KR101136995B1 - Manufacturing method of natural detergent and natural detergent of the same - Google Patents

Abstract

PURPOSE: A manufacturing method of environment-friendly detergent is provided to manufacture natural detergent with improved detergency and disperse stability at room temperature and high temperatures by using environment-friendly materials like persimmon or salt. CONSTITUTION: A manufacturing method of environment-friendly detergent comprises: a step of preparing one or more materials selected from the shell of persimmon, acorn and nut which contain 1-16 weight% of tannin; a step of adding sodium chloride in the mixture after mixing the tannin-containing materials with water; a step of aging the mixture at room temperature for 7-15 days; and a step of removing the residue of the aged mixture through a net or a sieve.

Description

MANUFACTURING METHOD OF NATURAL DETERGENT AND NATURAL DETERGENT OF THE SAME

The present invention relates to a method for preparing a natural detergent and a natural detergent prepared by the method, and more particularly, a method for preparing a natural detergent capable of performing a washing function by aging a natural fruit such as persimmon or pear. And to a natural detergent produced by the manufacturing method.

Generally, detergents are used to wash oil, fat or food residues on various dishes including plates. The ideal dish detergent should not only be able to completely remove the contamination of the object to be cleaned, but also the purpose of hygiene and aesthetics should be fulfilled within the limits to maintain the health of the skin and the properties of the object to be cleaned.

However, most of the currently known kitchen detergents have to be washed repeatedly with excess detergent in order to sufficiently remove the food residues on the tableware, which causes damage to the natural environment and damages of the user's skin. There is a problem.

This has the disadvantage of making the user's skin rough and endangering skin health.

Due to the above problems, it is required to develop a detergent that can protect skin by minimizing skin irritation and damage while maintaining excellent cleaning power.

In general, in order to differentiate the formulation of the liquid detergent and to enhance cleaning power, skin moisturizing power, and the like, granules or fine bubbles impregnated with abrasive particles or active ingredients are often dispersed. In this case, in order to maintain the dispersion stability of the product for a long time, a thickener such as an acrylic acid-based synthetic polymer, or colloidal silica, gum or cellulose natural validators have been used.

For example, in International Patent Application WO 93/021299, baking soda was dispersed using an acrylic polymer-based thickener, and European Patent No. 630179 describes a natural gum for stabilization of a liquid detergent composition containing an enzyme component. natural gum) is applied.

However, in general, acrylic acid polymer thickener has a disadvantage in that the cost increases when the liquid detergent is applied, and when the acrylic polymer that is hardly soluble in water is used, a premixer step of solubilizing in water using a homomixer must be added. There is this. In addition, xanthan gum and cellulose are more economical than acrylic polymer thickeners, but require a heating process to solubilize in water, and have weaknesses in phase stability under acid, alkali, low temperature, and high temperature conditions. Some raw materials have greatly improved water solubility by supplementing these shortcomings of acrylic, gum and cellulose thickeners recently. However, they are economically expensive when applied to products, and even if the viscosity is increased by the addition of thickeners, these raw materials have a positive effect on the cleaning power. It has a disadvantage of not being slippery or easy to dissolve in water, and even though the dispersibility of effective particles and fine bubbles at high viscosity using a thickener is good, the fluidity is not good when applied to liquid detergents. There was a problem.

Therefore, it is economical even with a combination of a surfactant and an electrolyte, and does not use a thickener that is expensive or difficult to apply as in the prior art, and excellent dispersion stability at room temperature and high temperature, especially dispersion of microbubbles and effective particles. However, it was necessary to develop a liquid detergent with excellent flowability and excellent usability and excellent cleaning power.

Korean Patent Publication 10-0943629 (Method for preparing persimmon tannin)

The present invention has been made to solve the problems described above, the object of the present invention is to provide a method for producing a natural detergent while improving the cleaning power by using a natural material such as persimmon or salt. For the purpose of

Method for producing a natural detergent of the present invention, the step of preparing any one or more selected from persimmon, acorn, oak, chestnut shell containing 1 to 16% by weight of tannin (S10) and the prepared persimmon, oak, acorn, One or more selected from the skin of chestnut is weighed and mixed so that the weight ratio with water is 2: 1 to 1: 2, and then 0.1 to 0.4 with respect to 1 part by weight of any one selected from the persimmon, oak, acorn and chestnut skin. Adding a weight part of sodium chloride (S20), and the step of aging a mixture of any one or more selected from the salt added persimmon, acorn, oak, chestnut bark and water at room temperature for 7 days to 15 days (S30) and the And removing the residue of the mixture of persimmon, acorn, oak, chestnut peel and water added with aged salt through a net or a sieve (S40).

