KR101115184B1 - Production method of automatic oxygen generating insole using the green environmental solid material - Google Patents

Abstract

The present invention relates to a functional fiber fabric that generates oxygen and a method of manufacturing the same, the purpose of which is to generate oxygen constantly to promote blood circulation (血 行), thereby smoothing the human metabolic activity, oxygen consumed during the activity It can be supplied directly through the skin or respiration to activate the pancreas function through neural reflex, and at the same time prevent the congestion of blood donation caused by lack of oxygen, and can solve the numbness of the feet, cold, heat and heaviness. It is to provide a functional fiber fabric that generates oxygen present and a method of manufacturing the same.
In the present invention, the oxygen generating mixture is applied to the textile fabric, and the oxygen generating mixture is 100 parts by weight of potassium superoxide powder, 45 to 55 parts by weight of sodium superoxide powder, 85 to 95 parts by weight of aluminum hydroxide, and 280 to 320 parts by weight of polyethylene glycole. 85 to 95 parts by weight of zeolite, 75 to 85 parts by weight of calcium superoxide, and 35 to 45 parts by weight of iron dioxide.

Description

Functional fiber fabrics that generate oxygen and a method of manufacturing the same {Production method of automatic oxygen generating insole using the green environmental solid material}

The present invention relates to a functional fiber fabric that generates oxygen and a method of manufacturing the same, which is a harmless human-friendly solid that processes oxygen-generating materials together with a green stabilizer and coats it with a specially processed cloth, while walking, working, or The present invention relates to a functional fiber fabric that generates oxygen that can smoothly metabolize the body by maximizing sterilization and antiviral action while releasing sweat while exercising, and releasing fatigue.

Recently, with the rapid development of society and the improvement of living standards, the demand for well-being materials such as ecology and hygiene is increasing socially, and the same desire is reflected in various fabrics that directly contact the body.

In particular, modern people with high interest in sports have increased interest in clothing, shoes, and sportswear that are in direct contact with the skin, and many consumers want functional fibers that provide warmth and comfort during exercise. Eggplant, the demand for so-called "functional fabrics" is increasing, and in response to the needs of consumers, the development of fabrics having antibacterial, deodorant, healing (healing) effect is in earnest.

In particular, the foot of the human body is directly connected to the health of the human body. Not only in the East, but also in Western medicine, the feet describe that all five human viscera are connected. Thus the foot is called the second heart. Medicines that control arthritis, musculoskeletal pain, skin diseases, neurovascular and diabetic complications by controlling each nerve reaction point and meridians on the sole of the foot have been used for treatment in China, Egypt and India since 5000 years ago.

In the human body, the foot supports and balances the heavy body until the morning wakes up and at night. The technology for manufacturing shoes that fit the functions of these important feet leaps the footwear industry into a high-tech industry, and various functional shoes are invented, manufactured, and sold. Recently, shoes manufactured using the optimal ratio between the body's weight and earth's gravity have been used to improve the body's metabolism, improve blood circulation, control blood sugar, reduce complications caused by diabetes, and help children's height growth. Shoes are introduced to help health. Health shoes, which are scientifically designed and eco-friendly, have been manufactured and sold by many domestic and overseas shoe manufacturers. Most of these functional shoes have antibacterial properties to prevent or treat athlete's foot, emphasize the breathability of shoes, and apply simple functions to balance the human body. These shoes are produced and sold in various ways and have a great effect. It is recognized by the people. Produced on the market now. The functional shoes sold are those that balance the body shape of each part of the body or attach antibacterial materials, and do not fundamentally solve the excessive health of the feet in the fixed space of the shoes.

The skin of our human body is always exposed to the air to accept oxygen and release sweat, but the skin on the feet trapped in the space of shoes always lacks oxygen and the lack of oxygen interferes with human metabolic activity. . Even in India, many people go barefoot for foot health, and supplying oxygen directly to the feet trapped in shoes provides oxygen molecules to the skin cells in the feet, which can help the body's metabolism.

However, shoes that promote blood circulation and help metabolic activity by incorporating oxygen-producing functions into the soles of shoes are not produced in Korea as well as in foreign countries. Although there are no materials or devices that directly supply oxygen to shoes, oxygen generators, devices, and materials for supplying oxygen directly to the nose or mouth are widely available.

The simplest oxygen supply device of the oxygen generator is to provide oxygen gas directly into the barrel and another method is to use a metal peroxide capable of producing oxygen gas. However, these methods are difficult to apply to the special space and environment of shoes. Oxygen generators, which are used in oxygen masks worn by firefighters or used as portable oxygen-generating materials, are currently patented by American Blum and Mei (Patent name: Hand-held potassium super oxide oxygen generating apparatus: US Pat. No .: 20060280656, A1, filed on December 14, 2006) and an emergency oxygen mask (Patent name: Emergency oxygen mask: US Patent No .: 20070144513 A1, filed on June 28, 2007) and American Simplified dual mode medical oxygen concentrator (US Patent No .: 20050161043 A1, filing date: June 28, 2005), filed with Whitley, Roger in the US Patent Office. These devices consist of peroxides of alkali metals.

