KR100906588B1 - Heat activated durable styling compositions comprising saccharide type compounds and film forming agents - Google Patents

Abstract

A composition for durable maintenance of a durable non-permanent molding or non-permanent shape of one or more keratin fibers comprising:

(a) at least one film former; And

(b) one or more saccharide type compounds selected from C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains, and one or more C ₅ to C ₇ saccharides substituted with one or more amino groups Compounds containing units.

Durable styling composition comprising a saccharide compound and a film former

Description

Heat activated durable styling composition comprising a saccharide compound and a film former {HEAT ACTIVATED DURABLE STYLING COMPOSITIONS COMPRISING SACCHARIDE TYPE COMPOUNDS AND FILM FORMING AGENTS}

One or more compounds selected from compounds comprising C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups Human keratinous fibers may be prepared by applying a composition comprising a saccharide type compound and a compound comprising at least one film forming agent different from at least one compound in certain embodiments to one or more keratin fibers and heating the one or more keratin fibers. Compositions for durable non-permanent molding or non-permanent shape of one or more keratinous fibers, including kits comprising the compositions, and methods of using the compositions. The composition can impart a durable non-permanent shape to one or more keratin fibers and maintain the non-permanent shape of the one or more keratin fibers.

In today's market, many consumers prefer a non-permanent hairstyle, ie, the flexibility of the style obtained through non-permanent shaping of the hair. Typically, the non-permanent style disappears when the hair is wet, especially when the hair is washed with water and / or shampoo. Non-permanent molding methods of keratin fibers include, for example, brushing hair, teasing hair, braiding hair, using hair rollers and optionally commercial styling products. Heating styling. Non-limiting examples of heating styling include methods for blowing hair, curling and curling hair (eg, color and heating) using elevated temperatures. Setting hair with curling curling iron and / or hot rollers).

Although the compositions and methods can provide non-permanent shaping of keratinous fibers, many consumers want a higher degree of styling than the most commercial products and methods of applying the products provide. For example, many consumers want compositions and methods that enhance non-permanent curl formation. Accordingly, there is a need for compositions and methods for non-permanent shaping of keratin fibers that produce a higher degree of styling, such as non-permanent curl formation.

In addition, many people want compositions and methods to maintain the special non-permanent shape or style of keratin fibers, such as hair. A common way of maintaining a particular hairstyle is the use of a hairspray, which is typically applied after hair styling. Other methods of maintaining the hairstyle or shape of the keratinous fibers include the use of mousse, gels, and lotions. The materials in the compositions are generally film formers, resins, gums and / or adhesive polymers.

Although the compositions and methods may provide for non-permanent shaping of keratin fibers, many consumers find durable maintenance of special non-permanent shapes or styles of keratin fibers such as hair, for example, keratin fibers may be water and / or shampoo. There is a need for compositions and methods for sustaining or maintaining the shape of keratinous fibers until they are washed with. In addition, many consumers want compositions and methods that allow hair to maintain a special shape longer than untreated hair even after washing or shampooing hair.

Thus, while commercial compositions can provide temporary setting advantages, many consumers want a higher level of maintenance or persistence. Good sustainability is the property consumers are looking for in styling products for keratin fibres. Specifically, under conditions of changing humidity, for example to a change to higher humidity, curl maintenance is what consumers seek. In addition, good curl retention in damaged hair is important to the consumer because hair fibers are weak and poorly maintained. Thus, there is also a need for a method for maintaining the shape of keratinous fibers durable even under high humidity conditions, such as greater than 40% atmospheric humidity.

Sugars and sugar derivatives are a class of numerous compounds added to hair care compositions. The use of sugars in the reported hair care compositions includes: the use of glucose to improve the texture and flexibility of the substance of natural hair (Hollenberg and Mueller, SOFW J. 121 (2) (1995)); The use of glucose to prevent hair damage and repair damaged hair (Hollenberg & Matzik, Seifen, Oele, Fette, Wachase 117 (1) (1991)); The use of glucose in shampoos (J04266812, assigned to Lion Corp.); The use of trehalose for water retention (J06122614, assigned to Shiseido Co. Ltd.); Lanthionization compositions comprising sugars (US Patent Nos. 5,348,737 and 5,641,477, assigned to Avlon Ind. Inc.); Incorporation of xylobiose into cosmetic compositions that provide increased moisture retention and reduce excessive roughness and dryness of the skin and hair (assigned to US Patent No. 5,660,838, Suntory Ltd.); Compositions for the regeneration of hair crumbs containing one or more mono- or di-saccharides (assigned to US Patent No. 4,900,545, Henkel); Hair care compositions that improve hair force, duration and volume containing C ₅ to C ₆ carbohydrates such as glucose; The use of fucose in hair treatment to prevent cravings (DE29709853, transferred to Goldwell GMBH); And the use of saccharides in shampoos (J09059134, assigned to Mikuchi Sangyo KK) to improve combing properties and to control hair damage.

In practice, sugars have been applied to hair for a number of reasons, from moisturizing to increased hair growth (assigned to J10279439, Kureha Chem. Ind. Co. Ltd.). Obviously, however, when applied to keratinous fibers, not all sugars are the same nor all sugars impart the same properties.

The inventors have at least one selected from compounds comprising at least one C ₃ to C ₅ monosaccharide substituted with at least one C ₁ to C ₂₂ carbon chain and at least one C ₅ to C ₇ saccharide unit substituted with at least one amino group. It has been found to apply one or more compositions comprising saccharide type compounds to one or more keratinous fibers. In particular, the inventors have one selected from compounds comprising C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups A composition and method using the composition comprising applying at least one saccharide type compound to at least one keratin fiber and heating at least one keratin fiber is a durable non-permanent molding of at least one keratin fiber or at least one keratin fiber. It has been found useful for the durable maintenance of non-permanent shapes.

Thus, in order to achieve one or more of these and other advantages, the present invention provides, in one aspect, a C ₃ to C ₅ monosaccharide optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more amino groups substituted with one or more amino groups. Durable non-permanent molding of one or more keratin fibers or one or more keratinous fibers, comprising one or more saccharide type compounds selected from compounds comprising C ₅ to C ₇ saccharide units and one or more film formers different from the one or more compounds A composition for durable maintenance of a non-permanent shape of keratinous fibers, wherein one or more compounds and one or more film formers impart a durable non-permanent shape to one or more keratinous fibers or a non-permanent shape of one or more keratinous fibers Present in an amount effective to maintain durability) Provided. In one embodiment, the composition is heat-activated.

