KR100907049B1 - Manufacturing method of granular carbon block filter - Google Patents
Manufacturing method of granular carbon block filter Download PDFInfo
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- KR100907049B1 KR100907049B1 KR1020090035236A KR20090035236A KR100907049B1 KR 100907049 B1 KR100907049 B1 KR 100907049B1 KR 1020090035236 A KR1020090035236 A KR 1020090035236A KR 20090035236 A KR20090035236 A KR 20090035236A KR 100907049 B1 KR100907049 B1 KR 100907049B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2055—Carbonaceous material
- B01D39/2058—Carbonaceous material the material being particulate
- B01D39/2062—Bonded, e.g. activated carbon blocks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/003—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/36—Moulds for making articles of definite length, i.e. discrete articles
- B29C43/40—Moulds for making articles of definite length, i.e. discrete articles with means for cutting the article
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/52—Heating or cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2623/00—Use of polyalkenes or derivatives thereof for preformed parts, e.g. for inserts
- B29K2623/18—Polymers of hydrocarbons having four or more carbon atoms, e.g. polymers of butylene, e.g. PB, i.e. polybutylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/14—Filters
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Abstract
Description
본 발명은 정수기에 장착되어 수돗물에 함유된 철, 녹 및 유기물 등의 각종 불순물을 걸러내는 입상카본블럭 필터의 제조방법에 관한 것으로, 특히 입상활성탄과 입상PE바인더를 이용하여 통수량과 여과력이 뛰어난 입상카본블럭 필터를 압축성형으로 제조하는 기술분야에 속하는 발명이다.The present invention relates to a method for producing a granular carbon block filter mounted on a water purifier to filter out various impurities such as iron, rust, and organic matter contained in tap water, and in particular, the granular activated carbon and granular PE binder are used to provide excellent water flow rate and filtering power. It is an invention belonging to the technical field which manufactures a particulate carbon block filter by compression molding.
일반적으로 정수기에 장착되는 필터는 수돗물에 함유된 철, 녹 및 유기물 등의 각종 불순물을 걸러내는 기능과 세균을 살균하고 바이러스를 비활성화시키는 등의 기능을 갖는다.In general, a filter installed in a water purifier has a function of filtering out various impurities such as iron, rust, and organic matter contained in tap water, sterilizing bacteria, and inactivating viruses.
이러한 필터는 다양한 종류의 것이 제안되고 있으며, 특히 카본블럭 필터는 카본블럭을 필터용기에 내장시켜 물이 상기 카본블럭을 통과하면서 정수가 이루어질 수 있도록 하는 것이다.Various kinds of such filters have been proposed, and in particular, the carbon block filter embeds the carbon block in the filter container so that water can be purified while passing through the carbon block.
상기 카본블럭 필터를 제조하는 종래의 방법은 분말활성탄과 일반적인 PE바인더를 주원료로 하여 압축프레스 방식 또는 압출방식을 통해 매우 제한적인 형태로 필터를 제조함에 따라 통수량 및 정수성능이 현저하게 저하되고 있는 실정이다.In the conventional method of manufacturing the carbon block filter, the amount of water flow and the water purification performance are remarkably deteriorated as the filter is manufactured in a very limited form using a powder activated carbon and a general PE binder as a main raw material by a compression press method or an extrusion method. It is true.
더욱이 상기 카본블럭 필터의 정수성능을 개선하기 위해서는 필요 이상으로 카본블럭 필터를 크게 제조하여야만 함으로써 카본블럭 필터의 자체적인 부피가 증가하여 취급이 불편함은 물론 정수기 전체의 부피가 커지는 불합리한 문제점이 야기된다.Furthermore, in order to improve the water purification performance of the carbon block filter, the carbon block filter should be made larger than necessary to increase the volume of the carbon block filter itself, resulting in inconvenience in handling and unreasonable problem of increasing the volume of the whole water purifier. .
이와 같은 문제점을 해소하기 위한 방안으로 본 발명의 출원인에 의해 선출원되어 특허결정된 『특허등록 제785686호 명칭 고성능 카본블럭 필터의 제조방법』이 제안되고 있다.In order to solve such a problem, a "patent method for producing a high performance carbon block filter, registered in Korean Patent No. 785686", which has been filed and patented by the applicant of the present invention, has been proposed.
