JP5595956B2 - Evaluation method of fouling of separation membrane and operation method of membrane separation equipment - Google Patents

Description

  The present invention relates to a method for evaluating fouling of a separation membrane provided in a membrane separation apparatus for obtaining a permeate from a liquid to be treated and a method for operating a membrane separation facility.

  2. Description of the Related Art Conventionally, as a method for treating organic wastewater or the like, a membrane separation activated sludge method for separating activated sludge into solid and liquid together with purification treatment using microorganisms in activated sludge has been widely practiced. As a method of solid-liquid separation, various methods for solid-liquid separation of a liquid to be treated using a membrane separation apparatus including a separation membrane such as a microfiltration membrane and an ultrafiltration membrane have been studied.

  Such a membrane separation device is placed in a state of being immersed in the liquid to be treated, so that the solid content such as activated sludge itself or impurities brought in from the raw water does not adhere to the surface of the separation membrane and the filtration efficiency is not lowered. It is equipped with a diffuser installed at the bottom, aeration of the air etc. by the diffuser, to suppress or peel the adhesion of the deposit on the separation membrane surface by the vibration effect and stirring effect of the separation membrane due to bubbles and upward flow Yes.

  However, poorly soluble components, polymer solutes, colloids, micro solids, etc. contained in the liquid to be treated adhere and deposit on the membrane surface, so that the separation membrane is clogged by so-called fouling, and the processing efficiency is reduced. There's a problem. Therefore, if fouling prevention measures are required or if membrane clogging occurs due to fouling, the separation membrane is taken out and washed with chemicals, or the chemical and permeate flow through the separation membrane in the direction opposite to the filtration direction. It was necessary to wash.

  For example, Patent Document 1 discloses a wastewater treatment method using a membrane separation activated sludge method, in which the uronic acid unit concentration in the aqueous phase of the activated sludge exceeds a predetermined value, or the uronic acid in the activated sludge. When the value obtained by multiplying the unit concentration by the polyvalent cation concentration in the organic wastewater exceeds a predetermined value, the activated sludge or the organic wastewater is brought into contact with the polyvalent cation capturing means, and then the separation membrane device There has been proposed a method for preventing membrane fouling by performing solid-liquid separation by the above method.

  In Patent Document 2, the sugar concentration of a supernatant obtained by centrifuging a liquid to be treated is measured in a method for treating the liquid to be treated by an activated sludge treatment tank in which a separation membrane is installed. There has been proposed a method for treating a liquid to be treated, characterized by performing a differential pressure suppressing step for suppressing an increase in the transmembrane pressure difference of the separation membrane when the pressure is within a specific range.

  In Patent Document 3, the COD in a membrane filtrate that has permeated through a submerged membrane separator is measured, and a biological treatment tank is used with a filtration means having pores having a predetermined diameter larger than the pores of the filtration membrane of the submerged membrane separator. When the COD in the filtration means filtrate obtained by filtering the activated sludge mixed liquid is measured and the COD difference value obtained by subtracting the COD in the membrane filtrate from the COD in the filtration means filtrate is equal to or greater than a predetermined value, A treatment method has been proposed in which a liquid phase containing a biological polymer is separated and removed from an activated sludge mixed solution by two separation means.

JP 2009-66589 A JP 2007-75754 A Patent No. 4046661

  The wastewater treatment method described in Patent Document 1 is configured to detect the uronic acid unit concentration only in the aqueous phase of activated sludge, and uronic acid that permeates the separation membrane, which does not necessarily cause fouling of the separation membrane. As a result, the fouling state of the separation membrane cannot be evaluated correctly.

  The treatment method of the liquid to be treated described in Patent Document 2 measures the sugar concentration of the supernatant obtained by centrifuging the liquid to be treated, and the gravitational acceleration during centrifugation is 8000 to 12000 G. There was a problem that the range was high, and the sugar causing the fouling of the separation membrane was separated, and the sugar concentration was underestimated. In addition, since the structure is evaluated based on the sugar concentration of only the supernatant liquid, the sugar that does not necessarily cause the fouling of the separation membrane and the permeation of the separation membrane cannot be detected and the fouling state of the separation membrane cannot be evaluated correctly. was there.

  The method for treating sewage described in Patent Document 3 is a filtration membrane comprising a nonwoven fabric or the like in which pores having a pore size larger than the pores of the filtration membrane of a submerged membrane separator (more than 10 times the pore ratio) are formed. Although the configured filtration means is used, since the substance causing the fouling of the separation membrane is removed from the pores formed in the nonwoven fabric or the like together with a part of the activated sludge, the COD of the permeated liquid of the filtration membrane Was detected low, that is, there was a problem of underestimating the substance causing fouling.

  In view of the above-described problems, an object of the present invention is to provide a method for evaluating fouling of a separation membrane and a method for operating a membrane separation facility that can correctly evaluate the fouling state of the separation membrane and can appropriately wash the separation membrane. There is in point to do.

