KR101096136B1 - Water-solubility adhesive and resin particle for real flower decoration and decoration method therof - Google Patents

Abstract

PURPOSE: A water-soluble adhesive for decorating rear flowers, and a real flower decorating method using thereof are provided to secure the freshness of the real flowers for a long time. CONSTITUTION: A water-soluble adhesive for decorating rear flowers is obtained by the following steps: inserting a latex mixture containing 100g of natural latex, 30g of water, and 2g of ammonia water into a stirrer; dripping a methyl methacrylate mixture containing 25g of methyl methacrylate and 1g of oleic acid into the latex mixture for 1 hour; aging the mixture for 1 hour to obtain a first compound; and dropping a tetraethylenepentamine mixture containing 1g of tetraethylenepentamine and 10g of water into the mixture for 1 hour.

Description

Water-solubility adhesive and resin particle for real flower decoration and decoration method therof}

The present invention relates to a method for decorating flowers using a water-soluble adhesive for a decorative flower and a water-soluble adhesive for a decorative flower. More specifically, by applying a unique decoration not found at all in a natural state to a living plant, it is possible to increase the added value of commercial properties. At the same time, the freshness of fresh flowers can be maintained for a long time.

Natural flowers, including roses and various other flowers, give the plant its own color.

These flowers are used in a variety of applications, such as flower arrangements, but there is a limit in providing a variety of visual effects to the consumer due to the limitation of the color as mentioned above.

In order to solve this problem, various methods have been studied in the flower industry.

In recent years, the dyeing method of spraying the dye solution to the petals is used, but this is only limited to white roses.

In order to solve the above-mentioned problems of the conventional method of dyeing petals, the present inventors have researched and developed the present invention, and in the present invention, by applying a unique decoration that is not found at all in the natural state to living plants to increase the added value of merchandise. The present invention has been completed in view of the technical problem of the present invention by providing a flower decorating method using a water-soluble decorative adhesive for a flower arrangement and a water-soluble decorative adhesive for a flower arrangement that enables to maintain the freshness of the flower for a long time.

In order to solve the problem, the present invention provides a water-soluble adhesive agent on the surface of the flower, thereby making it possible to maintain the freshness of the flower for a long time.

And the present invention provides a powder of decorative resin particles of various sizes that can be adhered by the water-soluble adhesive, or coated decorative resin particles coated with a coating agent comprising a functional material is applied to a variety of colors and regardless of the color of the flowers Image production was made possible.

In addition, functional materials such as decorative resin particles, coated decorative resin particles, or glitter (rainbow or hologram) can be scattered in an airtight container, and a new method of adding a water-soluble adhesive with a water-soluble adhesive can be found in existing bio-dyeing. The unique image is missing.

According to the flower decorating method using the flower decorating water-soluble adhesive and the flower decorating water-soluble adhesive provided in the present invention has the following effects.

-As adhesive is water soluble, it can improve working environment.

-After applying the adhesive, the decorative resin particles can be fixed and adhered in a few minutes, which greatly shortens the working time, thereby ensuring the freshness of the plant.

-As it can provide original colors that cannot be produced by existing dyeing methods, it can increase the added value of productability such as high-quality products.

-Dyeing was limited to the conventional white roses, but the present invention can be used regardless of the type or color of flowers.

Figure 1, Figure 2 is a picture of a bio flower showing an example of decorating the flowers by the decoration method of the flowers using the water-soluble adhesive agent for decorative flowers in the present invention

An embodiment of the flower decorating method using the flower decorating water-soluble adhesive agent and the flower decorating water-soluble adhesive agent provided by the present invention will be described with reference to the accompanying drawings.

The present invention provides a water-soluble adhesive agent (adhesive that maintains a sticky state such as a tape) on the surface of the flower, to maintain the freshness of the flower for a long time, and powdered in various sizes that can be adhered by the water-soluble adhesive agent. It is possible to provide a variety of colors and images by providing a decorative decorative resin particles containing a decorative resin particles or a functional material.

