KR100964917B1 - Loess korean paper manufactural system - Google Patents

Abstract

The present invention relates to a method for manufacturing a papermaker's papermillicus based on papermillic fiber and loess, wherein the ratio of papermill to papermaking wallpaper and papermill papermaking using loess and quartz has been too low, The present invention is based on the fact that the present invention is characterized in that in the case where the surface of the paper is not stable due to the loose powder coming off from the paper fiber produced, 50% (weight ratio), water and daphnia are put into a trough and mixed with a rod to mix well. Then, the feet of the paper are immersed in a trough to swing back and forth, And a second step of spraying the water to the surface of the sheet, and a second step of spraying the water, After the third step of removing the water by lifting a heavy stone or a bundle of stones, Korean paper of yellow clay was removed from the heated steel sheet one by one and dried in a sequential step in a fourth step, whereby the water repellent agent was surface- The humidity control ability capable of absorbing moisture is reduced while the durability is lowered such that cracks are generated in the humidity control process and the surface is floated without interfering with the far-infrared radiation emitted from the duck fiber and the loess And a method for manufacturing a yellow clay paper.

Duck fiber, loess, water repellent, daphnia, dyes, yellow ocher, wood chips

Description

Loess korean paper manufactural system

More particularly, the present invention relates to a method for manufacturing a clay loam based on clay fiber and loess.

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While humans enjoy economic growth and prosperous living benefits due to industrial development, they are threatened by the destruction of the natural environment and exposure to various pollution.

Therefore, environmental protection and pollution prevention policies are carried out, and there are less pollution in the production process of products from industrial sites and consumers, and eco-friendly products that are easily decomposed in nature after disposal, and health supplement products to protect the health from pollution and various diseases It is receiving favor from consumers.

Recently, studies on traditional products using materials and traditional techniques that have been used since the ancient times as environment friendly products are being actively conducted. Accordingly, the present invention is to propose a method of producing a yellow clay wallpaper containing a large amount of far infrared rays, a good hungry property, a humidity control ability, a good ventilation ability, and the like.

The mackerel and the loess which are the main ingredients of the present invention will now be described.

First, the main ingredients of Korean paper mulberry are processed woody parts and barked bark parts of mulberry trees such as mulberry (mulberry), mountain mulberry (mulberry), mulberry mulberry and mountain mulberry The obtained fiber is called a bast fiber.

Hanji is long fiber of hemp bast fiber. It is strong and tough, does not tear well, smells odor, material is very smooth, ventilation is good, and it can be made by putting various patterns. It is easy to put on paints, It has the advantage of easy to manufacture, but has drawbacks in that it is weak in water, has a lot of dust on the ground for a long time, has good ventilation and is not good for winter cold,

Also, since the pores of Korean paper act as a filter, air purifying ability and wood are breathtaking. Also, it has a function to absorb it when the humidity of the surroundings increases, and the light is known to have the ability to reflect far It is known to have excellent long-term preservation ability as a neutral region.

When you refer to Doosan World Encyclopedia (EnCyber), you can see how to make Hanji using the "mulberry tree" or "samji mulberry tree" as a raw material. They are bundled with a bundle of trees and placed in a cauldron The dried peel is then poured into the water again, then the foot is touched with the foot, only the white endothelium is removed, and the lye is mixed with the lye and boiled for more than 3 hours. Put the sticky water that is squeezed out from the root of the dapple, mix it well and let it loosen, then float it with the paper [liquid] by the foot [簾] .If there are various according to the order of the consumer, × 2.4m is the main type.

The main production area is Jangseong-gun, Jeollanam-do, and the representative place is Jangseong-eup (蜈 蜈) village where Jangseong-eup is located.

The name and quality are different according to the use of hanji. For example, if it is used at the door, it is used for paper papers, genealogy, disgrace, and the seal of the old paper. If the copy paper is used, then the sari or flower is used for painting paper and greeting cards and wedding invitations. It is called "moss paper". "The traditional manufacturing method is described.

On the other hand, loess is a sediment composed mainly of particles with a diameter of 0.002 ~ 0.005mm. It has a yellowish brown color and does not receive weathering well. It mainly contains quartz. In addition, it contains calcite containing pyroxene and amphibolite. Far infrared rays It absorbs a large amount, and it is known that it has far-infrared radiation effect, room temperature and humidity control function, antibacterial and deodorizing action, heavy metal adsorption action.