  In order to achieve the above-described object, the first characteristic configuration of the fouling evaluation method of the separation membrane according to the present invention is a membrane for obtaining a permeate from a liquid to be treated as described in claim 1 of the document of the claims. A method for evaluating fouling of a separation membrane provided in a separation device, wherein an organic substance concentration in a supernatant obtained by centrifuging the liquid to be treated at a gravitational acceleration of 1800 to 6000 G, and a permeation liquid of the separation membrane The organic matter concentration is measured, and the separation membrane fau is determined based on the difference or ratio between the measured value of the organic matter concentration in the supernatant and the measured value of the organic matter concentration in the permeate, or the rate of change of the difference or ratio. The point is to evaluate the ring state.

  A large amount of activated sludge and other suspended substances remain in the supernatant obtained by centrifuging the liquid to be treated such as activated sludge at a gravitational acceleration smaller than 1800G, so the organic matter concentration is accurately measured. There is a possibility that it cannot be done. On the other hand, if the liquid to be treated such as activated sludge is centrifuged at a gravitational acceleration greater than 6000 G, even organic substances that cause fouling of the separation membrane are separated together with the solids, and the organic substance concentration in the supernatant liquid is low. There is a risk of being measured.

  Centrifugation is performed at a gravitational acceleration of 1800 to 6000 G, so that the concentration of organic substances contained in the supernatant liquid can be accurately measured while separating the liquid to be treated such as activated sludge, that is, contained in the liquid to be treated. It is possible to accurately measure the concentration of organic substances.

  The properties of the liquid to be treated flowing into the treatment tank are not always constant, and the organic substance concentration in the tank is constantly changing depending on the environment such as the water temperature. Even if the organic matter concentration in the supernatant liquid is high, not all substances cause fouling, so the fouling state of the separation membrane is not necessarily bad, and conversely the organic matter concentration in the supernatant liquid is low. However, the separation membrane is not always free of fouling.

  Moreover, not all organic substances contained in the liquid to be treated in the tank cause fouling of the separation membrane, but also include those that permeate the separation membrane. Therefore, the organic matter concentration in the permeate that has passed through the separation membrane is measured, and the difference or ratio with the measured value of the organic matter concentration in the supernatant liquid described above, or the rate of change of the difference or ratio, and the change in the difference or the ratio is measured. Since the organic substance concentration that causes the ring can be calculated, the fouling state of the separation membrane can be correctly evaluated.

The second characteristic configuration is a method for evaluating fouling of a separation membrane provided in a membrane separation device for obtaining a permeate from a liquid to be treated as described in claim 2, wherein the absorbance of the supernatant after centrifugation is measured. Is an organic substance concentration in the supernatant obtained by centrifuging the liquid to be processed at a gravitational acceleration that is greater than 0.015 (ABS 660 nm, optical path length 10 mm ) and smaller than 0.025 (ABS 660 nm, optical path length 10 mm ), Measure the organic substance concentration in the permeate of the separation membrane, respectively, the difference or ratio between the measured value of the organic substance concentration in the supernatant and the measured value of the organic substance concentration in the permeate, or the rate of change of the difference or ratio The fouling state of the separation membrane is evaluated based on the above.

  A large amount of activated sludge is present in the supernatant obtained by centrifuging the liquid to be treated such as activated sludge at a gravitational acceleration such that the turbidity of the supernatant after centrifugation is 0.025 (ABS 660 nm) or more. Therefore, the organic substance concentration may not be measured accurately. On the other hand, if the liquid to be treated such as activated sludge is centrifuged at a gravitational acceleration such that the turbidity of the supernatant after centrifugation is 0.015 (ABS 660 nm) or less, it may cause fouling of the separation membrane. Even the organic matter is separated together with the solid content, and the organic matter concentration of the supernatant liquid may be measured low.

  Centrifugation is performed at a gravitational acceleration where the turbidity of the supernatant after centrifugation is greater than 0.015 (ABS 660 nm) and smaller than 0.025 (ABS 660 nm), while separating the solid content in activated sludge and the like. The organic substance concentration contained in the supernatant liquid can be accurately measured, that is, the organic substance concentration contained in the liquid to be treated in the tank can be accurately measured.

  Thereby, there can exist an effect similar to the evaluation method of the fouling of the separation membrane provided with the above-mentioned 1st characteristic structure.

In the third feature configuration, as described in claim 3, in addition to the first or second feature configuration described above, the measured value of the organic substance concentration in the supernatant is smaller than a predetermined first threshold value. And evaluating the fouling state of the separation membrane based on the difference between the measured value of the organic matter concentration in the supernatant and the measured value of the organic matter concentration in the permeate or the rate of change thereof, and the organic matter concentration in the supernatant. When the measured value of the separation membrane is equal to or greater than the first threshold value, the fouling state of the separation membrane is based on the ratio of the measured value of the organic substance concentration in the supernatant and the measured value of the organic substance concentration in the permeate or the rate of change thereof. It is in the point to evaluate.

  When the organic substance concentration in the supernatant liquid is smaller than a predetermined first threshold, the ratio is a ratio between the measured value of the organic substance concentration in the supernatant liquid and the measured organic substance concentration in the permeate liquid, or the ratio is changed. It is difficult to evaluate the fouling state of the film. Therefore, the fouling state of the separation membrane can be correctly evaluated based on the difference between the measured value of the organic substance concentration in the supernatant and the measured value of the organic substance concentration in the permeate or the change rate of the difference.

