KR100935413B1 - Manufacturing method of concrete block - Google Patents

Manufacturing method of concrete block Download PDF

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KR100935413B1
KR100935413B1 KR1020080039320A KR20080039320A KR100935413B1 KR 100935413 B1 KR100935413 B1 KR 100935413B1 KR 1020080039320 A KR1020080039320 A KR 1020080039320A KR 20080039320 A KR20080039320 A KR 20080039320A KR 100935413 B1 KR100935413 B1 KR 100935413B1
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weight
photoluminescent
concrete block
plate
manufacturing
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KR1020080039320A
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Korean (ko)
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KR20090113545A (en
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김천수
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(주)장성산업
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
    • B28B7/0064Moulds characterised by special surfaces for producing a desired surface of a moulded article, e.g. profiled or polished moulding surfaces
    • B28B7/0076Moulds characterised by special surfaces for producing a desired surface of a moulded article, e.g. profiled or polished moulding surfaces with surfaces for moulding letters or marks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/14Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted
    • B28B1/16Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted for producing layered articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
    • B28B7/0097Press moulds; Press-mould and press-ram assemblies
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/22Glass ; Devitrified glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/26Carbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/30Oxides other than silica
    • C04B14/305Titanium oxide, e.g. titanates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2605Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing polyether side chains
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/02Portland cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/32Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent, e.g. electroluminescent, chemiluminescent materials
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/06Pavings made of prefabricated single units made of units with cement or like binders

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Architecture (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Road Signs Or Road Markings (AREA)

Abstract

본 발명은 야간이나 화재 시 방향 유도를 할 수 있는 문양의 축광판이 표면에 삽입된 콘크리트 블록의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing a concrete block is inserted into the surface of the patterned phosphorescent plate that can guide the direction at night or fire.

축광, 콘크리트, 블록 Photoluminescent, concrete, block

Description

축광 콘크리트 블록의 제조방법{Manufacturing method of concrete block}Manufacturing method of photoluminescent concrete block

본 발명은 야간이나 화재 시 방향 유도를 할 수 있는 문양의 축광판이 표면에 삽입된 콘크리트 블록의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing a concrete block is inserted into the surface of the patterned phosphorescent plate that can guide the direction at night or fire.

종래 방향유도 표시층이 형성된 인조석의 개발에 대한 특허가 출원되었으나, 인조석은 유기 고분자물질로 이루어져 화재 시 녹아내릴 수 있거나 유해한 연기를 발생하게 되므로 실질적으로 방향유도 표시 기능을 하지 못하게 된다. 이에 따라 난연제 등을 추가하는 기술이 개발되고 있으나 이 역시 큰 효과를 기대하기는 어렵다.Patents have been applied for the development of artificial stone in which the aromatic induction display layer is formed. However, the artificial stone is made of an organic high molecular material, so that it may dissolve in a fire or generate harmful smoke, thereby substantially preventing the aromatic induction function. Accordingly, technologies for adding a flame retardant, etc. have been developed, but it is difficult to expect a great effect.

본 발명은 비교적 간단하고, 연속적인 방법으로 방향 유도를 할 수 있는 축광판을 콘크리트 블록에 삽입하는 제조방법을 제공하고자 한다.The present invention is to provide a manufacturing method for inserting a photoluminescent plate into a concrete block that can be directed in a relatively simple, continuous manner.

또한 본 발명은 표면이 매끈하여 표면재료로 사용할 수 있도록 하는 콘크리트 블록의 제조방법 및 이에 사용되는 조성물을 제공하고자 한다.In another aspect, the present invention is to provide a method for producing a concrete block and a composition used therein so that the surface can be used as a surface material smooth.

본 발명은 축광판이 삽입된 콘크리트 블록에 관한 것이다.The present invention relates to a concrete block in which a photoluminescent plate is inserted.

보다 구체적으로 More specifically

a) 골재 60 ~ 80 중량%, 포틀랜트 시멘트 10 ~ 30 중량%, 물 1 ~ 10 중량%, 혼화제 0.1 ~ 0.5 중량%를 포함하는 하부몰탈조성물을 성형기에 투입하는 단계;a) injecting a lower mortar composition including 60 to 80% by weight of aggregate, 10 to 30% by weight of portland cement, 1 to 10% by weight of water, and 0.1 to 0.5% by weight of admixture to the molding machine;

b) 상기 하부몰탈조성물을 20 ~ 40톤의 유압실린더를 이용하여 1차 압축하는 단계;b) first compressing the lower mortar composition using a 20 to 40 ton hydraulic cylinder;

