KR101141263B1 - ADHESIVE MATERIALS OF WC-Fe BASED HARD METAL AND MANUFACTURING METHOD OF THE SAME - Google Patents

ADHESIVE MATERIALS OF WC-Fe BASED HARD METAL AND MANUFACTURING METHOD OF THE SAME Download PDF

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KR101141263B1
KR101141263B1 KR1020090095338A KR20090095338A KR101141263B1 KR 101141263 B1 KR101141263 B1 KR 101141263B1 KR 1020090095338 A KR1020090095338 A KR 1020090095338A KR 20090095338 A KR20090095338 A KR 20090095338A KR 101141263 B1 KR101141263 B1 KR 101141263B1
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cemented carbide
bonding
weight
base material
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KR20110037774A (en
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손인진
박나라
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김기열
전북대학교산학협력단
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/32—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
    • B23K35/327—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C comprising refractory compounds, e.g. carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
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    • B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/02—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
    • B22F7/04—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers with one or more layers not made from powder, e.g. made from solid metal

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Abstract

본 발명은 WC-Fe계 초경합금이 철계 합금인 모재에 직접 접합된 접합재료 및 이의 제조방법에 관한 것이다.The present invention relates to a joining material and a method for manufacturing the bonded cemented carbide is directly bonded to the base material of the iron alloy.

본 발명의 WC-Fe계 초경합금 접합재료는, 철계 합금인 모재부; 및 상기 모재에 접합되며, Fe 5 내지 40중량%, 상기 Fe와 고용체를 형성하는 원소 1 내지 10중량%, 그리고 다른 소재와의 접합부위의 젖음성을 향상시키는 물질 0.1 내지 3중량%, 그리고 잔부가 WC인 초경합금부로 이루어지는 것을 특징으로 한다.WC-Fe cemented carbide alloy bonding material of the present invention, the base material portion is an iron-based alloy; And 5 to 40% by weight of Fe, 5 to 40% by weight of Fe, 1 to 10% by weight of an element forming a solid solution with Fe, and 0.1 to 3% by weight of a material for improving the wettability of the bonding portion with other materials. WC is a cemented carbide section.

이때, 상기 모재부와 상기 초경합금부의 접촉면에, 상기 모재부와 상기 초경합금부 상호간의 확산에 의하여 형성된 접합부를 포함하는 것을 특징으로 한다.At this time, the base material portion and the cemented carbide portion, the contact surface is characterized in that it comprises a junction formed by the diffusion between the base material portion and the cemented carbide portion.

본 발명에 따르면, 가격이 저렴한 Fe를 초경합금의 바인더로 사용함으로써, 초경합금 접합재료의 생산비용을 크게 감소시킬 수 있는 효과가 있다.According to the present invention, by using Fe, which is inexpensive, as a binder of cemented carbide, it is possible to greatly reduce the production cost of cemented carbide cemented material.

또한 기존의 간단한 가열장치만으로 초경합금을 모재에 직접 접합함으로써, 낮은 온도에서도 접합성이 우수한 접합재료를 제조할 수 있는 효과가 있다.In addition, by bonding the cemented carbide directly to the base material using only the existing simple heating device, there is an effect that can be produced a bonding material excellent bonding properties even at low temperatures.

WC-Fe, 초경합금, 소결, 접합, 접합재료 WC-Fe, cemented carbide, sintering, bonding, joining materials

Description

ＷＣ?Ｆｅ계 초경합금 접합재료 및 이의 제조방법{ADHESIVE MATERIALS OF WC-Fe BASED HARD METAL AND MANUFACTURING METHOD OF THE SAME}BFC-based cemented carbide bonding material and its manufacturing method {ADHESIVE MATERIALS OF WC-Fe BASED HARD METAL AND MANUFACTURING METHOD OF THE SAME}

본 발명은 초경합금 접합재료에 관한 것이며, 더욱 자세하게는 WC-Fe계 초경합금이 철계 합금인 모재에 직접 접합된 접합재료 및 이의 제조방법에 관한 것이다.The present invention relates to a cemented carbide joining material, and more particularly, to a joining material in which a WC-Fe cemented carbide is directly bonded to a base material of an iron alloy and a method of manufacturing the same.

초경합금이란 경도가 매우 높은 WC가 인성이 좋은 Co나 Ni에 분산된 형태의 재료이다. 따라서 경도와 동시에 인성이 좋기 때문에 현재 절삭공구, 인발다이, 노즐 및 금형에 활용되고 있다.Cemented carbide is a material in which WC having high hardness is dispersed in Co or Ni having good toughness. Therefore, it is used in cutting tools, drawing dies, nozzles and molds because of its hardness and toughness.