In another embodiment, the invention provides (i) C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups At least one saccharide type compound selected from the compound comprising (ii) at least one film forming agent different from at least one compound to at least one keratin fiber; A method for durable non-permanent molding of one or more keratin fibers or durable maintenance of the non-permanent shape of one or more keratin fibers, comprising heating one or more keratin fibers, wherein the one or more compounds and one or more films are formed The agent is present in an amount effective to impart a durable non-permanent shape to one or more keratinous fibers or to maintain a durable non-permanent shape of one or more keratinous fibers, further wherein the composition is applied before or during heating. Doing.

The present invention, in another aspect, comprises C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups A composition for durable non-permanent molding of one or more keratin fibers or for the durable maintenance of a non-permanent shape of one or more keratin fibers, comprising one or more saccharide type compounds selected from compounds, wherein the one or more compounds Or is present in an amount effective to impart a durable non-permanent shape to the keratinous fibers or to maintain the non-permanent shape of the one or more keratinous fibers durable. In one embodiment, the composition is heat-activated.

In another embodiment, the invention comprises C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups Applying at least one saccharide type compound selected from the compounds to at least one keratin fiber; A method for durable non-permanent molding of one or more keratin fibers or for the durable maintenance of a non-permanent shape of one or more keratin fibers, comprising heating one or more keratin fibers, wherein the one or more compounds comprise one or more keratin fibers Is present in an amount effective to impart a durable non-permanent shape to or to maintain the non-permanent shape of one or more keratinous fibers, further wherein the composition is applied before or during heating.

In another embodiment, the invention relates to one or more compartments, wherein the first compartment is a C ₃ to C ₅ monosaccharide optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ substituted with one or more amino groups. To a non-permanent molding of one or more keratin fibers or a non-permanent form of one or more keratin fibers, comprising a first composition comprising one or more saccharide type compounds selected from compounds containing C ₇ saccharide units. Kits are provided for durable maintenance of permanent shapes. In one embodiment, the one or more compartments comprise one or more additional sugars different from the one or more compounds, and in another embodiment, the one or more compartments comprise one or more film formers.

Specific terms used herein are defined below:

As used herein, "one or more" means one or more, and therefore includes mixtures / combinations as well as individual components.

The term “keep shape durable” as used herein refers to the ability to maintain a special shape after styling, as compared to the ability to maintain a special shape after styling of an untreated hair following six or more shampoos after treatment. It means to keep.

"Durable molding" as used herein relates to maintaining or maintaining the shape of the keratin fibers until the keratin fibers are washed with water and / or shampoo. Retention of shape is, in terms of curl efficiency (see, eg, Examples 1 and 2), by measuring and comparing the ability to maintain curl of treated and untreated hair under conditions of high relative humidity. Can be evaluated.

“Heating” relates to the use of elevated temperature (ie, above 100 ° C.). In one embodiment, the heating in the inventive method may be provided by direct contact of the one or more keratin fibers with a heat source, for example by heating styling of the one or more keratin fibers. Non-limiting examples of heating styling by direct contact with one or more keratinous fibers include curling methods using flat ironing and elevated temperatures (eg, hair setting and heating in color, and curling irons and / or Or curling with a hot roller). In another embodiment, heating in the inventive method may be provided by heating one or more keratinous fibers with a heating source that may not be in direct contact with the one or more keratinous fibers. Non-limiting examples of heating sources that may not be in direct contact with one or more keratinous fibers include blow dryers, hood dryers, heating caps, and steamers.

As used herein, a “heat-activated” composition refers to a composition that, for example, forms one or more keratinous fibers better than the same composition that was not heated during or after application of the composition. Another example includes compositions that maintain the shape of one or more keratinous fibers better than the same composition not heated during or after application.

As used herein, "high humidity" refers to atmospheric humidity above 40%.

As used herein, "keratin fibers" can be human keratin fibers, for example selected from hair.

As used herein, “non-permanent shaping” of keratin fibers refers to a method of setting keratin fibers in a particular shape or style that does not involve breaking and reforming disulfide bonds in keratin fibers.

As used herein, the "non-permanent shape" of a keratinous fiber refers to the shape or style of the keratinous fiber obtained without breaking up the disulfide bonds of the keratinous fiber and reforming.

As used herein, "oligosaccharide" generally refers to a compound comprising 2 to 10 monosaccharide units bonded together, which may be the same or different.

"Polysaccharide" as used herein generally refers to a compound comprising more than 10 monosaccharide units bonded together, which may be the same or different.

As used herein, "polymer" includes copolymers (including terpolymers) and homopolymers.

The foregoing general description and the following detailed description are exemplary and explanatory only and, as claimed, do not limit the invention. Reference will now be made in detail to exemplary embodiments of the invention.

As described above, sugars have been used in hair care compositions and other treatments for the moisture retention properties of hair. In addition to retaining moisture, however, it has been unexpectedly discovered by the inventors that certain classes of sugars impart durable retention of durable non-permanent shapes or non-permanent shapes or styles to one or more keratin fibers. With respect to hair, in particular from compounds comprising C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups It has been found that the saccharide type compounds that give good curl formation to one or more keratin fibers and prevent the curl from sagging due to, for example, humidity. In addition, the compounds may impart the ability to shampoo one or more keratin fibers to one or more keratin fibers and then maintain a particular style even after treatment with a composition comprising one or more of the compounds. This is especially true when the compound is applied to the hair and then the hair is heated.

Accordingly, the present invention provides a compound comprising (i) a C ₃ to C ₅ monosaccharide optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups At least one saccharide type compound selected from and optionally (ii) at least one film former (wherein, in accordance with embodiments, at least one compound and optionally at least one film former are non-permanent shapes that are durable in at least one keratin fibre). Durable non-permanent molding of the one or more keratin fibers or non-permanent shape of the one or more keratin fibers, the present invention being in an amount effective to impart or to maintain the non-permanent shape of the one or more keratin fibers durable. To provide a composition for maintenance. In one embodiment, the composition is heat-activated. In another embodiment, the composition imparts a durable non-permanent shape to the one or more keratin fibers and also maintains the non-permanent shape of the one or more keratin fibers. The composition may further comprise one or more additional sugars.