Patents for oxygen generating materials for the purpose of oxygen generation only include the oxygen generating materials (Patent name: Oxygen generating composition: US Patent No .: 20050287224 A1, filing date: December 29, 2005) and Japanese Simple oxygen producer (patent name: Simple oxygen producer: Japan Patent Office Patent Number: JP 80-51537, filed November 19, 1981) filed with Japan Patent Office by Monma, Takamichi and Russian Ferapontov Ju A. There is a continuous oxygen generator (patent name: Regenerative product and a method for preparation): Russian Patent No .: RU2210416 (C1), filed August 20, 2003, jointly filed with Zhdanov DV and Gladyshev NF. Research on devices and materials that safely generate oxygen without using oxygen cylinders has been carried out by using photocatalysts on titanium dioxide to produce oxygen (Claudia Gomes Silva, Younnes Bouizi, Vincente Fornes and Hermenegildo Garcia, Layered Double Hydroxides as Highly Efficient). Photocatalysis for Visible Light Oxygen Generation from Water, Journal of the American Chemical Society, 2009, 131 , 13833-13839. And a study of portable oxygen generators for biotherapies soiled with petroleum by-products (Yasemin Kacar Kunukcu, In bioremediation of groundwater contaminated with petroleum constituents using oxygen release compounds (ORCs), Environmental & Ecological Toxicology: Environmental Health, 2007, 14 , 839-845). In recent years, research has been carried out to produce oxygen using nano-molecules surrounded by carbon as an oxygen source resource that generates oxygen molecules in a way that is portable and stable to supply oxygen molecules (Jisheng Zhou, Huaihe Song , Xiaohong Chen, Linjie Zhi, Shubin Yang, Junping Huo and Wantai Yang, Chemistry of Materials, 2009, 21, 2935-2940. And a method for preparing nanostructures surrounded by oxygen-causing metal oxides with porous carbon (Porous Carbon and Carbon / Metal Oxide Microfibers with Well-Controlled Pore Structural and Interface, Journal of the American Chemical Society, 2008 , 130 , 5034-5035) have also been reported. Existing patents and results of oxygen generators and materials discussed above are difficult to apply to shoes. Portable oxygen generators and materials that have been patented so far are convenient to carry or carry on the back, but are difficult to apply to shoe soles. For example, the American hand-held potassium super oxide oxygen generating apparatus, patented by Blum and Mei, uses potassium super oxide as a material, and potassium superoxide (KO ₂ ) is sensitive to moisture and simultaneously reacts with carbon dioxide to produce potassium carbonate. . The foot generates a lot of water when walking or moving, and at the same time carbon dioxide is released from the skin of the foot. At this time, potassium superoxide easily reacts with sweat and carbon dioxide to produce potassium carbonate (K ₂ CO ₃ ), so it is not easy to deliver only clean oxygen to the skin of the foot. And the simplified medical oxygen generator filed by Whitley, Roger has a pump that continuously injects air into a small portable oxygen generator, which makes it difficult to apply such a device to a shoe sole because it uses a portable fuel cell that runs the pump. Oxygen-generating material composition, jointly applied by Norman Kyun, Takamichi Monma, Ferapontov Ju A., Zhdanov DV and Gladyshev NF, is also designed to operate in water, so that titanium dioxide reacts with photons of light. It is difficult to apply to shoes because it generates oxygen. Oxygen generators, jointly announced by Yasemin Kacar KunukcuJisheng Zhou, Huaihe Song, Xiaohong Chen, Linjie Zhi, Shubin Yang, Junping Huo, and Wantai Yang, use carbon nanostructures, which is good for stability and continuity of oxygen generation. It is costly for astronomical applications to apply to the market.

The present invention is to solve the above problems, the purpose is to generate oxygen constantly to promote blood circulation (행 行), thereby smoothing the human metabolic activity, the oxygen consumed during the activity of the skin or breathing It is supplied directly through the nerves to activate the pancreas function, while at the same time prevents the congestion of blood (생기) caused by the lack of oxygen, and generates oxygen to solve the numbness of the feet, cold, heat, heaviness To provide a functional textile fabric and a method of manufacturing the same.

Another object of the present invention is to provide oxygen at a constant rate automatically by adding eco-friendly stabilizer that maintains a constant rate per unit time of oxygen molecules generated from the metal peroxide as the main material and metal peroxide, which is eco-friendly and relatively inexpensive It is to provide a functional fiber fabric that generates oxygen that can induce generation and a method of manufacturing the same.

Another object of the present invention is to add an eco-friendly moisture remover to prevent the metal oxide reacts with the sweat from the foot and decomposes before the metal oxide provides oxygen directly to the skin of the foot, thereby improving the oxygen generation time. It is to provide a functional fiber fabric that can generate oxygen and a method for producing the same.

