KR101151887B1 - Fire retardant paint - Google Patents
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- KR101151887B1 KR101151887B1 KR1020120007272A KR20120007272A KR101151887B1 KR 101151887 B1 KR101151887 B1 KR 101151887B1 KR 1020120007272 A KR1020120007272 A KR 1020120007272A KR 20120007272 A KR20120007272 A KR 20120007272A KR 101151887 B1 KR101151887 B1 KR 101151887B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
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Abstract
Description
본 발명은 방염 페인트에 관한 것으로, 코팅면에 균열이 발생하지 않아 내화 및 방염성이 우수하고, 유해가스를 발생시키지 않아, 인체에 해롭지 않는 방염 페인트에 관한 것이다.The present invention relates to a flame retardant paint, which is excellent in fire resistance and flame retardancy due to no cracking on the coating surface, and does not generate harmful gases, and thus relates to a flame retardant paint that is not harmful to the human body.
일반적으로 산업플랜트에서 사용되는 산업설비자재는 높은 열원에 노출되어 있다. 특히 제철, 철강 및 석유화학 분야에서 사용되는 산업설비는 공정 구조상에 고온의 열에 접촉되어 빠르게 노후화되는 한편, 열을 외부에 전달하는 역할을 하여 열손실을 야기하며, 그곳에서 일하는 노동자들 역시 그로 인해 악조건에서의 작업환경에 노출될 수밖에 없다.In general, industrial equipment materials used in industrial plants are exposed to high heat sources. In particular, industrial facilities used in the steel, steel and petrochemical sectors are rapidly aging due to high temperature heat in the process structure, and serve to transfer heat to the outside, causing heat loss. It can only be exposed to the working environment under adverse conditions.
따라서 이러한 문제를 해결할 수 있는 페인트를 개발이 꾸준히 제기되어 오고 있다.Therefore, the development of paint that can solve this problem has been steadily raised.
또한 일반적으로 실내 건축에 사용되는 페인트는, 화재가 발생하였을 때 화재의 전이속도를 증가시키는 역할을 하고, 유독가스를 생성하여 많은 인명 피해를 발생시켜, 화재에 매우 취약하다.In addition, paints generally used in indoor construction play a role of increasing the speed of fire when a fire occurs, and generate toxic gas, causing a lot of human damage, and are very vulnerable to fire.
그리고 상기와 같이 화재가 발생할 시 건축 구조물로 높은 열이 전달되면, 열에 의해 구조물이 매우 약해지는 문제점이 발생한다.And when high heat is transferred to the building structure when a fire occurs as described above, the structure is very weak by the heat occurs.
이러한 점을 보완하기 위해 최근에는 물유리를 이용한 페인트가 사용되고 있다.Recently, paint using water glass has been used to compensate for this.
하지만 상기와 같이 물유리를 이용한 페인트는 균열이 발생하기 쉬웠다. However, as described above, paint using water glass was susceptible to cracking.
따라서 종래의 페인트는 높은 열에서도 건축 구조물의 내구성이 변하지 않도록 하는 데 많은 어려움이 있었으며, 실내 건축에 있어서 화재 시에 페인트에 의해 발생하는 유독가스를 미연에 방지하고, 화재 전이를 늦추는 데 문제점이 발생하였다.Therefore, the conventional paint has a lot of difficulties to prevent the durability of the building structure does not change even at high heat, and in indoor construction, there is a problem in preventing the toxic gas generated by the paint in case of fire and delaying the fire transition. It was.
또한 종래의 페인트는 산업설비자재에 코팅될 시, 산업설비 전반에서 발생하는 열원을 효과적으로 제어하고, 생산 작업현장의 환경을 개선하는데 한계가 있었다.In addition, when the conventional paint is coated on the industrial equipment materials, there is a limit to effectively control the heat source generated in the overall industrial equipment, and improve the environment of the production workplace.
본 발명은 상기와 같은 요구에 의해 발명된 것으로, 코팅면에 균열이 발생하지 않아 내화 및 방염성이 우수하고, 유해가스를 발생시키지 않아, 인체에 해롭지 않는 방염 페인트를 제공하는 것을 해결하려는 과제로 한다. The present invention has been invented according to the above-described requirements, and it is an object of the present invention to provide a flame-retardant paint which does not generate cracks on the coated surface, which is excellent in fire resistance and flame resistance, does not generate harmful gases, and is not harmful to the human body. .