In addition, it is a new method of dispersing functional materials such as decorative resin particles, coated decorative resin particles, or glitter (rainbow or hologram) in a sealed container and injecting the flowers with water-soluble adhesives. The unique image makes it possible to produce.

1. Water soluble adhesive

(1-1) latex adhesive

Preferred embodiments of the water-soluble adhesive agent provided by the present invention include a latex mixture of natural latex, water and ammonia water, an MMA mixture of methyl methacrylate (MMA) and oleic acid, and It is prepared by mixing a TEPA mixture of tetraethylenepentamine (TEPA: tetraethylenepentamine) and water.

As the composition ratio of each mixture, a latex mixture is prepared by mixing 100 g of natural latex, 30 g of water, and 2 g of ammonia water by weight.

Natural latex (natural latex) is a plant-based adhesive that adheres to the surface of the natural flowers, the tissues similar to the natural plants to help maintain the freshness of the natural flowers.

MMA compound is prepared by mixing 25 g of methyl methacrylate (MMA) and 1 g of oleic acid.

Methyl methacrylate increases transparency to maintain the inherent color of the flower while the adhesive is applied, and serves to improve adhesion.

And oleic acid serves to delay the adhesive from curing quickly in the air.

TEPA compounds are mixed by mixing 1 g of tetraethylenepentamine (TEPA) and 10 g of water.

Tetraethylenepentamine plays a role in removing odors generated when unreacted to latex and methyl methacrylate.

The adhesive prepared as described above is to provide a viscosity to adhere the adherend while the latex, which is a natural adhesive, is slowly vulcanized while water is vaporized after being applied to the organism.

The preparation procedure of the latex adhesive is first performed by mixing the MMA mixture with the latex mixture, and mixing the TEPA mixture with the primary mixture obtained by the mixing.

In the mixing step of mixing the MMA mixture with the latex mixture, the MMA mixture is mixed while dropping for 1 hour while the latex mixture is added to the stirrer, followed by aging for 1 hour to prepare a primary mixture.

This is to delay the excessive chemical reaction of the latex mixture and the MMA mixture. If the MMA mixture is rapidly added and stirred, the primary mixture does not show the flowability as water, but has a viscosity in a gel state.

Mixing the TEPA mixture in the primary mixture of the MMA mixture in the latex mixture is mixed with the TEPA mixture for 1 hour while dropping the TEPA mixture in the primary mixture mixed in a stirrer as described above.

This is also for delaying excessive chemical reaction of the primary mixture and TEPA mixture, and when the TEPA mixture is rapidly added and stirred, the adhesive does not show the flowability as water and has a gel viscosity. do.

(1-2) acrylic adhesive

Other embodiments of the water-soluble adhesive agent provided by the present invention include methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (2-Ethyl) and 2-ethylhexyl acrylic acid (2-Ethyl). Hexylacrylate (BAM) Butyl Acrylate monomer (BAM), vinyl acetate monomer (VAM: vinyl acetate monomer) and acrylic acid (acrylic acid) mixed with a mixture of water and a nonionic surfactant (trade name: NP-10 Nonidet P-10) and an anionic surfactant (Dodecyl Benzene Sulfonic Acid) mixed with a surfactant mixture, water and a catalyst calcium persulfate (trade name; Potassium Persulfate (KPS) The mixture is composed by mixing sequentially.

The composition ratio of each mixture was 5.5 g of methyl methacrylate (MMA), 11.5 g of 2-hydroxyethyl methacrylate (2-Ethyl hexylacrylate), and 2-ethylhexyl acrylate. 250g, 160g of butyl acrylic acid monomer (BAM), 10g of vinyl acetate monomer (VAM) and 6g of acrylic acid (acrylic acid) are prepared.

The methyl methacrylate is to increase the transparency to maintain the intrinsic color of the flower in the state where the adhesive is applied serves to improve the adhesion.

The 2-hydroxyethyl methacrylic acid is an OH group imparting agent, 2-ethyl hexyl acrylic acid and butyl acrylic acid unit is to act as an adhesive as a tackifier.

And the vinyl acetate unit improves the adhesion, acrylic acid serves to increase the adhesion of the adherend.

