KR100902138B1 - Apparatus For Purifying Waste Water Using Ozone - Google Patents

Abstract

The present invention relates to a wastewater purification apparatus using ozone (O ₃ ), and a power supply unit for supplying a voltage; An oxygen generator for generating oxygen (O ₂ ); A water tank for storing and supplying waste water; A high pressure generator for receiving a voltage from the power supply unit to generate a high pressure; A circulating pump for discharging a mixture of ozone (O ₃₎ generated in the ozone generator and the mixture of waste water and ozone (O ₃₎ is supplied from the water tank unit; An injection pump unit configured to receive and discharge a mixture of ozone (O ₃ ) discharged from the circulation pump and water (H ₂ O) purified from wastewater; A dissolved part that receives the mixture discharged from the circulation pump part or the injection pump part and circulates and discharges to increase the dissolved rate of the ozone (O ₃ ) and waste water; And supplying oxygen (O ₂ ) or air generated from the oxygen generator to a discharge space and discharging the high pressure received from the high pressure generator to the discharge space to generate ozone (O ₃ ) and discharged from the dissolved portion. An ozone generator receiving a mixture of ozone (O ₃ ) and wastewater and cooling the high heat generated in the discharge space and then discharging it into the water tank; wherein the mixture of ozone (O ₃ ) and wastewater is the circulation pump unit. The waste water is purified by the ozone (O ₃ ) while circulating the injection pump unit, the dissolved unit, the ozone generator, and the water tank.

Ozone generator, ozone, oxygen, discharge, electrode, cooling, heat sink

Description

Apparatus For Purifying Waste Water Using Ozone

The present invention is ozone (O ₃₎ to the waste water purification relates to an apparatus, in particular, sewage or waste water purification device using ozone (O ₃₎ with various kinds of waste water can be purified process using ozone (O ₃₎ of the sewage, such as using It is about.

Today, due to the rapid development of the industrial society and the improvement of living standards, the use of water has increased, and a large amount of waste water is generated.In recent years, poorly disinfected waste water is introduced into rivers and groundwater, and viruses are detected in tap water and drinking contaminated ground water. Disinfection and purification of wastewater has become a social problem, such as a person suffering from water-borne infections.

Currently used water treatment technologies include biological treatment techniques using microorganisms and physicochemical treatment techniques such as filtration, flocculation, sedimentation or adsorption, but biological treatment techniques are expensive to construct and difficult to remove hardly degradable contaminants. Physicochemical treatment technology not only requires a lot of operating costs but also has a disadvantage of causing a large amount of sludge.

On the other hand, chlorine disinfection, which has been widely used in water treatment plants, generates THM (Trihalomethanes) substances harmful to the human body in the treated water and has a disadvantage in that it cannot remove chlorine-based organic compounds emitted from various industries. Therefore, in order to remove such hardly decomposable substances, some treatment plants use activated carbon adsorption and ozone oxidation. However, activated carbon adsorption may be contaminated by physical adsorption. ) Produces a compound.

Accordingly, in recent years, ultraviolet disinfection that can sterilize pathogenic bacteria and harmful microorganisms without causing secondary pollution has attracted attention. This ultraviolet disinfection action is to sterilize bacteria or microorganisms that may survive in the effluent by irradiating the microorganisms with ultraviolet rays having a main wavelength of 253.7 nm to destroy the microorganism's DNA or inhibit the proliferative action. However, the ultraviolet disinfection technique has a problem in maintenance because the short distance of ultraviolet rays is required in water, and thus the number of ultraviolet lamps and periodic cleaning of contaminants on the surface of the ultraviolet lamps are required to process an appropriate amount. In addition, UV sterilization may kill pathogenic microorganisms, but there is a limit in that it is not possible to completely decompose organic materials. In order to promote the decomposition of organic materials, photocatalysts reacting with ultraviolet rays are used. However, when sludge or contaminants adhere to the surface of the UV lamp over time, the light transmittance is lowered and the decomposition efficiency is lowered. There is this.

In addition, conventionally, there is a method of purifying sewage and wastewater using an ion generating device as follows.

First, when a high voltage is applied between the positive electrode and the negative electrode, a discharge occurs between the two electrodes to form an electric field. At this time, free electrons that move freely in the negative electrode are released and move to the opposite electrode, and the released free electrons are in a high energy state, thereby activating various gas components of air existing between the two electrodes. or the like is generated and, while the generated electrons collide with molecules of the gas causes the the outermost electrons of the gas molecules changes a highly reactive radical, where electrons and ions ^-, ozone (O _3), oxygen anion (O ₂₎ Produce new chemical reactions.