Another manufacturing method of the natural detergent of the present invention, the step of preparing a bark of the pear (S11), and the weight of the prepared pear bark so that the weight ratio of water is 2: 1 to 1: 2 and Adding sodium chloride after mixing (S21), aging the mixture of the sodium chloride added pear shell and water for 3 days to 10 days at room temperature (S31) and the shell of the aged sodium chloride added pear And removing the residue of the mixture of water and the net through a sieve (S41).

In the method for producing a natural detergent according to the present invention, the natural detergent further comprises a spice consisting of preservatives and gardenia.

In the method for producing a natural detergent according to the present invention, the acorn has a water content of 8.6 ~ 21.7% by weight, ether extract 4.6 ~ 38.8% by weight, crude fiber 2.4 ~ 3.4% by weight, ash 1.3 ~ 2.7% by weight, crude protein 3.9 ~ 7.5 Wt%, tannins 0.6-8.8%, nitrogen free extracts 47.8-87.6 wt%.

According to the natural detergent according to the present invention, it is possible to efficiently remove the dust and debris from the smeared object such as glass or sneakers. In addition, it is possible to remove grease and dirt efficiently without having to put a lot of effort on the difficult parts such as tiles, tableware, roasted iron plate, rust bowl, stove floor.

In addition, using the properties of tannins in persimmons, they are susceptible to decay, like animal skins, and, when immersed in water, swell and dry, can perform an excellent cleaning role for objects such as hard slabs.

1 is a process diagram showing a process for making a cleaning agent according to the present invention.

Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the following embodiments are provided to those skilled in the art to fully understand the present invention, and may be modified in various forms, and the scope of the present invention is limited to the embodiments described below. It doesn't happen.

1 is a procedure showing a method of making a natural cleaner using persimmon according to the present invention.

Referring to FIG. 1, a thin persimmon is prepared first (S10). Table 1 is a table showing the components of red persimmon according to the present invention.

nutrient Energy kcal moisture% Protein g Fat g Sugar g Fiber 44 86.5 0.5 0.1 11.4 1.1 Mineral Calcium mg Iron mg Potassium mg Phosphorus mg Sodium mg 8 0.3 149 18 2 vitamin A (R.E) B1mg B2mg Niacin mg C (R, E) 23 0.03 0.03 0.3 50

In Table 1, R.E represents Retinol Equivalents. In other words, RE (Retinol equivalents), an active unit of Vitamin A, corresponds to 1 μg of all-trans-retinol, 6 μg of β-carotene, and 12 μg of caroteinoid provitamine.

Persimmons have a rich taste before ripening. The reason for the astringent taste is because of the tannin, Shubuol (C ₁₄ H ₂ OO ₉ ). When the astringent taste disappears in nature, ethyl alcohol (Ethylalchohol) produced in persimmon cell molecules is dehydrogenated by deceleration oxygen to become acetaldehyde, and the acetaldehyde reacts with Shibuol and is insoluble. By changing it to a substance.

Therefore, in the case of the natural cleaner according to the present invention, it is preferable to cultivate as a pretreatment before losing the astringent taste. In order for the natural cleaner according to the present invention to achieve the effect of washing effectively, it is preferable that tannin contains 1 to 16% by weight.

When the weight ratio is 1% or less, the content of tannin is too small to achieve a cleaning effect, and it is almost impossible to obtain tannin which is 16% or more in the natural state.

Tannins are widely found in the roots of leaf stems of plants, especially in undercooked fruits and seeds of plants. Others have no color, but may combine with oxygen to produce brown, black or red color. Tannins also have a bitter astringent taste and bitterness, which affects the taste of food. This is because tannins, like anthocyanins, react with various metal ions to form insoluble salts. In addition, canned fruits and vegetables containing tannins are made of gray salts from iron cans, and when the cans contain a small amount of oxygen, they can become black, blue, or blue. Usually tannins are oxidized as the fruit ripens, turning into anthocyanins or anthanthines. Therefore, when the fruit ripens, bitter or astringent taste disappears.