  On the contrary, when the measured value of the organic substance concentration in the supernatant is equal to or greater than the predetermined first threshold value, the measured value of the organic substance concentration in the supernatant liquid and the organic substance concentration in the permeate liquid are considered in consideration of the measurement error of the organic substance concentration. The fouling state of the separation membrane can be correctly evaluated based on the ratio of the measured values or the rate of change of the ratio.

  In the fourth feature configuration, in addition to the first or second feature configuration described above, the measurement value of the organic substance concentration in the supernatant and the measurement of the organic substance concentration in the permeate are added. When the difference from the value is smaller than a predetermined second threshold, the fouling state of the separation membrane is evaluated based on the difference between the measured values or the rate of change thereof, and the measured value of the organic matter concentration in the supernatant liquid When the difference from the measured value of the organic substance concentration in the permeate is equal to or greater than the second threshold value, the fouling state of the separation membrane is evaluated based on the ratio of each measured value or the rate of change thereof.

  When the difference between the measured value of the organic substance concentration in the supernatant and the measured value of the organic substance concentration in the permeate is smaller than the predetermined second threshold value, the organic substance concentration in the supernatant liquid is calculated in consideration of the measurement error of the organic substance concentration. It is difficult to evaluate the fouling state of the separation membrane based on the ratio of the measured value to the measured value of the organic substance concentration in the permeate or the rate of change of the ratio. The fouling state of the separation membrane can be correctly evaluated based on the difference between the measured value of the organic matter concentration in the supernatant and the organic matter concentration in the permeate or the change rate of the difference.

  Conversely, when the difference between the measured value of the organic substance concentration in the supernatant and the measured value of the organic substance concentration in the permeate is equal to or greater than a predetermined second threshold, the measured value of the organic substance concentration in the supernatant liquid and the permeate The fouling state of the separation membrane can be correctly evaluated based on the ratio of the measured value of the organic substance concentration in the medium or the rate of change of the ratio.

  In the fifth feature configuration, as described in claim 5, in addition to any of the first to fourth feature configurations described above, the organic substance concentration is at least any of total sugar, total protein, and uronic acid. It is in the point which is the density.

  Even if a wide variety of liquids to be treated flows into a tank filled with activated sludge, the fouling state of the separation membrane can be correctly evaluated based on the concentration of organic substances such as total sugar, total protein, and uronic acid. can do.

  In the sixth feature configuration, as described in claim 6, in addition to any of the first to fifth feature configurations described above, the organic substance concentration may be a TOC meter, a COD meter, or an ultraviolet absorptiometer. It is at a point measured by any measuring instrument.

  The total organic carbon, chemical oxygen demand, and UV absorbance are correlated with the concentration of organic substances in the liquid to be treated and the permeated liquid. Therefore, the organic substance concentration can be correctly calculated based on any index measured by any measuring instrument such as a TOC meter, a COD meter, or an ultraviolet absorption photometer.

  The first characteristic configuration of the operation method of the membrane separation equipment according to the present invention is the operation method of the membrane separation equipment provided with the membrane separation device for obtaining the permeate from the liquid to be treated, as described in claim 7, During the filtration operation step of obtaining the permeate through the membrane separation device, the evaluation step by the evaluation method of the fouling of the separation membrane having any one of the first to sixth characteristics described above is executed However, when fouling is occurring in the separation membrane in the evaluation step or when it is evaluated that fouling has occurred, a cleaning step of cleaning the separation membrane of the membrane separation apparatus is performed.

  When it is evaluated that fouling has occurred in the separation membrane by the method for evaluating fouling of the separation membrane having any one of the first to sixth features described above, the separation membrane permeates in the direction opposite to the filtration direction. Fouling can be eliminated and membrane clogging can be prevented by washing the separation membrane by performing a washing step such as flowing a fluid such as a liquid.

  Further, when it is evaluated that fouling is occurring in the separation membrane, by performing a removal step such as adding a flocculant to the liquid to be treated and aggregating a substance that causes fouling, The progress of fouling can be suppressed.

  The frequency of fouling evaluation is appropriately set according to, for example, once a day or once a week, depending on the properties of the liquid to be treated, the treatment tank, and the configuration of the separation membrane. The At this time, it may be either during execution or stop of the filtration operation step of obtaining the permeate through the membrane separator.

  In addition to the first characteristic configuration described above, the second characteristic configuration is further characterized by the fact that the separation membrane has a transmembrane pressure difference or a permeate during the filtration operation step. When the flow rate is measured and the transmembrane differential pressure or the measured value of the permeate flow rate is equal to or higher than a preset differential pressure threshold value for fouling determination, the evaluation step is executed.

  The transmembrane differential pressure of the separation membrane during the filtration operation process with the permeate flow rate set is determined by fouling of the separation membrane, or the attachment of activated sludge between the separation membrane surface and the separation membrane, It rises due to the adhesion of inorganic salts caused by calcium or the like, the blockage of the suction pipe for permeate, the decrease in the amount of aeration due to the failure of the diffuser.

  The cause of fouling of the separation membrane can be solved by taking out the separation membrane and washing it with a chemical solution, or by passing the chemical solution or permeate through the separation membrane in the direction opposite to the filtration direction and backwashing.