This property can be used to decompose contaminating components in fluids. In other words, when ionization gas is injected into the wastewater containing pollutants, the active substances such as radicals, excitation electrons and ions react with the pollutants contained in the wastewater to oxidatively decompose and remove the pollutants. It is called).

1 is a block diagram of an ion generating device disclosed in Korean Patent Laid-Open No. 2000-0027032. As shown in FIG. 1, the ion generator disclosed in FIG. 1 is installed in a horizontal direction perpendicular to a vertical direction of a conical negative electrode 20 to which a high voltage current is applied and the conical negative electrode 20. The negative electrode 20 includes a positive electrode 22 on a plate which is provided at a predetermined distance from the top 21 of the negative electrode 20 and has a circular hole centered on a vertical line passing through the top 21. However, in the conventional ion generating device having such a configuration, since the shape of the two electrodes is composed of a large area of flat plate shape, power consumption for discharging is high when a high voltage is applied, and the flat plate shape (-) Compared with the power consumption per unit area applied to the electrode, the amount of generated ions is small, resulting in inefficient problems. In addition, there is a problem that a short occurs at high current and high voltage.

2 is a block diagram illustrating a wastewater purification apparatus using plasma disclosed in Korean Laid-Open Patent No. 2001-47773. As shown in FIG. 2, the wastewater purification apparatus using the disclosed plasma includes a pipe-shaped dielectric 11, an external electrode 13 plated on an outer surface of the dielectric, and a coil spring-shaped internal electrode 14 disposed in the dielectric. And a discharge tube 10 including a power supply device 15 for generating a plasma in the dielectric by applying a high current between the external electrode 13 and the internal electrode 14, but a fine ceramic must be used as the dielectric. Since the ion generation efficiency is not satisfactory and clean compressed air must be used, there is a problem that the overall equipment is required and the cost is excessively required.

The present invention is waste water purification device using ozone (O ₃₎ which as been made to solve the above problems, a first object of the present invention can be by using the ozone (O ₃₎ various kinds of waste water such as sewage or waste water treatment purification To provide.

Further, a second object of the present invention is to provide a waste water purification device using ozone (O _3), which purification can be treated using the ozone (O ₃₎ such as a high concentration of livestock waste water and waste water in sewage.

In addition, a third object of the present invention is to provide a wastewater purification apparatus using ozone (O ₃ ) that can increase the dissolved rate by circulating the waste water in which ozone (O ₃ ) is dissolved.

Further, the fourth object is the life of and to efficiently cool the room, the heat transfer occurring during the discharge to minimize the power consumed to generate ozone (O _3), and maximize the efficiency of generation of ozone (O ₃₎ ozone generating apparatus of the present invention The present invention provides a wastewater purification apparatus using ozone (O ₃ ) which can be used semi-permanently by maximizing.

Waste water purification apparatus using ozone (O ₃ ) according to the present invention for achieving the above object, the power supply unit for supplying a voltage; An oxygen generator for generating oxygen (O ₂ ); A water tank for storing and supplying waste water; A high pressure generator for receiving a voltage from the power supply unit to generate a high pressure; A circulating pump for discharging a mixture of ozone (O ₃₎ generated in the ozone generator and the mixture of waste water and ozone (O ₃₎ is supplied from the water tank unit; An injection pump unit configured to receive and discharge a mixture of ozone (O ₃ ) discharged from the circulation pump and water (H ₂ O) purified from wastewater; A dissolved part that receives the mixture discharged from the circulation pump part or the injection pump part and circulates and discharges to increase the dissolved rate of the ozone (O ₃ ) and waste water; And supplying oxygen (O ₂ ) or air generated from the oxygen generator to a discharge space and discharging the high pressure received from the high pressure generator to the discharge space to generate ozone (O ₃ ) and discharged from the dissolved portion. An ozone generator receiving a mixture of ozone (O ₃ ) and wastewater and cooling the high heat generated in the discharge space and then discharging it into the water tank; wherein the mixture of ozone (O ₃ ) and wastewater is the circulation pump unit. The waste water is purified by the ozone (O ₃ ) while circulating the injection pump unit, the dissolved unit, the ozone generator, and the water tank.