상기 선등록 발명은 압축프레스 작업으로 고성능의 카본블럭 필터를 제조함으로써 정수성능이 획기적으로 향상됨은 물론 통수량이 많아 필터의 수명이 연장되는 유용한 효과를 제공한다.The pre-registered invention provides a useful effect of prolonging the life of the filter, as well as significantly improving the water purification performance by producing a high-performance carbon block filter by a compression press operation.
그러나 선등록 발명은 입자크기가 미세한 분말활성탄과 고분자 PE바인더를 주원료로 하여 카본블럭 필터를 제조함으로써 공극이 작아 저압이나 수질이 좋지 않은 지역에서는 통수량이 저하되어 필터가 제 성능을 발휘하지 못하는 일부의 개선점이 요구되고 있는 실정이다.However, in the pre-registered invention, a carbon block filter is manufactured using powder activated carbon and a polymer PE binder having a fine particle size as a main raw material. Improvements are required.
본 발명은 종래의 카본블럭 필터가 내포하고 있는 제반 문제점을 적극적으로 해소하기 위한 것으로, 입상활성탄과 특수 고분자 입상PE바인더를 주원료로 하여 통수량이 풍부하면서도 여과력이 높은 입상카본블럭 필터를 압축성형할 수 있도록 함을 발명의 해결과제로 한다.The present invention is to actively solve all the problems in the conventional carbon block filter, and the granular activated carbon and the special polymer granular PE binder as the main raw material to compress the granular carbon block filter having a high water flow rate and high filtering power. It is to be an object of the invention.
본 발명은 상기한 과제를 적극적으로 해결하기 위한 수단으로 입자상태의 입상활성탄과 제1 입상PE바인더 및 제2 입상PE바인더를 골고루 혼합하도록 하고, 상기 혼합된 원료를 금형에 충진한 후 압축프레스를 이용하여 가압하면서 입상카본블럭 필터를 압축 성형하도록 하며, 상기 금형 전체를 열처리한 후 냉각과정을 거친 금형으로부터 입상카본블럭 필터를 인출하도록 하는 기술을 강구한다.According to the present invention, the granular activated carbon, the first granular PE binder and the second granular PE binder are mixed evenly as a means for actively solving the above problems, and the compressed raw material is filled in a mold and then compressed. The present invention seeks to compress the granular carbon block filter while pressurizing, and to take out the granular carbon block filter from the mold after the entire heat treatment of the mold and the cooling process.
본 발명에 따르면, 입상활성탄과 특수 고분자 입상PE바인더를 골고루 혼합한 후 상기 혼합된 원료를 압축프레스 작업을 통해 통수량이 뛰어나면서도 여과력이 우수한 입상카본블럭 필터로 제조할 수 있게 된다.According to the present invention, after evenly mixing the granular activated carbon and the special polymer granular PE binder, the mixed raw material can be manufactured as a granular carbon block filter having excellent water flow rate and excellent filtering power through a compression press operation.
따라서, 수돗물의 품질 및 상수관의 시설이 노후되거나 수압이 낮은 지역에서도 우수한 정수기능을 발휘하는 효과를 제공한다.Therefore, it provides the effect of exerting an excellent water purification function even in areas where the quality of tap water and water pipes are old or low in water pressure.
본 발명이 해결하고자 하는 과제의 해결수단을 보다 구체적으로 구현하기 위 한 바람직한 실시예에 대하여 설명하기로 한다.It will be described with respect to the preferred embodiment for implementing the solution of the problem to be solved by the present invention in more detail.
우선적으로 본 발명은 분말활성탄 및 PE분말바인더를 이용하여 카본블럭 필터를 제조하던 종래의 방법을 탈피하여 수압이 낮거나 수질이 좋지 않은 수돗물의 경우에도 원활하게 필터를 통과하면서 정화될 수 있는 통수량이 풍부한 입상카본블럭 필터를 제조함을 발명의 특징적인 요지로 한다.Firstly, the present invention breaks through the conventional method of manufacturing a carbon block filter using powder activated carbon and PE powder binder, and the amount of water flowing through the filter can be smoothly purified even in the case of tap water having low water pressure or poor water quality. It is a characteristic gist of the invention to produce this rich particulate carbon block filter.