Tannins are generic names for polyphenols present in various plants, and have been called tannins since they have been used for tanning animal skins since ancient times. It is also called tannin.

Tannin is a type of polyphenol and has a molecular weight of 500-3000. Although the components are separated in crystalline form as a single substance, most of the products are a mixture of several kinds of substances, and are obtained as a white or light brown powder.

Tannins are broadly classified into condensed tannins, hydrolyzed tannins and new tannins, depending on their chemical structure. Condensed tannins are also classified into dimers, trimers, and multimers according to the number of constituent units, and are also referred to as proanthocyanidins because they produce anthocyanidins by acid treatment. Tannin present in persimmon is a multimer of proanthocyanidins whose basic structure is based on catechins and gallocatechins, and it is reported that gallic acid (as a molar asset or gallic acid) is bound to its side chain.

As described above, the astringent taste component of persimmon is a tannin component called diosphrine, and since it is water-soluble, it shows an astringent taste. When acetaldehyde is insoluble in combination with tannins, the astringent taste disappears. The dark spots on the persimmons and rinds of sweet persimmons are modifications of tannin cells insoluble in tannins. In the West, the persimmon is careful to eat, because the tannin component of persimmon acts with fat to harden the stool.

Tannins are widely present in plants and generally tend to decrease as they are more mature and less ripe in fruits or seeds. In particular, many oak, oak, gluttony, gallengja such as a lot of bark of certain trees.

Tannins are widely used to soften leather, as revealed in the description above. Animal skin is susceptible to decay and swells when submerged in water. When it comes to a board like this, tanning is necessary. When tanning, the raw skin is first washed with water, fat or flesh is removed, and an emulsion is applied to suit the intended use. There are many ways to tanning, but the most commonly used is tannin tanning using tannins.

Persimmon is widely used for food, and is known to exert its effect on parts such as strokes, frostbite or limbs. However, in the case of the present invention, since it is used in a cleaning agent, it is omitted below.

Thus, in the state containing a lot of tannins, the head of the persimmon is removed, mixed so that the weight ratio of persimmon and water is 2: 1 to 1: 2, and 0.1 to 0.4 parts by weight of sodium chloride is added to 1 part by weight of the persimmon. It includes (S20). It is preferable that the amount of salt added is 1000 g of persimmon and the amount of salt added when the weight of water is 1000 g.

The period of storage in the cup is 7 to 15 days and is preferably stored at room temperature (S30).

After the long-term storage as described above, the natural detergent is completed by the step (S40) of removing the residue of the mixture of persimmon, acorn, oak, chestnut husk and water added to the aged salt through a net or sieve.

At this time, it is preferable to add a preservative that is harmless to the human body.

What can be used as the above-mentioned preservative is preferably an antifungal agent containing a mountain root or stem extract as an active ingredient.

You can also add spices. Gardenia etc. are suitable as a spice which can be used for the detergent which used persimmon. Gardenia, which is well watered without special mordant, is a yellow dye traditionally used most because of its clear color and rich color. In these days, it is very difficult to dye because the people who wear water and the people who wear water are different, but the old women always used fresh water after washing clothes. Gardenia staining is simple and clear.

As mentioned above, what can be used as a washing | cleaning agent is not limited to persimmon. Acorns, oaks and pears can be used as natural cleaners through the same process.

Acorn trees are larch tall trees belonging to the oak and oak trees. The height is 20-25m and grows to about 60cm in diameter. The acorn tree refers to a tree that bears all acorn fruit, but it refers to an oak tree called oak.

Also called oak. There are about 200 species of oak, and about 19 species are distributed in Korea. The oak tree native to Korea is red, oak, oak, sol, oak, oak, blue oak, oak, oak, oak, oak, oak, oak, oak Brown, oak, water, oak, bramble, bondong, oak tree, pruning oak, brown oak, and oyster oak grow.