Far-infrared rays are a kind of electromagnetic waves with a longer wavelength than the red light of the visible ray, and have a short wavelength. It is characterized by strong resonance (resonance) and resonance (resonance) action of molecules of organic compounds (not shown). In addition, when it comes into contact with moisture and protein molecules that make up the cell, the cells are shaken 2,000 times per minute to activate the cell tissue to prevent various diseases such as anti-aging, metabolism promotion and chronic fatigue It is said to be helpful.

As described above, loess is used in various fields such as housing and building materials, kitchen utensils, textiles, clothes, bedding, medical instruments, and jjimjilbang.

As mentioned above, both Hanji and Hwangto are environmentally friendly, and they are useful for health and are used in various fields such as housing and building materials, packaging materials, clothing, bedding, etc. They are also marketed as Hanji wallpaper, However, most of the products that have been transferred with patterns and shapes using the existing vinyl, and most of them have not been able to utilize the useful functions of the paper due to the coating, varnish, and waste paper when the paper is applied with some wallpaper and paperboard.

In addition, among the products mainly made of loess, there are beds, coats and mats. In general, the loess is weakly bonded to each other and is molded using an adhesive. Some products are coated with synthetic resin to prevent loess In many cases, the radiation effect of far infrared rays can not be obtained.

For reference, the technique of mixing yellow soil with hanji and applying binding force to yellow soil was introduced as "Registered Patent Registration No. 10-0259747 of Korea Patent Office Registration No. 10-0259747" How to make fuji with mixed wallpaper of ocher and elvan.

The present inventor has succeeded in fabricating thirty different pieces of fuji with difficulty in the same manner as the description of the invention patent. However, since the ratio of the fleece fiber is too low, the papermaking is not easily performed, It was difficult to produce Korean yellow clay, and it was found that the surface was not stabilized because yellow clay was removed from the produced paper.

In addition, steam was applied to the produced Fuji at a distance of about 3 cm from the electric steam iron to make a wet state, and drying in the shade was repeated twice, so that a severe crack was generated, It was inadequate to put it in a place where it was abandoned and wet with yellow soil buried in contact with people.

At the time of applying the paste, the moisture of the grass was instantaneously absorbed and severely sagged, requiring a skilled construction technique.

Therefore, in order to solve the above problems, the present invention has been made to solve the above problems by using the advantage of the loess which is known to have far-infrared radiation effect, room temperature and humidity control action, antibacterial and deodorizing action, heavy metal adsorption action, The present invention aims to provide a practically usable clay paper having high workability and durability while maximizing the advantage of good ventilation.

In order to achieve the above-mentioned object, the present invention provides a method for manufacturing a yellow clay loam based on bast fiber and loess, comprising the steps of preparing a material, a papermaking step, a water draining step, a drying step, a dyeing step, .

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The main materials to be prepared in the material preparation step are dac fiber fiber liquid, ocher suspension and dac lot, and the sizing agent, wood chips and dyestuff are prepared as follows.

[Preparations of Dachen fiber stock solution]
Dac Fiber Filler is a traditional folklore technique that is used to cut the bark from the bark of a year old bark that has been grown in the year since December every year, [Stage 1: Saffi production stage].

The white rice produced in the first step is cut to a proper size and cut into a proper size and then put in a kettle and boiled for 2 to 3 hours with water, caustic soda or soda ash. [Step 2:

Instead of caustic soda and soda ash, in the past, we used lye that poured water on rice straw, buckwheat flour, soybeans, etc., but the lye is not used well in modern times.

Washing the lye with water flowing through the safflower which is boiled in the second step, then dipping the safflower in cold water and evenly shaking it for 2 to 3 days while sunlight is bleached and sunshine bleaching - [Step 3: Bleaching]

Removing the remaining skin flaws in the white skin obtained in the third step; [Step 4: damping step]

Squeeze out the water of the bag which has undergone the fourth step and place it on a flat surface such as a pit or a wooden board and beat it for 2 to 3 hours. [Step 5:

In the defatting step, it is possible to perform a mechanical operation instead of a manual operation using a conventional defrosting machine used in the manufacturing process of the sunny spot.

Step 5 is a step of flowing the lignin, which is a fine fiber, while flowing the dod fiber, which is finished in the fifth step, while wrapping it in a fine cloth and shaking it well in flowing water - [Step 6: washing step].