A surfactant mixture was prepared by mixing 320 g of water, 9 g of a nonionic surfactant (trade name: NP-10 (Nonidet P-10), and 5 g of an anionic surfactant (Dodecyl Benzene Sulfonic Acid).

The surfactant is used in a state of being completely dissolved in water of 50 ± 5 ℃, and serves to help the acrylic mixture is dispersed in water.

A catalyst mixture was prepared by mixing 80 g of water and 1.6 g of calcium persulfate (trade name; Potassis Persulfate (KPS)).

The catalyst plays a role in causing the polymerization reaction while forming active radicals in a medium containing units contained in the acrylic mixture.

The acrylic adhesive prepared as described above is to provide viscosity to adhere the adherend while the acrylic adhesive is slowly vulcanized while water is vaporized after being applied to the organism.

The preparation procedure is first performed by mixing the surfactant mixture in the acrylic mixture and mixing the catalyst mixture in the primary mixture obtained by the mixing.

The step of mixing the surfactant mixture to the acrylic mixture is a mixture of stirring and dropping the surfactant mixture for 1 hour while maintaining the temperature of 75 ~ 80 ℃ while the acrylic mixture in the stirrer and then aged for 1 hour 1 Prepare a tea mixture.

This is to delay the excessive chemical reaction of the acrylic mixture and the surfactant mixture. If the surfactant mixture is rapidly added and stirred, the primary mixture will have a gel viscosity, so be careful.

In the step of mixing the catalyst mixture in the primary mixture, while stirring the temperature of the mixture mixture while stirring 2/3 of the total weight of the catalyst mixture for 4 hours while maintaining the stirring temperature of 75 ~ 80 ℃, aged for 1 hour, the remaining 1/3 While stirring while maintaining the stirring tank temperature at 75 ~ 80 ℃ stirred mixing for 2 hours and slowly cooled to 50 ℃ or less.

This is also to delay excessive chemical reaction of the acrylic mixture and catalyst.

2. Decorative resin particles and decorative coating resin particles

The decorative resin particles which adhere to the flowers using the water-soluble adhesive agent is used by processing a transparent or white acrylic resin or glitter in the form of powder particles.

It may be provided by a method of grinding the shiny colored film (commonly known as 'hologram' in the industry) or transparent film (commonly known as 'rainbow' in the industry).

The size of the decorative resin particles is composed of a powder, such as a powder or a particle shape of 0.05 ~ 1mm in diameter so that it can be easily blown by the wind in a closed space.

In addition, the decorative coating resin particles form a coating layer together with a functional material on the outside in the state of processing the acrylic resin decorative resin particles as described above in the form of powder particles.

As the functional material may be used a mixture of one or more of a Zion pigment, which changes color depending on temperature, a luminous pigment, which changes color depending on light, photoluminescent pigment, and the like.

The coating agent for coating a functional material on the powder particles is formed by mixing alcohol (alcohol), polyvinylbutyral (polyvinylbutyral) and a small amount of pigment (pigment).

As the composition ratio, 95 g of alcohol (alcohol), 5 g of polyvinylbutyral, and a small amount of pigment are mixed. The ratio of the pigment is 0.1g-2g is suitable, and does not deviate much from this range.

The alcohol may be any one of ethyl alcohol and methyl alcohol, but it is preferable to use ethyl alcohol, which is harmless to the human body.

The alcohol is evaporated after coating, and polyvinyl butyral is applied thinly coated on the outside of the decorative resin particles.

3. Flower decoration method using flower decoration resin

According to the present invention, there is provided a method of decorating a flower using a flower for decorative flowers, comprising: applying an adhesive to the flower, drying the flower to which the adhesive is applied, and fixing a resin particle to fix the decorative resin to the flower to which the adhesive is applied. It is done sequentially to be able to decorate the flowers in a short time.

1) Application of adhesive

Adhesive application is provided by spraying, which is widely used in common dyeing methods, with the possibility of selectively spraying all or a portion of the flowers, including well-groomed petals.

2) Resin particle fixing step

In the state in which the adhesive is fixed as described above, the decorative resin particles or the decorative coating resin particles are fixed to the adhesive. In some cases, you may want to fix pieces such as glitter (rainbow or hologram).