Acorn trees grow near villages and at the foot of the mountain. The bark is grey-brown black grey, irregularly cracked vertically. The leaves are alternate, long oval lanceolate, with sharp needle-like teeth at the edges. Leaf front is glossy, hairy on back, light green. A male and female plant blooms with leaves, and yellow male spikes hang down. Acorn claws are covered with thin pieces of scale, and the ends of the pieces are flipped backwards. The flowering period is April to May, and the fruiting season is October.

Considering the components of the acorns, the moisture content is 8.6-21.7 wt%, the ether extract is 4.6-38.8 wt%, crude fiber 2.4-3.4 wt%, ash 1.3-2.7 wt%, crude protein 3.9-7.5 wt%, tannin 0.6-8.8 Wt%, nitrogen free extract (nitrogen free extract) consists of 47.8 ~ 87.6% by weight.

As can be seen from the components of the acorn, tannin is included, so that the same working effect as in the case of using a natural detergent composition mainly containing persimmon in the present invention can be achieved.

At this time, although not described above, it is also possible to prepare a natural detergent through the process of S10 to S40 described above for the mixture of acorn and persimmon.

The same principle applies to hydrostatics.

Osu is the fruit of the oak, which belongs to the beech family, and is widely distributed throughout the country. Geographically, it is distributed in Japan, Manchuria, and India. Osuri, unlike other seeds, is characterized by containing 6 to 9% by weight of tannin, which gives a rich taste. There are many types of tannins, the chemical structure is very complex, and there is no uniform structure, so there is no complete classification. However, chemically, they are all polyphenol compounds, and are generally classified into hydrolyzed tannins and condensed tannins. Hydrolyzed tannins are a group of tannins that are decomposed into alcohols and phenolcarbonyl acids by acids, alkalis or tanases, which produce only gallotic acid by hydrolysis. The production of ellagic distraction is called ellagitannin. Galotenin is contained in the gall bladder and gluttony, and ellagitannin is contained in divi-divi, chestnut, oak leaves, and the like. Condensed tannins are usually composed of flaben-3-ol (catechin) to form dimers, trimers, oligomers, and polymers by various binding modes.

This is an anthocyanidin produced by acid treatment and is called proanthocyanidin. The monomers include catechin, gallocatechin, epicatechin, dimer for procyanidin A-2, trimer for procyanidin C-1, and the like.

These tannins are known for their physiological activities such as antioxidant activity, antitumor action, antiviral action, antiallergic action, urea nitrogen lowering action.

The same holds true for night. The night is also called the ruler. It is a dark brown ripening fruit and is native to Asia, Europe, and North Africa. At night, it is rich in carbohydrates, proteins and vitamins, and rich in nutrients such as calcium, iron and potassium, making it a good source of nutrients. The digestive system can be strengthened and used as a baby food and patient recovery material. Chestnuts are of three types: round, oval, and triangular. The meat is hard and can be used for processing such as canning. Chestnuts are produced in the central region, and Gongju, Sancheong, Hadong, and Hamyang are famous for their chestnut cultivation. The skin of the chestnut is called Yulpi, which is often used for skin care.

In the case of the chestnut tree, the fruit is used for food, and the chestnut tree consists mainly of starch kernels and the outer skin and the inner skin of the two layers surrounding the kernels. After removing the outer skin and the inner skin that has been used only pure pulp as food.

Among the ingredients of the chestnut, the skin of the chestnut fruit has been used as a variety of medicines called Yulpi, and in oriental medicine, it is known to be effective as an antidote for wrinkles, bleeding, hemostasis, dry stomach, bosin action and chitoxin.

In particular, the skin of Yulpi, the inner skin of chestnut, was found to have functions such as inhibiting tyrosinase activity, inhibiting automatic oxidation of aging, and inhibiting melanin production. It is used as a raw material for cosmetic packs and whitening cosmetics.

In addition, yulpi, as well as sugars, amino acids, and various minerals, polyphenol tannin and free radical scavenging action, which has recently been spotlighted as a physiologically active substance, significantly reduces the occurrence of lung cancer. Contains large amounts of identified catechins. In the case of the natural detergent according to the present invention, even if it is not configured to make the activity of the human body positively, it contains tannins in the same way, so that it can be used as a cleaning agent.

In the case of this yulpi can be used as a cleaning agent only through the same manufacturing method as the peel of less ripe persimmon.