The invention also relates to compounds comprising (i) C ₃ to C ₅ monosaccharides optionally substituted with one or more C ₁ to C ₂₂ carbon chains and one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups. Applying to at least one keratinous fiber a composition comprising at least one saccharide type compound selected and (ii) at least one film former; Provided are methods for durable non-permanent molding of one or more keratin fibers or for the durable maintenance of non-permanent shapes of one or more keratin fibers comprising heating one or more keratin fibers. The composition can be applied before or during heating. In addition, the one or more compounds and optionally one or more film formers, depending on the embodiment, the one or more compounds and optionally one or more film formers impart a durable non-permanent shape to the one or more keratin fibers or the ratio of one or more keratin fibers It is present in an amount effective to keep the permanent shape durable. In one embodiment, the composition imparts a durable non-permanent shape to the one or more keratin fibers and also maintains the non-permanent shape of the one or more keratin fibers durable. The composition may further comprise one or more additional sugars.

According to certain embodiments of the present invention, one or more compounds may be used with one or more film formers, such as, for example, film forming polymers and resins. For example, the film forming polymer can be selected from cationic polymers, anionic polymers and nonionic polymers. Non-limiting examples of one or more film formers are those described in pages 1744-1747 of the CTFA International Cosmetic Ingredient Dictionary, 8 ^th edition (2000). In one embodiment, the one or more film formers can be selected from water soluble compounds, fat soluble compounds and compounds soluble in organic solvents. According to the invention, one or more film formers may generally be present in an amount ranging from 0.01% to 30% by weight of the active material relative to the total amount of the composition, such as from 0.1% to 10% by weight of the active material. One of ordinary skill in the art is that one or more film formers according to the present invention may be commercially available and may come from suppliers in the form of diluents. The amount of one or more film formers disclosed herein thus reflects the weight percent of the active material.

Non-limiting examples of one or more film formers are those disclosed in WO 01/18096, the disclosure of which is incorporated herein by reference. Other non-limiting examples of at least one film former include (i) at least one vinyl monomer comprising at least one quaternary ammonium group and (ii) acrylamide, methacrylamide, alkyl acrylamide, dialkyl acrylamide, alkyl methacryl From one or more additional monomers selected from amides, dialkyl methacrylamides, alkyl acrylates, alkyl methacrylates, vinyl caprolactones, vinyl pyrrolidones, vinyl esters, vinyl alcohols, maleic anhydrides, propylene glycols and ethylene glycols It includes a copolymer of.

Further non-limiting examples of one or more film formers are:

U.S., the disclosure of which is incorporated herein by reference. Patent No. Vinyl acetate / vinyl tert butylbenzoate / crotonic acid terpolymers as described in 4,282,203;

N-octylacrylamide / methyl methacrylate / hydroxypropyl methacrylate / acrylic acid / tert-butylamino-ethyl methacrylate copolymer such as product name "AMPHOMER LV-71" manufactured by NATIONAL STARCH;

로 판매되는 Corn Starch Modified 와 같은 옥수수 전분/폴리비닐피롤리돈 공중합체 ;-Product name of Amaize by National Starch and Chemicals

Corn starch / polyvinylpyrrolidone copolymers such as Corn Starch Modified;

Vinylpyrrolidone / vinyl acetate copolymers such as BASF product name “LUVISKOL VA 64 Powder”;

28-2930" 과 같은 비닐 아세테이트/크로톤산/비닐 네오데카노에이트 삼중합체 ;-NATIONAL STARCH's product name "RESYN

Vinyl acetate / crotonic acid / vinyl neodecanoate terpolymer, such as 28-2930 ";

Acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymers, such as the product name “ULTRA-HOLD 8” from BASF;

Acrylic acid / acrylate / hydroxyacrylate / succinic acid copolymers, such as acrylate / C1-2 succinate hydroxyacrylate copolymers, sold as ALLIANZ LT-120 by ISP.

Vinyl acetate / crotonic acid (90/10) copolymers such as the product name “LUVISET CA 66” from BASF;

-Amerchol Corp. Acrylic acid / methacrylic acid / acrylate / methacrylate copolymers such as Acrylates Copolymer from Edison, N.J., USA; And

Vinyl caprolactam / vinylpyrrolidone / dimethylamino ethyl methacrylate copolymer such as the product name “POLYMER ACP-1018” from GAF.

Further non-limiting examples of one or more film formers are:

(I) 1-vinyl-2-pyrrolidone and (ii) 1-vinyl-3-methylimidazolium salt sold under the trade name LUVIQUAT (e.g. LUVIQUAT FC 370) by BASF Corporation (designed CTFA: Poly Copolymer derived from quaternium-16);

Copolymers derived from the reaction of (iii) vinylcaprolactam and (ii) vinylpyrrolidone sold by BASF with methylvinylimidazolium methosulfate (CTFA design: polyquaternium-46);

Copolymers derived from (i) vinylpyrrolidone and (ii) quaternized imidazoline monomers available from BASF (CTFA Design: Polyquaternium-44);

Copolymers derived from (i) 1-vinyl-2-pyrrolidone and (ii) 1-vinyl-3-methylimidazolium salt sold under the trade name LUVIQUAT (e.g. LUVIQUAT FC 370) by BASF Corporation. (CTFA design: polyquaternium-16);

Poly (vinylamine), optionally quaternized;

Poly-4-vinylpyridine, optionally quaternized;

Poly (ethyleneimine), optionally quaternized;

Dimethyldiallylammonium chloride homopolymer (CTFA design: polyquaternium-6);

-(Iii) copolymers derived from acrylamide and (ii) dimethyldiallylammonium chloride (CTFA design: polyquaternium-7);

A copolymer derived from (iii) dimethyldiallylammonium chloride, and (ii) sodium acrylate (CTFA design: polyquaternium-22); And

A terpolymer (CTFA design: polyquaternium-39) derived from (iii) dimethyldiallylammonium chloride, (ii) acrylamide and (iii) sodium acrylate.

Other non-limiting examples of one or more film formers are, for example, salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide (CTFA design: Polyquaternium-10), such as polymer series Polymer JR ™, LR ™ and SR ™ with Amerchol Corp. Cationic cellulose derivatives such as cationic cellulose commercially available from Edison, N.J., USA; Amerchol Corp. Polymeric quaternary ammonium salt of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substituted epoxide marketed under the trade name Polymer LR-200 ™ by Edison, NJ, USA (Design of CTFA: Polyquaternium-24) ; And derivatives of polysaccharide polymers such as cationic starch such as Croda quaternary starch and derivatives thereof.

