moldability.
The biaxially stretched polyester film having excellent moldability is characterized in that the ratio of the stretching ratio in the transverse direction to the longitudinal direction is 0.90 to 1.1, and the ratio of the stretching temperature in the transverse direction to the longitudinal direction is 0.85 to 1.15. Excellent biaxially stretched polyester film.
A first step of melting and extruding a polyester composition comprising an aromatic dicarboxylic acid component and an aliphatic glycol component at a crystal melting temperature of + 10 ° C. to 60 ° C. to produce an unstretched sheet;
A second step of stretching the unstretched sheet 2.0 times to 4.5 times in the longitudinal direction (MD) and 2.0 times to 4.5 times in the transverse direction (TD) at a temperature above the glass transition temperature;
And a third step of heat-treating the stretched film at a glass transition temperature of + 10 ° C to 250 ° C for 5 seconds to 60 seconds.
The ratio of the stretching ratio in the transverse direction to the longitudinal direction in the second step is 0.90 to 1.1, the ratio of the stretching temperature in the transverse direction to the longitudinal direction is 0.85 to 1.15, excellent biaxially stretched poly Method for producing an ester film.
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| WO2019235693A1 (en) * | 2018-06-07 | 2019-12-12 | 도레이첨단소재 주식회사 | Biaxially oriented polyester reflective film and method for manufacturing same |
| KR102401632B1 (en) | 2020-11-30 | 2022-05-26 | 명성티엔에스주식회사 | Apparatus for biaxially-oriented polyester film |
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| WO2018221944A1 (en) | 2017-05-31 | 2018-12-06 | 에스케이케미칼 주식회사 | Polyester resin, method for preparing same, and resin molded product formed therefrom |
| KR102568694B1 (en) | 2017-06-22 | 2023-08-22 | 에스케이케미칼 주식회사 | Polyester container and preparation method thereof |
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| KR20050036251A (en) * | 2003-10-15 | 2005-04-20 | 에스케이씨 주식회사 | Biaxial oriented polyester film |
| JP2009145450A (en) * | 2007-12-12 | 2009-07-02 | Toyobo Co Ltd | Surface light-diffusing polyester film |
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|---|---|---|---|---|
| JP2001354843A (en) * | 2000-06-14 | 2001-12-25 | Unitika Ltd | Biaxially stretched polyester film for molding |
| JP2003251694A (en) * | 2002-03-06 | 2003-09-09 | Teijin Dupont Films Japan Ltd | Polyester film for agriculture |
| KR20050036251A (en) * | 2003-10-15 | 2005-04-20 | 에스케이씨 주식회사 | Biaxial oriented polyester film |
| JP2009145450A (en) * | 2007-12-12 | 2009-07-02 | Toyobo Co Ltd | Surface light-diffusing polyester film |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019235693A1 (en) * | 2018-06-07 | 2019-12-12 | 도레이첨단소재 주식회사 | Biaxially oriented polyester reflective film and method for manufacturing same |
| US11602926B2 (en) | 2018-06-07 | 2023-03-14 | Toray Advanced Materials Korea Inc. | Biaxial oriented polyester reflection film and manufacturing method thereof |
| KR102401632B1 (en) | 2020-11-30 | 2022-05-26 | 명성티엔에스주식회사 | Apparatus for biaxially-oriented polyester film |
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| KR20120072484A (en) | 2012-07-04 |
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