상기한 특징적인 요지를 달성하기 위한 본 발명에 의한 입상카본블럭 필터의 제조방법을 각각의 공정별로 상세하게 설명하기로 한다. A method of manufacturing a particulate carbon block filter according to the present invention for achieving the above-described characteristic gist will be described in detail for each process.
1)원료 혼합공정1) Raw material mixing process
본 발명은 입상카본블럭 필터의 성분원료인 입상활성탄(Granular Activated Carbon)에 인장응력, 입자크기, 밀도가 다른 2종류의 제1 입상PE바인더 및 제2 입상PE바인더를 첨가하여 산업용 믹서기에 투입한 후 460RPM으로 30분간 골고루 혼합함으로써 입상카본블럭 필터를 성형하기 위한 혼합원료를 준비한다. In the present invention, two types of first granular PE binders and second granular PE binders having different tensile stresses, particle sizes, and densities are added to granular activated carbon, which is a raw material of the granular carbon block filter, and added to an industrial mixer. After the mixture is mixed evenly for 30 minutes at 460 RPM to prepare a mixed raw material for forming a granular carbon block filter.
한편, 본 발명에서 사용되는 입상활성탄은 물속의 염소 및 냄새를 제거하고, 휘발성 유기화합물 및 일부 중금속을 제거하며, 물맛을 개선하는 입상의 활성탄으로, 아래의 일람표 1과 같은 특성을 갖는 상업적으로 이용되는 제품인 신광활성탄(Shin Kwang 사의 제품)을 사용한다.Meanwhile, the granular activated carbon used in the present invention is a granular activated carbon which removes chlorine and odors in water, removes volatile organic compounds and some heavy metals, and improves water taste, and is commercially available having the characteristics as shown in Table 1 below. Shin Kwang Co. (Shin Kwang Co., Ltd.) is used.
[표 1]TABLE 1
또한, 본 발명에서 사용되는 제1 입상PE바인더 및 제2 입상PE바인더는 열처리과정에서 필터를 블럭의 형태로 성형하기 위해 입상활성탄의 연결사슬을 형성시키는 접착제의 역할을 수행하는 것으로, 아래의 일람표 2와 같은 특성을 갖는 상업적으로 이용되는 제품인 GUR X 155(제1 입상PE바인더) 및 GUR4022-6(제2 입상PE바인더)(Ticona Engineering 사의 제품)을 사용한다.In addition, the first granular PE binder and the second granular PE binder used in the present invention serve as an adhesive for forming a connection chain of granular activated carbon to form a filter in the form of a block during the heat treatment process. Commercially available products having the same characteristics as GUR X 155 (first granular PE binder) and GUR4022-6 (second granular PE binder) (product of Ticona Engineering) are used.
[표 2]TABLE 2
이하, 상기한 입상활성탄, 제1 입상PE바인더 및 제2 입상PE바인더를 적정비율로 혼합하여 10~30㎛ 기공크기를 갖는 입상카본블럭 필터를 제조하기 위한 본 발명의 혼합 원료를 생성하는 다양한 실시 예에 대해 설명하기로 한다.Hereinafter, various embodiments of the present invention are used to produce the mixed raw material of the present invention for producing a granular carbon block filter having a pore size of 10 to 30 μm by mixing the granular activated carbon, the first granular PE binder, and the second granular PE binder in an appropriate ratio. An example will be described.
① 제1 ① First 실시예Example
본 발명의 제1 실시예는, 주원료인 입상활성탄에 대하여 부원료인 제1 입상PE바인더 및 제2 입상PE바인더의 첨가비율이 중량대비 10: 3: 3의 비율이 되도록 첨가하여 골고루 혼합한다.In the first embodiment of the present invention, the addition ratio of the first granular PE binder and the second granular PE binder, which are the subsidiary materials, to the granular activated carbon, which is the main raw material, is added and mixed evenly.