In one embodiment, the one or more film formers are selected from cationic polymers such as polyquaternium-16, polyquaternium-46 and polyquaternium-44. In another embodiment, the one or more film formers comprise (1) corn starch and (2) polymers derived from polyvinylpyrrolidone; And nonionic polymers such as (1) vinyl acetate and (2) copolymers derived from vinylpyrrolidone. In another embodiment, the at least one film forming agent is a polymer derived from (1) vinyl acetate (2) crotonic acid and (3) vinyl neodecanoate, (1) acrylic acid (2) acrylate (3) hydroxyacrylic Rate and (4) anionic polymers such as polymers derived from succinic acid and polymers derived from two or more monomers selected from acrylic acid, methacrylic acid, esters of acrylic acid and esters of methacrylic acid. One or more film formers selected from anionic polymers may be neutralized to render the anionic polymers soluble.

The C ₃ to C ₅ monosaccharides according to the invention can be selected from any trios, tetros and pentose. In addition, the C ₃ to C ₅ monosaccharides may be selected from D-form, L-form and any mixtures described above. Non-limiting examples of C ₃ to C ₅ monosaccharides include aldopentose (such as xylose, arabinose, lyxos and ribose), ketopentose (such as ribulose and xylose), aldoterose ( Ketotetrose (such as erythrose), aldotriose (such as glyceraldehyde), and ketotriose (such as dihydroxyacetone). C ₃ to C ₅ monosaccharides may be selected from C ₃ to C ₅ monosaccharides including aldehyde groups (aldos), furanos and other ring structures. C ₃ to C ₅ monosaccharides may be further substituted with one or more groups different from the C ₁ to C ₂₂ carbon chains.

Derivatives of C ₃ to C ₅ monosaccharides substituted with one or more C ₁ to C ₂₂ carbon chains may be used as one or more compounds of the invention. For example, ammonia or primary amines can react with aldehyde or ketone groups of sugars to form imine derivatives (ie compounds containing functional group C = N). The imine compound is sometimes considered as a Schiff base. C ₃ to C ₅ mono different ratio of the derivative of the saccharide-limiting examples of C ₃ to C ₅ mono-saccharide of the hemiacetal derivatives, C ₃ to C ₅ monosaccharides hemi ketal derivative thereof and C ₃ to C ₅ of the monosaccharides Any oxidized derivative of a ride. Such derivatives can be formed, for example, from the reaction of alcohols with aldehyde or ketone groups of sugars. C ₃ to C ₅ mono-saccharide derivatives of other examples of the fluoride, but may comprise a C ₃ to C ₅ mono-saccharide derived from a saccharide such as agarobiose oligonucleotide of yarn size is not limited thereto. As described above, one or more C ₁ to C ₂₂ with C ₃ substituted with a carbon chain to C ₅ mono-saccharide at least one compound selected from fluoride is optionally substituted with one or more C ₁ to C ₂₂ carbon chain with more different one or more group Can be. Thus, in one embodiment, derivatives of C ₃ to C ₅ monosaccharides may be further substituted with one or more groups different from one or more C ₁ to C ₂₂ carbon chains.

According to the invention, one or more C ₁ to C ₂₂ carbon chains may be selected from saturated or unsaturated linear, branched and cyclic C ₁ to C ₂₂ carbon chains. One or more C ₁ to C ₂₂ carbon chains may be optionally substituted. In one embodiment, the at least one C ₁ to C ₂₂ carbon chain is selected from C ₁₆ to C ₁₈ carbon chains. In another embodiment, the at least one C ₁ to C ₂₂ carbon chain is selected from C ₁₆ carbon chains and C ₁₈ carbon chains. Non-limiting examples of C ₁₆ carbon chains are linear hexadecyl chains, and non-limiting examples of C ₁₈ carbon chains are linear octadecyl chains.

In addition, C ₃ to C ₅ monosaccharides may be substituted with one or more C ₁ to C ₂₂ carbon chains at any position of the sugar. For example, in one embodiment, the C ₃ to C ₅ monosaccharides are at the C ₁ position of the C ₃ to C ₅ monosaccharides. Substituted with one or more C ₁ to C ₂₂ carbon chains. In another embodiment, the C ₃ to C ₅ monosaccharides are substituted with one or more C ₁ to C ₂₂ carbon chains in one or more hydroxy groups of the C ₃ to C ₅ monosaccharides. As used herein, the substitution at one or more of the hydroxy groups of the C ₃ to C ₅ monosaccharides is at the hydroxy group itself (ie, the ether linkage between the C ₃ to C ₅ monosaccharides and the C ₁ to C ₂₂ carbon chains). Means a substituent at a carbon atom with at least one substituent and a hydroxy group which is usually bonded. Additionally, C ₃ to C ₅ monosaccharides are carbon atoms free of hydroxy groups (ie, carbon atoms in C ₃ to C ₅ monosaccharides with substituents other than CH ₂ or hydroxy groups in C ₃ to C ₅ monosaccharides). It may be substituted with one or more C ₁ to C ₂₂ carbon chain in. In addition, C ₃ to C ₅ monosaccharides may be further substituted with one or more substituents different from one or more C ₁ to C ₂₂ carbon chains.

In one embodiment, the one or more film formers are selected from cationic polymers such as polyquaternium-16, polyquaternium-46 and polyquaternium-44. In another embodiment, the one or more film formers comprise (1) corn starch and (2) polymers derived from polyvinylpyrrolidone; And nonionic polymers such as (1) vinyl acetate and (2) copolymers derived from vinylpyrrolidone. In another embodiment, the at least one film forming agent is a polymer derived from (1) vinyl acetate (2) crotonic acid and (3) vinyl neodecanoate, (1) acrylic acid (2) acrylate (3) hydroxyacrylic Rate and (4) anionic polymers such as polymers derived from succinic acid and polymers derived from two or more monomers selected from acrylic acid, methacrylic acid, esters of acrylic acid and esters of methacrylic acid. One or more film formers selected from anionic polymers may be neutralized to render the anionic polymers soluble.

