KR100889475B1 - Method for manufaturing of mineral mixed sulfate zinc and manganese sulfate, ferrous sulfate - Google Patents

Method for manufaturing of mineral mixed sulfate zinc and manganese sulfate, ferrous sulfate Download PDF

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KR100889475B1
KR100889475B1 KR1020020016290A KR20020016290A KR100889475B1 KR 100889475 B1 KR100889475 B1 KR 100889475B1 KR 1020020016290 A KR1020020016290 A KR 1020020016290A KR 20020016290 A KR20020016290 A KR 20020016290A KR 100889475 B1 KR100889475 B1 KR 100889475B1
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manganese
sulfate
zinc
ore
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문상우
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C01G9/06—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/10—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/14—Sulfates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Processing Of Solid Wastes (AREA)
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Abstract

본 발명은 아연광석, 제강공장 전기로더스트, 고철, 폐로망간과 이산화망간, 탄산망간광석(광석상태로 사용한다) 도금공장 아연재등에서 황산아연, 황산망간 및 황산제1철이 혼합된 미네랄을 제조하는 방법에 관한 것이다.The present invention is a method for producing minerals mixed with zinc sulfate, manganese sulfate and ferrous sulfate in zinc ore, steel mill electric furnace, scrap iron, manganese and manganese dioxide, manganese carbonate ore (used in the ore) plating factory zinc material, etc. It is about.

즉, 순도 50중량%의 황산수용액 100중량%에 대하여 아연광석 8중량%, 제강공장전기로더스트 8중량%, 페로망간 8중량%, 도금공장의 아연재 8중량%, 고철 4중량%, 이산화망간 4중량% 탄산망간광석 2중량%, 페로망간합금철 전기로더스트 2중량%를 넣어 95℃로 5시간 가열하고 여과시킨 용액에 아연말 1~3중량%를 넣어 중금속을 제거하고 여과한 용액을 농축건조하므로서 황산아연, 황산망간, 황산제1철이 일정비율 혼합되는 황산아연,황산망간 및 황산제1철이 혼합된 미네랄의 제조방법이다.That is, with respect to 100% by weight of 50% by weight aqueous sulfuric acid solution, 8% by weight of zinc ore, 8% by weight of steel mill electric furnace, 8% by weight of ferro-manganese, 8% by weight of zinc material in plating plant, 4% by weight of scrap metal, 4% by weight of manganese dioxide 2% by weight of manganese carbonate ore and 2% by weight of ferro-manganese alloy electric furnace were heated at 95 ° C. for 5 hours, 1 ~ 3% by weight of zinc powder was added to the filtered solution to remove heavy metals, and the filtered solution was concentrated to dryness. Therefore, zinc sulfate, manganese sulfate, and ferrous sulfate are mixed in a proportion of zinc sulfate, manganese sulfate, and ferrous sulfate.

아연광석, 페로망간, 아연재, 고철, 이산화망간Zinc Ore, Ferro-Manganese, Zinc, Scrap Metal, Manganese Dioxide

Description

황산아연,황산망간 및 황산제1철이 혼합된 미네랄의 제조방법{Method for manufaturing of mineral mixed sulfate zinc and manganese sulfate, ferrous sulfate}Method for manufacturing mineral mixed with zinc sulfate, manganese sulfate and ferrous sulfate {Method for manufaturing of mineral mixed sulfate zinc and manganese sulfate, ferrous sulfate}

본 발명은 아연광석, 제강공장전기로더스트, 고철, 폐로망간과 이산화망간, 탄산망간광석(광석상태로 사용한다),도금공장 아연재등에서 황산아연, 황산망간 및 황산제1철이 혼합된 미네랄을 제조하는 방법에 관한 것이다.The present invention is to produce a mineral mixed with zinc sulfate, manganese sulfate and ferrous sulfate in zinc ore, steel mill electric furnace, scrap iron, manganese and manganese dioxide, manganese carbonate ore (used in the ore state), galvanizing plant, etc. It is about a method.