일반적으로 초경합금은 그 자체만으로 사용되기 보다는 철계 합금, 특히 탄소강인 모재의 표면에 접합하여, 자동차용 타펫의 재료로 사용된다. 이러한 접합에 사용되는 방법으로는 브레이징용 용가재 금속을 이용하는 것이 일반적다. 브레이징을 통하여 접합한 경우에 용가재 금속이 초경합금 및 모재와의 접합성이 모두 우수한 재료를 사용하여야 하며, 용가재 금속 자체의 강도와 내충격성 등의 기계적 성질이 좋아하므로 이를 만족하는 재료를 찾기 어려워 만족할 만한 특성을 나타내 지 못하고 있는 실정이다.In general, cemented carbide is used as a material for automobile tappets by bonding to the surface of the base metal, which is an iron-based alloy, especially carbon steel, rather than being used alone. As a method used for such joining, it is common to use a brazing filler metal. In the case of joining through brazing, the filler metal should be made of both cemented carbide and the base metal, and the mechanical properties such as strength and impact resistance of the filler metal itself are good. This situation is not represented.

최근에는 브레이징을 통한 접합의 문제를 해결하기 위한 노력이 계속되고 있으나, 이러한 초경합금 접합재료의 대부분은 고가인 Ni 또는 Co를 바인더로 사용하고 있어, 생산단가가 매우 높다는 단점을 해결하지 못하고 있다.Recently, efforts have been made to solve the problem of bonding through brazing. However, most of the cemented carbide bonding materials use expensive Ni or Co as a binder, and thus do not solve the disadvantage of very high production cost.

따라서 브레이징 접합의 문제를 해결하면서도 초경합금의 생산비용을 줄일 수 있는 새로운 방법에 대한 관심이 높다.Therefore, there is a great interest in new ways to reduce the cost of producing cemented carbide while solving the problem of brazing bonding.

본 발명은 상기 문제점을 해결하기 위하여 발명된 것으로서, 가격이 저렴한 Fe를 바인더로 사용하고, 접합성을 향상시키기 위한 물질을 첨가한 WC-Fe계 초경합금을 직접 접합한 접합재료 및 이를 제조하는 방법을 제공하는 것이 목적이다.The present invention has been invented to solve the above problems, using a low-cost Fe as a binder, and provides a bonding material directly bonded to the WC-Fe-based cemented carbide added with a substance for improving the bonding property and a method of manufacturing the same The purpose is to.

상기 목적을 달성하기 위한 본 발명의 WC-Fe계 초경합금 접합재료는, 철계 합금인 모재부; 및 상기 모재에 접합되며, Fe 5 내지 40중량%, 상기 Fe와 고용체를 형성하는 원소 1 내지 10중량%, 그리고 다른 소재와의 접합부위의 젖음성을 향상시키는 물질 0.1 내지 3중량%, 그리고 잔부가 WC인 초경합금부로 이루어지는 것을 특징으로 한다. WC-Fe-based cemented carbide bonding material of the present invention for achieving the above object, the base material portion is an iron-based alloy; And 5 to 40% by weight of Fe, 5 to 40% by weight of Fe, 1 to 10% by weight of an element forming a solid solution with Fe, and 0.1 to 3% by weight of a material for improving the wettability of the bonding portion with other materials. WC is a cemented carbide section.

이때, 상기 모재부와 상기 초경합금부의 접촉면에, 상기 모재부와 상기 초경합금부 상호 간의 확산에 의하여 형성된 접합부를 포함하는 것을 특징으로 한다.At this time, the base material portion and the cemented carbide portion, the contact surface, characterized in that it comprises a junction formed by the diffusion between the base material portion and the cemented carbide portion.

Fe와 고용체를 형성하는 원소는 Si, Ni 및 Cr로 이루어지는 군에서 선택되는 어느 하나 이상이다. 또 젖음성을 향상시키는 원소는 B, C, B4C 및 B2O3로 이루어지는 군에서 선택되는 어느 하나 이상이다. The element which forms a solid solution with Fe is at least one selected from the group consisting of Si, Ni, and Cr. Also elements for improving wettability is at least one selected from the group consisting of B, C, B 4 C and B 2 O 3.

그리고 초경합금부의 입자 성장 억제를 위한 화합물로서 Cr3C2 및 VC로 이루어진 군에서 선택되는 어느 하나 이상이 더 첨가될 수 있으며, 입자 성장 억제를 위한 화합물의 첨가량은 0.5 내지 2 중량%이다. And one or more selected from the group consisting of Cr 3 C 2 and VC can be added as a compound for inhibiting the grain growth of the cemented carbide portion, the amount of the compound for inhibiting grain growth is 0.5 to 2% by weight.