여기에서 585㎛의 입자크기를 갖는 제1 입상PE바인더와 340㎛의 입자크기를 갖는 제2 입상PE바인더는 상호 동일한 비율로 혼합되는 경우 최종적으로 완성되는 입상카본블럭 필터의 기공은 약 30㎛를 형성하여 통수량이 매우 우수하다.Here, when the first granular PE binder having a particle size of 585 μm and the second granular PE binder having a particle size of 340 μm are mixed at the same ratio, the pore length of the final granular carbon block filter is about 30 μm. The amount of water flow is very good.
② 제2 ② Second 실시예Example
본 발명의 제2 실시예는, 주원료인 입상활성탄에 대하여 부원료인 제1 입상PE바인더 및 제2 입상PE바인더의 첨가비율이 중량대비 10: 2: 4의 비율이 되도록 첨가하여 골고루 혼합한다.In the second embodiment of the present invention, the addition ratio of the first granular PE binder and the second granular PE binder, which are the subsidiary materials, to the granular activated carbon, which is the main raw material, is added and mixed evenly.
여기에서 제1 실시예와 다른 점은 585㎛의 입자크기를 갖는 제1 입상PE바인더의 비율은 감소한 반면, 340㎛의 입자크기를 갖는 제2 입상PE바인더의 비율은 증가한 점으로써 입자의 크기가 작은 제2 입상PE바인더의 증가로 인해 최종적으로 완성되는 입상카본블럭 필터의 기공은 줄어들면서 약 20㎛을 형성한다.The difference from the first embodiment here is that the proportion of the first granular PE binder having a particle size of 585 µm is decreased, whereas the proportion of the second granular PE binder having a particle size of 340 µm is increased. Due to the increase of the small second granular PE binder, the pore of the finally completed granular carbon block filter is reduced to form about 20 mu m.
따라서, 상기 제1 입상PE바인더 및 제2 입상PE바인더의 비율에 따라 기공크기를 자유롭게 조절함으로써 각기 통수량이 다른 입상카본블럭 필터를 제조하는 효과를 제공한다.Accordingly, by freely adjusting the pore size according to the ratio of the first granular PE binder and the second granular PE binder, it provides an effect of producing a granular carbon block filter having a different water flow rate.
③ 제3 ③ Third 실시예Example
본 발명의 제3 실시예는, 주원료인 입상활성탄에 대하여 부원료인 제1 입상PE바인더 및 제2 입상PE바인더의 첨가비율이 중량대비 10: 1: 5의 비율이 되도록 첨가하여 골고루 혼합한다.In a third embodiment of the present invention, the addition ratio of the first granular PE binder and the second granular PE binder, which are the subsidiary materials, to the granular activated carbon, which is the main raw material, is added and mixed evenly.
여기에서 제2 실시예와 다른 점은 제1 입상PE바인더의 비율은 더욱 감소하고, 제2 입상PE바인더의 비율은 더욱 증가한 점이다.The difference from the second embodiment here is that the ratio of the first granular PE binder is further reduced, and the ratio of the second granular PE binder is further increased.
따라서, 입자의 크기가 작은 제2 입상PE바인더의 비율이 더욱 증가하여 최종적으로 완성되는 입상카본블럭 필터의 기공은 줄어들면서 약 10㎛를 형성함으로써 통수량이 제2 실시예보다 낮아진다.Therefore, the proportion of the second granular PE binder with smaller particle size is further increased to form about 10 μm while reducing the pores of the granular carbon block filter, which is finally completed, so that the water flow rate is lower than that of the second embodiment.