In addition, the wastewater purification apparatus using ozone (O ₃ ) according to the present invention for achieving the above object, the power supply unit for supplying a voltage; An oxygen generator for generating oxygen (O ₂ ); A water tank for storing and supplying waste water; A high pressure generator for receiving a voltage from the power supply unit to generate a high pressure; A circulation pump unit which mixes and discharges the wastewater supplied from the water tank and ozone (O ₃ ) generated from an ozone generator; Supplying oxygen (O ₂ ) or air generated from the oxygen generating unit to the discharge space and discharges the high pressure received from the high pressure generator in the discharge space to generate ozone (O ₃ ) and is discharged from the circulation pump unit ozone (O ₃₎ and then a mixture of the waste water when supplied with cooling a high heat is generated in the discharge space by using the ozone (O ₃₎ and at the same time purifying the wastewater and the ozone generator to discharge into the water tank; An injection pump unit configured to receive and spray a mixture of ozone (O ₃ ) discharged from the ozone generator and water (H ₂ O) for purifying wastewater; And a dissolved part that receives the mixture discharged from the ozone generator or the injection pump part and circulates to discharge the ozone (O ₃ ) and waste water to be discharged to the water tank. The ozone (O ₃ ) The wastewater mixture is characterized in that the wastewater is purified by the ozone (O ₃ ) while circulating the circulation pump portion, the ozone generator, the injection pump portion, the dissolved portion and the water tank.

Here, the ozone generator comprises: a first electrode tube (110) forming a first electrode and flowing waste water or cooling material into an internal space; A dielectric tube 120 spaced apart from the first electrode tube 110 at a predetermined interval to form a discharge space and inducing ozone generation in the discharge space; A heat sink 130 disposed outside the dielectric tube 120 and integrally forming a second electrode tube 131 forming a second electrode and dissipating heat generated in the discharge space; It is fastened to one side of the second electrode tube 131 to fix one side of the first electrode tube 110 and the dielectric tube 120, the oxygen (O ₂ ) or air flows into the discharge space A first stopper 140a of non-conductive material having an airflow inlet 142a and a wastewater inlet 141a for introducing wastewater or cooling material into the inner space of the first electrode tube 110; And fastened to the other side of the second electrode tube 131 to fix the first electrode tube 110 and the other side of the dielectric tube 120 to fix ozone (O ₃ ) or air from the discharge space. And a second stopper 140b of non-conductive material having an airflow outlet 142b for discharging and a wastewater outlet 141b for discharging wastewater or cooling material from the internal space of the first electrode tube 110. It features.

The dielectric tube is characterized in that one of the quartz tube, glass tube, ceramic tube.

The first and second stoppers are characterized in that consisting of a Teflon material or a polymer material.

The first and second plugs have the wastewater inlet or the wastewater outlet formed on one side, and a fixing groove and a female screw portion for fixing the first electrode tube and the dielectric tube, respectively, are formed inside the other side. The air flow inlet or the air flow outlet is characterized in that formed on one side of the outer peripheral surface.

The first and second stoppers are characterized in that the use of the O-ring or packing to maintain the airtight when fixing the first electrode tube and the dielectric tube, respectively.

The heat sink is characterized in that a plurality of cooling fans are integrally formed on the outer circumferential surface of the second electrode tube to dissipate heat generated in the discharge space.

The first electrode tube, the heat sink and the second electrode tube may be any one of gold, silver, copper, aluminum, tin, and zinc or at least two alloys.

According to the wastewater purification apparatus using ozone (O ₃ ) according to the present invention, it is possible to purify not only various wastewater such as sewage and sewage but also high concentration livestock wastewater and phosphorus manure wastewater using ozone (O ₃ ). There is.

In addition, ozone (O ₃ ) can increase the dissolution rate by circulating the dissolved waste water, and the process of generating a silent discharge between the first electrode and the second electrode to purify the waste water by generating ozone in the silent discharge method High heat generated during use can be significantly reduced by using cooling water or refrigerant.

Hereinafter, the wastewater purification apparatus according to the present invention will be described in detail with reference to the accompanying drawings.

First embodiment

3 is a block diagram of a wastewater purification apparatus according to a first embodiment of the present invention.

In the wastewater purification apparatus according to the first embodiment of the present invention, as shown in FIG. 3, the ozone generator 100, the water tank 200, the circulation pump unit 300, the injection pump unit 400, and the dissolved unit ( 500, a power supply unit 600, a high pressure generator 610, an oxygen generator 700, and the like.