  However, in the case of causes such as activated sludge adhering to the surface of the separation membrane or between the separation membranes, blockage of the permeate suction pipe, or reduction of aeration due to failure of the diffuser, By changing the suction amount of the permeated liquid, changing the aeration amount of the diffuser, removing the separation membrane and removing the deposits by the worker, cleaning the suction pipe, repairing the diffuser, etc. Otherwise, it will not be resolved.

  Therefore, when the pressure difference between the membranes is increased due to adhesion of activated sludge, etc. between the separation membrane surface or between separation membranes, obstruction of the suction pipe for permeate, or reduction of aeration volume due to failure of the diffuser. In other words, even if fouling does not occur in the separation membrane, if it is judged that fouling has occurred and backwashing with a chemical solution is frequently performed, the chemical solution is wasted. There is a problem that the efficiency of such membrane separation activated sludge treatment itself is lowered. In order to eliminate wasteful backwashing, there is a problem that it is complicated because it is necessary to pull up the separation membrane from the treatment tank and visually check it by the operator in order to confirm the cause of the increase in the transmembrane pressure difference.

  According to the above-described configuration, the measured value of the transmembrane differential pressure of the separation membrane measured during the filtration operation step is greater than or equal to a preset differential pressure threshold value for fouling determination, and fouling has occurred. The above-mentioned problem can be solved because the cleaning process such as backwashing can be executed only when it is evaluated.

  Due to fouling on the separation membrane during the filtration operation process with a transmembrane differential pressure such as natural water head filtration, or due to activated sludge adhering to the surface of the separation membrane or between the separation membranes, calcium in the liquid to be treated, etc. When adhesion of the generated inorganic salt, blockage of the permeate suction tube, or reduction of the aeration amount due to a malfunction of the diffuser occurs, the permeate amount of the separation membrane decreases.

  Therefore, when the measurement value of the permeate amount of the separation membrane measured during the execution of the filtration operation step is less than or equal to a preset liquid amount threshold value for fouling determination, by executing the evaluation step, The same effect as the case where the transmembrane pressure difference is measured can be obtained.

  Furthermore, the fouling state can be more correctly evaluated by measuring both the transmembrane pressure difference and the permeated liquid amount of the separation membrane and using them as triggers for the evaluation process.

  In addition to the first or second characteristic configuration described above, the third characteristic configuration further includes the raw water treated in the membrane separation tank during the filtration operation step. When the concentration of the hardly-decomposable organic substance contained is measured and the measured value of the concentration of the hardly-decomposable organic substance is equal to or higher than a preset concentration threshold for fouling determination, the evaluation step is executed.

  Even if all of the persistent organic matter does not cause fouling of the separation membrane, it is correlated with the organic matter that causes fouling, so it is processed in the membrane separation tank during the filtration operation step. Membrane separation equipment having the above-described first or second characteristic configuration by measuring the concentration of hardly decomposable organic substances contained in raw water and comparing it with a preset concentration threshold for fouling determination The same operational effects as those of the driving method can be obtained.

  As described above, according to the present invention, it is possible to correctly evaluate the fouling state of the separation membrane, and to provide a method for evaluating fouling of the separation membrane and an operation method of the membrane separation equipment capable of appropriately cleaning the separation membrane. Can now.

Illustration of sewage treatment equipment Illustration of control device Explanatory diagram of the relationship between gravity acceleration and turbidity of the obtained supernatant Illustration of accumulated flow rate and permeation flux of supernatant liquid at each gravitational acceleration

Hereinafter, a method for evaluating fouling of a separation membrane and a method for operating a membrane separation facility according to the present invention will be described.
As shown in FIG. 1, a sewage treatment facility 1 includes a pretreatment facility 2, a flow rate adjustment tank 3, a membrane separation tank 4 filled with activated sludge, and a treatment target in the tank that is immersed in the membrane separation tank 4. A membrane separation device 6 for obtaining a permeate from the liquid and a treated water tank 5 are provided.

  The pretreatment facility 2 is provided with a bar screen 2a and the like for removing impurities mixed in the raw water, and the liquid to be treated from which the impurities are removed by the bar screen 2a and the like is temporarily stored in the flow rate adjusting tank 3. Even when the inflow amount of raw water fluctuates, the liquid to be treated at a constant flow rate is stably supplied from the flow rate adjusting tank 3 to the membrane separation tank 4 by the flow rate adjusting mechanism 3a such as a pump or a valve. ing.

  The membrane separation device 6 includes a plurality of separation membranes and an air diffuser 7 installed below the separation membrane. The plurality of separation membranes are arranged at regular intervals so that each membrane surface has a vertical posture. A filtration pump 8 is connected to each separation membrane via a collecting tube, and the liquid to be treated in the membrane separation tank 4 permeates through the separation membrane due to a differential pressure by the filtration pump 8.

  The air diffuser 7 includes an air diffuser tube in which a plurality of air diffuser holes are formed, and an air supply source such as a blower or a compressor that supplies air to the air diffuser tube. The air diffuser 7 and the filtration pump 8 are respectively controlled by the control device 10.