c) 상기 압축된 몰탈의 상부에 골재 40 ~ 50 중량%, 알루미나 시멘트 20 ~ 40 중량%, 물 10 ~ 30 중량%를 포함하는 상부몰탈조성물을 투입하는 단계;c) injecting an upper mortar composition including 40 to 50% by weight of aggregate, 20 to 40% by weight of alumina cement, and 10 to 30% by weight of water on the compressed mortar;

d) 상기 상부몰탈조성물을 40 ~ 60톤의 유압실린더를 이용하여 2차 압축하는 단계;d) second compressing the upper mortar composition by using a hydraulic cylinder of 40 to 60 tons;

e) 상기 상부몰탈 가압면에 축광판투입장치를 이용하여 축광판을 올려놓는 단계;e) placing the photoluminescent plate on the upper mortar pressing surface using a photoluminescent plate input device;

f) 150 ~ 300톤의 유압실린더를 이용하여 1 ~ 20초간 압축시켜 축광판이 일 체화되면서 압축되도록 하는 단계;f) using a hydraulic cylinder of 150 ~ 300 tons for 1 to 20 seconds to compress the photoluminescent plate being integrated;

g) 탈형 후 양생하는 단계;g) curing after demolding;

를 포함하는 축광판을 갖는 콘크리트 블록의 제조방법에 관한 것이다.It relates to a method of manufacturing a concrete block having a photoluminescent plate comprising a.

본 발명은 상기 a) ~ f) 단계가 원형으로 된 하나의 회전판에서 연속적으로 이루어지는 콘크리트 블록의 제조방법에 관한 것이다.The present invention relates to a method for producing a concrete block made continuously in one rotating plate of the steps a) to f) are circular.

또한 본 발명은 상기 f)단계에서 유압실린더를 이용하여 압축 시 요철이 형성된 압축판을 사용하여 표면에 돌기를 형성하는 콘크리트 블록의 제조방법에 관한 것이다.In another aspect, the present invention relates to a method of manufacturing a concrete block to form a protrusion on the surface by using a compression plate formed with irregularities during compression using the hydraulic cylinder in step f).

또한, 상기 e)단계의 축광판 투입장치는 유압과 전동장치를 이용하여 정해진 위치에 내려놓는다.In addition, the phosphorescent plate input device of step e) is lowered to a predetermined position by using a hydraulic pressure and a transmission device.

또한 본 발명에서 상기 상부몰탈조성물은 안료, 혼화제, 강도강화제, 크랙방지제에서 선택되는 하나 이상의 첨가제가 더 포함될 수 있으며, 상기 안료는 1 ~ 10 중량%, 혼화제는 0.1 ~ 5 중량%로 사용된다.In the present invention, the upper mortar composition may further include one or more additives selected from pigments, admixtures, strength enhancers, and anti-cracks, wherein the pigments are used in an amount of 1 to 10 wt% and 0.1 to 5 wt%.

또한 본 발명에서 상기 축광판은 폴리에틸렌 또는 폴리프로필렌 40 ~ 70 중량%, 유리분말 30 ~ 60 중량%를 혼합한 조성물 100 중량부에 대하여, 축광안료 20 ~ 40 중량부를 포함하는 상부층조성물을 용융한 후 몰드에 부어 경화시키는 단계;In the present invention, the luminescent plate is melted the upper layer composition containing 20 to 40 parts by weight of the phosphorescent pigment with respect to 100 parts by weight of the composition of 40 to 70% by weight of polyethylene or polypropylene, 30 to 60% by weight of the glass powder Pouring into the mold to cure;

폴리에틸렌 또는 폴리프로필렌 30 ~ 50 중량%, 탄산칼슘 50 ~ 60 중량%, 이산화티탄 1 ~ 10 중량%를 포함하는 하부층조성물을 용융한 후 상기 상부층조성물의 상부에 부어 경화시키는 단계;Melting the lower layer composition comprising 30 to 50% by weight of polyethylene or polypropylene, 50 to 60% by weight of calcium carbonate, and 1 to 10% by weight of titanium dioxide, followed by curing by pouring on the upper layer composition;

를 포함하여 제조된다. It is prepared to include.

본 발명은 바닥의 보도블럭으로 사용할 수 있으며, 표면에 돌기를 형성하는 경우 시각장애인용 점자블럭에 삽입생산하여 방향유도용으로도 사용할 수 있다. The present invention can be used as a sidewalk block of the bottom, when forming a projection on the surface can be used in the direction-induced by inserting into the braille block for the blind.

본 발명에 따른 축광 콘크리트 블록의 제조방법은 비교적 간단하고, 연속적인 방법으로, 방향 유도를 할 수 있는 축광판을 콘크리트 블록에 삽입하는 제조방법을 제공할 수 있다.The method of manufacturing a photoluminescent concrete block according to the present invention can provide a manufacturing method of inserting a photoluminescent plate capable of guiding a direction into a concrete block in a relatively simple and continuous method.