Still another object of the present invention is to provide a functional fiber fabric which generates oxygen capable of protecting the body such as feet and bacteria from bacteria and bacteria simultaneously with the generation of oxygen and a method of manufacturing the same.

The present invention by applying the oxygen generating mixture to the textile fabric,

The oxygen generating mixture is 100 parts by weight of potassium superoxide powder, 45-55 parts by weight of sodium superoxide powder, 85-95 parts by weight of aluminum hydroxide, 280-320 parts by weight of polyethylene glycole, 25-30 parts by weight of calcium carbonate, silica gel 20-25 It is composed of 20 parts by weight, 20 to 25 parts by weight of zeolite, 280 to 320 parts by weight of aromatic heavy oil, 75 to 85 parts by weight of calcium superoxide, and 35 to 45 parts by weight of iron dioxide.

As described above, the present invention automatically generates oxygen using only environmentally friendly solid materials that are harmless to the human body, so that it is harmless even when directly in contact with the body, and the supply of oxygen can be continued.

In addition, the present invention attached oxygen autogenous material (oxygen generating mixture) containing the active ingredients of the 10 compounds to the textile fabric in a certain area and thickness to induce the generation of oxygen continuously oxygen generated on the skin such as feet Oxygen molecules are directly supplied to skin cells to help the body's metabolic activity.

In another aspect, the present invention provides continuous oxygen during exercise or work to promote blood circulation (血 行) to help human body metabolism.

In addition, since the present invention is manufactured in an environmentally friendly manner, there is no environmental pollution even after disposal for a certain period of time, and natural antibacterial and antiviral extracts extracted from lotus leaf are added to the environment, and thus have excellent antibacterial and bactericidal effects.

In addition, the present invention by automatically generating oxygen using only environmentally friendly solid material harmless to the human body, it is harmless even if it is in direct contact with the body, it is possible to continue the supply of oxygen. In other words, oxygen-producing substances are generally poisonous toxins that are fatal to humans. For example, while ozone, hydrogen peroxide, and other organic peroxides generate oxygen but have a fatal effect on the human body, the eco-friendly solid material according to the present invention refers to an eco-friendly solid material or an eco-friendly solid material called a green material in the compound system. These eco-friendly solid materials are compounds that prove to be harmless to the human body by carefully selecting oxygen-generating substances that are harmless to the human body. They are not chemical products but are extracted from natural plants and are harmless to the human body. And, it is possible to supply a continuous oxygen, has the effect of promoting metabolism.

In addition, the present invention can be applied to all parts of the body contact, such as shoe soles, socks, clothes, cushions, mats, sportswear, etc., there are many effects such as having a very large ripple effect in the industry.

1 is a block diagram showing a manufacturing process according to the present invention

The present invention by applying the oxygen generating mixture to the textile fabric,

The oxygen generating mixture is 100 parts by weight of potassium superoxide, 45-55 parts by weight of sodium superoxide, 85-95 parts by weight of aluminum hydroxide, 280-320 parts by weight of aromatic heavy oil, 280-320 parts by weight of polyethylene glycole, calcium carbonate (powder, 10 Μm) 25-30 parts by weight and silica gel (230-400mesh: ~ 0.8 cm 3 / g: surface area 550) 20-25 parts by weight, zeolite 20-25 parts by weight, calcium superoxide 75-85 parts by weight, iron dioxide 35- by weight 45 parts by weight.

In addition, the present invention further comprises 7 to 13 parts by weight of natural antibacterial and antiviral extract.

The oxygen-generating mixture is formed using environmentally friendly green chemistry stabilizers using peroxides of metal ions, which are environmentally-friendly solid materials, and continuously provide oxygen to facilitate blood metabolism.

In the present invention, eco-friendly and inexpensive metal peroxides are used as main materials, and a stabilizer for maintaining a constant generation rate per unit time of oxygen molecules generated from the metal peroxides is automatically induced to generate oxygen.

In addition, the present invention was added to make the oxygen by adding a calcium carbonate, silica gel, zeolite and polyethyleneglycole harmless to the human body as a stabilizer.

In addition, the present invention added an eco-friendly moisture remover to prevent the metal oxide reacts with the sweat from the foot and decomposes before the metal oxide provides oxygen directly to the skin of the foot.

That is, in the present invention, metal peroxides such as K ₂ O, NaO _{2, and} CaO ₂ are the main raw materials for generating oxygen, and all of them are moisture removers and stabilizers.

That is, the silica gel and aluminum oxide are moisture removers, and the zeolite serves to prevent the metal peroxide from directly reacting with the moisture remover such as silica gel and aluminum oxide and to stably exist the metal peroxide and the moisture remover. It has a stabilizer function.

In addition, polyethleneglycole and aromatic heavy oil allow the above substances to exist in the colloidal state, so that polyethyleneglycole and aromatic heavy oil adhere to the textile fabric as well as a buffer that continuously applies a certain amount of oxygen to the foot even after wearing shoes for a long time. With functions.