  As shown in FIG. 2, the control device 10 includes a flow rate control unit 11 that controls the flow rate adjustment mechanism 3 a, an air diffusion control unit 12 that controls the air diffusion device 7, and a pump control unit 13 that controls the filtration pump 8. The measured value L of the water level from the main control unit 14 provided and the water level sensor installed in the membrane separation tank 4, the measured value P of the pressure from the pressure gauge for measuring the transmembrane pressure difference of the separation membrane, and the separation A signal input unit 15 to which signals such as a measurement value Q from a flow meter for measuring the amount of permeate from the membrane are input, a fouling evaluation unit 16 for evaluating the fouling state of the separation membrane, and the like. It is configured to operate the separation activated sludge facility. Each control unit is constituted by a sequencer or a microcomputer.

  Usually, the control device 10 controls the flow rate adjustment mechanism 3a based on the measured value L of the water level from the water level meter installed in the membrane separation tank 4 so that the water level in the tank is maintained constant. The liquid to be treated to be supplied from the flow rate adjustment tank 3 to the membrane separation tank 4 is adjusted, aeration is performed by the air diffuser 7, and the liquid to be treated biologically treated by activated sludge by controlling the filtration pump 8 is treated as a membrane. A filtration operation step of performing solid-liquid separation by the separation membrane of the separation device 6 is performed.

  The permeated liquid of the separation membrane of the membrane separation device 6 is guided to the treated water tank 5 and temporarily stored, and is sterilized and discharged as necessary. In addition, the excess sludge propagated in the membrane separation tank 4 is configured to be drawn out of the tank.

  In the membrane separation tank 4, the inflow amount of the liquid to be treated from the flow rate adjustment tank 3 is adjusted, and the excess sludge is pulled out, so that the inside of the tank is controlled to be maintained at a constant sludge concentration. The properties of the liquid to be treated flowing into the tank are not always constant, and the concentration of organic substances in the tank is constantly changing due to changes in the water temperature, etc., and an environment in which fouling can occur in the separation membrane. ing.

  Here, even if the organic substance concentration in the tank is high, not all organic substances contained in the liquid to be treated are substances that cause fouling, so the fouling state of the separation membrane is not necessarily bad, and conversely Even if the organic substance concentration in the inside is low, fouling does not always occur in the separation membrane due to other conditions. Furthermore, even if fouling has occurred, it may be resolved over time by the treatment of activated sludge.

  Therefore, the control device 10 operates according to the present invention during the filtration operation step of operating the air diffuser 7 and the filtration pump 8 to permeate the liquid to be treated through the separation membrane to obtain a permeated liquid having a set flow rate. When the evaluation process by the evaluation method of the fouling of the separation membrane is executed and it is evaluated that fouling has occurred in the separation membrane in the evaluation process, the cleaning step of cleaning the separation membrane of the membrane separation device 6 is executed.

  The control device 10 evaluates when the measured value P of the transmembrane differential pressure of the separation membrane input from the pressure gauge during the filtration operation step is equal to or higher than a preset differential pressure threshold Pth for fouling determination. It is comprised so that a process may be performed.

  The evaluation step includes a centrifugation step for centrifuging the liquid to be treated in the membrane separation tank 4, a first measurement step for measuring the organic substance concentration in the supernatant obtained in the centrifugation step, and a permeate for the separation membrane. A second measurement step for measuring the concentration of organic matter therein, and evaluating the fouling state based on the first measurement value measured in the first measurement step and the second measurement value measured in the second measurement step It is configured as follows.

  In the centrifugation step, the worker centrifuges the activated sludge in the membrane separation tank 4 at a predetermined gravitational acceleration using a known centrifuge to obtain a supernatant. The centrifugation step can be automated using a sampling device or the like.

FIG. 3 shows the relationship between the gravitational acceleration when centrifuging the liquid to be treated and the turbidity of the obtained supernatant liquid. Turbidity is a value obtained by measuring the absorbance of the obtained supernatant at 660 nm with a spectrophotometer . As used herein, “turbidity” means “absorbance”.

  For example, when the gravity acceleration of centrifugation is less than 1000 G, the turbidity of the supernatant after centrifugation is greater than 0.05 (ABS 660 nm), and activated sludge and other suspended substances in the liquid to be treated are Since a large amount remains without being settled, the organic matter concentration cannot be measured accurately. Therefore, it is preferable to centrifuge at a gravitational acceleration of about 1800 G in which the turbidity in which the activated sludge and other suspended substances in the liquid to be treated are almost settled is in a range smaller than 0.025 (ABS 660 nm). .

  On the other hand, if the liquid to be treated is centrifuged at a gravitational acceleration such that the turbidity of the supernatant after centrifugation is 0.015 (ABS 660 nm) or less, for example, a gravitational acceleration greater than 6000 G, it may cause fouling of the separation membrane. Even such organic substances may be separated together with activated sludge and the like, and the organic substance concentration of the supernatant liquid may be measured low.

  In FIG. 4, the supernatant obtained by centrifuging the liquid to be treated containing organic substances causing fouling at each gravitational acceleration of 2000G, 4000G, 6000G, 8000G, 10000G, and 12000G passes through the separation membrane. The relationship between the integrated flow rate and the permeation flux per unit transmembrane pressure is shown.