Since the lignin discolors and promotes oxidation of the paper, it shortens the life of the paper and entangles between the long fibers to make the paper hard. Therefore, it is necessary to remove as much lignin as possible to make a good paper.

After completion of the process of preparing the fiber fiber stock solution in the sequential steps from the first step to the sixth step, the fiber paper stock solution is prepared in an arbitrary container.

[Preparation stage of clay suspension]
The loess is the step of drying and crushing the selected loess soil - [Step 1: crushing].

Immersing the first-stage ground loess in water for at least one hour - [second stage immersion step].

And filtering the yellow loess obtained through the second step using a cloth such as a gravel as a filter medium - [third filtering step].

Step 3 is a step of sterilizing the microorganisms in the clay by adding the yellow loess that has been processed in the third step into a pot and boiling them.

Collecting the filtrate which has passed through the filter material of the third step and collecting the filtrate in the container to settle the precipitate; [Step 4: precipitation step].

In order to remove the foreign matter such as tree roots or humus which is mixed with the ocher powder, the ocher soil is precipitated through the above-mentioned step 4, Discard and prepare loess material.

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In the present invention, in the present invention, there is no difference in the shape of the hanji and the outer shape of the hanji mixed with the duck fiber in the papermaking stage, but the far infrared rays are mixed in a large amount It is possible to manufacture a Korean paper having a higher far-infrared radiation amount by preparing a yellow paper by mixing the yellow paper and the fiber paper stock solution with the above-mentioned yellow paper.

[Preparation phase]
Daphnia is a perennial herbaceous plant belonging to the family Arugacea, which refers to 黄 喀 葵 (daphnia). Dapper roots contain many mucus such as galactose, elamanose and galactooligosaccharide. Is essential for the manufacture of Korean paper, and it has the function of preventing the long fibers from sinking in the tank, controlling the flow speed of water on the feet, adjusting the lipid level by using the grass, and restoring the wetland accumulated on the ground plate There is a function to prevent sticking after squeezing.

The present inventors have found that the use of polyacrylamide (PAM) as a dispersant in the market instead of dodecahedra is not suitable for the production of oily soil due to the effect of the dispersant due to the effect of loess, It is possible to mix the materials and use them as dispersants, but the use of PAM alone is difficult.                     

[Others]
Others include wood chips, dyes and sizing agents.

First, the wood chips are pine trees, pine trees, fir trees, deciduous trees, conifer trees, bamboo trees, German spruce, spruce trees, It is possible to use wooden chips independently or to mix two or more kinds of wooden chips by arbitrarily choosing wooden chips such as Japanese pine, apricot, chestnut tree, pine wood, oyster, thyme, quince and magnolia.

Since the surface roughness of the finished paper is determined according to the size of the wood chip particles, the size of the particles can be adjusted according to the use of the finished yellow clay paper. And can be arbitrarily determined depending on the degree of use.

The wood chip has the effect of giving the pattern of the Korean paper of the present invention and the effect of releasing the far infrared rays of the wooden chip and the smell of the loess that is emitted from the loess in the low pressure, In sunny weather, it emits a gentle fragrance to provide a useful fragrance for health.

It is said that the tree is fragrant in order to protect itself from insects during the growth process. It is said that this fragrance is called peton cheeid, and the tree is evacuated for 1,000 years even after being cut. Peton cheeid has aromatherapy or aroma It is being introduced as a therapy and is becoming an alternative medicine.

In recent years, a microencapsulation technique has been developed to delay the divergence of the essential oil used in the fragrance therapy, and it has been applied in paper and textile industries. Thus, it is possible to use the microcapsule-treated essential oil in Korean paper of the present invention.

The other woody vinegars are prepared by diluting with water to a concentration of wood vinegar of 10 to 60% in water.

The wood vinegar is obtained by liquefying the smoke from the process of making charcoal from wood. It is a strong acidic liquid of pH 3, which is mainly composed of acetic acid.

The vinegar aqueous solution has an acidity, so that it has an effect of suppressing the growth of fungi or microorganisms caused by moisture and increasing the lifespan of the fiber.

In addition, dyestuffs among dyestuffs are hydrophilic materials of dyad fibers and yellow loam, so that dyes can be fixed without auxiliaries because they have affinity with dyes basically. In the case of deep dyes, auxiliaries for bonding dyestuffs to dyad fibers and loess are required. Myeongseong, such as lye soda ash, alum and ferrous sulfate, is used.

