KR100889915B1 - Auto controlling apparatus of clean in place and its method by using membrane fouling rate - Google Patents

Abstract

The present invention is to monitor and set the optimum chemical cleaning cycle in the entire membrane filtration process for water treatment, and to automatically control the operation mode according to the set optimal chemical cleaning cycle, the present invention for this, pressurized membrane filtration Measure the TMP while monitoring the unit in real time, calculate the total filtration resistance (Rt) by detecting the measured TMP, the temperature correction coefficient (viscosity coefficient) (μ) and the flux (permeate flow rate / unit membrane area) (J). After monitoring the total filtration resistance (Rt), the difference of the total filtration resistance (Rt) per unit time on the preset PLC program (ΔR) (Rt2-Rt1) and the time interval per unit time (ΔT) (t2-t1), Calculate the constant value (γ) that can be automatically controlled by detecting the constant (α) of the influent source concentration, and determine the range of the calculated constant value (γ) that can be derived from the chemical cleaning cycle to set the operation mode. And the membrane filtration process Automatic control. Therefore, it is possible to solve the problem of not satisfying the 'performance indicator', 'economic indicator' and 'stability indicator' as in the past, and also to determine the appropriate irreversible degree of membrane contamination, and thus less irreversible membrane contamination will proceed. When the chemical cleaning is automatically performed, the membrane recovery rate can be restored more easily and quickly so that the operation performance can be stably improved, and the type and amount of cleaning chemicals can be saved, and the cleaning time can be saved. It can reduce the maintenance cost and save the maintenance cost and installation control cost.

Total filtration resistance, chemical cleaning cycle, pressurized membrane filtration, transmembrane pressure (TMP), membrane fouling rate

Description

Automatic control device for chemical cleaning using membrane fouling speed and its method {AUTO CONTROLLING APPARATUS OF CLEAN IN PLACE AND ITS METHOD BY USING MEMBRANE FOULING RATE}

1 is a block diagram for an automatic chemical cleaning apparatus using a membrane fouling rate according to an embodiment of the present invention,

2 is a flowchart illustrating a method for automatically controlling chemical cleaning using a membrane fouling rate according to an embodiment of the present invention;

3 is a schematic diagram between the operating time (T) and the total filtration resistance (Rt) according to the present invention.

<Description of the symbols for the main parts of the drawings>

11: control unit 13: pressurized membrane filter unit

15: treated water tank 17: backwash pump

19: CIP tank portion 21: raw water tank portion

23: feed pump portion 25: flocculant inlet

27: mixer section 29: settling section

31: filtration pump

The present invention relates to a device for controlling chemical clean (Clean In Place, CIP) using a membrane fouling rate, and more particularly, to real-time monitoring of the optimal chemical cleaning cycle in a membrane filtration process for water treatment. An apparatus and method for automatically controlling an operation mode according to an optimal chemical cleaning cycle are provided.

As is well known, in the membrane filtration process for water treatment, CIP is performed when fouling continues and exceeds a predetermined threshold pressure as a method for guaranteeing treatment capacity.

That is, when performing CIP as described above, the number of CIPs is performed to maintain the target processing performance, which is the 'performance index' of the operation performance evaluation in the entire membrane filtration process, and the CIP It is a 'economic indicator' in connection with the maintenance costs (cleaning time), cleaning chemicals, waste liquid treatment, and by-product treatment costs required, and it is also a 'stability indicator' of the membrane filtration process.

In addition, the stable long-term operation with minimum CIP while maintaining the target processing capacity in the membrane filtration process means that the entire membrane filtration process is optimized. Here, the minimum CIP means that the loss of processing performance is minimized. The optimal CIP cycle should satisfy all of the above-described performance indicators, economic indicators, and stability indicators.