  Compared to the supernatant obtained by centrifuging the liquid to be processed at a gravitational acceleration of 2000G, 4000G, and 6000G, the supernatant obtained by centrifuging the liquid to be processed at a gravitational acceleration of 8000G, 10000G, and 12000G, Even if the integrated flow rate increases, the degree of decrease in the permeation flux is moderate. In other words, even organic substances that cause fouling of the separation membrane are separated together with activated sludge and the like. Underestimate the concentration of organic matter that causes

  Therefore, in the centrifugation step, the activated sludge in the membrane separation tank 4 is centrifuged at a gravitational acceleration of 1800 to 6000 G using a known centrifuge to obtain a supernatant. The gravitational acceleration is preferably in the range of 1800 to 4000G, and more preferably in the range of 2000 to 3000G.

  In the first measurement step, the organic substance concentration in the supernatant obtained in the centrifugation step is measured. In the second measurement step, the concentration of organic substances in the permeate of the separation membrane is measured. Here, the organic substance concentration is a concentration of at least one of total sugar, total protein, and uronic acid, and each organic substance concentration is measured by any one of a TOC meter, a COD meter, and an ultraviolet absorptiometer. The measurement value is input to the fouling evaluation unit 16 of the control device 10 connected to a measuring instrument such as a TOC meter, a COD meter, and an ultraviolet absorption photometer through a signal line. Alternatively, the measurement value is input to the fouling evaluation unit 16 by an operator.

  In addition, when measuring an organic substance density | concentration with an ultraviolet absorptiometer, the light absorbency in the wavelength of the range of 220-300 nm is measured. In particular, measuring the absorbance at a wavelength in the range of 250 to 260 nm is preferable in that the concentration of organic substances that cause fouling of the separation membrane can be accurately measured.

  As described above, the measured value C1 of the organic substance concentration in the supernatant measured in the first measuring step and the measured value C2 of the organic substance concentration in the permeate measured in the second measuring step are Input to the fouling evaluation unit 16.

The fouling evaluation unit 16 calculates the difference D (= C1-C2) or the ratio R (= C1 / C2) from the measured value C1 of the organic substance concentration in the supernatant and the measured value C2 of the organic substance concentration in the permeate. Or at least one of the difference change rate Dr (= D _{n + 1} −D _n ) or the ratio change rate Rr (= R _{n + 1} / R _n ), and the fouling state of the separation membrane is evaluated based on the calculation result To do.

The fouling evaluation unit 16 includes a storage unit that stores the calculation result, and the storage unit stores the calculation result over time. The difference D _{n + 1} when calculating the change rate of the difference indicates the next calculation result of the difference D _n stored in the storage unit. Note that the difference D _n may be an average value D _nav of the difference D _{n + 1} of may be the result of only immediately before, the difference D _{n + 1} predetermined number of times of calculation results stored before is calculated.

Similarly, the ratio R _{n + 1} when calculating the rate of change of the ratio indicates the next calculation result of the ratio R _n stored in the storage unit. The ratio R _n may be the only result immediately preceding ratio R _{n + 1,} may be an average value R _nav predetermined number of times of calculation results stored before calculating the ratio R _{n + 1.}

  As described above, on the basis of the result calculated from the measured value C1 of the organic substance concentration in the supernatant and the measured value C2 of the organic substance concentration in the permeate, the fouling evaluation unit 16 performs the fouling of the separation membrane as follows. Evaluate the ring condition.

  When the difference D (= C1−C2) is equal to or larger than a predetermined fouling evaluation threshold value Dth set in advance, the fouling evaluation unit 16 generates fouling in the separation membrane or generates fouling. Assess that it is going.

  Or, when the ratio R (= C1 / C2) is equal to or higher than a predetermined fouling evaluation threshold value Rth, the fouling evaluation unit 16 generates fouling in the separation membrane, or fouling occurs. Assess that it is occurring.

Alternatively, the fouling evaluation unit 16 generates fouling when the change rate Dr (= D _{n + 1} −D _n ) of the difference is equal to or higher than a predetermined fouling evaluation threshold value Drth. Evaluate that a ring is occurring.

Alternatively, the fouling evaluation unit 16 generates fouling when the ratio change rate Rr (= R _{n + 1} / R _n ) is equal to or higher than a predetermined fouling evaluation threshold value Rrth, Evaluate that a ring is occurring.

Here, when the measured value C1 of the organic substance concentration in the supernatant liquid is smaller than the predetermined first threshold value Cth, the measured value C1 of the organic substance concentration in the supernatant liquid and the organic substance in the permeate liquid are taken into account when taking into account the measurement error of the organic substance concentration. The fluctuation range of the fouling state of the separation membrane due to the ratio R (= C1 / C2) of the concentration measurement value C2 or the rate of change Rr (= R _{n + 1} / R _n ) of the ratio becomes large, and evaluation is difficult.

Accordingly, the difference D (= C1-C2) measurements C2 organics concentration permeate and the measured value C1 of the organic matter concentration in the supernatant or be based on the rate of change of the difference _{Dr (= D n + 1 -D} n) Thus, the fouling state of the separation membrane can be correctly evaluated.

On the contrary, when the measured value C1 of the organic substance concentration in the supernatant liquid is equal to or higher than the predetermined first threshold value Cth, the ratio R of the measured value C1 of the organic substance concentration in the supernatant liquid and the measured value C2 of the organic substance concentration in the permeate liquid ( = C1 / C2) or the change rate Rr (= R _{n + 1} / R _n ) of the ratio can correctly evaluate the fouling state of the separation membrane.