The ozone generator 100 supplies oxygen (O ₂ ) or air generated from the oxygen generator 700 to a discharge space and discharges the high pressure received from the high pressure generator 610 to the discharge space to generate ozone ( O ₃ ) and receiving a mixture of ozone (O ₃ ) and wastewater discharged from the circulation pump unit 300 or the injection pump unit 400 to purify the wastewater using the ozone (O ₃ ) and At the same time, the high heat generated in the discharge space is cooled and then discharged into the water tank 200.

The water tank 200 stores the fresh water mixture of ozone (O ₃ ) and wastewater discharged through the discharge space of the ozone generator 100. In addition, the water tank 200 stores fresh water by introducing wastewater to be purged from the outside.

The circulation pump unit 300 receives wastewater from the water tank 200, receives ozone (O ₃ ) from the ozone generator 100, mixes it, and discharges the mixed water. In this case, the wastewater discharged from the water tank 200 may include ozone (O ₃ ) due to the mixture discharged from the ozone generator 100.

The injection pump 400 receives a mixture of ozone (O ₃ ) and wastewater discharged from the circulation pump unit 300 or a mixture of ozone (O ₃ ) and water (H ₂ O) purified from wastewater. Spray and discharge.

The power supply unit 600 supplies a voltage to the high pressure generator 610, and the high pressure generator 610 boosts the voltage received from the power supply unit 600 to generate a high pressure to the ozone generator 100. .

The oxygen generator 700 generates (or supplies) oxygen (O ₂ ) to the ozone generator 100.

On the other hand, the dissolved part 500 is supplied with a mixture of ozone (O ₃ ) and waste water discharged from the circulation pump 300 and / or the injection pump 400 400 of the ozone (O ₃ ) and waste water It is circulated to increase the dissolution rate and discharged to the ozone generator 100. The dissolved part 500 having such a function is connected between the output end of the circulation pump 300 and / or the injection pump 400 and the ozone generator 100. However, the dissolved part 500 may not be configured as necessary.

In the wastewater purification apparatus having the above configuration, first, oxygen (O ₂ ) or air is supplied from the oxygen generator 700 to the ozone generator 100, and the ozone generator 100 is supplied from the high pressure generator 610. Supply the high pressure.

Next, the ozone generator 100 supplies oxygen (O ₂ ) or air generated from the oxygen generator 700 to the discharge space and discharges the high pressure received from the high pressure generator 610 to the discharge space. To generate ozone (O ₃ ). At this time, the ozone generator 100 receives a mixture of ozone (O ₃ ) and wastewater discharged from the circulation pump unit 300 or the injection pump unit 400 to receive wastewater using the ozone (O ₃ ). While purifying, the high heat generated in the discharge space is cooled and then discharged into the water tank 200.

Next, the circulation pump unit 300 receives the wastewater from the water tank 200 and the ozone (O ₃ ) from the ozone generator 100, mixes them, and discharges them, and discharges the injection pump unit 400. Is supplied with a mixture of ozone (O ₃ ) and waste water discharged from the circulation pump unit 300 is injected and discharged.

Next, the dissolved part 500 receives a mixture of ozone (O ₃ ) and wastewater discharged from the circulation pump part 300 and / or the injection pump part 400, and receives the ozone (O ₃ ) and wastewater. In order to increase the dissolved rate of the circulating inside and discharged to the ozone generator (100).

The mixture of ozone (O ₃ ) and wastewater discharged to the ozone generator 100 through the dissolved part 500 is oxidized and decomposed by reacting the ozone (O ₃ ) with contaminants contained in the wastewater to remove contaminants. As a result, the wastewater is purified and then discharged back to the water tank 200. At this time, the high heat generated in the discharge space of the ozone generator 100 is cooled by the wastewater passing through the ozone generator 100, the configuration and principle of the ozone generator (shown in Figures 5 and 6) 100 will be explained in more detail.

On the other hand, in the wastewater purification apparatus according to the present invention, when the ozone (O ₃ ) is injected into the wastewater containing contaminants, radicals, excitation electrons and ions react with the contaminants contained in the wastewater. By oxidative decomposition, contaminants are removed.

Second embodiment

4 is a block diagram of a wastewater purification apparatus according to a second preferred embodiment of the present invention.