To this end, the decorative resin particles are first scattered using air in a sealed cylinder, and the resin applied to the adhesive is passed through the barrel so that the resin adheres to the adhesive.

When the decorative resin particles are to be attached a lot, the drying time is shortened and the flowering residence time of the barrel is increased.

Example 1

The water-soluble adhesive agent was apply | coated to the rose | membrane, and the resin particle containing a luminous pigment was passed through the barrel.

As a result, as shown in FIG. 1, it can be seen that the resin particles including the luminous pigment applied to the surface of the rose in a dark place emit light.

Example 2

The water-soluble adhesive agent was apply | coated to the rose and passed the barrel through which the resin particle which consists of hologram pieces scatters.

As a result, as shown in Figure 2 it can be seen that the image of the resin particles composed of holographic pieces on the surface of the rose is produced.

Although the detailed description of the present invention has been described with respect to specific embodiments, it is possible to appropriate modifications within the scope without departing from the technical scope of the present invention. Therefore, the protection scope of the present invention is not limited to the embodiments described in the foregoing specification, and the protection scope of the present invention also extends to the equivalent means related to the following claims.

Claims (6)

A MMA compound containing 25 g of methyl methacrylate (MMA) and 1 g of oleic acid was added to a stirrer while a latex mixture containing 100 g of natural latex, 30 g of water, and 2 g of ammonia water was added to the stirrer. Mixing while dropping (dropping) and then aged for 1 hour to prepare a primary mixture,
The water-soluble adhesive agent for biochemical decoration, characterized in that the TEPA compound mixed with 1 g of tetraethylenepentamine (TEPA: tetraethylenepentamine) and 10 g of water was prepared by dropping the mixture for 1 hour.
5.5 g of methyl methacrylate (MMA), 11.5 g of 2-hydroxyethyl methacrylate, 250 g of 2-ethylhexylacrylate, and butylacrylic acid monomer ( BAM: Butyl Acrylate monomer (160g), vinyl acetate monomer (VAM) 10g and acrylic acid (6g) mixed acrylic mixture mixed in agitator to maintain a temperature of 75 ~ 80 ℃, 320g of water and nonionic interface Surfactant mixture containing 9 g of an active agent (trade name; NP-10 (Nonidet P-10) and 5 g of anionic surfactant (Dodecyl Benzene Sulfonic Acid) was stirred for 1 hour while dropping. After mixing for 1 hour to prepare a primary mixture,
While maintaining the temperature of the stirring tank at 75 ~ 80 ℃ stirring stirring while dropping 2/3 of the total weight of the catalyst mixture mixed with 80g of water and 1.6g calcium persulfate (trade name; Potassisium Persulfate (KPS)) for 4 hours After aging for 1 hour, the remaining 1/3 was mixed by stirring while dropping for 2 hours while maintaining the temperature of the stirring tank at 75 ~ 80 ℃, and gradually cooled to 50 ℃ or less, water-soluble decorative adhesives for natural flowers .
An adhesive applying step of selectively spraying a water-soluble adhesive on all or part of the flowers including the groomed petals;
The step of fixing the resin particles in which the decorative resin particles are adhered to the adhesive by passing through the barrel through the barrel of the adhesive-coated flower in a state where the decorative resin particles are scattered using air in the sealed container. Natural flower decoration method using decorative water-soluble adhesive agent.
The method of claim 3, wherein
The decorative resin particles are natural or decorative decoration method using a water-soluble adhesive adhesive for decorative flowers, characterized in that the transparent or white acrylic resin in the form of powder particles or granules, or selected from pulverized glitter.
The method of claim 4, wherein
Further forming a coating layer on the surface of the resin particles,
The coating layer is a mixture of one or more of a Zion pigment, a light pigment, a photoluminescent pigment to an adhesive formed by mixing 95 g of alcohol (alcohol), 5 g of polyvinylbutyral, and 0.1 to 2 g of pigment. Natural flowers decorative method using a water-soluble adhesive for decorative flowers, characterized in that. delete

Images