  Thus, the fouling state of the separation membrane can be more correctly evaluated by comparing the measured value C1 of the organic substance concentration in the supernatant with the predetermined first threshold value Cth and appropriately selecting the calculation method.

  As described above, when it is evaluated by the fouling evaluation unit 16 that fouling has occurred in the separation membrane based on any of the calculation results, the control device 10 performs the separation membrane cleaning step.

  In addition, when it is evaluated that fouling is occurring in the separation membrane based on the calculation result, the control device 10 performs a process of removing a substance that causes fouling.

  The washing step is a step of backwashing the separation membrane by passing a chemical solution or permeate in the direction opposite to the filtration direction, or taking out the separation membrane and washing the solution with chemicals, and the removal step. It is a step of injecting a flocculant or the like for suppressing fouling into the tank or discharging the liquid to be treated as surplus sludge, and may be configured to be automatically controlled by the control device 10, depending on the worker The configuration may be performed manually.

  Further, the flow rate of the liquid to be treated supplied to the membrane separation tank 4 by the flow rate adjusting mechanism 3a and the flow rate and suction pressure of the permeate liquid by the filtration pump 8 are reduced, so that the liquid to be treated in the membrane separation tank 4 is retained. A configuration may be adopted in which the time is lengthened and the amount of aeration by the air diffuser 7 is increased to facilitate the elimination of fouling.

  When the fouling evaluation unit 16 determines that no fouling has occurred, the increase in the transmembrane pressure difference is not caused by fouling of the separation membrane, for example, between the separation membrane surface and the separation membrane. This is thought to be due to adhesion of activated sludge, adhesion of inorganic salts caused by calcium in the liquid to be treated, blockage of the suction pipe of the permeate, and reduction of aeration volume due to failure of the diffuser. Without removing the chemical solution for organic substances, change the suction amount of the permeated liquid from the separation membrane, change the aeration amount of the diffuser, remove the separation membrane, and remove the deposits by the workers. , Cleaning the suction tube, repairing the diffuser, etc.

  In the above-described embodiment, the control device 10 determines that the measurement value P of the transmembrane differential pressure of the separation membrane input from the pressure gauge during the filtration operation step is equal to or greater than the preset differential pressure threshold Pth for fouling determination. Then, the evaluation process is executed, and when the fouling is generated in the separation membrane in the evaluation process or the fouling is evaluated to be generated, the cleaning process is executed. Even if the measured value P of the inter-differential pressure is smaller than a preset differential pressure threshold value Pth for fouling determination, the evaluation process is periodically performed, and the measured value P of the transmembrane differential pressure is set in advance. When it becomes equal to or higher than the differential pressure threshold Pth for determination, if it is evaluated that fouling has occurred in the separation membrane or that fouling is occurring in the evaluation step, the cleaning step is executed. Even if configured as There.

  Further, when the measured value Q of the permeated liquid amount of the separation membrane input from the flow meter during execution of the filtration operation step is equal to or less than a preset liquid amount threshold value Qth for fouling determination, The evaluation process may be executed, and a measured value Cr of the concentration of the hardly decomposable organic matter contained in the raw water treated in the membrane separation tank 4 during the filtration operation process is set in advance. When the density threshold value Crth for ring determination is exceeded, the evaluation process may be executed.

In the above-described process for evaluating fouling of the separation membrane, the configuration for determining the evaluation condition for fouling by comparing the measured value C1 of the organic substance concentration in the supernatant with the predetermined first threshold value Cth has been described. When the difference D (= C1-C2) between the measured value C1 of the organic substance concentration in the medium and the measured value C2 of the organic substance concentration in the permeate is smaller than the predetermined second threshold D2, the difference D (= C1-C2) or to evaluate the fouling state of the separation membrane based on the rate of change _{Dr (= D n + 1 -D} n), if the difference D (= C1-C2) is equal to or greater than the second threshold value D2, each measurement it may be configured to evaluate the fouling state of the separation membrane based on the value of the ratio R (= C1 / C2) or its rate of change _{Rr (= R n + 1 /} R n).

  Moreover, in embodiment mentioned above, although the control apparatus 10 demonstrated the structure which performs the evaluation process by the evaluation method of the fouling of the separation membrane by this invention during execution of the filtration operation process, the said evaluation process is filtration operation. The configuration may be executed while the process is stopped.

  Further, the evaluation process by the evaluation method of the fouling of the separation membrane is not limited to that by the fouling evaluation unit 16, and the worker calculates and evaluates the fouling state based on the measurement values from each measuring device such as a TOC meter. It may be a configuration.

  In the above-described embodiment, the configuration in which the liquid to be treated permeates the separation membrane by the control of the suction pump 8 has been described. However, the suction pump 8 is not necessarily provided, and the natural water head is used between the front and back of the separation membrane. The structure which permeate | transmits a to-be-processed liquid to a separation membrane by generating a differential pressure | voltage may be sufficient.

  In the above-described embodiment, the configuration in which the membrane separation apparatus is immersed in the membrane separation tank has been described. However, the membrane separation apparatus is disposed outside the storage tank of the liquid to be processed, and the storage tank and the membrane separation apparatus It is also possible to obtain a permeate that has permeated through the separation membrane while circulating the liquid to be treated.