상기와 같은 과제를 해결하기 위한 본 발명은, 방염 및 바인더 기능을 하는 물유리 42~48중량%와, 티타니아 29~38중량%와, 습도를 안정화시켜 도포 후 단시간에 갈라지는 것을 방지하는 퍼라이트 1~5중량% 및, 나머지 중량%의 물을 포함하는 것을 특징으로 한다.The present invention for solving the above problems, 42 to 48% by weight of water glass, flame retardant and binder function, 29 to 38% by weight of titania, and perlite 1 to 5 to stabilize the humidity to prevent cracking in a short time after application It is characterized by comprising a weight% and the remaining weight% of water.
또한 본 발명은, 물유리 45중량%와, 티타니아 34중량%와, 퍼라이트 2중량% 및, 나머지 중량%의 물을 포함하는 것을 특징으로 한다.The present invention is also characterized by containing 45% by weight of water glass, 34% by weight of titania, 2% by weight of perlite and the remaining weight% of water.
또한 본 발명은, 물유리가 규산나트륨인 것을 특징으로 한다.In addition, the present invention is characterized in that the water glass is sodium silicate.
상기와 같은 본 발명에 따르면, 코팅 후 장시간 균열이 발생하지 않아, 내열 내화성이 매우 우수하다. 따라서 본 발명은 화재가 발생할 시, 코팅 대상을 화염으로부터 안전하게 보호할 수 있으며, 화염 전이속도를 현저히 늦출 수 있어, 코팅 대상을 안전하게 보호할 수 있다.According to the present invention as described above, the crack does not occur for a long time after coating, it is very excellent in heat resistance fire resistance. Therefore, the present invention can safely protect the coating object from the fire when a fire occurs, can significantly slow the flame transition rate, it is possible to safely protect the coating object.
또한 본 발명은 퍼라이트가 함유됨로써, 화염이 코팅 대상에 전이되는 것을 효과적으로 지연시켜며, 화재시 유독가스가 거의 발생하지 않는 효과가 있다. 따라서 건축 구조물에 화재가 발생할 시, 대피할 수 있는 피난 시간을 확보할 수 있어, 대형 인명 피해를 막을 수 있는 한편, 환경에도 악영향을 끼치지 않는다.In addition, the present invention by containing the perlite, effectively delay the transition of the flame to the coating target, there is an effect that little toxic gas is generated in the event of fire. Therefore, when a fire breaks out in a building structure, it is possible to secure an evacuation time that can be evacuated, thereby preventing large-scale human damage, and not adversely affecting the environment.
그리고 본 발명은 코팅 후 장시간 균열이 발생하지 않기 때문에, 코팅 대상에 직접적으로 산소 또는 이물질 등이 접촉하지 않아, 내부식성이 향상되는 효과가 있다. 따라서 인테리어 마감재 등에 효과적으로 사용될 수 있다.In addition, since the present invention does not generate cracks for a long time after coating, oxygen or foreign matters do not directly contact the coating object, thereby improving corrosion resistance. Therefore, it can be effectively used for interior finishing materials.
도 1 내지 도 5는 본 발명의 효과를 설명하기 위한 이미지 도면이다.1 to 5 are image diagrams for explaining the effects of the present invention.
이하 첨부도면에 의거하여 본 발명을 설명하면 다음과 같다.Hereinafter, the present invention will be described with reference to the accompanying drawings.
본 발명에 따른 방염 페인트는, 물유리 42~48중량%와, 티타니아 29~38중량%, 퍼라이트 1~5중량%, 나머지 중량%의 물을 포함하며, 상기 물질들이 교반 혼합되어 이루어진다.The flame retardant paint according to the present invention comprises 42 to 48% by weight of water glass, 29 to 38% by weight of titania, 1 to 5% by weight of ferrite, and the remaining weight% of water, and the materials are mixed by stirring.
상기 물유리는, 물에 대해 용해성이 있는 규산염의 다른 이름으로, 알칼리금속이 실리카(SiO2)와 다양한 몰비로 결합한 화합물을 말한다. 물유리로는 규산나트륨, 규산칼륨, 리튬실리케이트 등이 있다. The water glass is another name for silicate that is soluble in water, and refers to a compound in which an alkali metal is bonded to silica (SiO 2) in various molar ratios. Water glass includes sodium silicate, potassium silicate, lithium silicate and the like.