아연광석에는 아연 55중량%, 철 6중량%가 포함되어 있고, 제강공장 전기로더스트는 아연 25중량%, 철 25중량%가 포함되어 있으며, 페로망간합금철 전기로더스트 망간 25중량%가 있다.Zinc ore contains 55% by weight of zinc, 6% by weight of iron, steel mill electric furnace contains 25% by weight of zinc, 25% by weight of iron, ferro-manganese alloy iron electric furnace is manganese 25% by weight.

페로망간에는 망간 70중량%, 철 15중량%가 포함되어 있고, 아연재에는 아연 65중량%가 포함되어 있으며, 이산화망간은 망간 50중량%와 철 15중량%가 포함되어 있고 탄산망간광석에는 망간(Mn) 30중량%가 포함되어 있다.Ferro-manganese contains 70% by weight of manganese and 15% by weight of iron, zinc contains 65% by weight of zinc, manganese dioxide contains 50% by weight of manganese and 15% by weight of iron, and manganese carbonate ore Mn) 30% by weight is included.

본 발명은 상기와 같은 소재에서 황산아연과 황산망간 그리고 황산제1철이 혼합되어 있는 미네랄을 생산하여 경제성 있는 효과를 얻는 것이다. The present invention is to produce a mineral with a mixture of zinc sulfate, manganese sulfate and ferrous sulfate in the material as described above to obtain an economic effect.                         

종래에는 황산제1철, 황산아연, 황산망간을 하나하나 별도로 생산하여 미네랄 제조에 사용하므로 제조과정에서 폐기물이 많이 발생하고 생산원가가 많아 경제성이 없는 결점이 있었다.
Conventionally, ferrous sulfate, zinc sulfate, and manganese sulfate are produced separately one by one to be used in the manufacture of minerals, resulting in a lot of waste in the manufacturing process and a large production cost, so there is a lack of economic efficiency.

본 발명은 상기와 같은 종래의 결점을 시정하기 위하여 개발된 것으로 이를 더욱 상세히 설명하면 다음과 같다.
The present invention was developed to correct the above-mentioned drawbacks as described in more detail as follows.

본 발명은 순도50중량% 황산수용액에 황산수용액을 100중량%로 했을 때 중량비로 아연광석 8중량%, 제강공장전기로더스트 8중량%, 페로망간 8중량%, 도금공장의 아연재 8중량%, 고철 4중량%, 이산화망간 4중량%, 탄산망간광석 2중량%, 페로망간 합금철 전기로더스트 25중량%를 넣어 조성물을 만들고 이를 95℃로 5시간 가열하고 여과하여 얻은 용액에 아연말 1~3중량%를 넣어 중금속을 제거한 후 용액을 여과하여 농축건조하여 황산아연, 황산망간 및 황산제1철이 혼합되어 있는 혼합 미네랄을 얻는 것이다.The present invention is a weight ratio of 50% by weight of sulfuric acid solution to 100% by weight of sulfuric acid solution in the weight ratio of zinc ore 8% by weight, 8% by weight of steel mill electrical furnace, 8% by weight of ferro manganese, 8% by weight of zinc in the plating plant, 4% by weight of scrap iron, 4% by weight of manganese dioxide, 2% by weight of manganese carbonate or 25% by weight of ferro-manganese ferroalloy electric furnace to make a composition, and heated to 95 ℃ for 5 hours and filtered to a solution of zinc powder 1-3 % Is added to remove heavy metals, the solution is filtered and concentrated to dryness to obtain a mixed mineral containing zinc sulfate, manganese sulfate and ferrous sulfate.