However, when using the conventional membrane filtration process as described above, the membrane fouling rate is sustained and the membrane fouling rate is increased above a predetermined limit differential pressure, even though the CIP is performed at random intervals to solve the membrane fouling. In addition, there is a problem in that the above-described 'performance indicators', 'economic indicators' and 'stability indicators' cannot be satisfied.

Accordingly, the technical problem of the present invention has been devised to solve the above problems, the object of the present invention is to monitor and set the optimum chemical cleaning cycle in the entire membrane filtration process for water treatment, the set optimal chemical cleaning cycle The present invention provides a CIP automatic control device and method using a membrane fouling speed that can automatically control an operation mode consisting of a normal mode (filtration process and backwash process) and a CIP mode (CIP process).

In the present invention for achieving the above object, the CIP automatic control apparatus using the membrane fouling rate calculates and calculates a constant value (γ) which can be automatically controlled according to the measured total filtration resistance (Rt) while monitoring the pressurized membrane filter unit. A control unit for deriving a chemical cleaning cycle by determining a range of constant values (γ) capable of automatic control, and setting an operation mode; and a backwash valve when the operating mode set according to the derived chemical cleaning cycle is a 'CIP process' cycle. A treatment water tank unit for automatically transporting the treated water to transfer collected water, a backwash pump unit for pumping the treated water, a CIP tank unit in which the pumped treatment water is mixed and transported into a chemically stored chemical, and a chemical It characterized in that it comprises a filtration pump for circulating pumping the mixed treated water to be filtered through the pressure membrane filter.

In addition, the CIP automatic control method using the membrane fouling rate in the present invention for achieving the above object is to measure the TMP while monitoring the pressurized membrane filter in real time, the measured TMP and the temperature correction coefficient (viscosity coefficient) (μ) And calculating the total filtration resistance (Rt) by detecting the flux (permeate flow rate / unit membrane area) (J), monitoring the total filtration resistance (Rt), and then monitoring the total filtration resistance per unit time in the preset PLC program ( Calculates the constant value γ that can be automatically controlled by detecting the difference ΔR (Rt2-Rt1), the time interval per unit time ΔT (t2-t1), and the constant (α) of the influent source concentration. And deciding the range of the calculated constant control value (γ) to derive a chemical cleaning cycle to set an operation mode, and automatically controlling the membrane filtration process according to the set operation mode. do.

Hereinafter, a plurality of embodiments of the present invention may exist, and a preferred embodiment will be described in detail with reference to the accompanying drawings. Those skilled in the art will appreciate the objects, features and advantages of the present invention through this embodiment.

1 is a block diagram for a CIP automatic control apparatus using a membrane fouling speed according to a preferred embodiment of the present invention, the control unit 11, the pressure-type membrane filter unit 13, the treated water tank unit 15 and , Backwash pump section 17, CIP tank section 19, raw water tank section 21, feed pump section 23, coagulant inlet section 25, mixer section 27, settling section 29 and the filtration pump part 31 are included.

The controller 11 refers to a programmable logic controller, and is an electronic device for digital operation using a memory (not shown) internally. The controller 11 operates / stops to enable an automated process of an automatic chemical cleaning controller. As a block for controlling the pressure, the trans-membrane pressure (TMP) is measured while monitoring the pressurized membrane filter unit 13 in real time (here, the limit pressure is usually in the range of 200 to 300 kPa), and the measurement is performed. Detected TMP, and temperature correction coefficient (viscosity coefficient) (μ) and flux (permeate flow rate / unit membrane area) (J).

Where Rt is the total filtration resistance, ΔP is the TMP, μ is the temperature correction coefficient (viscosity coefficient), and J is the flux (permeate flow rate / unit membrane area).

After calculating the total filtration resistance (Rt) by applying to, after monitoring the degree of rise of the total filtration resistance (Rt) at a certain time (for example, a schematic diagram as shown in Figure 3), per unit time on the preset PLC program After detecting the difference ΔR of the total filtration resistance Rt (Rt2-Rt1), the time interval per unit time ΔT (t2-t1), and the constant α of the influent source concentration, Equation 2

Where γ is a constant value that can be automatically controlled, ΔR is the difference in total filtration resistance (Rt) per unit time (Rt2-Rt1), ΔT is the time interval per unit time (t2-t1), and α is the influent source concentration Is a constant of.)