또한 본 발명에 따른 콘크리트 블록은 즉시탈형 가능한 콘크리트 제품의 표면 요부에 축광판을 매설 또는 유입하는 것에 의하여, 야간이나 정전사고, 화재발생 시에 축적된 빛에너지를 이용하여 장시간 발광하여 야간 보행시의 안내판으로서 적용할 수 있고, 특히 약시자용 블록 또는 맹인용 점자블록에 삽입하여 사용할 수 있다.In addition, the concrete block according to the present invention, by embedding or inflowing the photoluminescent plate in the surface recess of the concrete product that can be immediately demountable, by using light energy accumulated at night or blackout accident, fire occurrence for a long time during walking It can be applied as a guide plate, and in particular, it can be inserted into a blind block or blind braille block.

다음은 본 발명의 각 구성에 대하여 도면을 참고하여 보다 구체적으로 설명한다.Next, each configuration of the present invention will be described in more detail with reference to the accompanying drawings.

도 1에 도시된 바와 같이, 본 발명에 따른 축광 콘크리트 블록은 먼저 골재 60 ~ 80 중량%, 포틀랜트 시멘트 10 ~ 30 중량%, 물 1 ~ 10 중량%, 혼화제 0.1 ~ 0.5 중량%를 포함하는 하부몰탈조성물을 성형기에 투입(S1)한다. 다음으로 유압실린더를 이용하여 하부몰탈조성물이 판판하게 다져지도록 압력을 가한다(S2). 다음으로 압축된 하부몰탈의 상부에 골재 40 ~ 50 중량%, 알루미나 시멘트 20 ~ 40 중 량%, 물 10 ~ 30 중량%를 포함하는 상부몰탈조성물을 투입(S3)한다. 다음으로 유압실린더를 이용하여 하부몰탈조성물이 판판하게 다져지도록 압력을 가한다(S4). 다음으로 압축된 상부몰탈의 상부에 미리 성형된 축광판을 삽입한다(S5). 이때 축광판 삽입장치는 유압과 전동장치를 이용하여 정해진 위치에 정확하게 내려놓을 수 있도록 제조된 것을 사용한다(미도시). 다음으로 축광판이 제자리에 놓여지면 150 ~ 300톤의 유압실린더를 이용하여 1 ~ 20초간 압축시켜 축광판이 일체화되면서 압축되도록 한다(S6). 이때 상부층의 몰탈에 혼합되어 있는 수분이 마지막 압축력에 의해 하부층으로 흡수되며 제품전체의 수분함유량이 평준화되고, 표면이 매우 매끄러운 상태가 이루어진다. 또한 상기 마지막 압축 단계에서 요홈이 형성된 압축판을 상부면에 대고 압축을 하는 경우 돌기가 형성된 점자블록을 제조할 수도 있다. 이렇게 제조된 콘크리트 블록을 탈형한 후 양생하는 과정을 거친다. 이때 탈형은 블록 하부에 장치된 공기실린더(미도시)의 힘에 의해 상부로 밀어 올려지면서 몰드에서 탈형이 된다. 탈형된 블록은 자동이송 콘베이어벨트를 타고 이동하여 양생실로 가기 위한 레크에 탑재 된다. 이하 양생공정은 일반 콘크리트 제조 시 사용되는 양생 조건으로 한다.As shown in FIG. 1, the photoluminescent concrete block according to the present invention first comprises 60 to 80% by weight of aggregate, 10 to 30% by weight of portland cement, 1 to 10% by weight of water, and 0.1 to 0.5% by weight of admixture. Mortar composition is put into the molding machine (S1). Next, the pressure is applied to the lower mortar composition to be compacted using a hydraulic cylinder (S2). Next, the upper mortar composition including 40 to 50% by weight of aggregate, 20 to 40% by weight of alumina cement, and 10 to 30% by weight of water is added to the upper portion of the compressed lower mortar (S3). Next, a pressure is applied to the lower mortar composition to be compacted using a hydraulic cylinder (S4). Next, a pre-molded photoluminescent plate is inserted into the compressed upper mortar (S5). At this time, the photoluminescent plate inserting device uses the one manufactured to be accurately lowered to a predetermined position using a hydraulic pressure and an electric transmission device (not shown). Next, when the photoluminescent plate is put in place, it is compressed for 1 to 20 seconds using a hydraulic cylinder of 150 to 300 tons so that the photoluminescent plate is integrated and compressed (S6). At this time, the moisture mixed in the mortar of the upper layer is absorbed into the lower layer by the last compression force, the water content of the whole product is leveled, and the surface is very smooth. In addition, when compressing the compression plate formed in the groove in the last compression step to the upper surface may be produced a braille block formed with projections. After demolding the concrete block thus manufactured, it undergoes a curing process. At this time, the demolding is demolded from the mold while being pushed upward by the force of the air cylinder (not shown) installed at the bottom of the block. The demolded block is mounted on a rack to move on the automatic conveyor belt to the curing room. The curing process is defined as curing conditions used in the manufacture of general concrete.