In addition, the present invention was added to the natural antibacterial and antiviral extracts to protect the body from bacteria and bacteria at the same time as the generation of oxygen, environmentally friendly natural fungicides extracted from lotus leaf, Nelumbo nucifera and α-longifolene, pterodontoside.

The textile fabric is a functional cloth or polytetrafluoroethylene cloth, such as natural fiber fabrics, synthetic fiber fabrics, Gore-Tex, preferably functional fiber fabrics. In particular, the polytetrafluoroethylene cloth has a function that the oxygen generated from the oxygen-generating mixture is constantly generated and easily discharged to be in easy contact with the skin, and nitrogen and other carbon dioxide in the air are easily discharged into the air.

Hereinafter, the manufacturing method for the functional fiber of the present invention will be described.

The present invention is a mixture of potassium superoxide, sodium superoxide and dispersed in polyethylen glycole to produce a primary mixture to produce a primary mixture;

Generating a secondary mixture by adding aluminum hydroxide to the primary mixture to produce a secondary mixture;

A dispersion mixture generating step of adding a calcium carbonate, silica gel and zeolite to the polyethylene glycole dispersion which is the secondary mixture and dispersing it in a colloidal solution mixed with aromatic heavy oil to produce a colloidal dispersion mixture;

A mixture generation step of generating an oxygen-generating mixture by mixing calcium superoxide and iron dioxide with the dispersion mixture;

It is to include a coating step of applying by applying the oxygen generating mixture to the surface of the textile fabric.

In addition, the coating step further includes an antibacterial treatment step of applying a natural antibacterial and antiviral extract on the fiber fabric coated with the oxygen-generating mixture.

The primary mixture production step is gradually made into powder in a rubber grinding mill 100 parts by weight of environmentally friendly and harmless potassium superoxide. In addition, 45 to 55 parts by weight of sodium superoxide, which is environmentally friendly and harmless to humans, is slowly powdered in a rubber grinding mill. At this time, the powdering process of the potassium superoxide, sodium superoxide is not used because the metal grinding mill is dangerous.

100 parts by weight of potassium superoxide and 45 to 55 parts by weight of sodium superoxide are mixed in a stirrer operating at 80 rpm, and 280 to 320 parts by weight (about 3: 1 by volume) of a stabilizer that is harmless to humans is mixed with a magnetic stirrer. Stir slowly and disperse the powder mixture of potassium superoxide and sodoum superoxide at a rate of 10 g / min through an induction tube to produce a primary mixed solution.

(KO ₂ + NaO ₂ ) in PE (polyethylene glycole: C _{2n + 2} H _{4n + 6} O _{n + 2} ) → Dispersion

In the step of producing the secondary mixture, 85-95 parts by weight of aluminum hydroxide 8 g / min is completely dried (heated in a drying oven for at least 2 hours and vacuum-cooled) through a separate induction tube while stirring the produced primary mixture solution at 70 rpm. The mixture is added at a rate of to produce a secondary mixture.

(KO ₂ + NaO ₂ ) in PE (polyethylene glycole: C _{2n + 2} H _{4n + 6} O _{n + 2} ) → Dispersion → Al ₂ O ₃ powder (particle size: 10㎛)

In the dispersing mixture generating step, 25-30 parts by weight of calcium carbonate, 20-25 parts by weight of silica gel and 20-25 parts by weight of zeolite are dispersed in a polyethylene glycole dispersion, which is a secondary mixture, and dispersed in a colloidal solution mixed with aromatic heavy oil. . The dispersion mixture generating step is to stir the secondary mixture at a speed of 50 ~ 80rpm while adding 170 ~ 190 parts by weight of aromatic heavy oil through a separate induction tube to generate a colloidal dispersion mixture.

That is, 20-25 parts by weight of zeolite (BioChemika: product No. 96096: particle size <45㎛), 25-30 parts by weight of calcium carbonate (powder, 10㎛) and silica while stirring the secondary mixture at a speed of 50 ~ 80rpm 20 to 25 parts by weight of gel (230 ~ 400mesh: ~ 0.8 cm 3 / g: surface area 550) is added to the aromatic heavy through a separate induction tube.

(KO ₂ + NaO ₂ ) in PE (polyethylene glycole: C _{2n + 2} H _{4n + 6} O _{n + 2} ) → Dispersion → Al ₂ O ₃ powder (particle size: 10㎛) → Zeolite (grain size: 1.8㎛ STPP ) + CaCO ₃ (powder, 10㎛) + SiO ₂ (230 ~ 400mesh: ~ 0.8 cm3 / g: surface area 550)

The mixture production step is slowly stirring the secondary dispersion mixture at a speed of 36rpm while slowly adding 75 ~ 85 parts by weight of calcium superoxide through a separate induction tube, and slowly adding 35 ~ 45 parts by weight of iron dioxide through another induction tube Generate the generating mixture.