상기 물유리는 친수성이 강한 알칼리금속을 함유하고 있어 점결력과 분산력이 우수하여 시멘트, 접착제, 코팅 등 다양한 용도로 사용되고 있다.The water glass contains alkali metals having a strong hydrophilicity and has excellent caking and dispersing power, and thus is used in various applications such as cement, adhesives, and coatings.
상기 티타니아는 이산화티타늄(TiO2)으로 불리우며, 일반적으로 도료로 사용된다. 본 실시예에서 티타니아는 파우더 형태를 이루는 것이 바람직하다.The titania is called titanium dioxide (TiO 2 ), and is generally used as a paint. In this embodiment, titania is preferably in the form of a powder.
상기 퍼라이트는, 진주암이라는 화산활동으로 생성된 천연광물을 고온으로 팽창시켜 생성된 일반적인 것이다. 이때 퍼라이트는 습도를 안정화시키는 기능을 하여 균열 발생을 방지한다. 본 실시예에서 퍼라이트는 파우더 형태를 이루는 것이 바람직하다.The perlite is a general one produced by expanding natural minerals produced by volcanic activity called pearlite at a high temperature. At this time, the ferrite functions to stabilize the humidity to prevent the occurrence of cracks. In this embodiment, the perlite is preferably in the form of a powder.
상기와 같은 구성물질의 혼합으로 이루어진 본 발명의 방염 페인트는, 코팅 후 장시간 균열이 발생하지 않아, 내열 내화성이 매우 우수하다.The flame retardant paint of the present invention made of a mixture of the above constituents does not generate cracks for a long time after coating, and is excellent in heat resistance and fire resistance.
따라서 본 발명은 화재가 발생할 시, 코팅 대상을 화염으로부터 안전하게 보호할 수 있으며, 화염 전이속도를 현저히 늦출 수 있어, 코팅 대상을 안전하게 보호할 수 있다.Therefore, the present invention can safely protect the coating object from the fire when a fire occurs, can significantly slow the flame transition rate, it is possible to safely protect the coating object.
또한 본 발명은 퍼라이트가 함유됨로써, 화염이 코팅 대상에 전이되는 것을 효과적으로 지연시켜며, 천연원료이므로 화재시 유독가스가 거의 발생하지 않는 효과가 있다. In addition, the present invention, by containing the perlite, effectively delays the transition of the flame to the coating target, and because it is a natural raw material, there is an effect that almost no toxic gas occurs in the fire.
따라서 건축 구조물에 화재가 발생할 시, 대피할 수 있는 피난 시간을 확보할 수 있어, 대형 인명 피해를 막을 수 있는 한편, 환경에도 악영향을 끼치지 않는다.Therefore, when a fire breaks out in a building structure, it is possible to secure an evacuation time that can be evacuated, thereby preventing large-scale human damage, and not adversely affecting the environment.
그리고 본 발명은 코팅 후 장시간 균열이 발생하지 않기 때문에, 코팅 대상에 직접적으로 산소 또는 이물질 등이 접촉하지 않아, 내부식성이 향상되는 효과가 있다. 따라서 인테리어 마감재 등에 효과적으로 사용될 수 있다.In addition, since the present invention does not generate cracks for a long time after coating, oxygen or foreign matters do not directly contact the coating object, thereby improving corrosion resistance. Therefore, it can be effectively used for interior finishing materials.
상기와 같이 본 발명은 다양한 효과가 있다. 따라서 본 발명이 산업 구조물에 사용될 시, 작업자의 우수한 작업환경 및 안전을 확보할 수 있고, 실내 건축 구조물에 사용될 시, 사용자의 우수한 생활환경 및 안전을 확보할 수 있는 부수적인 효과가 있다.As described above, the present invention has various effects. Therefore, when the present invention is used in an industrial structure, it is possible to secure an excellent working environment and safety of the worker, and when used in an indoor building structure, there is a side effect of ensuring an excellent living environment and safety of the user.
이하 하기와 같은 실시예를 통하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail through the following examples.
[실시예][Example]
본 발명의 방염 페인트는, 규산나트륨 42~48g와, 티타니아 파우더 29~38g과, 퍼라이트 파우더 1~5g과, 나머지로 물을 포함하며, 상기 물질들이 교반 혼합되어 이루어진다. The flame retardant paint of the present invention comprises 42-48 g of sodium silicate, 29-38 g of titania powder, 1-5 g of perlite powder, and water as the remainder, and the materials are stirred and mixed.
이때 상기 티타니아 파우더는 다양한 페인트와 코팅재료로 사용된다.The titania powder is used in various paints and coating materials.