본 발명에서 상기 하부몰탈조성물은 골재 60 ~ 80 중량%, 포틀랜트 시멘트 10 ~ 30 중량%, 물 5 ~ 10 중량%, 혼화제 0.1 ~ 0.5 중량%를 포함한다. 상기 골재는 최대 입경이 13 mm 이하, 보다 구체적으로는 0.1 ~13mm의 천연 골재 또는 부순골재를 사용하며, 60 ~ 80 중량% 범위로 사용한다. 하부층은 강도가 보강되어야 하므로 골재의 함량이 높도록 하는 것이 바람직하다. 혼화제로는 예를 들면, 콘크리 트용 감수제 등이 사용 가능하며, 이밖에도 통상적으로 사용되는 혼화제라면 제한되지 않고 사용할 수 있다. 혼화제는 물과 시멘트 비율을 낮게 해주는 역할을 하는 것으로, 0.1 ~ 0.5 중량% 범위로 사용하는 것이 바람직하다. In the present invention, the lower mortar composition includes 60 to 80 wt% of aggregate, 10 to 30 wt% of portland cement, 5 to 10 wt% of water, and 0.1 to 0.5 wt% of admixture. The aggregate has a maximum particle diameter of 13 mm or less, more specifically, 0.1 to 13 mm of natural aggregate or crushed aggregate, and is used in the range of 60 to 80% by weight. Since the lower layer should be reinforced in strength, it is desirable to have a high content of aggregate. As the admixture, for example, a concrete water reducing agent may be used, and any other admixture may be used without limitation. Admixture serves to lower the ratio of water and cement, it is preferable to use in the range of 0.1 to 0.5% by weight.

하부몰탈조성물은 물의 함량이 5 ~ 10 중량%인 것이 바람직하다. 5 중량% 미만인 경우수분부족으로 콘크리트의 수화반응을 저해하고 하고, 10 중량%를 초과하는 경우 상부층에서 압축 시 배출되는 수분을 흡수할 수 없어서 제품의 성형이 불가능하다.The lower mortar composition is preferably 5 to 10% by weight of water. If less than 5 wt% inhibits the hydration of concrete due to lack of moisture, and if it exceeds 10 wt% it is impossible to absorb the moisture discharged from the upper layer can not be molded of the product.

본 발명에서 상기 상부몰탈조성물은 골재 40 ~ 50 중량%, 알루미나 시멘트 20 ~ 40 중량%, 물 10 ~ 30 중량%를 포함한다. 여기에 필요에 따라 안료, 혼화제, 강도강화제, 크랙방지제에서 선택되는 하나 이상의 첨가제가 더 포함될 수 있으며, 상기 안료는 1 ~ 10 중량%, 혼화제는 0.1 ~ 5 중량%, 강도강화제는 시멘트의 0.5 ~ 2%, 크랙방지제는 시멘트의 0.1 ~ 0.3중량%범위로 사용한다.The upper mortar composition in the present invention comprises 40 to 50% by weight aggregate, 20 to 40% by weight alumina cement, 10 to 30% by weight water. This may further include one or more additives selected from pigments, admixtures, strength enhancers and anti-cracking agents as necessary, wherein the pigment is 1-10 wt%, the admixture is 0.1-5 wt%, and the strength-enhancer is 0.5-5% of cement. 2%, crack inhibitor is used in the range of 0.1 to 0.3% by weight of cement.

골재는 입경이 0.1 ~ 3mm의 천연 모래 및 인공모래를 사용하며, 40 ~ 50 중량% 범위로 사용한다. 상부몰탈조성물은 표면에 드러나는 부분이므로 매끄러운 표면을 형성하는 것이 바람직하며, 그러기 위해서는 골재의 함량보다는 시멘트의 함량을 증가하는 것이 바람직하다. 물은 하부몰탈조성물에 비하여 많은 양으로 사용하는 것이 바람직하며, 구체적으로 10 ~ 30 중량%를 사용한다. 물의 함량이 10 중량% 미만인 경우 안료와 골재, 시멘트가 충분히 섞이지 않아 표면상태가 매끄럽지 못하고, 30 중량%를 초과하는 경우 콘크리트 내 수분함량이 높아 내구성이 약해질 수 있다.Aggregate uses natural sand and artificial sand with a particle size of 0.1 ~ 3mm, 40 to 50% by weight. Since the upper mortar composition is a part exposed on the surface, it is preferable to form a smooth surface, and to do so, it is preferable to increase the cement content rather than the aggregate content. Water is preferably used in a large amount compared to the lower mortar composition, specifically 10 to 30% by weight. If the water content is less than 10% by weight, the pigment, aggregate, and cement are not sufficiently mixed, so the surface state is not smooth. If the water content is more than 30% by weight, the water content in the concrete may be high and the durability may be weakened.