2) 필터 성형공정2) Filter Forming Process
본 발명은 상기한 입상활성탄, 제1 입상PE바인더 및 제2 입상PE바인더를 골고루 혼합하여 생성한 혼합원료를 이용하여 도 1과 같은 원통형의 입상카본블럭 필터(1)를 성형한다.The present invention forms a cylindrical particulate
이와 같은 필터 성형공정은 상, 하부가 개방된 알루미늄 금형(3)의 내부에 입상카본블럭 필터(1)의 통수공(2)을 형성하기 위한 내부 코어(4)를 삽입 설치한다.In this filter forming step, an
따라서, 상기 코어(4)는 하단부에 형성된 밀폐판(5)이 금형(3)의 하부를 밀폐한 상태에서 금형(3) 내부의 중심에 위치한다.Accordingly, the
상기 코어(4)의 설치가 완료된 후 혼합원료(6)를 용기에 담아 정밀 전자저울을 이용하여 정량을 확인한 후 금형(3)의 내부에 혼합원료(6)를 충진한다.After the installation of the
그리고 프레스(7)를 가동하면 프레스(7)에 설치된 프레져(8)가 하부로 이동하면서 금형(3)의 내부로 투입되어 혼합원료(6)를 가압함으로써 원통형의 입상카본블럭 필터(1)를 성형할 수 있게 된다.Then, when the
3) 열처리공정3) Heat treatment process
본 발명은 열처리를 시행함에 있어서 상기 금형(3)으로부터 성형된 입상카본블럭 필터(1)를 분리하지 않고, 금형(3) 전체를 열처리로에 투입하여 전체 열처리를 시행함을 특징으로 한다.The present invention is characterized in that the entire heat treatment is performed by putting the
이는 고온의 열처리 과정에도 금형(3)이 입상카본블럭 필터(1)의 형태를 그대로 유지함으로써 제품의 외관이 우수하면서도 뛰어난 압축성 및 강성을 갖도록 하기 위함이다.This is to maintain the shape of the granular
이러한 열처리 작업은 수백 개의 필터를 동시에 열처리할 수 있는 크기의 전기로에서 200℃의 온도 조건하에 열처리를 한다.This heat treatment is performed under a temperature condition of 200 ° C. in an electric furnace of a size capable of simultaneously heating hundreds of filters.
이와 같은 열처리공정은 기존의 압출방식에 의해 제조된 카본블럭 필터가 순간적으로 고분자 PE가 열에 녹아 카본블럭의 표면을 코팅함으로써 여과력이 저하되던 문제점을 해소하여 여과력을 가일층 향상하는 효과를 제공한다.The heat treatment process is a carbon block filter prepared by the conventional extrusion method instantaneously melt the polymer PE to heat the coating of the surface of the carbon block to solve the problem that the filtering power is lowered to provide an effect of further improving the filtering power.
4) 냉각 및 분리공정4) Cooling and Separation Process
상기 열처리공정이 완료되면 각각의 금형을 외부로 인출한 후 냉풍을 이용하여 가열된 금형을 식힌다.After the heat treatment process is completed, each mold is withdrawn to the outside and the heated mold is cooled using cold air.
그리고 별도의 지그를 이용하여 금형(3)과 내부 코어(4)를 분리하여 인출하면 기존의 카본블럭 필터에 비하여 통수량이 매우 풍부하면서도 여과력이 우수한 원통형의 입상카본블럭 필터(1)를 제조할 수 있게 된다.When the
5) 절단 및 포장공정5) Cutting and Packing Process
상기와 같이 제조된 입상카본블럭 필터는 절단기를 이용하여 규격에 맞추어 절단한 후 포장을 통해 비로소 완성된 제품을 생산할 있게 된다.The granular carbon block filter manufactured as described above is finally cut to a standard using a cutter and then produced through a packaging.
도 1은 본 발명이 적용된 입상카본블럭 필터의 사시도1 is a perspective view of a granular carbon block filter to which the present invention is applied
도 2는 본 발명의 금형에 내부에 코어가 삽입되는 상태의 종단면도Figure 2 is a longitudinal cross-sectional view of the state in which the core is inserted into the mold of the present invention.
도 3는 본 발명의 금형에 혼합원료를 투입한 후 프레스를 가동하여 입상카본블럭 필터를 성형하는 상태의 종단면도3 is a longitudinal sectional view of a state in which a granular carbon block filter is formed by operating a press after adding a mixed raw material to a mold of the present invention;
[도면의 주요부분에 대한 부호의 설명] [Explanation of symbols on the main parts of the drawings]
1: 입상카본블럭 필터 3: 금형1: granular carbon block filter 3: mold
4: 코어 8: 프레져4: core 8: fraser
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