Calculate the constant value (γ) that can be controlled automatically by applying to, and determine the range of the calculated constant value (γ) that can be automatically controlled to derive the optimum chemical cleaning cycle to operate mode (eg normal mode vs. CIP mode).

Thereafter, the control unit 11 automatically controls the operation mode (eg, normal mode vs. CIP mode) according to the set optimal chemical cleaning cycle, and the raw water tank unit 21 and the supply pump unit during the 'filtration process' during the normal mode. (23) and coagulant inlet unit 25, mixer unit 27, sedimentation unit 29, filtration pump unit 31 and pressurized membrane filtration unit 13 are all controlled to operate automatically, during the 'backwashing process' The treated water tank unit 15, the backwash pump unit 17 and the pressurized membrane filtration unit 13 are all controlled to operate automatically.

In addition, the controller 11 automatically controls the operation mode (eg, normal mode vs. CIP mode) according to the set optimal chemical cleaning cycle, and the pressurized membrane filter unit 13 and the treated water during the CIP process, 'CIP process'. The tank unit 15, the backwash pump unit 17, and the CIP tank unit 19 and the filtration pump unit 31 are all controlled to operate automatically.

The pressurized membrane filtration unit 13 is classified into a membrane having selective permeability (for example, a steel membrane, a ceramic membrane, a polymer membrane, etc.), and the separation membrane according to this material classification is UF (Ultra-Filtration) and MF (Micro-) according to the process. The pore diameter within the range of 0.001-10 μm is described above because it has a pore size in the range of 0.001 to 10 μm, and removes impurities in raw water by sieving in water treatment to which the membrane filtration process is applied. As a block for removing all larger particles, under the automatic control of the control unit 11, the raw water transferred through the filtration pump unit 31 during the 'filtration process' is filtered to be transferred to the treated water tank unit 15. In the case of 'backwashing process', the treated water pumped by the backwashing pump unit 17 is transported back to the outside to be filtered. In addition, the pressurized membrane filtration unit 13 circulates treated water mixed with chemicals transferred from the CIP tank unit 19 through the filtration pump unit 31 during the 'CIP process' according to the automatic control of the control unit 11. / Filtered to be transferred back to the CIP tank 19.

The treated water tank unit 15 is a block for collecting the treated water filtered by the pressurized membrane filter unit 13, and is controlled by the pressurized membrane filter unit 13 during the 'filtration process' according to the automatic control of the controller 11. The filtered treated water is directly transported and collected, and automatically opens the backwash valve (not shown) located inside the 'backwashing process' to transfer the collected treated water to the backwash pump unit 17. In addition, the processing unit tank unit 15 automatically opens the backwash valve (not shown) located inside the 'CIP process' according to the automatic control of the control unit 11 to collect the treated water to the backwash pump unit 17. To be transported.

The backwash pump unit 17 is a block for centrifugally pumping the treated water, and under the automatic control of the control unit 11, the backwash pump unit 17 pressurizes the treated water collected in the treated water tank unit 15 during the 'backwashing process'. Back-filtered to pump to perform physical cleaning, and the backwash pump unit 17 also collects the treated water collected in the treated water tank unit 15 during the 'CIP process' according to the automatic control of the controller 11. Pumped to transfer to the CIP tank 19.

The CIP tank unit 19 is a block capable of mixing the treated water and the required chemicals for preparing the chemical to a certain concentration, and in the state having the chemicals internally, according to the automatic control of the control unit 11 At the CIP process, the treated water pumped by the backwash pump unit 17 is mixed with the chemical to be transferred to the filtration pump unit 31.