안료는 통상적으로 사용되는 유기안료를 사용할 수 있으며, 1 ~ 10 중량% 범위로 사용하는 것이 바람직하다. 상기 혼화제는 통상적으로 사용되는 혼화제라면 제한되지 않고 사용할 수 있다. 혼화제는 0.1 ~ 0.5 중량% 범위로 사용하는 것이 바람직하다.The pigment may be used an organic pigment that is commonly used, it is preferable to use in the range of 1 to 10% by weight. The admixture can be used without limitation so long as it is a commonly used admixture. The admixture is preferably used in the range of 0.1 to 0.5% by weight.

상기 강도강화제는 통상적으로 사용되는 강도강화제라면 제한되지 않고 사용할 수 있으며 시멘트 함량 대비 0.5 ~ 2 중량% 범위로 사용하는 것이 바람직하다.The strength enhancer can be used without limitation as long as it is a commonly used strength enhancer and is preferably used in the range of 0.5 to 2% by weight relative to the cement content.

상기 크랙방지제는 예를 들면, 유리섬유 또는 나이론섬유 등이 사용 가능하며, 시멘트 함량 대비 0.1 ~ 0.3 중량% 범위로 사용하는 것이 바람직하다. The crack preventing agent, for example, may be used, such as glass fibers or nylon fibers, it is preferable to use in the range of 0.1 to 0.3% by weight relative to the cement content.

본 발명에서 하부몰탈조성물에는 포틀랜트 시멘트를 사용하고, 상부몰탈조성물에는 알루미나 시멘트를 사용하는 이유는 하부에 사용하는 포틀랜드시멘트는 가격이 저렴하고 수급이 원활하기 때문이며, 상부에 사용하는 알루미나 시멘트는 가격은 고가이나, 안료를 배합했을 때 색도 발현율이 우수하기 때문에 표면층에 사용하게 되고 내마모성이 포틀랜드시멘트에 비해 상대적으로 우수하기 때문이다.In the present invention, the lower mortar composition uses portant cement, and the upper mortar composition uses alumina cement because the lower portland cement is used at a lower price and the supply and demand is smooth. Silver is expensive, but because it is excellent in the chromaticity expression rate when the pigment is blended, it is used in the surface layer, and wear resistance is relatively superior to Portland cement.

다음으로 본 발명에 사용되는 축광판의 구성에 대하여 설명하면, 상기 축광판은 폴리에틸렌 또는 폴리프로필렌 40 ~ 70 중량%, 유리분말 30 ~ 60 중량%를 혼합한 조성물 100 중량부에 대하여, 축광안료 20 ~ 40 중량부를 포함하는 상부층조성물을 용융한 후 몰드에 부어 경화시키는 단계;Next, the configuration of the photoluminescent plate used in the present invention, the photoluminescent plate is a phosphorescent pigment 20 with respect to 100 parts by weight of the composition mixed 40 to 70% by weight of polyethylene or polypropylene, 30 to 60% by weight of glass powder Melting and curing the upper layer composition including about 40 parts by weight to a mold;

폴리에틸렌 또는 폴리프로필렌 30 ~ 49 중량%, 탄산칼슘 50 ~ 60 중량%, 이산화티탄 1 ~ 10 중량%를 포함하는 하부층조성물을 용융한 후 상기 상부층조성물의 상부에 부어 경화시키는 단계;Melting the lower layer composition comprising 30 to 49% by weight of polyethylene or polypropylene, 50 to 60% by weight of calcium carbonate, and 1 to 10% by weight of titanium dioxide, followed by curing by pouring on top of the upper layer composition;

를 포함하여 여러 형태의 판상으로 성형한 것을 사용한다.Including the molded in various forms of plate, including.

상기 하부층은 백색을 나타내는 것으로 축광의 색상 발현을 보다 우수하게 하기 위한 것이며, 축광안료와 유리분말은 상기 상부층에만 사용된다.The lower layer is white to improve the color expression of the photoluminescent light, and the photoluminescent pigment and glass powder are used only for the upper layer.