또 본 발명에서는 아래 단계로 이루어지는 WC-Fe계 초경합금 접합재료의 제조방법을 제공한다.In addition, the present invention provides a method for producing a WC-Fe-based cemented carbide bonding material comprising the following steps.

Fe 5 내지 40중량%, 상기 Fe와 고용체를 형성하는 원소 1 내지 10중량%, 그리고 다른 소재와의 접합부위의 젖음성을 향상시키는 물질 0.1 내지 3중량%, 및 잔부가 WC로 이루어지는 원료를 이용하여 초경합금을 제조하는 단계;5 to 40% by weight of Fe, 1 to 10% by weight of the element forming the solid solution with Fe, and 0.1 to 3% by weight of a material for improving the wettability of the joint portion with other materials, and the remainder is WC Preparing a cemented carbide;

상기 제조된 초경합금을 철계 합금인 모재와 접촉시키고 가열하여 초경합금을 모재에 직접 접합시키는 단계; 및Contacting the manufactured cemented carbide with a base metal, which is an iron-based alloy, and heating the cemented carbide to directly bond the cemented carbide to the base metal; And

상기 직접 접합된 재료를 냉각하는 단계.Cooling the directly bonded material.

이때, 상기 초경합금을 제조하는 단계는, 상기 초경합금의 조성에 따른 원료분말을 혼합하는 단계; 상기 혼합된 원료분말을 건조시키는 단계; 상기 건조된 원료분말을 성형체로 성형하는 단계; 상기 성형체를 소결하는 단계; 및 소결된 합금을 냉각하는 단계를 포함하는 소결 방법인 것이 좋다.At this time, the step of manufacturing the cemented carbide, the step of mixing the raw powder according to the composition of the cemented carbide; Drying the mixed raw powder; Molding the dried raw material powder into a molded body; Sintering the molded body; And a step of cooling the sintered alloy.

초경합금을 제조하는 단계 중, 원료분말을 혼합하는 단계에서 WC 분말은 입자가 크면 기계적 성질과 균일혼합에 나쁜 영향을 주기 때문에, 0.1 내지 10㎛가 바람직하다. 반면 입자가 작을수록 가격이 비싸지는 문제가 있다. 더욱 바람직한 WC 입자크기는 0.1 내지 2㎛ 이하이다.In the step of preparing cemented carbide, WC powder in the step of mixing the raw powder is preferably 0.1 to 10㎛ because large particles adversely affect the mechanical properties and homogeneous mixing. On the other hand, the smaller the particle, the more expensive the problem. More preferred WC particle size is 0.1 to 2 mu m or less.

초경합금을 제조하는 단계 중, 원료분말을 성형하는 단계는 10~1000㎫ 압력에서 이루어지는 것이 바람직하다. 상기 압력 범위가 10㎫ 미만일 경우에는 시편을 충분히 성형할 수 없는 문제점이 있으며, 1000㎫를 초과할 경우에는 성형 장치제작 비용이 많이 소요되는 문제점이 있다.Among the steps of preparing cemented carbide, the step of molding the raw powder is preferably performed at a pressure of 10 to 1000 MPa. When the pressure range is less than 10 MPa, there is a problem in that the specimen cannot be sufficiently formed, and when it exceeds 1000 MPa, there is a problem in that the manufacturing cost of the molding apparatus is high.

또한, 초경합금을 제조하는 단계 중, 성형체를 소결하는 단계는 1000~1200℃ 온도에서 1시간 가열하는 것이 바람직하며, 소결을 위한 가열속도는 1~1000℃/min이 바람직하다. 가열속도가 1℃/min 미만일 경우에는 소결하는 시간이 많이 걸려서 결정립이 성장하는 문제점이 발생할 수 있고, 1000℃/min을 초과할 경우에는 가열속도가 너무 빨라서 시편에 열 응력이 발생하는 문제점이 있기 때문이다.In addition, during the step of manufacturing a cemented carbide, the step of sintering the molded body is preferably heated for 1 hour at 1000 ~ 1200 ℃ temperature, the heating rate for the sintering is preferably 1 ~ 1000 ℃ / min. If the heating rate is less than 1 ℃ / min may take a long time to sinter the grain growth may occur, and if the heating rate exceeds 1000 ℃ / min there is a problem that the thermal stress occurs in the specimen is too fast Because.

초경합금을 제조하는 단계 중, 소결된 합금을 냉각하는 단계는 10~1000℃/min의 속도로 이루어지는 것이 바람직하다. 본 발명에서 WC-Fe계 초경합금을 상온으로 냉각하는 단계는 통상의 방법에 따라 실시할 수 있다.Of the cemented carbide manufacturing step, the step of cooling the sintered alloy is preferably made at a rate of 10 ~ 1000 ℃ / min. In the present invention, the step of cooling the WC-Fe-based cemented carbide to room temperature may be carried out according to a conventional method.