(KO ₂ + NaO ₂ ) in PE (polyethylene glycole: C _{2n + 2} H _{4n + 6} O _{n + 2} ) → Dispersion → Al ₂ O ₃ powder (particle size: 10㎛) → Zeolite (grain size: 1.8㎛ STPP ) + CaCO ₃ (powder, 10㎛) + SiO ₂ (230 ~ 400mesh: ~ 0.8cm 3 / g: surface area 550) → (CaO ₂ + Fe ₂ O ₃ )

The coating step is a step of attaching the oxygen generating mixture to the surface of the textile fabric, the oxygen generating mixture is evenly applied to the textile fabric by milling, and the vacuum fabric pressure is reduced by connecting the textile fabric coated with the oxygen generating mixture to a vacuum pump Under heat to 45 ° C. for 20 minutes. At this time, the speed of the milling is applied evenly to the 70rpm or less, and care should be taken because the heating temperature is raised to 50 ℃ or more.

The antimicrobial treatment step is to be treated after application of the oxygen generating mixture, in order to protect the human body from harmful bacteria, bacteria and viruses, environmentally friendly natural fungicides extracted from lotus leaf, Nelumbo nucifera, α-longifolene, pterodontoside In the step of addition, 7 to 13 parts by weight of the natural antibacterial and antiviral extracts extracted from the lotus leaf is applied to the coated textile fabric 100 parts by weight of the oxygen generating mixture by milling. The weight ratio of the natural antibacterial and antiviral extracts as described above, if the natural antibacterial and antiviral extracts are treated more than necessary, rather it may damage the health of the foot, it is to define the optimum ratio to prevent this.

In addition, the natural antibacterial and antiviral extract is composed of 4 to 6 parts by weight of Nelumbo nucifera, 2 to 4 parts by weight of α-longifolene, and 1 to 3 parts by weight of pterodontoside.

In addition, the natural antibacterial and antiviral extract may be mixed in the oxygen generating mixture prior to the coating step without the antibacterial treatment step and attached to the surface of the fabric.

The Nulembo nucifera and α-longifolene, pterodotoside is a natural antibacterial, antiviral compound that can not be extracted only from the lotus leaf, the present invention is used to accurately extract and extract only Nulembo nucifera and α-longifolene, pterodotoside from the lotus leaf.

Natural antibacterial and antiviral extracts from the lotus leaf are extracted as follows. Connect the Soxhlet extractor to the round flask and crush 100 parts by weight of the dried dry leaves in a cold dark place into 1.0∼2.0 mm sizes, add 500 parts by weight of secondary distilled water, and extract at a temperature of 100 ℃. Filter the extract extracted from distilled water with a glass filter, extract it from above in another round flask, add 110-130 parts by weight of anhydrous ethanol (C ₂ H ₅ OH) to the soft leaf solid component on the remaining filtrate, and connect the Soxhlet extractor. After extraction at a temperature of 80 ℃, the extract extracted from anhydrous ethanol is filtered with a glass filter.

The components extracted from the secondary distilled water and the components extracted from anhydrous ethanol are combined and fractionated on a high performance preparative liquid chromatography to obtain Nelumbo nucifera and α-longifolene and pterodontoside contained in traces in the aliquot.

The natural antibacterial and antiviral extract extraction process will be described in more detail by specific values. Connect a Soxhlet extractor to a 1000 ml round flask, and add 100 g of dried leaves to the round flask. Break down to a size of 2.0 mm, add 500 mL of secondary distilled water, and extract at a temperature of 100 ° C. The extract extracted from distilled water was filtered with a glass filter, and extracted from the above in another 1000 ml round flask, and 120 ml of anhydrous ethanol (C ₂ H ₅ OH) was added to the solid component of the lotus leaf on the remaining filtrate. After connection and extraction at a temperature of 80 ℃, the extract extracted from anhydrous ethanol is filtered with a glass filter.

The components extracted from the secondary distilled water and the components extracted from anhydrous ethanol are combined and fractionated on a high performance preparative liquid chromatography to obtain Nelumbo nucifera and α-longifolene and pterodontoside contained in traces in the aliquot.

The yields of Nelumbo nucifera and α-longifolene and pterodontoside extracted from lotus leaf as described above are shown in Table 1 below.

Table 1

Functional textile fabric of the present invention made as described above can be applied to various material fields such as shoe soles, feet, pants, coats, coats, mats, mat covers, cushions, etc., oxygen is automatically supplied from these materials It will be beneficial to the human body and smooth the metabolism.

Hereinafter, the present invention will be described in detail by way of examples.

Example 1

100 g of potassium superoxide was slowly powdered in a rubber grinding mill, 50 g of sodium superoxide was slowly powdered in a rubber grinding mill, and then 100 g of potassium superoxide and 50 g of sodium superoxide were mixed in a stirrer operating at a speed of 80 rpm.

Stirring 300 ml of polyethylen glycole slowly with a magnetic stirrer, the mixture of potassium superoxide and sodoum superoxide powder was dispersed at a rate of 10 g / min through an induction tube to produce a primary mixed solution.