Wastewater purification apparatus according to a second embodiment of the present invention, as shown in Figure 4, ozone generator 1100, water tank 1200, circulation pump unit 1300, injection pump unit 1400, dissolved part ( 1500, a power supply unit 1600, a high pressure generator 1610, an oxygen generator 1700, and the like.

The ozone generator 1100 supplies oxygen (O ₂ ) or air generated from the oxygen generator 1700 to a discharge space, and discharges the high pressure received from the high pressure generator 1610 to the discharge space to generate ozone ( O ₃ ) and receiving a mixture of ozone (O ₃ ) and wastewater discharged from the circulation pump unit 1300 to purify the wastewater using the ozone (O ₃ ) and at the same time high heat generated in the discharge space After cooling to discharge to the tank (1200).

In this case, the power supply unit 1600 supplies a voltage to the high pressure generator 1610, and the high pressure generator 1610 boosts the voltage received from the power supply unit 1600 to increase the high pressure to the ozone generator 1100. Generate. The oxygen generator 1700 generates (or supplies) oxygen (O ₂ ) to the ozone generator 1100.

The injection pump unit 1400 receives and discharges a mixture of ozone (O ₃ ) discharged from the ozone generator and water (H ₂ O) purified from wastewater.

The water tank 1200 receives and stores a mixture of ozone (O ₃ ) and wastewater discharged through the discharge space of the ozone generator 100, and supplies the mixture stored to the circulation pump unit 1300.

The circulation pump unit 1300 is the ozone generator and mixed them when supplied with ozone (O ₃₎ from the ozone (O ₃₎ as a mixture with the ozone generator (100) of the waste water supplied from the water tank (1200) ( 1100).

On the other hand, the dissolved part 1500 is supplied with a mixture of ozone (O ₃ ) and waste water discharged from the ozone generator 1100 and / or the injection pump unit 1400 dissolved in the ozone (O ₃ ) and waste water In order to increase the rate is circulated to discharge to the tank (1200). The dissolved part 1500 having such a function is configured to be connected between the output terminal of the ozone generator 1100 and / or the injection pump part 1400 and the water tank 1200. However, the dissolved part 1500 may not be configured as necessary.

In the wastewater purification apparatus having the above configuration, first, oxygen (O ₂ ) or air is supplied from the oxygen generator 1700 to the ozone generator 1100, and the ozone generator 1100 is supplied from the high pressure generator 1610. Supply the high pressure.

Next, the ozone generator 1100 supplies oxygen (O ₂ ) or air generated from the oxygen generator 1700 to the discharge space and discharges the high pressure received from the high pressure generator 1610 to the discharge space. To generate ozone (O ₃ ). At this time, the ozone generator 1100 receives a mixture of ozone (O ₃ ) and cooling water (H ₂ O) discharged from the circulation pump unit 1300 to purify the waste water by using the ozone (O ₃ ) and At the same time, the high heat generated in the discharge space is cooled and then discharged into the water tank 1200.

Next, the injection pump unit 1400 receives a mixture of ozone (O ₃ ) discharged from the ozone generator 1100 and water (H ₂ O) purified from wastewater, and sprays the same.

Subsequently, the dissolved part 1500 receives a mixture of ozone (O ₃ ) and wastewater discharged from the ozone generator 1100 and / or the injection pump unit 1400 and receives the mixture of the ozone (O ₃ ) and the wastewater. In order to increase the dissolution rate it is circulated inside and discharged to the tank (1200).

Next, the water tank 1200 receives and stores a mixture of ozone (O ₃ ) and wastewater from the dissolved portion 1500, and stores the mixture of stored ozone (O ₃ ) and wastewater into the circulation pump unit 1300. Discharge.

Then, the circulation pump unit 1300, the ozone (O ₃₎ and being fed with a mixture of waste water ozone from the ozone generator (1100) (O ₃₎ to supply receives the ozone after mixing them from the tank (1200) It is discharged to the generator 1100. At this time, the mixture (H ₂ O + O ₃ ) supplied to the ozone generator 1100 is purifying the waste water using the ozone (O ₃ ) generated in the discharge space of the ozone generator 100 and at the same time the discharge After cooling the high heat generated in the space is discharged to the tank (1200).

The wastewater purification method in the wastewater purification apparatus according to the present invention is similar to the above, when the ozone (O ₃ ) is injected into the wastewater containing pollutants, the pollutants in which active substances such as radicals, excitation electrons and ions are contained in the wastewater. By reacting with oxidative decomposition, contaminants are removed.