Fe와 고용체를 형성하는 원소는 Si, Ni 및 Cr로 이루어지는 군에서 선택되는 어느 하나 이상이다. 또 젖음성을 향상시키는 원소는 B, C, B4C 및 B2O3로 이루어지는 군에서 선택되는 어느 하나 이상이다. The element which forms a solid solution with Fe is at least one selected from the group consisting of Si, Ni, and Cr. Also elements for improving wettability is at least one selected from the group consisting of B, C, B 4 C and B 2 O 3.

또, 초경합금을 제조하는 단계에서 입자 성장 억제를 위한 화합물로서 Cr3C2 및 VC로 이루어진 군에서 선택되는 어느 하나 이상의 원료가 더 이용될 수 있으며, 입자 성장 억제를 위한 화합물의 첨가량은 0.5 내지 2 중량%이다. In addition, any one or more raw materials selected from the group consisting of Cr 3 C 2 and VC may be further used as a compound for inhibiting grain growth in the manufacture of cemented carbide, and the amount of the compound for inhibiting grain growth may be 0.5 to 2 Weight percent.

그리고 초경합금을 모재에 직접 접합시키는 단계는 1000~1300℃의 온도에서 10~120분 동안 이루어지는 것이 바람직하며, 가열속도는 1~1000℃/min이 바람직하다. 가열속도가 1℃/min 미만일 경우에는 접합하는 시간이 너무 많이 걸리는 문제점이 발생할 수 있고, 1000℃/min을 초과할 경우에는 가열속도가 너무 빨라서 시편에 열응력이 발생하는 문제점이 있기 때문이다.And the step of bonding the cemented carbide directly to the base material is preferably made for 10 to 120 minutes at a temperature of 1000 ~ 1300 ℃, the heating rate is preferably 1 ~ 1000 ℃ / min. If the heating rate is less than 1 ℃ / min may cause a problem that takes too much time to bond, if the heating rate is too fast if the heating rate is too fast if the specimen has a problem that the thermal stress occurs.

직접 접합된 재료를 냉각하는 단계는 1～1000℃/min의 속도로 이루어지는 것이 바람직하다. 본 발명의 WC-Fe계 초경합금의 접합재료를 상온으로 냉각하는 단계는 통상의 방법에 따라 실시할 수 있다.The step of cooling the directly bonded material is preferably made at a rate of 1 ~ 1000 ℃ / min. The step of cooling the bonding material of the WC-Fe-based cemented carbide of the present invention to room temperature may be carried out according to a conventional method.

특히, 초경합금을 모재에 직접 접합시키는 단계는 상기 제조된 초경합금의 위에 상기 모재를 위치시킨 상태에서 이루어지는 것이 바람직하다. 철계 합금인 모재를 제조된 초경합금의 위에 위치시킴으로써, 별도의 압력수단이 없이도 모재 자체의 무게로 인하여 접촉면에 압력을 가하는 효과를 얻을 수 있다. 또한 소결과정을 통하여 초경합금을 제조한 경우에, 초경합금을 가열로에 그대로 위치시킨 상태에서 그 위에 모재를 위치시키는 간단한 방법으로 가열을 위한 준비가 완료된다.In particular, the step of directly bonding the cemented carbide to the base material is preferably made in the state of placing the base material on the prepared cemented carbide. By placing the base material of the iron-based alloy on the manufactured cemented carbide, it is possible to obtain the effect of applying pressure to the contact surface due to the weight of the base material itself without a separate pressure means. In addition, when the cemented carbide is manufactured through the sintering process, the preparation for heating is completed by a simple method of placing the base metal on the cemented carbide in the furnace.

본 발명에 따르면, 가격이 저렴한 Fe를 초경합금의 바인더로 사용함으로써, 초경합금 접합재료의 생산비용을 크게 감소시킬 수 있는 효과가 있다.According to the present invention, by using Fe, which is inexpensive, as a binder of cemented carbide, it is possible to greatly reduce the production cost of cemented carbide cemented material.

또한 기존의 간단한 가열장치만으로 초경합금을 모재에 직접 접합함으로써, 낮은 온도에서도 접합성이 우수한 접합재료를 제조할 수 있는 효과가 있다.In addition, by bonding the cemented carbide directly to the base material using only the existing simple heating device, there is an effect that can be produced a bonding material excellent bonding properties even at low temperatures.