[실시예 1]Example 1

물 1200g중 황산 600g이 혼합된 황산 50중량% 황산수용액에To a 50% by weight sulfuric acid solution mixed with 600 g of sulfuric acid in 1200 g of water

아연광석(ZNS) 100gZinc Ore (ZNS) 100g

제강공장 전기로더스트(E.A.F) 100g Steel mill electric furnace (E.A.F) 100g                     

페로망간 100gFerromangan 100g

도금공장 아연재 100gPlating Plant Zinc Material 100g

고철(쇠조각) 50gScrap metal 50 g

이산화망간 50gManganese Dioxide 50g

탄산망간광석 20gManganese Carbonate Ore 20g

페로망간합금철전기로더스트 20g을20g ferro-manganese alloy electric furnace

넣어 95℃로 5시간 가열하고 용융액을 여과한 다음 아연말 30g을 넣어 중금속을 제거하고 용액을 다시 여과한 후 얻은 여액을 농축, 건조하므로서 황산아연 38중량%(400g), 황산망간 33중량%(340g), 황산제1철 29중량%(300g)의 비율로 혼합이 되어 있는 미네랄제조용 제품을 얻었다.The mixture was heated at 95 ° C. for 5 hours, the melt was filtered, 30 g of zinc powder was added to remove heavy metals, and the solution was filtered again. The filtrate was concentrated and dried to obtain 38% by weight of zinc sulfate (400 g) and 33% by weight of manganese sulfate ( 340 g) and ferrous sulfate were obtained by mixing a mineral manufacturing product in a ratio of 29% by weight (300 g).

[실시예 2]Example 2

물 1200g중 황산 600g이 혼합된 황산 50중량% 황산수용액에To a 50% by weight sulfuric acid solution mixed with 600 g of sulfuric acid in 1200 g of water

제강공장 전기로더스트 350gSteel mill electric furnace 350g

페로망간 100gFerromangan 100g

이산화망간 50gManganese Dioxide 50g

탄산망간광석 50g
Manganese Carbonate Ore 50g

넣어 95℃로 5시간 가열하고 용융액을 여과한 다음 아연말 30g을 넣어 중금속을 제거하고 용액을 다시 여과한 후 얻은 여액을 농축,건조하므로서 황산아연 261g, 황산망간 330g, 황산제1철 351g의 비율로 혼합이되어 미네랄제조용에 사용할 수 있는 제품을 얻었다The mixture was heated at 95 ° C. for 5 hours, the melt was filtered, 30 g of zinc powder was added to remove heavy metals, and the solution was filtered again. The filtrate was concentrated and dried to obtain 261 g of zinc sulfate, 330 g of manganese sulfate, and 351 g of ferrous sulfate. To be used for mineral preparation

[실시예 3]Example 3

물 1200g중 황산 600g이 혼합된 황산 50중량% 황산수용액에To a 50% by weight sulfuric acid solution mixed with 600 g of sulfuric acid in 1200 g of water

제강공장 전기로더스트 350gSteel mill electric furnace 350g

페로망간 100gFerromangan 100g

탄산망간광석 90gManganese Carbonate Ore 90g

페로망간합금철전기로더스트 50g을50g ferro-manganese alloy electric furnace dust

넣어 95℃로 5시간 가열하고 용융액을 여과한 다음 아연말 30g을 넣어 중금속을 제거하고 용액을 다시 여과한 후 얻은 여액을 농축,건조하므로서 황산아연 261g, 황산망간 327g, 황산제1철 270g의 비율로 혼합이되어 미네랄제조용에 사용할 수 있는 제품을 얻었다The mixture was heated at 95 ° C. for 5 hours, the melt was filtered, 30 g of zinc powder was added to remove heavy metals, and the solution was filtered again. The filtrate was concentrated and dried to obtain 261 g of zinc sulfate, 327 g of manganese sulfate, and 270 g of ferrous sulfate. To be used for mineral preparation

이와같이 제조된 본원 발명은 황산아연과 황산망간과 황산제1철이 혼합된 미네랄용 소재를 생산할 수 있기 때문에 경제성 있는 제품의 생산이 가능하고 중금속을 아연말로 제거하기 때문에 안전하고 경제적이며 순도가 높은 제품생산이 달성되므로 제품을 동물사료용 미네랄 생산등에 바로 활용할 수 있는 이점을 얻는 것이다.The present invention manufactured as described above is capable of producing economical products because zinc sulfate, manganese sulfate and ferrous sulfate are mixed, and thus it is possible to produce economical products, and removes heavy metals with zinc powder to produce safe, economical and high purity products. Since this is achieved, the product can be immediately used for producing minerals for animal feed.