일반적으로 방염을 위해 물유리 바탕에 바인더로 만든 페인트가 목조 등의 코팅용으로 사용된다.In general, paint made of a binder on a water glass substrate is used for coating such as wood for flame prevention.
하지만 이러한 물유리 바탕의 코팅물은 짧은 시간에 균열이 발생하는 문제점이 있다.However, such a water-based coating has a problem that cracks occur in a short time.
본 실시예의 방염 페인트의 경우, 퍼라이트 파우더가 함유됨으로써, 철판, 벽돌, 나무 등에 방염 페인트가 코팅될 시, 장시간 동안 방염 페인트의 코팅면에 균열이 발생하지 않는다.In the case of the flame-retardant paint of the present embodiment, by containing the perlite powder, when the flame-retardant paint is coated on the iron plate, brick, wood, etc., no crack occurs on the coating surface of the flame-retardant paint for a long time.
아래 표 1은 퍼라이트가 포함되지 않은 페인트(A) 및 본 발명의 방염 페인트(B)를 세라믹판?벽돌?알루미늄판?나무에 코팅한 후, 건조 보관하였을 경우, 균열이 발생하기 시작하는 시점을 나타낸 표이다.Table 1 below shows the time when cracks start to occur when the paint (A) and the flame retardant paint (B) of the present invention are coated on a ceramic plate, a brick, an aluminum plate, and wood after drying, and are kept dry. Table shown.
또한 도 1 내지 4은 세라믹판?벽돌?알루미늄판?나무에 본 발명의 방염 페인트를 코팅 한 후, 30일 경과 후 균열이 발생하지 않은 상태를 나타낸 이미지이다.In addition, Figures 1 to 4 are images showing a state in which no crack occurs after 30 days after coating the flame retardant paint of the present invention on a ceramic plate, a brick, an aluminum plate, and a tree.
상기 표 1 및 도 1 내지 도 4를 살펴보면, 본 발명의 방염 페인트는 퍼라이트가 포함되지 않은 페인트에 비해 코팅 대상에 코팅되었을 시, 균열이 쉽게 발생하지 않고, 균열 발생 시점도 현저히 늦춰지는 것을 확인할 수 있다.Looking at the Table 1 and Figures 1 to 4, when the flame-retardant paint of the present invention is coated on the coating target compared to the paint does not contain a perlite, it is confirmed that the crack is not easily generated, the cracking time is also significantly delayed. have.
특히 본 발명은 목재에 코팅될 경우, 목재와 수분을 교환함으로써, 균열 발생이 방지된다. 이는 목재는 자연조건에서 우기 및 밤에 대기 중에서 수분을 흡수하고, 건기와 낮에 수분을 방출하여, 스스로 습도를 조절하는데, 이러한 과정에서 본 발명의 방염 페인트와 상호 작용하면서 방염 페인트에 균열이 발생하지 않는 것이다. 이때 퍼라이트는 습도를 안정화시키는 기능을 하여, 방염 페인트에 균열이 발생하지 않도록 선기능을 한다.In particular, the present invention, when coated on wood, by exchanging moisture with wood, the occurrence of cracking is prevented. The wood absorbs moisture in the atmosphere during the rainy season and at night under natural conditions, and releases moisture during the dry and during the day, thereby controlling the humidity on its own. It is not. At this time, the ferrite functions to stabilize the humidity, so as to prevent the occurrence of cracks in the flame retardant paint.
따라서 본 발명이 코팅된 코팅 대상은 화재가 발생했을 시, 화염의 전이속도가 늦어진다. Therefore, the coating object coated with the present invention, when a fire occurs, the flame transfer rate is slow.
즉 상기 코팅 대상의 코팅 면에 균열이 없기 때문에, 코팅 대상의 코팅 면에 접촉하는 화염은 코팅 대상에 쉽게 접근하지 못한다. 그러면 상기 코팅 대상은 화염으로부터 오랜 기간 보호받을 수 있으며, 이를 통해 자체 물성 등이 쉽게 변화되지 않는다.That is, since there is no crack in the coating surface of the coating target, the flame in contact with the coating surface of the coating target does not easily approach the coating target. Then, the coating target can be protected from the flame for a long time, through which the physical properties of the self are not easily changed.