Stir the produced primary mixed solution at 70 rpm and completely dry through a separate induction pipe (heated in a drying oven for 2 hours or more and vacuum cooled) to add 90 g of aluminum hydroxide at a rate of 8 g / min to generate a secondary mixture. It was.

Stirring the resulting secondary mixture 540g at a speed of 80rpm while zeolite (BioChemika: product No. 96096: particle size <45㎛) 25 parts by weight and calcium carbonate (powder, 10㎛) 30 parts by weight and silica gel (230 ~ 400mesh: ~ 0.8cm ³ / g: surface area 550) 25 parts by weight was added thereto, and 180 g of aromatic heavy oil was added through a separate induction tube to generate a colloidal dispersion mixture.

The colloidal dispersion mixture was stirred at a rate of 50 rpm, and 90 g of zeolite (BioChemika: product No. 96096: particle size <45) was added to a separate induction tube to generate a second dispersion mixture.

While slowly stirring the resulting secondary dispersion mixture at a speed of 36 rpm, calcium superoxide 81g was slowly added thereto through a separate induction tube, and 40.5 g of iron dioxide was slowly added through another induction tube to generate an oxygen generating mixture.

Example 2.

40 g of the oxygen-generating mixture produced according to Example 1 was applied on a milling machine rotating at a speed of 70 rpm on a polytetrafluoroethylene cloth cut to 22 cm in length and 8 cm in width, followed by 2.0 g of Nelumbo nucifera extracted from lotus leaf and 1.2 g of α-longifolene and 0.8 g of pterodontoside were applied by milling. At this time, the thickness of the polytetrafluoroethylene cloth was 1.0-1.2 mm.

The oxygen-coated mixture and the natural antibacterial and antiviral extract-coated fabric were heated to 45 ° C. under vacuum pressure for 20 minutes as described above, and then cooled to room temperature in a cooling desiccator. F. Chow and Kamerling, SE (Bacon F. Chow; Kamerling, SE The Journal of Biological Chemistry , 1933, pp 69-79.) And Troy Schmidtke; Measurements were made according to the Daniel White and Craig Woolard methods (Troy Schmidtke; Daniel White; Craig Woolard, Journal of Hazardous Materials , B64 , 1999, pp157-165.).

The sample was cut out with scissors in 1.5 cm width and 3.0 cm length, and 3.0 g of the cut sample was placed in a 50 ml round flask, and the flask was slowly stirred with a magnetic stirrer, and the flask was connected to the reflux cooling tube. The upper part of the reflux condenser was connected to the Liebig refrigeration conduit and the oxygen generated was transferred to a 100 ml measuring cylinder on the right side, and cooled around the induction tube with cooling water and 20 ml of phosphate buffer and 0.05 M oleic in the 100 ml measuring cylinder. 2.0 ml of acid and 0.2 ml of 0.1 M potassium hexacyanoferrate were charged.

After a certain time has elapsed since the start of the reaction with a stopwatch, the result of measuring the amount of oxygen generated by reading the point where the scale of the liquid in the right measuring cylinder has been pushed down is shown in [Table 2], [Table 3], and [Table 4]. same.

At this time, the oxygen generation reaction proceeded as shown in the following [Formula 1], the reactant was added to the first reaction, ₂ mol ratio KO ₂ and ₂ mol ratio of NaO ₂ and The amount of oxygen generated (7 / 2O ₂ mol) to CaO ₂ in a 1 mol ratio is measured.

[Formula 1]

2KO ₂ + ₂ NaO ₂ + CaO ₂ + ₃ CO ₂ → K ₂ CO ₃ + Na ₂ CO ₃ + CaCO ₃ + 7 / 2O ₂

[Table 2]

[Table 3]

Table 4

As shown in [Table 2], the functional fiber generating oxygen according to the present invention can be seen that the amount of oxygen generated per unit time is constant. In [Table 2], the ratio of O ₂ / K ₄ Fe (CN) ₆ is 0.35 in the first 20 minutes of measurement time, but is measured at 30 to 20 minutes and 30 minutes from thereafter. 1.16 ～ 1.32 shows almost constant ratio.

In addition, in [Table 3], the concentration of K ₃ Fe (CN) ₆ was reduced to one tenth of that of [Table 2]. However, as in [Table 2], the production rate per unit time was 1.02∼ after the first 30 minutes. It was almost constant at 1.03. In [Table 4], the concentration of K ₃ Fe (CN) ₆ was reduced to 1/20 compared to [Table 2], but as in [Table 2], the production rate per unit time was almost constant from 0.84 to 0.87 after the first 30 minutes. It was. These results demonstrate that the oxygen generation amount per unit time generated in the oxygen-generating functional fiber according to the present invention is constant.