Natural dyestuffs are blue dyestuffs. Yellow dyestuffs are natural dyestuffs, such as gardenia, gray or black dyes, and yellowish dyes, which are representative natural dyestuffs. More than 100 species extracted from leaves, flowers, The color is selected according to the symbol of " color "

Finally, the water repellent agent, which is one of the important elements of the present invention, can be generally used as a water repellent agent, such as silicone, water-based, wax-based, zirconium-based, ethylene urea-based, methinolamide-based, pyridinium-based or metal soap-based water repellent.

Duck fiber and loess have the advantage of moisture control ability, but they have the disadvantage that cracks occur due to repeated shrinkage and expansion in the humidity control process, and the surface is floated and durability is lowered.

In order to solve these disadvantages, it is necessary to coat water-repellent agent on the soil of yellow clay, that is, to coat colloidal material with water-resistant property on the duck fiber and the loess so as to fill the gap between the duck fiber and the loess and the moisture between the duck fiber and the loess, .

It is a known fact that the water repellent agent has the same air permeability as that of waterproofing agent or varnish. Thus, the humidity control ability of Korean paper of Hwangto is somewhat lower than that of conventional Korean paper and loess, There is no crack in the surface, the surface is not damaged by friction, the dust is not adhered well, and it is prevented from getting dirty, and it has a surface gloss effect and air permeability like varnish coating or coating, There is an effect that the fragrance of the wood chip is gradually discharged without interfering with the far-infrared radiation of the chip.

Conventionally, there have been water-repellent processes such as paper cups and packaging materials by surface-sizing using wax or paraffin in a paper factory. However, in the case of long fibers such as fiber or garment fiber, a thick film is required for surface sizing by wax or paraffin, And the surface is easily scratched. Traditionally, there has been a method of feeding oil to the paperboard, but the drawback is that the color becomes cloudy and it is difficult to dry and remove the oil on the surface.

Therefore, in the present invention, the water repellent applied to textile fibers and the water repellent for construction such as cement bricks are suitable for the paper of the present invention. Particularly, the water repellent agent and the silicone repellent agent are more suitable.

As a result of using the conventional silicone water repellent and a water-based water repellent distributed on the market in the finished product of the present invention, the inventors of the present invention have found that both of the products are excellent in water repellency and sprayed with water in a state of flowing down water, The surface did not crack, and the fluorinated water repellent had the effect of pushing the oil as well as moisture.

On the other hand, when producing yellow clay paper for printing or painting, it is possible to obtain engine sizing (inner sizing) effect by mixing loess and duck fiber in a jug and then adding rosin and other sizing agent and stirring for at least 10 minutes, So that a double sizing effect can be obtained.

The material preparation step was completed as described above.

After completing the material preparing step, the process according to the method for producing the yellow clay will be described in the following examples.

[Example 1]

Add 50 ~ 80% (weight ratio) of dodecane fiber and 20 ~ 50% (weight ratio) of loess suspension to the bag, add water and daphnia into the bag, stir with a rod and mix well, The first step is to shake the left and right and remove the yellow soil.

And a second step of spraying the water repellent agent on the Korean soil of the first step.

The third step is to put the weft or thread as a pillow between the paper of the second step and piled up as a pillow, put it between the planks when it reaches a certain height, and then lift a heavy stone or a shank to remove water.

After completing the above 3 steps, Hanji (Korean paper) is removed from the heat-treated steel sheet and dried.

[Example 2]

In the case of the bag, add 50% to 80% (weight ratio) of dodecane fiber and 20 to 50% (weight ratio) of the loess suspension, and stir in drippings and daphnia into a tongue and stir well. Then stir the paper- The first step to release Korean soil.

After the above steps are completed, the second step is to put the pillow in between the pillars and the pillow or the pillow, put the pillow in between the pillars, and then remove the water by lifting a heavy stone or a shank.

After finishing the above step, remove the yellow clay loaf paper one by one on the hot iron plate and let it dry.

The fourth step of dyeing the Korean yellow clay by using the dye.

And a fifth step of spraying the water repellent agent on the floating yellow soil.

After finishing the above steps, Hanji Korean paper is removed by heating one by one on an iron plate and dried to complete step 6.

[Example 3]

The water and daphnia were put into a trough, and the mixture was stirred with a rod to mix well. The first step to immerse the paper in the back of the trunk,

And a second step of spraying a water repellent agent on the floating yellow soil.