One or more C ₅ to C ₇ saccharide units according to the invention may be selected from any pentose, hexose and heptose. In addition, one or more C ₅ to C ₇ saccharide units may be selected from D-form, L-form and any mixtures described above. Non-limiting examples of C ₅ to C ₇ saccharide units include aldopentose (such as xylose, arabinose, lyxose and ribose), ketopentose (such as ribulose and xylose), aldohexose ( Such as glucose and galactose), ketohexose (such as fructose and sorbose) and heptose (such as aldoheptose and ketoheptose, for example galactoheptulose and glucoheptulose). One or more C ₅ to C ₇ saccharide units may be selected from those including aldehyde groups (aldos), furanos and other ring structures. One or more C ₅ to C ₇ saccharide units may be further substituted with one or more groups different from one or more amino groups.

C ₅ to C _7, a derivative of the saccharide units may be used with one or more C ₅ to C ₇ saccharide units in the present invention. For example, ammonia or primary amines can react with aldehyde or ketone groups of saccharide units to form imine derivatives (ie compounds containing functional group C = N). The imine compound is sometimes considered as a Schiff base. C ₅ to C ₇ saccharide other ratio of the derivative of fluoride unit-limiting examples of C ₅ to C ₇ saccharide units of the hemiacetal derivatives thereof, C ₅ to C ₇ saccharide hemi ketal derivatives, and C ₅ to C of a unit ₇ saccharide Any oxidized derivative of the unit. Such derivatives can be formed, for example, from the reaction of an aldehyde or ketone group of a saccharide unit with an alcohol. As mentioned above, one or more C ₅ to C ₇ saccharide units may be further substituted with one or more groups different from one or more amino groups. Thus, in one embodiment, derivatives of C ₅ to C ₇ saccharide units may be further substituted with one or more groups different from one or more amino groups.

According to the invention, one or more amino groups can be selected from substituted and unsubstituted amino groups. For example, one or more amino groups can be selected from N-acetyl amino groups.

In addition, one or more C ₅ to C ₇ saccharide units may be substituted with one or more amino groups at any position of the saccharide unit. For example, in one embodiment, one or more C ₅ to C ₇ saccharide units are substituted with one or more amino groups at the C 1 position of the one or more C ₅ to C ₇ saccharide units. In another embodiment, at least one C ₅ to C ₇ saccharide unit is substituted with at least one amino group at the C2 position of at least one C ₅ to C ₇ saccharide unit.

Non-limiting examples of one or more compounds include C ₅ monosaccharides substituted with one or more amino groups, C ₆ monosaccharides substituted with one or more amino groups, C ₇ monosaccharides substituted with one or more amino groups, substitutions with one or more amino groups A polymer comprising at least one C ₅ monosaccharide, a polymer comprising at least one C ₆ monosaccharide substituted with at least one amino group, a polymer comprising at least one C ₇ monosaccharide substituted with at least one amino group, and one Glucoproteins comprising at least one C ₅ to C ₇ saccharide unit substituted with at least amino groups. In one embodiment, the one or more compounds are selected from oligosaccharides derived from one or more C ₅ to C ₇ saccharide units that are substituted with one or more amino groups that may be further substituted with one or more groups different from one or more amino groups.

A non-limiting example of C ₅ monosaccharides substituted with one or more amino groups is pentosamine. In one embodiment, the pentosamine is selected from aldopentosamine and ketopentosamine (such as, for example, xyloseamine, arabinoseamine, lyxosamine, riboseamine, ribuloseamine and xyllosamine). .

Non-limiting examples of C ₆ monosaccharides substituted with one or more amino groups include hexosamine (such as, for example, aldohexamine and ketohexamine). In one embodiment, for example, hexosamine is selected from glucosamine, galactosamine, allosamine, altrosamine, mannosamine, glucosamine, isodosamine, galactosamine and thalosamine. In another embodiment, the one or more compounds is glucosamine, and in another embodiment, galactosamine.

Non-limiting examples of C ₇ monosaccharides substituted with one or more amino groups are heptosamins. For example, heptosamin can be selected from aldoheptosamine and ketoheptosamine.

According to the invention, the at least one saccharide type compound is generally present in the composition in an amount ranging from 0.01% to 10% by weight relative to the total amount of the composition, such as from 0.1% to 5% by weight.

In addition to those of the inventive method, the compositions of the present invention may further comprise one or more additional sugars different from one or more compounds selected from C ₃ to C ₅ monosaccharides substituted with one or more C ₁ to C ₂₂ carbon chains. Can be. One or more additional sugars may, for example, help maintain moisture. The effect of sugar to aid in water retention can be measured by monitoring the DSC peak in the temperature range of 75 ° C to 200 ° C.

One or more additional sugars may be selected from any sugar, carbohydrate and carbohydrate moiety. Non-limiting examples of one or more additional sugars include pentose (eg, ribose, arabinose, xylose, lyxose, ribulose and xylose) and hexose (eg, alos, altrose, Monosaccharides containing 3 to 7 carbon sugars such as glucose, mannose, gulose, idose, galactose, talos, sorbose, sicose, fructose and tagatose); Oligosaccharides such as disaccharides (eg maltose, sucrose, cellobiose, trehalose and lactose); And polysaccharides such as starch, dextrin, cellulose and glycogen. In one embodiment, one or more additional sugars of the present invention are selected from any aldose and ketose.

In addition, one or more additional sugars may be substituted or unsubstituted. For example, one or more additional sugars may be substituted with one or more C ₁ to C ₂₂ carbon chains. In one embodiment, the at least one C ₁ to C ₂₂ carbon chain is selected from saturated or unsaturated linear, branched and cyclic C ₁ to C ₂₂ carbon chains. For example, one or more C ₁ to C ₂₂ carbon chains may be selected from C ₁₆ to C ₁₈ carbon chains (eg, C ₁₆ carbon chains and C ₁₈ carbon chains). In addition, for example, the C ₁₆ carbon chain may be selected from linear hexadecyl chains, and the C ₁₈ carbon chain may be selected from linear octadecyl chains. In one embodiment, one or more additional sugars are substituted with one or more C ₁ to C ₂₂ carbon chains at the C ₁ position of the one or more additional sugars.

According to the invention, the at least one further sugar is generally present in the composition in an amount ranging from 0.01% to 10% by weight relative to the total amount of the composition, such as from 0.1% to 5% by weight.