Example 3

Using a sample prepared by the same method as in Example 2, the antimicrobial and antiviral effects were observed as follows. Barrow, GI (Barrow GI; Feltham RKA Manual for the Identification of Medical Bacteria , Cambridge University Press, Cambridge, UK.1933.) And Krogstad, DJ (Krogstad, DJ; Moellering, RC Combinations of Antibiotics, Mechanisms of Interaction against Bacteria , Chapter 11.In: Antibiotics in Laboratory Medicine , Lorian V. Ed., Williams and Wilkins, Baltimore / London, 1990: pp. 298-331.) And Sarkar, SA. (Sarkar, A .; Kumar, KA; Dutta, NK; Chakraborty, P .; Dastidar, SG Evaluation of in vitro and in vivo Antibacterial Activity of Dobutamine Hydrochloride , Indian Journal of Medical and microbiology , 2003, 21 (3), pp 172-178.) And Lopez, AI (Lopez, AI; Reins, RY; McDermott, AM; Trautner, B. W ,; Chengzhi, C. Antibacterial Activity and Cytotoxicity of PEGylated Poly (Amidoamine) Dendrimers, Molecular Biosystems, 2009, Vol . 5 , pp.1148-1156.) Was measured for the antimicrobial and antiviral effect.

For antimicrobial susceptibility testing, eight bacteria were screened according to Barrow GI; Feltham RKA Manual for the Identification of Medical Bacteria , Cambridge University Press, Cambridge, UK.1933. After confirming the characteristics of the bacteria, the minimum inhibitory concentration (MIC) was measured in the peptone solution.

Peptone solution was prepared as follows. Oxoid company's peptone 1.0% (w / v) is mixed with 0.5% (w / v) mixture made by dissolving pure NaCl (100%) in tertiary distilled water, and Oxoid company's nutrient broth 1.0% (w / v) v) and Hugo, Mueller Hinton broth agar 0.5% (w / v) was mixed. The mixed solution was adjusted to pH 7.2 ~ 7.4 to make a nutrient agar.

Antimicrobial susceptibility test was performed by the agar dilution method using the microbial medium prepared previously. The antimicrobial agent was diluted stepwise in Mueller-Hinton broth agar (pH 7.2 ~ 7.4) containing cations and added to each test tube. According to the macrodilution broth method, the concentration of 10, 20 and 50 100 mg was added by adding Mueller-Hinton agar (pH 7.2 to 7.4) containing the cation added to the solution prepared by standardizing the strain of 10 ⁶ CFU to 0.1 ml. / Ml.

Cut the sample into scissors 0.5cm long and 0.5cm long, and convert it to a concentration of 10, 20, 50 and 100 mg / ml, respectively, and dissolve it in nutrient agar. The incubator was incubated for 72 hours. Antimicrobial and antiviral susceptibility effects were observed in the following [Table 5].

[Table 5]

[Table 5] shows the antimicrobial and antiviral effects as Minimum Inhibitory Concentration: MIC ㎎ / ㎖,

It can be seen that the antibacterial and antiviral efficiencies of the oxygen-coated mixture and the material coated with the natural antibacterial and antiviral extracts are greater than those of the oxygen-coated mixture alone. For example, in the case of bacteria P. aeruginosa , the MIC, which exhibits antimicrobial and antiviral effects, on a material coated only with an oxygen-generating mixture shows 85 mg / ml. However, the MIC showing the antimicrobial and antiviral effects of the material coated with the natural antibacterial and antiviral extracts at the same time as the oxygen-generating mixture shows a very small value, 22-29mg / ml.

As such, the MIC showing the antimicrobial and antiviral effects of the material coated with the natural antibacterial and antiviral extracts simultaneously with the oxygen-generating mixture in all bacteria and viruses shows very small values.

In addition, in Table 5, when the converted concentrations of the natural antibacterial and antiviral extracts were changed to 10, 20, 50, and 100 mg / ml, the MIC values of the antimicrobial and antiviral concentrations were 50 mg / ml than when the concentrations were diluted. MIC value decreases when it becomes thick. However, as the concentration increased to 100 mg / ml, the MIC value increased. This indicates that the antimicrobial and antiviral effects of the material coated with the natural antibacterial and antiviral extracts at the same time as the oxygen-generating mixture prepared in the present invention are optimal at a concentration of 50 mg / ml.

From the above results, it can be seen that the material coated with the natural antibacterial and antiviral extracts at the same time as the oxygen generating mixture automatically generates oxygen at regular time intervals to help the human health and show antibacterial and antiviral effects.

The present invention is not limited to the above-described specific preferred embodiments, and various modifications can be made by any person having ordinary skill in the art without departing from the gist of the present invention claimed in the claims. Of course, such changes will fall within the scope of the claims.