본 발명에서 상기 축광판은 상부층 두께가 2 ~ 3mm이고, 하부층 5 ~ 7mm인 것이 바람직하다. 축광판의 두께는 2mm ~ 3mm인 경우 충분한 축광 효율을 달성할 수 있다. 3mm를 초과한다 하여도 축광 효율이 더 이상 상승하지 않으므로 제조 단가를 고려하여 상기 두께로 제조하는 것이 바람직하다.In the present invention, the photoluminescent plate is preferably an upper layer having a thickness of 2 to 3 mm and a lower layer of 5 to 7 mm. When the thickness of the photoluminescent plate is 2 mm to 3 mm, sufficient photoluminescent efficiency can be achieved. Even if it exceeds 3 mm, since the photoluminescence efficiency does not increase any more, it is preferable to manufacture the said thickness in consideration of manufacturing cost.

열가소성수지는 폴리에틸렌 또는 폴리프로필렌을 사용한다. 이는 펠렛화 하여 제품화된 것을 사용할 수 있으며, 함량은 하부층의 경우 30 ~ 50 중량%, 상부층인 경우 20 ~ 40 중량% 범위로 사용한다. 상기 함량범위 미만으로 사용하는 경우결합력이 약하고, 상기 범위를 초과하는 경우 경화 후 변형의 우려가 있다.Thermoplastics use polyethylene or polypropylene. It can be used to produce the pelletized product, the content is used in the range of 30 to 50% by weight for the lower layer, 20 to 40% by weight for the upper layer. In the case of using less than the content range, the bonding strength is weak, and if it exceeds the above range there is a fear of deformation after curing.

상기 축광판의 재료에 사용되는 축광안료는 태양광 또는 형광등의 광을 흡수하여 축적하였다가, 어두운 곳에서 장시간 발관하는 특성을 갖는 것으로, 소량의 희토류 금속 이온, 바람직하게는 유로퓸, 가돌리늄, 디스프로슘, 터븀 및 이터븀으로 이루어진 군에서 선택되는 어느 하나이상의 활성화된 알카리토금속 알루민산염 복합물인 무기계 축광안료를 사용한다. 보다 바람직하게 본 발명의 축광안료로서는 Y2O2S:Eu(레드), BaMg2Al16O27:Eu(그린), Sr5(PO4)3Cl:Eu(블루), Sr4Al14O25:Eu(블루그린), SrAl2O4:Eu(그린)로 표시되는 화합물을 사용하는 것이 바람직하다. 상기 Eu는 유로퓸이다. The photoluminescent pigment used in the material of the photoluminescent plate absorbs and accumulates light such as sunlight or fluorescent light, and has a characteristic of long-term extubation in a dark place. Inorganic phosphorescent pigments are used which are at least one activated alkaline earth metal aluminate composite selected from the group consisting of terbium and ytterbium. More preferably, as the photoluminescent pigment of the present invention, Y 2 O 2 S: Eu (red), BaMg 2 Al 16 O 27 : Eu (green), Sr 5 (PO 4 ) 3 Cl: Eu (blue), Sr 4 Al 14 It is preferable to use a compound represented by O 25 : Eu (blue green) or SrAl 2 O 4 : Eu (green). Eu is europium.

상기 유리분말은 축광 기능과 표면경도를 향상시키고, 빛에 반사되는 경우 시인성을 더욱 향상시키기 위하여 사용되는 것으로 비표면적이 2000㎠/g 이상인 것을 사용하는 것이 바람직하다. 함량은 30~50 중량% 범위로 사용하는 것이 바람직하며, 30중량% 미만으로 사용하는 경우 표면경도와 투명성이 떨어지고, 50중량%를 초과하는 경우 추광안료의 추가투입이 필요하다.The glass powder is used to improve the photoluminescence function and surface hardness, and further improve the visibility when reflected by light, it is preferable to use a specific surface area of 2000 cm 2 / g or more. It is preferable to use the content in the range of 30 to 50% by weight, and when used in less than 30% by weight, the surface hardness and transparency are inferior, and when it exceeds 50% by weight, additional injection of a pigment is required.

상기 탄산칼슘은 상부 축광층의 축광력을 상승하고 수지의 강도증진, 형태의 유지 등을 위하여 사용되는 것으로, 함량은 50 ~ 60 중량% 범위로 사용하는 것이 바람직하며, 50 중량% 미만으로 사용하는 경우 변형의 우려가 있고, 60중량%를 초과하는 경우 결속력이 저하될 우려가 있다.The calcium carbonate is used to increase the photoluminescent power of the upper photoluminescent layer and to increase the strength of the resin, to maintain the form, the content is preferably used in the range of 50 to 60% by weight, it is used in less than 50% by weight In the case of deformation, there is a fear of deformation, and when it exceeds 60% by weight, there is a fear that the binding force is lowered.