  In the above-described embodiments, the configuration in which the substance causing fouling of the separation membrane is an organic substance has been described. However, the present invention can also be applied to an inorganic substance containing a component such as calcium or phosphorus as a substance causing fouling. In this case as well, the fouling state can be evaluated from the inorganic concentration in the supernatant obtained by centrifuging the liquid to be treated and the inorganic concentration in the permeated liquid of the separation membrane.

  The above-described embodiment is one aspect of the present invention, and the present invention is not limited by the description. Specific configurations and control aspects of each part can be appropriately changed and designed within the scope of the effects of the present invention. Needless to say.

1: membrane separation device 2: pretreatment device 3: flow rate adjustment tank a: flow rate adjustment mechanism 3
4: Membrane separation tank 5: Treated water tank 6: Membrane separation tank Value 7: Air diffuser 8: Suction pump 8
10: Control device 11: Flow rate control unit 12: Aeration control unit 13: Pump control unit 14: Main control unit 15: Signal input unit 16: Fouling evaluation unit

Claims (9)

A fouling evaluation method for a separation membrane provided in a membrane separation device for obtaining a permeate from a liquid to be treated,
Measure the organic substance concentration in the supernatant obtained by centrifuging the liquid to be treated at a gravitational acceleration of 1800 to 6000 G and the organic substance concentration in the permeate of the separation membrane, respectively, and determine the organic substance concentration in the supernatant liquid. A method for evaluating fouling of a separation membrane, wherein a fouling state of the separation membrane is evaluated based on a difference or a ratio between a measured value and a measured value of an organic substance concentration in the permeate, or a change rate of the difference or the ratio. A fouling evaluation method for a separation membrane provided in a membrane separation device for obtaining a permeate from a liquid to be treated,
The absorbance of the supernatant after centrifugation is greater than 0.015 (ABS 660 nm , square cell with an optical path length of 10 mm ) and smaller than 0.025 (ABS 660 nm, square cell with an optical path length of 10 mm ), and the above-mentioned treatment is performed with gravitational acceleration. Measure the organic substance concentration in the supernatant obtained by centrifuging the liquid and the organic substance concentration in the permeate of the separation membrane, and measure the organic substance concentration in the supernatant and the organic substance concentration in the permeate. The evaluation method of the fouling of a separation membrane which evaluates the fouling state of the separation membrane based on the difference or ratio with respect to the measured value or the change rate of the difference or ratio.   When the measured value of the organic substance concentration in the supernatant is smaller than a predetermined first threshold, the difference between the measured value of the organic substance concentration in the supernatant and the measured value of the organic substance concentration in the permeate or the rate of change thereof The fouling state of the separation membrane is evaluated based on the measured value of the organic substance concentration in the supernatant liquid and the organic substance in the permeate liquid when the measured organic substance concentration value in the supernatant liquid is equal to or higher than the first threshold value. The method for evaluating fouling of a separation membrane according to claim 1 or 2, wherein the fouling state of the separation membrane is evaluated based on a ratio of measured values of concentration or a change rate thereof.   When the difference between the measured value of the organic matter concentration in the supernatant and the measured value of the organic matter concentration in the permeate is smaller than a predetermined second threshold, the separation is performed based on the difference between the measured values or the rate of change thereof. When the difference between the measured value of the organic matter concentration in the supernatant and the measured value of the organic matter concentration in the permeate is equal to or greater than the second threshold value, the ratio of each measured value or its The method for evaluating fouling of a separation membrane according to claim 1 or 2, wherein the fouling state of the separation membrane is evaluated based on a change rate.   The method for evaluating fouling of a separation membrane according to any one of claims 1 to 4, wherein the organic substance concentration is at least one of total sugar, total protein, and uronic acid.   The method for evaluating fouling of a separation membrane according to any one of claims 1 to 4, wherein the organic substance concentration is measured by any one of a TOC meter, a COD meter, and an ultraviolet absorptiometer. A method for operating a membrane separation facility comprising a membrane separation device for obtaining a permeate from a liquid to be treated,
The evaluation process according to the evaluation method for fouling of the separation membrane according to any one of claims 1 to 6 is executed during the execution or stop of the filtration operation process for obtaining a permeate through the membrane separation device, and the evaluation A method for operating a membrane separation facility, wherein a fouling is occurring in the separation membrane in the process, or if it is evaluated that fouling has occurred, a washing step of washing the separation membrane of the membrane separation apparatus is executed.   Furthermore, the transmembrane differential pressure or the permeate flow rate of the separation membrane is measured during the filtration operation step, and the measured value of the transmembrane differential pressure or the permeate flow rate is preset. The operation method of the membrane separation equipment according to claim 7, wherein the evaluation step is executed when the pressure difference threshold value for determination is exceeded. Furthermore, the concentration of the hardly decomposable organic matter contained in the raw water treated in the membrane separation tank is measured during the filtration operation step, and the measured value of the concentration of the hardly degradable organic matter is set in advance. The method for operating a membrane separation facility according to claim 7 or 8, wherein the evaluation step is executed when the concentration threshold value is greater than or equal to the threshold value.

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