The raw water tank unit 21 automatically opens the raw water valve (not shown) located inside the 'filtering process' according to the automatic control of the control unit 11 to transfer the stored raw water to the supply pump unit 23. .

The supply pump unit 23 pumps the raw water transferred from the raw water tank unit 21 at a constant pressure (static pressure) or a constant flow rate (static flow rate) during the 'filtration process' according to the automatic control of the control unit 11. 27).

The coagulant input unit 25 injects the coagulant into the raw water transferred to the mixer unit 27 by pumping the feed pump unit 23 during the 'filtration process' according to the automatic control of the control unit 11.

The mixer unit 27 is a type of in-line mixer of a pipe-stirring stirrer facility, and is supplied from the supply pump unit 23 during the 'filtration process' according to the automatic control of the controller 11. The raw water to be transferred and the coagulant introduced by the coagulant inlet unit 25 are mixed to be efficiently mixed to be transferred to the precipitation unit 29 or the filtration pump unit 31. Here, the precipitation unit 29 may be omitted in the process, but if not omitted, the particles mixed and condensed by the mixer unit 27 during the 'filtration process' according to the automatic control of the control unit 11 using gravity. It is allowed to sink, and the remaining raw water may be transferred to the filtration pump unit 31.

The filtration pump unit 31 pumps the raw water mixed and transferred from the mixer unit 27 at a constant pressure (static pressure) or a constant flow rate (static flow rate) during the 'filtration process' according to the automatic control of the control unit 11. In addition to the filtration unit 13, the filtration pump unit 31 is pressurized by the treated water mixed with the chemicals transferred from the CIP tank 19 during the 'CIP process' under the automatic control of the control unit 11 Pumped to transfer to the membrane filtration unit (13).

Therefore, the CIP automatic control apparatus using the membrane fouling rate according to the present embodiment monitors and sets the optimal chemical cleaning cycle in the entire membrane filtration process for water treatment, and the normal mode (filtration process) according to the optimal chemical cleaning cycle. And automatic control of the operation mode consisting of backwashing process) and CIP mode (CIP process), resulting in 'performance indicators', 'economic indicators,' The problem of failing to satisfy the 'stability indicator' can be solved.

Next, the CIP automatic control process using the membrane fouling rate in the present embodiment having the above-described configuration will be described.

2 is a flowchart illustrating a CIP automatic control method using a membrane fouling rate according to an embodiment of the present invention.

First, the control unit 11 measures the TMP while monitoring the pressurized membrane filter unit 13 in real time, and the measured TMP, the temperature correction coefficient (viscosity coefficient) (μ), and the flux (permeate flow rate / unit membrane). After the area (J) is detected, the total filtration resistance Rt is calculated by applying the above equation (S201).

Thereafter, the controller 11 monitors the degree of rise of the total filtration resistance Rt at a predetermined time (for example, a schematic diagram as shown in FIG. 3), and then the total filtration resistance Rt per unit time on the preset PLC program. The difference (ΔR) (Rt2-Rt1), the time interval per unit time (ΔT) (t2-t1) and the constant (α) of the influent source concentration are detected, and then the constants that can be automatically controlled by applying to the above equation (2) The value γ is calculated (S203), and the calculated chemical control period is determined by determining the range of the constant constant value γ that can be automatically controlled (e.g., the normal mode 'filtration process' and 'backwash process'). While the process proceeds to the CIP mode 'CIP process' in accordance with how long the cycle to proceed in accordance with) to derive (S205) to set the determination of the operation mode (S207).

As described above, when the operation mode is set, the control unit 11 performs the 'CIP process', which is the CIP mode set according to the optimal chemical cleaning cycle, during the process of focusing on the normal mode 'filtration process' and 'backwash process'. It is determined whether or not to proceed (S209).

As a result of the determination (S209), in the normal mode 'filtration process' (S211), the raw water valve (not shown) located inside the raw water tank unit 21 is automatically opened to transfer the stored raw water to the supply pump unit 23. (S213).