In addition to those of the inventive method, the compositions of the present invention may be in the form of liquids, oils, pastes, sticks, dispersions, emulsions, lotions, gels or creams. In addition, the composition may further comprise one or more suitable additives selected from additives commonly used in compositions for keratinous fibers. Non-limiting examples of one or more suitable additives include anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, fragrances, permeants, antioxidants, sequestrants, opacifiers, solubilizers, emollients, colorants , Screening agents (eg, sunscreens and UV filters), preservatives, proteins, vitamins, silicones, polymers such as thickening polymers, vegetable oils, mineral oils, synthetic oils and keratin fibres, typically in compositions for care and / or treatment Any other additives used. Needless to say, those skilled in the art will be careful to select one or more suitable additives in that the benefits of the composition according to the invention are not substantially and conversely affected by the addition (s) to be appreciated.

Compositions of the present invention and compositions used in the methods of the present invention may also comprise one or more compounds selected from C ₃ to C ₅ monosaccharides substituted with one or more C ₁ to C ₂₂ carbon chains and optionally one or more additional sugars, and It may additionally be provided as a one-part composition optionally comprising one or more film formers or in the form or kit of a multicomponent treatment. One skilled in the art will be able to determine how the compositions and / or multicomponent compositions should be stored and mixed based on the composition and the stability of the application to be understood. For example, simple sugars such as C ₃ to C ₅ monosaccharides are known to be stable at pH levels in the range of 4-9. In compositions where the pH range is below or above this level, sugars will be stored separately and added to the composition only when applied.

Accordingly, the present invention includes one or more compartments, wherein the first compartment comprises a first composition comprising one or more compounds selected from C ₃ to C ₅ monosaccharides substituted with one or more C ₁ to C ₂₂ carbon chains. It also relates to durable non-permanent molding of at least one keratin fiber comprising or durable maintenance of the non-permanent shape of at least one keratin fiber. In one embodiment, the first composition further comprises one or more additional sugars that differ from the one or more compounds, while in another embodiment, the first composition further comprises one or more film formers.

According to one aspect of the present invention, at least one compound suitable for the present invention is a mixture of pentose substituted with at least one C ₁ to C ₂₂ carbon chain. XYLIANCE brand modified pentose is a blend of hexadecyl glycosides and octadecyl glycosides, wherein the glycosides include D-xycloside, L-arabinoside and D-glucoside. XYLIANCE can be obtained from Soliance, Route de Bazancourt-51110 Pomacle, France.

Unless otherwise indicated, all numbers expressing components, reaction conditions and amounts used in the specification and claims are understood to be adjusted in all cases by the term "about". Accordingly, unless indicated to the contrary, the numerical scale within the following specification and appended claims is an approximation that may vary depending on the desired properties to be obtained by the present invention. At the very least, it is not intended to limit the application of theories corresponding to the scope of the claims, and each numerical scale should be interpreted in the light of certain digits and routine rounding approaches.

Notwithstanding that the numerical ranges and scales indicated in the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. However, any number contains certain errors that inevitably result from the standard deviation found in each test measurement. The following examples are intended to illustrate the invention without limiting the scope as a result.

Examples 1 and 2

Unless otherwise noted, the following procedure was used in the examples below to determine the efficiency of C ₃ to C ₅ monosaccharides substituted with one or more C ₁ to C ₂₂ carbon chains. Hair swatches (2 g., 6.5-7.5 in.) Were treated with a solution of film former / XYLIANCE (0.5 g solution / hair g) and then dried with a dryer. The hair swatches were then styled with curling iron for 1 minute and the curled swatches were placed in a humidity chamber for 1 hour at 90% relative humidity.

Curl Efficiency was calculated as follows:

L _t / L _o × 100

here :

L _o represents the original length of the fully elongated hair,

L _t represents the length of the hair after 1 hour in a humidity chamber.

Lower curl efficiencies indicate better curl retention.

Example 1 Curl Efficiency of XYLIANCE and Film Forming Agents

The hair is styling solution containing 3% of octylacrylamide / acrylate / butylaminoethyl / methacrylate copolymer (AMPHOMER LV-71 from National Starch and Chemicals Co., Ltd.) while varying the amount of XYLIANCE. Treatment was as described. The results are shown in Table 1.

TABLE 1

The data showed that XYLIANCE improved the curl efficiency of hair treated with the styling polymer.

Example 2 Effect of Xyliance and Neutralized Film Forming Agent

Hair was treated as described above with a solution of 0.5% XYLIANCE and 6% Amphomer LV-71 neutralized with AMP at various degrees of neutralization. The results are shown in Table 2.

TABLE 2

The data indicated that XYLIANCE improved curl retention of hairs heat treated with styling polymer at various degrees of neutralization.

Example 3

28-2930 (AMP 로 85% 로 중화된) 및 1% Xyliance (0.5 g 용액/헤어 g) 을 함유한 에탄올 용액으로 처리한 다음, 드라이어로 건조시켰다. 다음, 헤어 견본을 플랫 아이런으로 1 분 동안 가열시 킨 다음, 10% 나트륨 라우레스 술페이트 (SLES) 용액으로 샴푸하였다. 지시된 바대로, 상기 처리를 6 회까지 반복하였다. 처리된 헤어 견본을 2, 4, 및 6 회 샴푸한 다음, 30 초 동안 컬링 아이런으로 스타일링하고, 90% 상대 습도에서 습도 챔버에 두어, Curl Droop 을 측정하였다. 컬이 습도 챔버에서 천천히 느슨해지기 때문에, 헤어 견본의 길이를 매 분 마다 측정하였다 (15 분까지).The following procedure was used to treat hair and to measure Curl Droop (curl sag): Resyn the hair swatches (2 g., 6.5-7.5 in.)

It was treated with an ethanol solution containing 28-2930 (neutralized to 85% with AMP) and 1% Xyliance (0.5 g solution / hair g) and then dried with a dryer. The hair swatches were then heated with flat iron for 1 minute and then shampooed with 10% sodium laureth sulfate (SLES) solution. As indicated, the treatment was repeated up to six times. The treated hair swatches were shampooed 2, 4, and 6 times, then styled with curling iron for 30 seconds and placed in a humidity chamber at 90% relative humidity to measure Curl Droop. Since the curls loosened slowly in the humidity chamber, the length of the hair swatches was measured every minute (up to 15 minutes).

Curl Droop was calculated as follows:

[(L _o -L _t ) / (L _o -L _i )] × 100

here :

L _o represents the original length of the fully elongated hair,

L _t represents the length of the hair after t hours in the humidity chamber,

L _i denotes the starting length of the hair at 0 min in a humidity chamber (i.e. after styling with curling iron for 30 seconds).

