KR100893234B1 - 고탄성율, 고연성 폴리올레핀 - Google Patents

고탄성율, 고연성 폴리올레핀 Download PDF

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KR100893234B1
KR100893234B1 KR1020047005335A KR20047005335A KR100893234B1 KR 100893234 B1 KR100893234 B1 KR 100893234B1 KR 1020047005335 A KR1020047005335 A KR 1020047005335A KR 20047005335 A KR20047005335 A KR 20047005335A KR 100893234 B1 KR100893234 B1 KR 100893234B1
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polymer
reactor
stage
propylene
astm
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KR1020047005335A
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Korean (ko)
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KR20050034608A (ko
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빌 알. 보디포드
릭신 썬
제럴드 커밍즈
피에르 도날드손
조지 알렌
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헌츠만 폴리머스 코포레이션
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1020047005335A 2001-10-12 2002-10-09 고탄성율, 고연성 폴리올레핀 KR100893234B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US32914101P 2001-10-12 2001-10-12
US60/329,141 2001-10-12
US33013201P 2001-10-17 2001-10-17
US60/330,132 2001-10-17

Publications (2)

Publication Number Publication Date
KR20050034608A KR20050034608A (ko) 2005-04-14
KR100893234B1 true KR100893234B1 (ko) 2009-04-10

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Country Link
US (1) US7348381B2 (de)
EP (1) EP1458810A4 (de)
JP (1) JP2005505655A (de)
KR (1) KR100893234B1 (de)
CN (1) CN1276020C (de)
CA (1) CA2463561C (de)
MX (1) MXPA04003384A (de)
WO (1) WO2003031513A1 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7226977B2 (en) 2004-04-19 2007-06-05 Sunoco, Inc. ( R&M) High melt flow rate thermoplastic polyolefins produced in-reactor
US8026311B2 (en) * 2005-03-25 2011-09-27 Braskem America, Inc. Process for production of propylene copolymers
US20070099883A1 (en) * 2005-10-07 2007-05-03 Cheryl Lynn Calis Anhydrous mometasone furoate formulation
DE602007004745D1 (de) * 2007-12-18 2010-03-25 Borealis Tech Oy Heterophasisches Polypropylen mit hoher Schlagfestigkeit
US8664129B2 (en) * 2008-11-14 2014-03-04 Exxonmobil Chemical Patents Inc. Extensible nonwoven facing layer for elastic multilayer fabrics
US20100266824A1 (en) * 2009-04-21 2010-10-21 Alistair Duncan Westwood Elastic Meltblown Laminate Constructions and Methods for Making Same
US9498932B2 (en) * 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same
US10161063B2 (en) 2008-09-30 2018-12-25 Exxonmobil Chemical Patents Inc. Polyolefin-based elastic meltblown fabrics
US9168718B2 (en) * 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
US20100266818A1 (en) * 2009-04-21 2010-10-21 Alistair Duncan Westwood Multilayer Composites And Apparatuses And Methods For Their Making
CN102395464A (zh) 2009-02-27 2012-03-28 埃克森美孚化学专利公司 具有非弹性区的双轴弹性非织造层压体
US8217116B2 (en) * 2009-07-15 2012-07-10 Braskem America, Inc. Polypropylene composition for buried structures
US8668975B2 (en) * 2009-11-24 2014-03-11 Exxonmobil Chemical Patents Inc. Fabric with discrete elastic and plastic regions and method for making same
US8044135B2 (en) * 2010-02-24 2011-10-25 Braskem America, Inc. Polypropylene impact copolymer compositions
WO2012064468A2 (en) * 2010-11-09 2012-05-18 Exxonmobil Chemical Patents Inc. Meltblown nonwoven compositions and methods for making them
KR101309354B1 (ko) * 2011-06-28 2013-09-17 롯데케미칼 주식회사 직조 성형백에 적합한 미끄러짐성이 작은 압출 라미네이션용 폴리프로필렌계 수지 조성물 및 이를 이용하여 제조되는 직조 성형백
US10465025B2 (en) 2014-01-15 2019-11-05 Exxonmobil Chemical Patents Inc. Low comonomer propylene-based impact copolymers
CN105899599B (zh) 2014-01-15 2018-10-02 埃克森美孚化学专利公司 基于丙烯的抗冲共聚物
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US9593179B2 (en) 2014-02-07 2017-03-14 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
WO2015123334A1 (en) * 2014-02-11 2015-08-20 Flint Hills Resources, Lp Blended compositions, methods for making same, and articles made therefrom
CN104844939B (zh) * 2015-06-05 2017-07-07 苏州艾兴无纺布制品有限公司 非粘性高摩擦系数高分子材料、无纺布复合材料及其应用
KR102342077B1 (ko) * 2019-12-24 2021-12-21 한화토탈 주식회사 에틸렌 중합용 촉매의 제조 방법
CN114058112B (zh) * 2020-08-06 2023-08-22 中国石油天然气股份有限公司 一种低熔指无规共聚聚丙烯树脂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4316966A (en) 1979-10-16 1982-02-23 Mitsui Petrochemical Industries Ltd. Process for producing chemically blended propylene resin composition
US6201069B1 (en) 1997-08-29 2001-03-13 Chisso Corporation Polypropylene/propylene-ethylene copolymer composition and process for the preparation thereof
US6284833B1 (en) 1997-09-18 2001-09-04 Bp Corporation North America Inc. Olefin polymers with improved paintability
US6300415B1 (en) 1995-11-24 2001-10-09 Chisso Corporation Propylene composition, process for preparing the same, polypropylene composition, and molded articles