The feed pump unit 23 pumps the raw water transferred from the raw water tank unit 21 at a constant pressure (static pressure) or a constant flow rate (static flow rate) according to the automatic control of the control unit 11 (S215) to the mixer unit 27. To be transported.

At this time, the coagulant injecting unit 25 injects the coagulant into the raw water transferred to the mixer unit 27 by the pumping of the feed pump unit 23 under the automatic control of the control unit 11 (S217).

Then, in the mixer 27, the mixing is performed to efficiently mix the raw water transferred from the feed pump 23 and the coagulant introduced by the coagulant injector 25 under the automatic control of the control unit 11 (S219). To be transferred to the precipitation unit 29 or the filtration pump unit 31. Here, the precipitation unit 29 may be omitted in the process, but if not omitted, the particles mixed and condensed by the mixer unit 27 according to the automatic control of the control unit 11 are settled using gravity, and the rest is restrained. Raw water may be transferred to the filtration pump unit 31.

The filtration pump unit 31 pumps (S221) the raw water mixed and transferred from the mixer unit 27 according to the automatic control of the control unit 11 at a constant pressure (static pressure) or a constant flow rate (static flow rate) to pressurized membrane filter unit. Transfer to (13).

The pressurized membrane filtration unit 13 filters the raw water transferred through the filtration pump unit 31 according to the automatic control of the control unit 11 to transfer the raw water to the treated water tank unit 15.

After the 'filtration process' as described above, the 'backwashing process' should always be performed.

That is, during the 'backwashing process' (S227), the treated water tank unit 15 automatically opens the backwash valve (not shown) located therein under the automatic control of the control unit 11 to collect the treated water collected in the backwash pump unit. Transfer to (17) (S229). The backwash pump unit 17 pumps the treated water collected in the treated water tank unit 15 according to the automatic control of the controller 11 to the pressurized membrane filter unit 13 to perform physical cleaning (S231). do. The pressurized membrane filtration unit 13 filters the treated water pumped by the backwash pump unit 17 according to the automatic control of the controller 11 to be reversely filtered (S233) to be transported to the outside.

Here, the 'filtration process' and the 'backwashing process' are continuously circulated, for example, a two-minute 'backwashing process' is performed in a 28-minute 'filtration process', and the two are combined for 30 minutes in one cycle. It operates in the normal mode for a total of 48 cycles, and the total filtration resistance (Rt) is calculated in each filtration process every cycle, and it is calculated every cycle and the normal mode (filtration / backwash) and CIP mode are executed. It is a standard to judge.

As a result of the determination (S209), the cycle of the 'CIP process' (S235), which is the CIP mode set according to the optimum chemical cleaning cycle, is performed every cycle, focusing on the 'filtration process' and 'backwashing process', which are normal modes. In this case, the treated water tank unit 15 automatically opens the backwash valve (not shown) located therein under the automatic control of the controller 11 to transfer the collected treated water to the backwash pump unit 17 (S237). Do it.

The backwash pump 17 pumps the treated water collected in the treated water tank 15 during the 'CIP process' back to the CIP tank 19 during the 'CIP process' according to the automatic control of the controller 11 (S239). .

The CIP tank unit 19 has the chemicals internally, and the treated water pumped by the backwash pump unit 17 during the 'CIP process' according to the automatic control of the control unit 11 is mixed with the chemicals ( S241) to be transferred to the filtration pump unit 31.

The filtration pump unit 31 circulates pumping the treated water mixed with the chemicals transferred from the CIP tank unit 19 to the pressure-type membrane filtration unit 13 under automatic control of the controller 11 (S243).

Then, the pressurized membrane filtration unit 13 circulates / filters the treated water mixed with the chemicals transferred from the CIP tank unit 19 through the filtration pump unit 31 according to the automatic control of the control unit 11 (S245). To the CIP tank 19 again.