본 발명의 바람직한 실시예를 첨부된 도면을 참조하여 상세히 설명하면 다음과 같다. Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 실시예에 따른 초경합금 접합재료의 제조과정을 나타내는 순서도이고, 도 2는 도 1의 과정을 따라서 초경합금 접합재료를 제조하는 모습을 나타내는 모식도이다. 1 is a flow chart showing a manufacturing process of cemented carbide bonding material according to the present embodiment, Figure 2 is a schematic diagram showing a state of manufacturing a cemented carbide cemented material according to the process of FIG.

본 실시예에 따른 초경합금 접합재료의 제조과정은 먼저 WC-Fe계 초경합금을 제조하는 단계, 제조된 WC-Fe계 초경합금과 모재를 별도의 접합재료 없이 직접 접촉시킨 상태에서 가열하는 단계, 및 냉각하는 단계를 포함하여 구성된다.The manufacturing process of cemented carbide cemented material according to the present embodiment comprises the steps of first manufacturing a WC-Fe cemented carbide, heating the prepared WC-Fe cemented carbide and the base material in direct contact without a separate bonding material, and cooling It consists of steps.

초경합금을 제조하는 방법은 다양하지만, 본 실시예에서는 일반적으로 사용되는 소결방법을 이용하여 WC-Fe계 초경합금(10)을 제조하였다.Although there are various methods of manufacturing cemented carbide, in the present embodiment, WC-Fe based cemented carbide 10 was manufactured by using a sintering method which is generally used.

먼저 입자크기가 각각 0.8㎛인 텅스텐 카바이드, 10㎛ 미만인 철, 7.5㎛인 실리콘 및 1.0㎛인 보론카바이드 원료분말 15g을 준비하고, 이들 원료분말을 에탄올을 이용하여 24시간 동안 습식 밀링하여 혼합하였다. First, 15 g of tungsten carbide having a particle size of 0.8 μm, iron less than 10 μm, silicon having 7.5 μm, and boron carbide raw material having 1.0 μm were prepared, and these raw powders were mixed by wet milling for 24 hours using ethanol.

혼합된 원료분말을 건조한 뒤에, 공구강 다이에 충전하고 80㎫의 기계적 압력을 가해 성형하였다.The mixed raw powder was dried and then filled into a tool steel die and molded by applying a mechanical pressure of 80 MPa.

성형한 시편을 가열로 안에 넣고 진공펌프로 0.01 torr의 진공상태를 만든 후, 5℃/min로 가열하여 1150℃에서 1 시간동안 가열 후 상온으로 노냉하여 최종적으로 치밀한 WC-Fe계 초경합금(10)을 수득하였다.The molded specimen was placed in a heating furnace to make a vacuum of 0.01 torr by a vacuum pump, and then heated at 5 ° C./min, heated at 1150 ° C. for 1 hour, and then cooled to room temperature to finally form a compact WC-Fe cemented carbide (10) Obtained.

본 실시예의 특징은 도 2(a)에 도시된 것과 같이, 완전한 소결과정을 통하여 WC-Fe계 초경합금(10)을 제조한 뒤에 모재와 접합하는 단계를 실시하는 점이다.The characteristic of this embodiment is that, as shown in Figure 2 (a), after the WC-Fe-based cemented carbide (10) is manufactured through a complete sintering process and the step of bonding with the base material.

다음으로 도 2(b)에 도시된 것과 같이, 완전한 소결과정을 통하여 수득된 WC-Fe계 초경합금(10)의 위에 탄소강 모재(20)가 직접 접촉하도록 위치시켰다. 이러한 과정은 WC-Fe계 초경합금(10)을 가열하는 가열로의 내부에서 이루어진다. 따라서 가열로 내부에 별도의 가압수단이 없이도, 탄소강 모재(20) 자체의 무게로 인하여 접촉면에 압력을 가하는 효과를 얻을 수 있다. 또한 WC-Fe계 초경합금(10)을 소결한 가열로에서 WC-Fe계 초경합금(10)을 이동시킬 필요가 없어 공정효율이 높다. Next, as shown in Figure 2 (b), the carbon steel base material 20 is placed in direct contact on the WC-Fe-based cemented carbide (10) obtained through a complete sintering process. This process is performed in the interior of the heating furnace for heating the WC-Fe-based cemented carbide (10). Therefore, even without a separate pressurizing means inside the heating furnace, due to the weight of the carbon steel base material 20 itself, it is possible to obtain the effect of applying pressure to the contact surface. In addition, it is not necessary to move the WC-Fe-based cemented carbide 10 in the heating furnace sintered WC-Fe-based cemented carbide 10, the process efficiency is high.