Ozone generator

5 and 6 are exploded perspective and sectional views of the ozone generator used in the present invention.

As shown in FIGS. 5 and 6, the ozone generator 100 or 1100 includes a first electrode tube 110, a dielectric tube 120, a heat sink 130, a first and second teflon plugs 140a, 140b) and the like.

Here, the first electrode tube 110 is composed of a metal pipe forming the first electrode, the cooling material (cooling water or refrigerant) flows into the inner space of the pipe.

The dielectric tube 120 is composed of a pipe made of one of glass and ceramic materials, including quartz, glass, and ceramics, to induce ozone generation in the discharge space, and the first electrode tube 110 and predetermined The discharge spaces are formed at intervals of.

The heat sink 130 is located outside the dielectric tube 120 and has a plurality of cooling fans 132 formed on an outer circumferential surface of the second electrode tube 131 and the second electrode tube 131 forming a second electrode. ) Is integrally formed and serves to dissipate heat generated in the discharge space.

The first plug 140a is fastened to one side of the second electrode tube 131 to fix the first electrode tube 110 and one side of the dielectric tube 120 to fix the oxygen to the discharge space. (O ₂ ) or a non-conductive material having an airflow inlet 142a for introducing air and a wastewater inlet 141a for introducing wastewater (or cooling material) into the inner space of the first electrode tube 110. In addition, a fixing groove and a female screw portion 143a for fixing the first electrode tube 110 and the dielectric tube 120 are formed inside the other side.

The second stopper 140b is fastened to the other side of the second electrode tube 131 to fix the other side of the first electrode tube 110 and the dielectric tube 120 to fix ozone from the discharge space. (O ₃ ) or a non-conductive material having an airflow outlet 142b for discharging air and a wastewater outlet 141b for discharging wastewater (or cooling material) from an internal space of the first electrode tube 110. In addition, a fixing groove and a female screw portion 143b for fixing the first electrode tube 110 and the dielectric tube 120 are formed inside the other side.

The first and second stoppers 140a and 140b are fixed by using O-rings 151 and 152 to maintain airtightness when fixing the first electrode tube 110 and the dielectric tube 120. .

Here, the first and second plugs 140a and 140b may be formed using packing instead of the O-rings 151 and 152 to maintain airtightness.

The first and second stoppers 140a and 140b may be made of a Teflon material or a polymer material.

The first electrode tube 110, the heat sink 130, and the second electrode tube 131 may be formed of any one of gold, silver, copper, aluminum, tin, zinc, or at least two alloys. .

Here, the dielectric tube 120 may be formed by coating and coating with powder using an ozone gas generating derivative of a glass material and a ceramic material along the inner diameter of the heat sink 130.

In addition, the heat sink 130 may further install a cooling fan (not shown) outside the heat sink 130 to heat the heat transferred to the cooling fan 132 through the second electrode tube 131. It can also be configured to force cooling.

In the ozone generator 100 according to the present invention having the above configuration, the first electrode tube after injecting oxygen (O ₂ ) or air into the discharge space through the air flow inlet 142a of the first stopper 140a. When the first electrode is applied to the first electrode 110 and the second electrode is applied to the second electrode tube 131 of the heat sink 130, the dielectric electrode 120 induces a discharge in the discharge space. As the silent discharge occurs, ozone (O ₃ ) is generated.

For example, when the oxygen supply method is air, the practical ozone concentration range is 13-15 g / m 3, and the power consumption is about 15-18 kW / kg-O ₃ . When the oxygen supply method is pure oxygen (O ₂ ), the practical ozone concentration range is 100-200 g / m 3, and the power consumption is about 7-13 kW / kg-O ₃ .

The principle of generating ozone (O ₃ ) by the silent discharge is represented by the following reaction schemes 1 and 2.

^{_{O 2 + e - ⇒ O +}} O + e -

O + O ₂ + M ⇒ O ₃ + M

That is, the oxygen atoms collided and dissociated by the electrons accelerated by the reaction accelerated by the reaction as shown in Scheme 1 and then react with the oxygen atoms, so that the reaction that dissociates like the reverse reaction of Scheme 2 due to the thermal decomposition of ozone (O ₃ ). do. Therefore, for efficient ozone (O ₃ ) generation, the thermal decomposition of generated ozone (O ₃ ) should be minimized.