Claims (13)

Apply an oxygen-generating mixture to the fabric,
The oxygen generating mixture is 100 parts by weight of potassium superoxide powder, 45 to 55 parts by weight of sodium superoxide powder, 85 to 95 parts by weight of aluminum hydroxide, 280 to 320 parts by weight of aromatic heavy oil, 280 to 320 parts by weight of polyethylene glycole, calcium carbonate 25 to An oxygen-generating functional textile fabric comprising 30 parts by weight, 20 to 25 parts by weight of silica gel, 20 to 25 parts by weight of zeolite, 75 to 85 parts by weight of calcium superoxide, and 35 to 45 parts by weight of iron dioxide.
The method of claim 1,
The fiber fabric is a functional fiber fabric that generates oxygen, characterized in that selected from natural fiber fabrics, synthetic fiber fabrics, Gore-Tex, functional cloth or polytetrafluoroethylene cloth.
The method of claim 1,
The oxygen-generating mixture is a functional fiber fabric for generating oxygen, characterized in that it further comprises 7 to 13 parts by weight of natural antibacterial and antiviral extract.
The method of claim 3,
The natural antibacterial and antiviral extract is a functional fiber fabric that generates oxygen, characterized in that 4 to 6 parts by weight of Nelumbo nucifera, 2 to 4 parts by weight of α-longifolene, and 1 to 3 parts by weight of pterodontoside.
The method according to any one of claims 1 to 4;
The functional textile fabric is a functional fiber fabric that generates oxygen, characterized in that the sole, socks, cloth, cushion, mat.
a primary mixture generating step of mixing potassium superoxide and sodium superoxide and dispersing in polyethylen glycole to produce a primary mixture;
Generating a secondary mixture by adding aluminum hydroxide to the primary mixture to produce a secondary mixture;
A dispersion mixture generating step of adding calcium carbonate, silica gel and zeolite to the polyethylene glycole dispersion of the secondary mixture and dispersing it in a colloidal solution mixed with aromatic heavy oil to produce a colloidal dispersion mixture;
A mixture generation step of generating an oxygen-generating mixture by mixing calcium superoxide and iron dioxide with the dispersion mixture;
Method for producing a functional fiber fabric for generating oxygen, characterized in that it comprises a coating step of applying by applying the oxygen generating mixture on the surface of the textile fabric.
The method according to claim 6;
The oxygen generating mixture is 100 parts by weight of potassium superoxide powder, 45 to 55 parts by weight of sodium superoxide powder, 85 to 95 parts by weight of aluminum hydroxide, 280 to 320 parts by weight of aromatic heavy oil, 280 to 320 parts by weight of polyethylene glycole, calcium carbonate 25 to 30 parts by weight, silica gel 20 to 25 parts by weight, zeolite 20 to 25 parts by weight, calcium superoxide 75 to 85 parts by weight, iron dioxide 35 to 45 parts by weight, characterized in that oxygen producing functional fiber fabric manufacturing method.
The method according to claim 6;
The primary mixture production step is 100 parts by weight of potassium superoxide powdered in a rubber grinding mill, 45 to 55 parts by weight sodium superoxide powder in a rubber grinding mill, 100 parts by weight of potassium superoxide and 45 to 55 parts by weight of sodium superoxide in a stirrer Mixing and stirring 280-320 parts by weight of polyethylen glycole with a magnetic stirrer while dispersing the potassium superoxide and sodoum superoxide mixture powder at a rate of 10 g / min through an induction tube to generate the oxygen, characterized in that to produce a primary mixed solution Functional textile fabric manufacturing method.
The method according to claim 6;
In the step of producing the secondary mixture, the secondary mixture is added by adding 85 to 95 parts by weight of aluminum hydroxide, completely mixed (heated in a drying oven for at least 2 hours, and vacuum-cooled) through a separate induction pipe while mixing the generated primary mixture solution. Method for producing a functional textile fabric generating oxygen, characterized in that to produce.
The method according to claim 6;
In the coating step, the oxygen-generating mixture is applied to the fiber fabric by milling, and the oxygen-generating mixture is coated with the fabric to which the oxygen-coated oxygen is heated for 20 minutes at 45 ° C. under reduced pressure. Method for producing functional textile fabrics.
The method according to claim 6;
The coating step is a method for producing a functional textile fabric producing oxygen, characterized in that it further comprises an antibacterial treatment step of applying a natural antibacterial and antiviral extract to the fiber fabric coated with the oxygen generating mixture.
The method of claim 11;
The natural antibacterial and antiviral extracts are finely crushed into 100 parts by weight of 1.0 to 2.0 mm of dried dry leaves in a cool dark place, and extracted at a temperature of 100 ° C. by adding 500 parts by weight of secondary distilled water.
The extract extracted from distilled water is filtered with a glass filter,
110-130 parts by weight of anhydrous ethanol (C ₂ H ₅ OH) was added to the lead leaf solid component on the remaining filtrate, and the Soxhlet extractor was connected and extracted at a temperature of 80 ° C. Filtered with
The components extracted from the secondary distilled water and the components extracted from anhydrous ethanol are combined and fractionated on a high performance preparative liquid chromatography, and a small amount of Nelumbo nucifera and α-longifolene contained in the aliquot and oxygen, characterized in that pterodontoside is obtained. Method for producing functional textile fabrics.
The method according to claim 11 or 12;
The natural antibacterial and antiviral extract is Nelumbo nucifera 4 to 6 parts by weight, α-longifolene 2 to 4 parts by weight, pterodontoside 1 to 3 parts by weight of oxygen-producing functional textile fabric manufacturing method.

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