The same principle applies to ships.

Table 2 shows the components of a typical pear.

nutrient Energy kcal moisture% Protein g Fat g Sugar g Fiber 39 88.4 0.3 0.1 10.3 0.6 Mineral Calcium mg Iron mg Potassium mg Phosphorus mg Sodium mg 2 0.2 171 11 3 vitamin A (R.E) B1mg B2mg Niacin mg C (R, E) 0 0.02 0.01 0.1 4

The inside of the pear contains a lot of water, but if you experience frequent diarrhea, it is effective to remove the pear's bark and eat the pear. This can be reduced by diarrhea due to the intake of pears due to the tannin in the shell of the pear.

In the case of the natural detergent according to the present invention, the content of moisture is not a problem because the purpose of removing the difficult to wash, such as glass, sneakers, steamed tiles, stove bottom using tannins.

When using a pear in the method of manufacturing a natural detergent according to the present invention, the step of preparing a shell of the pear (S11), and the weight ratio of the prepared pear shell to water so that the weight ratio of 2: 1 to 1: 2. After weighing and mixing, adding a weight ratio of 0.1 to 0.4 parts by weight sodium chloride relative to 1 part by weight of the shell of the pear (S21).

The mixture of the shell and water of the pear to which the sodium chloride is added is subjected to aging at room temperature for 3 days to 10 days (S31). In the case of the natural detergent composition according to the present invention, in the case of the natural detergent composition according to the present invention, the residue of the bark and water mixture of the aged sodium chloride is removed through a net or a sieve in the natural detergent composition according to the present invention. Go through S41). This will give you a good cleaning solution for items that can't be rusted, such as glass, sneakers, scuffed tiles, and gas stove floors.

In the following, examples of the method for preparing a natural cleaner according to the present invention are presented in more detail, and the present invention is not limited to the examples presented below.

<Examples>

The content described below shows a case where the persimmon is applied as a natural detergent.

1 kg of persimmon persimmon was washed and put in a jar. 1000 ml of water was added thereto. The salt was then placed in a cup containing 250 g of salt and placed in a jar containing the persimmon. And stir so that the salt evenly entered.

The mixture of salt, water, and red persimmon prepared in this way was left at room temperature for 10 days, and then the liquid component was removed to make a detergent.

As described above, even with a simple manufacturing process, it is possible to obtain an excellent natural detergent that can remove stray oil and oil.

As mentioned above, although preferred embodiment of this invention was described in detail, this invention is not limited to the said embodiment, A various deformation | transformation by a person of ordinary skill in the art within the scope of the technical idea of this invention is carried out. This is possible.

Claims (4)

Preparing at least one selected from persimmon, oak, acorn, and chestnut shell containing 1 to 16% by weight of tannin (S10);
Any one or more selected from the prepared persimmon, oak, acorns and chestnut shells is weighed and mixed so that the weight ratio of water is 2: 1 to 1: 2, and then any one selected from the persimmons, oak, acorns and chestnut shells. Adding 0.1 to 0.4 parts by weight of sodium chloride based on 1 part by weight (S20);
Aging the mixture of any one or more selected from persimmon, acorn, oak, chestnut hulls and water added with sodium chloride at room temperature for 7 days to 15 days (S30); And
And removing the residue of the mixture of persimmon, acorn, oak, chestnut husk and water added to the aged salt through a net or a sieve (S40). Preparing a shell of the pear (S11);
The prepared pear shell is weighed and mixed in a weight ratio of water to a weight ratio of 2: 1 to 1: 2, and then mixed with 0.1 parts by weight of sodium chloride based on 1 part by weight of the pear shell (S21). ;
Aging the mixture of the shell and water of the pear to which the sodium chloride is added at room temperature for 3 days to 10 days (S31); And
And removing the residue of the mixture of the skin and water of the pear, to which the aged sodium chloride is added, through a net or a sieve (S41). The method according to claim 1 or 2,
The natural detergent further comprises a spice consisting of preservatives and gardenia,
The preservative is a method for producing a natural detergent, characterized in that the antifungal agent containing a mountain root or stem extract or an organic solvent fraction thereof as an active ingredient. A natural detergent prepared by the method of claim 1.

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