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2207145B1 (de) 1972-11-17 1975-09-12 Naphtachimie Sa
FR2312512A1 (fr) 1975-05-27 1976-12-24 Naphtachimie Sa Procede de polymerisation des olefines en lit fluidise
US4359561A (en) 1979-06-18 1982-11-16 Union Carbide Corporation High tear strength polymers
IT1227258B (it) 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
US5286791A (en) 1992-05-29 1994-02-15 Himont Incorporated Impact modified graft copolymer compositions containing broad molecular weight distribution polypropylene
CA2121721C (en) 1993-04-29 2004-11-23 Giampiero Morini Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution
WO1998004600A1 (fr) * 1996-07-31 1998-02-05 Japan Polyolefins Co., Ltd. Polypropylene a forte cristallinite
US6100351A (en) 1997-01-07 2000-08-08 Huntsman Polymers Corporation Olefin polymerization process and products thereof
WO1998031744A1 (en) * 1997-01-21 1998-07-23 Exxon Chemical Patents Inc. Impact polypropylene composition having high impact resistance and stiffness
DE69907785T2 (de) 1998-03-09 2004-02-12 Basell Poliolefine Italia S.P.A. Mehrstufiges Verfahren zur Olefinpolymerisation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4316966A (en) 1979-10-16 1982-02-23 Mitsui Petrochemical Industries Ltd. Process for producing chemically blended propylene resin composition
US6300415B1 (en) 1995-11-24 2001-10-09 Chisso Corporation Propylene composition, process for preparing the same, polypropylene composition, and molded articles
US6201069B1 (en) 1997-08-29 2001-03-13 Chisso Corporation Polypropylene/propylene-ethylene copolymer composition and process for the preparation thereof
US6284833B1 (en) 1997-09-18 2001-09-04 Bp Corporation North America Inc. Olefin polymers with improved paintability

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Publication number Publication date
US7348381B2 (en) 2008-03-25
WO2003031513A1 (en) 2003-04-17
EP1458810A1 (de) 2004-09-22
CA2463561A1 (en) 2003-04-17
CN1276020C (zh) 2006-09-20
JP2005505655A (ja) 2005-02-24
US20050027080A1 (en) 2005-02-03
EP1458810A4 (de) 2005-02-09
CN1610722A (zh) 2005-04-27
CA2463561C (en) 2011-05-24
MXPA04003384A (es) 2004-07-30
KR20050034608A (ko) 2005-04-14

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