In the present invention, in order to efficiently cool the high heat generated during the silent discharge in the discharge space, waste water (refrigerant) is injected into the pipe of the first electrode tube 110 to flow. In this case, since the high heat generated in the discharge space is mostly transmitted through the first electrode tube 110 made of a conductor having a higher thermal conductivity than the dielectric tube 120 installed on the heat sink 130 having the second electrode. Wastewater (refrigerant) flowing inside the first electrode tube 110 may rapidly cool the high heat generated in the discharge space.

Therefore, in the wastewater purification apparatus using ozone (O ₃ ) of the present invention, the high heat generated in the discharge space can be quickly cooled by using a refrigerant (wastewater), and thus the ozone generation efficiency can be further improved.

In addition, the wastewater purification apparatus using ozone (O ₃ ) according to the present invention is used to purify not only various wastewaters such as sewage and sewage but also high concentration livestock wastewater and phosphorus manure wastewater, sludge containing sewage, industrial factory wastewater and the like. Can be used.

Next, Table 1 shows the results of purifying livestock wastewater and phosphorus manure using a wastewater purification apparatus using ozone (O ₃ ) according to the present invention.

The present invention is not limited to the above-described embodiments, but can be variously modified and changed by those skilled in the art, which should be considered as being included in the spirit and scope of the present invention as defined in the appended claims. will be.

1 is a block diagram showing an ion generating device disclosed in Korean Patent Publication No. 2000-0027032

2 is a block diagram illustrating a wastewater purification apparatus using plasma disclosed in Korean Patent Laid-Open No. 2001-47773.

3 is a block diagram of a wastewater purification apparatus according to a first embodiment of the present invention

4 is a block diagram of a wastewater purification apparatus according to a second preferred embodiment of the present invention

5 and 6 are exploded perspective and sectional views of the ozone generator used in the present invention.

[Description of Major Symbols in Drawings]

100, 1100: ozone generator 110: first electrode tube

111a, 111b: fitting portion 120: dielectric tube

130: heat sink 131: second electrode tube

132: cooling fan

140a, 140b: first and second stopper

141a: wastewater inlet 142a: airflow inlet

143a: thread 141b: wastewater outlet

142b: Air flow outlet 143b: Female thread

151, 152: O-ring 200, 1200: Tank

300, 1300: circulation pump

400, 1400: injection pump unit

500, 1500: dissolved part 600, 1600: power part

610, 1610: high pressure generator

700, 1700: oxygen generator

Claims (9)