또한 본 발명의 방염 페인트는 코팅 후 장시간 균열이 발생하지 않기 때문에, 코팅 대상에 직접적으로 산소 또는 이물질 등이 접촉하지 않아, 내부식성이 향상되는 효과가 있다. In addition, since the flame-resistant paint of the present invention does not generate cracks for a long time after coating, oxygen or foreign matters do not directly contact the coating object, thereby improving the corrosion resistance.
한편 상기 도 5(a)는 본 발명의 방염페인트가 코팅된 철판의 이미지이고, 도 5(b)는 본 발명의 방염페인트를 코팅한 철판을 전기를 통해 1100℃의 열을 가한 상태를 나타낸 이미지이고, 도 5(c)는 본 발명의 방염페인트를 코팅한 철판을 전기를 통해 1200℃의 열을 가한 상태를 나타낸 이미지이고, 도 5(d)는 본 발명의 방염페인트를 코팅한 철판을 전기를 통해 1300℃의 열을 가한 상태를 나타낸 이미지로서, 도 5를 참조하면, 본 발명의 방염페인트를 도포한 철판은 내열 내화성이 매우 향상되는 것을 알 수 있다.On the other hand, Figure 5 (a) is an image of the iron plate coated with a flame-retardant paint of the present invention, Figure 5 (b) is an image showing the state of applying heat of 1100 ℃ through the iron plate coated with the flame-retardant paint of the present invention 5 (c) is an image showing a state in which heat is applied at 1200 ° C. through the iron plate coated with the flame retardant paint of the present invention, and FIG. 5 (d) shows the iron plate coated with the flame retardant paint of the present invention. As an image showing the state of applying heat of 1300 ℃ through, referring to Figure 5, it can be seen that the iron plate coated with the flame-retardant paint of the present invention is very improved in heat resistance fire resistance.
한편 본 발명의 방염 페인트는, 규산나트륨 45g과, 티타니아 파우더 34g과, 퍼라이트 파우더 2g 및, 물 19g이 혼합되어도 상기 실시예와 같은 동일한 효과가 발생되었다.On the other hand, the flame-retardant paint of this invention produced the same effect similar to the said Example even if 45 g of sodium silicates, 34 g of titania powders, 2 g of perlite powders, and 19 g of water were mixed.
Claims (3)
42 to 48% by weight of water glass that functions as flame retardant and binder, 29 to 38% by weight of titania, 1 to 5% by weight of ferrite to stabilize the humidity and prevent cracking in a short time after application, and remaining weight% of water Flame retardant paint, characterized in that.
상기 물유리 45중량%와, 티타니아 34중량%와, 퍼라이트 2중량% 및, 나머지 중량%의 물을 포함하는 것을 특징으로 하는 방염 페인트.The method of claim 1,
Flame-resistant paint comprising 45% by weight of the water glass, 34% by weight of titania, 2% by weight of perlite, and the remaining weight% of water.
상기 물유리는 규산나트륨인 것을 특징으로 하는 방염 페인트.The method according to claim 1 or 2,
The water glass is flame retardant paint, characterized in that sodium silicate.
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CN113755044A (en) * | 2021-09-09 | 2021-12-07 | 深圳市广田环保涂料有限公司 | Pure inorganic non-combustible water-based sound insulation damping coating and preparation and use method thereof |
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KR100305908B1 (en) | 1999-06-02 | 2001-09-13 | 손연호 | Fireproofing and sound-absorbing composition |
JP2006307124A (en) | 2005-05-02 | 2006-11-09 | Kyushu Hi-Tech:Kk | Ordinary temperature-curable inorganic coating film and coating agent |
KR100770075B1 (en) | 2001-10-04 | 2007-10-24 | 닛데츠 고교 가부시키가이샤 | Powder coated with titania film and method for production thereof |
KR101064239B1 (en) | 2011-08-16 | 2011-09-14 | 유기자 | Composite of water-soluble paint for antifouling and manufacturing process of the same |
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KR100305908B1 (en) | 1999-06-02 | 2001-09-13 | 손연호 | Fireproofing and sound-absorbing composition |
KR100770075B1 (en) | 2001-10-04 | 2007-10-24 | 닛데츠 고교 가부시키가이샤 | Powder coated with titania film and method for production thereof |
JP2006307124A (en) | 2005-05-02 | 2006-11-09 | Kyushu Hi-Tech:Kk | Ordinary temperature-curable inorganic coating film and coating agent |
KR101064239B1 (en) | 2011-08-16 | 2011-09-14 | 유기자 | Composite of water-soluble paint for antifouling and manufacturing process of the same |
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