Higher curl sag indicates better curl retention.

TABLE 1

28-2930 (AMP 로 85% 로 중화된)), 하나 이상의 C₁ 내지 C₂₂ 탄소쇄로 치환되는 C₃ 내지 C₅ 모노사카라이드로부터 선택되는 하나 이상의 화합물 (Xyliance) 및 가열로 처리된 헤어가, 하나 이상의 C₁ 내지 C₂₂ 탄소쇄로 치환되는 C₃ 내지 C₅ 모노사카라이드로부터 선택되는 하나 이상의 화합물이 없이 하나 이상의 필름형성제 (Resyn

28-2930 (AMP 로 85% 로 중화된)) 및 가열로 처리된 헤어보다 6 번의 샴푸 후에도 더 높은 컬 유지를 가짐을 보여주었다.The data includes one or more film forming agents (Resyn

28-2930 (neutralized to 85% with AMP), one or more compounds (Xyliance) selected from C ₃ to C ₅ monosaccharides substituted with one or more C ₁ to C ₂₂ carbon chains and hair treated with heat One or more film formers without one or more compounds selected from C ₃ to C ₅ monosaccharides substituted with one or more C ₁ to C ₂₂ carbon chains (Resyn

28-2930 (neutralized to 85% with AMP) and heat showed higher curl retention even after 6 shampoos.

Unless otherwise noted, the procedure used to treat hair and measure curl sag is as follows: hair swatches (2 g., 6.5-7.5 in.) Are added to film formers / xylose (0.5 g). Solution / hair g) solution and then dried with a dryer. The hair swatches were then heated with flat iron for 1 minute and then shampooed with 10% sodium laureth sulfate (SLES) solution. As indicated, the treatment was repeated up to eight times. For heat activated tests (Examples 1-8), hair swatches were styled with curling irons for 30 seconds and then placed in a humidity chamber at 90% relative humidity to measure Curl Droop. For the durability test (Example 9), the hair swatches were shampooed up to six times and then placed in a humidity chamber. Since the curls loosened slowly in the humidity chamber, the length of the hair swatches was measured every minute (up to 15 minutes).

Curl Droop was calculated as follows:

[(L _o -L _t ) / (L _o -L _i )] × 100

here :

L _o represents the original length of the fully elongated hair,

L _t represents the length of the hair after t hours in the humidity chamber,

L _i denotes the starting length of the hair at 0 min in a humidity chamber (i.e. after styling with curling iron for 30 seconds).

Higher curl sag indicates better curl retention.

Examples 4-7

Examples 4-7 show the utility of cationic polymers as one or more film formers in the compositions of the present invention, as well as the compositions used in the methods of the present invention.

Example 4 Styling Heat-Activated with Polyquaternium-16

Following this procedure, the bleached hair can be treated with a solution comprising 6% (active) polyquaternium-16 free of xylose (composition (a)) or 6% (active) polyquaternium-16 and 1% crochet. The solution was treated eight times with a solution containing silane (composition (b)). Polyquaternium-16 is a polymeric quaternary ammonium salt formed from methylvinylimidazolium chloride and vinylpyrrolidone. The results are shown in Table 1.

TABLE 1

Example 5 Styling Heat-Activated with Polyquaternium-46

Following this procedure, normal brown hair was treated with a solution comprising 6% (active) polyquaternium-46 free of xylose (composition (a)) or 6% (active) polyquaternium-46 and 1%. The solution was treated eight times with a solution containing xylose (composition (b)). Polyquaternium-46 is a polymeric quaternary ammonium salt prepared by reacting vinylcaprolactam and vinylpyrrolidone with methylvinylimidazolium methosulfate. The results are shown in Table 2.

TABLE 2

Example 6 Styling Heat-Activated with Polyquaternium-44

Following this procedure, the bleached hair can be treated with a solution comprising 6% (active) polyquaternium-44 free of xylose (composition (a)) or 6% (active) polyquaternium-44 and 1%. The solution was treated eight times with a solution containing xylose (composition (b)). Polyquaternium-44 is a polymeric quaternary ammonium salt prepared by reacting vinylpyrrolidone and quaternized reacted imidazoline monomers. The results are shown in Table 3.

TABLE 3

Examples 7 and 8

Examples 7 and 8 show the utility of nonionic water soluble polymers as one or more film formers in the compositions of the present invention, as well as the compositions used in the methods of the present invention.

Example 7. Heat Activated Styling with Corn Starch

Following this procedure, the bleached hair can be treated with a solution containing 6% (active) Corn Starch Modified without xylose (composition (a)) or with 6% (active) Corn Starch Modified and 1% xylose. The solution (composition (b)) was treated 8 times. Corn Starch Modified was made by reacting corn starch with polyvinylpyrrolidone. The results are shown in Table 4.

TABLE 4

Example 8. Styling Heat-Activated with Corn Starch

Following the above procedure, normal brown hair is treated with a solution comprising 6% (active) PVP / VA copolymer free of xylose (composition (a)) or 6% (active) PVP / VA copolymer and 1% xylose. The solution was treated eight times with a solution containing os (composition (b)). PVP / VA copolymers are copolymers of vinyl acetate and vinylpyrrolidone. The results are shown in Table 5.

TABLE 5

Examples 9-11

Examples 9-11 show the usefulness of the anionic polymers as one or more film formers in the compositions of the present invention as well as the compositions used in the methods of the present invention.

Example 9. Heat Activated Styling with VA / Crotonate / Vinyl Neodecanoate Copolymer

Following this procedure, the bleached hair can be treated with a solution comprising 6% (active) VA / crotonate / vinyl neodecanoate copolymer free of xylose (composition (a)) or 6% (active) VA / The treatment was carried out four times with a solution containing the crotonate / vinyl neodecanoate copolymer and 1% xylose (composition (b)). VA / crotonate / vinyl neodecanoate copolymers are formed from vinyl acetate, crotonic acid and vinyl neodecanoate monomers. The polymer was neutralized with 100% heavy arc with AMP (amino methylpyridine). The results are shown in Table 6.