In the wastewater purification device using ozone (O ₃ ), A power supply unit supplying a voltage; An oxygen generator for generating oxygen (O ₂ ); A water tank for storing and supplying waste water; A high pressure generator for receiving a voltage from the power supply unit to generate a high pressure; A circulating pump for discharging a mixture of ozone (O ₃₎ generated in the ozone generator and the mixture of waste water and ozone (O ₃₎ is supplied from the water tank unit; An injection pump unit configured to receive and discharge a mixture of ozone (O ₃ ) discharged from the circulation pump and water (H ₂ O) purified from wastewater; A dissolved part that receives the mixture discharged from the circulation pump part or the injection pump part and circulates and discharges to increase the dissolved rate of the ozone (O ₃ ) and waste water; And Supply oxygen (O ₂ ) or air generated from the oxygen generator to the discharge space and discharge the high pressure received from the high pressure generator to the discharge space to generate ozone (O ₃ ) and discharged from the dissolved portion Including an (O ₃ ) and the ozone generator for supplying a mixture of waste water and cooling the high heat generated in the discharge space and discharged to the water tank; The ozone generator, A first electrode tube (110) forming a first electrode and flowing wastewater or cooling material into the internal space; A dielectric tube 120 spaced apart from the first electrode tube 110 at a predetermined interval to form a discharge space and inducing ozone generation in the discharge space; A heat sink 130 disposed outside the dielectric tube 120 and integrally forming a second electrode tube 131 forming a second electrode and dissipating heat generated in the discharge space; It is fastened to one side of the second electrode tube 131 to fix one side of the first electrode tube 110 and the dielectric tube 120, the oxygen (O ₂ ) or air flows into the discharge space A first stopper 140a of non-conductive material having an airflow inlet 142a and a wastewater inlet 141a for introducing wastewater or cooling material into the inner space of the first electrode tube 110; And It is fastened to the other side of the second electrode tube 131 to fix the other side of the first electrode tube 110 and the dielectric tube 120, and discharge ozone (O ₃ ) or air from the discharge space By including a second stopper (140b) of the non-conductive material in which the air flow outlet (142b) and the wastewater discharge port (141b) for discharging wastewater or cooling material from the inner space of the first electrode tube (110); The ozone (O ₃₎ and while the mixture of the waste water circulating the circulating pump unit, wherein the injection pump unit, the dissolved portion, the ozone generator and the water tank by the ozone (O ₃₎ characterized in that the purification process the waste water Wastewater Purification System Using Ozone . In the wastewater purification device using ozone (O ₃ ), A power supply unit supplying a voltage; An oxygen generator for generating oxygen (O ₂ ); A water tank for storing and supplying waste water; A high pressure generator for receiving a voltage from the power supply unit to generate a high pressure; A circulation pump unit which mixes and discharges the wastewater supplied from the water tank and ozone (O ₃ ) generated from an ozone generator; Supplying oxygen (O ₂ ) or air generated from the oxygen generating unit to the discharge space and discharges the high pressure received from the high pressure generator in the discharge space to generate ozone (O ₃ ) and is discharged from the circulation pump unit ozone (O ₃₎ and then a mixture of the waste water when supplied with cooling a high heat is generated in the discharge space by using the ozone (O ₃₎ and at the same time purifying the wastewater and the ozone generator to discharge into the water tank; An injection pump unit configured to receive and spray a mixture of ozone (O ₃ ) discharged from the ozone generator and water (H ₂ O) for purifying wastewater; And When supplied by the mixture discharged from the ozone generator or the injection pump circulation to increase the ratio of the dissolved ozone (O ₃₎ and the dissolved waste discharged from the water tank unit; including, but, The ozone generator, A first electrode tube (110) forming a first electrode and flowing wastewater or cooling material into the internal space; A dielectric tube 120 spaced apart from the first electrode tube 110 at a predetermined interval to form a discharge space and inducing ozone generation in the discharge space; A heat sink 130 disposed outside the dielectric tube 120 and integrally forming a second electrode tube 131 forming a second electrode and dissipating heat generated in the discharge space; It is fastened to one side of the second electrode tube 131 to fix one side of the first electrode tube 110 and the dielectric tube 120, the oxygen (O ₂ ) or air flows into the discharge space A first stopper 140a of non-conductive material having an airflow inlet 142a and a wastewater inlet 141a for introducing wastewater or cooling material into the inner space of the first electrode tube 110; And It is fastened to the other side of the second electrode tube 131 to fix the other side of the first electrode tube 110 and the dielectric tube 120, and discharge ozone (O ₃ ) or air from the discharge space By including a second stopper (140b) of the non-conductive material in which the air flow outlet (142b) and the wastewater discharge port (141b) for discharging wastewater or cooling material from the inner space of the first electrode tube (110); The ozone (O ₃₎ and while the mixture of the waste water circulating the circulating pump unit, wherein the ozone generator, the injection pump unit, the dissolved portion and the water tank by the ozone (O ₃₎ characterized in that the purification process the waste water Wastewater purification device using ozone. delete The method according to claim 1 or 2 , The dielectric tube is a waste water purification apparatus using ozone, characterized in that the quartz tube, glass tube, ceramic tube . The method of claim 1 or 2 , wherein the first and second stoppers are: Wastewater purification apparatus using ozone, characterized in that consisting of Teflon material or polymer material . The method of claim 1 or 2 , wherein the first and second stoppers are: The waste water inlet or the waste water outlet is formed on one side, A fixing groove and a female screw portion for fixing the first electrode tube and the dielectric tube, respectively, are formed inside the other side, The wastewater purification apparatus using ozone, wherein the airflow inlet or the airflow outlet is formed on one of the outer circumferential surfaces . The method of claim 6, wherein the first and second stoppers are: When the first electrode tube and the dielectric tube is fixed to each other O-ring or packing to maintain the airtight waste water purification apparatus using ozone. The heat sink of claim 1 or 2 , wherein the heat sink is: And a plurality of cooling fans are integrally formed on an outer circumferential surface of the second electrode tube to dissipate heat generated in the discharge space . The method according to claim 1 or 2 , The first electrode tube, the heat sink and the second electrode tube are: Gold, silver, copper, aluminum, tin, zinc is any one or at least two or more alloys, wastewater purification apparatus using ozone.

Images