상기 이산화티탄은 백색도를 향상시키기 위하여 사용되는 것으로, 1 ~ 10 중량% 범위로 사용하는 경우 다른 성분에 영향을 주지 않으면서 백색도가 증가된 판으로 성형을 할 수 있다.The titanium dioxide is used to improve whiteness, and when used in the range of 1 to 10% by weight, the titanium dioxide may be molded into a plate having increased whiteness without affecting other components.

상기와 같은 방법으로 용융 압출 성형함으로써 필요에 따라 원하는 형태의 모양으로 축광판을 성형 할 수 있다. By melt-extrusion molding in the same manner as described above, the photoluminescent plate can be molded into a desired shape as required.

도 2는 본 발명에 따른 축광판인 삽입된 콘크리트 블록의 단면을 나타낸 것이다. 즉, 하부층(10)과 상부층(20)으로 구성되며, 상부층(20)에는 미리 성형(숫자, 문자 또는 도형의 형태로 성형)된 축광판(30)이 삽입된 블록(100)이다. 이에 대한 사시도는 도 4에 나타내었다. Figure 2 shows a cross section of the inserted concrete block which is a photoluminescent plate according to the present invention. That is, the lower layer 10 and the upper layer 20, and the upper layer 20 is a block 100 is inserted into the photoluminescent plate 30 molded in advance (molded in the form of numbers, letters or figures). A perspective view thereof is shown in FIG. 4.

또한, 도 3에 나타낸 바와 같이, 하부층(10)과 상부층(20)으로 구성되며, 상부층(20)에는 미리 성형된 축광판(30)이 삽입되고, 상부층(20)의 표면에 돌 기(40)가 형성되어 장애인용 점자블록(200)으로 제조할 수도 있다. 이에 대한 사시도는 도 5에 나타내었다. In addition, as shown in FIG. 3, the lower layer 10 and the upper layer 20 are formed, and the preformed photoluminescent plate 30 is inserted into the upper layer 20, and the protrusions 40 are formed on the surface of the upper layer 20. ) May be formed may be manufactured as a braille block 200 for the disabled. A perspective view thereof is shown in FIG. 5.

도 1은 본 발명의 축광 콘크리트 블록을 제조하는 과정을 나타낸 것이다.Figure 1 shows a process for producing a photoluminescent concrete block of the present invention.

도 2는 본 발명의 축광 콘크리트 블록의 단면도이다.2 is a cross-sectional view of the photoluminescent concrete block of the present invention.

도 3은 본 발명의 축광 콘크리트 블록의 단면도이다.3 is a cross-sectional view of the photoluminescent concrete block of the present invention.

도 4는 본 발명의 축광 콘크리트 블록의 사시도이다.4 is a perspective view of a photoluminescent concrete block of the present invention.

도 5는 본 발명의 축광 콘크리트 블록의 사시도이다.5 is a perspective view of a photoluminescent concrete block of the present invention.

-도면의 주요 부분에 대한 설명-Description of the main parts of the drawing

10 : 하부몰탈 20 : 상부몰탈10: lower mortar 20: upper mortar

30 : 축광판 40 : 돌기30: photoluminescent plate 40: projection

100 : 일반블록 200 : 점자블록100: general block 200: braille block

Claims (8)