After the above steps are completed, the third step is to put the pillow or thread of the Hwangto-jiji-siji between the pillows and stack the pillow. When the pillow is at an arbitrary height, put it in between the planks and then lift the heavy stone or the shank to remove the water.

After completing the above steps, Hanji (Korean paper) is removed from the heat-treated steel sheet and dried to complete the fourth step.

[Example 4]

Put 17 ~ 45% (weight ratio) of loam soil solution, 3 ~ 5% (weight ratio) of wood chips and 50 ~ 80% (weight ratio) The first step is to immerse the paper soaked in the tongue and shake the front,

And a second step of spraying a water repellent agent on the floating yellow soil.

After the above steps are completed, the third step is to put the pillow or thread of the Hwangto-jiji-siji between the pillows and stack the pillow. When the pillow is at an arbitrary height, put it in between the planks and then lift the heavy stone or the shank to remove the water.

After completing the above steps, Hanji (Korean paper) is removed from the heat-treated steel sheet and dried to complete the fourth step.

The main embodiment has been described above.

In the case of applying the above embodiment, when the dyeing or printing step is included, the water repellent agent is not applied but dried, so that the yellow paper is immersed in the dyeing tube and is dyed or printed, followed by spraying and drying the water repellent agent.

As described above, in the present invention, the surface sizing with the water repellent agent during the process of the method of producing the Korean clay soil reduces the humidity control ability of the fiber and the loess to absorb moisture, There is an effect of improving the durability such that cracks are generated in the humidity control process and the surface is floated.

Paper that has been dried and dyed can be used as an interior accessory, ie, as a tapestry or as a craftsman. In the process of applying paint, varnish, paraffin, etc. at the completion stage, the surface gloss and durability of the paper are improved.

Claims (9)

Add 50 ~ 80% (weight ratio) of dodecane fiber and 20 ~ 50% (weight ratio) of loess suspension to the bag, add water and daphnia into the bag, stir with a rod and mix well, A first step of swinging left and right to release the yellow soil; A second step of spraying a water repellent agent on the Korean earth of the first step; A third step of sandwiching the pillow or thread between pillars of the second stage and piling up the pillow, placing the pillow between the pillars when the pillow is at an arbitrary height, and lifting a heavy stone or a shank to remove water; The third step is a step of removing the yellow clay from the clay on which the heat is applied one by one and drying it. Wherein said step is performed in a sequential step. [2] The method according to claim 1, wherein the first step of releasing the yellow clay from the bag is used instead of water. The method according to claim 1, wherein, in the first step of floating the yellow clay paper from the bag, the clay fiber is dispersed in an amount of 50 to 80% (weight ratio), 17 to 45% (weight ratio) Water and daphnia are put into a trough and mixed with a rod to mix well. Then, the feet of the paper are immersed in the trough to swing back and forth to swing the left and right troughs so as to float the trough. The method according to claim 1, wherein in the first step of releasing the yellow clay from the bag, the clay fiber is added in an amount of 50 to 80% (weight ratio), 17 to 45% (weight ratio) Weight ratio) is put into a tongue, the water and daphnia are put into a trough and mixed with a rod to mix well. Then, the foot of the paper is immersed in the tongue, and the tongue is shaken back and forth to lift the paper. 5. The method according to claim 4, wherein the wood chips are selected from the group consisting of pine, pine, fir, spruce, conifer, bamboo, German spruce, spruce, Wherein the plant is selected from at least one or more selected from the group consisting of acanthopanax nucifera, azalea, azalea, persimmon, persimmon, oyster, thyme, corn, and magnolia. The method of claim 4, wherein at least one of petals, tree leaves, and grass leaves is arbitrarily selected instead of wood chips. The method according to claim 1, further comprising the step of spraying a water repellent agent onto a Korean soil of yellow ocher stained by immersing Korean yellow clay in a dye bucket after completion of a third step of removing water. The method according to any one of claims 1, 2, 3, or 4, wherein the rosin sizing agent is mixed for at least 10 minutes or more before mixing the dregs in the first step to remove the loess, Sizing), and then putting the daphnia and stirring it again with a rod so as to float the Korean soil. The method according to claim 1, wherein after the fourth step of drying the yellow clay on a hot iron plate, the water repellent agent is sprayed and surface-sized.