가열로 내부에 놓인 WC-Fe계 초경합금(10)의 위에 탄소강 모재(20)를 위치시키고, 진공펌프로 0.01 torr의 진공상태를 만든 후, 5℃/min로 가열하여 1100℃로 30분을 유지하였다. 그 뒤에 노냉하여 접합재료를 제조하였다. Place the carbon steel base material 20 on the WC-Fe-based cemented carbide (10) placed inside the furnace, make a vacuum of 0.01 torr with a vacuum pump, and then heated to 5 ℃ / min to maintain 30 minutes at 1100 ℃ It was. Thereafter, the furnace was cooled to prepare a bonding material.

본 실시예에 따른 제조과정을 통하여 제조된 접합재료는 WC-Fe계 초경합금(10)과 탄소강 모재(20)의 계면에 접합부(30)가 형성되어 있다. 이 접합부(30)는 WC-Fe계 초경합금(10)과 탄소강 모재(20)를 접촉시킨 상태에서 가열하는 동안에, WC-Fe계 초경합금(10)과 탄소강 모재(20)의 사이에 실리콘, 보론 및 카바이드와 같은 첨가물이 상호 확산함으로써 철의 액상온도를 낮추어 형성되는 것으로 판단된다. 특히 본 실시예에 따른 접합재료는 초경합금의 바인더로 Fe를 사용하였기 때문에 접합부(30)를 통한 WC-Fe계 초경합금(10)과 탄소강 모재(20) 사이의 접합력이 뛰어날 뿐만 아니라, 낮은 온도에서도 접합부(30)를 형성할 수 있다.In the bonding material manufactured through the manufacturing process according to the present embodiment, the bonding portion 30 is formed at the interface between the WC-Fe-based cemented carbide alloy 10 and the carbon steel base material 20. The joint portion 30 is formed between silicon, boron and carbonaceous material between the WC-Fe-based cemented carbide alloy 10 and the carbon steel substrate 20 during heating while the WC-Fe cemented carbide alloy 10 and the carbon steel substrate 20 are in contact with each other. Additives such as carbide are believed to be formed by lowering the liquidus temperature of iron by mutual diffusion. In particular, since the bonding material according to the present embodiment used Fe as the cemented carbide binder, the bonding strength between the WC-Fe-based cemented carbide alloy 10 and the carbon steel base material 20 through the bonding portion 30 was excellent, and the bonding portion even at a low temperature. 30 can be formed.

도 3은 본 실시예에 따라 제조된 접합재료의 단면을 촬영한 현미경 사진인데, 도면에서 접합부(30)와 WC-Fe계 초경합금(10) 및 탄소강 모재(20)의 사이에 결함이나 크랙이 발생되지 않은 것을 확인할 수 있다.3 is a micrograph photographing a cross section of the bonding material manufactured according to the present embodiment, in which the defects or cracks are generated between the bonding portion 30 and the WC-Fe-based cemented carbide alloy 10 and the carbon steel base material 20. You can see that it is not.

이상에서는 본 발명을 특정의 바람직한 실시예에 대해서 도시하고 설명하였다. 그러나 본 발명은 상술한 실시예에만 국한되는 것은 아니며, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 본 발명의 기술적 사상을 벗어남이 없이 얼마든지 다양하게 변경 실시할 수 있을 것이다. 따라서 본 발명의 권리범위는 특정 실시예에 한정되는 것이 아니라, 첨부된 특허청구범위에 의해 정해지는 것으로 해석되어야 할 것이다.In the above, the present invention has been shown and described with respect to certain preferred embodiments. However, the present invention is not limited only to the above-described embodiment, and those skilled in the art to which the present invention pertains can make various changes without departing from the technical spirit of the present invention. Therefore, the scope of the present invention should not be limited to the specific embodiments, but should be construed as defined by the appended claims.

도 1은 본 발명의 실시예에 따른 초경합금 접합재료의 제조과정을 나타내는 순서도이다.1 is a flow chart showing the manufacturing process of cemented carbide cemented material according to an embodiment of the present invention.

도 2는 도 1의 과정을 따라서 초경합금 접합재료를 제조하는 모습을 나타내는 모식도이다.FIG. 2 is a schematic diagram illustrating a method of manufacturing cemented carbide alloy material according to the process of FIG. 1.

도 3은 본 발명의 실시예에 따라 제조된 접합재료의 단면을 촬영한 현미경 사진이다.3 is a photomicrograph of the cross section of the bonding material prepared according to an embodiment of the present invention.