a) 골재 60 ~ 80 중량%, 포틀랜트 시멘트 10 ~ 30 중량%, 물 1 ~ 10 중량%, 혼화제 0.1 ~ 0.5 중량%를 포함하는 하부몰탈조성물을 성형기에 투입하는 단계;a) injecting a lower mortar composition including 60 to 80% by weight of aggregate, 10 to 30% by weight of portland cement, 1 to 10% by weight of water, and 0.1 to 0.5% by weight of admixture to the molding machine; b) 상기 하부몰탈조성물을 20 ~ 40톤의 유압실린더를 이용하여 1차 압축하는 단계;b) first compressing the lower mortar composition using a 20 to 40 ton hydraulic cylinder; c) 상기 압축된 몰탈의 상부에 골재 40 ~ 50 중량%, 알루미나 시멘트 20 ~ 40 중량%, 물 10 ~ 30 중량%를 포함하는 상부몰탈조성물을 투입하는 단계;c) injecting an upper mortar composition including 40 to 50% by weight of aggregate, 20 to 40% by weight of alumina cement, and 10 to 30% by weight of water on the compressed mortar; d) 상기 상부몰탈조성물을 40 ~ 60톤의 유압실린더를 이용하여 2차 압축하는 단계;d) second compressing the upper mortar composition by using a hydraulic cylinder of 40 to 60 tons; e) 상기 상부몰탈 가압면에 축광판투입장치를 이용하여 모양을 갖으며, 폴리에틸렌 또는 폴리프로필렌 40 ~ 70 중량%, 유리분말 30 ~ 60 중량%를 혼합한 조성물 100 중량부에 대하여, 축광안료 20 ~ 40 중량부를 포함하는 상부층조성물을 용융한 후 몰드에 부어 경화시키고, 폴리에틸렌 또는 폴리프로필렌 30 ~ 49 중량%, 탄산칼슘 50 ~ 60 중량%, 이산화티탄 1 ~ 10 중량%를 포함하는 하부층조성물을 용융한 후 상기 상부층조성물의 상부에 부어 경화시킨 2층의 축광판을 올려놓는 단계;e) a phosphorescent pigment 20 having a shape on the upper mortar pressurized surface by using a photoluminescent plate injection device, and based on 100 parts by weight of a composition in which 40 to 70% by weight of polyethylene or polypropylene and 30 to 60% by weight of glass powder are mixed. ~ 40 parts by weight of the upper layer composition is melted and poured into a mold to harden, melt the lower layer composition comprising 30 to 49% by weight of polyethylene or polypropylene, 50 to 60% by weight of calcium carbonate, 1 to 10% by weight of titanium dioxide Placing a two-layer photoluminescent plate which is then poured and cured on top of the upper layer composition; f) 150 ~ 300톤의 유압실린더를 이용하여 1 ~ 20초간 압축시켜 축광판이 일체화되면서 압축되고, 상부몰탈조성물의 수분이 하부층으로 흡수되며 표면이 매끄러운 상태가 되도록 하는 단계;f) compressing by using a hydraulic cylinder of 150 to 300 tons for 1 to 20 seconds to be integrated while the photoluminescent plate is integrated, so that the moisture of the upper mortar composition is absorbed into the lower layer and the surface is smooth; g) 탈형 후 양생하는 단계;g) curing after demolding; 를 포함하는 축광 콘크리트 블록의 제조방법.Method of manufacturing a photoluminescent concrete block comprising a. 제 1항에 있어서,The method of claim 1, 상기 a) ~ f) 단계가 원형으로 된 하나의 회전판에서 연속적으로 이루어지는 축광 콘크리트 블록의 제조방법.The method of manufacturing a photoluminescent concrete block made of a continuous rotating plate of the steps a) to f) are circular. 제 1항에 있어서,The method of claim 1, 상기 f)단계에서 유압실린더를 이용하여 압축 시, 요철이 형성된 압축판을 사용하여 표면에 돌기를 형성하는 축광 콘크리트 블록의 제조방법.When the compression using the hydraulic cylinder in the step f), the manufacturing method of the photoluminescent concrete block to form a projection on the surface by using a compression plate formed with irregularities. 제 2항 또는 제 3항에 있어서,The method of claim 2 or 3, 상기 e)단계의 축광판 투입장치는 유압과 전동장치를 이용하여 정해진 위치에 내려놓는 축광 콘크리트 블록의 제조방법.Wherein the light-emitting plate injector of step e) is a manufacturing method of the photoluminescent concrete block to be lowered to a predetermined position by using a hydraulic and a transmission. 제 1항에 있어서,The method of claim 1, 상기 상부몰탈조성물은 안료, 혼화제, 강도강화제, 크랙방지제에서 선택되는 하나 이상의 첨가제가 더 포함되는 축광 콘크리트 블록의 제조방법.The upper mortar composition is a method of producing a photoluminescent concrete block further comprises one or more additives selected from pigments, admixtures, strength enhancers, anti-cracking agents. 제 5항에 있어서,The method of claim 5, 상기 안료는 1 ~ 10 중량%, 혼화제는 0.1 ~ 5 중량%, 강도강화제는 시멘트중량의 0.5 ~ 2% 중량%, 크랙방지제는 시멘트중량의 0.1 ~ 0.3 중량%로 사용되는 축광 콘크리트 블록의 제조방법.The pigment is 1 to 10% by weight, admixture is 0.1 to 5% by weight, strength enhancer is 0.5 to 2% by weight of cement weight, cracking agent is used to manufacture a photoluminescent concrete block used 0.1 to 0.3% by weight of cement weight . 삭제delete 제 1항에 있어서,The method of claim 1, 상기 축광판 상부층 두께가 2 ~ 3mm이고, 하부층 5 ~ 7mm인 축광 콘크리트 블록의 제조방법.The thickness of the upper layer of the photoluminescent plate is 2 ~ 3mm, the lower layer 5 ~ 7mm manufacturing method of the photoluminescent concrete block.
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