TABLE 6

Example 10. Heat activated styling with acrylate / C1-2 succinate hydroxyacrylate copolymer

Following this procedure, the bleached hair can be treated with a solution comprising xylose-free 6% (active) acrylate / C1-2 succinate hydroxyacrylate copolymer (composition (a)) or 6% (active) acrylic The treatment was performed eight times with a solution containing the rate / C1-2 succinate hydroxyacrylate copolymer and 1% xylose (composition (b)). The acrylate / C1-2 succinate hydroxyacrylate copolymer is formed from acrylic acid, acrylate, hydroxyacrylate and succinic acid. The polymer was neutralized by 100% neutralization with AMP. The results are shown in Table 7.

TABLE 7

Example 11. Heat Activated Styling with Acrylate Copolymer

Following this procedure, normal brown hair is treated with a solution comprising 6% (active) acrylate copolymer free of xylose (composition (a)) or 6% (active) acrylate copolymer and 1% xylose. The solution (composition (b)) was treated eight times. The acrylate copolymer is a copolymer of two or more monomers selected from acrylic acid, methacrylic acid and simple esters thereof. The polymer was neutralized by 100% neutralization with AMP. The results are shown in Table 8.

TABLE 8

Example 12 Durability Heat Activated with Corn Starch

Following the procedure for durability testing, the bleached hair was treated eight times with a solution containing 6% (active) Corn Starch Modified with or without 1% xylose. At 15 minutes, curl sag was measured at the indicated time. The results are shown in Table 9.

TABLE 9

The data indicate that at least one film forming agent (Corn Starch Modified), at least one sugar (xylose) selected from C ₃ to C ₅ monosaccharides and hair treated with heating, C ₃ to C ₅ monosaccharides ( It has been shown to have a higher curl retention after six shampoos than one or more film forming agents (Corn Starch Modified) and heat treated without one or more sugars selected from cilose).

Example 13

The following procedure was used to treat hair and measure curl sag: hair swatches (2 g., 6.5-7.5 in.) Containing 6% Corn Starch Modified and 1% glucosamine (0.5 g solution / hair g). The solution was treated and then dried with a dryer. The hair swatches were then heated with flat iron for 1 minute and then shampooed with 10% sodium laureth sulfate (SLES) solution. As indicated, the treatment was repeated up to eight times. The treated hair swatches were shampooed 2, 4, and 6 times, then styled with curling iron for 30 seconds and then placed in a humidity chamber at 90% relative humidity to measure curl sag. Since the curls loosened slowly in the humidity chamber, the length of the hair swatches was measured every minute (up to 15 minutes).

Curl sag was calculated as described above.

TABLE 1

The data indicate that one or more film forming agents (Corn Starch Modified), one or more compounds comprising one or more C ₅ to C ₇ saccharide units substituted with one or more amino groups (glucosamine) and the hair treated with heating, It has been shown to have higher curl retention after six shampoos than hair treated with at least one film forming agent (Corn Starch Modified) and no heat, without one or more compounds comprising at least one substituted C ₅ to C ₇ saccharide unit .

Claims (20)

A composition for durable maintenance of durable non-permanent molding or non-permanent shape of keratinous fibers comprising: (a) at least one film former selected from: (Iii) a polymer derived from (1) corn starch, and (2) polyvinylpyrrolidone; And (ii) a nonionic polymer selected from (1) vinyl acetate, and (2) copolymers derived from vinylpyrrolidone; And (Iii) a polymer derived from (1) vinyl acetate, (2) crotonic acid, and (3) vinyl neodecanoate; And (ii) polymers derived from (1) acrylic acid, (2) acrylate, (3) hydroxyacrylate and (4) succinic acid; And (iii) anionic polymers selected from polymers from two or more different monomers each selected from acrylic acid, methacrylic acid, esters of acrylic acid and esters of methacrylic acid; And (b) xylose Wherein the at least one film former and the xylose are each present in the overall composition in an amount effective to impart a durable non-permanent shape to the keratinous fiber or to maintain a durable non-permanent shape of the keratinous fiber. From 0.01 to 30% by weight and from 0.01 to 10% by weight). delete delete delete delete delete delete delete The composition of claim 1 wherein said anionic polymer is neutralized to become soluble. delete delete delete delete 10. The composition of claim 1 or 9, wherein said composition further comprises an additional sugar different from said xylose. 15. The composition of claim 14, wherein said additional sugar is hexose selected from alluls, altrose, glucose, mannose, gulose, idose, galactose, talos, sorbose, psicos, fructose and tagatose. 15. The composition of claim 14, wherein said additional sugar is present in said composition in an amount ranging from 0.01% to 10% by weight relative to the total weight of the composition. 10. The composition of claim 1 or 9, wherein said composition is in the form of a liquid, oil, paste, stick, dispersion, emulsion, lotion, gel or cream. 10. Anionic surfactant, cationic surfactant, nonionic surfactant, amphoteric surfactant, fragrance, permeating agent, antioxidant, sequestering agent, opacifying agent, solubilizer, softener, coloring agent according to claim 1 or 9. And at least one suitable additive selected from polymers such as screening agents, preservatives, proteins, vitamins, silicones, thickening polymers, vegetable oils, mineral oils and synthetic oils. A method for durable non-permanent molding of keratinous fibers or for the durable maintenance of non-permanent shape of keratinous fibers, comprising: (a) one or more film formers; And (b) applying a composition according to claim 1 or 9 comprising xylose to said keratin fibers; Heating the keratinous fibers Wherein the one or more film formers and xylose are present in an amount effective to impart a durable non-permanent shape to the keratinous fiber or to maintain a durable non-permanent shape of the keratinous fiber, and further Wherein the composition is applied before or during the heating). A kit for protecting keratinous fibers from exogenous damage or for recovering keratinous fibers after said exogenous damage, said kit comprising a compartment comprising a composition comprising: (a) at least one film former selected from: (Iii) a polymer derived from (1) corn starch, and (2) polyvinylpyrrolidone; And (ii) a nonionic polymer selected from (1) vinyl acetate, and (2) copolymers derived from vinylpyrrolidone; And (Iii) a polymer derived from (1) vinyl acetate, (2) crotonic acid, and (3) vinyl neodecanoate; And (ii) polymers derived from (1) acrylic acid, (2) acrylate, (3) hydroxyacrylate and (4) succinic acid; And (iii) anionic polymers selected from polymers from two or more different monomers each selected from acrylic acid, methacrylic acid, esters of acrylic acid and esters of methacrylic acid; And (b) xylose; Wherein said xylose is present in an amount effective to impart a durable non-permanent shape to said keratin fibers or to maintain a durable non-permanent shape of said keratin fibers.