< 도면의 주요부분에 대한 부호의 설명 >Description of the Related Art

10: WC-Fe계 초경합금 20: 탄소강 모재10: WC-Fe cemented carbide 20: carbon steel base material

30: 접합부30: junction

Claims (15)

철계 합금인 모재부; 및Base material portion which is an iron-based alloy; And 상기 모재에 접합되며, Fe 5 내지 40중량%, 상기 Fe와 고용체를 형성하는 원소 1 내지 10중량%, 그리고 다른 소재와의 접합부위의 젖음성을 향상시키는 물질 0.1 내지 3중량%, 그리고 잔부가 WC인 초경합금부로 이루어지며,5 to 40% by weight of Fe, bonded to the base material, 1 to 10% by weight of the element forming the solid solution with Fe, and 0.1 to 3% by weight of the material to improve the wettability of the joint with other materials, and the balance WC Made of cemented carbide, 상기 모재부와 상기 초경합금부의 접촉면에, 상기 모재부와 상기 초경합금부 상호간의 확산에 의하여 형성된 접합부를 포함하는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료.WC-Fe-based cemented carbide bonding material, characterized in that the contact surface formed by the diffusion between the base material portion and the cemented carbide portion on the contact surface of the base material portion and the cemented carbide portion. 삭제delete 청구항 1에 있어서,The method according to claim 1, 상기 초경합금부의 상기 Fe와 고용체를 형성하는 원소가 Si, Ni 및 Cr으로 이루어지는 군에서 선택되는 어느 하나 이상인 것을 특징으로 하는 WC-Fe계 초경합금 접합재료.WC-Fe-based cemented carbide bonding material, characterized in that any one or more elements selected from the group consisting of Si, Ni and Cr is the element forming the Fe and the solid solution of the cemented carbide. 청구항 1에 있어서, The method according to claim 1, 상기 초경합금부의 상기 WC-Fe계 초경합금부에서 상기 젖음성을 향상시키는 원소가 B, C, B4C 및 B2O3로 이루어지는 군에서 선택되는 어느 하나 이상인 것을 특징으로 하는 WC-Fe계 초경합금 접합재료.WC-Fe-based cemented carbide joining material, characterized in that at least one element selected from the group consisting of B, C, B 4 C and B 2 O 3 to improve the wettability in the WC-Fe cemented carbide part of the cemented carbide portion . 청구항 1에 있어서,The method according to claim 1, 상기 초경합금부에 입자 성장 억제를 위한 화합물로서 Cr3C2 및 VC로 이루어진 군에서 선택되는 어느 하나 이상이 더 첨가되는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료.WC-Fe-based cemented carbide joining material, characterized in that any one or more selected from the group consisting of Cr 3 C 2 and VC is further added to the cemented carbide compound. 청구항 5에 있어서, The method according to claim 5, 상기 입자 성장 억제를 위한 화합물이 0.5 내지 2 중량%로 첨가되는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료.WC-Fe-based cemented carbide bonding material, characterized in that the compound for inhibiting grain growth is added in 0.5 to 2% by weight. Fe 5 내지 40중량%, 상기 Fe와 고용체를 형성하는 원소 1 내지 10중량%, 그리고 다른 소재와의 접합부위의 젖음성을 향상시키는 물질 0.1 내지 3중량%, 및 잔부가 WC로 이루어지는 원료를 이용하여 초경합금을 제조하는 단계;5 to 40% by weight of Fe, 1 to 10% by weight of the element forming the solid solution with Fe, and 0.1 to 3% by weight of a material for improving the wettability of the joint portion with other materials, and the remainder is WC Preparing a cemented carbide; 상기 제조된 초경합금을 철계 합금인 모재와 접촉시키고 가열하여 초경합금을 모재에 직접 접합시키는 단계; 및Contacting the manufactured cemented carbide with a base metal, which is an iron-based alloy, and heating the cemented carbide to directly bond the cemented carbide to the base metal; And 상기 직접 접합된 재료를 냉각하는 단계를 포함하고,Cooling the directly bonded material, 상기 초경합금을 제조하는 단계는,Preparing the cemented carbide, 상기 초경합금의 조성에 따른 원료분말을 혼합하는 단계;Mixing the raw powder according to the composition of the cemented carbide; 상기 혼합된 원료분말을 건조시키는 단계;Drying the mixed raw powder; 상기 건조된 원료분말을 성형체로 가압하여 가압성형하는 단계;Pressing the dried raw material powder into a molded body to form a mold; 상기 성형체를 소결하는 단계; 및Sintering the molded body; And 소결된 합금을 냉각하는 단계를 포함하며,Cooling the sintered alloy, 상기 가압성형단계는 10 내지 10000MPa의 압력으로 가압하는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.The pressing molding step is a method for producing a WC-Fe-based cemented carbide bonding material, characterized in that the pressure of 10 to 10000MPa. 삭제delete 청구항 7에 있어서,The method of claim 7, 상기 WC 분말의 크기가 0.1 내지 10㎛인 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.The size of the WC powder is 0.1 to 10㎛ The manufacturing method of the cemented carbide joints WC-Fe type, characterized in that. 청구항 7에 있어서, The method of claim 7, 상기 Fe와 고용체를 형성하는 원소가 Si, Ni 및 Cr으로 이루어지는 군에서 선택되는 어느 하나 이상인 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.The method for producing a WC-Fe cemented carbide joined material, characterized in that the element forming the solid solution with Fe is at least one selected from the group consisting of Si, Ni and Cr. 청구항 7에 있어서,The method of claim 7, 상기 초경합금을 제조하는 단계가, 입자 성장 억제를 위한 화합물로서 Cr3C2 및 VC로 이루어진 군에서 선택되는 어느 하나 이상의 원료를 더 이용하는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.The manufacturing method of the cemented carbide, WC-Fe-based cemented carbide composite material, characterized in that further using any one or more raw materials selected from the group consisting of Cr 3 C 2 and VC as a compound for inhibiting grain growth. 청구항 7에 있어서,The method of claim 7, 상기 젖음성을 향상시키는 원소가 B, C, B4C 및 B2O3로 이루어지는 군에서 선택되는 어느 하나 이상인 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.The method for producing a WC-Fe cemented carbide joining material, characterized in that the element for improving wettability is any one or more selected from the group consisting of B, C, B 4 C and B 2 O 3 . 청구항 12에 있어서,The method according to claim 12, 상기 입자 성장 억제를 위한 화합물이 0.5 내지 2 중량%로 첨가되는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.Method for producing a WC-Fe-based cemented carbide bonding material, characterized in that the compound for inhibiting grain growth is added in 0.5 to 2% by weight. 청구항 7에 있어서,The method of claim 7, 상기 초경합금을 모재에 직접 접합시키는 단계가, 1000~1300℃의 온도에서 10~120분 동안 이루어지는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.The step of directly bonding the cemented carbide to the base material, the manufacturing method of the WC-Fe-based cemented carbide bonding material, characterized in that made for 10 to 120 minutes at a temperature of 1000 ~ 1300 ℃. 청구항 7에 있어서,The method of claim 7, 상기 초경합금을 모재에 직접 접합시키는 단계가, 상기 제조된 초경합금의 위에 상기 모재를 위치시킨 상태에서 이루어지는 것을 특징으로 하는 WC-Fe계 초경합금 접합재료의 제조방법.The step of directly bonding the cemented carbide to the base material, the manufacturing method of the WC-Fe-based cemented carbide bonding material, characterized in that the base material is placed on the prepared cemented carbide.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160064397A (en) 2014-11-28 2016-06-08 박수흥 Manufacturing process of hard metal assembly and hard metal assembly thereby
KR102279857B1 (en) * 2020-10-08 2021-07-22 (주)하이엠시 Improved Method for manufacturing WC (Tungsten Carbide) bonding tappet used Diesel Engine