Claims (1)

순도 50중량%, 황산수용액 100중량%에 대하여 중량비로 아연광석 8중량%, 제강공장전기로더스트 8중량%, 페로망간 8중량%, 도금공장의 아연재 8중량%, 고철 4중량%, 이산화망간 4중량%, 탄산망간광석 2중량%, 페로망간합금철 전기로더스트 2중량%를 넣어 조성물을 만들고 이를 95℃로 5시간 가열하고 여과시킨 용액에 아연말 1~3중량%를 넣어 중금속을 제거하고 여과한 용액을 농축건조하여 얻어지는 황산아연, 황산망간 및 황산제1철이 혼합된 미네랄의 제조방법.50% by weight, 8% by weight of zinc ore, 8% by weight of electric furnace, 8% by weight of ferro-manganese, 8% by weight of zinc in the plating plant, 4% by weight of scrap metal, 4% by weight of manganese dioxide Add weight%, 2% by weight manganese carbonate or 2% by weight ferro-manganese alloy electric furnace to make a composition, heat it to 95 ℃ for 5 hours, add 1 ~ 3% by weight of zinc powder to the filtered solution to remove heavy metals, and filter A method for producing minerals in which zinc sulfate, manganese sulfate and ferrous sulfate are obtained by concentrating and drying one solution.
KR1020020016290A 2002-03-26 2002-03-26 Method for manufaturing of mineral mixed sulfate zinc and manganese sulfate, ferrous sulfate KR100889475B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012157957A2 (en) * 2011-05-17 2012-11-22 주식회사 티엠바이오 Method for manufacturing multi-mineral from waste battery
KR101966065B1 (en) 2018-10-31 2019-04-05 주황윤 Manufacturing method of multi-mineral from industrial waste
KR101966063B1 (en) 2018-10-31 2019-04-05 주황윤 Manufacturing method of multi-mineral comprising Zinc sulfate, Iron sulfate, Copper sulfate and manganese sulphate from electric arc furnace dust, copper waste and Manganese waste

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000050698A (en) * 1999-01-14 2000-08-05 문상우 Process for isolating solid material from liquid mixture using magnetic field and the apparatus therefor
KR20020020318A (en) * 2000-09-08 2002-03-15 문상우 Method for manufacturing sulfate zinc and manganese sulfate, ferrous sulfate from electric furnace dust of tin and zinc coatingplant and ferromanganese
KR20020020322A (en) * 2000-09-08 2002-03-15 문상우 Method for manufacturing zinc sulfate manganese sulfate and ferrous sulfate by using zinc ore, ferromanganese, manganese dioxide, scrap iron

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000050698A (en) * 1999-01-14 2000-08-05 문상우 Process for isolating solid material from liquid mixture using magnetic field and the apparatus therefor
KR20020020318A (en) * 2000-09-08 2002-03-15 문상우 Method for manufacturing sulfate zinc and manganese sulfate, ferrous sulfate from electric furnace dust of tin and zinc coatingplant and ferromanganese
KR20020020322A (en) * 2000-09-08 2002-03-15 문상우 Method for manufacturing zinc sulfate manganese sulfate and ferrous sulfate by using zinc ore, ferromanganese, manganese dioxide, scrap iron

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012157957A2 (en) * 2011-05-17 2012-11-22 주식회사 티엠바이오 Method for manufacturing multi-mineral from waste battery
WO2012157957A3 (en) * 2011-05-17 2013-01-24 주식회사 티엠바이오 Method for manufacturing multi-mineral from waste battery
KR101966065B1 (en) 2018-10-31 2019-04-05 주황윤 Manufacturing method of multi-mineral from industrial waste
KR101966063B1 (en) 2018-10-31 2019-04-05 주황윤 Manufacturing method of multi-mineral comprising Zinc sulfate, Iron sulfate, Copper sulfate and manganese sulphate from electric arc furnace dust, copper waste and Manganese waste

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