At this time, the control unit 11 is automatically controlled to repeat the process (C247) according to the cycle of the set operation mode (S247) when the 'CIP process' cycle ends (S249), and returns to the normal mode again.

Therefore, the present invention is the CIP automatic control device using the membrane fouling rate is set by monitoring the optimal chemical cleaning cycle in the entire membrane filtration process for water treatment, and the filtration process and backwashing process, and CIP according to the optimal chemical cleaning cycle set By automatically controlling the operation mode consisting of the process, it is possible to judge the appropriate irreversible membrane fouling degree and to perform chemical cleaning automatically when less irreversible membrane fouling progresses to make the membrane recovery rate closer to the initial state more easily and quickly. It can improve the driving performance stably.

In addition, since the present invention is disclosed as a right within the spirit and claims of the present invention, the present invention may include any modification, use and / or adaptation using general principles, and the present invention as a matter deviating from the description of the present specification. It includes everything that falls within the scope of known or customary practice in the art to which it belongs and falls within the scope of the appended claims.

As described above, the present invention is a CIP automatic control device using the membrane fouling rate is set by monitoring the optimal chemical cleaning cycle in the entire membrane filtration process for water treatment, and according to the normal chemical cleaning cycle set in accordance with the normal mode and By automatically controlling the operation mode consisting of the CIP mode, the membrane fouling speed increases beyond the preset limit differential pressure as in the past, so that the 'performance indicators', 'economic indicators' and 'stability indicators' are not satisfied. The problem can be solved.

In addition, the present invention is to determine the appropriate irreversible degree of membrane fouling and to automatically perform chemical cleaning when less irreversible membrane fouling to recover the membrane recovery rate to the initial state more easily and quickly recovering stable operation performance It can improve the efficiency, save the type and amount of cleaning chemicals, reduce the cleaning time, there is an effect that can save the maintenance cost and control of the installation.

Claims (7)

delete delete delete delete delete A method of automatically controlling a chemical cleaning (CIP) cycle by using the membrane fouling rate of the pressurized membrane filter in an operation mode of filtering the raw water through the pressurized membrane filter and storing it in a treated water tank. A filtration process step of filtering the raw water with the pressurized membrane filter; A backwashing step of filtering the raw water stored in the filtered water tank back to the pressurized membrane filter unit; The pressurized membrane filter was monitored to measure TMP (Trans-Membrane Pressure), and the measured TMP, temperature correction coefficient (viscosity coefficient) (μ) and flux (permeate flow rate / unit membrane area) J were detected. Total filtration resistance (Rt) Equation

Where Rt is the total filtration resistance, ΔP is the TMP, μ is the temperature correction coefficient (viscosity coefficient), and J is the flux (permeate flow rate / unit membrane area). Using the step of calculating, The total filtration resistance (Rt) is monitored and the difference (ΔR) (Rt2-Rt1) of the total filtration resistance (Rt) per unit time on a preset PLC (Programmable Logic Controller) program and the time interval per unit time (ΔT) (t2-t1). ) And the constant value (γ) for automatic control by detecting the constant (α) of the influent source concentration. Equation

Where γ is a constant value that can be automatically controlled, ΔR is the difference in total filtration resistance (Rt) per unit time (Rt2-Rt1), ΔT is the time interval per unit time (t2-t1), and α is the influent source concentration Is a constant of.) Using the step of calculating, Deriving a chemical cleaning (CIP) cycle based on the calculated range of the constant value? Determining whether the cycle is a 'CIP' cycle according to the derived CIP cycle during the normal mode including the filtration process and the backwash process; In the case of the 'CIP' cycle, the step of automatically opening the backwash valve to transfer and pump the collected treated water, Transporting and circulating pumping the chemicals into the pumped treated water so as to be filtered through the pressurized membrane filter. Chemical cleaning automatic control method using a membrane fouling rate comprising. delete

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