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114571134B (en) * 2022-03-08 2023-04-25 江苏省徐州技师学院 Brazing material for brazing hard alloy cutter and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61221352A (en) * 1985-03-27 1986-10-01 Sumitomo Electric Ind Ltd Sintered hard alloy for warm and hot forging tool
JPH0633183A (en) * 1992-07-16 1994-02-08 Hitachi Tool Eng Ltd Fine-grained sintered hard alloy
KR20030052618A (en) * 2001-12-21 2003-06-27 대우종합기계 주식회사 Method for joining cemented carbide to base metal
KR20080091921A (en) * 2007-04-10 2008-10-15 두산인프라코어 주식회사 Wc-ni hard metal and method for producing the same

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08225878A (en) * 1995-02-17 1996-09-03 Toshiba Tungaloy Co Ltd Iron-base high strength sintered hard alloy and its production
JP3066571B2 (en) * 1996-08-07 2000-07-17 北海道 WC-Fe alloy using iron-carbon as binder and method for producing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61221352A (en) * 1985-03-27 1986-10-01 Sumitomo Electric Ind Ltd Sintered hard alloy for warm and hot forging tool
JPH0633183A (en) * 1992-07-16 1994-02-08 Hitachi Tool Eng Ltd Fine-grained sintered hard alloy
KR20030052618A (en) * 2001-12-21 2003-06-27 대우종합기계 주식회사 Method for joining cemented carbide to base metal
KR20080091921A (en) * 2007-04-10 2008-10-15 두산인프라코어 주식회사 Wc-ni hard metal and method for producing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160064397A (en) 2014-11-28 2016-06-08 박수흥 Manufacturing process of hard metal assembly and hard metal assembly thereby
KR102279857B1 (en) * 2020-10-08 2021-07-22 (주)하이엠시 Improved Method for manufacturing WC (Tungsten Carbide) bonding tappet used Diesel Engine

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